Physics HSC Course Stage 6 Ideas to implementation Part 5: Crystals Contents Introduction ............................................................................... 2 Transistors take over................................................................. 4 Triode versus transistor ......................................................................4 So what is a microchip? ......................................................................7 Crystals .................................................................................. 10 What is a crystal? ..............................................................................10 The Braggs: Australian Nobel laureates ................................. 15 Electron flow in metals ........................................................... 17 The heating effects of a current .............................................. 24 Summary................................................................................. 29 Suggested answers................................................................. 31 Exercises – Part 5 ................................................................... 33 Part 5: Crystals 1 Introduction The crystalline nature of materials once understood enabled the scientists to make great forward leaps in the development of their understanding of the electrical behaviour of solids. That basic understanding led to the theoretical development of semiconductor technology and an understanding of superconductivity. In Part 5 you will be given opportunities to learn to: • discuss differences between solid state and thermionic devices and discuss why solid state devices replaced thermionic devices • outline the methods used by the Braggs to determine crystal structure and assess the impact of their contribution to an understanding of crystal structure • explain that metals possess a crystal lattice structure • identify that the conducting properties of metals are related to the large number of electrons able to drift through their crystal lattice structure • discuss why drift velocity is related to: • – the density of electrons – the cross sectional area of wire – the electronic charge discuss how the lattice impedes the paths of electrons causing heat to be generated. In Part 5 you will be given opportunities to: • 2 gather, process and present secondary information to discuss how shortcomings in available technology lead to an increased knowledge of the properties of materials with particular reference to the invention of the transistor From ideas to implementation • identify data sources, gather, process, analyse information and use available evidence to assess the impact of the invention of transistors on society with particular reference to their use in microchips and microprocessors. • plan, chose equipment or resources for, and perform a first-hand investigation to observe the heating effects of current in a range of conductors. Extracts from Physics Stage 6 Syllabus © Board of Studies NSW, originally issued 1999. The most up-to-date version can be found on the Board's website at http://www.boardofstudies.nsw.edu.au/syllabus99/syllabus2000_list.html Part 5: Crystals 3 Transistors take over Triode versus transistor A triode is a modified cathode ray tube. The triode has a wire grid inserted between the cathode and the anode. The idea is that a small potential difference set up between the grid and the cathode can make a large difference to the amount of current flowing through the evacuated environment of the tube between the cathode and the anode. The triode is useful for amplification of current in a situation such as a radio where the signal generates a small current in the aerial that needs to be amplified to power speakers and produce sound. The use of a triode (or an alternative thermionic device that behaved similarly) was essential in this application prior to 1954. anode grid heating filament cathode A triode. The idea was that the current set up in the radio aerial would be introduced into the grid of the triode and the result would be a proportionally amplified current flow between the cathode and anode and hence in the external circuit to power the speakers. In 1954 the transistor began to be used in radio. After that initial use the transistor continuously replaced the triode. 4 From ideas to implementation So what is a transistor? In the previous part of this module you learned about p-type and n-type semiconductors and their use in photovoltaic cells. If you don’t recall this information you should return to Part 4 and revise that learning. n p n em itt er co lle ct ba or se The same p and n-type semiconductor materials in contact are used to make transistors. In a transistor the action of the device is analogous to that of a triode. The transistor can be made in two ways. Firstly by sandwiching a thin layer of n-type semiconductor material between two layers of p-type semiconductor material to make a p-n-p transistor or by sandwiching a thin layer of p-type material between two layers of n-type material to make a p-n-p transistor. A schematic figure of a n-p-n transistor is shown in the figure below. A schematic of a transistor. The thin layer of material in the centre can be made to act in the same way as the grid in a thermionic valve. That is, the current flowing from emitter to collector is proportional to the current introduced into the base material. The size of the current flowing between the emitter and the collector is therefore determined by the size of the current available to the base. The maximum size of the current flowing between the collector and emitter is determined by the potential supplied by an external circuit feeding in to the collector and returning to the circuit by the emitter. In a n-p-n transistor as shown in the figure above, electron flow from the n-type material known as the emitter to the p-type material occurs under the influence of a forward potential difference. This is known as a bias voltage. The p-type (or base) material has only a few holes so the current to plug those holes is small. Because the p-type layer is so thin, most electrons are attracted across the thin base by the reverse potential set up on the other side at the p-n connection. This n-type material is acting as an electron collector. Part 5: Crystals 5 The large flow of electrons from the emitter to the collector n-type semiconductor layers is proportional to the small current introduced into the p-type layer. The result is a small current introduced in the p-type (base) material from an external circuit such as from a radio aerial results in a situation where a larger current is able to flow across the n-type materials. This larger current is in proportion to the size of the current introduced into the p-type material and therefore represents an amplification of that introduced current. If no current is introduced into the p-type material then there will be no current flow across the transistor at all. In this way a small current, such as one produced by a radio wave in an aerial that is fed into the transistor base, can be greatly magnified by a signal fed into the transistor collector from an external circuit. This transistor device produces a much stronger signal in the radio circuit than is produced in the antenna. The current in the circuit is, however, proportionally larger. That is, the current is amplified. The setup for a simple crystal, (one transistor) radio is shown below. If the external circuit is connected to a small speaker an audio signal would be heard. itt em n p n a small current flow into the p-type semiconductor results in a large but proportional current flow from collector to emitter er ba se co lle ct or external circuit A transistor in a circuit acting as an amplifier. The relative thickness of the base is magnified in this figure. The potential of the external circuit will determine the maximum size of the current flowing between the emitter and the collector. To see sites that outline the history of the development of the transistor see sites on the physics websites page at: http://www.lmpc.edu.au/science 6 From ideas to implementation The transistor as a switch Transistors can also be used as variable current switches in electrical circuits. Computerised processors rely on logic circuits that work on a binary or on/off system to operate. On/off switching devices are important in this respect. Miniaturised switches are therefore essential. The transistor provides the basis for such a switch. The transistor can operate as a switch because it will not allow current to flow at all until a threshold potential is applied to the base. In a silicon based transistor that potential is around 0.6 V. The miniaturisation of the transistor onto the microchip has meant that circuits using millions of transistors or switches can be placed onto a single microchip device. The transistor can act as a switch because the size of the electric current introduced into the base material of the transistor can vary from zero up to some maximum value. This controls the flow of current through the transistor via the collector and emitter as none or at various levels. So what is a microchip? An electrical circuit on a square of silicon semiconductor crystal. Often the chips are around the size of a finger nail but they may be larger in specialised cases where the circuit is extremely complex. Microprocessors are made on large circular silicon wafers. Each microprocessor or chip is only a small square or rectangle on the large wafer. At the end of the production process individual microprocessor chips are covered in a resin to protect the circuit and are cut from the wafer. After cutting, individual chips are covered in a protective coat of resin and stamped so the processor can be identified. These are the microprocessor chips you see in electronic devices. The process of making an individual microchip is described below. The chip is really a three dimensional complex electrical circuit with each vertical layer built separately. Even individual components such as transistors are built as three separate layers in the circuit. A microprocessor circuit may be made up of millions of transistors and connecting wires. The microprocessor is built up in layers. It starts with a layer of p-type silicon. Layers of conducting material or insulating silicon dioxide are then added. These extra layers are built up using chemicals that are affected by light. The layering process is repeated up to 20 or more times to produce separate layers of the microchip circuit and components onto the chip. Part 5: Crystals 7 The circuits are built by layering insulators and conductors into a twenty or so stack sandwich. The sandwiches are connected by thin layers of metal. These act as wires, joining one layer with another. Building a chip The first step in building circuits is to apply a silicon dioxide insulator to the surface of the silicon wafer. Once the silicon dioxide is in place, it is covered with another layer made of a substance called photoresist. The general process of making the microchip involves shining light through a mask or stencil of the circuit, reducing that light image through the use of optics, and then ‘printing’ the circuit design on a layer of soft lightsensitive material (photoresist). The printing of the circuit and components using light is a process called photolithography. A template is placed over photoresist and exposed to UV light. The template shadows part of the photoresist. The rest is hit with the UV light. The UV exposed photoresist chemical becomes soluble. It is washed off therefore leaving a pattern of photoresist on top of a layer of insulating silicon dioxide. In the next step, a new layer of silicon dioxide is grown on the disc, covering the existing silicon wafer and silicon dioxide pattern. A conducting layer of polysilicon is then applied to the disc along with a new layer of photoresist. The photolithography process is used make a new pattern on the layer of polysilicon. The wafer is etched to cut away any exposed polysilicon and silicon dioxide. The remaining photoresist is cleaned off. This leaves a pattern of silicon dioxide interlaced with a layer of conducting polysilicon. Before more layers are added, completely covering the wafer, a process called doping is used to add ions to the exposed areas of silicon on the wafer. The doping ions alter the conductivity of the semiconducting silicon, creating conducting points within the wafer. After the doping, a thin layer of pure metal is added to the wafer by a plasma spray. This is followed by another round of photolithography and etching that leaves a pattern of metal that wires the various sandwiches together and creates the contact points for the circuits on the next layer. After the initial round of layering an insulator, conductor, and wiring, the whole process repeats, over and over around 20 times. The layers slowly build up, creating a three-dimensional circuit of thousands if not millions of transistors. To see pages that describe the manufacture of microchips see pages on the physics website page at: http://www.lmpc.edu.au/science 8 From ideas to implementation Do Exercises 5.1 to 5.4 now. Early transistors Early transistors were based on germanium crystals. The very first transistor supposedly worked because it was doped with tin. However, there is some debate about this as tin should not have made it work. Instead it may have been an impurity in the tin that caused the first transistor to work. To see a page that has link that describe the chemistry and history of germanium see a page on the physics websites page at: http://www.lmpc.edu.au/science To see a page that has video clips and text that describes how someone tried to replicate the construction of the first transistor, see a site on the physics websites page at: http://www.lmpc.edu.au/science Part 5: Crystals 9 Crystals What is a crystal? You are familiar with crystals. Make a close examination of a grain of sugar or salt with a magnifying glass or hand lens. It will reveal that those substances are crystals. You have probably seen mineral samples that are crystals. The figure below shows a sample of the mineral, quartz. The crystalline nature of the material is obvious. A mineral sample showing quartz crystals. (Photo: Tim Reid) 10 From ideas to implementation Of course these crystals are very large. Many rocks are made of smaller crystals that interlock to hold the rock together. It may surprise you to know that metals are thought of as crystalline. Can you think of an example of a metal or two that is obviously crystalline in nature? If you can, write them down in the space below. _________________________________________________________ _________________________________________________________ Looking for metal crystals Take a walk around the neighbourhood. See if you can find a sheet of corrugated iron that hasn’t been painted. Look closely at the surface of the metal. Describe what you see. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Did you see the crystals? You should have. Those crystals are made up of the metal zinc that is plated on to the surface of the corrugated iron to protect the surface from corrosion. Because the crystals are grown slowly the crystals reach a large size. The longer the time the crystals are allowed to grow over the larger they tend to become. Rapid formation of crystals results in small crystals. Look closely at the crystals of zinc on the surface again. Can you comment on the shape of the crystals. If so, write down what you can see in the space below. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Did you notice that the crystals are all of a similar shape and have similar pointed angles although some of the crystals appear to have grown into each other? If all of the crystals were free to grow without bumping into each other they would have very similar shapes. Part 5: Crystals 11 Now take a look at the quartz crystals shown in the photograph on the previous page. What can you say about the shape of the quartz crystals shown in the figure? _________________________________________________________ _________________________________________________________ Did you say that they were of different sizes but had a similar shape? You should have. In general all substances that form crystals tend to form crystals of a particular shape. In other words the chemical composition of the material determines the shape of the crystals of that material. Iron meteorites are chunks of iron rich material that have grown slowly in outer space. These chunks of rock if cut with a diamond saw often show a distinctive crystalline pattern. An example of such a crystalline pattern is shown in the figure below. The etched surface of an iron meteorite showing a crystalline pattern. You may recall from the preliminary module The world communicates that mineralogists study thin sections of rocks that are made up of minerals with a petrological microscope. Rocks that form from molten lava that have cooled quickly have very small crystals. When they are examined closely they tend to have similar shapes to examples of the same minerals that have grown slowly. The difference is the size of the crystal. Scientists using electron microscopes that can magnify many thousand of times tend to find a similar situation with rocks that have cooled very fast. The crystals are really small but are of the same shape. The obvious conclusion from all these observations is that the crystalline nature of a substance appears to be determined by its chemical composition. That is, the crystalline nature of the substance is controlled and determined at the atomic level. In other words, it is the way that the atoms are bonded together in substance that determines the crystalline nature of the substance. 12 From ideas to implementation You learned in Part 2 of this module that the electron microscope can magnify smaller objects with high resolution to see the finer detail because the electrons used have a shorter wavelength than light. It is the wavelength of the incident ‘radiation’ that determines the resolving power of the instrument. Imagine now that you are a scientist just after the turn of the 19th century. You want to look at atoms and how they are arranged at the finest possible level. That is the finest structure that can be seen. What sort of radiation would you try to use? (Hint: Think about the different wavelengths of the electromagnetic spectrum. You might also consider the size of the atom is of the order of 10-10 m. You also need that radiation to be of a type that is easily recorded on film.) _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answer. If you said in your answer to the question above, a very short wavelength radiation would be best used to study the material, you were absolutely correct. The short wavelength radiation that was available at the time and could leave a record on film was X-ray radiation. This was fortuitous because the recently discovered X-ray radiation was easily produced by common sources and had a wavelength that coincided with the typical distances between atoms in crystalline materials (on the order of 10-10 m). What’s the advantage of that you might ask? The answer is simple. The crystals in materials are characterized by a regular arrangement of atoms. To ‘see’ that arrangement the wavelength of the radiation must be able to resolve the positions of individual atoms. Soon after the discovery of X-rays by Roentgen in 1895, Max von Laue discovered that X-rays were diffracted when passing through crystalline solids. This diffraction pattern was similar to the effect of passing light through an optical grating (a transparent material with hundreds or thousands of parallel lines scratched into it per cm) to produce a diffraction pattern. You may have seen diffraction gratings or the effect of such gratings today. The finely spaced lines on a CD are in effect a diffraction grating. The reflection of light you see coming off the CD is the result of light reflected back from the silvering beneath the diffraction grating. Part 5: Crystals 13 If you take a cheap diode laser pointer and reflect its beam from a CD onto a wall a reflection pattern will form on the wall. That pattern is characteristic of the reflection of light from the irregular surface of the CD. Diffraction patterns Be careful of reflections when you do this activity. Laser light may cause permanent damage to eyes. This activity is optional. You may have access to a small cheap laser pointer. These laser pointers produce red light in the range 630 to 680 nm. They often come with four or five interchangeable heads that can produce different patterns by producing a series of dots when shone on the wall. Those dots are the result of the small lens that the laser light shines through being cut or etched at different angles to produce a diffraction pattern. If you have access to a laser pointer with different pattern heads look at the dots that are produced. Can you see how the central dot is the brightest and most focussed? Also notice that as you move further away from the wall where you are shining the beam, the pattern gets bigger. That is the space between the dots gets bigger. This effect is a type of angular magnification. The size of the diffraction grating lens doesn’t get bigger, just the dot separations do as the laser is moved a larger distance from the wall. If you were to trace each of the beams back to the grating their angle with respect to one another would not have changed over their path of travel. Notice that even a small movement of your hand causes a relatively large movement of the laser pattern on the wall. You may also have access to a piece of diffraction grating. This type of paper is often sold as wrapping paper and gives a hologram or threedimensional effect when you look through it. If the paper is clear it produces a rainbow reflection at its surface when looked at in sunlight. This paper has very fine lines etched into its surface. You can shine a laser beam through the diffraction grating paper and produce the diffraction pattern characteristic of that paper on a wall. 14 From ideas to implementation The Braggs: Australian Nobel laureates The diffraction of light by a crystalline substance produces a characteristic set of dots as radiation is scattered from the different orientations of the solid surface. This idea was used by William Henry Bragg and his son, William Lawrence Bragg to determine the pattern of atoms in the crystal lattice of many substances. They used this technique with particular success in studying the structure of metals. The technique the Braggs applied was relatively simple. The pattern of diffraction of X-rays from the minute crystal lattice surfaces formed as a result of the arrangement of the metal atoms was characteristic. Since these were extremely tiny crystals (at the atomic level) the diffraction patterns could be reinterpreted to give the angles of atoms with respect to one another in the atomic crystal lattice. The technique was using some new technology. The method required the development of efficient X-ray generators, X-ray sensitive film and a stable platform where the sample being studied could be placed so that the reflections could be faithfully recorded. The idea behind the Bragg's technique was that if you couldn’t see how the atoms were arranged directly you could shine a beam of X-rays at the crystal lattice then look at the much magnified diffraction patterns represented as dots and recorded on film. The patterns of dots were drawn back to a point to give the shape of the atomic crystal lattice. That shape could then give clues on the arrangement of the atoms in the atomic crystal. This technique of recording crystalline structures using X-rays was used systematically by Sir William Henry Bragg and William Lawrence Bragg to measure interatomic distances in the crystalline lattice and to analyse the geometrical arrangement of atoms in simple crystals. For that pioneering work on X-ray crystallography they received the Nobel Prize in Physics in 1915. Part 5: Crystals 15 To learn more about the Braggs and their work see the physics websites page at: http://www.lmpc.edu.au/science Do Exercise 5.5 now. 16 From ideas to implementation Electron flow in metals You learned in the module, Electrical energy in the home that the ability of a solid to conduct electricity depends on the type of bonding between the individual atoms. The model of bonding in metals can be described as a sea of valence electrons being common property of all of the positive atomic ions in the metal. These electrons form a so-called sea of electrons that are relatively free to move from positive metal ion to positive metal ion. The 'free' electrons are said to be delocalised. They have random motion at normal temperatures often bouncing about among positive ions but having no uniform direction of motion. Because of this random movement of electrons with equal numbers moving in each direction, a steady state is established. There is no net movement of electric charge in any direction. The situation changes rapidly though when an electric field is applied to the metal. The electric field produces a net velocity of the electrons in the direction opposite to the electric field. The result is a net movement of electric charge in one direction. There is a drift of electrons. In other words a current flows. Even when an electric field is applied across the conductor the passage of the electrons through the conductor is not direct. The speed of the electron movement within the conductor is of the order of 1.6 ¥ 106 ms-1. -5 The electron drift speed is of the order of 1 ¥ 10 ms-1. The reason for this discrepancy is the electrons move in largely random directions within the conducting material, still colliding with positive ions in their path. They simply have a net drift forward induced by the electric field. You may recall that metal conductivity reduces with increasing temperature. If the temperature of the conductor is increased the energy of the electrons is increased, but the net effect is the electrons have more collisions. The figure following shows the passage of the electrons through a conductor under the influence of an electric field. Part 5: Crystals 17 Dv – + The path of an electron passing along a conductor. The passage of the electron even under the influence of an electric field is still largely a random motion. This is because of the numerous collisions with positive ions in its passage toward the positive side of the field. Note that in the figure above all the changes in direction of the electron in its passage along the conductor are the result of collisions between the electron and the positive ionic nuclei of the conductor material atoms. Each of these collisions involves the loss of some energy. That energy is converted to heat energy. In general, the more collisions the electron has, the greater the resistance to its passage. In metals this implies that as the metal heats up, the electrons gain more energy. Their increased movement results in increased numbers of collisions. That increases resistance to current flow. atoms of lattice Electrons bouncing off the vibrating ions. Energy is converted to heat in these collisions Vibrations of the lattice are large and rapid above the superconducting state. Electrons moving through the crystal lattice. The bouncing off from positive ions results in resistance. 18 From ideas to implementation If the energy level of a conductor is lowered to approach absolute zero (0K) the vibration of the ions in the crystal lattice is much reduced. How would that affect the conductivity? _________________________________________________________ _________________________________________________________ Check your answer. When you switch on an electric appliance the appliance receives the flow of electrons called the electric current almost instantly. In fact for practical purposes the appliance receives the electric current instantly. The signal that represents the electrical current could be thought of as travelling at the speed of light. The flow of individual electrons along the conductor is, however, a different matter. That velocity is often much slower. More of the order of mms-1 not 3¥108 ms-1. Predict how the velocity of individual electrons could be so low yet the speed of the electric signal along the conductor could be so high. Write your prediction in the space below then read on to see if you were correct. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ At normal temperatures the ease with which the electrons can flow in a specific direction is controlled by two factors: y The purity of the metal conductor. Impurities affect the metal structure and disrupt the electron sea. This inhibits the forward passage of the electrons. y The temperature of the metal. Higher temperatures tend to cause disruption to the passage of the electrons as the positive ions are vibrating more as they have more energy. The electrons also have more kinetic energy, so collisions between electrons and positive ions are more common. These collisions are inelastic and so transfer energy to the crystal lattice. This slows the direct passage of the electrons. Part 5: Crystals 19 The actual number of electrons that can flow along a particular conductor of depends on two factors. y The type of material from which the conducting wire is made. Different metals conduct with different efficiencies. The resistance of a metal is a specific property of that metal. The relationship is basically governed by the number of free electrons each atom in the conductor can provide to move under the influence of an electric field. y The thickness of the conductor. Like a flow of water along a pipe, the amount of electrons that can flow along a thick (high crosssectional area) conducting wire is greater than the amount of electrons that can flow along a thin (small cross-sectional area) wire. The result of all these factors combined is that even for a pure metal there is a maximum velocity for the passage of individual electrons for a particular conductor of set cross-sectional area at a particular temperature. That velocity is called the drift velocity of electrons. Drift velocity of electrons The drift velocity, v, of an electron in a conducting wire is an average velocity rather than a real velocity. It can be calculated if the following is known: y e, the charge on the electron y the number density of electrons or number of free electrons m-3, n y the cross-sectional area of the wire, A y the length of the conductor, l y the current flowing through the conductor, I These quantities are related through the relationship I = nAev therefore v= I nAe Example Determine the drift speed in a copper wire of cross- sectional area 1 ¥ 10-7 m2 if a current of 1 A is flowing through it. The n for copper metal is 8 ¥ 1028 m-3. 20 From ideas to implementation Solution v= I nAe 1 8 ¥ 10 ¥ 1 ¥ 10 -7 ¥ 1.6 ¥ 10 -19 = 0.00078 ms -1 = 28 As you can see this drift velocity is very slow indeed! 1 If the current in the wire above is raised to 10 A, what is the new drift velocity of the electrons in the wire from the example above? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ 2 Look at the equation for determining the drift velocity of electrons along a conductor. v= I nAe Discuss why the drift velocity is related to each of the variables represented in the equation above. _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Check your answers. Part 5: Crystals 21 The crystal lattice and electron passage The passage of a free electron in a metal crystal lattice occurs from atom to atom. That passage is impeded because of the following factors. • Collisions take place between conductive free electrons and the ionic cores of the metal atoms as they vibrate about their median positions in the lattice randomly. • Impurities exist in the lattice. These could include the substitution of a smaller ion or a larger ion. • Lattice imperfections such as the missing atoms or caused by the inclusion of an additional small atom of a different type into the lattice. These all tend to disrupt the passage of the free electrons through the lattice. That increases the resistance of the metal. The diagrams following show situations where impurities in the metal cause an increase in the resistance in the conductor. Note how each situation tends to deform the lattice in some way. 22 missing atom small atom substituting for metal ion small additional atom large atom substituting for metal ion From ideas to implementation If a free electron travelling from atom to atom in the crystal lattice encounters an irregularity in the lattice its path must deviate in order to navigate past the irregularity. That deviation can be considered as resistance and is usually caused by collisions of the free electrons with other core metal ions in the lattice. Do Exercise 5.6 now. Part 5: Crystals 23 The heating effects of a current One of the activities you are required to perform in this module is to: ‘Plan, chose equipment or resources for, and perform a first-hand investigation to observe the heating effects of current in a range of conductors.’ Extracts from Physics Stage 6 Syllabus © Board of Studies NSW, originally issued 1999. The most up-to-date version is to be found at http://www.boardofstudies.nsw.edu.au/syllabus99/syllabus2000_list.html Read the information following. You will then be asked to design an exercise to do this activity. For a current to produce heating effects, the conductor must resist the flow of current. Heat is produced as power is dissipated in the conductor. Really the power is just a way of saying the rate at which energy is converted from electrical energy to some other form of energy. In the case of a conducting wire electrical energy is simply converted directly into heat energy. This is a real problem in power lines where the electricity must be conducted along wires from a power station to the user of the electricity many kilometres away. The equations that describe power are: P = I 2 R and P = VI Where I is the current in the conductor, R is the resistance of the conductor and V is the voltage across the conductor Consider the resistance of copper wire of typically used in wires is around 8 W km-1. This means if the electricity is transported at a current of 100 A over a distance of only 1 km from the power station, the power used in conduction can be staggering. 24 From ideas to implementation P = I2R = 100 2 ¥ 8 = 80 000 W This power is converted into heat energy. Using efficient conductors is therefore critical. In the next part of this module you will be introduced to the concept of using superconductors with no resistance to transport electrical currents. The energy savings could be well worth the effort. Consider the equations describing power. What factor should be kept constant in order to be able to systematically study the heating effect of an electric current in a variety of conductors as a result of power dissipation? _________________________________________________________ _________________________________________________________ Check your answer. The electric current supplied by a new 6 V DC battery is usually fairly constant. This is because of the large size of the battery. Smaller batteries have difficulty in maintaining current output for extended periods. In the module Electrical energy in the home you learned that the resistance of a conductor is determined from the relationship: R = r¥L where A r is the resistivity of the conductor used R is the resistance A is the cross sectional area of the conductor L is the length of the conductor. The units of resistivity are ohm metres ( Wm ). An examination of this equation leads to the relationship that the resistance is dependent upon the following factors. • The type of material from which the conductor is made. • The diameter of the conductor (assuming it is cylindrical). This information allows the calculation of the cross-sectional area. • The length of the conductor. If you were to seek to determine the heating effect of a current in a range of conductors you would need to limit the experiment to consider only the type of material tested as the variable. That is, the type of material the current passes through should be the only difference in separate trials of the experiment to determine the difference between any conductors examined to determine the heating effects of a current. Part 5: Crystals 25 What factors would you need to keep constant between different conductors used in your investigation to determine the heating effects of a current? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answer. Consider how the heat energy produced by the electrical energy can be converted to heat energy and measured in your investigation. Measuring the temperature of a wire directly is difficult. An easier alternative is to indirectly the measure the rise in temperature of the wire by measuring the energy dissipated from the wire to a known mass of water in a set period of time. You may recall from the module Electrical energy in the home the experiment that you performed to measure the energy dissipated by passing an electrical current at a known voltage across a resistive wire. To refresh your memory the experiment is repeated below. Do not repeat this experiment exactly again. This experiment is simply repeated here to give you a hint as to how you might plan an experiment to enable you to observe the heating effects of current in a range of conductors. You may do this activity yourself, or at your practical session with your teacher. You will need the following equipment to perform this experiment: 26 • a 6 V DC power source either a battery or a transformer rectifier unit • a 10 cm length of nichrome wire • a multimeter • connecting wires • a styrofoam coffee cup that will act as a calorimeter (a device useful to measure energy gain by a liquid) • a thermometer like the ones used in tropical fish tanks • a watch with a second hand. From ideas to implementation Procedure: 1 Coil the length of nichrome wire around a pencil to produce a coil. This will act as your heating element. 2 Add 50 mL of water to the styrofoam cup using a measuring cup or a medicine measuring cup. 3 Connect the circuit up as shown in the figure following. Make sure you have your heating coil submerged under the water in the styrofoam cup when you connect up the circuit to prevent overheating the nichrome heating element. 6V nichrome wire coil 50 mL of water styrofoam cup 4 Connect your multimeter into the circuit in series as shown in the circuit below with the setting dial on the A settings. Record the current flowing in the circuit. 5 Record the temperature and time when you start heating the water. 6 Connect your multimeter into the circuit in parallel across the nichrome wire heating element with the multimeter on the V setting. Record the actual voltage across the nichrome heating element. 7 After three minutes measure the temperature of the water again. Record the temperature rise. Complete the table below to calculate the temperature rise of the water. Disconnect the battery to avoid it going flat. 8 Calculate the energy gain of the water using the formula: Egained = mcDT Part 5: Crystals where m is the mass of water in kg (1000 mL = 1 kg) c is the specific heat of the water (4.18 kJkg-1K-1) DT is the temperature rise in degrees 27 temperature of water after 3 min heating = ___________________ temperature of water at start of heating = ____________________ therefore the temperature difference (DT) = __________________ mass of water, m = 0.05 kg Egained = mcDT = _______________________________________ 9 Calculate the energy input by the heating coil from the formula: E = VIt Current in circuit, I = ____________________________________ voltage across heating coil, V = ____________________________ time, t = 180 s E = VIt = _____________________________________________ 10 How does the energy supplied to the water by the electric heating coil compare to the energy actually gained by the water? Propose an explanation for any differences ______________________________________________________ ______________________________________________________ You should now design an experiment based on the information above incorporating any variations necessary to observe the heating effects of current in a range of conductors. Do not perform the experiment until you ensured that the procedure you intend to use is safe. You must discuss what you intend to do with your supervisor before you do the experiment. After receiving approval to perform your planned experiment from your supervisor you should perform the experiment and report your results and observations to your teacher. Write up your experiment as a practical report and submit it to your teacher with your exercises for Part 6 of this module. Remember to describe what you did and found accurately. Discuss any improvements you might make to your experiment to improve its accuracy in your report. It may be you could not do these modifications because of equipment limitations. You should, however, include any proposed improvements with your report. 28 From ideas to implementation Summary The differences between thermionic and solid state devices especially with respect to triodes and transistors are: _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ The major impact of the invention of the transistor on society has been to: _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ The Braggs developed a method of determining the crystal structure of materials. What was that method? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Conduction of electric currents in a metal can be explained as due to: _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Part 5: Crystals 29 Drift velocity of electrons in a conductor is related to: ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ 30 From ideas to implementation Suggested answers Looking for metal crystals The shortest possible wavelength radiation that could be produced reliably and safely would have been required to observe atomic structure. X-ray radiation may have come to mind because it was discovered, easily produced and relatively well understood by early in the 20th century. X-ray radiation was also of a wavelength approaching atomic distances and diameters. Electron flow in metals Resistance to conductivity should be reduced almost to zero, if not to zero. This is because of the reduced number of collisions between the electrons and the lack of vibrating atoms. Drift velocity of electrons 1 v = I nAe 10 8 ¥ 10 ¥ 1 ¥ 10 -7 ¥ 1.6 ¥ 10 -19 = 0.0078 ms-1 = 2 28 Increasing the current flow along the wire means an increase in the number of charges per second passing along the wire. This is shown from I = q where q is the charge and t is the time. t The increased cross sectional area of the wire means a greater number of atoms to facilitate movement and increase in the electrons available to be conducted. The type of material is important because that determines the number of electrons available in the conduction band. The charge on the electron determines the type of interactions the charge carrier will have with other atoms in the material along which conduction is occurring. Part 5: Crystals 31 The heating effects of a current The current flowing through the conductor should be kept constant. This can be accomplished by using a DC source such as a fresh dry cell battery. The length of the conductor should be kept constant. The cross-sectional area of the conductor s tested should be the same. If using wires, then the wires should be the same gauge wire. These factors, if kept constant, ensures that you are looking for variation in the resistance due only to a difference in the material from which the conductor is made. 32 From ideas to implementation Exercises – Part 5 Exercises 5.1 to 5.6 Name: _________________________________ Exercise 5.1 Microchips and microprocessors are a part of your daily life. They have invaded almost all aspects of the way you live. In this exercise you will assess the impact of the invention of the transistor on society. Refer particularly to the use of transistors in microchips and microprocessors. To do this you must first locate relevant information eg. Internet search, library search, survey a cross-section of your community. Then you must collect and organise this information so you can make a judgement about the impact of the invention of the transistor on society. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Part 5: Crystals 33 Exercise 5.2 The invention of solid state (or transistor) devices was desirable because the use of thermionic devices was often too difficult, too costly and required a large power input. Portability was essential to the development of modern communication devices. Gather, summarise and present information from secondary sources that describe how increased knowledge of semiconductor behaviour lead to the development of the solid state equivalent of the triode, the transistor. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Exercise 5.3 The structure of the transistor is particularly suited to being constructed in layered manufacturing procedures such as those used in the manufacture of microchips. Explain why. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ 34 From ideas to implementation Exercise 5.4 Describe, with the aid of diagrams how doping affects a p and n type semiconductors and their ability to conduct electricity. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Exercise 5.5 The contribution of the Braggs to an understanding of the crystal structure is undisputed. Assess the impact of their contribution to the understanding of the crystalline structure of materials. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Part 5: Crystals 35 Exercise 5.6 What are the factors in the crystal lattice of a metal that can impede the flow of electrons causing heat to be generated? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ 36 From ideas to implementation
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