TECH BUZZ // ENERGY BY MICHAEL E. WEBBER MECHANICAL ENGINEERING | DECEMBER 2015 | P.16 ENTROPY AND THE ENVIRONMENT A fundamental law of engineering can help inform our future energy decisions. E ngineers generally love orderly solutions to messy problems. But one of the most powerful insights of engineering is that disorder naturally increases, and restoring order takes effort. This revelation is captured by the second law of thermodynamics. That disorder, or entropy, manifests itself through inefficiencies, which means that losses will occur as we use energy. Such losses are unavoidable and show up as waste products that impact the environment. The greater the entropy, the greater the losses, waste, and environmental impact—everything from heated waterways and degraded air quality to land contamination. We may, however, be able use that fundamental insight to help us plan our energy future and tackle greenhouse gas pollution. For example, processes and energy conversions seem to have a natural sequence. A wood log is highly ordered; it contains energy that is neatly organized into a compact space. As the wood burns, its energy disperses as highly disordered smoke, heat, and soot. That example illustrates increasing entropy and exemplifies the second law of thermodynamics: turning fuel into heat and smoke is easy; turning smoke and heat back into fuel is difficult to envision. 1215MEM_Energy_Webber.indd 16 The processes we use to power society follow the natural direction from order to disorder. We burn fuel or run falling water through turbines to turn their stored energy into power. Doing the reverse— taking heat and combustion byproducts to make fuel or pumping water uphill into a reservoir—not only requires energy, but more energy than was released in the first place. Entropy never sleeps. The lessons of the second law of thermodynamics can be used to frame the discussion of environmental impacts. Reversing a process, or increasing order, requires work, so reversing environmental impacts takes energy. The higher the entropy, the greater the environmental impact and the harder it is to reverse it. We as engineers can use entropic flows and measures of entropy to prioritize which impacts to avoid and which to mitigate after the fact. Pollution with the highest entropy is the hardest to remediate. For example, air pollution is made up of very small, highly dispersed particles, which makes it difficult to clean up. Water pollution can flow with the water, so water pollution is also dispersed, but not as much as air pollution. Solid pollution is the most ordered as it does not flow or disperse without help from air and water. From the entropic standpoint, then, avoiding air pollution ought to be the highest environmental priority, since air pollution is the hardest to clean once it has been produced. By contrast, the effects of solid pollution are the easiest to mitigate. That means our environmental mitigation efforts should prioritize avoiding air pollution—including emission of greenhouse gases. At power plants across the United States, pollutants such as NOx and SOx that were once released as gases out of the smokestack are now captured via scrubbers and turned to solid-phase compounds. From the lens of entropic assessment, that seems quite rational. We could look at doing the same with carbon pollution, if feasible. An entropic consideration also supports the cause for nuclear energy and renewables. Nuclear energy avoids hardto-remediate air pollution, and instead creates solid waste that should be easier to contain and manage. This framework can also be helpful for considering approaches to climate change. From an entropic point of view, avoiding the greenhouse gases in the first place is cheaper and less energy-intensive than trying to scrub the atmosphere after the fact. If we use entropic considerations as our guide, then nuclear, wind, and solar, which create finite amounts of solid pollution but avoid air pollution and heat trapping gases, are the choices we should prioritize for a low-carbon energy future. Applying the concept more strictly means that traditional nuclear energy is still somewhat problematic because of the thermal pollution of waterways caused by cooling power plants. We can never escape thermodynamic constraints, but if we use insights about entropy to our advantage, we can make better decisions and avoid wasteful energy consumption. ME MICHAEL E. WEBBER is the Josey Centennial Fellow in Energy Resources and associate professor of mechanical engineering at the University of Texas at Austin. 10/28/15 2:57 PM
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