Product # LNIT
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MATERIAL SAFETY DATA SHEET
Lead Nitrate
Section 01 - Chemical And Product And Company Information
Product Identifier ……………………..
Lead Nitrate
Product Use ……………………………
Not Available
Supplier Name……………………….…
ClearTech Industries Inc.
2303 Hanselman Avenue
Saskatoon SK S7l 5Z3
Canada
Prepared By................……………..….
ClearTech Industries Inc. Technical Department
Phone: (306)664-2522
Preparation Date.........…………….….
August 12, 2002
24-Hour Emergency Phone………….
306-664-2522
Section 02 - Composition / Information on Ingredients
Hazardous Ingredients....…………..
Lead Nitrate
99.0%
CAS Number...................…….……..
Lead Nitrate
10099-74-8
Synonym (s)...................…………….
Lead (II) nitrate (1:1); lead dinitrate; nitric acid, lead (2+)
Section 03 - Hazard Identification
Inhalation...................………….….
Lead can be absorbed through the respiratory system. Local irritation of
bronchia and lungs can occur and, in cases of acute exposure, symptoms
such as metallic taste, chest and abdominal pain, and increased lead blood
levels may follow. See also Ingestion.
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Skin Contact / Absorption…….…
Lead and lead compounds may be absorbed through the skin on prolonged
exposure; the symptoms of lead poisoning described for ingestion exposure
may occur. Contact over short periods may cause local irritation, redness and
pain.
Eye Contact................………….…...
Absorption can occur through eye tissues but the more common hazards are
local irritation or abrasion.
Ingestion.....................………………
Poisonous. The symptoms of lead poisoning include abdominal pain and
spasms, nausea, vomiting, headache. Acute poisoning can lead to muscle
weakness, "lead line" on the gums, metallic taste, definite loss of appetite,
insomnia, dizziness, high lead levels in blood and urine with shock, coma and
death in extreme cases. Nitrates entering the body by any route (ingestion,
inhalation, or absorption), can cause headache vomiting, dizziness, cyanosis,
decreased blood pressure, and possibly respiratory paralysis.
Exposure Limits……………………..
TLV = 0.15mg/m3 (ACGIH)
PEL = 0.05mg/m3 (OSHA)
Section 04 - First Aid Measures
Inhalation....................………………
Remove victim to fresh air. Give artificial respiration only if breathing has
stopped. If breathing is difficult, give oxygen. Seek immediate medical
attention.
Skin Contact / Absorption…………
Remove contaminated clothing. Wash affected area with soap and water.
Seek medical attention if irritation occurs or persists
Eye Contact..................……………..
Flush immediately with water for at least 20 minutes. Forcibly hold eyelids
apart to ensure complete irrigation of eye tissue. Seek immediate medical
attention
Ingestion......................………………
Induce vomiting immediately as directed by medical personnel. Never give
anything by mouth to an unconscious person. Get medical attention.
Section 05 - Fire Fighting
Conditions of Flammability………..
Not combustible but is a hazardous oxidizing material. In contact with easily
oxidizable substances may cause ignition, violent combustion or explosion.
Increases the flammability of combustible materials.
Means of Extinction........…………..
Use any means suitable for extinguishing surrounding fire. Do not allow water
runoff to enter sewers or waterways.
Flash Point....…………………………
Not Applicable.
Auto-ignition Temperature…………
Not Applicable.
Product # LNIT
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Upper Flammable Limit ……………
Not Applicable.
Lower Flammable Limit...……….…
Not Applicable.
Hazardous Combustible Products.
Oxides of Nitrogen and Lead Fumes
Special Fire Fighting Procedures...
Wear NIOSH-approved self-contained breathing Apparatus and protective
clothing.
Explosion Hazards………………….
Strong oxidants may explode when shocked, or if exposed to heat, flame, or
friction. Also may act as initiation source for dust or vapor explosions.
Section 06 - Accidental Release Measures
Leak / Spill................….……………..
Steps to be taken in event of spill or release (in all cases notify applicable
Government Authority if spill is significant): Wear self-contained breathing
apparatus and full protective clothing. Keep combustibles (Wood, paper, oil,
etc.) away from spilled materials. With clean shovel, carefully place material
into clean, dry container and cover; remove from area. Flush spill area with
water.
Deactivating Materials...……….…...
Not Available.
Section 07 - Handling and Storage
Handling Procedures.......…………..
Use proper equipment for lifting and transporting all containers. Use sensible
industrial hygiene and housekeeping practices. Wash thoroughly after
handling. Avoid all situations that could lead to harmful exposure.
Storage Requirements......……...….
Keep in a tightly closed container. Store in a cool, dry, ventilated area away
from sources of heat or ignition. Protect against physical damage. Store
separately from reactive or combustible materials, and out of direct sunlight.
Isolate from incompatible substances. Areas in which exposure to lead metal
or lead compounds may occur should be identified by signs or appropriate
means, and access to the area should be limited to authorized persons.
Containers of this material may be hazardous when empty since they retain
product residues (dust, solids); observe all warnings and precautions listed for
the product.
Section 08 - Personal Protection and Exposure Controls
Protective Equipment
Eyes.………………………….………..
Chemical goggles, full-face shield, or a full-face respirator is to be worn at all
times when product is handled. Contact lenses should not be worn; they may
contribute to severe eye injury.
Product # LNIT
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Respiratory…………………………...
Gloves………………………………....
None required when adequate ventilation conditions exist. If airborne
concentration exceeds TLV, a high efficiency particle respirator is
recommended. If concentration exceeds capacity of respirator, a selfcontained breathing apparatus is advised.
Impervious gloves of chemically resistant material (rubber or PVC) should be
worn at all times. Wash contaminated clothing with soap and water, dry
thoroughly before reuse.
Clothing………………………..……...
Body suits, aprons, and/or coveralls of chemical resistant material should be
worn at all times. Wash contaminated clothing with soap and water, dry
thoroughly before reuse.
Footwear……………………………....
Impervious boots of chemically resistant material should be worn at all times
Other…………………………….……..
Eating, drinking, and smoking should not be permitted in areas where solids
or liquids containing lead compounds are handled, processed, or stored.
Engineering Controls
Ventilation Requirements……….....
A system of local and/or general exhaust is recommended to keep employee
exposures below the Airborne Exposure Limits. Local exhaust ventilation is
generally preferred because it can control the emissions of the contaminant at
its source, preventing dispersion of it into the general work area.
Other…………………………………...
Emergency shower and eyewash should be in close proximity.
Section 09 - Physical and Chemical Properties
Physical State.......……....…………..
Solid, oxidizer
Odor and Appearance…..…………..
Colourless or white crystals, odorless
Odor Threshold....……………..........
Not applicable
Specific Gravity (Water=1)…………
4.53
Vapor Pressure (mm Hg, 20C)….…
Not available
Vapor Density (Air=1)..……………..
11.0
Evaporation Rate........……..…….….
Not available
Boiling Point...............………….…...
Not available
Freeze/Melting Point....……………..
470°C (878°F)
pH............................……………….…
3.0 – 4.0 (20% aq. Solution)
Water/Oil Distribution Coefficient...
Not available
Bulk Density..............…………….….
130 lbs per cubic foot
Product # LNIT
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% Volatiles by Volume………..…….
0% at 20°C
Solubility in Water...………………...
Appreciable (>10%)
Molecular Formula......………….…..
N2O6Pb
Molecular Weight........……………...
331.21
Section 10 - Stability and Reactivity
Stability.................…………....……………
Stable under ordinary conditions of use and storage
Incompatibility..............…………..……….
Ammonium thiocyanate, powdered carbon, lead hypophosphite,
hydrogen peroxide, combustibles and organic materials.
Hazardous Products of Decomposition
Oxides of nitrogen, lead fumes
Polymerization...........…………….…….…
Will Not Occur.
Section 11 - Toxicological Information
Irritancy.................……..………….…
Not available
Sensitization........…….......…………
Not available
Chronic/Acute Effects……...……….
Not available
Synergistic Materials...……....……..
Not available
Animal Toxicity Data......…..……….
Not available
Carcinogenicity......……......………..
Lead is listed as a IARC(Group 2B) possible carcinogen to humans
Reproductive Toxicity..…...………..
Lead may have teratogenic effects on preborn offspring and adverse effects
on human reproductive capabilities.
Teratogenicity..........….....…………..
Not available
Mutagenicity...........…….....…………
Not available
Section 12 - Ecological Information
Fish Toxicity..................…………….
Not avaliable
Biodegradability.............……….…...
Not available
Product # LNIT
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Environmental Effects………………
For lead and inorganic lead compounds: When released into the soil, this
material is not expected to leach into groundwater. This material may
bioaccumulate to some extent
Section 13 - Disposal Considerations
Waste Disposal...........…...………….
Whatever cannot be saved for recovery or recycling should be handled as
hazardous waste and sent to a RCRA approved waste facility. Processing,
use or contamination of this product may change the waste management
options. Provincial and local disposal regulations may differ from federal
disposal regulations. Dispose of container and unused contents in accordance
with federal, provincial and local requirements, including the Canadian
Environmental Protection Act.
Section 14 - Transportation Information
TDG Classification
Class……………..………………..…..
5.1 (6.1) (9.2)
Group...............…………….......…….
II
PIN Number.................……..………..
UN1469
Other…………………………………...
Secure containers (full and/or empty) with suitable hold down devises during
shipment.
Section 15 - Regulatory Information
WHMIS Classification.......………… C D1, D2
NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD
CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL
INFORMATION REQUIRED BY THOSE REGULATIONS
Section 16 - Other Information
Note: The responsibility to provide a safe workplace remains with the user. The user should consider the
health hazards and safety information contained herein as a guide and should take those precautions
required in an individual operation to instruct employees and develop work practice procedures for a safe
work environment. The information contained herein is, to the best of our knowledge and belief, accurate.
However, since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to
comply with all applicable laws and regulations.
Product # LNIT
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ClearTech Industries Inc. - Locations
Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3
Phone: 306-664-2522
Fax: 306-665-6216
www.ClearTech.ca
Location
Richmond BC
Calgary AB
Edmonton AB
Saskatoon SK
Regina SK
Winnipeg MB
Mississauga ON
Address
12431 Horseshoe way
5516E - 40th St. S.E.
11750 - 180th Street
2302 Hanselman Avenue
555 Henderson Drive
340 Saulteaux Crescent
7480 Bath Road
Postal Code
V7A 4X6
T2C 2A1
T5S 1N7
S7L 5Z3
S42 5X2
R3J 3T2
L4T 1L2
Phone Number
604-272-4000
403-279-1096
780-452-6000
306-933-0177
306-721-7737
204-987-9777
905-612-0566
Fax Number
604-272-4596
403-236-0989
780-452-4600
306-933-3282
306-721-8611
204-987-9770
905-612-0575
24 Hour Emergency Number - All Locations - 306-664-2522