MUNISH KAKAR's INSTITUTE OF CHEMISTRY PHOTOELECTRIC EFFECT WS # 3 Q1. What happens to kinetic energy of photoelectron when (a) frequency of radiation is increased (a) Kinetic energy increases (b) Wavelength of radiation is increased. (b) Kinetic energy decreases. If energy is decreased further photoelectric effect may not be observed Q2. Is it possible to change Ionization energy of metal by changing energy of radiation ? No Q3. Which in between frequency or intensity can help to increase photoelectric current ? Intensity, as it helps to generate more number of electrons Q4. Among the following given metals, how many metals will be able to show photoelectric effect when exposed to radiation having wavelength 400 nm ; Erad. = 3.1 eV A ( = 2.27 eV ) , B ( = 3.5 eV ) , C ( = 3.94 eV ) , D ( = 0.46 eV ) ¸ E ( = 2.13 eV ) F ( = 4.15 eV ) , G ( = 3.03 eV ) , H ( = 4.67 eV ) Q5. What happens to kinetic energy of photoelectron when ; (a) Frequency of radiation is doubled (b) Wavelength of radiation is made one-third ? (a) Kinetic energy becomes more than double (b) Kinetic energy becomes more than triple Q6. Under which among the following condition (s), photoelectric effect will be observed ? (a) Frequency of radiation larger than threshold frequency (b) Wavelength of radiation longer than threshold wavelength (c) both and b Q7. (d) both a and b are incorrect 15 1 Certain metal is exposed to radiation having frequency 3 10 sec , if works function of such metal is one-third of energy of radiation, calculate ; (a) Threshold frequency of metal ( 1 1015 ) Q8. 5 (b) Velocity of photoelectron ( appr. 16 10 ) The work function of a metal is 4.0 eV. The longest wavelength of light that can cause photoelectron emission from the metal is approximately: (a) 540 nm Q9. (b) 400 nm (c) 300 nm (d) 220 nm The work function of a photoelectric material is 3.3 eV, its threshold frequency will be ; (a) 8 × 1014 Hz (b) 5 × 1033 Hz (c) 8 × 1010 Hz (d) 4 × 1011 Hz Q10. When light of frequency 3.2 × 1016Hz is used to irradiate a metal surface, the maximum kinetic energy of the emitted photoelectron is 3 of the energy of the irradiating photon. 4 What is the threshold frequency of the metal ? (a) 2.4 × 1025 Hz (b) 2.4 × 1016 Hz (c) 1.6 × 1015 Hz (d) 8 × 1015 Hz Q11. A near UV photon of 300 nm is absorbed by a gas and then re-emitted as two photons. One photon is red with wavelength 760 nm. Hence wavelength of the second photon is: (a) 460 nm (b) 1060 nm (c) 496 nm (d) 300 nm SCO # 203 , SECOND FLOOR , SECTOR - 14 , PKL. 4634812 (O) , 9888019721 , 9988819721 Page 1 MUNISH KAKAR's INSTITUTE OF CHEMISTRY Q12. The work function of a metal is 4.0 eV. The longest wavelength of light that can cause photoelectron emission from this metal is approximately (a) 540 nm (b) 400 nm (c) 310 nm (d) 220 nm Q13. An electron in H-atom in its ground state absorbs 1.50 times as much as energy as the minimum required for its escape (13.6 eV) from the atom. Thus KE of emitted electron is: (a) 13.6 eV (b) 20.4 eV (c) 34.0 eV (d) 6.8 eV Q14. Of the following, radiation with maximum wavelength is: (a) UV (b) Radio wave (c) X-ray (d) IR o Q15. Photoelectric work function of a metal is 1 eV. If a light of wavelength 3000 A falls on the metal, the velocity of the photoelectron ejected will be (a) 10 ms-1 (b) 103 ms-1 (c) 104 ms-1 (d) 106 ms-1 Q16. Calculate the energy in kilocalorie per mol of the photons of an electromagnetic radiation of wavelength 7600 Å. Ans : 37.58 kcal/mole Q17. Calculate the kinetic energy of an electron produced in Cs, when it is exposed to radiation having wavelength 400 nm. Given that the threshold wavelength of Cs is 660 nm. (1.22eV or 1.95 × 10-19 J ) Q18. When light with a wavelength of 400 nm falls on the surface of sodium, electrons with a kinetic energy 1.05 x 105 J mol-1 are emitted. (a) What is the minimum energy needed to remove an electron from sodium ? (b) What is the maximum of light that will cause a photoelectron to be emitted ? 19 J Ans (a) 3.27 10 7 (b) 6.08 10 m Q19. When light frequency is shown on metal surface with threshold frequency o , photo electrons are emitted with maximum kinetic energy 1.3 1018 J . If : o 3:1 , calculate the threshold frequency o ( 9.81 1014 Hz ) Q20. When a certain metal was irradiated with light of frequency 3.2 x 10 16 Hz, the photoelectrons emitted had twice the kinetic energy as did photoelectrons emitted when the same metal was irradiated with light of frequency 2.0 x 1016 Hz. Calculate v0 Ans : 8 1015 Hz Q21. Yellow light emitted from a sodium lamp has a wavelength () of 580 nm. Calculate the frequency and wave number of this light. 5.17 x 1014 s1 ; 1.72 x 106 m1 Q22. Calculate (i) wave number (ii) frequency of yellow radiation having 5800 Ǻ. Ans. (i) 1.724 x 106 m1 (ii) 5.172 x 1014 s1 SCO # 203 , SECOND FLOOR , SECTOR - 14 , PKL. 4634812 (O) , 9888019721 , 9988819721 Page 2 MUNISH KAKAR's INSTITUTE OF CHEMISTRY Q23. A photon of wavelength 4000 Å strikes a metal surface, the work function of the metal being 2.13 eV. Calculate (i) the energy of the photon in eV, (ii) the kinetic energy of the emitted photoelectron, and (iii) the velocity of the photoelectron. Ans : (i) 3.1 eV (ii) 0.97 eV (iii) 5.8 105 m / s Q24. For silver metal, the threshold frequency v0 is 1.13 x 1017 Hz. What is the maximum kinetic energy of photoelectrons produced by ultraviolet light of wavelength 15.0 Ǻ ? Ans.=5.652 x 1017 J SCO # 203 , SECOND FLOOR , SECTOR - 14 , PKL. 4634812 (O) , 9888019721 , 9988819721 Page 3
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