MATERIAL SAFETY DATA SHEET PRODUCT NAME: Sodium Nitrite Solution 40% SO701-40 SECTION 01: PRODUCT INFORMATION AND COMPANY INFORMATION MANUFACTURER: PREPARED BY: VERSION DATE: TELEPHONE NO.: EMERGENCY PHONE NO.: CHEMICAL FAMILY MOLECULAR WEIGHT SYNONYMS: Same as above Production Department 19-Jan-15 (519) 451-1614 (613) 996-6666 Not Available CHEMICAL FORMULA Not Applicable Not Applicable MATERIAL USE: Please Refer to technical literature SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredients Conc. Approx. % C.A.S. # 35-45 Sodium Nitrite 55-65 Water SECTION 03: HAZARD IDENTIFICATION 7632-00-0 7732-18-5 LD/50 (RTE/SPEC) N.Av. N.Av. LC/50 (RTE/SPEC) TLV N.Av. N.Av. N.Av. N.Av. ROUTE OF ENTRY Eyes: Liquid or mist contact may cause irritation. Inhalation Mist may cause irritation of respiratory tract, coughing may occour. Inhalation of large amounts of mist may cause systemic effects (see ingestion). Contact with acids may cause evolution of N2O3 which can cause severe and potentially fatal effects. Skin: Ingestion: Liquid or mist contact may cause irritation. Sodium Nitrite has been infrequently associated with kin sensitization in humans. May irritate gastrointestinal tract - larger amounts may cause poisoning. Large doses: conversion of hemoglobin to methemoglobin, producing cycanosis (blue skin); marked fall in blood pressure, leading to collapse, coma, and possibly death. SECTION 04: FIRSTAID Skin Contact: Eye Contact: Inhalation, Acute Ingestion: Flush skin with plenty of water while removing contaminated clothing. Clean clothing before reuse. Immediately flush eyes with water while holding eyelids open. If irritation persists, get medical attention. Immeciately remove to fresh air. If victim is not breathing, give artificial respiration. Get promt medical attention. If conscious give 2 to 4 glasses of water, and induce vomiting by touching finger to back of throat. Continue until vomit fluid is clear. Get immediate medical attention. If cyanosis (blue skin) develops, give oxygen, provided a qualified operator is available. Notes to physician: N.Av. Page 1 of 3 SECTION 05: FIRE EXPLOSION HAZARD AND FIRE FIGHTING MEASURES FLAMMABLE? No FLASH POINT (TCC) (C): FLAMMABLE LIMITS: AUTO IGNITION TEMPERATURE (C) EXTINGUISHING MEDIA SPECIAL PROCEDURES: Not Available IF YES, UNDER WHICH CONDITIONS? LEL(% BY VOL.): Not Available UEL(% BY VOL): Not Available Not Available Flooding amounts of water in early stages. Carbon dioxide may be used. Wear self-contained breathing apparatus and protective clothing. Not Available HAZARDOUS COMBUSTION PRODUCTS: UNUSUAL FIRE AND EXPLOSION HAZARDS If evaporated to dryness, residue is an oxidizer and can stimulate or accelerate combustion of organic or other combustible materials. Not Available SENSITIVITY TO STATIC DISCHARGE Not Available SENSITIVITY TO MECHANICAL IMPACT: SECTION 06: ACCIDENTAL RELEASE MEASURES Leak and Spill Procedure: Personel with proper protective equipment should dike and contain spill. Avoid contact with incompatible materials. Remove to containers for disposal/recovery. Foar small spills, cover with any inert absorbent and shovel into clean containers. SECTION 07: HANDLING AND STORAGE Handling Procedures and Storage Requirements Protect from physical damage. Store in a warm place, away from combustible materials and wooden floors. Keep tightly closed. Material decomposes even by weak acids with evolution of brown fumes of N2O3. It is slowly oxideized to sodium nitrate when exposed to air. May be fatal if directly ingested (the Adult leathal dose id approximately 2-5 grams). Breathing mistmay cause irritation of respiratory tract. Liquid or mist contact with skin eyes may cause irritation. Ingestion can cause irritation to gastrointestianal tract. Large doses can cause death. Do not take internally. Avoid breathing mist. Use with Adequate ventilation. Avoiud contact with eyes, skin and clothing. Wash throughly after handling. SECTION 08: PERSONAL PROTECTIVE EQUIPMENT / EXPOSURE CONTROLS GLOVES/TYPE: Impervious chemical resistant gloves. EYE/TYPE: Chemical splash goggles. RESPIRATOR/TYPE: OTHER/TYPE: ENGINEERING CONTROL A NIOSH/MSHA respirator for dust or mist - or nitrogen oxide gases - as a pplicable. Some expousers may requier a NIOSH approved, self contained breathing apparatus or an air supplied respirator. For prolunged or repeated contact, wear full, imperivous clothing. Provide eye wash fountaiin and safety shower. Not Available SECTION 09: PHYSICAL AND CHEMICAL PROPERTIE PHYSICAL STATE/APPEARANCE: ODOUR: Liquid Not Available ODOUR THRESHOLD: N. Av. N. Av. SPECIFIC GRAVITY: 1.3 VAPOUR PRESSURE (mm Hg @ 20C): 17 EVAPORATION RATE (Ether = 1): BOILING POINT (C): Ph (% SOLUTION): SOLUBILITY IN WATER (% W/W) N. Av. VAPOUR DENSITY (Air=1): FREEZING POINT (C) >1 % VOLATILE (WT): 100% SECTION 10: STABILITY AND REACTIVITY CHEMICALLY STABLE? Yes IF NO, UNDER WHICH CONDITIONS? INCOMPATIBILITY WITH OTHER SUBTANCES Yes IF YES, WITH WHICH ONES: Reducing agents, e.g. Cyanides, thiocyanates, thiosulfates, ammonium salts, cause vigorous reactions, somethimes explosive. Some combustibles and organics and waterreactive substances, such as oleum, cause exothermic reactions. See Handling and Page 2 of 3 Storage. SPECIAL REACTIVITY AND UNDER WHAT CONDITIONS Heat sepecially heating to dryness, increases the pobability and the nazard of oxidizing reactions. HAZARDOUS DECOMPOSITION PRODUCTS: If evaporated, the residue is a dangerous fire risk when heated to 1,000 F and may explode. This residue is alsolikely to yeild on heating, toxic brown fumes or nitrogen oxides. These are corrosive and oxidizing. SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL LC 50 OF MATERIAL, SPECIES AND ROUTE 71mg/kg Oral Man LD 50 OF MATERIAL, SPECIES AND ROUTE 321 mg/kg Man CARCINOGENICITY OF MATERIAL REPRODUCTIVE EFFECTS: IRRITANCY OF MATERIAL SENSITIZING CAPABILITY OF MATERIAL SYNERGISTIC MATERIALS SECTION 12: ECOLOGICAL INFORMATION AQUATIC TOXICITY SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL: SECTION 14: TRANSPORT INFORMATION TDG CLASSIFICATION Class 5.1(6.1), Sodium Nitrite Solution 1500 UN NUMBER: PACKING GROUP: II Special Provisions for Transport SECTION 15: REGULATORY INFORMATION WHMIS CLASSIFICATION SECTION 16: OTHER INFORMATION ABBREVIATIONS USED: N.Av. = Not Available N.App. / N.Ap. = Not Applicable DISCLAIMER: SOURCES: Although the information herein is to the best of our knowledge accurate, no guarantee expressed or implied, is made regarding the information or the performance of any product. We assume no liability for incidental or direct damages of any kind, no matter what, including negligence. Supplier MSDS For updated copies of an MSDS, please contact Anchem Sales at the address/phone number on Page 1 or fax the MSDS Co-ordinator at (519) 451-4593. LAST PAGE Form 074 Revised Aug 2016 Page 3 of 3
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