Physical Properties and Molecular Composition of the Region of Massive Star Formation L379IRS1 S. V. Kalenskii and M. A. Shchurov Astro Space Center, Moscow DSS2 image of L379 Introduction The region of massive star formation L379IRS1 (IRAS18265–1517) is located in a dark cloud L379 at a distance of 2 kpc. Submillimeter observations showed that IRS1 consists of two clumps, situated 0.2 pc north and 0.14 pc south of the IRAS position and connected by an arc of submillimeter emission west of this position (Kelly and Macdonald, 1996). Each clump probably contains a B0-5 protostar, which drives a bipolar outflow. Class I methanol masers, detected at 36, 44, 132 GHz and some other frequencies are related to the northern outflow (Slysh et al, 1999), while a group of Class II methanol masers have been found towards the southern clump (Walsh et al., 1998). We tried to study the molecular composition and the physical parameters of L379IRS1 in more detail. For this purpose we observed with the Pico Veleta radio telescope a number of positions in this object in seven spectral bands that include the frequencies of CS, SiO, N2H+, CH3CN, CH3OH lines etc. Results Lines of 24 molecules, beginning with simple diatomic or triatomic species, such as SiO, CS, OCS, and ending with complex eight-atom or nine-atom chemical compounds, such as CH3OCHO, CH3OCH3 were detected (Table 1). The richest molecular composition was found towards the −400, +2000 direction (the position of the northern submm peak). Lines of 21 molecules were detected there. Dimethyl ether Table 1. Molecules detected in L379IRS1 Diatomic Triatomic Four-atom Five-atom Six-atom Seven-atom Eight-atom Nine-atom CS, C33S, C34S, SiO CCS?, DCN, H2S, N2H+, OCS, SO2 H2CO, HDCS?, HNCO? c-C3H2, HCCCN, HC13CCN, HCOOH CH3CN, CH3OH HC5N, CH3CHO? CH3OCHO, CH2OHCHO? CH3OCH3 Methanol I. Gas parameters determined from methanol lines Rotation diagrams built from the 145 and 241 GHz lines (Type I rotation diagrams) estimate density rather than temperature (Kalenskii & Kurtz, in preparation; see also Leurini et al, 2004) Type I rotational temperature about 7 − 8 K corresponds to a density of about Fig. 1. Rotation diagrams, built from the 3K − 2K 106 cm−3. For such a density rotational temperatures lines at 145 GHz, the 5K − 4K lines at 241 GHz, and the J0 − J−1E lines at 157 GHz derived from the 157 GHz lines (Type II rotational temperatures) should be multiplied by a factor of 1.5 − 2. The gas density and temperature in L379IRS1 proved to be about 106 cm−3 and 40–50 K, respectively. II. A and E-methanol abundance ratio Methanol forms on dust grains at a temperature 10–15 K (Watanabe et al., 2004). As the ground state of E-methanol lies 7.9 K above the ground state of A-methanol the ratio of E-methanol to A-methanol abundances should be about 0.7. But our rotation diagrams show Rotation diagrams, built from the observed that the ratio of A to E-methanol abundances in L379IRS1 is close to and model lines at 145 and 241 GHz. Filled squares represent E-methanol, asterisks, unity. A-methanol. Methyl cyanide Rotation diagrams built from the 8K − 7K lines of methyl cyanide shows the presence of two components: warm component, traced by the low-energy lines, and hot component, traced by the high-energy lines. The warm gas is the same as observed in the methanol lines. CH3CN abundance in the warm gas is about 10−11, similar to that found by Kalenskii et al (2000). The high-energy lines suggest an existence of a hot core in the southern clump, which also reveals itself in the 6.7 GHz maser emission. Those observed towards the northern core may arise either in another hot core, related to the northern protostar, or in hot postshock gas. It is considered that the emission of complex organic molecules (COM), such as dimethyl ether (CH3OCH3) or methyl formate (CH3OCHO) arises in hot cores or hot postshock gas. But recently CH3OCH3 emission was detected in cold prestellar cores and cold envelopes of low-mass protostars. Can these molecules be observable in the quiescent gas of dense cores? Fig. 3. Rotation diagrams built from CH3OCH3 lines observed towards the northern (left plot) and southern (right plot) submillimeter peaks. CH3OCH3 rotational temperature proved to be 44 K towards the southern peak and 33 K towards the northern peak. It is possible that: quiescent gas emission dominates the observed low-energy lines. our set of CH3OCH3 lines significantly underestimates the gas kinetic temperature, like Type I methanol lines. A careful mapping and a thorough analysis of dimethyl ether excitation is necessary in order to choose between this possibilities. Other molecules Apart from the lines of methanol, methyl cyanide, and dimethyl ether, a number of single lines of different molecules were detected. Each such line was used to determine the column density of the relevant molecule. Column densities of the most of molecules in L379IRS1 are nearly the same as those obtained in the DR21(OH) by Kalenskii & Johansson (2010). The only exception is sulfur dioxide. In L379IRS1, the derived column density proved to be twenty times lower than that found by Kalenskii & Johansson in DR21(OH). Abundance ratios [CS]/[SO2], [OCS]/[SO2], [H2S]/[SO2] show that L379IRS1 may be younger than 105 years, according to modeling by Wakelam et al.(2004). Conclusions Spectral observations of a region of massive star formation L379IRS1 in the 1, 2, and 3-mm wavelength ranges resulted in the detection of the lines of different molecules, starting with simple diatomic or triatomic species, such as SiO, CS, or OCS, and ending with complex eight- or nine-atom chemical compounds, such as CH3OCHO or CH3OCH3. Rotation diagrams showed that the temperature of the quiescent gas is about 40–50 K, and the density is about 106 cm−3. The abundances of A and E-methanol proved to be virtually the same, in contradiction with the current views on methanol formation. Apart from the quiescent gas, there is a hot component. One of the hot regions is a compact hot core in the southern submillimeter clump. The northern clump can host another hot core or/and and hot postshock regions. The rotational temperature for dimethyl ether proved to be about 40 K. The [SO2]/[CS] and [SO2]/[H2S] abundance ratios show that the age of L379IRS1 is less than 105 years. 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