•
NOTICL
The information contained in this report is regar~ed as con­
fidential and proprietary. It is provided subject to the
proviaions regarding confidential, proprietary information
contained in the ::zesearch l\greement among the Participating
Parties.
r!.OBIL OIL CORPORATIOi.J
RESEAP..CH DEPARTi,i£NT
TLCHi:HCAL
HEI'iOP~.NDurC
NO.
67- 9
HEAT AND l'lATERIAL BALANCE COllPUTER PROGFAIv1
ANVIL POH1TS OIL SHALE RESEARCH
CEi'iTER
Rifle, Colorado
August 4, 1967
Author:
R. A. Reitz
Approval:
..-~ \~
\ ,
Contributing Author:
E. E. Turner
J
R. h. Cramer
Program !1anager
- 2 ­
The primary object of the Anvil Points Oil Shale Research
Center TECHNICAL r~I.IlORANDU1'il is to advise authorized personnel
employed by the Participating Parties(l) that various
activities are in progress or that certain significant data
have been obtained within the Research Center.
These TECHNICAL r1Ei10RAUDA have been prepared to provide rapid,
on-the-spot reporting of research currently in progress at
Anvil Points. The conclusions drawn by project personnel are
tentative and may be subject to change as work progresses.
The TECHNICAL MU'lORANDP. have not been edited in detail.
(l)Mobil Oil Corporation, Project Manager
Continental Oil Company Humble Oil and Refining Company Pan American Petroleum Corporation Phillips Petroleum Company Sinclair Research, Inc. - 3 ­
HEAT AND r-1ATERIAL BALANCE COHPUTER PROGRAM
TABLE OF CONTENTS
Page
I. ..•
Introduction.
4
• 5
II. Summary • • • •
III. Detailed Discussion • • • • • • • • • •
• ••••
A.
Retort No. 3 Configuration • • • • • • •
• •
B.
Description of The Appendices.
• • • • •
C. Future Program Documentation • • • • • • • • • •
6
6
6
6
FIGURES 1
Computer Program Analogue For Retort No. 3 TABLES 1
Computer Terminology For Flow Meters APPENDICES
A
Block Diagram of Computer Program
B
Conversion of Variable Names
C
Dictionary of Variables
D
Index To Computer Variables
E
Sample Case Input and Output Forms with Definitions for
Input Terms
- 4 ­
HEAT AND l·1ATERIAL BALANCE CONiPUTER
I.
PROGRAI~
INTRODUCTION
The computer program to calculate material and heat balances
for the pilot retorts has been in general use since its incep­
tion. Details of the original program are described in Tech­
nical lo1emorandum 65-3, iYlaterial and Heat Balances For Pilot
Retorts. However, many changes have been made to the original
program to correct minor errors, extend its usefulness, and
to adapt it to Retort No.3. Technical f'lemorandum 65-3 has
not been kept up to date, and details of the changes were not
widely distributdd.
Results of the computer program calculations are important to
the research effort, and ~etails of the calculations must be
readily available. The documentation effort presented in this
memorandum was done to provide an updated and usable reference
for the heat and material balance calculations.
... 5 ... II
SUMIvlARY
A complete and updated documentation of the computer program
for pilot retort heat and material balances is given in the
Appendices. The goals of this work were to provide sufficient
information so that persons relatively unfamiliar with the
calculations would find it useful, and to present the infor­
mation in a format that can be easily updated.
The calculation sequence, which is given in Appendix A, was
translated directly from the FOR'l'RAN compilation, and cross
checked against the required equations to insure correctness.
A revised dictionary of variables and an index to where
variables appear are included as Appendices. These will allow
quick identification of the terms in an equation, and allow
quick tracing of variables to see how they enter into the
calculations.
Should any changes in the computer program become necessary
in the future, this work will be updated simply by issuing
revisions for those pages of the appendices affected.
- 6 ­
III. DETAILED DISCUSSION
A.
Retort No. ·3 Configuration
Several changes were made in the fall of 1966 to account
for minor differences in equipment configurations between
Retort No. 2 and the then to be started up Retort No.3.
Figure 1 shows a schematic of Retort No. 3 flow streams
as the computer program is set up to handle them. Table 1
gives additional information on the meters and the correct
data input for the various gas rates.
Heat and material balances can be calculated for either
Retort No. 2 or Retort No.3. The calculation option is
specified by setting input variable "li" as 0.0 for Retort
1-;0. 3 or 1.0 for Retort No.2.
Bases used for the heat and material balance are essentially
unchanged from those stated in Technical Nemorandum 65-3.
B.
Description of The Appendices
Five appendices are attached which document the current
version of the computer program. Appendix A is a block
diagram of the program \'lhich gives the calculation steps
in exactly the same way as the computer handles them.
Appendix A is a direct translation of the FORTRru~ source
program.
Appendix C lists the meaning and units associated with each
of the computer variables. Appendix B gives a conversion
between variable names used in Technical 1·1emorandum 65-3
and this memorandum for those names which are different.
Appendix D
on which a
times on a
only once.
Appendix D
is an index which gives the pages of Appendix A
variable appears. A variable may appear several
specific page, but that page will be listed
The type of variable is also listed in
as an addeQ convenience.
Appendix E contains input and output forms based on an
actual Retort No. 3 balance. Also included in this
appendix are definitions and sources for all input data.
C.
Future Program Documentation
It is planned to promptly document any future changes to
the computer program. The pages of the appendices affected
will be revised, and these revisions will be distributed
to all recipients.of technical memoranda.
~ SEAL
GAS
SeAL
TOP
RAW SHALti'
~----~
I
r-r.' --"-1
R~COVERY
SYSTeM
GAS
~-~
Llc.9tJID
PRODUCT
VENT PtJRGE
CONtJE/lSER
~/R
RETORT
I
I
PROPANe
: RECYCLE
~_ J
BOTTOM
S/tAL
GA-=...S_ _ _ _.....J
n
SPl:fI't
SHALE:
VeNT pl.JRGe
l.ltJU/P$
== LEG£NIJ ==
--11r--
S
ROTAMcT6"R
~
COMPUTER
-
-
_
•• _
PROGR,4M
ORIFICE METER
-
METER NUMBE'!?
(SlfE TAELE I)
MATERIAl..
... HEAT
BALANce BOUNDARY
ANALOGUE
=..::....-:::-...:;:::'::..-=.":.--::::-.::;::::::.::=:::;.~.::;::::-;:.=:::'=.====:=:::=:..'==-~;:::=:::::--"~::--::::-~-::.::...-;-=--::--=-~.~:.;;:;:;-...::.:::::.-:..
FOR
R TORT __ NO.3
===::::=~,""",==:====-=.::-:c- ,,:::.=-="=";.:c.::;;
J3ALANC£ BOIJ/IOARY
I
TABLE 1
COMPUTER TERMINOLOGY FOR FLOW METERS
No.
Stream
Internal
Computer
Variable
1
. Air
A
2
Recycle
REC
3
Dilution
DILG
4
Propane
P
5
Vent
G
6
Vent Purge
VPR
7
Top Seal Gas
GL
8
Bottom Seal Gas
Input Data
Pressure
Temperature
PDG
TDG PP
TP Chart
Reading
Meter Factor CRA
ZZMFA* Flow Computer CRRG
ZZMFRG* Flow Computer CRDG
ZZMFDG Standard Orifice
p**
CRVG PVP
CRVP TVP
Meter Type Rotameter
ZZMFVG* VPMF Flow Computer
Standard Orifice
Rotameter
*Should be specified as 1.0
**Program input should be in SCFM of propane
-.....
RAReitz
7/28/67
APPENDIX A
BLOCK DIAGRAM OF COr.'lPUTER PROGRAH
LEGEND:
Terminal point in program.
C---} Calculation.
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(----.. ..
I
I
--.J~
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Data output.
o
-----t;..­
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Flow direction. Flow is always left to
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~_I)U.:)
END HESShGB
~~i~tG~
out
sho~n
in
Paqe 13
o lPI'PU 'P
YIELDS
A.
(FAY)
(H2)
(CH4)
(C0)
(C9-i2)
FAY
H2
CH4
co
CO2
B.
RECG
AIR
DHYGli.S
O'I'HEE
02
_"'_ •.-1'
~"
D.
COMBUSTION PRODUCTS C02 C
,(C02C) CIIE
(CHR) r1A'l'EIUAL IH
(rl:'")GC
'[~-)
YJI-. 'I .,~
(ZBh'I'IN)
F.
SSY
DIL
(DIT.)
rrlU::CG
(r~er~I;(~(~
C.
110T.1 \':'1' & HEhTING Vl'.l.,(JE OF VEd'.r GAS
MW'JG
(ZZ:'JU\JG) IIvc'r
GSrrU
(GS'i'U) E.
(02)
(Cy1 2 DEC)
f~: i~~",i
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nGC-.'('"<~
O .\.
IvlA'rIN
Ui·JI()i;fl~O
•
(~,ijnJq6L)
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C02DI~C
l'm'1'mmD C;ZiS l~li'I'I~S
(PT'Cr: )
J 1;
. _
(Z'JUl\Jl')
(DrC'!.:"
s)
J. y. . . 7. 1-:"1.
(o'nrr'C)
t,.L\. }
)
\'JVEn"l'G
(I'J"VEN!,['G)
'l'GF
(ll'Gr:' )
(Z Z,:ll:JDG)
(lIVC'?)
COC
CO)':lBCP
(C0C)
(Cyt,lDCP)
H20 C
(E2)OC)
RSI{
(RSR)
ORH2IN
COKEC
ORII2 VG
OR1:l20L
ORCSSP
(qolmC)
(jOHH2VG)
(0R H2vJI.)
(0RCSSP)
UNHETII
COKI!:H
ORC01.P
llCCVGP
(UNRETH)
(C0l<EH)
(0RC¢LP)
(HCCVGP)
OHlI2
(0HGH 2)
TC
(,re)
(\'Jl'.'rEH)
'1' II 2
(TH2)
02BAL
HA'l'EH
GAS1.
QH20C
(Q82)
QI\.IR
QOILC
(Q83 )
QHCYJ..,
QKEROD
QOFG1\S
J.JBLOSS
(Q75)
VPOIL
t'JCG
(VP0IL)
I
•
NI1TERIAL OUT
ORGCVG
ORGCOL
(jORGCVG)
(0HGC):61.)
UNRETC
(UNRETC)
ORCVGP
(0RCVGP)
G.
Ilh'rERIAL DALAI''JCES
(¢VAI.L)
OVJ\J':'L
ASH
(ASH)
ORGC
(~EGC)
ASBE
(02BA.L)
(Gli.SL)
(ASHn)
H.
HE1\T IN QCONE
(QC0HB) QPROP
((2515 ) (QSmUN) QSUl1IN
HEA'I' 0'01'
(Q74)
Qj':'IQO
(QL1Q0)
QGilB1.
(QGl\SI..)
QSUI-lO'l'
(QSUMr6T)
(Ol\IH)
(QRCYL)
I •
QMC0 2 D
J. MISCBLLANEOUS
ORCSS
(0RCSS)
VPj1
(VPN)
(Q~J?GAS)
QSS
(ZHL0SS)
(i'JCG)
Ei'lD HESSll.GE
in
'1'('.1.
P110P
(Q84)
(QSS)
(HE'I'Ly5S)
('rGL)
(PR0P)
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+
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APPENDIX B
CONVERSION OF VARIABLE NAMES
This Hemorandum .
Technical Memorandum 65-3
L
ZZL
LBHL¢SS
ZBL¢SS
LBHL
ZZLBHL
M
ZZM
MATIN
I
MAT¢UT
ZMATIN
ZAT¢UT
MEG
ZZMEG
MH2¢
ZZMH2¢
MH2¢VG
ZH2¢VG
MIST
ZZMIST
MISTFA
ZISTFA
MISTRG
'e I
,.
ZISTRG
MRS
ZZHRS
MWDG
ZZMWDG
MWWG
ZZMW\vG
N
ZZN NG
ZZNG N2RG
ZZN2RG APPENDIX C
DICTIONARY OF VARIABLES - CONPU'rr'::R PROGRAN
Fot Pilot Retort Material and Heat Balances
Term
Air entering retort, lbs. Air/hour. Air entering retort, lbs. Air/ton raw shale. Ash Balance, Ash Out/Ash In, Weight %. Basis for calculation of ra\V' and spent shale rates. -1 when measured raw shale rate used and
spent shale rate calculated from ash
balance.
D when measured raw shale and spent shale
rates used.
1 vlhen measured spent shale rate used and
raw shale rate calculated from ash balance.
Ash entering retort in raw sha~e, lbs. Ash/ton
raw shale.
Ash in spent shale, lbs. Ash/ton raw shale.
Raw shale ash content, Weight %.
Spent shale ash content, Weight %.
A
AIR ASH ASHB . ASHI
ASII~UT
ASRS
ASSS
Program option. Specify:
-1 to use measured raw shale rate and cal­
culate spent shale rate by ash balance.
D to use measured raw and spent shale rates.
1 to use measured spent shale rate and
calculate raw shale rate by ash balance.
Barometric pressure. Input in inches of Hg
which is converted to inches of H20 in the
program.
B
, BP
CG
CHR
CH2~GF ('1' 1,
CH4 CH4RG C~ C~C C~G C~KEC T 2)
Total
carbon in the dry vent gas, lbs. per MSCF.
Carbon to hydrogen ratio of material burned,
Ibs. carbon/lbs. hydrogen.
Mean specific heat of water vapor between tempera­
tures Tl and T2, BTU/lb.- F.
Methane in dry vent gas, SCF/Ton rat., shale.
Methane in total dry recycle gas, lbs/ton raw ~hale.
CO in dry vent gas, SCF/Ton raw shale.
CO formed by combustion, SCF/Ton rm., shale.
CO in dry vent gas, Volume %.
Carbon as organic residue in spent shale, lbs/ton
ra1.., shale.
-
e
CIOKEH
CIOL
CIOHBCP
CIOIOG
CIORG
CIORS
C.IOSS
CI02
C9,j2 C
CI02 DEC
CI02 RG
CI02RS
C9,j2SS
CPASHF(Tl, T2)
CPCH4F(Tl, T2)
CPCIOF(Tl, T2)
CPCI02F(Tl, T2)
CPC 3F ('rl, T2)
CPH2F(Tl, T2)
CPrUSF (Tl, T2)
CPN2F ('1'1, T2)
CP9,jI]:'F (Tl, T2)
CP>02F(Tl, T2)
CRA
CRDG CRRG Hydrogen as organic residue in spent shale,
Ibs/ton raw shale.
Shale oil carbon content, Weight %.
Organic carbon burned, 'Vleight % of organic carbon
into retort •.
C02 in dry vent gas, Volume %.
CO in total drv recycle gas, lbs/ton raw shale.
Raw shale mineral C02 content, Weight %.
Spent shale mineral C02 content, l';eight %.
C02 in dry vent gas, SCF/Ton raw shale.
C02 formed by combustion, SCF/Ton raw shale.
Mineral carbonate decomposed, %.
C02 in total dry recycle gas, Ibs/ton raw shale.
Raw shale minc~al C02 content, lbs/ton raw shale.
Spent shale mineral C02 content, Ibs/ton raw shale.
Mean specific heat for ash between temperatures
Tl and T2, BTU/lb. F.
I,lean specific heat for methane IbebJeen temperatures
Tl and T2, BTU/lb. F.
•
I,lean specific heat for carbon monoxide bebJeen
Tl and T2' BTU/lb. F.
Mean specific heat for carbon dioxide between
Tl and T2, BTU/lb. F.
Nean specific heat for propane bebleentemperatures
Tl and T2, BTU/lb. F.
1-1ean specific heat for hydrogen bet\1een temperatures
Tl and T2, BTU/lb. F.
Mean specific heat for C2 + material beti:Jeen temp­
eratures Tl and T2, BTU/lb. F.
Nean specific heat for nitrogen bet\veen temperatures
Tl and T2, BTU/lb. F.
Mean specific heat for shale oil between temperatures
Tl and T2, BTU/lb. F.•
l1ean specific heat for oxygen bet\'leen temperatures
Tl and T2, BTU/ln. F.
Air rate, chart reading for Retort No. 2 or SCFM
for Retort No.3.
Dilution gas rate chart reading.
Recycle gas rate, chart reading for Retort No. 2
or SCFM for Retort No.3.
.
Raw shale total carbon content, Weight %.
Total gas flow rate chart reading.
(Used for
Retort No. 2 only)
Vent gas rate, chart reading for Retort No. 2
or SCFM for Retort No.3.
Vent purge rate chart reading.
Spent shale total carbon content, Weight %•
Propane burned in line burner, Ibs/ton raw shale.
.
CRS CRTG CRVG
CRVP CSS .
C3
e
2 ­
.
-
e
D¢L
DRYGAS
Metered dilution gas rate, SCF/Ton raw shale.
Metered dilution gas rate, Ibs/hr. (29 MW basis)
Water condensed from d{lution gas in vent purge
condensor, Ibs/ton raw shale.
.
Density of shale oil, Ibs/gallon.
Dry vent gas p~oduced, SCF/Ton raw shale.
FA
FAY
Oil yield from Fischer Assay, gallons/ton
Retort oil yield, LV% of Fischer Assay.
G
GASL
GB'l'U
v.Jet gas produced (29 Mt1 basis), Ibs/hr.
Calculated vIet vent gas lost, SCI"/Ton ra\V shale.
Gross heating value of dry vent gas, BTU/SCF dry
vent gas.
Top seal gas rate, SCFM.
Gas + loss for raw shale by Fi~cher Assay, Weight I.
Gas + loss for spent shale by Fischer Assay, Height %.
DIL DILG
DILh'
GL
GRS
GSS
raw shale.
HETL¢S
HG
HHG
lI¢L
HRS
HSS
HVGT
H2
H2¢C
H2¢G
H2¢L
H2¢RG
H2¢VG
H2¢VP
H2 RG
Program option:
o used for Retort No.3.
1 used for Retort No.2.
Percent of organic carbon in vent gas "lhich is in
the form of hydrocarbons.
Error in heat balance (heat in - heat out), BTU/ton.
H2 in dry vent gas, Ibs/ MSCF.
Hydrogen content of dry vent gas product, Volume %. Hydrogen content of shale oil, Weight %. Hydrogen content of rmv shale, rveight %. Hydrogen content of spent shale, Weight %. Heating value of dry Vent gas, MBTU/ton raw shale. Hydrogen in vent gas, SCF/Ton raw shale. Water formed by co~bustion, Ibs/ton raw shale. Water vapor in retort offgas, Ibs/ton raw shale. Liquid water in retort offgas, lbs/ton raw shale. Water vapor in recycle gas, Ibs/ton raw shale. Water in vent gas product, lbs/ton raw shale. Water in dry gas, ft 3 H20 per ft 3 dry gas. Hydrogen in recycle gas, Ibs/ton raw shale. ICTR
IeTl
Number of data line being checked. Number of pieces of input data on data line. LYNS
Total number of lines of data input. H
HCCVGP
e
3 ­
- 4 ­
~G
~IL
~ILC¢L
~ILLP
~II..H
~LL
~LRS
~LSS
~RC~I4P
~RCSS
~RCSSP
ORCVGP
~RGC
~RGCIN
~RGC¢L
~RGCSS
~RGCVG
~RGH2
¢RH 2 IN
~RH2~L
¢RH 2 SS
¢RH2VG
¢TG
¢THER
~'1'HRG
~VALL
P
PA
PDG
02 used in burning carbon to CO, lbs/ton raw shale.
02 used in burning carbon to C02, lbs/ton raw shale.
Total dry gas leaving top of retort, lbs/ton raw
shale.
02 content. of dry vent gas product Volume %. Shale oil produced I lbs/ton rmv shale. Oil yield, gal/ton raw shale. Product dry oil collected, lbs/hr. Product dry oil as mist, lbs/1-1SCF dry gas. Oil content of liquid product, \'1eight %. Shale oil in raw shale by Fischer Assay, Weight %. Shale oil in spent shale by Fischer Assay, lveight %. % of entering organic carbon which appears in oil liquid product.
% organic carbon in spent shale.
% of entering organic carbon which appears in
spent shale.
% of entering organic carbon w~ich appears in
vent gas.
I
Organic carbon balance, Organic carbon out/Organic
carbon in.
Total organic carbon in, lbs/ton ra'iV' shale.
Organic carbon in shale oil, lbs/ton raw shale.
Organic carbon in spent shale, lbs/ton raw shale.
Organic carbon in vent gas, lbs/ton ra·w shale ..
Organic hydrogen balance t Organic hydrogen out/
Organic hydrogen in.
Organic H2 in raw shale, lbs/ton raw shale.
Organic H2 in shale oil, lbs/ton raw shale.
Organic H2 in spent shale, lbs/ton ra"v shale.
Organic II2 in vent gas, lbs/ton raw shale.
C2 + Gases in dry vent gas, Volume %.
C2 + Gases in vent gas, SCF/'1'on ravl shale.
C2 + Gases in recycle gas, lbs/ton raw shale.
Overall material b~lance, Total Material Out/
Total Material In, Weight %.
02 in dry vent gas, SCF/':1.'on ra"ld shale.
Percent oxygen balance, oxygen out/oxygen in.
02 into retort, lbs/ton raw shale.
02 out of retort t lbs/ton raw shale.
02 in recycle gas, lbs/ton raw shale.
Propane burned in line burner.
Input to program
in SCFH, \'1hich is converted in program to
Ibs/hr.
Pressure of air at lueter t inches of H20. Pressure of dilution gas at meter, inches of H20. - 5 ­
e
PH20
PP
PRG
PR0P
PVP
pVPc
OAIR
QCOHB
QGASL
,
I
Vapor pressure of H20, rt:'ll'TI fIg. Pressure of propane at meter, inches of H20. Pressure of recycle gas at meter, inches of H20. Propane burned in line burner, SCF/Ton raw shale. Pressure of the vent purge gas at meter, inches of H20. Pressure of the vent purge condenser, inches of H2 0 . Total heat content of air entering, sum of Q59 1
Q5l0, BTU/Ton raw shale.
Total heat of combustion, sum of Q7l, Q72, Q73,
BTU/Ton raw shale.
Total heat content of gas lost, sum of 091, Q92,
Q93, Q94, 095, Q96, 097, 098, Q99, BTU/Ton
raw shale.
,
Q1120S8
OLIQ0
00FGAS
ORCYL
QSS
QSmlIN
QSUI1jOT
021·
022
Q28
Q312
0313
0314
Q3l5
Q33
Q34
Q35
Q36
Q37
e
Note:
•
Heat content of liquid water in spent shale,
BTU/Ton raw shale.
Total heat content of liquid product, sum of Q3l3,
Q38, BTU/Ton raw shale.
Total heat content of offgas, sum of Q33, 034,
035, Q36, Q37, Q3l2, 0314, 0315, BTU/Ton raw shale.
Total heat content of recycle gas into retort,
BTU/Ton raw shale.
Total heat content of spent shale, Sum of Q2l,
Q22, 028, BTU/Ton raw shale.
Total heat in, sum of QC9JI'-1B, 082, Q83, QAIR, QRCYJ.J,
Q5l5, BTU/T6n raw shale.
Total heat out, sum of Q74, Q75, Q84, QLIQ0,
00FGAS, QSS, QGASL, LBL0SS, also QSUH0T. minus
liETL0S, BTU/Ton raw shale.
Heat content of C02 in spent shale, BTU/Ton raw
shale.
Heat content of ash in spent shale, BTU/Ton raw
shale.
Heat content of organic residue in spent shale,
BTU/Ton raw shale.
Heat content of water vapor in offgas, BTU/Ton
. raw shale.
Heat content of water (liquid) in product, BTU/Ton
ravl shale.
Heat content of N2 in offgas, B'l'u/'l'on ra'iil shale.
Heat content of °2 in offgas, BTU/tron raw shale.
Heat content of CO in offgas, BTU/Ton ra\v shale.
Heat content of CO 2 in offgas, BTU/rron ravl shale.
Heat content of 112 in offgas, B'l'U/Ton raw shale.
Heat content of CH4 in offgas, B'l'U/Ton ra"v shale.
Heat content of C2 + Gases in offgas, BTU/Ton
raw shale.
All heat content are relative to "the reference temperature
- 6 ­
Q38
Q5l0
Q5l2
Q5l5
Q5l6
Q5l7
Q53
Q54
Q55
Q56
Q57
Q58
Q59
Q7l
Q72
Q73
Q74
Q75
Q82
Q83
Q84
Q9l
Q92
Q93
Q94
Q95
Q96
Note:
Heat content of liquid shale oil
product, BTU/Ton
ray; shale.
Heat content of 02 in enterl~g air, BTu/ron raw
shale.
Heat content of water vapor in total recycle, BTU/
Ton raw shale.
Heat content of propane in total recycle, BTU/Ton
raw shale.
Heat content of N2 in total recycle, BTU/Ton raw
shale.
Heat content of 02 in total recycle, BTU/Ton raw
shale.
Heat content of C02 in total recycle, BTU/Ton raw
shale.
Heat content of CO in total recycle, BTU/Ton raw
shale.
Heat content of H2 in total recycle, B'rU/'I' on raw
shale.
Heat content of CH4 in total r¢cycle, BTU/Ton
raw shale.
Heat content of C2 + Gas in total recycle, B'rU/Ton
raw shale.
Heat content of shale oil in total recycle, BTU/Ton
raw shale.
Heat content of N2 in entering air, BTU/Ton raw
shale.
Heat of combustion, carbon burned to CO, BTU/Ton
rmv shale.
Heat of combustion, carbon burned to C02, BTU/Ton
raw shale.
Heat of combustion, hydrogen burned to water, BTU/
Ton ravl shale.
Heat of decomposition"of mineral C02, B'l'U/rl ' on rm,v
shale.
Iieat of decomposition of kerogen, based on gas
plus shale oil, BTU/Ton raw shale.
Heat of condensing water in retort offgas, BTU/Ton
raw shale.
Heat of condensing oil in retort offgas, BrrU/Ton
raw shale.
Heat of water evaporation,and desorption, BTU/Ton
raw shale.
Ileat content of C02 in gas loss, BTU/Ton raw shale.
Heat content of CO in gas loss, BTU/Ton raw shale.
Heat content of H2 in gas loss, BTU/Ton raw shale.
Heat content of CH4 in gas loss, BTU/Ton raw shale.
Heat content of C2+ in gas loss, BTU/Ton raw shale.
Heat content of oil in gas loss, BTU/Ton raw shale.
All heat contents are relative to the reference temperature
\vhich is the ra\v shale temperature.
-
e
Q97
Q98
Q99
RBC RECG RS
RSR
SATH2~
SS
SSRS
SSY
S'l'~REl
TA
TC
'l'DG
TGP
TGL
TH2
'l'H2IN
TH2~
'lIH2 SS
TI12VG
T~G
T~TCIN
T~'fCSS
T~TCVG
T0TREC
TP
TRECG
TRG
TRS
Note:
7 ­
Heat content of H2 O vapor in gas loss, BTU/Ton
raw shale.
Heat content of N2 in gas loss, BTU/Ton raVl shale.
Heat content: of °2 in gas loss, BTU/Ton rmv shale.
Metered recycle gas rate (29 MW basis), Ibs/hr.
Hetered recycle gas rate corrected for moisture,
SCP/Ton raw shale.
Raw shale rate, Ibs. raw shale/hour.
Raw shale mass rate, Ibs/(hr) (ft 2 ).
Saturated water content of gas stream, Ibs/SCF of
gas.
Spent shale produced, Ibs. spent shale/hour.
Spent shale produced, Ibs. spent shale/ton raw
shale.
Spent shale yield, weight % of/raw shale.
Variable used as temporary storage location.
Temperature of air at meter,oF (later converted
to OR) •
Percent total carbon balance, carbon out/carbori in.
Temperature of dilution gas at meter, OF.
Total gas flow, SCFM.
Total gas loading at top of retort, SCF/(hr) (ft 2 ).
Percent total hydrogen balance, total hydrogen out/
total hydrogen in.
Total hydrogen into retort, Ibs/ton raw shale.
'fotal water
into retort, 1bs/ton raw shale.
Total hydrogen in spent shale, Ibs/ton raw shale.
Total hydrogen in vent gas, 1bs/ton raw shale.
Temperature of offgas at top of retort, OF.
'l'otal carbon into retort, Ibs/ ton raw shale.
Total carbon in spent shale, Ibs/ton raw shale.
rrotal carbon in vent gas, 1bs/ton raw shale.
Total dry recycle gas entering retort, Ibs/ton
raw shale.
Temperature of propane at meter, 0p.
Sum of recycle and dilution gas, SCF/Ton raw shale.
Temperature of recycle gas at meter, OF; also con­
verted to temperature of recycle and dilution
gas, of; also converted to OR.
Temperature of raw shale entering retort, °P; later
converted to OR.
All heat contents are relative to the reference ter.1perat:ure
which is the ra\·'l shale temperature.
- 8 ­
TSS
e
TVG TVP
TVPC
UNRETC
UNRETH
UNRET¢
VPiOIL
VPI>1
VPi\lF
VPR
VPN
Temperature of spent shale leaving retort, of;
later converted to oR.
Temperature of vent + dilution gas for Retort No.2;
or vent gas for Retort No.3. Temperature of vent purge gas at meter, of. Temperature of the vent purge condenser, of. Un retorted organic carbon in spent shale, lbs/ton raw shale. Unretorted organic hydrogen in spent shale, lbs/ton raVI shale. Unretorted shale oil in spent shale, LV% Fischer Assay. Oil as mist in dry vent gas, gms/hr for input,
converted to lbs/HSCF in program.
Wa~er in vent gas, lbs~1SCF dry vent gas.
Vent purge meter factor.
'
Vent purge gas rate, SCF/Ton raw shale.
Water collected from vent purge system, lbs/hr.
'VJlvG
Water addition ~ate, lbs/hour. Moisture in air, lbs/?1SCF of dry air. Percent water balance, total water out/total water in.
Water content of vent gas, Volume I.
Dry vent gas produced, lbs/ton raw shale.
l-1easured 'vater in dry vent gas, lbs/MSCF.
Vent gas lost, lbs/ton raw shale.
Water into the retort, lbs/ton raw shale.
Water in liquid produ~t, lbs/hr.
Water in raw shale, Weight %.
water in spent shaie, "\\!eight %.
Wet vent gas rate, SCF/Ton raw shale.
Wet vent gas rate, lbs/ton raw shale.
XA
Cross sectional area of retort, ft2.
ZAT¢UT
ZAXH2¢
ZBLy,lSS
ZH2y,lVG
Total material leaving retort, lbs/ton raw shale.
Total H20 from offgas, vapor plus liquid, lbs/SCF.
Heat loss from line burner, BTU/Ton raw shale.
Water content (as saturated vapor) of vent gas,
lbs/ton raw shale.
N
\'VA
tvA'l'ER
~vCG
\vDG
t\JG
WGASL
NI
"V'lLP
vJRS
i\lSS
vNEN'l'G
- 9 ­
ZISTFA
ZISTRG
ZMATIN
ZNUAIR
ZZL
ZZLBHL
ZZM
ZZMEG
ZZr-1FA
ZZ]>lFDG
ZZI1FRG
ZZMF'l'G
ZZl1FVG
ZZHII2~
ZZl>1IST
Z~I-1RS
ZZHHDG
ZZ~H'l\'JG
ZZN
ZZNG
Z~N2RG
Shale oil in vent gas, LV% Fischer Assay. Shale oil in recycle gas, lbs/ton raw shale. Total material entering retort, lbs/ton raw shale. Air rate, SCF/Ton raw shale. Liquid product produced, lbs/hr. Heat loss from line burner, BTU/hour. Program option for vent gas oil and water: value
oil water
o
VP0IL used
ca"iculated--as -s-c-"lt'--u-r-a-t-=-e--:;"d-,
TVPC, PVPC, VPWused
1
0ILH used
WG used
Methane content of vent gas, Volume %.
Meter factor for air.
Meter factor for dilution gas.
Meter factor for recycle gas.
Meter factor for total gas.
Meter factor for wet gas.
Total water out, lbs/ton raw shale.
Shale oil in vent gas, Ibs/to~/raw shale. Measured raw shale rate, lbs/hr. Molecular weight of dry vent gas. Molecular weight of wet vent gas. Salt in brine solution, lbs.hr. N2 content of vent gas, Volume %. N2 content of recycle gas, lbs/ton raw shale. APPENDIX D
INDEX '1'0 C01vlPUTER VARIABLES
Variable TYPE is as follows:
I
O.
C
IC
F
PAGES
Input variable
Output variable
Internal variable
Input variable later
fined in program
FyJRrrRAN ~"unction (in'ternal variable representing a
predefined arithmetic equation)
signated are the pages of Appendix A on which the
variable appears.
VARIABLE.
TYPE
0
0
2,
7,
6,
6;
C
C
I
I
3, 6
3, 6
1, 3
I, 3, 11
B
BP
I
IC
1, 2, 3, 6
1, 2, 5, 8
I
1, 6
5, 13
10, 11; 15
4, 7 , 13
7 , 9, 10, 11
(
,
0
)
0
C
0
0
I
0
0
I
0
I
C
I
I
qoss
C02
CyJ2C
Cy52DEC
CyJ2RG
C02 RS
C\i52SS
CPASHF
F
0
0
0
(
,
)
C
C
C
F
PAGES
3, 4, 5, 7, ~
A
AIR
ASH
ASHB
ASHI
ASHyJU '1'
ASRS
ASSS
CG
CHR
CH2\i5GF
CH4
CH4RG
C0
C0C
CyJG
CyJKEC
CyJKEH
CyJL
cyJ:,mcp
CyJyJG
CyJHG
CyJRS
C
C
-_._--9
•
13
13
4 , 6, 7 , 8, 13
4, 8, 13
I, 4
4, 8, 13
4, 13
1, 4, 6
8, 13
1, 4
7, 9, 10, 11
1, 3
1, 3, 8, 11
4, 6, 7, 8, 13
4, 8, 13
3, 13
7, 9, 10, 11
3, 4, 6, 8, 10
3, 4, 6, 8, 10, 11
II, 14
._--_... ­
,
- 2­
VARI.hBLE
CPCII4F ( ,
CPC¢F( , )
CPC¢2F ( ,
C-PC3F ( , )
CPH2F'( , )
cpr·nSF ( ,
CPN2F( , )
CP¢ILF( ,
CP¢2F ( , )
CRA
CRDG
CRHG
CRS
CR'fG
CRVG
CRVP
CSS
C3
TYPE )
)
)
)
F
F
F
F
F
F
F
F
F
I
I
I
I
I
I
I
I
-PAGES
9, 10, 11, 14
9, 10, 11, 14
9, 11, 14
10, 15
9, 10, 11, 14
9, 10, 11, 14
9 , 10, 11, 14
10, 11, 14
10, 11, 12, 15
1, 2
1, 2
I, 2
1, 3
1, 8
I, 2
I
I
C
1, 5
I, 3, 8
8, 10
0
7, 8, 13
C
C
I
DIL
DILG
DILhT
D¢L
DRYGAS
0
2,
6,
1,
4,
FA
FAY
I
0
I, 4, 6, 8
4, 8 , 13
G
GASL
GB'fU
GL
GRS
GSS
C
2, 7
7, 8 , 13
H
HCCVGP
HETL¢S
HG
HHG
H¢L
HRS
HSS
HVGT
H2
H20C
H20G
I
0
0
0
0
I
I
I
I
I
I
I
I
0
0
0
C
3, 6 , 7
9
4, 6
5, 6, 7, 8 , 13
F.
6, 8 , 13
1, 7
I, 4, 8, 10
1, 4
1,2,5, 6, 7, 8
8, 13
12 , 13
I, 6
1, 4
1, 4, 6
I, 3
1, 3, 4
8 , 13
4, 7 , 13
5, 6, 8, 13
9, 11
VARIABLE
3 ­
PAGES TYPE
H2011
H2ltJHG
H20VG
H2ltJVP
H2RG
C
C
C
C
C
9,
8,
5
5,
7,
ICTR·
ICT1
C
C
1
1
LYNS
C
1
0C0
0C02
0FFGAS
0G
0IL
0ILC0L
0ILLP
0ILM
0LIJ
0LRS
0LSS
0RC0LP
0RCSS
0RCSSP
0RCVGP
0RGC
0RGCIN
0RGC0L
ItJRGCSS
0RGCVG
0RGH2
0RH2IN
0RH20L
0RH2SS
0RH2VG
0TG
0THER
C
C
C
I
C
4, 5
4, 5
10
10, 11
7, 8
9, 10, 11
7, 9, 10, 11
~THRG
C
OVALL
02
02BAL
0
0
0
1, 4
4, 6, 9, 10
8, 13
1, 4
1, 5
4 , 5, 6
1, 4, 10
1, 4, 10
8, 13
8, 13
S, 13
S, 13
6, 13
3, 6, 8, 13
4, 6, 8, 13
3, 4, '6
6, 13
6, i3
3, 6, 13
4, 6, 7, 13
3, 4, 6
6, 13
1, 4
4, 7 , 13
7, 9, 10, 11
6, 13
4, 5, 7, 8, 13
8, 13
~2IN
~2¢UT
C
C
8
B
~2RG
C
7, 10, 11, 12
P
PA
IC
I
I, 2, 3, 8
1, 2
0
I
I
C
I
I
0
0
0
0
0
0
0
C
0
0
0
0
C
0
I
0
I
/
.
-
- 4 ­
VARIABLE
PP
PRG
I
C
I
I
PR~P
0
PVP
PVPC
I
I
QAIR
0
0
0
.PDG
PH2~
QC~MB
QGASL
QlI2ylSS
QLIQ0
QyWGI.l.S
QRCYL
QSS
QsmUN
QSUH¢T
Q21
Q22
Q28
Q312
Q313
C314
Q315
Q33
Q34
Q35
Q36
Q37
Q38
Q510
Q512
Q515
Q516
Q517
Q53
Q54
Q55
Q56
Q57
Q58
Q59
Q71
Q72
Q73
Q74
Q75
Q82
PAGES
TYPE
C
0
0
0
0
0
0
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
0
C
C
C
C
C
C
C
C
C
C
C
C
0
0
0
-
I, 2
5, 9
I, 2
I, 2, 8
8, 13
1, 5
I, 5
9, 10 13
8, 10 ,' 13
12 13
11'
10, 12 13
11, 12', 13
10, 13
11, 12 13
10, 12', 13
12, 13
11
11
11
11
10
11
11
10, 11
10, 11
10, 11
10, 11
10, 11
10, 11
9
10
10, '13
10
10
9, 10
9, 10
9, 10
9, 10
9, 10
10
9
8
8
8
10, 12, 13
10, 12, 13
9, 10, 13
,I
- 5 ­
VARIABLE
Q83
Q84
Q91
Q92
Q93
Q94
Q95
Q96
Q97
Q98
Q99
REC
RECG
ns
RSR
SATH20
SS
SSRS
SSY
ST¢RE1
TA
TC
TDG
TGF
TGL
TH2
TH2IN
TH2¢
TII2SS
TH2VG
T¢G
T¢TCIN
T¢TCSS
T¢TCVG
T¢TREC
TP
THECG
TRG
TRS
TSS
TVG
TVP
TVPC
PAGES
TYPE
0
0
C
C
C
C
C
C
C
C
C
C
0
C
0
C
IC
C
0
C
IC
0
·I
0
0
0
C
C
C
C
IC
C
C
C
C
I
0
IC
IC
IC
I
I
I
9, 10, 13
10, 12, 13
II, 12
11, 12
II, 12
II, 12
11, 12
11, 12
11, 12
11, 12
12
2,
7,
3,
8,
3, 7
8, 13
4, 5, 6, 7 , 8, 10, 12
I
13
I
9
I, 3, 5, 6
3, 4, 6, 9, 10, 11
3, 13
10, 11, 12
2, 9, 10
13
2, 3
13
8 I 13
7, 13
3, ?
5, 7, 9
4, 7
6, 7
1, 9, 10, 11
3, 6
3, 6
1,
6,
1,
8,
6
7, 9,
1~ 2
8, 13
1, 2,
I, 9,
I, 9,
I, 2
I, 5
I, 5
10, 11
3, 8, 9, 10
10, 11, 12
II, 12
Vl-I.RIABLE
UHRE'l'C
UNHE'I'H
UNRET0
VP0IL
VPI',l
VPUIF
VPR
VPvi
TYPE
6
­
P}\GES
--~-,.-------~-.------~---....--~
0
0
0
4, 8, 13
4 , 13
4, 13
IC, 0
I, 5, 13
5, 13
1, 5
0
C
C
C
5, 6
1, 5, 6
C
1, 3, 10
I, 3, 7, 8
7 , 13
8 , 13
4, 5, 6 , 7 , 9, 11
I, 5
7 , 11
3, 5, 8
I
I
I, 4
1, 3, 10
I, 3, 5, 6, 9, 11
7, 8, 13
5, 7, 8
XA
I
1, 8
ZAT)OU/f
ZAXH20
ZBL¢SS
ZII2)OVG
ZISTFA
C
C
6
0
ZIS~['J(G
C
Z!,li\TIi~
0
0
12, 13
5, 6 , 7 , 8, 9
6, 13
7 , 10, 11
3, 6, 13
8 , 13
4, 5, 6
1, 12
I, 2, 5
I, 4
I, 2
I, 2
1, 2
I, 2
I, 2
6, 7, 8, 13
5, 6, 7 , 11
1, 3
4, 5, 7 , 9, 13
5, 7, 8, 13
I, 3
I, 4 , 7
7, 10, 11
H
\qA
WATEH.
l'ICG
WDG
\\1G
WGASL
v.:I
IIJLP
{llRS
WSS
vNEN'l'G
HNG
ZNUAIH
ZZL
ZZLBHL
ZZH
ZZj\1EG
ZZf,lFA
ZZHFDG
ZZNFRG
ZZlllFTG
ZZHFVG
ZZi\1H2¢
ZZMIS'T
ZZMRS
ZZHHDG
ZZH1>Ji'YG
ZZ~~
ZZlJG
ZZl:~2RG
I
I
0
0
C
I
C
C
I
I
I
0
C
0
C
I
I
I
I
I
I
I
I
0
C
I
0
0
I
I
C
9
RAReitz
APPENDIX E
SAI>lPLE CASE INPU'l' AND OU'l'PUrl' FOHI"lS
DEFINI'rIONS FOR INPUT TERMS
~1I'rH
,
j
.
2
PROGRAH INPUT Dh'l'A
i
!
--~-----~>
USER IDENTIFICATION
LlN.~ n ,---------------------.,.----.---------.-----.------..---------------------------.--------------------.--------.----._-­__-_-_-_J
v
.-­
vms
[
R 0 G-I:/!,;
~)
-"--~-.-
B
TRS
OLRS
IL<L~] [--/0--9---]
____
MRS
<;;­
~2-=~~
[:=-
CORS
CIIS
[-/~/-~-l
3
"--'---­
CRA
.(
5
DL~~:-(~ ~J
CRI(G
MH<G
_
, ... _ ./ ....
~---~J
)
__ ___
l ~L~ ~_~'
HRS
[-...LP,/]
:......I...!.~~
-
C-;-;-·
-,---­I [
MFOG
TRG
L;;06:~-;o
VIA
LBHl
[Q~/~]
Co--~
'crHC
MFTG
]
N
ASSS
CSS
'PROPANE AN
SS
HSS
U~L_=:J
L~""~LJ
Hal
DOL
[=-a-'~_9J
1\
[
CRVG
'J70~2j
C/.~L_J
H
.TVG
eLl
"'1
MEG
.[ ;fj- ]
COG
~
~_9~~_
HHG
•• r­
6;{
(-­
OTG
VENT
GAS
.,e-"I
HG
D ~-~~
TYP.
LIQUID
( ; : - - PRODUCT
NG
OG
1 0 l-s=! I·
-,
C~-~
SI\ALE
WlP
C~./r~zl
,.t.j_L_
SPENT
'<;;
OILM
'"'-j , ..,
0
12
}
TSS
LcP.tI./] [-­ II ,,_U [2,,/:12 J [/P?L]
MFVG
DILUTION CA
AGENT
COSS
W'/(~3--:-1
AI'­
TOT AL GAS
~---- NUCLEATI~lG
GSS
10
<__ RECYCLE
~--
VI
OLSS
COL
AIR
.
VlSS
QS9J C_8'tL.3l
~
"
PDQ
lOG
PI'
TP
c_~{_=a
OILU'
14
. L IlI.!::_J.
-~~.:-:./
~ 7~i~]
8
e
TOG
L7S=J
P
13
SP
[~---~
'} 1/
(
PRG
6
·9
SHALE
Mf'A
L ---f&]
CRDG
'I
RAW
[--li~:2J
2
<­
pyp
FJV
rc~
0----]
~J~)!
~l.
1 ~.
<
/
VENT
PURGE
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6.557E 03
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3b878E 01
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C02D~C
~.
NH20
9,,500E 01
OILGOL
2.3C6E OJ
::rrn.:
8. METERSO GAS R~
RECS
1.121E O~
AIR
5~20~[ 03
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c.
V~LUE
MOL WI & HEATING
IE 01
8.tO/i~:
01
WV~NTG
1GOIBE 03
TGV
O~O
07
3,,050E 01
6c951E: 02
G8TU
leOGOE 08
D~
C02C
PRODUCTS
6.606E 02
coe
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50130£ 01
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506GIE 05
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QLIQO
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"
- 4 ­
DEFINITION OF TERI1S USED IN J:.1ATERIAL AND HEAT BALhNCES INPUT FORl-iS Program
Line No.
0
1. a. (1)
b.
c.
d. e. 2. a. (1)
'Program ID WRS OLRS TRS B
f.1RS
FA
b. GRS
c. CORS
d. XA
3. a. (1)
ASRS
b. CRS
c. HRS
d.
e.
BP TOG 4. a.
Description and units
~mbol
CRA
b. MFA
c. TA
d. PA
e. NA
f. LBHL
Run Number and date
Water content by Fischer Assay, Wt %.
Oil
content by Fischer Assay, Wt %.
Temperature of ra\,l shale, OF.
Enter "1" to calculate with spent shale
rate and ash analyses.
Enter 110" to calculate '\tlith measured
raw and spent shale rates.
Enter "-III to calculate \vi th ra'\v shale
rate and ash analyses.
Ra\,l shale rate on, moisture free basis,
lbs/hr.
•
Oil yield, moisture free basis, Fischer
Assay, gal/ton.
Gas content + loss, moisture free· basis,
Fischer Assay, Wt %.
Mineral carbon dioxide, moisture free
basis, by acid decomposition, Wt %.
Cross sectional area in retorting zone,
square feet.
Ash content of raw shale on moisture
free basis by ignition, Nt %.
Total carbon content by combustion,
Wt %. '
Total hydrogen content by combustion,
wt %.
Barometric pressure, inches Hg.
Temperature of gas leaving retort, OF.
Chart reading for air on Retort No.2.
SCF/M for air on Retort No.3,. SCFM.
Orifice meter factor for Retort No.2,
enter "111 for Retort No.3.
Temperature upstream of air orifice
meter, OF.
Pressure upstream of air orifice meter,
"H2 0 •
Moisture content of air, lbsH20/MSCF
(Dry)
Line burner - air distributor heat loss, BTU/hr. (l)Calculated on moisture free basis.
.. - 5 ­
Program
Line No.
,~mbol
5. a.
CRRG
b.
lvlFRG
c.
TRG
d.
PRG
e.
CRTG
f.
MFTG
6. a.
b.
c.
d.
PDG
_ _ _ _ _Desc£ption and units,____,
Chart reading for recycle gas on Retort
No.2.
SCF /1'1 for recycle gas on Retort No.3, sel
Orifice meter factor for recycle gas
on Retort No.2.
Enter "111 for recycle gas for Retort No.
'l'emperature of recycle gas upstream of
'f'
of .
orJ."1Ce,
Pressure
upstream of recycle gas
0'
orJ.' f 'l.ce, IIH 2
Chart reading for total gas on Retort
No.2.
Enter "0" for Retort No.3.
Meter factor for total gas on Retort No.
Enter 110" for Ret.brt No.3.
Chart reading for dilution gas.
Orifice meter factor for dilution gas.
Temperature of dilution gas upstream
of orifice, of.
Pressure of dilution gas upstream of
orifice, "H 20.
c.
PP
SCF /J'.1 for propane, SCFM.
Temperature of propane upstream of
orifice, of.
Pressure of propane upstream of orifice,
d.
e.
W
N
Moisture content of raw shale, Ibs/hr.
Nucleatirig agent addition, Ibs/hr.
8. a.
WSS b.
OLSS c.
GSS d.
SS
9. a.
COSS
b.
ASSS
7. a.
b.
P
TP "H2 0 • '
Water content of spent shale by Fischer
'Assay, Wt %.
Oil content of spent shale by Fischer
Assay, Wt %.
Gas + loss on spent shale by Fischer
Assay, Wt %.
Spent shale rate on Retort No.2, Ibs/hr.
Enter 110" for Retort No.3.
Mineral carbon dioxide by acid decom­
position on spent shale, Wt %.
Ash content spent shale by ignition,
~]t
c.
CSS
d.
HSS
e.
'l'SS
%.
Total carbon content by combustion in
spent shale, Wt %.
Total hydrogen content of spent shale
by combustion, Wt %.
'I'em~~~~~"lT~
~.1!.;;':\;""J~CI,.'-\.,.<_t:._
crol,t
.,:::.t:H.,. . . . . . .c·J.1~le
::; t..;J.. ..
I
0 7J. •
:::q
.. .'
-
Line No.
10. s.
b.
0
­
Program Symbol OILLP COL c;
HOL
d.
e.
DOL
HLP
11. a.
CRVG
b.
HFVG
c.
TVG
Water free oil product, lbs/hr.
Total carbon content of oil by com­
bustion, Wt %.
Total hydrogen content of oil by com­
bustion, Wt %.
Density of oil, lbs/gal.
Liquid water product, lbs/hr.
Chart reading for vent plus dilution
gases in Retort No.2.
SCFN for vent only in Retort No.3, SCFH.
Orifice meter factor (SCFM) for Retort
No 2.
Enter "I" for vent gas MFVG for Retort
No.3.
Temperature of vent gas upstream of
orifice, of.
Moisture content of vent gas, lbsH 20/MSCF
dry gas.
Use calculated amount or "a" if using
vent purge raw data.
Oil mist and condensate in vent gas.
Use calculated amount or "a" if using
vent purge rm'l data, lbs oil/I'1SCF
dry gas.
Enter "l"to externally calculate mois­
ture and mist (WG and OILH)
Enter "all to calculate from vent purge
raw da,ta.
I
d.
e.
OILH.
f.
M
12. a.
CG
b.
H
c.
COOG
d.
e.
OG NG 13. a.
HEG COG
b.
c.
d.
HRG
OTG
e.
HG
14. a.
CRVP
Total. carbon content of vent gas by
combustion, lbs/HSCF.
Enter "0" for Retort No.3.
Enter Ifl" for Retort No.2.
Carbon dioxide content of dry vent gas,
Vol %.
Oxygen content of dry vent gas, Vol %.
Nitrogen content of dry vent gas, Vol %.
Methane content of dry vent gas, Vol %.
Carbon monoxide content of dry vent
gas, Vol %.
Hydrogen content of dry vent gas, Vol %.
Other content (100 - sum of measured
components), Vol %.
Hydrogen content of vent gas by com­
bustion, lbs/HSCF dry gas.
Chart reading for vent purge cond8nser
for Retort No.2.
rCLlcling on ~i21S s2f~1plc
orifice for Retort No.3, "H20.
NOEorl1e-tE~r
- 7 ­
Line No.
1.4. b.
c.
d.
e. 15. a.
Program
Symbol
,----­
VPHF
TVP PVP PVPC
TVPC
b. VPOIL
c. VPW
d.
GL ______D_~s_c_r_i.2_t_'_·-on_a_.n_~_~_n_i_t_~_ __
Orifice meter factor. .
Temperature upstream of orifice, of.
Pressure upstream of orifice, "H 20.
Pressure of outlet of vent purge con­
denser for Retort No.2, or pressure
at outlet of gas sample condenser
on Retort No.3, IIH 20.
Temperature of gas at vent purge
condenser outlet on Retort No~ 2.
Temperature of gas sample condenser
outlet on Retort No.3, OF.
Dry oil mist and condensate from
vent purge condenser
on Retort No. 2
I
or from gas sample
condenser on
Retort No. 3, grams oil/hr.
Liquid water from vent purge condenser
on Retort No. 2 or from gas sample
condenser on Retort No.3, Ibs/hr.
Seal gas to top of retort, SCFM.