UNIVERSITY OF HELSINKI DEPARTMENT OF PHYSICS REPORT SERIES IN GEOPHYSICS No 77 BALTICA FROM THE SVECOFENNIAN UNTIL THE EDIACARAN: A PALEOMAGNETIC STUDY OF PRECAMBRIAN FORMATIONS OF FINLAND Robert Klein Cover images: Top left: Geomagnetic field Top right: Åland diabase dyke Bottom left: Satakunta sandstone (Satu Mertanen) Bottom right: Laurentia, Baltica, Amazonia and Siberia in Nuna configuration HELSINKI 2016 Supervisors: Prof. emer. Lauri J. Pesonen Department of Physics University of Helsinki Helsinki, Finland Dr. Satu Mertanen Geological Survey of Finland Espoo, Finland Prof. Ilmo Kukkonen Department of Physics University of Helsinki Helsinki, Finland Pre-examiners: Dr. Sergei Pisarevsky School of Earth and Environment University of Western Australia Crawley, Australia Prof. Phil McCausland Department of Earth Sciences Western University London, Ontario Canada Opponent: Custos: Prof. David A.D. Evans Department of Geology and Geophysics Yale University New Haven, USA Prof. Ilmo Kukkonen Department of Physics University of Helsinki Helsinki, Finland Report Series in Geophysics No. 77 ISBN 978-951-51-1945-2 (printed version) ISBN 978-951-51-1946-9 (pdf version) ISSN 0355-8630 Helsinki 2016 Unigrafia BALTICA FROM THE SVECOFENNIAN UNTIL THE EDIACARAN: A PALEOMAGNETIC STUDY OF PRECAMBRIAN FORMATIONS OF FINLAND Robert Klein ACADEMIC DISSERTATION IN GEOPHYSICS To be presented, with the permission of the Faculty of Science of the University of Helsinki for public criticism in the Auditorium E204 of Physicum, Gustaf Hällströminkatu 2a, on 11 March, 2016, at 12 pm. Helsinki 2016 Table of contents List of original articles 7 Abstract 8 Acknowledgments 11 1. Introduction 12 1.1. Supercontinents 12 1.1.1. Nuna 13 1.1.2. Rodinia 15 1.2. Paleomagnetism 17 1.2.1. The geocentric axial dipole 17 1.2.2. Magnetism in rocks 18 1.2.3. Paleomagnetic measurements 21 1.2.4. Apparent polar wander paths and paleogeographic reconstructions 22 1.2.5. Mafic dykes and sedimentary rocks in paleomagnetic studies 23 2. Aims of this study 25 3. Materials and methods 25 3.1. Sampling and sample preparation 25 3.2. Laboratory measurements. 26 3.2.1. Petrophysical measurements 26 3.2.2. Paleomagnetic and rock magnetic measurements 27 28 4. Review of articles 4.1. Article I 28 4.2. Article II 29 5 4.3. Article III 30 4.4. Article IV 31 4.5. Author’s contribution 32 33 5. Results and discussion 5.1. Paleomagnetic results obtained in this work 33 5.1.1. Diabase dykes 33 5.1.2. Sedimentary rocks 36 5.1.3. Secondary component 36 5.2. Apparent polar wander paths for Baltica (1.87 – 0.57 Ga) 38 5.3. Paleogeographic reconstructions (1.87 – 0.57 Ga) 41 6. Conclusions 50 7. References 52 6 List of original articles This thesis is based on the following four articles, which are referred to in the text by their Roman numerals: I. Klein, R., Pesonen, L.J., Salminen, J., Mertanen, S., 2014. Paleomagnetism of Mesoproterozoic Satakunta sandstone, Western Finland. Precambrian Research 244, 156169. II. Salminen, J.M., Klein, R., Mertanen, S., Pesonen, L.J., Fröjdö, S., Mänttäri, I., Eklund, O., 2015. Palaeomagnetism and U–Pb geochronology of c. 1570 Ma intrusives from Åland archipelago, SW Finland – implications for Nuna. In Li, Z. X., Evans, D. A. D. and Murphy, J. B. (eds) Supercontinent Cycles Through Earth History. Geological Society, London, Special Publications 424, http://doi.org/10.1144/SP424.3. III. Klein, R., Salminen, J., Mertanen, S., 2015. Baltica during the Ediacaran and Cambrian: A paleomagnetic study of Hailuoto sediments in Finland. Precambrian Research 267, 94-105. IV. Klein, R., Pesonen, L.J., Mänttäri, I., (submitted). A new late Paleoproterozoic pole for Baltica: A paleomagnetic and geochronological study of the Keuruu diabase dykes, Central Finland. Precambrian Research. Article I and III are reprinted from Precambrian Research with the permission of Elsevier. Article II is reprinted from Geological Society of London Special Publications with permission from the Geological Society. 7 Abstract This dissertation presents paleomagnetic results from Baltica for three significant time intervals during the evolution of Precambrian supercontinents: i) 1.87 Ga – the onset of the supercontinent Nuna; ii) 1.58–1.57 Ga – maximum compaction of Nuna; and iii) ca. 0.6–0.57 Ga – the break-up between Baltica and Laurentia which marked the final break-up of the supercontinent Rodinia. Paleogeographic reconstructions at 1.25 Ga and 1.05 Ga – which marks the transition from Nuna to Rodinia - is briefly discussed based on existing paleomagnetic results; no new data were produced for these two reconstructions. New paleomagnetic results were obtained from samples from the 1.87 Ga Keuruu diabase dyke swarm (Central Finland), 1.58-1.57 Ga Åland intrusives (Åland archipelago, SW Finland) and ca. 0.6-0.57 Ga Hailuoto sedimentary formation (Western Finland). In addition to these, new paleomagnetic results were obtained from the Satakunta sandstone formation (SW Finland), providing a new paleomagnetic age estimate of ca. 1.63 – 1.45 Ga for the sandstone deposition, older than previously thought (ca. 1.4-1.3 Ga). The 1.87 Ga Keuruu diabase dykes yield a dual polarity intermediate NNW downward or SSE upward characteristic remanent magnetization (ChRM), positioning Baltica at low latitudes in a way that would proceed into the 1.8-1.2 Ga NENA (North Europe – North America) configuration. The age of the Keuruu dykes are defined by a U-Pb (zircon) age of 1870 ± 9 Ma and a Pb-Pb (zircon) age of 1869 ± 7 Ma. The primary nature of the Keuruu ChRM is supported by positive baked contact tests. The Åland intrusives and Satakunta sandstone both yield dual polarity shallow (upward and downward) NNE or SSW characteristic remanent magnetizations (ChRM), positioning Baltica on equatorial paleolatitudes and supporting the NENA configuration between Baltica and Laurentia during the Mesoproterozoic. Well determined U-Pb (zircon) ages narrows the occurrence of intrusion to 1570 – 1580 Ma. The primary nature of the Åland intrusives ChRM is supported by positive baked contact tests. The Hailuoto sedimentary samples were obtained from a 272 m deep fully oriented drill core. The depostional age of the Hailuoto sediments is poorly constrained at 570-600 Ma, based on fossil records. The Hailuoto pole adds to the scattered Ediacaran paleomagnetic data of Baltica and indicates large distances between other late Neoproterozoic and early Cambrian paleomagnetic poles, implying rapid movement of Baltica from high latitudes at 615 Ma, over the polar region, to low latitudes at 550 Ma. 8 In all these cases a secondary component with shallow to intermediate downward inclinations and northeasterly declinations were observed. This secondary component is commonly observed in the Fennoscandian Shield and has previously been interpreted as a result of oxidizing fluids during the Phanerozoic. In the case of Keuruu and Åland, meteorite impact (from Keurusselkä and Lumparn, respectively) cannot be ruled out as a possible cause of the secondary component. This component is mostly observed at low coercivities/blocking temperatures, but sometimes also at higher coercivities/blocking temperatures, causing asymmetry in the dual polarity results of Keuruu diabase dykes and Åland intrusives. In summary, the work presented in this dissertation provides new paleomagnetic results for Baltica, adding two new key poles to the Paleoproterozoic-Mesoproterozoic apparent polar wander path (APWP) of Baltica. Furthermore, the results provide a better understanding of the movement of Baltica during the enigmatic Ediacaran period. Paleogeographic reconstructions are presented at 1.87 Ga, 1.57 Ga, 1.25 Ga, and 1.05 Ga. The 1.87 Ga reconstruction do not support the NENA or SAMBA configurations, but indicates the onset of Nuna. The 1.57 Ga and 1.25 Ga reconstructions indicate similarities in the relative positions between Baltica, Laurentia, Amazonia, and Siberia during this period. The transition between Nuna and Rodinia is marked by a rotation between Laurentia, and Baltica and Amazonia (and possibly West Africa), forming the Grenville collisional belt. 9 10 Acknowledgments Support for this work was provided by the Finnish Doctoral Program in Geosciences (formerly the Finnish Graduate School in Geology), and the Vilho, Yrjö and Kalle Väisälä Foundation. Additional funding for field work and travel was provided by the Satakunta Regional Fund of the Finnish Cultural Foundation, the Oskar Öflund Foundation, and the University of Helsinki Chancellor’s travel grant. I would like to express my gratitude to my supervisors, Prof. emer. Lauri Pesonen, Dr. Satu Mertanen, and Prof. Ilmo Kukkonen, for their support during my thesis work. I would especially like to thank Prof. emer. Pesonen for giving me the opportunity to work at the Solid Earth Geophysics Laboratory. I sincerely thank the pre-examiners of this thesis, Dr. Sergei Pisarevsky (University of Western Australia), and Prof. Phil McCausland (Western University, Canada) for their constructive reviews, which helped to improve this thesis significantly. A special thanks to my co-authors, and colleagues (former and current), without whom this work would not have been possible. I am especially indebted to Johanna Salminen and Tomáš Kohout for their scientific and technical support. Finally, I would like thank my family and friends for their moral support. My warmest gratitude goes to my wife, Anu, for her support and patience, especially during the final stages of my thesis. 11 1. Introduction. 1.1. Supercontinents Supercontinents are assemblies that contain all, or most of the Earth’s continental blocks (Rogers and Santosh, 2004). The most recent supercontinent, Pangea, reached its maximum packing at ca. 250 Ma (e.g. Torsvik et. al., 2012), after which it started to rift apart, forming our present ocean basins. The configuration of Pangea can be best determined by tracing the patterns of magnetic stripes in the oceans that opened within it. Pangea consisted of Gondwana in the south, and Laurasia in the north. Gondwana comprised the southern continents - South America, Africa, India, Madagascar, Australia, and Antarctica - and had already formed at ca. 550 Ma (Meert and Van der Voo, 1997), and accreted to Pangea as a single block. The concept of Gondwana originated when paleontologists noted that Paleozoic and Early Mesozoic fossils from South America, Africa, India and Australia were all very similar. Laurasia consisted of Laurentia (core of the North American continent) and Eurasia, however a large part of it formed during the accretion of Pangea (Rogers and Santosh, 2004). Several pre-Pangea supercontinents have been proposed. Apart from paleomagnetic data (explained below), there is also geological evidence of the existence of Precambrian supercontinents. Orogenic belts are thought by some to have developed during the formation of supercontinents, and are now scattered over the present day continents. The Paleo- to Mesoproterozoic supercontinent Nuna (also called Columbia; e.g. Zhao et al., 2004) was reconstructed largely on the basis of aligning the 2.1-1.8 Ga orogenic belts that occur on many continental blocks. Evidence for the late Meso- to Neoproterozoic supercontinent, Rodinia, is partly based on the presence of 1.1-0.9 Ga orogenic belts (Hoffman, 1991). Also, dyke swarms provide evidence of the existence of Precambrian supercontinents where they occur on several continents that have rifted apart after the dyke intrustion (e.g. Pesonen et al., 2003). Furthermore, global peaks in isotopic age determinations at 2.7-2.6 Ga, 1.9-1.8 Ga and 1.2-1.1 Ga coincide with the existence of supercontinents prior to Pangea and Gondwana (Reddy and Evans, 2009) namely Rodinia (ca. 1.05-0.7 Ga), Nuna (ca. 1.8-1.26 Ga) and Kenorland (2.7-2.1 Ga) (Pesonen et al., 2012b). Gurnis (1988) proposed a supercontinent model, in which supercontinents insulate the mantle beneath them, eventually leading to a breakup over a geoid high, which is created by rising plumes. The rising plumes/superplumes in turn are proposed to exist as a result of slab avalanches caused by slabs of subducted oceanic lithosphere that drop into the lower mantle (e.g. Condie, 1998; 2001). The subsequent development of supercontinents after break-up can be explained by three different models, namely extroversion, introversion and orthoversion (e.g. Murphy and Nance, 2013; Mitchell et al., 12 2012). Extroversion refers to a process in which dispersing continents move towards subduction zones in the exterior ocean where they amalgamate and form a new supercontinent. Introversion, as was the case during the amalgamation of Pangea, involves a reversal in the direction of the motion of continents leading to the subduction of the interior oceanic crust resulting in a new supercontinent where its predecessor was located. Orthoversion refers to the process in which a new supercontinent forms at a location orthogonal to from its predecessor and involves the subduction of either exterior or interior oceanic crust, or a combination (Murphy and Nance, 2003; Mitchell et al., 2012). Supercontinents have played a key role in the evolution of the Earth’s surface at least since Paleoproterozoic time (Evans and Pisarevsky, 2008). For example the compression of continents associated with supercontinent amalgamation is expected to lower sea levels, and crustal thinning and seafloor spreading associated with supercontinent break-up is expected to give rise to an increase in sea level (Reddy and Evans, 2009 and references therein). The increase or decrease in energyabsorbing oceanic surfaces may affect global climate. Supercontinent cycles also have significant effects on the carbon cycle, as higher precipitation rates on low-latitude supercontinents enhance silicate weathering (e.g. Kirschvink, 1992). 1.1.1. Nuna Orogenic activity between 2.1 Ga and 1.6 Ga (Zhao et al., 2004, Rogers and Santosh, 2004) and evidence of widespread extension starting at ca. 1.5 Ga (Rogers and Santosh, 2004) indicates the existence of the pre-Rodinian superconinent Nuna (also known as Columbia or Hudsonland). Several reconstructions of Nuna have been proposed (e.g. Rogers, 1996; Hoffman, 1997; Meert, 2002; Zhao et al., 2004, Pisarevsky et al., 2014a), most of which feature Laurentia, Baltica, Amazonia, Siberia, and Australia connections. The core of the supercontinent Nuna, NENA (North Europe – North America), in which Greenland aligns with Kola Peninsula and northern Norway, is proposed by many authors to have existed during 1.8-1.2 Ga (e.g. Gower et al., 1990; Buchan et al., 2000; Pesonen et al., 2003; Salminen and Pesonen, 2007; Evans and Pisarevsky, 2008; Evans and Mitchell, 2011; Salminen et al., 2014). It is supported by a tight cratonic fit, concordance with basement geology, geochronological correlations, and matching paleomagnetic poles at 1.75 Ga, 1.63 Ga, 1.59 Ga, 1.46 Ga and 1.27 Ga (Salminen et al., 2014). 13 Baltica consists of the Sarmatian craton, Volgo-Uralian crustal segment, and Fennoscandian Shield. Sarmatia and Volgo-Uralia collided at ca. 2.1-2.0 Ga forming Sarmatia/Volgo-Uralia, which later collided with the Fennoscandian Shield between 1.82 and 1.80 Ga along the Russian collisional belt (Bogdanova et al., 2008, 2015; Elming et al., 2010). Based on bedrock geological studies, Johansson (2009) proposed a PaleoproterozoicMesoproterozoic assembly between Baltica and Amazonia (SAMBA model) as the 1.9-1.8 Ga Svecofennian orogen in Baltica continues into the 1.98-1.81 Ga Ventuari-Tapajós province in Amazonia. The slightly younger 1.85-1.65 Ga Transscandinavian igneous belt (TIB) and 1.64-1.52 Ga Gothian orogens of Baltica continues into the 1.78-1.55 Ga Rio Negro-Juruena province in Amazonia. It is widely accepted that Amazonia and West Africa formed a rigid continent, similar to their Gondwana configuration, during the Mesoproterozoic (Trompette, 1994). Some authors (e.g. Pisarevsky et al., 2014a) position Amazonia together with West Africa, in the antiparallel posision, as an alternative to the SAMBA configuration. Laurentia consists of Superior, Wyoming, Slave, Nain, and Churchill (Hearne, Rae and Burwell domains) cratons which were assembled by collisional orogens by 1.8 Ga (Buchan et al., 2000; Hoffman, 1989). Slave and Rae collided at 1.97 Ga (Thelon orogeny), and the the Slave-Rae-Hearne assembly collided with Superior between 1.91 and 1.81 Ga, forming the Trans-Hudson orogeny (Hoffman, 1988; Mitchell et al., 2014). It is proposed that Siberia also formed part of the core of Nuna (Wingate et al., 2009; Evans and Mitchell, 2011), since the Siberian APWP can be juxtaposed with that of NENA between 1.8 Ga and 1.4 Ga (Evans and Mitchell, 2011). Geological correlations suggest that the Aldan shield of Siberia was connected to northern Greenland and Canada (Rainbird et al., 1998). Pisarevsky et al. (2014a) on the other hand proposes a distant, but fixed position of Siberia relative to Laurentia between 1.5 Ga and 1.0 Ga, based on coeval paleomagnetic poles (Wingate et al., 2009; Meert and Stuckey, 2002). Australia formed by the assembly of the North Australian, West Australian and South Australian cratons. The time of assembly is uncertain, however Li and Evans (2011) proposed that they were in close proximity to each other since ca. 1.8 Ga. North Australia was possibly connected to NW Laurentia during the Mesoproterozoic (Zhang et al., 2012; Pisarevsky et al., 2014a). Mafic magmatism of ca. 1.59 – 1.46 Ga across Nuna, and dyke swarms of the 1.38-1.24 Ga period, are linked with the break-up of Nuna (Roberts, 2013 and references within). However, many of the dyke swarms occurring at craton margins may be related to plate-margin processes and not the breakup of the supercontinent (Söderlund et al., 2005; Shellnutt and MacRae, 2012; Roberts, 2013). 14 Furthermore, the break-up of supercontinents are followed by rifting and the gradual formation of passive margins, however Nuna has a low passive margin abundance, suggesting that no significant break-up and dispersal of continents took place (Bradley, 2008; 2011). Fig. 1. Examples of Nuna and Rodinia reconstructions. 1.1.2. Rodinia Rodinia assembled through orogenic activity between 1.3 Ga and 0.9 Ga (e.g. Li et al., 2008), and reached complete assembly at ca. 1.0 Ga (Rogers and Santosh, 2004). All continental blocks were likely to be involved and Laurentia is thought to have formed the core of Rodina as it is surrounded by Neoproterozoic passive margins (McMenamin and McMenamin, 1990; Hoffman, 1991; Meert and Torsvik, 2003; Li et al., 2008). Different configurations of Rodinia have been proposed, including the SWEAT, AUSWUS, AUSMEX, and “missing-link” models, each containing difficulties. The SWEAT (Southwest U.S. – East Antarctica) model (Fig. 1), proposed by Moores (1991), and shown in Fig. 1, assumes that Grenville orogenic belts are zones of oceanic closure between continental blocks (Rogers and Santosh, 2004). In this configuration eastern Antarctica and eastern Australia are connected to southwestern Laurentia. The AUSWUS (Australia-Southwest U.S.) model is based on 15 matching basement provinces and sedimentary provenances between Australia and southwestern Laurentia (Karlstrom et al., 2001; Burrett and Berry, 2000). Based on paleomagnetic results, Wingate et al. (2002) proposed the AUSMEX (Australia – Mexico) model in which northeastern Australia is joined to Mexico of southern Laurentia. The “missing link” model (Li et al., 1995) proposes that the South China block was situated between Australia-East Antarctica and Laurentia due to the mismatches in crustal provinces of Australia-East Antarctica and Laurentia in the SWEAT model as well as similarities in stratigraphy and crustal provinces between South China, southeastern Australia and western Laurentia. Meert (2014a) points out the similarities between Nuna, Rodinia and Pangea, in particular the assembly of Baltica, Laurentia and Siberia, as well as parts of East Gondwana. Such recurring similarities would be unlikely with extroversion and introversion of ocean basins leading Meert (2014a) to suggest lid-style tectonics with episodes of true polar wander (i.e. the rotation of the Earth with respect to its spin axis). Roberts (2013) proposes a model in which Nuna underwent only minor modifications to form Rodinia at 1.1-0.9 Ga, which include the transformation of external accretionary belts into the internal Grenville and equivalent collisional belts. Piper (1982) proposed an alternative Proterozoic supercontinent, namely Palaeopangea, that are also based on lid-style tectonics, and survived until a major break-up event during the Ediacaran (ca. 0.6 Ga; Piper, 2013). Piper (1982, 2013, 2015) further showed that the paleomagnetic record conformed to a single, global APWP using the Paleopangea reconstruction from ca. 2.7 Ga to 0.6 Ga and that the majority of paleomagnetic poles at 2.7-2.5 Ga, 1.5-1.2 Ga, and 0.75-0.6 Ga are positioned in a quasi-static position. Palaeopangea is a crescentric shaped supercontinent, similar in shape as Pangea, confined to a single hemisphere (Piper, 2015). Palaeopangea is made up of the 3.0 Ga Ur (Kaapvaal, Pilbara, Dharwar and Signhbum cratons), 2.5 Ga Arctica (Siberian and Canadian cratons), and 2.0 Ga Atlantica (South American and West African cratons). The period 2.1-1.8 Ga was marked by significant crustal growth forming long linear mobile belts within the core of Ur-Atlantica-Arctica and accreted to the periphery, with the orogenic belts forming an axial trend through the continental lid (Piper, 2015). Similarly, the Grenville orogenic belts (1.1 Ga) formed linearly along Palaeopangea. However, the Palaeopangea model is critized for being based on incorrect application of paleomagnetic data, and for lacking geological evidence (Li et al., 2009). 16 1.2. Paleomagnetism 1.2.1. The geocentric axial dipole The role of paleomagnetism in supercontinent reconstruction is based on the concept of a geocentric axial dipole (GAD) model. According to this model the Earth’s magnetic field is produced by a single magnetic dipole (consisting of a North and South pole) at the centre of the Earth, and is aligned with the Earth’s rotation axis (Butler, 2004). The magnetic field vector (H), at any one location on Earth, is expressed: ܪൌ ܯ ඥͳ ͵݊݅ݏଶ ߣ ܴଷ (1) And can be divided into a vertical (Hv) and horizontal (Hh) component: ܪ௩ ൌ ʹߣ݊݅ݏܯ ܴଷ (2) ߣݏܿܯ ܴଷ (3) ܪℎ ൌ In Eq. (1) – (3) M is the dipole moment of the geocentric axial dipole (Am2), λ is the geographic latitude (ranging from -90° to +90°), and Re is the mean radius of the Earth (6371 km). The magnetic field strength observed at the Earth’s surface increases from the equator to the poles. The magnetic inclination (I) is defined as the vertical angle between the horizontal component (Hh) and the total magnetic field vector (H) for a given latitude. The relationship between magnetic inclination and geographic latitude (λ) is expressed by the following equation: tanI = 2 tanλ (4) where I is magnetic inclination and λ is the geographic latitude. 17 Fig. 2. Geocentric axial dipole model (from Butler (2004)), illustrating the relationship between latitude (λ) and magnetic inclination (I). The reconstruction of Precambrian supercontinents using paleomagnetism assumes that 1) the Earth has had an internal magnetic field since at least the Paleoproterozoic, and 2) that the Precambrian field was generated by a GAD. Paleosecular variation studies support a geodynamo during Neoarchean and Proterozoic times (e.g. Smirnov et al., 2011). Inclination frequency analysis (Veikkolainen et al. 2014a), geomagnetic field reversal symmetry studies (Veikkolainen et al. 2014b), and paleointensity investigations (Biggin et al., 2015), indicate a predominantly GAD field, with weak axial quadrupole and octopole coefficients (<10%) that have negligible consequences to Precambrian continental assemblies. Furthermore, Precambrian magnetostratigraphy (Pavlov and Gallet, 2011) and latitudinal control of paleoclimatic indicators, such as evaporates (mid-latitudes) or glacial deposits (polar latitudes) further support a GAD (Evans, 2006). 1.2.2. Magnetism in rocks Recording the magnetic field vector of a rock formation depends on the material. Induced magnetization is linearly related to the magnetic field and is expressed: Ji = χH (5) where χ is the magnetic susceptibility of the material (dimensionless, or ‘SI’), and H is the magnetic field (Am-1). Rocks contain diamagnetic, paramagnetic, and ferromagnetic minerals. Ferromagnetism is used here in a broad sense, and unless indicated otherwise, also implies ferri- and antiferromagnetism. 18 In response to a magnetic field, diamagnetic particles, such as quartz, acquire a small induced magnetization opposite to the applied field. Diamagnetic magnetization is very small, does not depend on temperature, and becomes zero in the absence of an external magnetic field. Paramagnetic minerals, such as biotite and pyrite, acquire an induced magnetization parallel to the magnetic field. Paramagnetic magnetization is relatively small and depends on temperature. In the absence of an external magnetic field the magnetization is zero (Dunlop and Özdemir, 1997). Only ferromagnetic particles have the ability to record the direction of the applied magnetic field so that it exists in the absence of the applied magnetic field. This is known as remanent magnetization, which is the focus in paleomagnetic research. Unlike dia- and paramagnetic magnetization, ferromagnetic materials exhibit hysterisis (an irreversable path of magnetization) in response to an external magnetic field. Ferromagnetic elements also acquire induced magnetizations, which are orders of magnitude higher than paramagnetic minerals, due to strong interactions between spin moments. Natural remanent magnetization (NRM) of a rock is obtained from the geomagnetic field during rock formation and the subsequent geological history of the rock. NRM can be stable over geological time and resist the changes of the Earth’s magnetic field. Although remanent magnetization undergoes a natural viscous decay with time, described as its relaxation time, at typical Earth surface temperatures the relaxation time for ferromagnetic grain sizes ≤100μm is of the order of 109 yr or more (Butler, 2004). There are different types of natural remanent magnetization, depending on how it is acquired. Thermoremanent magnetization (TRM) is acquired during cooling after formation (igneous rocks) or after high metamorphic temperatures. If the metamorphic temperature is below the original formation temperature, the rock may acquire a partial thermoremanent magnetization (pTRM). Each given ferromagnetic mineral has a characteristic Curie temperature, above which the mineral becomes paramagnetic. Relaxation time is temperature dependent. As the rock cools below its Curie temperature, the relaxation time increases rapidly with decreasing temperature. For a given relaxation time there is a specific temperature known as the blocking temperature. As the ferromagnetic grains cool below their respective Curie temperatures and the temperature decreases through the blocking temperatures the grains acquire a TRM along the prevailing field, and experience a significant increase in relaxation time, becoming increasingly stable. Table 1 shows the properties of different ferromagnetic minerals. Magnetite, a ferrimagnetic iron oxide, does not only have a relatively high Curie temperature (578°C) but also strong magnetic susceptibility (χ) as well as high saturation 19 magnetization (Js) and high to moderate coercivity values, making it one of the most important minerals in igneous rocks for paleomagnetic studies. Table 1 Chemical composition and basic magnetic properties of the main ferromagnetic minerals (Dunlop and Özdemir, 1997). Mineral Composition TC (°C) χ (SI) JS (kA/m) HC (T) Goethite αFeOOH 120 ca. 20-30* ca. 2 2.2 Magnetite Fe3O4 580 1.2-19.2 480 0.1-0.25 Maghemite γFe2O3 590-675 ** 380 ca. 0.1 Hematite αFe2O3 675 0.5-35 × 10-3 ca. 2.5 2.5-7.6 Titanomagnetite Fe3-xTixO4 150-540 *** 125 0.2 Pyrrhotite Fe7S8 320 0.001-6 ca. 80 0.2-0.35 TC = Curie temperature, χ = magnetic susceptibility, JS = saturation magnetization, HC = coercivity * Özdemir and Dunlop (1996) ** Difficult to measure in laboratory due to chemical alteration *** Depends on Ti-content: decreases with increasing Ti-content. Chemical changes of a rock can give rise to chemical remanent magnetization (CRM) or thermochemical remanent magnetization (TCRM) if the chemical changes involve a rise in temperature. CRM occurs as a result of the alteration of pre-existing minerals to a ferromagnetic mineral or the precipitation of ferromagnetic minerals from a solution (Butler, 2004). CRM is common in sedimentary rocks. In marine and lake sediments CRM can form soon after deposition as as ironsulfate reduction diagenesis (Kodama, 2012). When secondary magnetic minerals first form they are too small to carry a stable remanent magnetization, however as they grow they can eventually attain stable remanance with relaxation times of the order of 109 yr. Detrital remanent magnetization (DRM) is acquired during deposition and lithification of sedimentary rocks. During deposition pore spaces in the non-magnetic matrix are larger than the magnetic grains. The magnetic grains can therefore freely move and align with the Earth’s magnetic 20 field. As the sediment is buried and becomes dewatered from compactions, the pore spaces become smaller and the magnetic minerals become trapped and immobile obtaining a post-depostional remance (pDRM). The pDRM is usually aquired at a burial depth of below 20 cm (eg. Tauxe et al., 1996; Kodama, 2012). Viscous remanent magnetization (VRM) is gradually acquired when a formation is exposed to weak magnetic fields, like the Earth’s magnetic field, and typically has low unblocking temperatures. The direction of VRM gradually aligns with the ambient magnetic field direction. Characteristic remanent magnetization (ChRM), on the other hand, is the highest stability component of a sample during the course of demagnetization, and is usually an ancient magnetization. ChRM can be TRM, CRM, TCRM, or DRM (Butler, 2004). 1.2.3. Paleomagnetic measurements Remanent magnetization of a rock can be determined through paleomagnetic measurements. By means of demagnetization methods, secondary NRM is removed and the ChRM is isolated. The two most common demagnetization techniques are alternating field (AF) demagnetization and thermal demagnetization. During alternating field demagnetization the specimen is exposed to an alternating magnetic field in a zero ambient field. The applied alternating field decreases in magnitude with time, magnetizing all ferromagnetic minerals with a coercivity smaller than the peak demagnetizing field in alternating antiparallel directions, resulting in a net magnetization of zero. Coercivity is defined as the intensity of the applied magnetic field required to reduce the magnetization of the material to zero. The stepwise alternating field process is repeated with a progressively increasing peak applied field until the specimen is demagnetized completely, or the maximum field of the instrument is reached. A typical AF progression would comprise peak fields of 2.5, 5, 7.5, 10, 15, 20, 25, 30, 40, 50, 60, 80, 100, 120, 140, and 160 mT. Thermal demagnetization involves the heating and subsequent cooling to room temperature of a specimen in zero magnetic field. This is repeated with progressively increasing temperatures, and with each step the remanent magnetization with a blocking temperature equal to or lower than the applied temperature is demagnetized. A typical thermal progression would be temperatures of 200, 300, 400, 500, 520, 540, 560, 570, 580, 600, 620, 640, 660, 670, and 680°C, tailored to reveal the 21 characteristic unblocking temperature ranges of magnetite (500° - 580°C) and hematite (620° 680°C) After each AF or thermal step, the remaining remanent magnetization of the vertical and horizontal axes (Mx, My, Mz) is measured, and from these the total magnetic moment (M), and magnetic declination (D) and inclination (I) are calculated as follows: ܯൌ ටܯ௫ଶ ܯ௬ଶ ܯ௭ଶ ܦൌ ି݊ܽݐଵ ൬ ܫൌ ି݊ܽݐଵ ቆ (6) ܯ௬ ൰ ܯ௫ ܯ௭ ඥܯ௫ଶ ܯ௬ଶ (7) ቇ (8) To isolate different remanent components, linear least square analysis (Dunlop, 1979) is a commonly used method. For visualization of remanence components, a Zijderveld diagram (Zijderveld, 1967) is used to identify as well as quantify multiple components. A Zijderveld diagram is a plot of magnetization direction and intensity during the course of AF or thermal demagnetization, projected on two orthogonal planes. The slopes of linear successions of demagnetization steps, in three dimensions, corresponds with the declination and inclination of magnetic components. Other methods for quantifying remanence components include principal component analysis (Kirschvink, 1980), intersecting great circle technique, and analysis of vector end points (Halls, 1976; 1978). Fisher statistics are used to calculate mean declination and inclination values for components of samples or sites (Fisher, 1953) 1.2.4. Apparent polar wander paths and paleogeographic reconstructions Paleomagnetic pole positions are calculated from paleomagnetic declination and inclination. A paleomagnetic pole is the position of the North pole at the time of magnetization in relation to the current geographic position of the craton/continent under investigation. The position of the paleomagnetic pole is independent of the observing locality, and is therfore used to compare paleomagnetic results between different localities or continents. Paleomagnetic poles are used to construct apparent polar wander paths (APWP's). An APWP is a series of age-successive paleomagnetic poles indicating the movement of a continental/craton over time. APWP’s from 22 separate continents/cratons can be used to test their assembly and break-up. The denser the data set of reliable paleomagnetic poles for each APWP, the more precisely the periods of amalgamation and break-up between continents/cratons can be determined (Evans and Pisarevsky, 2008). In articles I-IV, the most reliable poles were used for any given time to construct APWP’s. The reliability of paleomagnetic poles is determined by seven criteria proposed by Van der Voo (1990). They are i) a well determined rock age that corresponds with the age of magnetization, ii) a sufficient number of samples (N>24), iii) adequate demagnetization (including vector subtraction), iv) a positive field stability test (such as a baked contact test), v) tectonic coherence with the craton/continent in question, vi) the presence of anti-parallel polarities, and vii) no resemblance to younger paleopoles. The more of these criteria a paleomagnetic pole fulfills the more reliable it is, however for it to be regarded a key paleomagnetic pole (i.e. well dated and well defined pole for reconstruction) it has to fulfill at least the basic criteria: a well determined rock age and a field stability tests, in addition to other criteria (Buchan et al. 2000; Buchan, 2013). Paleomagnetism is an essential tool in paleogeographic reconstructions to show the ancient positions of continents/cratons relative to each other. Combined with geochronology, paleomagnetism remains the only quantitative method to reconstruct Precambrian continents to an absolute paleogeographic reference frame. The paleolatitude of a continent is determined by the magnetic inclination. Magnetic declination determines the vertical axis rotation of the continent. Paleolongitude cannot be determined with paleomagnetism, so geological features such as dyke swarms and orogenic belts are used to constrain the relative positions of continental blocks. 1.2.5. Mafic dykes and sedimentary rocks in paleomagnetic studies Mafic dykes are ideal for paleomagnetic studies, because they cool rapidly and therefore provide an accurate record of the Earth’s magnetic field. In addition, they may contain zircon and/or baddeleyite which are used to establish the precise crystallization ages of the dykes (e.g. French and Heaman, 2010; Halls et al., 2007). Sedimentary rocks, on the other hand, present challenges as they are more difficult to be dated accurately, and they can be subject to inclination shallowing. However, sedimentary rocks can give a continuous record of the magnetic field (Kodama, 2012) and therefore fill important age gaps in paleomagnetic records. Another reason why the continuity of sedimentary paleomagnetic records is important is because it allows time averaging of the secular variation of the geomagnetic field (Butler, 2004; Kodama, 2012). 23 It is important to make inclination corrections for paleomagnetic results obtained from sedimentary rocks, since inclination shallowing can be as much as 20° at mid-latitudes (Kodama, 2012). Inclination shallowing occurs as a result of burial compaction at depths of tens to hundreds of meters (Kodama, 2012). Examples of sedimentary inclination shallowing are numerous in a variety of natural settings (e.g. Bilardello and Kodama, 2010) and in several laboratory re-deposition experiments (e.g. Tauxe and Kent, 1984). Due to the great diversity of sediment characteristics and depositional conditions, in addition to the assortment of specific mechanisms by which a magnetization may acquire a shallow inclination bias, the magnitude of the bias in sedimentary rocks varies (Domeier et al., 2012). There are several ways to correct this including: 1) the DRM tensor approach of Jackson et al. (1991); 2) the high field anisotropy of isothermal remanent magnetization (hf-AIR) approach of Bilardello and Kodama (2009); 3) the Elongation/Inclination (E/I) method of Tauxe and Kent (1984) using the statistical field model TK03.GAD; 4) the E/I method of Tauxe and Kent (2004) using samples from a single horizon and assuming a Fisher (1953) distribution; and 5) a blanket correction based on assumed values for flattening factor f using an inclination correction equation by King (1955): tan(Io) = f tan(If) (9) where Io is the observed inclination, If is the field inclination and f is an empirically derived ‘flattening factor’ (Tauxe et al., 2008). According to the compilation of Bilardello and Kodama (2010), f-values from magnetite dominated sedimentary rocks range from 0.54 to 0.79, with a mean of 0.65, whereas hematite-dominated sedimentary rocks have yielded f values from 0.4 to 0.83, with a mean of 0.59. The basic requirement in making paleomagnetic reconstructions is to verify that the observed magnetization direction is original, recording a primary ambient field direction during emplacement of the rock formation. In this study a baked contact test, and a fold test were applied. In the case of remanent magnetization of thermal origin it can be tested by the baked contact test (Everitt and Clegg, 1962). The concept of the test is that an igneous body, e.g. a dyke, heats (or bakes) the contact zone of the host rock to near or above the Curie temperature of the magnetic minerals. Such minerals gain the direction of the Earth’s magnetic field at the cooling time. This direction is likely to be similar to the remanence direction in the dyke itself as both cool simultaneously. As temperature decreases with increasing distance from the dyke, the remanence directions of the baked zone gradually change. A positive baked contact test therefore requires that the dyke and its baked host rock carry similar stable remanence directions, and that the unbaked host rock carries a significantly different stable direction 24 (e.g. Irving, 1964; Buchan, 2013). The baked contact test is strengthened if the host rock contains a hybrid zone, where both host rock and dyke remanent components occur together in addition to the two above mentioned remanence zones (Buchan, 2013). In the case of sedimentary rocks, the fold test (e.g. McFadden, 1990), establishes that the age of remanence is pre-, syn-, or post-fold. In the fold test, if a ChRM was acquired prior to folding, directions of ChRM from different limbs of a fold are dispersed, but they converge when the structural correction is made. If the structural correction results in more dispersed ChRM direction, the ChRM direction was acquired after folding took place. Unless it can be demonstrated that folding occurred during deposition of the rock unit under study, it does not establish the primary nature of remanent magnetization. This can be established if the maximum clustering of ChRM directions occurs at less than 100% unfolding. 2. Aims of this study The main objective of this work was to obtain new Precambrian paleomagnetic data for Baltica, to refine the Precambrian APWP of Baltica, and to test the assemblies of the Precambrian supercontinents Nuna and Rodinia. The objective with studying the Keuruu diabase dykes was to establish the position of Baltica related to Laurentia at the onset (1.87 Ga) of the NENA assembly. With the Åland intrusives and Satakunta sandstone formation the objective was to test the proposed 1.8-1.2 Ga NENA connection within the supercontinent Nuna. In the case of the Hailuoto sedimentary formation, the objective was to test the Late Neoproterozoic paleogeographic positions of Baltica to better understand the environmental conditions during that time. With a new Late Neoproterozoic pole a further aim was to explore if the large sways in the Ediacaran APWP can be explained by high plate velocities alone. In order to achieve firm conclusions an additional aim of this study was to obtain precise U-Pb ages from Åland and Keuruu diabase dykes, and to obtain a new relative paleomagnetic age of deposition from the paleomagnetic results of Satakunta sandstone. 3. Materials and methods 3.1. Sampling and sample preparation Field sampling for this work was carried out on the Satakunta sandstone formation, Åland diabase and quartz porphyry dykes, and the Keuruu diabase dyke swarm. The samples were taken with a portable rock drill or as oriented block samples. The samples were oriented with a magnetic and/or 25 sun compass and the local declination was corrected. Multiple specimens were prepared from each sample; block samples were drilled in the laboratory and all the drill cores were sawn into standard cylindrical specimens (2.56 cm diameter (D), ~2.3 cm length (h), with h/D ≈ 0.9). Further samples were obtained from an inclined 272 m deep, fully oriented sedimentary drill core from the Hailuoto sedimentary formation. Samples with a maximum length of about 6 cm were first cut from the drill core and from these 7 - 8cm3 cubic specimens parallel to the core axis, were prepared. 3.2. Laboratory measurements. Measurements were carried out at the Solid Earth Geophysics Laboratory of the University of Helsinki (UH), Finland (Pesonen, 2006) and at the Paleomagnetic laboratory of the Geological Survey of Finland (GTK), Espoo (Pesonen, 1989). 3.2.1. Petrophysical measurements Magnetic susceptibility, intensity of natural remanent magnetization (NRM), and rock density were measured for each specimen using the Risto-5 petrophysics assembly of the Solid Earth Geophysics laboratory at the University of Helsinki. The magnetic susceptibility was measured at room temperature with the Risto-5 kappabridge at a frequency of 1025 Hz and a field of 48 A/m and the NRM was measured with the Risto-5 fluxgate magnetometer. From the NRM and magnetic susceptibility the Königsberger (Q) ratio was calculated. The Q ratio is the ratio of remanent magnetization to the induced magnetization in Earth’s magnetic field using the formula: Q = μ0NRM/χB (10) Where μ0 is the magnetic permeability in a vacuum (4πx10-7H/m), NRM is the natural remanent magnetization (A/m), χ is magnetic susceptibility (SI), and B is the geomagnetic reference field value (for Finland a value of 50 μT is used). If Q>1, the remanent magnetization is stronger than the induced magnetization and the specimen is able to maintain a stable remanence. Specimens with high Q values (>10) must be treated with caution, since it may indicate either fields other than the Earth’s internal magnetic field (e.g. lightning induced fields), or unstable magnetic carriers. 26 3.2.2. Paleomagnetic and rock magnetic measurements Stepwise alternating field (AF) demagnetizations were done using a Schonstedt SD-1 demagnetizer up to 100 mT (GTK) or a three-axis demagnetizer with maximum field up to 160 mT, coupled with a 2G–DC SQUID magnetometer (UH) or a 2G-RF SQUID magnetometer (GTK). Stepwise thermal demagnetizations were performed using a GTK built or Schonstedt TSD-1 furnace (GTK), an MMTD1 thermal demagnetizer (UH), or an ASC Model TD48-SC controlled atmosphere (Ar) furnace (UH). Remanent magnetizations were measured with a 2G–DC (or 2G–RF) cryogenic magnetometer or a GTK-built spinner magnetometer (Pesonen et al., 1989). Magnetic carriers were studied by thermomagnetic analysis of selected specimens using an Agico CS3-KLY-3S Kappabridge system (UH), which measures the bulk susceptibility (k) of the samples during heating from -192° to 700°C and cooling back to room temperature (in Argon gas). Ferromagnetic minerals (senso lato) are identified by changes in magnetic susceptibility with increasing temperature. Vector components were visually identified using stereographic and orthogonal projections (Zijderveld, 1967) and the directions were calculated by a least squares method (Leino, 1991). Mean remanence directions for the different components were calculated according to Fisher (1953), giving a unit weight to each sample (each specimen has a unit weight within a sample) to compute site mean directions and corresponding paleomagnetic poles (Irving, 1964). The paleogeographical reconstructions were done with GMAP (Torsvik and Smethurst 1999), and GPlates programs. Inclination corrections were made for paleomagnetic results obtained from sedimentary rocks. In Article III we used Eq. 9 to correct inclination shallowing of the Hailuoto sedimentary rocks. In Article I, high field anisotropy of isothermal remanent magnetization (hf-AIR) measurements were carried out to correct inclination shallowing of the Satakunta sandstone. The hf-AIR measurement technique of Bilardello and Kodama (2009) was followed; 5T isothermal remanent magnetization (IRM) was applied in 9 orientations (Girdler, 1961) of oriented samples, using a MMPM 10 pulse magnetizer. Samples were then thermally demagnetized at 125°C in a MMTD1 thermal demagnetizer, to demagnetize goethite. The samples were then AF demagnetized at 100 mT, to demagnetize magnetite. The remaining hematite component was measured in a 2G SQUID magnetometer. The best-fit anisotropy tensor was determined using the least square fitting, and the eigenvalues were calculated from the tensor. The inclination correction was applied by using the hematite correction equation of Tan and Kodama (2003): 27 Tan Ic = tan Im (2a+1)kmax-1 / (2a+1)kmin-1 (11) where Ic and Im are the corrected and measured inclinations, respectively, kmax and kmin are the normalized maximum and minimum principal axes, respectively of the fabric, and a is the individual particle anisotropy. The latter was not measured, but a value of 1.4 was used, which is considered to be reasonable for hematite (Tan et al. 2007; Kodama, 2012). In addition to the inclination correction, a tilt correction was carried out on the Satakunta sandstone samples (Article I). Baked contact tests were carried out on Åland (Article II) and Keuruu (Article IV) dykes of both polarities. 4. Review of articles 4.1. Article I Klein, R., Pesonen, L.J., Salminen, J., Mertanen, S., 2014. Paleomagnetism of Mesoproterozoic Satakunta sandstone, Western Finland. Precambrian Research 244, 156-169. In this article a paleomagnetic study of the Mesoproterozoic Satakunta sandstone formation is presented. The aim of the study is to identify the ChRM of the Satakunta sandstone in order to estimate the relative paleomagnetic age of deposition, and to use the new paleomagnetic pole for Baltica to check the validity of NENA at the estimated age of the sandstone. The Satakunta sandstone formation is a fluvial formation situated in the Satakunta region in Western Finland (61.25°N; 22°E). The formation consists of unmetamorphosed sandstone that was deposited in a deltaic environment and has been preserved in a SE-NW trending graben within the Paleoproterozoic Svecofennian Domain. It is part of a much wider sandstone basin extending across the Baltic Sea to the Gävle valley and Nordingrå area in Sweden (Kohonen et al., 1993; Pokki et al. 2013). Two components of natural remanent magnetization (NRM) were isolated in the sandstone with alternating field (AF) and thermal demagnetization treatments. The first is a high coercivity/unblocking temperature component which, after tilt and inclination shallowing corrections, yields a dual polarity remanent magnetization of D = 25.2°, I = 3.9° with α95 = 9.1° (10 sites), corresponding to a paleomagnetic pole of Plat. = 27.8° N, Plon = 173.2° E, with A95 = 6.5°. Positive reversal and tilt tests, an inverse baked contact test, as well as a stratigraphic order of the site mean poles, indicates a primary remanence. The second component is a lower coercivity/unblocking 28 temperature component with a remanent magnetization direction D = 34.0°, I = - 40.7° with α95 = 8.1° (13 sites) similar to the 1.26 Ga Postjotnian Satakunta diabase intrusions, which are widespread in the area. This indicates that the component reported as the Satakunta sandstone component in an earlier study by Neuvonen (1973), is an overprint (baked) component. The relative age of the sandstone is estimated at ca. 1600 based on the proximity of the Satakunta sandstone pole to other well defined poles of 1452-1630 Ma from Baltica. Comparing APWPs of Baltica and Laurentia during 1.77-1.27 Ga gives strong support to the NENA configuration during the Mesoproterozoic. 4.2. Article II Salminen, J.M., Klein, R., Mertanen, S., Pesonen, L.J., Frödjö, S., Mänttäri, I., Eklund, O. 2015. Palaeomagnetism and U–Pb geochronology of c. 1570 Ma intrusives from Åland archipelago, SW Finland –implications for Nuna. In Li, Z. X., Evans, D. A. D. and Murphy, J. B. (eds) Supercontinent Cycles Through Earth History. Geological Society, London, Special Publications 424, doi: 10.1144/SP424.3 In this article, new paleomagnetic and isotope age data of Early Mesoproterozoic (i.e. Subjotnian) intrusives from the Åland archipelago, SW Finland is reported. The motivation for this study was to obtain Early Mesoproterozoic key-paleomagnetic data for Baltica, to obtain a preliminary pole for the rapakivi granite in Åland, to refine the Early Mesoproterozoic APWP of Baltica, to obtain an additional precise U–Pb age from a reversely magnetized dyke in Åland (Korsö) and finally to test the proposed NENA connection within supercontinent Nuna. The Åland archipelago is situated at the entrance to the Gulf of Bothnia in the Baltic Sea. In Åland, the Svecofennian crust consists of Paleoproterozoic granitoids, paragneisses, and felsic and intermediate metavolcanic rocks. These are cut by Subjotnian rapakivi granite intrusions, mafic dykes, as well as quartz porphyritic dykes generally trending SSW–NNE. Several Subjotnian units in Åland have been dated before. The rapakivi granites yield U–Pb (zircon) ages of 1568±10 Ma and 1579±13 Ma (Suominen 1991), correlating with ages from Vehmaa rapakivi granite in mainland Finland, NE from Åland. Previous U–Pb (zircon) ages for diabase dykes in Åland vary between 1540±12 Ma and 1577±12 Ma. Previous U–Pb (zircon) ages for quartz porphyry dykes range between 1576±13 Ma, 1576±13 Ma and 1571±20 Ma (Suominen 1991). 29 The paleomagnetic results reveal dual-polarity magnetizations with a pronounced reversal asymmetry. The asymmetry is explained by an unremoved secondary component, which is affecting the N-polarity dykes more. The primary nature of magnetization in dykes for both normal (N) and reversed (R) groups is verified by positive baked contact tests. A dyke showing reversed polarity from Korsö is dated 1575.9±3.0 Ma (U–Pb, zircon) in this study. This and previous U–Pb data tighten the magmatic activity in Åland to 1580–1570 Ma. The new paleomagnetic data is combined with those from earlier studies to provide a new key paleomagnetic pole for Baltica. The normal polarity ChRM (D = 12.4°; I = 10.5°; α95 = 6.9°; k = 12.9; N = 31) yields a paleomagnetic pole of Plat = 34.6°N and Plon = 185.5°E with A95 = 6.5°, and the reversed polarity ChRM (D = 186.2°; I = 24.9°; α95 = 3.5°; k = 31.1; N = 56) yields a paleomagnetic pole of Plat = 16.2°N and Plon = 194.8°E with A95 = 5.0°. The data positions Baltica on equatorial latitudes, supporting the NENA (North Europe– North America) connection between Baltica and Laurentia at 1.59–1.58 Ga. Furthermore, it is demonstrated that NENA was valid also at 1.75, 1.46, and 1.26 Ga, forming the core of Mesoproterozoic Nuna supercontinent. 4.3. Article III Klein, R., Salminen, J., Mertanen, S., 2015. Baltica during the Ediacaran and Cambrian: A paleomagnetic study of Hailuoto sediments in Finland. Precambrian Research 267, 94-105. This article presents a new Late Neoproterozoic paleomagnetic pole for Baltica from a 272 m deep, fully oriented sedimentary drill core in Hailuoto, Western Finland. The aim of the study was to obtain a new paleomagnetic pole for Baltica, to test the Late Neoproterozoic paleogeographic positions of Baltica, and to better understand the environmental conditions during that time. With a new Late Neoproterozoic pole, a further aim is to explore if the large sways in the Ediacaran APWP can be explained by high plate velocities alone. Hailuoto Island is situated off the coast of the city of Oulu, Northern Finland (65°N, 25°E). The island arose from the Bothnian Bay during the Quaternary post-glacial land uplift (Tynni and Donner, 1980). The sedimentary bedrock of Hailuoto is covered by a Quaternary layer of loose sand of up to ca. 70 m thick. The bedrock consists of interbedded conglomerate, sandstone and mudstone up to a maximum depth of ca. 560 m. The dominant rock type of the Hailuoto formation is a medium-grained, pale pink or light greenish subarkose (Veltheim, 1969; Tynni and Donner, 1980). The depositional age of the Hailuoto sediments is poorly constrained at 570-600 Ma based on fossil records (Tynni and Donner, 1980). 30 Three components of magnetization were isolated from the Hailuoto sedimentary rocks with thermal and alternating field (AF) demagnetization treatments. The ChRM component is a high coercivity/unblocking temperature dual polarity component that passes a reversal test. The combined observed ChRM component of the Hailuoto sediments (D = 334.2°; I = 44.4°; α95 = 7.2°; k = 16.5) yields a paleomagnetic pole of Plat = 48.7°N and Plon = 241.1°E with A95 = 8.1°. The inclination corrected direction (using f = 0.6 as a correction factor) of D = 334.4°; I = 57.7°; α95 = 5.8°; k = 25.2 yields a paleomagnetic pole of Plat = 60.5°N and Plon = 247.9°E with A95 = 7.6°. As it is a dualpolarity ChRM pole carried by both magnetite and hematite, with no resemblance to younger poles, we interpret it as a primary component. A paleolatitude for Hailuoto of 38.3° was calculated from the ChRM. Two secondary components were identified. The first is a low coercivity/blocking temperature component with a remanent magnetization of D = 239.0°; I = 67.3°; α95 = 8.7° (N = 13 samples), which we interpret as drilling-induced remanent magnetization (DIRM). The other secondary component has a remanent magnetization of D = 49.4°; I = 34.9°; α95 = 8.6° (N = 5 samples) and is commonly seen in Fennoscandian formations. The ChRM Hailuoto pole adds to the scattered Ediacaran paleomagnetic data of Baltica and indicate large distances between other late Neoproterozoic and early Cambrian paleomagnetic poles, which can be explained by high plate velocity. However, considering an older age for Hailuoto sediments, the TPW and a non-actualistic geodynamo hypotheses cannot be ruled out. Reconstructions of Baltica and Laurentia between 616 and 550 Ma is shown, which move Baltica from high latitudes (615 Ma), over the polar region, to low latitudes (550 Ma), and Laurentia from low latitudes (615 Ma) to a polar position (570 Ma) and back to an equatorial position (550 Ma). A low to mid latitude position of Baltica determined by the Hailuoto paleomagnetic pole is in agreement with the earlier studies of Hailuoto sediments which indicate a lack of glaciogenic sediments and a warm deposition environment. 4.4. Article IV Klein, R., Pesonen, L.J., Mänttäri, I., (submitted). A new late Paleoproterozoic pole for Baltica: A paleomagnetic and geochronological study of the Keuruu diabase dykes, Central Finland. Precambrian Research. In this article a new paleomagnetic pole and isotope age for the late Paleoproterozoic (Svecofennian) diabase dykes from Keuruu, Central Finland is presented. The motivation for this study is to obtain late Paleoproterozoic key paleomagnetic data for Fennoscandia with precise U-Pb ages, to refine the 31 late Paleoproterozoic APWP of Baltica, and to present a paleogeographic reconstruction for the late Paleoproterozoic that shows the onset of Nuna. The Keuruu diabase dyke swarm is situated within the Central Finland Granitoid Complex (CFGC), which was formed 1.89-1.86 Ga ago during the peak phase of the Svecofennian orogeny. Granitoids are predominant rocks in the CFGC together with granodiorites, diorites and schists, as well as numerous gabbroic bodies. These rocks are cut by the Keuruu diabase dyke swarm. An earlier preliminary study of the dykes yielded a U-Pb (zircon) age of 1876±9 Ma, however the upper intercept isochron age is based on only two zircon fractions. The paleomagnetic results reveal a dual-polarity ChRM with a reversal asymmetry, which is explained by an unremoved secondary component contaminating both N and R vectors. The normal polarity ChRM (D = 346.1°; I = 37.0°; α95 = 4.8°; k = 57.2; N = 17) yields a paleomagnetic pole of Plat = 47.9°N and Plon = 224.2°E with A95 = 4.0°, and the reversed polarity ChRM (D = 144.6.1°; I = -23.3°; α95 = 13.4°; k = 33.5; N = 5) yields a virtual geomagnetic pole (VGP) of Plat = 34.0°N and Plon = 247.9°E with A95 = 13.0°. The primary nature of magnetization in reversed polarity dykes is supported by a baked contact test. As the normal polarity dykes and the unbaked host rocks show similar paleomagnetic directions (similar ages), the baked contact test is illustrated by means of remanent magnetization intensity decay behavior. A dyke showing reversed polarity is dated 1870±9 Ma by U-Pb. The youngest zircons from another dyke of normal polarity show a Pb-Pb age of 1868±7 Ma. A combined N and R pole of Plat = 45.4°N and Plon = 230.9°E with A95 = 5.5° positions Fennoscandia at low latitudes (19°), and aligns with Laurentia in a way that would proceed into the subsequent long lasting 1.8-1.2 Ga NENA configuration. 4.5. Author’s contribution Article I: R. Klein was the leading author. He collected and prepared 10% of the samples and measured 40% of the samples; the remaining samples had been collected, prepared and measured by the second author, L.J. Pesonen with the help of Dirk Kettrup. Klein was responsible for the data analysis, including the tilt test and inclination correction. Klein wrote most of the manuscript and handled the review and proof stage. Article II: R. Klein was the second author. He participated in the collection and preparation of the samples in 2013, together with J. Salminen and S. Mertanen, as well as the paleomagnetic and rock measurement of the samples. Klein was responsible for analyzing samples that had been collected by L.J. Pesonen prior to the 2013 collection trip. Salminen was the leading author of the article, writing 32 most of the manuscript and handling the review and proof stage. Klein interpreted the paleomagnetic results of the Rapakivi granites, participated in image preparation and participated in the proof reading. Article III: R. Klein was the leading author. He conducted most of the measurements and was responsible for data analysis and interpretation. Klein did most of the writing, with significant input by the co-authors. He was responsible for handling the manuscript during the review and proof stage. Article IV: R. Klein was the leading author. Sample collection and preparation, and paleomagnetic measurements had been carried out by L.J Pesonen with the help of R. Puranen and S. Raiskila. Paleomagnetic data analysis and interpretation were carried out by Klein. Geochronological sample preparation and measurements were carried out by Klein and I. Mänttäri, and geochronological data analysis were done by Mänttäri. Klein wrote most of the manuscript. 5. Results and discussion 5.1. Paleomagnetic results obtained in this work 5.1.1. Diabase dykes A dual polarity ChRM was obtained from Keuruu diabase dykes with a combined ChRM of D = 323.8°, I = 37.5°, k = 31.0, α95 = 5.8°. However the normal (D = 346.1°, I = 37.0°, k = 57.2, α95 = 4.8°) and reversed (D = 144.6°, I = -23.3°, k = 33.5, α95 = 13.4°) observed ChRM directions do not pass the McFadden and McElhinny (1990) reversal test. The main possible cause for the asymmetry between the N and R polarity Keuruu diabase dykes is interpreted to be an unremoved secondary component. Furthermore, as the reversed direction is carried by only 5 dykes (compared to 17 dykes of N polarity), the effect of unaveraged secular variation may therefore also contribute to the asymmetry between normal and reversed distributions. A reversed polarity dyke yielded a U-Pb zircon age of 1870±9 Ma and a normal polarity dyke yielded a Pb-Pb age of 1868±7 Ma. The primary magnetization of the reversed component is supported by a positive baked contact test. As the granodiorite host rock is only slightly older (1.89 Ga) than the diabase dykes, and shows a similar normal polarity remanence direction as the normal polarity dykes, it is not possible to distinguish between baked and unbaked host rock. However, baked and unbaked host rocks can be distinguished based on the shapes of the remanent magnetization intensity decay curves (Article IV), which support the primary nature of the N dyke direction as well. 33 Paleomagnetic results from Subjotnian intrusives of the Åland archipelago also show a dual polarity ChRM with a combined ChRM of D = 14.9°, I = -2.6°, k = 14.0, α95 = 4.0°. The normal (D = 18.4°, I = 19.9°, k = 13.0, α95 = 6.9°) and reversed D = 192.5°, I = 17.7°, k = 31.0, α95 = 3.5°) ChRM also show a pronounced reversal asymmetry occurring in both quartz porphyry and diabase dykes. The asymmetry is also explained by an unremoved secondary component. The main magmatic activity is defined by U-Pb (zircon) data as 1580-1570 Ma, which is also regarded as the age of remanence, supported by a positive baked contact test for both normal and reversed polarity dykes. Non-antiparallel polarities One of the reliability criteria for a paleomagnetic pole is the presence of reversals (Van der Voo, 1990), i.e. normal and reversed poles that are antiparallel in 95% confidence level. Both normal and reversed directions of both Satakunta sandstone and Hailuoto sediments are antiparallel, and therefore pass the reversal test. Keuruu and Åland poles, however, show reversal asymmetry, i.e. their normal and reversed directions are non-antiparallel. In both cases, it is interpreted to be a result of an unremoved secondary component. This is apparent from the demagnetization data of several specimens. It was further tested through vector addition, adding the secondary components to the expected original N and R ChRM’s of Keuruu and Åland dykes. The respective combined Fisher means of the observed N and R ChRM’s of Keuruu and Åland dykes (Table 2) were used as the expected original ChRM’s (Donadini, 2007). In the case of Keuruu dykes, an R to N intensity ratio of 2:3 based on the mean R and N susceptibilities (Table 2) was used for the expected original NRM values, assuming that susceptibility would reflect the original NRM intensity ratio of the dykes prior to the partial secondary overprint. Since the observed secondary direction is likely to be contaminated by PEF, we used the direction (D = 47°; I = 64°; Pesonen et al., 2012a) obtained by great circle analysis. A secondary component intensity of 23% of the primary intensity resulted in an N direction of D = 341°; I = 39°, and an R direction of D = 147°; I = -20°, which is within the 95% confidence of observed N and R directions (Table 2), with a similar declination and inclination asymmetry. The same procedure was followed for the Åland dykes, using an N to R intensiy ratio of 1:6, also based on susceptibility values. The Fisher mean for the Åland secondary component (D = 19°; I = 57°) was used, with an intensity of 32% of the primary intensity. This resulted in an N direction of D = 9°; I = 9°, and an R direction of D = 184°; I = 24°, which is within the 95% confidence of the observed N and R directions (Table 2). 34 Table 2 Summary of ChRM results obtained from Articles I-IV. Age (Ma) d.m. B/N/n N 1868±7 g(z) 17*/53/98 348.1 40.0 4.8 57 47.9 224.2 4.0 R 1870±9 g(z) 5*/18/46 146.7 -24.9 13.4 34 34.0 247.9 13.0 C 1870 21*/71/144 342.8 37.5 5.8 31 45.4 230.9 5.5 N 1569±3 g(z) 31*/150/272 18.4 19.9 6.9 13 34.6 185.5 6.5 R 1576±3 g(z) 56*/216/331 192.5 17.7 3.5 31 16.2 194.8 5.0 C 15801570 87*/366/603 14.9 -2.6 4.0 14 23.7 191.4 2.8 28.8 17.1 10.2 26 31.0 174.0 8.3 28.8 9.2 9.9 28 27.0 175.1 8.1 28.6 11.1 12.0 20 28.0 175.0 8.0 217.3 0.3 44.5 9 20.2 167.5 24.6 218.5 -17.0 19.2 42 28.3 163.4 14.9 Inc 218.8 -22.4 23.0 31 31.0 162.0 17.0 Obs 29.8 12.7 12.0 17 28.5 173.5 8.7 30.2 9.5 8.0 37 26.8 173.5 7,4 30.2 11.5 9.1 29 27.8 173.2 6.5 326.4 39.8 14.5 19 43.0 252.0 15.4 326.0 54.0 12.0 26 53.9 259.2 14.8 160.6 -43.8 8.5 17 49.5 235.1 9.7 161.0 -57.4 6.7 26 61.6 240.4 9 336.2 44.0 7.2 17 48.7 241.1 8.1 336.1 57.6 5.8 25 60.5 247.9 7.6 Rock unit Pol Keuruu diabase dykes Åland diabase and quartz porphyry dykes Dr (°) Obs Tilt N 9*/30/72 Inc Obs Satakunta sandstone Tilt Tilt R 16301450 m,a C 3*/7/16 10*/37/88 Inc Obs Inc Hailuoto sedimentary drill core Obs Inc Obs Inc N R C 7*/10 600570 F 19*/21 26*/31 Ir (°) α95 (°) k Plat (°N) Plon (°E) A95 (°) Obs, Tilt, and Inc indicate observed, tilt-corrected and inclination corrected results from sedimentary formations. Pol = polarity. d.m. shows dating method: g(z) = U-Pb (zircon), m = APWP, a = geology (cross-cutting), and f = fossils. B/N/n = sites/samples/specimens (* marks level of statistics). Dr and Ir are declination and inclination of the remanent magnetization component calculated for a common reference locality at Kajaani (64.1°N, 27.7°E). α95 = radius of the 95% confidence circle of the mean direction, k = precision parameter (Fisher, 1953). Plat and Plon = paleolatitude, paleolongitude of the pole. A95 = 95% confidence circle of the paleopole. 35 5.1.2. Sedimentary rocks Samples from the Satakunta sandstone formation, SW Finland) provided a stable ChRM component of D = 27.8°, I = 3.9°, k = 28.9, a95 = 9.1° after tilt- and inclination- corrections. Results were obtained from 10 outcrops of which 7 outcrops yielded normal polarity directions, 2 outcrops yielded both normal and reversed polarity directions, and 1 outcrop yielded reversed polarity directions only. The normal and reversed directions pass the McFadden and McElhinny (1990) reversal test. In addition, the results passes a fold test as well as an inverse baked contact test. The sandstone is partially baked by 1264±12 Ma (Suominen et al., 1991) olivine diabase dykes and sills. An earlier paleomagnetic study on Satakunta sandstone (Neuvonen, 1973) was unable to isolate the sandstone component, and interpreted the secondary diabase overprint as the ChRM of the sandstone. As a result the paleomagnetic age of the Satakunta formation was estimated at 1400-1300 Ma. The paleomagnetic age based on the new ChRM is estimated at 1630-1450 by comparing the new Satakunta pole to reliable, dated poles (Fig. 3). A dual polarity ChRM was obtained from a 272 m deep, fully oriented sedimentary drill core in Hailuoto, Western Finland. The depositional age of the Hailuoto sediments is poorly constrained at 600-570 Ma based on fossil records. The normal and reversed polarity directions pass the McFadden and McElhinny (1990) reversal test. The combined observed ChRM component is D = 334.2°; I = 44.4°; k = 16.5; α95 = 7.2° and the inclination corrected direction (f = 0.6) is D = 334.4°; I = 57.7°; k = 25.2; α95 = 5.8°. There was no possibility for field tests. However, as it is a dual-polarity ChRM carried by both magnetite and hematite, with no resemblance to younger events, we interpret it as a primary component. 5.1.3. Secondary component Both Satakunta sandstone and Hailuoto sediments show a secondary component with intermediate downward inclinations and northeasterly declinations. In the case of Satakunta sandstone it is D = 27.2° I = 33.7° α95 = 13.0° and is observed in addition to the Postjotnian component mentioned above (section 4.1.). In the case of the Hailuoto sedimentary formation the secondary component is D = 49.4° I = 34.9° α95 = 8.6°. Secondary components are also observed in Keuruu and Åland dykes, however it is difficult to isolate the present Earth field component (PEF) and secondary component, as they co-exist in a similar coercivity range of ≤ 20 mT or a blocking temperature range of ≤ 300°C. The secondary component, however, is also carried at coercivities of >200 mT and temperatures of > 500°C in some of the samples, where they co-exist with, and contaminate the ChRM. The Fisher 36 mean of the secondary component at low coercivity/blocking temperature and at high coercivity/blocking for both Keuruu and Åland cases are shown in Table 3. A great circle analysis on Keuruu dykes (Pesonen et al., 2012a) isolated a secondary component of D ≈ 47°, I ≈ 64°. Raiskila et al. (2011) obtained a similar direction (D=42°, I = 64°) from the 1.14 Ga Keurusselkä impact structure ca. 20 km South of Keuruu, and interpreted it as an impact component. This may be a possible source of the secondary component in Keuruu dykes, however there is no significant proof that this is an impact component. Similarly, the ca. 0.55-0.45 Ga Lumparn impact (Tynni, 1982) cannot be ruled out as a possible source of the secondary component in the Åland case. An intermediate to steep NE component is widely observed in Baltica in ealier paleomagnetic studies (e.g. Mertanen et al., 1989; Preeden et al., 2009; Salminen et al., 2014). The paleomagnetic pole derived from this component corresponds with Permian to Triassic (ca. 300-200 Ma) poles of Europe (Torsvik et al., 2012). Preeden et al. (2009) interpret the cause of this component to be the migration of orogenic fluids related to the Hercynian orogeny at the southern margin of Baltica and/or the Uralian orogeny at the eastern margin. Table 3 Fisher means of secondary components obtained in this work B/N/n D (°) I (°) k Plat (°N) Plon (°E) A95 (°) <20mT <300°C 19*/47/71 24.8 68.4 8.0 18.5 75.7 131.1 11.5 >30mT >500°C 18*/42/57 9.1 51.6 8.7 16.6 61.9 188.1 8.5 <20mT <300°C 24*/52/52 38.8 68.7 6.3 22.9 67.6 110.2 12.0 >30mT >500°C 10*/20/20 19.0 57.0 8.5 33.6 65.1 164.7 19.7 Component B 8*/29/44 27.7 33.7 13.0 19.2 44.3 163.7 11.4 Baked component 13*/50/112 34.0 -40.7 8.1 27.5 -1.1 350.6 12.3 5*/7 49.4 34.9 8.6 80.7 34.1 144.7 6.9 Rock unit α95 (°) Keuruu diabase dykes Åland diabase and quartz porphyry dykes Satakunta sandstone Hailuoto sedimentary drill core B/N/n = sites/samples/specimens (* marks level of statistics). Dr and Ir are declination and inclination of the remanent magnetization component. α95 = radius of the 95% confidence circle of the mean direction, k = precision parameter (Fisher, 1953). Plat and Plon = paleolatitude, paleolongitude of the pole. A95 = 95% confidence circle of the paleopole. 37 5.2.Aparent polar wander paths for Baltica (1.87-0.57 Ga) The ChRM poles of Keuruu diabase dykes, Åland intrusives, and Satakunta sandstone are plotted with selected Paleo- and Mesoproterozoic poles (Fig. 3). The poles used are classified into highly reliable A grade poles (well determined age and positive field stability test) and seemingly reliable B grade poles (well determined age or positive field test). Questionable to unreliable C and D grade poles (neither well determined age nor positive field test) are not included here. In Fig. 3 the late Paleoproterozoic to Mesoproterozoic APWP of Baltica starts at an overlapping cluster of poles consisting of the Tsuomasavarri (1931 Ma), mean 1880 Ma Svecofennian, Keuruu dykes (1870 Ma), mean 1800 Ma Svecofennian, Hoting gabbro (1786 Ma), Shoksha sandstone (1770 Ma), and Ropruchey sill (1751 Ma) poles; all positioned at intermediate latitudes. The APWP then moves down to the subjotnian (ca. 1.65-1.45 Ga), Mashak (1376 Ma), and postjotnian (1.26 Ga) poles at low to equatorial latitudes, anchored by Keuruu dykes (1870 Ma), Åland intrusives (1578 Ma), Satakunta dykes (1578 Ma), Lake Ladoga (1452 Ma), and 1258 Ma mean postjotnian key poles. Fig. 3. Late Paleoproterozoic to late Mesoproterozoic APWP for Baltica. A grade poles are marked in red, B grade poles are marked in orange, and C grade poles marked in green. The poles of this work are shown with arrows. 38 The late Mesoproterozoic and Neoproterozoic is an enigmatic period for Baltica and contains few reliable paleomagnetic poles and has large age gaps between them, making a continuous APWP between the Precambrian and Paleozoic impossible. In this dissertation, an APWP of only the transition from Precambrian to Ordovician (615 – 475 Ma) is discussed. The ChRM pole of Hailuoto is plotted with selected A and B grade Neoproterozoic – Cambrian poles (Fig. 4). Although the exact deposition age of the Hailuoto sediments is unkown, for the purpose of this discussion the age range proposed by Tynni and Donner (1980) of 600 - 570 Ma is used, which places the age of the Hailuoto pole between the Egersund (616 Ma) and the Verkhotina (Popov et al. 2005) and Zolotitca (Iglesia Llanos et al. 2005) poles (ca. 550 Ma). This forms a loop in the APWP that starts at the Egersund pole (616 Ma), jumps to the Hailuoto pole (ca. 600 - 570 Ma), and follows the poles of Krivaya Luka, Kurgashlya and Bakeevo formations (570 – 560 Ma) (Lubnina et al. 2014), continues to the 550 Ma Verkhotina (Popov et al. 2005) Zolotitca (Iglesia Llanos et al. 2005) and Winter Coast (Popov et al., 2002) poles, and ends at the 478 Ma St. Petersburg limestone pole (Smethurst et al. 1998) close to the Egersund pole (illustrated with black dotted line in Fig. 4). Fig. 4. Late Neoproterozoic to Ordovician APWP for Baltica (left) and Laurentia (right). Neoproterozoic poles marked in yellow, Cambrian poles marked in green, and Ordovician poles marked in orange. The angle of the Baltica APWP segment between the Egersund dyke pole (616 Ma) and the Hailuoto pole is 98° for the uncorrected pole and 86° for the inclination corrected pole (f=0.6), which infers a plate motion of between ca. 24 and 21 cm/yr, respectively, considering the lower Hailuoto age limit 39 of 570 Ma. This is consistent with the upper speed limit for plate tectonics (between 20 and 25 cm/yr) suggested by Meert et al. (1993) and Gurnis and Torsvik (1994). The APWP of Baltica between the 550 Ma mean pole and the St Peterburg (478 Ma) (Smethurst et al. 1998) pole (Fig. 4) yields an 87° angle which results in a velocity of ca. 16 cm/yr when considering only A and B grade poles. Although the the large sways in the APWP of Baltica can be explained by high plate velocity alone, considering the lower age 570 Ma for Hailuoto sediments, when considering an older age for Hailuoto, high plate velocity becomes unrealistically high (ca. 65 cm/yr at 600 Ma), and other explanations, such as TPW (Mitchell et al., 2011) and non-actualistic geodynamo (Abrajevitch and Van der Voo, 2010) hypotheses should be considered. True polar wander (TPW) (Evans, 2003; Mitchell et al., 2011) and a non-actualistic geodynamo (Abrajevich and Van der Voo, 2010) are two hypotheses given as possible mechanisms for the rapid continental motion during the Ediacaran. True polar wander is the rotation of the Earth with respect to its spin axis causing the geographic locations of the North and South poles to change or “wander”. Such a shift in poles results in a systematic change in the APWP’s of all cratons. In the Laurentia APWP (Fig 4.), the segment between the 613 Ma Long range pole (Murthy et al., 1992) and the 585 Ma Grenville B+E pole (Halls et al., 2015) form an 88° angle. This is similar to the segment between the 616 Ma Egersund pole (Walderhaug et al., 2007; Bingen et al., 1998) and the Hailuoto pole in the Baltica APWP, and therefore supports the TPW hypothesis. However, the Laurentia APWP is inconclusive, as there are other high quality poles for ca. 585 Ma at different positions that would result in smaller APWP angles with the Long Range pole. Furthermore, the angles between poles younger than 585 Ma differ between Baltica and Laurentia, and therefore negates TPW as the main cause of large APWP segments after 585 Ma. However, in the case of Laurentia, the large angle of 66q of the APWP segment between Catoctin Basalts (572 Ma) and SeptIles intrusions (564 Ma), which equates to 105 cm/yr, cannot be explained by high plate velocity alone. The non-actualistic geodynamo hypothesis by Abrajevitch and Van der Voo (2010), which postulates an alternation of the geomagnetic dipole axis between a co-axial and an equatorial alignment, partly relies on problematic poles for both Laurentia and Baltica. The Grenville dykes yield both a high and low latitude pole (Halls et al., 2015; Murthy, 1971). Halls et al. (2015) propose that the high latitude pole is the result of an intermediary stage in the reversal of an axial dipole field. In the case of Baltica the model is based on the Alnö carbonate complex (584 r 7 Ma) (Meert et al., 2007; Piper, 1981) in which both a high and a low latitude component co-exist in the same unit. However the primary nature 40 has not been proven for either. Furthermore, the Fen carbonate complex pole (Meert et al., 1998), another pole in the model, lacks stability tests and is likely a Permo-Triassic overprint (Meert, 2014b). 5.3. Paleogeographic reconstructions (1.87-0.57 Ga) Mesoproterozoic Paleogeographic reconstructions at 1.87 Ga and 1.57 Ga are presented here based on the Keuruu diabase dyke and Åland intrusives paleomagnetic poles, respectively, with other poles listed in Table 4. The 1.87 Ga reconstruction presented here (Fig. 5) indicates the onset of the supercontinent Nuna, which was assembled by at least ca. 1650 – 1580 Ma (Pisarevsky et al, 2014a). At 1.87 Ga, Baltica and Laurentia were not yet assembled. Sarmatia and Volgo-Uralia collided with the Fennoscandian Shield only between 1.82 and 1.80 Ga along the Russian collisional belt to form Baltica (Bogdanova et al., 2008, 2015; Elming et al., 2010). The Trans-Hudson orogeny, connecting Superior-Nain and Slave-Rae-Hearne blocks of Laurentia, occurred between 1.91 and 1.81 Ga (Hoffman, 1988). For ease of illustration, Laurentia is shown as a united craton at 1.87 Ga (Fig. 5), however the position of Superior and Slave poles do not support a united craton at this time yet. In the 1.87 Ga reconstruction (Fig. 5), Fennoscandia is positioned at low latitudes and aligns with Laurentia in a way that would proceed into the 1.8-1.2 Ga NENA configuration, which is established in the 1.57 Ga reconstruction (Fig. 6). Although there are no high quality paleomagnetic poles for Amazonia at ca. 1.87 Ga and ca. 1.57 Ga, interpolations were used in both cases (Table 4), positioning Amazonia at near equatorial positions. The position of Amazonia in the 1.87 Ga reconstruction (Fig. 5) resembles a SAMBA-type configuration (South America – Baltica), in which northern Amazonia is attached to SW Baltica (Johansson, 2009). The SAMBA configuration is supported by the 1.79 Ga Avanavero intrusions pole (Bispo-Santos et al., 2014b; Pisarevsky et al., 2014a). The position of Amazonia at 1.57 Ga (Fig. 6) is supported by the 1789 Ma Colider Volcanics pole (Bispo-Santos et al., 2008) and the 1439 Ma Aquapei pole (Elming et al., 2009; Geraldes et al., 2014), both of which overlap with the Åland pole of Baltica. Siberia possibly formed part of the Nuna core (Wingate et al., 2009; Evans and Mitchell, 2011). The 1863 Ma Upper Akitkanchaya pole indicates a low latitudinal position of Siberia with a large distance between Siberia and Laurentia, similar to the position of Siberia at ca. 1770 - 1720 Ma (Pisarevsky et al., 2014a). In the 1.57 Ga reconstruction (Fig.6), a direct connection between Siberia and Laurentia 41 is shown as in the reconstruction by Mitchell and Evans (2011). Rainbird et al. (1998) identified northwest Canada as the source region for Mesoproterozoic zircons in mid-late Riphean sandstone in southeastern Siberia, supporting a close connection between Laurentia and Siberia during the Mesoand Neoproterozoic. Fig. 5A. Paleogeographic reconstruction of continents at 1.87 Ga based on results from Article IV. 1.88 Ga reconstructions by Pesonen et al. (2012) and Belica et al. (2014) added for comparison. FSc = Fennoscandia, La = Laurentia, Am = Amazonia, Si = Siberia, WAU = Western Australia, In = India, NC = North China, Ka = Kalahari. The colour of the poles correspond with the colour of craton outlines. Closed and open Laurentia poles indicate Superior and Slave poles, respectively. B. Postion of Keuruu pole and selected poles from Laurentia, Siberia and Amazonia (Table 4) in the 1.88 Ga paleogeographic reconstruction by Pesonen et al. (2012). C. Paleogeographic reconstruction modified after Belica et al. (2014) with alternative position for Siberia (Baltica and Laurentia the same as in B). The 1.57 Ma Nuna reconstruction (Fig. 6) shows the North Australian craton located at NW Laurentia in a SWEAT-like configuration (e.g. Pisarevsky, 2014a; Furlanetto et al., 2013; Zhang et al., 2012; Betts et al., 2008, 2009). The North Australian craton is currently the only Australian craton with reliable paleomagnetic results for the 1.57 Ma reconstruction, however the North Australian, West 42 Australian and South Australian cratons were either already assembled into present day Australia, or were in close proximity to each other since ca. 1800 Ma (Pisarevsky et al., 2014a and references therein; Li and Evans, 2011). The Western Australian craton is situated at low latitudes in the 1870 Ma reconstruction (Fig. 5) from where it possibly moved northwards to form the SWEAT-like configuration with Laurentia during the Mesoproterozoic. Fig. 6A. Paleogeographic reconstruction of continents at 1.57 Ga based on results from Article II. 1.58 Ga reconstructions by Pisarevsky et al. (2014a) and 1.59 Ga reconstruction by Zhang et al. (2012) added for comparison. Ba = Baltica, La = Laurentia, Am = Amazonia, Si = Siberia, NAU = Northern Australia, In = India, NC = North China, Ka = Kalahari, C = Congo, SF = São Francisco. The colour of the poles correspond with the colour of craton outlines. Baltica rotated to Laurentia: Elat = 47.5°, Elon = 1.5°, angle = 49° (Evans and Pisarevsky, 2008). Siberia rotated to Laurentia: Elat = 76.8°, Elon = 106.2°, angle = 146.6° (Evans and Mitchell, 2011). North Australia rotated to Laurentia: Elat = 31.5°, Elon = 98°, angle = 102.5° (Evans and Mitchell, 2011). India is rotated to the absolute framework: Elat = -13.21°, Elon = 136.86°, angle = 197.48° (Pisarevsky et al., 2014a). B. Postion of Åland pole and selected poles from Laurentia, Siberia and Amazonia (Table 4) in the 1.58 Ga paleogeographic reconstruction by Pisarevsky et al. (2014a). C. 1.59 Ga reconstruction by Zhang et al., 2012) with same euler rotations for Baltica, Laurentia, Amazonia, and Siberia as in A. 43 Both the 1.88 Ga Dharwar dykes pole and the 1.47 Ga Lakhna dykes pole position India at an equatorial position. In the 1.87 Ga reconstruction (Fig. 5) India is positioned south of Fennoscandia based on geological matches between India and Sarmatia (e.g. Pisarevsky et al., 2013). The low latitudinal position of North China during the late Paleoproterozoic and Mesoproterozoic is supported by paleomagnetic data (e.g. Table 4) and ca. 1.7 Ga stromatolites (Zhang, 1988). In the 1.87 Ga reconstruction (Fig. 5) North China is positioned close to Western Australia, as proposed by Zhang et al. (2012). Based on the 1.77 - 1.27 reconstructions of Pesonen et al. (2003), Jacobs et al. (2008), and Pisarevsky et al. (2014a) in which Kalahari is surrounded by ocean, Kalahari is positioned as a “lone” continent in the Southern hemisphere in the 1.87 Ga reconstruction (Fig. 5). Based on a mismatch of the 1.87 – 1.88 Ga Mashonaland pole from the Zimbabwe craton and the 1.88 Ga Post-Waterberg pole from the Kaapvaal craton (Table 4), Hanson et al. (2011) proposed that Kalahari did not assemble until after 1.87 Ga. However the qualtity of the Post-Waterberg pole is questionable as it is not supported by a field test nor a reversal test. We therefore keep Kalahari as a unified craton in the 1.87 Ga reconstruction. Table 4 Paleomagnetic poles used in the reconstructions Plat (°N) Plon (°E) A95 (°) Age (Ma) Q(1-7) Reference Keuruu diabase dykes 45 231 5.5 1870 1101110=5 Article IV Åland intrusives 24 191 2.8 15801570 1111111=7 Article II Mean Postjotnian intr. -1.8 159 3.4 1258 1111101=6 Pesonen et al., 2003 Laanila-Ristijarvi dykes -2 212 13.8 1044 0011100=3 Mertanen et al., 1996 Egersund dykes -31 224 15.7 616 ± 3 1111101=6 Walderhaug et al. (2007), Bingen et al. (1998) obs. -49 61 8.1 600-570 0110111=5 Article III i.c. -61 68 7.6 Formation Baltica Hailuoto sediments 44 Mean 570 Ma -52 118 570 1111111=7 1 obs. -30 111 550 1111111=7 2 i.c. -42 116 Molson dykes B+C2 28.9 218 3.8 1877 +7/- 1111111=7 4, 1884 ± 2 Halls and Heaman (2000) Zhai et al. (1994) Halls and Evans (2010) MEAN 1: Haig/Flaherty/Sutton 1 246 3.9 1870 ± 1 1111111=7 Luleå working group (2009) MEAN 2: Seton/Akaitcho/Mara -6 260 4.0 1885 ± 5 1111111=7 Mitchell et al. (2010) MEAN 3: -12 Kahochella/Peacock Hills 285 7.0 1882 ± 4 1100111=5 Mitchell et al. (2010) MEAN 4: Pearson A /Peninsular sill/ Kilohigok basin sill -22 269 6.0 1870 ± 4 1101111=6 Mitchell et al. (2010) Stark formation -15 215 4.9 1876±10 1110111=6 Bingham and Evans (1976) Western Channel diabase 9.0 245.0 6.6 1590± 3 1101101=5 Irving et al. (1972) Hamilton and Buchan (2010) MacKenzie dykes 4 190 5.0 1267 1111101=6 Buchan et al. (2000) Freda sandstone 2 179 4.2 1050 1110100=4 Henry et al. (1977) Long Range dykes -19 175 17.4 615 ± 2 1111111=7 Murthy et al.(1992) Grenville dykes (B+E) -57 48 9.1 585 1111110=6 Halls et al. (2015) Baie de Mouton complex (A) -43 153 12.0 583 ± 2 1110001=4 McCausland et al. (2011) Baie de Mouton complex (B) 34 142 15.4 Catoctin Basalts -42 117 17.5 572 ± 5 1111111=7 Meert et al. (1994b) Sept Iles intrusion 20 142 6.7 565 ± 4 1111100=5 Tanczyk et al. (1987) Skinner Cove volcanics 16 157 9.0 550 ± 3 1111100=5 McCausland and Hodych (1998) Surumu volcanics 27 235 8.1 1970 ± 10 1111101=6 Bispo-Santos et al., 2014a Avanavero mafic rocks 48 208 9.2 1789 ± 3 Bispo-Santos et al., 2014b Mean 550 Ma Laurentia 1010010=3 Amazonia 45 1111101=6 Colider volcanics 63 119 9.5 1789 ± 7 1110111=6 Bispo-Santos et al., 2008 Aguapei sills/dykes 65 101 10.1 1439 ± 7 1110111=6 Elming et al., 2009 Geraldes et al., 2014 Nova Guarita dykes 48 66 6.6 1419 ± 4 1111111=7 Bispo-Santaos et al., 2012 Nova Floresta formation 25 165 5.5 1200 ± 7 1110101=5 Tohver et al. (2002) Rio Negro basement 5.2 7.5 1035 1000011=3 Bettencourt et al. (1996) Upper Akitkanchaya igneous and sedimentary rocks -22 98 5.2 1863 ± 9 1110100=5 Didenko et al. (2009) Sololi-Kyutingde intrustions -37 73 10.4 1473 ± 24 Linok formation 15.2 76 7.5 1050 0111111=6 Gallet et al. (2000) Frere formation 45 40 1.8 1890±10 1110111=6 Williams et al. (2004) Rasmussen et al. (2012) Gnowangerup-Fraser dykes 56 324 6.3 1215 1111111=7 Pisarevsky et al. (2014b) Balbirini dolomite (upper -52 part) 176 7.5 1589± 3 1110110=5 Idnurm (2000) Alcurra dykes and sills 3 80 8.8 1077 1111001=5 Schmidt et al. (2006) Dharwar 1.88 Ga dykes 37 334 3.2 1885± 3 1111110=6 Belica et al. (2014) Lakhna dykes 41 121 20.5 1466± 3 1110111=6 Pisarevsky et al. (2013) Majhgawan Kimberlite 37 213 12.2 1074±14 1010100=3 Gregory et al. (2006) Mashonaland dolerites -8 158 5.0 1871.9 ± 1111111=7 2.2, 1881.1 +5.9/-5.1, 1882.7 +1.6/-1.5 Bates and Jones (1996) Hanson et al. (2011) Söderlund et al. (2010) Post-Waterberg sills -9 194 18.0 1875±4 Hanson et al. (2004) Siberia Wingate et al., (2009) W. Australia N. Australia India Kalahari 46 1110101=5 Port Edward pluton -7 328 4.4 1025 ± 8 1110001=4 Gose et al. (2004) Bahia dykes 8 6 11.9 1500 Late Kibaran intrusives -17 113 7.7 1236 1110001=4 Meert et al. (1994a) 281 7 1078±18 0111101=5 D’Agrella-Filho et al. (2004) Congo Salminen et al. (submitted) São Francisco Salvador and Olivença 9 dykes (R-polarity results) North China Taihang dykes 36 246 3.0 1769±3 1111101=6 Halls et al. (2000) Yangzhuang formation 17 214 5.7 1560 0111111=6 Wu et al. (2005) Pei et al. (2006) Yanliao mafic sills -6 180 4.3 1323±7 1111101=6 Chen et al. (2013) Zhang et al. (2012) 1060 Ma interpolation 21 217 ca. 1060 3 Plat, Plon is latitude and longitude of the paleomagnetic pole. A95 = 95% confidence circle of the pole, Q(1-7) = Van der Voo reliability criteria of paleomagnetic poles References: 1.The 570 Ma mean pole was calculated from the Krivaya Luka, Kurgashlya and Bakeevo poles (Lubnina et al., 2014). 2. The 550 Ma mean pole was calculated from the Verkhotina comp. Z (Popov et al., 2005) and Zolotitca comp. B (Iglesia Llanos et al., 2005) poles. 3. The 1060 Ma North China pole was interpolated from the ca. 1175 Ma Tieling sills (Zhang et al., 1991) and ca. 950 Ma Qingbaikouan (Zhang et al., 2006) poles. Reconstructions at 1.25 Ga and 1.05 Ga are also presented here (Fig. 7), although no new poles were obtained in this study for this period. In both the 1.25 Ga and 1.05 Ga reconstructions Baltica and Laurentia are connected; in the 1.25 Ga reconstruction Baltica and Laurentia is in the 1.78-1.27 Ga NENA configuration, whereas in the 1.05 Ga reconstruction western Norway is attached to eastern Greenland. Furthermore, Amazonia is close to Baltica in the 1.25 Ga reconstruction, but is rotated towards Laurentia in the 1.05 Ga reconstruction. The rotational changes of Baltica and Amazonia between 1.25 Ga and 1.05 Ga, possibly forming the Grenville collisional belt, mark the transition to Rodinia (Yakubchuk, 2010; Ibanez-Mejia et al., 2011; Roberts, 2013). 47 Fig. 7 (left). Paleogeographic reconstruction of continents at 1.25 Ga. 1.27 Ga reconstructions by Pisarevsky et al. (2014a) and Evans and Mitchell et al. (2011) added for comparison. Ba = Baltica, La = Laurentia, Am = Amazonia, Si = Siberia, Au = Australia (WAU and NAU = Western and Northern Australia, respectively), In = India, NC = North China, C = Congo, SF = São Francisco. Baltica rotated to Laurentia: Elat = 47.5°, Elon = 1.5°, angle = 49°(Evans and Pisarevsky, 2008). Siberia rotated to Laurentia: Elat = 76.8°, Elon = 106.2°, angle = 146.6° (Evans and Mitchell, 2011). Amazonia rotated to Laurentia: Elat = 53.93°, Elon = -68.94°, angle = 122.19° (based on SAMBA) (right). Paleogeographic reconstruction of continents at 1.05 Ga. 1.05 Ga reconstructions by Evans (2009) and Li et al. (2008) added for comparison. Ba = Baltica, La = Laurentia, Am = Amazonia, Si = Siberia, Au = Australia (WAU and NAU = Western and Northern Australia, respectively), In = India, NC = North China, C = Congo, SF = São Francisco, Ka = Kalahari. From the 1.27 Ga McKenzie dykes pole (Buchan et al. 2000) Laurentia moves to mid to high latitudes, based on ca. 1.1 Ga paleomagnetic poles (e.g. Ernst and Buchan, 1993; Swanson-Hysell et al., 2014), and gradually back to low latitudes, where it is again connected with Baltica at 1.05 Ga. Baltica lacks good quality poles for this time period. The 1.12 Ga Salla dyke VGP (Salminen and Pesonen, 2007) does not support the NENA configuration, however it closely resembles the secondary component (component B), discussed above, commonly observed in Fennoscandian formations, and may possibly not present the actual position of Baltica during that time. However some poor quility poles from Sweden (Bylund, 1992) and Ukraine (Mikailova, 1989) suggest an excursion of Baltica to mid latitudes, similar to Laurentia. 48 No good quality paleomagnetic data are available for Siberia at ca.1.25 Ga. Based on the 1.47 Ga Sololi-Kyutingde (Windgate, 2009), and 1.05 Ga Linok (Gallet et al. 2000) pole positions, a connection between Siberia and Laurentia is plausible at 1.25 Ga. The 1.05 Ga Linok pole, however positions Siberia at higher latitudes and does not support a southeast Siberia- northwest Laurentia connection, which contradicts geological support by Rainbird (1998). The Australian cratons are positioned in the northern hemisphere in the 1.25 Ga (not shown in Fig. 7A) and 1.05 Ga reconstructions, alongside western Laurentia. Li et al. (2008) proposed that the Australian cratons existed in close proximity to each other but in a different configuration than today, until ca. 650 Ma. This notion is followed in the 1.25 Ga and 1.05 Ga reconstructions, as a presentday configuration would imply an unusual vertical axis rotation between 1.25 Ga and 1.05 Ga. Neoproterozoic At ca. 615 Ma Baltica and Laurentia were possibly still connected with Baltica at intermediate latitudes and Laurentia at low latitudes (Fig. 8). The 613 Ma Long Range dykes (Laurentia) and the 616 Ma Egersund dykes are rift-related (Bingen et al. 1998, Puffer 2002), and may mark the start of the break-up between Baltica and Laurentia. The orientation of Baltica changes by ca. 180° between 615 Ma and 600-570 Ma (Article III), suggesting that Baltica moved across the polar region, which is consistent with earlier reconstructions (Meert, 2014; Li et al., 2013; McCausland et al., 2011). In this model we propose two possible positions for Laurentia at 585 Ma, based on two high quality paleomagnetic poles (Fig. 8). Considering the Grenville B+E pole (Halls et al. 2015), Laurentia followed Baltica over the polar region, suggesting that these two cratons were still connected at ca. 585 Ma. Based on the Baie de Moutan A pole, Baltica and Laurentia had already separated by ca. 585 Ma. The Baie de Moutan A poles also positions Laurentia at high latitudes, but with eastern Laurentia facing Baltica. At ca. 570 Ma Baltica is positioned at intermediate to low latitudes where it remains at 550Ma. Laurentia, however remains at the polar region at ca. 570 Ma, and at 550 Ma is positioned at equatorial latitudes. 49 Fig. 8. Reconstructions of Baltica and Laurentia between 615 -550 Ma. Baltica shown observed (obs.) and inclination corrected (i.c.) positions in 550 Ma reconstruction. The polar position of Laurentia at 570 Ma (Fig. 8) and the high latitude model of early Gondwana at 575 Ma (Pisarevsky et al. 2008), as well as the low to intermediate latitude of Baltica presented in this study and warm deposition environment of Hailuoto sediments (Tynni and Donner, 1980), suggest that no global scale glaciation event, as presented in the snowball Earth model (Kirschvink, 1992), took place at that time. These conditions further indicate zonal surface temperature gradients similar to today, i.e. warm equatorial areas and cold polar areas, unlike the high obliquity model presented by Williams (1975, 1993, 2008), which proposes an obliquity of the Earth’s spin axis with respect to the ecliptic of >54° resulting in warm polar areas and ice ages in the tropics. 6. Conclusions New paleomagnetic results were obtained from samples from 1.87 Ga Keuruu diabase dykes (Central Finland), 1.58-1.57 Ga Åland intrusives (Åland archipelago, SW Finland) and ca. 0.6-0.57 Ga Hailuoto sedimentary formation (Western Finland). In addition to these results, new paleomagnetic results were obtained from the Satakunta sandstone formation (SW Finland), providing a new relative (paleomagnetic) age estimate of ca. 1.63 – 1.45 Ga, older than previously thought (ca. 1.4-1.3 Ga). Results from Åland intrusives and Satakunta sandstone place Baltica at equatorial positions and support the NENA configuration between Baltica and Laurentia during the Mesoproterozoic. Results from the older Keuruu diabase dykes positions the Fennoscandian Shield at low latitudes and aligns 50 with Laurentia in a way that would naturally proceed into the 1.8-1.2 Ga NENA configuration. The primary nature of the Åland and Keuruu ChRM is supported by U-Pb rock ages, and a positive baked contact tests, yielding two new key poles to the late Paleoproterozoic to late Mesoproterozoic APWP. Results from the Hailuoto sediments add to the scattered Ediacaran paleomagnetic data of Baltica and indicate large distances between other late Neoproterozoic and early Cambrian paleomagnetic poles, implying rapid movement of Baltica from high latitudes at 615 Ma, over the polar region, to low latitudes at 550 Ma. A low to mid latitude position of Baltica determined by the Hailuoto paleomagnetic pole is in agreement with earlier geological studies of Hailuoto sediments that show the lack of glaciogenic sediments and indications of a warm depostion environment. Paleogeographic reconstructions are presented for 1.87 Ga, 1.57 Ga, 1.25 Ga, and 1.05 Ga. The 1.87 Ga reconstruction do not support the NENA or SAMBA configurations, but indicates the onset of Nuna. The 1.57 Ga and 1.25 Ga reconstructions indicate similarities in the relative positions between Baltica, Laurentia, Amazonia, Siberia. The transition between Nuna and Rodinia is marked by a rotation between Laurentia, and Baltica and Amazonia (and possibly West Africa), forming the Grenville collisional belt. In all these cases a secondary component with shallow to intermediate inclinations and northeasterly declinations were observed. It has been observed widely by previous authors and has been interpreted as a Phanerozoic overprint. In the case of Keuruu and Åland, meteorite impact (from Keurusselkä and Lumparn impacts, respectively) cannot be ruled out as a possible cause of the secondary component. The secondary component is mostly carried by low coercivities/blocking temperatures, but sometimes also at high coercivities/blocking temperatures causing asymmetry in the dual polarity results of Keuruu and Åland diabase dykes. 51 7. References Abrajevitch, A. and Van der Voo, R. 2010. Incompatible Ediacaran paleomagnetic directions suggest an equatorial geomagnetic dipole hypothesis. Earth and Planetary Science Letters 293, 164-170. Bates, M.P., Jones, D.L., 1996. A palaeomagnetic investigation of the Mashonaland dolerites, northeast Zimbabwe. Geophys.J.Int. 126, 513-524. Belica, M.E., Piispa, E.J., Meert, J.G., Pesonen, L.J., Plado, J., Pandit, M.K., Kamenov, G.D., Celestino, M., 2014. Paleoproterozoic mafic dyke swarms from the Dharwar craton; paleomagnetic poles for India from 2.37 to 1.88 Ga and rethinking theColumbia supercontinent. Precambrian Research 244, 100-122. Bettencourt, J.S., Onstott, T.C., Teixeira, W., 1996. Tectonic interpretation of 40Ar/39Ar Ages on Country Rocks from the Central Sector of the Rio Negro-Juruana province, Southwest Amazonian Craton. Int. Geology Review 36, 42-56. Betts, P. G., Giles, D. and Schaefer, B. F. 2008. Comparing 1800–1600 Ma accretionary and basin processes in Australia and Laurentia; possible geographic connections in Columbia. Precambrian Research, 166, 81–92. Betts, P.G., Giles, D., Foden, J., Schaefer, B.F., Mark, G., Pankhurst, M.J., Forbes,C.J., Williams, H.A., Chalmers, N.C., Hills, Q., 2009. Mesoproterozoic plume-modified orogenesis in eastern Precambrian Australia. Tectonics 28, TC3006,http://dx.doi.org/10.1029/2008TC002325. Biggin, A.J., Piispa, E.J., Pesonen, L.J., Holme, R., Paterson, G.A., Veikkolainen, T., Tauxe, L., 2015. Palaeomagnetic field intensity variations suggest Mesoproterozoic inner-core nucleation. Nature 526, 245 – 248. Bilardello, D., Kodama, K.P., 2009. Measuring remanence anisotropy of hematite in red beds: anisotropy of high field isothermal magnetization (hf-AIR). Geophysical Journal International 178, 1260-1272. Bilardello, D., Kodama, K.P., 2010. Rock magnetic evidence for inclination shallowing in the early Carboniferous Deer Lake Group red beds of western Newfoundland. Geophysical Journal International 181, 275-289. Bingen B., Demaiffe D., Van Breemen O., 1998. The 616 Ma old Egersund basaltic dike swarm, SW Norway, and Late Neoproterozoic opening of the Iapetus Ocean. Journal of Geology 106, 565-574. Bingham, D.K., Evans, M.E. 1976. Paleomagnetism of the Great Slave Supergroup, Northwest Territories, Canada: the Stark Formation. Canad. J. Earth Sci. 13, 563-578. Bispo-Santos, F., D’Agrella-Filho, M. S. et al. 2008. Columbia revisited: paleomagnetic results from the 1790 Ma colider volcanics (SW Amazonian Craton Brazil). Precambrian Research, 164, 40–49. Bispo-Santos, F., D’Agrella-Filho, M. S. et al. 2012. Tectonic implications of the 1419 Ma Nova Guarita mafic intrusives paleomag- netic pole (Amazonian Craton) on the longevity of Nuna. Precambrian Research, 196/197, 1–22. Bispo-Santos, F., D'Agrella-Filho, M.S., Janikian, L., Reis, N.J., Trindade, R.I.F., Reis, M.A.A.A. 2014a. Towards Columbia: Paleomagnetism of 1980–1960 Ma Surumu volcanic rocks, Northern Amazonian Craton. Precambrian Research 244, 123-138 52 Bispo-Santos, F., D'Agrella-Filho, M.S., Trindade, R.I.F., Janikian, L., Reis, N.J. 2014b. Was there SAMBA in Columbia? Paleomagnetic evidence from 1790 Ma Avanavero mafic sills (northern Amazonia Craton). Precambrian Research 244, 139-155. Bogdanova, S.V., Bingen, B., Gorbatschev, R., Kheraskova, T.N., Kozlov, V.I., Puchkov, V.N., Volozh, Yu. A., 2008. The East European Craton (Baltica) before and during the assembly of Rodinia. Precambrian Research, 160, 23-45. Bogdanova S., Gorbatschev R., Skridlaite G., Soesoo A., Taran L., Kurlovich D., 2015 Trans-Baltic Palaeoproterozoic correlations towards the reconstruction of supercontinent Columbia/Nuna. Precambrian Research 259, 5-33. Bradley, D.C., 2008. Passive margins through earth history. Earth-Science Reviews 91, 1-26. Bradley, D.C., 2011. Secular trends in the geologic record and the supercontinent cycle. EarthScience Reviews 108, 16-33. Buchan, K.L., Mertanen, S., Park, R.G., Pesonen, L.J., Elming, S.-Å., Abrahamsen, N., Bylund, G., 2000. Comparing the drift of Laurentia and Baltica in the Proterozoic: the importance of key palaeomagnetic poles. Tectonophysics 319, 167-198. Buchan, K.L., 2013. Key paleomagnetic poles and their use in Proterozoic continent and supercontinent reconstructions: A review. Precambrian Research 238, 93-110. Burrett C., Berry R., 2000. Proterozoic Australia-western United States (AUSWUS) fit between Laurentia and Australia. Geology 28, 103-106. Butler, R.F., 2004. Paleomagnetism: Magnetic domains to geologic terranes. Electronic Edition Bylund G., 1992. Palaeomagnetism, Mafic dykes and Protogine Zone, southern Sweden. Tectonophysics 201, 49-63. Chen, L., Huang, B., Yi, Z., Zhao, J., Yan, Y., 2013. Paleomagnetism of ca. 1.35 Ga sills in northern North China craton and implications for paleogeographic reconstruction of the Mesoproterozoic supercontinent. Precambrian Research 228, 36-47. Condie, K.C., 1998. Episodic continental growth and super continents: a mantle avalanche connection? Earth Planet. Sci. Lett. 163, 97–108. Condie K.C., 2001. Mantle plumes and their record in earth history. Cambridge, Cambridge University Press. Didenko, A.N., Vodovozov, V.Yu., Pisarevsky, S.A., Gladkochub, D.P., Donskaya, T.V., Mazukabzov, A.M., Stanevich, A.M., Bibikova, E.V., Kirnozova, T.I., 2009. Palaeomagnetism and U-Pb dates of the Palaeoproterozoic Akitkan Group (South Siberia) and implications for preNeoproterozoic tectonics. In: Reddy, S.M., Mazumber, R., Evans, D.A.D., Collins, A.S. (Eds). Palaeoproterozoic Supercontinents and Global Evolution. Geological Society Special Publication 323, 145-163 Domeier, M., Van der Voo, R., Torsvik, T.H., 2012. Paleomagnetism and Pangea: The road to reconciliation. Tectonophysics 514-517, 14-43. 53 Donadini, F., 2007. Features of the geomagnetic field during the Holocene and Proterozoic. Report series in Geophysics 52. University of Helsinki Division of Geophysics. Helsinki. Dunlop, D.J., 1979. On the use of Zijderveld vector diagrams in multicomponent paleomagnetic studies. Physics of the Earth and Planetary Interiors 20, 12-24 Dunlop, D.J., Özdemir, Ö., 1997. Rock magnetism, Fundementals and frontiers. Cambridge University Press, Cambridge, England, 573pp. Elming, S.-Å., D'Agrella-Filho, M.-S., Page, L.M., Tohver, E., Trindade, R.I.F., Pacca, I.I.G., Geraldes, M.C., Teixeira, W., 2009. A palaeomagnetic and 40Ar/39Ar study of late Precambrian sills in the SW part of the Amazonian craton: Amazonia in the Rodinia reconstruction. Geophys. J. Int. 178, 106-122. Elming, S-Å., Shumlyanskuu, L., Kravchenko, S., Layer, P., Söderlund, U., 2010. Proterozoic Basic dykes in the Ukrainian Shield: A palaeomagnetic, geochronologic and geochemical study – The accretion of the Ukrainian Shield to Fennoscandia. Precambrian Research 178, 119-135. Ernst, R.E., Buchan, K.L., 1993. Paleomagnetism of the Abitibi dyke swarm, southern Superior Province, and implications for the Logan Loop. Canadian Journal of Earth Science 30, 1886-1897. Evans, D.A.D., 2003. True polar wander and supercontinents. Tectonophysics 362, 303–320. Evans, D.A.D., 2006. Proterozoic low orbital obliquity and axial-dipolar geomagnetic field from evaporate palaeolatitudes. Nature 444, 51 – 55. Evans, D.A.D., 2009. The palaeomagnetically viable, long-lived and all-inclusive Rodinia supercontinent reconstruction. Geological Society, London, Special Publications 327, 371-404. Evans, D.A.D., Mitchell, R.N., 2011. Assembly and breakup of the core of PaleoproterozoicMesoproterozoic supercontinent Nuna. Geology 39, 443-446. Evans, D.A.D., Pisarevsky, S.A., 2008. Tectonics on early Earth? Weighing the paleomagnetic evidence. The Geological Society of America, Special Paper 440, 249-263. Everitt, C.W.F., Clegg, J.A., 1962. A field test of paleomagnetic stability. Geophysical Journal of London, 6, 312-319.Fisher, R., 1953. Dispersion of sphere. Proceedings of the Royal Society A 217, 293-305. Fisher, R., 1953. Dispersion of sphere. Proceedings of the Royal Society A 217, 293-305. French, J.E., L.M. Heaman, 2010. Precise U-Pb dating of Paleoproterozoic mafic dyke swarns of the Dharwar craton, India: implications for the existence of the Neoarchean supercratons Sclavia. Precambrian Research 183, 416–441. Furlanetto, F., Thorkelson, D.J., Gibson, H.D., Marshall, D.D., Rainbird, R.H., Davis, W.J., Crowley, J.L., Vervoort, J.D., 2013. Late Paleoproterozoic terrane accretionin northwestern Canada and the case for circum-Columbian orogenesis. Pre-cambrian Research 224, 512–528. Gallet, Y., Pavlov, V.E., Semikhatov, M.A. 2000. Late Mesoproterozoic magnetostratigraphic results from Siberia: paleogeographic implications and magnetic field behavior. J. Geophys. Res. 105, 16481 – 16499 54 Geraldes, M.C., Nogueira, C., Vargas-Mattos, G., Mattos, R., Teixeira, W., Valencia, V., Ruiz, J., 2014. U-Pb detrital zircon ages from the Aguapei Group (Brazil): Implications for the geological evolution of the SW border of the Amazonian Craton. Precambrian Research 244, 306 – 316. Girdler, R.W., 1961. The measurement and computation of anisotropy of magnetic susceptibility in rocks. Geophysical Journal. Royal Astronomical Society 5, 34-44. Gower, C.F., Ryan, A.F., Rivers, T., 1990. Mid-Proterozoic Laurentia–Baltica: an overview of its geological evolution and a summary of the contributions made by this volume. In: Gower, C.F., Rivers, T., Ryan, B. (Eds.), Mid Proterozoic Laurentia–Baltica. Geological Association of Canada, St. John’s Newfoundland, pp. 23–40. Gose, W.A., Johnston, S.T., Thomas, R.J., 2004. Age of magnetization of Mesoproterozoic rocks from the Natal sector of the Namaqua-Natal belt, South Africa. J.Afr.Earth Sci. 40, 137 - 145 Gregory, L.C., Meert, J.G., Pradhan, V., Pandit, M.K., Tamrat, E., Malone, S.J., 2006. A paleomagnetic and geochronologic study of the Majhgawan kimberlite, India: Implications for the age of the Upper Vindhyan Supergroup. Precambrian Research 149, 65-75 Gurnis, M., 1988. Large-scale mantle convection and the aggregation and dispersal of supercontinents. Nature 232, 695-699. Gurnis, M., Torsvik, T.H., 1994. Rapid drift of large continents during the late Precambrian and Paleozoic: Paleomagnetic constraints and dynamic models. Geology 22, 1023-1026. Halls, H.C., 1976. A least square method to find a remanence direction from converging remagnetization circles. Geophysical Journal of Royal Astronomical Society 45, 297-304. Halls, H.C., 1978. The use of coverging remagnetization circles in palaeomagnetism. Physics of the Earth and Planetary Interiors 16, 1-11. Halls, H.C., Evans, D.A.D., 2010. Restoring Proterozoic deformation within the Superior craton. Precambrian Research 183, 474 – 489. Halls, H.C., Heaman, L.M., 2000. The paleomagnetic significance of new U-Pb age data from the Molson dyke swarms, Cauchon Lake area, Manitoba. Can. J. Earth Sci. 37, 957 – 966 Halls, H.C., Kumar, A., Srinivasan, R., Hamilton, M.A., 2007. Paleomagnetism and U-Pb geochronology of easterly trending dykes in the Dharwar craton, India: feldspar clouding, radiating dyke swarms and the position of India at 2.37 Ga. Precambrian Research 155, 47–68. Halls, H.C., Li, J., Davis, D., Hou, G., Zhang, B., Qian, X., 2000. A precisely dated Proterozoic palaeomagnetic pole for the North China craton, and its relevance to palaeocontinental reconstruction. Geophys. J. Int. 143, 185-203. Halls, H.C., Lovette, A., Hamilton, M., Söderlund, U., 2015. A paleomagnetic and U-Pb geochronology study of the western end of the Grenville dyke swarm: Rapid changes in paleomagnetic field direction at ca. 585 Ma related to polarity reversals? Precambrian Research 257, 137-166. Hamilton, M.A., Buchan, K.L., 2010. U-Pb geochronology of the Western Channel Diabase, northwestern Laurentia: Implications for a large 1.59 Ga magmatic province, Laurentia's APWP and 55 paleocontinental reconstructions of Laurentia, Baltica and Gawler craton of southern Australia. Precambrian Research 183, 463 – 473. Hanson, R.E., Gose, W.A., Crowley, J.L., Ramezani, J., Bowring, S.A., Bullen, D.S., Hall, R.P., Pancake, J.A., Mukwakwami, J., 2004. Paleoproterozoic intraplate magmatism and basin development on the Kaapvaal Craton: age, paleomagnetism and geochemistry of ca. 1.93-1.87 Ga post-Waterberg dolerites. S. Afr. J. Geol. 107, 233-254. Hanson, R.E., Rioux, M., Gose, W.A., Blackburn, T., Bowring, S.A., Mukwakwami, J., Jones, D., 2011. Paleomagnetic and geochronological evidence for large-scale post–1.88 Ga displacement between the Zimbabwe and Kaapvaal cratons along the Limpopo belt. Geology 39, 487 – 490. Henry, S.G., Mauk, F.J., Van der Voo, R., 1977. Paleomagnetism of the Upper Keweenawan sediments: the Nonesuch Shale and Freda Sandstone. Canad.J.Earth Sci. 14, 1128-1138 Hoffman, P.F., 1988. United Plates of America, the birth of a craton: early Proterozoic assembly and growth of Laurentia. Annual Review of Earth and Planetary Sciences 16, 543 – 603. Hoffman, P.F., 1989. Precambrian geology and tectonic history of North America. In Bally, A.W., Palmer, A.R. (Eds). The Geology of North America – An overview Vol. A. Geological Society of America Hoffman, P. F. 1991. Did the breakout of Laurentia turn Gondwanaland inside-out? Science, 252, 1409–1412. Hoffman, P. F.1997. Tectonic genealogyofNorthAmerica. In: Van der Pluijm, B.A. and Marshak, S. (eds.) Earth Structure: An Introduction to Structural Geology and Tectonics. McGraw-Hill, New York, 459–464. Ibanez-Mejia, M., Ruiz, J., Valencia, V.A., Cardona, A., Gehrels, G., Mora, A.R., 2011. The Putumayo Orogen of Amazonia and its implications for Rodinia reconstructions: new U-Pb geochronological insights into the Proterozoic tectonic evolution of northwestern South America. Precambrian Research 191, 58-77. Idnurm, M., 2000. Towards a high resolution Late Palaeoproterozoic - earliest Mesoproterozoic apparent polar wander path for northern Australia. Aust.J.Earth Sci. 47, 405 – 429. Iglesia Llanos, M. P., Tait, J. A., Popov, V., Abalmassova, A. 2005. Palaeomagnetic data from Ediacaran (Vendian) sediments of the Arkhangelsk region, NW. Russia: An alternative apparent polar wander path of Baltica for the Late Proterozoic – Early Palaeozoic. Earth and Planetary Science Letter 240, 732 – 747. Irving, E., 1964. Paleomagnetism and its application in geological and geophysical problems. John Wiley, New York. 399pp. Irving, E., Donaldson, J.A., Park, J.K., 1972. Paleomagnetism of the Western Channel Diabase and associated rocks, Northwest Territories. Canad.J.Earth Sci. 9, 960 – 971. Jacobs, J., Pisarevsky, S.A., Thomas, R.J., Becker, T., 2008. The Kalahari Craton duringthe assembly and dispersal of Rodinia. Precambrian Research 160, 142–158. 56 Jackson, M.J., Banerjee, S.K., Marvin, J.A., Lu. R., Gruber, W., 1991. Detrital remanence, inclination errors and anhysteretic remanence anisotropy: quantitatively model and experimental results. Geophysical Journal International 104, 95-103. Johansson, Å. 2009. Baltica, Amazonia and the SAMBA connection – 1000 million years of neighbourhood during the Proterozoic? Precambrian Research, 175, 221–234. Karlstrom, K. E., Ahall, K. I., Harlan, S. S., Williams, M. L., McLelland, J. and Geissman, J. W. 2001. Long-lived (1.8–1.0 Ga) convergent orogen in southern Laurentia, its extension to Australia and Baltica, and implications for refining Rodinia. Precambrian Research, 111, 5–30. King, R.F., 1955. Remanent magnetism of artificially deposited sediments. Monthly Notices Royal Astronomical Society Geophysical Supplements 7, 115-134 Kirschvink, J. L. 1980. The least-squares line and plane and the analysis of palaeomagnetic data. Geophysical Journal of the Royal Astronomical Society, 62, 699–718. Kirschvink, J.L. 1992. Late Proterozoic Low-Latitude Global Glaciation: The Snowball Earth. In: Schofp, J. W. and Klein, C. (Eds) The Proterozoic Biosphere. Cambridge University Press, Cambridge, 51–52. Kodama, K.P., 2012. Paleomagnetism of Sedimentary Rocks: Process and Interpre-tation. WileyBlackwell, Chichester, West Sussex. Kohonen, J., Pihlaja, P., Kujala, H., Marmo, J., 1993. Sedimentation of the Jotnian Satakunta sandstone, western Finland. Geological Survey of Finland Bulletin 369.Kodama, K.P., 2012. Paleomagnetism of Sedimentary Rocks: process and interpretation. Wiley-Blackwell. Leino, M.A.H., 1991. Paleomagneettisten tulosten monikomponenytianyalyysi pienimmän neliösumman menetelmällä (Multicomponent analysis of paleomagnetic data by least-square method). Geological Survey of Finland Report Q29.1/91/2 (in Finnish). Li, Z. X., Bogdanova, S. V. et al. 2008. Assembly, configuration, and break-up history of Rodinia: a synthesis. Precambrian Research, 160, 179–210. Li, Z. X., Bogdanova, S. V. et al. 2009. How not to build a supercontinent: A reply to J.D.A. Piper. Precambrian Research 174, 208-214. Li, Z.X., Evans, D.A.D., 2011. Late Neoproterozoic 40° intraplate rotation withinAustralia allows for a tighter-fitting and longer-lasting Rodinia. Geology 39, 39–42. Li, Z. X., Evans, D.A.D., Halverson, G.P., 2013. Neoproterozoic glaciations in a revised global palaeogeography from the breakup of Rodinia to the assembly of Gondwanaland. Sedimentary Geology 294, 219-232. Li, Z. X., Zhang, L., Powel, C. M., 1995. Sourth China in Rodinia: part of the missing link between Australia-East Antarctica and Laurentia? Geology 23, 407-410. Lubnina N.V., Pisarevsky, S.A., Puchkov, V.N., Kozlov, V.I., Sergeeva, N.D., 2014. New paleomagnetic data from Late Neoproterozoic sedimentary successions in Southern Urals, Russia: implications for the Late Neoproterozoic paleogeography of the Iapetan realm. International Journal of Earth Sciences 103, 1317-1334. 57 McCausland, P.J.A., Hankard, F., Van der Voo, R., Hall, C.M., 2011. Ediacaran paleogeography of Laurentia: paleomagnetism and 40Ar-39Ar geochronology of the 583 Ma Baie de Moutons syenite, Quebec. Precambrian Research 187, 58-78. McCausland, P.J.A., Hodych, J.P., 1998. Paleomagnetism of the 550 Ma Skinner Cove volcanics of western Newfoundland and the opening of the Iapetus Ocean. Earth and Planetary Science Letters 163, 15-29. McFadden, P.L., 1990. A new fold test for palaeomagnetic studies. Geophysical Journal International 103, 161–169. McFadden, P.L., McElhinny, M.W. 1990. Classification of the reversal test in palaeomagnetism. Geophysical Journal International 103, 725-729. McMenamin, M.A.S., McMenamin, D.L.S., 1990. The emergence of animals: the Cambrian breakthrough. New York, Columbia University Press. Meert, J.G. 2002. Paleomagnetic evidence for a Paleo-Mesoproterozoic supercontinent Columbia. Gondwana Research 5, 207-215. Meert. J.G., 2014a. Strange attractors, spiritual interlopers and lonely wanderers: The search for prePangean supercontinents. Geoscience Frontiers 5, 155-166 Meert, J.G. 2014b. Ediacaran-Early Ordovician paleomagnetism of Baltica: A review. Gondwana Research 25, 159-169. Meert, J.G., Hargraves, R.B., Van der Voo, R., Hall, C.M., Halliday, A.N., 1994b. Paleomagnetic and 40Ar/39Ar studies of Late Kibaran intrusives in Burundi, East Africa: implications for Late Proterozoic supercontinents. J. Geol. 102, 621 – 637. Meert, J.G., Stuckey, W., 2002. Revisiting the paleomagnetism of the 1.476 Ga St. Francois Mountains igneous province. Missouri. Tectonics 21, 1-19. Meert, J.G. and Torsvik, T.H., 2003. The making and unmaking of a supercontinent: Rodinia revisted, Tectonophysics, 375, 261-288. Meert, J.G., Torsvik, T.H., Eide, E.A., Dahlgren, S., 1998. Tectonic significance of the Fen Province, S. Norway: constraints from geochronology and pleomagnetism.J. Geol. 106, 553–564. Meert, J.G., Van der Voo, R., 1997. The assembly of Gondwana 800–550 Ma. Journal of Geodynamics 23, 223–235. Meert, J.G., Van der Voo, R., Powell, C.Mca., Li. Z.X., McElhinny, M.W., Chen, Z., Symons, D.T.A., 1993. A plate tectonic speed limit? Nature 363, 216-217. Meert, J.G., Van der Voo, R., Payne, T.P., 1994b. Paleomagnetism of the Catoctin Volcanic province: a new Vendian-Cambrian apparent polar wander path for North America. Journal of Geophysical Research 99, 4625-4641. Meert, J. G., Walderburg, H. J., Torsvik, T. H., Hendriks, B. W. H. 2007. Age and paleomagnetic signature of the Alnø carbonatite complex (NE Sweden): Additional controversy for the Neoproterozoic paleoposition of Baltica. Precambrian Research 154, 159 - 174. 58 Mertanen, S., Pesonen, L.J., Huhma, H., Leino, M., 1989.Paleomagnetism of the Early Proterozoic layered intrusions, northern Finland. Bulletin of the Geological Society of Finland, 347. Mertanen, S., Pesonen, L.J., Huhma, H., 1996. Palaeomagnetism and Sm-Nd ages of the Neoproterozoic dykes in Laanila and Kautokeno, northern Fennoscandia. In: Brewer, T.S. (Ed.). Precambrian Crustal Evolution in the North Atlantic Region. Geological Society Special Publication 112, 331 – 358. Mikhailova N.P., 1989. Paleomagnetic directions and pole positions: Data for the USSR, Issue 7. Soviet Geophysical Committee: Word Data Center-B (Moscow). Mitchell, R.N., Bleeker, W., Van Breemen, O., Lecheminant, T.N., Peng, P., Nilsson, M.K.M., Evans, D.A.D., 2014. Plate tectonics before 2.0 Ga: Evidence from paleomagnetism of cratons within supercontinent Nuna. American Journal of Science 314, 878 – 894. Mitchell, R.N., Killian, T.M., Evans, D.A.D., 2012. Supercontinent cycles and the calculation of absolute palaeolongitude in deep time. Nature 482, 208 – 212. Mitchell, R.N., Kilian, T.M., Raub, T.D., Evans, D.A.D., Bleeker, W., Maloof, A.C., 2011. Sutton hotspot track: resolving Ediacaran-Cambrian tectonics and true polar wander of Laurentia. American Journal of Science 311, 651-663 Mitchell, R.N., Hoffman, P.F., Evans, D.A.D., 2010. Coronation loop resurrected: Oscillatory apparent polar wander of Orosirian (2.05–1.8 Ga) paleomagnetic poles from Slave craton. Precambrian Research 179, 121-134. Moores, E.M., 1991. Southwest U.S.-East Antarctica (SWEAT) connection: a hypothesis. Geology 19, 425-428. Murphy, J.B., Nance, R.D., 2013. Speculations on the mechanisms for the formation and breakup of supercontinents. Geoscience Frontiers 4, 185 – 194. Murthy, G.S., 1971. The paleomagnetism of diabase dikes from the GrenvilleProvince. Can. J. Earth Sci. 8, 802–812. Murthy, G., Gower, C., Tubrett, M., Pätzold, R., 1992. Paleomagnetism of Eocambrian Long Range dykes and Double Mer Formation from Labrador, Canada. Canadian Journal of Earth Sciences 29, 1224-1234 Neuvonen, K.J. 1973. Remanent magnetization of the Jotnian sandstone in Satakunta, SW-Finland. Bulletin of the Geological Survey of Finland 45, 23-27 Özdemir, Ö., Dunlop, D.J., 1996. Thermoremanence and Néel Temperature of Goethite. Geophysical Research Letters 23, 921-924. Pavlov, V.E., Gallet, Y., 2011. Precambrian Magnetostratigraphy. American Geophysical Union, Fall Meeting 2011, abstract #DI34A-04 Pei, J., Yang, Z., Zhao, Y., 2006. A Mesoproterozoic paleomagnetic pole from the Yangzhuang Formation, North China and its tectonics implications. Precambrian Research 151, 1-13. Pesonen, L.J., 1989. Esittäytymisvuorossa Gtk:n paleomagnetismin laboratorio, Suomen Akatemian Luonnontieteellisen Toimikunnan kokous GTK:ssa. Open file report Q10.3/89/10, Geophysics Department, Geological Survey of Finland, Espoo 8 p. (in Finnish) 59 Pesonen, L.J., 2006. Kiinteän maan geofysiikan uudet laboratoriot Kumpulassa. Geologi 58, 144 – 148. (in Finnish) Pesonen, L.J., Elming, S.-Å., Mertanen, S., Pisarevsky, S., D’Agrella-Filho, M.S., Meert, J.G., Schmidt, P.W., Abrahamsen, N., and Bylund, G., 2003. Paleomagnetic configuration of continents during the Proterozoic. Tectonophysics 375, 289-324. Pesonen L.J., Klein, R., Raiskila, S., Mertanen, S., Sangchan, P., 2012a. Paleomagnetism and petrophysics of the Keuruu dykes. In: Pesonen, L.J., Mertanen, S., Sangchan, P., Koljonen, E. (Eds). Supercontinent Symposium 2012 Pre-Symposium Excursion Guidebook: Keuruu, Jormua, Taivalkoski, Siurua, Tervola. Pesonen, L.J., Mertanen S., Veikkolainen, T., 2012b. Paleo-Mesoproterozoic Supercontinents – A Paleomagnetic View. Geophysica 48, 5-48. Piper, J.D.A., 1981. Magnetic properties of the Alnö Complex. Geoligiska Foreningen i Stockholm Forhandlinger 103, 9-15. Piper, J.D.A., 1982, The Precambrian palaeomagnetic record: The case for the Proterozoic supercontinent: Earth and Planetary Science Letters, v. 59, p. 61–89. Piper, J.D.A., 2013, A planetary perspective on Earth evolution: Lid Tectonics before Plate Tectonics: Tectonophysics, v. 589, p. 44–56. Piper J.D.A., 2015 The Precambrian supercontinent Palaeopangaea: two billion years ofquasiintegrity and an appraisal of geological evidence, International Geology Review, 57:11-12, 13891417 Pisarevsky, S.A., Biswal, T.K., Wang, X.-C., De Waele, B., Ernst, R., Söderlund, U., Tait,J.A., Ratre, K., Singh, Y.K., Cleve, M., 2013. Palaeomagnetic, geochronologicaland geochemical study of Mesoproterozoic Lakhna Dykes in the Bastar Cra-ton, India: Implications for the Mesoproterozoic supercontinent. Lithos 174,125–143. Pisarevsky, S.A., Elming, S-Å., Pesonen, L.J., Li, Z-X., 2014a. Mesoproterozoic paleogeography: Supercontinent and beyond. Precambrian Research 244, 207 – 225. Pisarevsky, S.A., Murphy, J.B., Cawood, P.A., Collins, A.S., 2008. Late Neoproterozoic and Early Cambrian paleogeography: models and problems. In: Pankhurst, et al. (Ed.), West Gondwana: PreCenozoic Correlations Across the South Atlantic Region: Geological Society of London Special Publication, 294, 9-31. Pisarevsky, S.A., Wingate, M.T.D., Li, Z-X, Wang, X-C, Tohver, E. Kirkland, C.L., 2014b. Age and paleomagnetism of the 1210 Ma Gnowangerup–Fraser dyke swarm, Western Australia, and implications for late Mesoproterozoic paleogeography. Precambrain Researh 246, 1-15. Pokki, J., Kohonen, J., Lahtinen, R., Rämö, O.T., Andersen, T., 2013. Petrology and provenance of the Mesoproterozoic Satakunta formation, SW Finland. Geological Survey of Finland Report of Investigation 204, 61pp. Popov, V., Iosifidi, A., Khramov, A., 2002. Paleomagnetism of Upper Vendian sedi-ments from the Winter Coast, White Sea Region, Russia: Implications for thepaleogeography of Baltica during Neoproterozoic times. J. Geophys. Res., 107, http://dx.doi.org/10.1029/2001JB001607 60 Popov, V.V., Khramov, A.N., Bachtadse, V., 2005. Palaeomagnetism, magnetic stratigraphy, and petromagnetism of the Upper Vendian sedimentary rocks in the sections of the Zolotitsa River and in the Verkhotina Hole, Winter Coast of the White Sea, Russia. Russian Journal of Earth Sciences 7, 129. Preeden, U., Mertanen, S., Elminen, T., Plado, J., 2009. Secondary magnetizations in shear and fault zones in southern Finland. Tectonophysics, 479(3-4), 203-213. Puffer, J.H., 2002. A late Neoproterozoic eastern Laurentian superplume: location, size, chemical composition, and environmental impact. Am. J. Sci. 302, 1–27. Rainbird, R.H, Stern, R.A., Khudoley, A.K., Kropachev, A.P., Heman, L.M., Sukhorukov, V.I., 1998. U-Pb geochronology of Riphean sandstone and gabbro from southeast Siberia and its bearing on the Laurentia-Siberia connection. Earth and Planetary Science Letters, 164, 409 – 420. Raiskila, S., Salminen, J., Elbra, T., Pesonen, L.J., 2011. Rock magnetic and paleomagnetic study of the Keurusselkä impact structure, central Finland. Meteoritics and Planetary Science 46, 1670 – 1687. Rasmussen, B., Fletcher, I.R., Bekker, A., Muhling, J.R., Gregory, C.J., Thorne, A.M., 2012. Deposition of 1.88-billion-year-old iron formations as a consequence of rapid crustal growth. Nature 484, 498 – 501. Reddy, S.M., Evans, D.A.D., 2009. Palaeoproterozoic supercontinents and global evolution: correlations from core to atmosphere. In: Reddy, S.M., Mazumder, R., Evand, D.A.D., Collins, A.S. (Eds). Palaeoproterozoic Supercontinents and Global Evolution. Geological Society Special Publication 323, 1 – 26. Roberts N.M.W., 2013. The boring billion? – Lid tectonics, continental growth and environmental change associated with the Columbia supercontinent. Geoscience Frontiers 4, 681-691. Rogers, J.J.W., 1996. A history of continents in the past three billion years. Journal of Geology 104, 91-107. Rogers, J. J. W., Santosh, M. 2004. Continents and Supercontinents. Oxford University Press, New York. Salminen, J.M., Evans, D.A.D., Trindade, R.I.F., Oliveira, E.P., Piispa, E.J., Smirnov, A.V., (submitted). Paleogeography of the Congo/São Francisco craton at 1.5 Ga: expanding the core of Nuna supercontinent. Precambrian Research Salminen, J., Mertanen, S., Evans, D.A.D., Wang, Z. 2014. Paleomagnetic and geochemical studies of the Mesoproterozoic Satakunta dyke swarms, Finland, with implications for a Northern EuropeNorth America (NENA) connection within Nuna supercontinent. Precambrian Research 244, 170191. Salminen, J., Pesonen, L.J., 2007. Paleomagnetic and rock magnetic study of the Mesoproterozoic sill, Valaam Island, Russian Karelia. Precambrian Research 159, 212-230. Schmidt, P.W., Williams, G.E., Camacho, A., Lee, J.K.W., 2006. Assembly of Proterozoic Australia: implications of a revised pole for the ~1070 Ma Alcurra Dyke Swarm, central Australia. Geophys. J. Int. 167, 626-634. 61 Shellnutt, J.G., MacRae, N.D., 2012. Petrogenesis of the Mesoproterozoic (1.23 Ga) Sudbury dyke swarm and its questionable relationship to plate separation. International Journal of Earth Sciences 101, 3-23. Smirnov, A.V., Tarduno, J.A., Evans, D.A.D., 2011. Evolving core conditions ca. 2 billion years ago detected by paleosecular variation, Phys. Earth planet. Inter., 187, 225–231. Smethurst, M. A., Khramov, A. N., Pisarevsky, S. 1998. Palaeomagnetism of the Lower Ordovician Orthoceras Limestone, St. Petersburg, and a revised drift history for Baltica in the early Palaeozoic. Geophysical Journal International 133, 44 – 56. Suominen, V. 1991. The Chronostratigraphy of South-Western Finland with Special Reference to Postjotnian and Subjotnian Diabases. Geological Survey of Finland Bulletin, 356, 100 pp. Swanson-Hysell, N.L., Vaughan, A.A., Mustain, M.R., Asp, K.E., 2014. Confirmation of progressive plate motion during the Midcontinent Rift’s early magmatic stage from the Olser Volcanic Group, Ontario, Canada. Geochemistry, Geophysics, Geosystems 15, 2039 – 2047. Söderlund, U., Isachsen, C.E., Bylund, G., Heaman, L.M., Patchett, J., Vervoort, J.D., Andersson, U.B., 2005. UePb baddeleyite ages and Hf, Nd isotope chemistry constraining repeated mafic magmatism in the Fennoscandian Shield from 1.6 to 0.9 Ga. Contributions to Mineralogy and Petrology 150, 174 - 194. Söderlund, U., Hofmann, A., Klausen, M.B., Olsson, J.R., Ernst, R.E., Persson, P.O., 2010. Towards a complete magmatic barcode for the Zimbabwe craton: Baddeleyite U-Pb dating of regional dolerite dyke swarms and sill complexes. Precambrian Research 183, 388 – 398. Tan, X., Kodama, K.P., 2003. An analytical solution for correcting paleomagnetic inclination error. Geophysical Journal International 152, 228-236. Tan, X., Kodama, K.P., Gilder, S., Courtillot, V., 2007. Rock magnetic evidence for inclination shallowing in the Passaic Formation red beds from the Newark basin and a systematic bias of the Late Triassic apparent polar wander path of North America, Earth and planetary. Science Letters 254, 345357. Tanczyk, E.I., Lapointe, P., Morris, W.A., Schmidt, P.W., 1987. A paleomagnetic study of the layered mafic intrusion at Sept-Ȋles, Quebec. Canadian Journal of Earth Sciences 24, 1431-1438. Tauxe, L., Herbert, T., Shackleton, N.J., Kok, Y.S., 1996. Astronomical calibration of the MatuyamaBrunhes boundary: Consequences for magnetic remanence acquisition in marine carbonates and the Asian loess sequences. Eart and Planetary Science Letters 140, 133 – 146. Tauxe, L., Kent, D.V., 1984. Properties of a detrital remanence carried by haematite from study of modern river depostis and laboratory redeposition sediments. Geophysical Journal of the Royal Astronomical Society 76, 543-561. Tauxe, L., Kent, D.V., 2004. A simplified statistical model for the geomagnetic field and the detection of shallow bias in paleomagnetic inlinations: Was the ancient magnetic field dipolar? In: Channell, J.E.T. (Ed.) ‘Timescales of the Paleomagnetic field’, Vol. 145, American Geophysical Union, Washington, D.C., pp.101-116. 62 Tauxe L., Kodama, K.P., Kent, D.V., 2008. Testing corrections for paleomagnetic inclination error in sedimentary rocks: A comparative approach. Physics of the Earth and Planetary Interiors 169, 152165. Tohver, E., van der Pluijm, B.A., Van der Voo, R., Rizzotto, G., Scandolara, J.E., 2002. Paleogeography of the Amazon craton at 1.2 Ga: early Grenvillian collision with the Llano segment of Laurentia. Earth Planet.Sci.Letters 199, 185 - 200 Torsvik, T.H, Smethurst, M., 1999. Plate tectonic modeling: virtual reality with GMAP. Computers and Geosciences 25, 395-402. Torsvik, T.H., Van der Voo, R., Preeden, U., MacNiocaill, C., Steinberger, B., Doubrovine, P.V., Van Hinsbergen, D.J.J., Domeir. M., Gaina, C., Tohver, E., Meert, J.G., McCausland, P.J.A., Cocks, R.M., 2012. Phanerozoic polar wander, paleogeography and dynamics. Earth-Science Reviews 114, 325-368. Trompette, R., 1994. Geology of Western Gondwana (2000 – 500 Ma). A.A. Balkema, Rotterdam/Brookfield, 350 p. Tynni, R., Donner, J. 1980. A microfossil and sedimentation study of the Late Precambrian formation of Hailuoto, Finland. Geological Survey of Finland, Bulletin 311. Tynni, R. 1982. On Paleozoic microfossils on clastic dykes in the Åland Islands and in the core samples of Lumparn. Geological Survey of Finland, Bulletin 317, 35–94. Van der Voo, R., 1990. The reliability of paleomagnetic data. Tectonophysics 184, 1-9. Veikkolainen, T., Pesonen, L. J., Korhonen, K. and Evans, D. A. D. 2014a. On the low-inclination bias of the Precambrian geomagnetic field. Precambrian Research, http://doi.org/10.1016/j.precamres.2013.09.004 Veikkolainen, T. H. K., Pesonen, L. and Korhonen, K. 2014b. An analysis of geomagnetic field reversals supports the validity of the Geocentric Axial Dipole (GAD) hypothesis in the Precambrian. PrecambrianResearch, 244, 33–419. Veltheim, V. 1969. On the pre-Quarternary geology of the Bothnian Bay area in the Baltic Sea. Bulletin de la Commission Géologique de Finlande 239, 60p. Walderhaug, H. J., Torsvik, T. H., Halvorsen, E. 2007. The Egersund dykes (SW Norway): a robust Early Ediacaran (Vendian) palaemagnetic pole from Baltica. Geophysical Journal International 168, 935 – 948. Williams, G. E., 1975. Late Precambrian glacial climate and the Earth’s obliquity. Geol. Mag. 112, 441–465. Williams, G.E., 2008. Proterozoic (pre-Ediacaran) glaciation and the high obliquity, low-latitude ice, strong seasonality (HOLIST) hypothesis: Principles and tests. Earth-Science Reviews 87, 61 - 93. Williams, G. E., 1993. History of the Earth’s obliquity. Earth Sci. Rev. 34,1–-45.Zijderveld, J.D.A., 1967. Demagnetization of Rocks: Analysis of Results, in: Collinson, D.V., Kreer, K.M., Runcorn, S.K. (Eds.), Methods in Palaeomagnetism. Elsevier, New York. 63 Williams,G.E., Schmidt,P.W., Clark,D.A., 2004. Palaeomagnetism of iron-formation from the late Palaeoproterozoic Frere Formation, Earaheedy Basin, Western Australia: palaeogeographic and tectonic implications. Precambrian Research 128, 367-383. Wingate, M.T.D., Pisarevsky, S.A., Evans, D.A.D., 2002. Rodinia connections between Australia and Laurentia: no SWEAT, no AUSWUS? Terra Nova 14, 121-128. Wingate, M. T. D., Pisarevsky, S. A., Gladkochub, D. P., Donskaya, T. V.,Konstantinov, K.M.,Mazukabzov, A. M. and Stanevich, A. M. 2009. Geochronology and paleo- magnetism of mafic igneous rocks in the Olene¨k Uplift, northern Siberia: implications for Mesoproterozoic supercontinents and paleogeography. Precambrian Research, 170, 256–266. Wu, H., Zhang, S., Li, Z.X., Li, H., Dong, J. 2005. New paleomagnetic results from the Yangzhuang Formation of the Jixian System, North China, and tectonic implications. Chin. Sci. Bull. 50, 14831489. Yakubchuk, A., 2010. Restoring the supercontinent Columbia and tracing its fragments after its breakup: a new configuration and a Super-Horde hypothesis. Journal of Geodynamics 50, 166-175. Zhai, Y., Halls, H.C., Bates, M.P., 1994. Multiple episodes of dike emplacement along the northwestern margin of the Superior Province, Manitoba. J. Geophys. Res. 99, 21717-21732 Zhao, G., Sun, M., Wilde, S.A., Li, S., 2004. A Paleo-mesoproterozoic supercontinent: assembly, growth and breakup. Earth-Science Reviews 67, 91-123. Zhang, Y., 1988. Proterozoic stromatolitic micro-organisms from Hebei, North China: Cell preservation and cell division. Precambrian Research 38, 165 – 175. Zhang, H., Zhang, W., Elston, D.P., 1991. Paleomagnetic Study of Middle and Late Proterozoic Rock in Jizian North China. Chin. J. Geophys. 34, 631-646. Zhang, S., Li, Z., Wu, H., 2006. New Precambrian palaeomagnetic constraints on the position of the North China Block in Rodinia. Precambrian Research 144, 213-238. Zhang, S., Li, Z.-X., Evans, D. A. D., Wu, H., Li, H. and Dong, J. 2012. Pre-Rodinia supercontinent Nuna shaping up: a global synthesis with new paleomagnetic results from North China. Earth and Planetary Science Letters, 353–354, 145–155. Zhang, S-H., Zhao, Y., Santosh, M., 2012. Mid-Mesoproterozoic bimodal magmatic rocks in the northern North China Craton: Implications for magmatism related to breakup of the Columbia supercontinent. Precambrian Research 222-223, 339-367. Zijderveld, J.D.A., 1967. Demagnetization of Rocks: Analysis of Results, in: Collinson, D.V., Kreer, K.M., Runcorn, S.K. (Eds.), Methods in Palaeomagnetism. Elsevier, New York 64
© Copyright 2026 Paperzz