EUROGRANITES 2005— Proterozoic and Archean Granites and Related Rocks of the Finnish Precambrian O.T. Rämö, J. Halla, M. Nironen, L.S. Lauri, M.I. Kurhila, A. Käpyaho, P. Sorjonen-Ward, O. Äikäs 1 ISSN 1795-8946 ISBN 952-10-2603-0 paperback ISBN 952-10-2604-9 pdf Addresses: O.T. Rämö, L.S. Lauri, M.I. Kurhila: Department of Geology, P.O. Box 64, FI-00014 University of Helsinki, Finland J. Halla: Geological Museum, Arppeanum, P.O. Box 11, FI-00014 University of Helsinki, Finland M. Nironen, A. Käpyaho: Geological Survey of Finland, P.O. Box 96, FI-02151 Espoo, Finland P. Sorjonen-Ward, O. Äikäs: Geological Survey of Finland, P.O. Box 1237, FI-70211 Kuopio, Finland This publication should be referred to as: Rämö, O.T., Halla, J., Nironen, M., Lauri, L.S., Kurhila, M.I., Käpyaho, A., Sorjonen-Ward, P., Äikäs, O., 2005. EUROGRANITES 2005— Proterozoic and Archean Granites and Related Rocks of the Finnish Precambrian. Eurogranites 2005 Field Conference, September 11–17, 2005. Publications of the Department of Geology A1, 130 p. Layout and technical editing: Laura S. Lauri Printed by: Gummerus Kirjapaino Oy, Saarijärvi 2005 Cover photo: the lateorogenic (~1.80 Ga) Puruvesi granite in Puruvesi, southeastern Finland Photo: O. Tapani Rämö (Geological Survey of Finland) (Geological Survey of Finland) Back cover photo: Jukka Lehtinen 2 3 4 Foreword Didier (1971–1975), L. Lameyre (1976–1980), and B. Bonin (since 1981). Most of the past Eurogranites Precambrian granitoids and related rocks have been at the focus only sporadically, the last time in southern Norway in 1996. We are now more than pleased to have the opportunity to take the Eurogranites to the heart of the Fennoscandian shield of northern Europe to examine a wide variety of Proterozoic and Archean granites and related rocks. an overview of the lithology and evolution of the Fennoscandian shield, with special emphasis on the synorogenic, postorogenic, and anorogenic granitoid and related rocks of southern and central Finland. of Helsinki and the Geological Survey of Finland. It will run for six days (September 12–17, 2005), examining a total of 22 lithological targets in (1) the classic mid-Proterozoic rapakivi granite region of southeastern Finland; (2) the synorogenic, lateorogenic, and postorogenic granitoid realms of the Paleoproterozoic Svecofennian orogen; and (3) the Karelian craton hosting Meso- and Neoarchean TTG’s, sanukitoids, and related rocks as well as early Paleoproterozoic A-type granites in east-central Finland. No formal technical sessions are arranged, but a pre-conference seminar will be given on September 11, delegates. With great pleasure, we welcome Eurogranites to Finland. We are pleased to have the opportunity to arrange this meeting and sincerely hope that your visit will be rewarding. O. Tapani Rämö Jaana Halla Mikko Nironen Laura S. Lauri Matti I. Kurhila Asko Käpyaho Peter Sorjonen-Ward Olli Äikäs 5 6 Table of contents Foreword ..................................................................................................................................................... 7 Table of contents ......................................................................................................................................... 9 PART I: GENERAL .................................................................................................................................. 13 ....................................................................................................... 15 2. The Finnish Precambrian in a nutshell.................................................................................................. 16 2.1. The Archean domain ....................................................................................................................... 17 2.2. The Svecofennian domain .............................................................................................................. 17 2.3. Younger units .................................................................................................................................. 17 3. Finnish granitoids through time ............................................................................................................ 19 3.1. Archean TTGs ................................................................................................................................. 19 3.1.1. Introduction ......................................................................................................................... 19 3.1.2. Occurrence and geochemistry of selected TTG suites in Finland ....................................... 21 3.1.3. Concluding remarks ............................................................................................................. 24 3.2. Neoarchean sanukitoids (2.74–2.70 Ga) ......................................................................................... 24 3.2.1. Introduction ......................................................................................................................... 24 3.2.2. Distribution and age............................................................................................................. 24 3.2.3. Geochemistry ....................................................................................................................... 27 3.2.4. Petrogenetic remarks ........................................................................................................... 28 3.3. Neoarchean leucogranites ............................................................................................................... 29 3.3.1. Introduction ......................................................................................................................... 29 3.3.2. Key localities of Neoarchean leucogranite in the Finnish Archean..................................... 29 3.3.3. U–Pb ages ............................................................................................................................ 29 3.3.4. Geochemical constraints on origin ...................................................................................... 30 3.3.5. Concluding remarks ............................................................................................................. 32 3.4. Early Paleoproterozoic anorogenic granites ................................................................................... 33 3.4.1. Introduction ......................................................................................................................... 33 3.4.2. Description of the ~2.44-Ga silicic intrusions ..................................................................... 33 3.4.3. Elemental geochemistry ...................................................................................................... 35 3.4.4. Nd isotopes .......................................................................................................................... 37 3.4.5. Concluding remarks ............................................................................................................. 37 3.5. Intermediate magmatism at the craton margin, central Finland ..................................................... 38 3.5.1. Introduction ......................................................................................................................... 38 3.5.2. Field geology and petrography ............................................................................................ 38 3.5.3. Geochemistry ....................................................................................................................... 40 3.5.4. Concluding remarks ............................................................................................................. 40 3.6. Proterozoic synorogenic granitoids ................................................................................................ 41 3.6.1. Distribution and age............................................................................................................. 41 3.6.2. General mode of occurrence ................................................................................................ 41 3.6.3. Geochemical constraints on origin ...................................................................................... 43 3.7. Proterozoic lateorogenic granites ................................................................................................... 45 3.7.1. Introduction ......................................................................................................................... 45 3.7.2. Geochemical features .......................................................................................................... 45 3.7.3. Nd isotopes .......................................................................................................................... 46 3.7.4. U–Pb ages ............................................................................................................................ 48 3.7.5. Sources and origin of the lateorogenic granites................................................................... 48 3.8. Postorogenic intrusions................................................................................................................... 49 3.8.1. Mode of occurrence ............................................................................................................. 49 3.8.2. Geochemical constraints on origin ...................................................................................... 50 7 3.9. Rapakivi granites ............................................................................................................................ 51 .................. 51 3.9.2. Distribution and age............................................................................................................. 51 3.9.3. Petrology .............................................................................................................................. 52 4. Tectonic evolution: the granitoid perspective ....................................................................................... 56 4.1. Introduction .................................................................................................................................... 56 4.2. Archean ........................................................................................................................................... 58 4.3. Proterozoic ...................................................................................................................................... 59 4.3.1. Rifting of the Archean craton .............................................................................................. 59 4.3.2. Proterozoic orogenic granitoids ........................................................................................... 60 PART II: FIELD TRIP STOP DESCRIPTIONS....................................................................................... 65 DAY 1 (Monday September 12, 2005) ..................................................................................................... 67 Stop 1/1: Topaz-bearing alkali feldspar granite and associated marginal pegmatite ............................. 67 Stop 1/2: Wiborgite at Summa, Vehkalahti, south-central part of the Wiborg batholith ....................... 69 Stop 1/3: Pyterlite at Virolahti, south-central part of the Wiborg batholith ........................................... 69 Stop 1/4: Anorthositic raft in wiborgite at Ylijärvi, Ylämaa, east-central part of the Wiborg batholith ............................................................................................................................................. 70 DAY 2 (Tuesday September 13, 2005) ..................................................................................................... 73 Stop 2/1: Keittomäki lateorogenic granite, Juva ................................................................................... 73 Stop 2/2: The marginal type of the Puruvesi granite, Herttuansaari, Kerimäki..................................... 73 Stop 2/3: The central type of the Puruvesi granite, Rastiniemi, Kesälahti ............................................ 74 Stop 2/4: The Valkamo layered granite, Imatra ..................................................................................... 76 Stop 2/5: The Eräjärvi postorogenic granite dike, Ruokolahti .............................................................. 77 DAY 3 (Wednesday September 14, 2005) ................................................................................................ 79 Stop 3/1: Type 2 Puula pluton at Sokkasenmäki ................................................................................... 79 Stop 3/2: Synkinematic granodiorite at Kollinkangas ........................................................................... 79 Stop 3/3: Type 3 Jämsä pluton, margin.................................................................................................. 80 Stop 3/4: Type 3 Jämsä pluton, center ................................................................................................... 81 Stop 3/5: Type 3 Jämsä pluton, evolved center ..................................................................................... 81 DAY 4 (Thursday September 15, 2005) ................................................................................................... 83 Stop 4/1: Microtonalite dikes at Kivennapa .......................................................................................... 83 Stop 4/2: The Pisa augen gneisses— Paleoproterozoic deformation of K-feldspar megacrystic Neoarchean sanukitoids .................................................................................................................... 84 Stop 4/3: Neoarchean sanukitoids of the Lieksa complex in the Ilomantsi terrain ............................... 88 DAY 5 (Friday September 16, 2005) ........................................................................................................ 91 Stop 5/1: Arola leucogranite .................................................................................................................. 91 Stop 5/2: Arola granodiorite .................................................................................................................. 91 Stop 5/3: Kuusamonkylä tonalitic gneiss .............................................................................................. 92 Stop 5/4: ~2.43-Ga A-type granite at Tuliniemet .................................................................................. 93 Stop 5/5: Kaihlankylä migmatite ........................................................................................................... 93 DAY 6 (Saturday September 17, 2005) .................................................................................................... 95 PART III: ACKNOWLEDGMENTS AND REFERENCES .................................................................... 97 ACKNOWLEDGMENTS ........................................................................................................................ 99 REFERENCES ....................................................................................................................................... 101 PART IV: APPENDIX ............................................................................................................................ 113 Field trip stop coordinates ....................................................................................................................... 115 8 PART V: NOTES .................................................................................................................................... 117 Day 1 ....................................................................................................................................................... 119 Day 2 ....................................................................................................................................................... 121 Day 3 ....................................................................................................................................................... 123 Day 4 ....................................................................................................................................................... 125 Day 5 ....................................................................................................................................................... 127 Day 6 ....................................................................................................................................................... 129 9 10 PART I: GENERAL 11 12 (O.T. Rämö) The Fennoscandian (or Baltic) shield of Finland, Sweden, Norway, and northwestern Russia (Fig. 1) has been at the focus of active petrological research since the late 19th century and is one of the bestknown Precambrian shield areas in the world (e.g., Sederholm, 1932; Rankama, 1963; Gorbatschev, 1993; Vaasjoki et al., 2005). The glacially polished bedrock of the shield has provided ample sample material for petrological and geochemical studies. Since the pioneering works of J.J. Sederholm (Director of the Geological Survey of Finland 1892– 1933) and Pentti Eskola (Professor of Geology and Mineralogy of the University of Helsinki 1924– 1953), the knowledge of the Precambrian bedrock of Finland has evolved into a remarkably detailed picture of Paleoproterozoic, and also Archean, crust (e.g., Korsman et al., 1997, 1999; Lehtinen et al., 2005). Granitoid rocks are important constituents of the Fennoscandian shield, and form more than half of the Finnish bedrock. The Proterozoic granites of Ga), lateorogenic (~1.83 Ga), and postorogenic Regarding Archean granitoids of east-central and northeastern Finland, much still needs to be done in order to reach the level of knowledge currently available for the Proterozoic granitoid rocks. New data are, however, continuously emerging and these will form the essence of the Archean targets that nalite–trondhjemite–granodiorite (TTG) associations and sanukitoid suites as well as Neoarchean leucogranites. The classic mid-Proterozoic rapakivi granites of southern Finland have been the subject of active research since the late 19th century (Sederholm, 1891), and during the last thirty years in particular (see, e.g., Rämö and Haapala, 1995, 1996; Haapala et al., 2005). Extensive mineralogical, geochemical, geochronological, and geophysical data are rocks and they have allowed a comprehensive assessment of the petrogenesis of these rocks. Many details regarding the interplay of crustal accretion and granitoid magmatism in this part of the shield are, however, still open and will be addressed dur- as synkinematic, latekinematic, and postkinematic according to their relation to tectonic movements during the Svecofennian (or Svecokarelian) orogeny. Sederholm (1932) suggested a four-fold division, with the two earlier granitoid suites (Group I and Group II) corresponding to Eskola’s synkinematic and latekinematic granites; Group III consisting of small discordant plutons, and the rapakivi granites comprising Group IV. Simonen The principal aim of Eurogranites 2005 in Finland is to bring together an enthusiastic group of colleagues to examine and discuss the origin and rocks along a circa 1500-km-long traverse (see inside covers) from the south coast (Helsinki area) to east-central Finland (Kuhmo-Suomussalmi area). postorogenic and considered the rapakivi granites as anorogenic. A remarkably comprehensive U–Pb zircon data base (e.g., Vaasjoki , 1996) has constrained the ages of the Proterozoic synorogenic plutonic rocks at 1.93–1.87 Ga, lateorogenic at 1.84–1.82 Ga, postorogenic at 1.81–1.79 Ga, and rapakivi granites at 1.65–1.54 Ga (Vaasjoki, 1996). Syn-, late-, and postorogenic may still be used as age groups in the Finnish Svecofennian although these terms cannot be applied to the whole Svecofennian orogen because of overlapping ages (e.g., Nironen, 1997). The current division (Nironen, 2005) divides the Finnish Proterozoic orogenic granitoid rocks into four groups: preorogenic (~1.93 Ga), synorogenic (~1.88 der, (1) the classic ~1.64-Ga rapakivi granites and syn-, late-, and postorogenic granites of the ~1.9Ga Svecofennian orogen; and (3) the K-feldspar megacrystic sanukitoids (high-Mg granitoids), TTG suites, and A-type granites of the late Archean Karelian craton. All of the latest data from geochronologic, isotope geological, geochemical, petrological, and regional tectonic studies will be available for discussion, with a particular focus on comparisons and contrasts with Phanerozoic granitoid-forming processes. 13 2. The Finnish Precambrian in a nutshell (L.S. Lauri, M. Nironen, O.T. Rämö) Norway. Most of the Proterozoic rocks in Finland and Sweden were formed between 1.89–1.82 Ga. The crustal processes that caused this magmatism have traditionally been ascribed to the Svecofen- The Fennoscandian shield (Fig. 1) is one of the largest Precambrian shield areas in the world. It forms the northernmost part of the Precambrian East European craton that is mostly covered by Paleozoic sedimentary rocks. The shield consists of both Archean and Proterozoic rocks. Archean rocks are exposed in northwestern Russia, eastern and northern Finland, and northern Sweden. They form the Archean domain that consists of three Meso- to Neoarchean terrains, the Kola province, the Belomorian province, and the Karelian province. Juvenile Proterozoic rocks form the bedrock of central and southern Finland, Sweden, and southern the Svecofennian domain (Gaál and Gorbatschev, 1987). Younger Proterozoic rocks in the shield comprise the 1.85–1.67-Ga Transscandinavian igneous belt and the 1.75–1.50-Ga Southwest Scandinavian domain in Sweden and Norway. The northwestern margin of the shield is buried beneath and tectonically interleaved with the Early to Middle Paleozoic Caledonides. Fig. 1. Geology and major structural units of the Fennoscandian shield. PAC— Primitive arc complex; WAC— Arc complex of western Finland; SAC— Arc complex of southern Finland; CFGC— Central Finland granitoid complex; CLGC— Central Lapland granite complex; LGB— Lapland granulite belt. Right-diagonal ruling marks the northern edge of platform sediments. 14 2.1. The Archean domain Archean rocks underlie the Proterozoic supracrustal rocks, the Central Lapland granite complex (CLGC), and the Lapland granulite belt (LGB) that form the bedrock in northern and eastern Finland (Fig. 1). The oldest Proterozoic rocks within the Archean The Archean domain comprises extensive tonalite– trondhjemite–granodiorite (TTG) areas, remnants of granite–greenstone complexes, and Proterozoic rocks that have deposited on or intruded into the Archean crust. Archean rocks crop out in the northeastern half of Finland, northeast of the line connecting the tip of the Gulf of Bothnia and the Lake Ladoga in Russia (Fig. 1). The largest continuous Archean areas are found in the central and eastern parts of the country but smaller, scattered occurrences are present also in the northern parts. The ages of the Archean rocks in Finland range from rare occurrences of >3.0 Ga old rocks (e.g., the 3.5-Ga Siurua gneiss— the oldest rock so far found in Europe; Mutanen and Huhma, 2003) to the major population of ~2.9 Ga to 2.7 Ga old rocks (e.g., Vaasjoki et al., 1999, and references therein). in north-central Finland (e.g., Alapieti et al., 1990). The supracrustal belts that have been deposited on the Archean craton range in age from ~2.4 Ga to 1.9 Ga and contain both volcanic and sedimentary sequences (e.g., Lehtonen et al., 1998; Vaasjoki, 2001; Kohonen and Marmo, 1992; Kohonen, 1995). The central Lapland granites and the granulite belt are the result of continent–continent collision between the Karelian province and the Kola province at ~1.9–1.8 Ga (Daly et al., 2001). 2.2. The Svecofennian domain The main feature in the Svecofennian domain is the large (40,000 km2) Central Finland granitoid complex (CFGC) that is surrounded by volcanic– sedimentary belts (Fig. 1). The 1.92-Ga primitive island arc rocks in central Finland, between the Archean craton and the Central Finland granitoid complex, are the oldest documented rocks in the Svecofennian domain of Finland. However, isotope geological data suggest that older (~2.1–2.0 Ga) rocks may have formed the nucleus of the complex (Lahtinen and Huhma, 1997; Rämö et al., 2001a). Metagraywacke-dominated sedimentary rocks and island arc-type volcanic rocks (1.90– 1.87 Ga), intruded by calc-alkaline granitoids, comprise the schist belts in central and western Finland whereas metapelite-dominated sedimentary rocks, quartzites, and carbonate rocks characterize the supracrustal rocks of southern Finland. The mainly felsic to intermediate plutonic rocks of the Central Finland granitoid complex and adjacent supracrustal belts have yielded ages in the range of 1.89–1.87 Ga (Vaasjoki, 1996). Migmatites with tonalite leucosome were formed from immature psammites 1.89–1.88 Ga ago, whereas younger migmatization, associated with S-type granites, took place at ~1.84–1.82 Ga in southern Finland and formed the Late Svecofennian granite–migmatite zone (Korsman et al., 1999). There are indications that the Svecofennian bedrock grew by sequential accretion of arcs and probably includes several collision zones and remnants of marine basins (Lahtinen, 1994; Nironen, 1997). The present concept (Korsman et al., 1997) is that the Finnish Svecofennian consists of three arc complexes (Fig. 1): (1) the Primitive arc complex (PAC); (2) the Arc complex of western Finland (WAC); and (3) the Arc complex of southern Finland (SAC). 2.3. Younger units The youngest major rock units in the Finnish bedrock are the mid-Proterozoic rapakivi granites that comprise four large batholiths and several smaller batholiths or stocks, as shown in Fig. 2. The U–Pb zircon ages of the rapakivi granites of Finland range from 1.65 Ga to 1.54 Ga (Vaasjoki, 1977; Vaasjoki et al., 1991; Suominen, 1991). The intrusions cut sharply across the Svecofennian medium- to high-grade 15 Fig. 2. Geological sketch map of southern Finland and vicinity showing the distribution of various Precambrian lithologic units for dolerite dikes that cut sandstones in a fault-bounded basin in the Satakunta area (Fig. 3A). However, in the clastic sequence in the Lake Ladoga basin of Russian Karelia (Fig. 3B) a monzodioritic sill has been dated at 1457 ± 3 Ma (Rämö et al., 2001b). These two chronologic piercing points yield maximum (~1.46 Ga) and minimum (~1.26 Ga) ages for the duration of post-rapakivi basin sedimentation. Small-scale igneous activity occurred in northern Finland at ~1.1–1.0 Ga when several diabase dikes were emplaced in the Salla and Laanila areas (Lauerma, 1987; Pihlaja, 1987). The ~400-Ma Caledonian domain also extends to the northwesternmost tip of Finland (Fig. 1). The Caledonian area in Finland, although very small, contains the highest point of the country (Halti, 1328 m a.s.l.). The present erosional level of the Fennoscandian shield was attained already in the Neoproterozoic times. The shield was covered by sedimentary rocks in the Paleozoic but only a few small, scattered occurrences of Cambrian sandstones and Ordovician limestones have survived the recent glaciations that again exposed and polished the ancient bedrock of the shield. metamorphic and plutonic rocks and produce contact metamorphic aureoles (Vorma, 1972). Lithologic, structural, and textural features (e.g., sharp intrusive contacts, local presence of volcanic or subvolcanic members, roof pendants, roof breccia outcrops) suggest that the present erosion level generally represents the upper parts of epizonal intrusive complexes (Wahl, 1925, 1947; Vorma, 1975; Haapala, 1977a; Bergman, 1986). The rapakivi granite intrusions are spatially and bro–anorthosite complexes, basaltic dikes, and rare monzonitic/ferrodioritic rocks). They are also spatially intimately associated with Mesoproterozoic (Jotnian/Riphean) clastic basins of redbed-type sandmatism (gabbroic sills and dikes, basaltic lavas; Fig. 2). The time of the onset of the basin formation is not known in detail and thus the temporal relation of the rapakivi granite intrusions and basin sedimentation and basaltic magmatism is therefore unconstrained. U–Pb mineral data indicate ages in the 1268–1256 Ma range (Suominen, 1991; Söderlund et al., 2004) 16 al. (1996). 3. Finnish granitoids through time 3.1. Archean TTGs (A. Käpyaho, L.S. Lauri) 3.1.1. Introduction models were put forward by Martin (1987a), who concluded that the TTGs of the Kuhmo district, eastern Finland, were formed by partial melting of Archean tholeiites and that garnet and hornblende were necessary residual minerals. The genesis of TTG magmas has also been attributed to melting of The oldest known felsic crustal rocks in Finland are mainly members of the tonalite–trondhjemite– granodiorite (TTG) association. In general, these rocks provide one of the most informative data sources of the early Earth. The oldest TTGs so far reported are the ~4.0-Ga Acasta gneisses from the Slave craton, Canada (Bowring and Williams, 1999). Early Archean (>3.5 Ga) TTGs are also known from, e.g., Greenland (Nutman et al., 1996), South Africa (Kröner et al., 1996), the United States (Mueller at al., 1996), and Finland (Mutanen and Huhma, 2003). The petrogenesis of the TTGs is controversial and has received considerable attention in recent years. Experimental petrology has shown that the Archean TTGs may be produced by partial melting of partially hydrated metabasalts, leaving a garnetbearing residue (Rapp and Watson, 1995). Similar (Kröner, 1985; Condie, 2005). Foley et al. (2002) confronted this view on the basis of amphibole trace element systematics and pointed out that the Nb/Ta and Zr/Sm ratios in the Archean TTGs are inconsistent with an eclogite residue. However, experimental evidence shown by Rapp et al. (2003) indicate that eglocite residue may be stable with melts resembling the TTGs. Martin (1999) noted that modern adakites and Archean TTGs are remarkably similar in geochemistry and thus could have been produced in a similar 17 Some locations mentioned in the text are denoted. The Kuhmo greenstone belt is shown in black. Sanukitoid zones (see Section 3.2) are marked with dotted lines: K— Kuusamo (Halla, in prep.); N— Nilsiä (Halla, 2005); ESZ and WSZ— eastern and west- manner. Modern adakites are found in a subduction setting where a young and hot oceanic slab melts, and the melt is further contaminated with mantle wedge material (Kay, 1978). However, high Mg# and elevated Ni and Cr contents that would be expected in these melts owing to interaction with mantle wedge are seldom observed in the Archean TTGs (cf. Smithies, 2000). The ongoing debate on the origin of the TTGs (cf. Rollinson and Martin, 2005) certainly renders these rocks a healthy ground for further elaborations. This review of Archean TTGs is far from comprehensive— our aim is to summarize some geochemical data from selected key localities in the Finnish Archean, concentrating on the Karelian province of the Fennoscandian shield. Some granodiorites, 18 tonalites, and enderbites (e.g., from Ilomantsi and Halla in Section 3.2. 3.1.2. Occurrence and geochemistry of selected TTG suites in Finland Siurua The trondhjemite gneiss from Siurua, north-central Finland, is the oldest rock unit so far recognized in the Fennoscandian shield (Mutanen and Huhma, 2003; cf. Fig. 4). It is a gneissose tonalite within a granulite-facies block in the Archean Pudasjärvi complex. The chemical composition of the Siurua trondhjemite gneiss (Table 1; Sample A1602; Mutanen and Huhma, 2003) has SiO2 and Mg# close to the average Early Archean TTG of Condie (2005) (Fig. 5). The rock is slightly peraluminous (Fig. 6) and shows strong enrichment in the LREE compared to the HREE (Fig. 7). The single grain U–Pb zircon age of the sample (3.5 Ga) is close to the (DePaolo, 1981) TDM model age (3.48 Ga) and initial εNd (at 3.5 Ga) value is +1.4 (Fig. 8) (Mutanen and Huhma, 2003). Fig. 5. SiO2 (wt.%) vs. Mg# [Mg2+/(Mg2++Fetot)*100, Fetot as Fe2+] diagram showing the composition of the Siurua tonalite gneiss (Mutanen and Huhma, 2003) and pyroxene tonalite (sample A1661) from Koillismaa (Lauri et al., 2005), and gneisses (Jahn et al., 1984). Mean values of Early and Late after Smithies (2000). Tojottamanselkä Tojottamanselkä in northern Finland is another occurrence of >3.0-Ga rocks in the Fennoscandian shield (Fig. 4). It is a small (1 km by 2 km) Archean gneiss dome within Paleoproterozoic supracrustal rocks (Puustinen, 1977) and consists of tonalitic and trondhjemitic gneisses. The Tojottamanselkä gneisses have relatively low Mg number and plot Fig. 6. SiO2 (wt.%) vs. A/CNK [molar Al2O3/ (CaO+Na2O+K2O)] diagram showing the composition of TTGs of the Karelian province. See Fig. 5 for data sources. metaluminous to peraluminous with increasing SiO2 values (Fig. 6) and show strong enrichment of the LREE compared to the HREE and commonly have a small positive Eu anomaly (Fig. 7). Singlegrain U–Pb zircon datings on the Tojottamanselkä gneisses yielded an intrusive age of 3115 ± 29 Ma (Kröner and Compston, 1990). Initial εNd values of the Tojottamanselkä gneisses are mostly negative (~ –3.5) but more radiogenic (depleted mantle-like) values are also observed (Fig. 8; Jahn et al., 1984; Hanski et al., 2001). Jahn et al. (op. cit.) suggested that the compositional variation in Tojottamanselkä implies several source components; some tonalites may represent partial melts from basaltic sources that have nearly chondritic REE compositions, whereas some (those with a distinctly negative ini- Fig. 7. Chondrite-normalized REE patterns of selected TTGs from the Karelian province compared to the mean values reported for the Early and Late Archean TTGs and adakites by Condie (2005). See Table 1 for references. Normalizing values (C1 chondrite) from Sun and McDonough (1989). 19 older crustal components similar to the Siurua or Koillismaa samples (Fig. 8). There are indications of TDM model ages in excess of 3.3 Ga from the Naavala tonalite in the Kuhmo district (Luukkonen, 2001). tial Nd) represent partial melts of older continental crustal material. Kuhmo In the Kuhmo district, eastern Finland (Fig. 4), TTGs are found as distinct, relatively homogeneous plutons and metatexitic and diatexitic migmatitic gneisses. Martin (1987a) summarized geochemical and age data on the gray TTG gneisses of Kuhmo. The ages he reported are, however, based on the Rb–Sr whole-rock method and, as indicated by Vaasjoki (1988), do not represent crystallisation ages of the plutons. Vaasjoki et al. (1999) and Luukkonen (2001) reported U–Pb zircon ages between 2.83 Ga and 2.75 Ga for tonalites in the Kuhmo district. The TTGs in Kuhmo have SiO2 between 64 wt.% and 74 wt.% and Mg number between 59 and 31 (Table 1; Fig. 5). They are mostly peraluminous, samples with the lowest SiO2 tend to be metaluminous (Fig. 6). The REE patterns of the rocks from Kuhmo resemble average adakite, and show moderate enrichment of the LREE relative to the HREE (Fig. 7), thus implying garnet-bearing residue. The 2.83 Ga and 2.75 Ga tonalitic gneisses analysed from the Kuhmo district indicate no contribution of Koillismaa TTGs form a large part of the Archean bedrock in Koillismaa, eastern Finland (Fig. 4). They are variably deformed granitoids and gneisses in which the metamorphic grade extends up to granulite facies (Lauri et al., 2005). A granulite-facies pyroxene tonalite from Koillismaa (Table 1; sample A1661; Lauri et al., 2005) plots on the border of adakite 0.93, corresponding to the samples from Kuhmo that have similar SiO2 values (Fig. 6). TTGs in Koillismaa are enriched in the LREE with (La/Yb)N of 54 (Fig. 7). Conventional U–Pb zircon analyses yielded an age of 2808 ± 20 Ma for the sample A1661 (Lauri et al., 2005). The ~2.8-Ga TTGs from Koillismaa have initial Nd values from –1.9 to –0.8 bution from an older crustal component (Fig. 8). A sample of migmatite paleosome from the Kuhmo Fig. 8. εNd vs. age diagram for the TTGs from the Karelian province. Key to references: 1— Mutanen and Huhma (2003); 2— Käpyaho et al. (in review); 3— Luukkonen (2001); 4— Lauri et al. (2005); 5— Hanski et al. (2001). DM (depleted mantle) evolution line is from DePaolo (1981), CHUR denotes the Chondritic Uniform Reservoir (DePaolo and Wasserburg, 1976). 20 Table 1 Selected analyses of TTGs Siurua (1) Kuusamon- Naavala (2) Kivijärvi (2) Koillismaa kylä (2) (3) Tojottamanselkä (4) Early Archean Late Archean TTG (5) TTG (5) A1602 H52 H413 H42 A1661 average (n = 7) average (n = 212) average (n = 831) SiO2 70.3 70.5 72.9 72.1 64.6 68.8 70.4 68.3 TiO2 0.45 0.37 0.20 0.15 0.71 0.48 0.31 0.42 Sample Al2O3 15.6 14.6 15.0 14.4 16.3 15.4 15.2 15.5 Fe2O3tot 2.33 2.46 1.52 1.94 4.93 3.38 2.79 3.42 MnO 0.02 0.04 0.01 0.03 0.07 0.04 0.06 0.07 MgO 0.92 1.47 0.47 0.70 1.87 0.85 0.96 1.39 CaO 3.17 2.23 2.26 2.09 4.64 3.14 2.74 3.26 Na2O 4.48 4.85 4.30 4.03 4.44 4.80 4.71 4.51 K2 O 1.83 1.81 2.72 2.82 1.66 2.10 2.22 2.20 P2O5 0.03 0.10 0.06 0.07 0.19 0.12 0.10 0.14 S < - - - 67 - - - F 600 - - - - - - - Cl 170 - - - 200 - - - Cu < - - - 30 - - - Ga 22 - - - 24 - - - Zn 52 - - - 66 - - - Cr < - - - 31 - 45 35 Ni 8 - 6 3 24 - 17 22 Co 5.6 - 4 5 - - - - V 32 - - - 73 - - - Sc 3.6 - - - 9.77 - - - Sr 311 255 320 238 516 - 362 515 Ba 503 408 740 - 830 - 500 769 Rb 57 92 89 90 41 - 76 67 Zr 294 136 108 122 270 - 152 154 Hf 6.9 - - - - - 3.8 4.7 Ta < - - - - - 0.41 0.84 Nb 5.2 - - - 3 - 6.1 6.2 Pb 32 - - - 21 - - - U 2.0 - - - 0.22 - 1.20 1.5 Th 46 - - - 5.11 - 4.10 8.1 Y 7.5 7 3 9 11.8 - 8.5 9.1 La 123.0 21.5 7.5 56.2 61.1 15.66 22 36 65 Ce 213.0 39.4 14.3 92 105.0 30.32 40 Pr 22.2 - - - 10.8 - - - Nd 75.8 13.69 - - 36.0 10.52 16 25 Sm 10.0 1.8 0.95 4.13 5.00 1.86 2.9 4.2 Eu 1.35 0.48 0.56 0.94 1.27 0.63 0.82 1.07 Gd 6.77 1.24 - - 3.88 1.46 2.2 2.9 Tb 0.59 - 0.09 0.35 0.51 - 0.31 0.38 Dy 1.90 0.73 - - 2.43 1.20 - - Ho 0.27 - - - 0.41 - - Er 0.60 0.37 - - 1.28 0.62 - - Tm < - - - 0.15 - - - Yb 0.55 0.38 0.32 0.69 0.81 0.62 0.82 0.71 Lu < 0.063 0.08 0.076 0.14 0.10 0.14 0.11 Mg# 43.9 54.2 38.0 41.7 42.9 33.20 40.8 46.2 A/CNK 1.03 1.04 1.06 1.07 0.93 0.97 1.00 0.99 References: (1) Mutanen and Huhma (2003); (2) Martin (1987a); (3) Lauri et al. (2005); (4) Jahn et al. (1984); (5) Condie (2005). Oxides in wt.%, trace elements in ppm. < below detection limit, - not analyzed. 21 jor and trace element and Nd isotope composition it seems likely that these TTGs were produced from varying sources in various geotectonic environments. Figure 5 shows that most of the TTGs in the district has a rather similar Nd (at 2.8 Ga) value and could thus represent one possible source for the Koillismaa tonalites. 3.1.3. Concluding remarks supporting the argument of Smithies (2000) that most Late Archean TTGs do not show evidence of adakite-like mantle wedge contamination (see also Section 3.2). The Karelian province of the Fennoscandian shield implies TTG emplacement between 3.5 Ga and 2.75 Ga. Because of large variation in the ma- 3.2. Neoarchean sanukitoids (2.74–2.70 Ga) (J. Halla) 3.2.1. Introduction luminous TTGs in Archean granite–greenstone terrains. Sanukitoids have been recognized from the Superior province, Canada (Shirey and Hanson, 1984, 1986; Stern et al., 1989; Stern and Hanson, 1991; Beakhouse et al., 1999; Stevenson et al., 1999), the Fennoscandian shield (Lobach-Zhuchenko et al., 2005; Kovalenko et al., 2005; Halla, 2002, 2005), the Dharwar craton, South India (Sarvothaman, 2001; Moyen et al., 2003), the Ukrainian shield (Artemenko et al., 2003), the Pilbara craton, Western Australia (Smithies and Champion, 2000), the Zimbabwe craton (Kampunzu et al., 2003), and Greenland (Steenfelt et al., 2005). The Archean Karelian craton of the Fennoscandian shield is divided into three domains with different crust-formation ages (Lobach-Zhuchenko et al., 2000a): West Karelian (~3.0 Ga), Central Karelian (~2.85 Ga), and southeastern Vodlozero (~3.0 Ga). Lobach-Zhuchenko et al. (2005) divided sanukitoids of the Karelian granite–greenstone terrain into two distinct zones of different age and composition, roughly coinciding with the domain boundaries: the western sanukitoid zone (WSZ) in the West Karelian domain and the eastern sanukitoid zone (ESZ) in the Central Karelian domain (Fig. 4). Bibikova et al. (2005) showed that the sanukitoids in the Karelian craton were formed in two narrow time intervals, at ~2705 Ma (western part) and ~2745 Ma (eastern part). Thus there is a 30-Ma age difference between the western and eastern sanukitoid zones of the Karelian craton. The time gap between TTG and sanukitoid formation is shorter in the west (60 Ma) than in the east (100 Ma). In the westernmost part of the Karelian craton in The rate of magma production and continental growth was especially rapid during the Neoarchean time. At around 2.7 Ga, large amounts of new continental crust were formed and accreted into a single supercontinent, Kenorland, or several supercratons such as Superia and Sclavia (e.g., Bleeker, 2003). One of the key factors for understanding crustal evolution 2.7 b.y. ago is the petrogenesis of sanukitoids, a series of high-Mg granitoids found in Archean terrains. Sanukitoids are narrowly restricted in time (generally 2.74–2.72 Ga) and were formed during the later stages of Neoarchean cratonization. Knowing the origin of sanukitoids is fundamental to the understanding of the genesis of late Archean cratons as they provide a link between crust formation and mantle processes. The term sanukitoid is used as a synonym for Neoarchean high-Mg granitoids referring to a series of granitoid rocks having relatively high Mg numbers and high Ni, Cr, LILE (Sr, Ba, P), and LREE abundances at any given silica content (sanukitoid nadian shield by Shirey and Hanson (1984), who introduced the term sanukitoid as the rocks resemble high-Mg andesites termed sanukites in the Setouchi area of Japan. 3.2.2. Distribution and age The oldest sanukitoids (2.95 Ga) have been found in the granite–greenstone terrain of the Pilbara craton, Western Australia (Smithies and Champion, 2000) and most of the known sanukitoids were formed at ~2.7 Ga. Sanukitoids are late- to postkinematic (e.g., Shirey and Hanson, 1984; Stern et al., 1989; Beakhouse et al., 1999) and intrude vo- series granodiorites and monzodiorites are found in the Nilsiä area of the Iisalmi terrain and in the 22 Fig. 9. Plots of selected element pairs for sanukitoids from eastern Finland (Nilsiä, Lieksa, Kuittila, Arola), the western (WSZ) and eastern (ESZ) sanukitoid zones of the Karelian craton, and the Western Superior province, Canada. Data for TTGs in Finland are plotted for comparison. References as in Table 2. 23 Table 2 Comparison of selected major and trace element analyses of Karelian sanukitoids (SiO2 62–64 wt.%) with sanukitoids from the Superior province and TTGs in Finland Nilsiä1 Lieksa2 Kuittila3 Arola4 Kurgelampi (WSZ)5 Elmus (ESZ)6 Superior7 TTG Fi8 69.60 SiO2 62.90 63.50 63.00 61.91 62.25 62.51 66.40 TiO2 0.63 0.54 0.45 - 0.77 0.32 0.47 0.38 Al2O3 16.20 16.70 16.70 15.61 15.73 15.86 15.50 15.20 Fe2O3tot 4.76 4.63 3.68 5.02 5.68 3.43 3.25 2.79 MnO 0.07 0.07 0.07 0.08 0.09 0.06 0.06 0.04 MgO 2.27 2.32 2.24 2.97 4.07 2.65 1.23 1.17 CaO 3.66 3.83 4.42 3.84 4.72 3.74 2.75 2.63 Na2O 5.06 4.52 4.54 5.24 3.92 4.52 4.75 4.45 K2O 3.41 3.23 2.37 2.72 2.36 4.52 3.83 2.23 P2O5 0.41 0.27 0.14 0.26 0.40 0.37 0.23 0.10 70 70 86 92 99 45 43.4 - V Cr 50 70 64 131 66 224 27 - Ni 30 20 25 27 24 65 23.1 11 Rb 97.6 75.7 110 70 73 122 113 83 Sr 610 840 990 893 668 1200 1020 351 Y 26.8 12.2 20 10 12 16 13.1 9 152 Zr 289 170 100 156 132 242 198 Nb 9.46 3.93 20 - 5 8 8 - Ba 1200 1730 820 1307 1074 2259 1430 700 Hf 6.7 4.24 - - 3.5 6.2 4.79 - Ta 0.45 0.20 0.30 - 0.25 0.50 0.76 - Pb 12.7 23.2 8 - 20 51 30.3 - Th 9.12 6.12 4 - 10 36 17.3 - U 0.90 0.31 - - - - 3.25 - La 66.1 47.7 21.7 55.4 36.3 111.2 78.2 34.7 Ce 135.0 90.4 46.0 107.0 73.7 223.8 153 61.4 Pr 15.5 10.5 8.18 24.7 - - Nd 54.2 38.6 18.0 44.0 35.64 93.6 52.1 17.4 Sm 8.46 6.41 3.4 7.6 6.03 12.5 7.86 2.5 Eu 1.64 1.53 1.00 1.59 1.49 3.00 1.68 0.8 Gd 6.07 4.78 - 3.57 4.08 8.90 5.13 1.74 Tb 0.74 0.6 0.30 0.40 0.53 0.80 - - Dy 2.64 2.33 - - 2.30 3.10 2.36 0.91 Ho 0.47 0.4 - - 0.44 0.50 0.43 0.39 Er 1.14 1.08 - - 1.13 1.10 1.17 Tm 0.15 0.13 - - 0.17 0.10 0.14 - Yb 1.01 0.92 0.80 0.95 0.99 0.90 0.90 0.35 Lu 0.14 0.13 0.20 0.12 0.14 0.10 - 0.06 Mg# 0.49 0.50 0.52 0.54 0.56 0.58 0.43 0.45 Fe# 0.65 0.64 0.60 0.60 0.56 0.54 0.70 0.68 A/CNK 0.87 0.93 0.92 0.84 0.89 0.83 0.91 1.05 1 Sample PK-121 (Halla, 2005) Sample PK-50 (Halla, 2005) 3 Sample P498/6.2 (O’Brien et al., 1993) 4 Sample G 214 (Querré, 1985) 5 Sample 39/1-98 (sample 36/3-98 for REE), Kurgelampi, WSZ (Lobach-Zhuchenko et al., 2005) 6 Sample 189, Elmus, ESZ (Lobach-Zhuchenko et al., 2005) 7 Average of eight samples from the Western Superior Province, Canada (Stevenson et al., 1999) 8 Average of 48 samples from eastern Finland (Martin, 1987a) - not analyzed 2 24 Ilomantsi terrain. Sanukitoids are also found in the Kuhmo–Suomussalmi granite–greenstone belt in the Kianta terrain and in the Kuusamo area in the Koillismaa terrain. Sanukitoids of the Ilomantsi terrain comprise both a lower crustal level, high metamorphic grade sanukitoid complex in the Lieksa area and smaller, upper crustal level, lower metamorphic grade sanukitoid plutons, e.g., the Kuittila pluton (O’Brien et al., 1993) in the easternmost part of the Ilomantsi terrain. The Lieksa sanukitoids consist of porphyritic K-feldspar megacrystic granodiorites and gneisses, which produce positive anomalies on the aeromagnetic maps. The rare occurrence of pyroxene and granulite-facies supracrustal enclaves together with the low U content and low radiogenic Pb isotopic composition of the granitoids imply an extensive high-grade granulite–gneiss terrain. The conventional U–Pb zircon age for the Nilsiä sanukitoids in the Iisalmi terrain is 2727 ± 34 Ga (Paavola 1984), and the age obtained for the Lieksa sanukitoids is 2733 ± 29 Ga (Halla, 2002). The Kuittila tonalites in the eastern Ilomantsi terrain have a U–Pb zircon age of 2745 ± 10 Ma (O’Brien et al., 1993; Vaasjoki et al., 1993). lected major and trace element analyses of Karelian sanukitoids (SiO2 62–64 wt.%) from eastern Finland (Nilsiä, Lieksa, Kuittila), the Western sanukitoid zone (Kurgelampi), and Eastern sanukitoid zone (Elmus) with sanukitoids from the Western Superior Province, Canada, and TTGs in Finland. between sanukitoids and TTGs. The sanukitoids in the Karelian craton are similar to the sanukitoids of the Superior Province, Canada. Their A/CNK index is lower than 1 indicating a metaluminous composition. The western sanukitoid group in Karelia comprises more homogeneous single-phase intrusions higher in SiO2 and lower in K, Na, Sr, Ba, and LREE relative to the eastern sanukitoids, whereas the latter are strongly differentiated poly-phase intrusions showing lower SiO2 contents and a more profound enrichment in K and Na compared with the western sanukitoids. These geochemical differences are attributed to different degrees of enrichment of the source regions in the mantle wedge. Figure 10 compares the REE patterns of the two granitoid groups and shows that the sanukitoids from eastern Finland (except for the Kuittila pluton) have REE patterns very similar to those of Kurgelampi (WSZ) and the Superior province, differing clearly from the Elmus (ESZ) sanukitoids with higher LREE contents and TTGs with lower HREE contents. According to Lobach-Zhuchenko et al. (2000b) and Kovalenko et al. (2005), the sanukitoid intrusions from the younger Central Karelian domain of the Karelian craton have positive initial εNd values of +0.7 to +2.1 and TDM model ages of 2.70–2.85 Ga. The intrusions from the older West Karelian 3.2.3. Geochemistry The sanukitoid series includes diorites, monzodiorites, granodiorites, monzonites, syenites, and alkaline granites. The sanukitoids from the Iisalmi and Ilomantsi terrains in eastern Finland are mainly granodiorites or monzodiorites and show similar sanukitoid-type geochemical characteristics: low SiO2 contents (62.7–67.0 wt.%), high K2O contents (2.40–4.73 wt.%), high Mg numbers (45–52), fractionated REE patterns [(La/Yb)N = 19–65)], high HREE contents relative to TTGs, negative Eu anomaly (Eu/Eu* = 0.53–0.81), and high Cr (40–80 ppm), Ba (1200–2300 ppm), Sr (610–850 ppm), and P2O5 (0.25–0.42 wt.%) contents. They show strong long-term depletion in U, high Th/U, low U/Pb, high µ values for the source (~9), positive εNd (at 2.7 Ga) values of +0.3 to +1.4, and TDM model ages (DePaolo, 1981) of 2.75–2.86 Ga. The high µ and apparently contradict the positive εNd (at 2.7 Ga) values that support a mantle origin. The enrichment of sanukitoids in Mg, Cr, and Ni suggests a peridotitic mantle-wedge source. Compared with TTGs, sanukitoids are also strongly enriched in the LREE, Ba, Sr, and P, which points to an enriched mantle source. Table 2 compares se- Fig. 10. Chondrite-normalized REE patterns for sanukitoids from eastern Finland (Nilsiä, Lieksa, Kuittila, Arola), Kurgelampi (WSZ), Elmus (ESZ), the Western Superior province, Canada, and for TTGs in Finland. See Table 2 for references. 25 domain have initial εNd values of –1.7 to +0.7 and TDM model ages of 2.80–2.92 Ga. Results from eastern Finland overlap with those of the Central and West Karelian domains and militate against a prolonged crustal prehistory (Fig. 11). On the contrary, the Pb isotope composition of sanukitoids of the Iisalmi and Ilomantsi terrains (model µ values for the source ~9) indicates a substantial crustal Pb component in the source (Halla, 2005). Similar results have been obtained from the Western Superior province (Stevenson et al., 1999). Based on Pb isotopes, Halla (2005) suggested that sediment-derived position of sanukitoids is also paradoxical: Nd, Sr, and Hf isotopes point to a mantle origin (Corfu and Stott, 1993, 1996), but Pb isotope compositions of K-feldspars point to a crustal source (Stevenson et al., 1999; Halla, 2005). The geochemical features of wedge-derived sanukitoids are explained by partial melting of a mantle-wedge source metasomatized amounts of slab-derived (TTG) melts (e.g., Smithies and Champion, 2000), or by elements mobilized processes (Kamber et al., 2002; Halla, 2005). The mechanisms that caused the enrichment and partial melting in the wedge are still unclear, as is the sig- to the mantle wedge in slab dehydration processes before melting. This conclusion is supported by a number of studies that report high δ18O in zircons in sanukitoids (e.g., King et al., 1998), also interpreted as a crustal signature. of sanukitoid series rocks. Kovalenko et al. (2005) suggested a two-stage model for the genesis of the Karelian sanukitoids. 3.2.4. Petrogenetic remarks somatized during subduction or tectonic underplating (up to 200 Ma before melting), either by sig- The somewhat paradoxical geochemical features of the sanukitoids— low SiO2, high Mg number and Mg, Ni, and Cr values— point to a mantle-wedge peridotite source, whereas enrichment in the LILE (Ba, Sr, and P) and the LREE indicate an enriched (metasomatized) mantle source. The isotope com- tion processes. In the second stage, at 2.74–2.70 Ga, a thermal event, probably related to the collision of the Belomorian mobile belt with the Karelian craton, caused melting in the previously metasomatized mantle. Kovalenko et al. (2005) presented Fig. 11. εNd vs. age diagram for the Nilsiä and Lieksa sanukitoids. Data for Central and West Karelian domains (black and white bars) from Lobach-Zhuchenko et al. (2000b) and Kovalenko et al. (2005). CHUR as in Fig. 8. 26 two alternative models for melting in the mantle wedge: (1) delamination of the lower crust that caused mantle upwelling and heating of the subcon- and slab dehydration. At ~2.73 Ga, melting in the mantle-wedge source produced high-Mg, high-K granitoid (sanukitoid) magmas with high LILE, U, Th, and Pb and radiogenic initial Pb isotope compositions. A strong U depletion event at 2.7–2.6 Ga during granulite-facies metamorphism further enriched these rocks in Th relative to U and in U relative to Pb. Halla (2005) suggested that the Nilsiä and Lieksa sanukitoids in eastern Finland originated from a mantle-wedge source enriched in the LILE, U, Th, and crust-derived Pb through sediment subduction 3.3. Neoarchean leucogranites (A. Käpyaho, L.S. Lauri) 3.3.1. Introduction One of the best-documented localities in the area is the Arola (or Pohjajärvi) quarry (Hyppönen, 1983; Martin and Querré, 1984; Querré, 1985; Käpyaho et al., in review). This two-mica leucogranite is pink, medium-grained, and slightly oriented. Main minerals are quartz, oligoclase, microcline, muscovite, and biotite, with accessory magnetite, zircon, rutile, allanite, and rare garnet. Some of the related intrusions contain magnetite crystals up to 0.5 cm in diameter, and some of the granite bodies lack muscovite. Neoarchaean leucogranites are found on all Archean cratons, yet the origin of this rock type is still far from understood. These granites have been interpreted to represent crustal melts (e.g., Sylvester, 1994), but some studies (e.g., Moyen et al., 2001) indicate that some high-K leucogranites could also a link to the high-Mg/Fe sanukitoids (see Section 3.2). A common emplacement order in most Archean cratons is that the leucogranites often postdate the much more voluminous TTG association rocks and greenstone belts (for a review, see Sylvester, 1994). In the Archean of the Fennoscandian shield, Neoarchean leucogranites are found, e.g., in northeastern Lapland (Juopperi and Vaasjoki, 2001) and in the Pudasjärvi (Mutanen and Huhma, 2003), Ilomantsi (Vaasjoki et al., 1993), Koillismaa (Lauri et al., 2005), and Kuhmo districts (Hyppönen, 1983; Martin and Querré, 1984; Martin, 1985; Querré, 1985; Käpyaho et al., in review). In this summary, we focus on the whole-rock geochemical composition, U–Pb ages, and Nd isotope characteristics of the most extensively studied leucogranite occurrences in the Kuhmo and Koillismaa districts in the Karelian province, and review the petrogenetic implications of these data. Koillismaa district The Archean part of Koillismaa forms the northernmost continuation of the Kuhmo district. The area is still relatively poorly mapped, but some leucogranite occurrences are known; these are assigned to the Harjavaara-type in the geologic map (see Räsänen et al., 2004; Lauri et al., 2005). The leucogranites are found as small bodies and dikes within the migmatitic gneisses. They are mediumto coarse-grained and commonly show evidence of deformation. Major minerals are quartz, plagioclase, microcline, biotite, and in some cases muscovite. 3.3.3. U–Pb ages The leucogranites of Kuhmo and Koillismaa have U–Pb ages on the order of 2.71 Ga to 2.68 Ga. Ion microprobe U–Pb zircon ages from the Kuhmo district vary between 2.70 and 2.68 Ga and the granites commonly contain inherited zircons (Käpyaho et al., in review). The conventional analyses from Koillismaa are rather imprecise and the most robust age determination (on the Aholamminvaara granite, sample A1656) yielded an age of 2711 ± 9 Ma (Lau- 3.3.2. Key localities of Neoarchean leucogranite in the Finnish Archean Kuhmo district Small leucogranite bodies (<1 km2) and crosscutting granite dikes are common in the Archean bedrock west of the Kuhmo greenstone belt (Fig. 4). 27 ri et al., 2005). Concordant monazite ages of ~2.69 Ga in the Koillismaa region are consistent with the ion microprobe results from Kuhmo. The zircon population is heterogeneous and the monazite may register the emplacement of the granites (Lauri et al., 2005). Similar U–Pb monazite ages have also been obtained from leucogranites in the Ilomantsi terrain (Vaasjoki et al., 1993). 3.3.4. Geochemical constraints on origin Whole-rock geochemistry Fig. 12. SiO2 (wt.%) vs. A/CNK [molar Al2O3/ (CaO+Na2O+K2O)] diagram showing the composition of the Archean leucogranites from Kuhmo and Koillismaa. Mean values for Archean calc-alkaline granites (CA1 and CA2), strongly peraluminous granites (SP3 and SP4) and alkaline granites (ALK4) are after Sylvester (1994). The Neoarchean leucogranites of Kuhmo and Koillismaa are generally rich in silica, most of them having >73 wt.% SiO2. They are moderately peraluminous, with A/CNK from 1.01 to 1.15 (Table 3). of Chappell and White (1974), whereas the granites from Kuhmo range from I-type to S-type (Fig. 12). Most leucogranites in Koillismaa are magnesian acwhereas the leucogranites from Kuhmo span from magnesian to ferroan with increasing SiO2 values (Fig. 13). The LREE are strongly fractionated compared to the HREE— the latter are under detection limit in most samples from Koillismaa (Fig. 14). The leucogranites of Kuhmo generally show a small negative Eu anomaly. In the granites of Koillismaa the Eu anomaly varies from slightly negative to slightly positive; positive values have been registered in one sample (A1657; Lauri et al., 2005) from a coarse-porphyritic granite that may register some feldspar accumulation. Fig. 13. FeOtot / (FeOtot + MgO) vs. SiO2 (wt.%) diagram for the Archean leucogranites of Kuhmo and Koillismaa. Line al. (2001). Symbols as in Fig. 12. Nd isotopes Leucogranites of the Kuhmo and Koillismaa districts are somewhat different in terms of Nd isotope composition (Fig. 15). In both districts, the highest values are ~+1. The lowest values in Kuhmo are Ndi around –2. However, in Koillismaa most values fall between –1.5 and –4, and are thus slightly more negative (at 2.70 Ga) than the 2.84 Ga migmatite paleo- Sylvester (1994) divided Archean granites into three main categories, namely calc-alkaline granites, strongly peraluminous granites, and alkaline granites, each with two subgroups. According to Sylvester (op. cit.), the calc-alkaline granites (CA) are partial melts of a mainly tonalitic source, whereas the strongly peraluminous granites (SP) are derived from a dominantly sedimentary source. The source of the alkaline granites (ALK) is not well constrained but, according to Sylvester (1994), the Archean alkaline granites differ from their Phanerozoic counterparts more than the other two types (CA and SP) do. component similar to the 3.5-Ga Siurua gneiss (Mutanen and Huhma, 2003) is present in the studied leucogranites (Fig. 15). Therefore it is likely that the leucogranites in eastern Finland were largely formed by melting of the local Neoarchean crust (Käpyaho et al., in review). 28 Table 3. Selected analyses of Neoarchean leucogranites Koillismaa (1) Koillismaa (1) Sample A1656 A1657 Kuhmo (2) Kuhmo (2) CA1 (3) CA2 (3) SP3 (3) SP4 (3) ALK4 (3) G16 G15 (n = 16) (n = 12) (n = 9) (n = 14) (n = 11) SiO2 74.8 74.1 75.1 76.1 70.0 71.9 73.7 74.4 74.2 TiO2 0.13 0.08 0.19 0.13 0.40 0.23 0.21 0.12 0.14 Al2O3 14.8 14.4 13.11 12.55 14.6 14.7 14.5 14.2 13.5 Fe2O3tot 1.10 1.03 1.28 0.91 3.02 1.83 1.70 1.22 1.47 MnO 0.02 0.01 0.01 0.01 0.05 0.03 0.03 0.03 0.04 MgO 0.30 0.11 0.32 0.15 0.84 0.48 0.41 0.26 0.23 CaO 2.57 1.18 0.63 0.52 2.28 1.69 1.12 0.57 0.94 Na2O 5.15 3.78 3.92 3.54 3.89 4.45 2.94 3.91 3.74 K2O 0.89 4.53 4.32 4.67 3.58 3.69 4.69 4.69 4.68 P2O5 0.01 0.01 0.06 0.05 0.17 0.08 0.09 0.10 0.60 Cl 0.01 0.01 - - - - - - - V 14 4 - - 28 15 9 3.1 9 Cr 0 18 26 8 26 73 9.9 6.3 37 Ni 0 7 - - 12 12 5 6.3 10 Cu 1 0 - - 19 13 60 12 11 Zn 18 13 - - 59 41 29 27 44 Ga 23 20 - - 18 17 14 23 20 Rb 28 49 141 191 117 125 140 292 339 Sr 257 550 185 120 479 455 189 73 102 Zr 51 55 142 859 218 142 116 90 134 Nb 2 1 7 12 9 3.3 16 19 Ba 172 4732 1629 936 1300 1210 740 372 505 Pb 48 49 - - 23 28 32 36 41 2.6 Sc 1.12 0.53 - - 4.7 1.8 2.8 1.8 Th 29.5 0.92 - - 21 22 22 21 41 U 0.3 < - - 2.4 3.3 11 5.4 6.8 Y 1.34 0.80 - 8 21 7 7.3 21 31 La 58.8 13.7 44.4 15.3 71 42 38.1 20.3 44 86 Ce 101 19.1 84.5 35 133 71 76.4 41.9 Pr 9.68 1.70 - - - - - - - Nd 29.4 4.82 - - 45 29 28 19 28 Sm 3.03 0.49 3.9 1.71 7.8 4.4 4.62 3.8 5.3 Eu 0.63 0.31 0.71 0.44 1.56 0.79 0.813 0.307 0.45 Gd 1.52 0.40 - - 5.1 3.4 3.78 2.76 3.00 Tb 0.2 < 0.18 0.19 0.73 0.41 0.43 0.57 0.85 Dy 0.41 0.13 - - 3.2 2.2 2.2 4.4 3.1 Ho < < - - - - - - - Er < < - - - - - - - Tm < < - - - - - - - Yb < < 0.63 0.58 1.55 0.51 0.82 2.05 1.9 Lu < < 0.12 0.09 0.24 0.09 0.14 0.32 0.37 A/CNK 1.05 1.08 1.07 1.06 1.01 1.02 1.21 1.13 1.04 Fe# 0.77 0.89 0.78 0.85 0.76 0.77 0.79 0.81 0.85 Oxides in wt.%, trace elements in ppm. < under detection limit, - not analyzed, 0 not detected. References: (1) Lauri et al. (2005); (2) Querré (1985); (3) Sylvester (1994). 29 3.3.5. Concluding remarks The ages thus far reported for the leucogranite magmatism in eastern Finland indicate that the leucogranites were emplaced at ~2.70 Ga. Thus these granites are coeval with high-grade metamorphism in central Finland (Mänttäri and Hölttä, 2002); further studies are, however, needed to establish whether there is a connection between this metamorphic event and leucogranite magmatism. Nd isotope results from the leucogranites of eastern Finland (Käpyaho et al., in review; Lauri et al., 2005) imply that these rocks most probably represent partial melts of the local crust. Nevertheless, the positive initial Nd values suggest that some of these granites could also be mixtures of juvenile magmas and melts from pre-existing crust. Based on whole rock chemical composition and Sr isotope data Querré (1985) noted that there are similarities between the leucogranites of Kuhmo district and the younger S-type plutons, especially the continental collision-related Himalayan leucogranites. The peraluminous nature and geochemical characteristics are, in general, similar to average Archean calc-alkaline and strongly peraluminous granites of Sylvester (1994). Fig. 14. Chondrite-normalized REE patterns for the Archean leucogranites of Kuhmo (Querré, 1985; Asko Käpyaho, unpublished data) and Koillismaa (Lauri et al., 2005). Normalizing values (C1 chondrite) are from Sun and McDonough (1989). The leucogranites of Koillismaa fall between the calc-alkaline (CA3, CA4) and alkaline (ALK4) categories whereas the leucogranites of Kuhmo resemble the strongly peraluminous granites (SP4) of source compositions and varying amounts of partial melting as the Archean leucogranites in different parts of the Karelian province were formed. Fig. 15. εNd vs. age diagram for the Archean leucogranites of Kuhmo and Koillismaa. DM (depleted mantle) evolution line from DePaolo (1981), CHUR denotes the Chondritic Uniform Reservoir of DePaolo and Wasserburg (1976). 30 3.4. Early Paleoproterozoic anorogenic granites (L.S. Lauri) 3.4.1. Introduction km (A in Fig. 16). It consists of coarse-grained to pegmatitic, pink granite that had intruded into Archean paragneisses. In the border zone, the granite shows a lineation but the center of the pluton is homogeneous and unoriented. Major minerals are quartz, K-feldspar, oligoclase, and biotite. Accessory minerals include muscovite, zircon, epidote, At the beginning of the Proterozoic Eon, a period of more than 200 m.y. of tectonic quiescence in the Fennoscandian Archean craton was broken by a stage of intermittent rifting that lasted for several hundred m.y. The onset of rifting has been attributed to mantle plume activity (e.g., Huhma et al., 1990; Amelin et al., 1995). The initial extension at ~2.44 Ga was manifested by bimodal magmatism Conventional U–Pb zircon age of the Rasimäki pluton is 2352 ± 25 Ma (Horneman, 1990), which implies that it is somewhat younger than the other intrusions described here. However, the Rasimäki granite geochemically resembles the ~2.44-Ga silicic intrusions and was probably formed by similar processes. The age of the pluton is also uncertain, as an alternative age of 2404 ± 155 Ma can be obtained from the same data (Horneman, 1990). Horneman (op. cit.) also associated the Rasimäki granite to some nearby granite dikes that contain 2410 Ma old titanite. and several small, silicic plutons (e.g., Luukkonen, 1988; Alapieti et al., 1990; Huhma et al., 1990; Amelin et al., 1995; Buyko et al., 1995; Lauri and Mänttäri, 2002; Lauri et al., 2003, 2005). Subsequent extensional phases are registered by diabase dike swarms and gabbroic intrusions at 2.3 Ga, 2.1 Ga, and 1.98 Ga (e.g., Vuollo et al., 2000) and they were followed by the Svecofennian orogeny at ~1.93–1.87 Ga. In Finland and adjacent Russia, a number of distinctive ~2.44-Ga silicic intrusions are found (Fig. 16). The Rasimäki granite pluton was emplaced close to the southwestern margin of the Archean craton (Horneman, 1990), while three small granite intrusions and associated granite porphyry dikes are known in the Kuhmo–Suomussalmi area (Luukkonen, 1988). A quartz alkali feldspar syenite intrusion is found farther north in Koillismaa, close Tuliniemet Tuliniemet-type granites are found in the Kuhmo district, on the eastern side of the Archean Kuhmo– Suomussalmi greenstone belt (Luukkonen, 1988; B and inset in Fig. 16). Three small intrusions and associated granite porphyry dikes intrude Neoarchean TTG gneisses. The intrusions are almost undeformed and clearly post-tectonic relative to the Archean deformation seen in the host rocks. The faint orientation seen in the brecciated border zone (Lauri and Mänttäri, 2002). East of Koillismaa, in northwestern Russia, is yet another granite pluton, complex (e.g., Buyko et al., 1995). All these silicic intrusions are within the Karelian province that also emplacement. Major minerals in the Tuliniemettype granites are K-feldspar, plagioclase, quartz, and biotite. Accessory minerals include sericite, intrusions. Some granites of similar age have also been reported from the Belomorian province (e.g., Lobach-Zhuchenko et al., 1998), but they have not been considered in this review. als. Central parts of the intrusions contain unmantled rapakivi-type K-feldspar ovoids, and mantled ovoids were also found in one of the plutons. The granite porphyry dikes contain microcline, quartz, 3.4.2. Description of the ~2.44-Ga silicic intrusions crystallized groundmass consisting of quartz, plagiRasimäki minerals. The U–Pb zircon age of one of the granite porphyry dikes is 2435 ± 12 Ma (Luukkonen, 1988). The Rasimäki granite pluton, described by Horneman (1990), is a small stock of 8 km by 3 31 vicinity of the 2.44-Ga Koillismaa layered igneous complex (Lauri and Mänttäri, 2002; C in Fig. 16). The pluton has intruded into Archean TTG gneiss- Recent U–Pb zircon results (Irmeli Mänttäri, unpublished data) imply an age of ~2425 Ma for one of the granites. Luukkonen (1988) correlated the Tuliniemet-type granites with the coeval Koillismaa layered igneous complex and with an EW-trending diabase dike swarm in the Kuhmo district. and extrusive rocks were also found near the contact. The Kynsijärvi pluton consists of homogeneous, undeformed, medium-grained, pink quartz alkali feldspar syenite. The main minerals present are mesoperthitic alkali feldspar, quartz and hornblende, with feldspar clearly dominating. Minor and accessory Kynsijärvi The Kynsijärvi quartz alkali feldspar syenite is a small (1 km by 5 km) EW-elongated intrusion in the Fig. 16. Geological sketch map of eastern Finland showing the distribution of the early Paleoproterozoic (~2.44 Ga) anorogenic 32 16) dates back to 1929, when the intrusion was still within the Finnish territory. Hackman and Wilkman (1929) described the intrusion and associated granite porphyry dikes in their explanation to the 1:400,000 geological map of the Kuolajärvi area. The Nuorunen granite is pink, medium- to coarsegrained subsolvus rock that mainly consists of microperthitic alkali feldspar, quartz, plagioclase, and amphibole. Accessory minerals include zircon, crographic intergrowths of quartz and alkali feldspar are common. The rock is somewhat deformed and slightly altered, with amphiboles partly replaced by chlorite. Other secondary minerals include sericite, stilpnomelane, and carbonate. Buyko et al. (1995) reported a U–Pb zircon age of 2450 ± 72 Ma for the Nuorunen granite. The Fig. 17. FeOtot / (FeOtot + MgO) vs. SiO2 (wt.%) diagram showing the composition of the early Paleoproterozoic anorogenic silicic intrusions of Finland and vicinity. Line sepa(2001). References: 1— Lauri and Mänttäri (2002); 2— Rämö and Luukkonen (in prep.); 3— Horneman (1990); 4— Lauri et al. (2005); 5— Luukkonen (1988). show similar ages (2445 Ma to 2435 Ma; Balashov et al., 1993; Amelin et al., 1995). At face value, the age of the Nuorunen granite implies that the granintrusions. 3.4.3. Elemental geochemistry The ~2.44-Ga silicic intrusions are all geochemically A-type, typically having, e.g., high alkali abundances, high Fe/Mg and Ga/Al ratios, high contents of Zr, Nb, Ce, Y, and REE, and negative Eu anomalies (Table 4). SiO2 varies from <72 wt.% in the Kynsijärvi pluton to between 72 wt.% and Fig. 18. SiO2 (wt.%) vs. A/CNK [molar Al2O3/ (CaO+Na2O+K2O)] diagram showing the composition of the early Paleoproterozoic anorogenic silicic intrusions of Finland and vicinity. See Fig. 17 for numbered data references. and stilpnomelane, which is probably of secondary origin. The pluton has suffered from post-magmatic alteration, manifested as intergranular albite rims between the mesoperthite crystals. The 2442 ± 3 Ma U–Pb zircon age of the Kynsijärvi pluton (Lauri and Mänttäri, 2002) is close to the age (2436 ± 5 Ma; are probably coeval. Fig. 19. Zr vs. 10,000*Ga/Al diagram showing the composition of the early Paleoproterozoic anorogenic silicic intru- Nuorunen The best available description of the Nuorunen granite pluton in northwestern Russia (D in Fig. al., 1987). See Fig. 17 for numbered data references. 33 Fig. 20. Chondrite-normalized REE patters for the early Paleoproterozoic anorogenic silicic intrusions of Finland and vicinity. Normalizing values (C1 chondrite) from Sun and McDonough (1989). See Fig. 17 for numbered data references. Fig. 21. εNd vs. age diagram for the early Paleoproterozoic anorogenic intrusions of Finland and vicinity. DM (depleted mantle) evolution line from DePaolo (1981), CHUR denotes the Chondritic Uniform Reservoir (DePaolo and Wasserburg, 1976). See 34 Table 4 Average compositions of the ~2.44 Ga A-type granites in the Fennoscandian shield Rasimäki1, 2 Tuliniemet2, 3 Kynsijärvi4 Nuorunen5 SiO2 75.7 75.6 70.8 75.4 TiO2 0.13 0.09 0.23 0.24 Al2O3 13.0 12.9 14.6 12.1 Fe2O3tot 1.43 1.41 3.06 1.71 MnO 0.02 0.04 0.05 0.03 MgO 0.12 0.28 0.11 0.18 CaO 0.80 0.59 0.58 0.69 Na2O 3.95 3.76 5.67 3.22 K2O 4.39 4.56 4.53 5.32 P2O5 0.02 0.03 0.03 0.03 Cl - < 100 100 V - - < 14 20 Cr - 30 17 Ni - 5 < 6 Cu - 7 < 7 Zn 32 44 75 23 Ga 22 24 31 22 Rb 181 398 102 168 Sr 56 51 35 77 Y 39 73 31.2 33.4 291 Zr 183 141 520 Nb 28 26 42 17 Ba 220 149 711 709 Sc - - 2.5 3.7 Th 27 48 11.1 9.9 U 18 8 1.06 1.4 Pb - 40 36 27 La 51.9 33.9 61.9 69.2 Ce 106.1 70.0 108.3 144.7 Pr 19.7 9.19 11.4 16.9 Nd 39.8 32.6 39.6 58.4 Sm 6.03 7.63 6.85 9.39 Eu 0.48 0.29 0.6 0.72 Gd 8.32 7.87 6.01 7.42 Tb 1.10 1.37 0.91 1.07 Dy 6.30 8.40 4.89 5.56 Ho 1.35 1.95 1.02 1.06 Er 4.16 6.55 3.06 3.19 Tm 0.64 1.08 0.45 0.48 Yb 4.39 7.93 3.29 3.32 Lu 0.70 1.17 0.47 0.48 from magnesian to ferroan (Fig. 17). Kynsijärvi and Nuorunen are metaluminous with A/CNK <1, Rasimäki is mildly peraluminous with A/CNK between 0.97 and 1.09, and in Tuliniemet the highest A/CNK values are >1.2 (Fig. 18). In the diagrams of Whalen et al. (1987), all the ~2.44-Ga silicic intruterns of these rocks show enrichment in the LREE compared to the HREE and a negative Eu anomaly (Fig. 20). 3.4.4. Nd isotopes Nd isotope compositions of the ~2.44-Ga granites are unique for each pluton or group and seem (Fig. 21). Kynsijärvi shows the least radiogenic values with initial εNd values between –4 and –5 (Lauri et al., 2005). The Nuorunen and Rasimäki granites have a somewhat more radiogenic isotope composition with εNd between –1.7 and –2.0 in the former (Lauri et al., 2005) and between –1.2 and –2.5 in the latter (Rämö and Luukkonen, in prep.). Tuliniemet-type rocks show the largest spread of εNd values, between –3.1 and +1.5 (Rämö and Luukkonen, in prep.). The Archean crust in Koillismaa has εNd (at 2440 Ma) values between –5 and –8.5 (Lauri et al., 2005), whereas for the Archean rocks in Kuhmo the corresponding values are between +1.0 and –4.5. (Käpyaho et al., in review; Section 3.3.). The Archean basement surrounding the Nuorunen pluton is somewhat less well documented but there are indications that also there the εNd (at 2440 Ma) values are close to zero or slightly negative (see discussion in Lauri et al., 2005). 3.4.5. Concluding remarks The ~2.44-Ga granitoids in the Fennoscandian shield are found as small plutons and dikes within the Late Archean basement of the Karelian province. They are mostly undeformed and show geochemical features typical for anorogenic granites. References: (1) Horneman (1990); (2) Rämö and Luukkonen (in prep.); (3) Luukkonen (1988); (4) Lauri and Mänttäri (2002); (5) Lauri et al. (2005). - not analyzed, < below detection limit. a bimodal magmatic association that was emplaced in the Archean craton in an extensional regime, the 77 wt.% in others. Rasimäki, Kynsijärvi, and Nuorunen have high Fe/Mg and are ferroan according icic rocks probably representing lower crustal melts Tuliniemet have somewhat lower Fe/Mg and span 35 3.5. Intermediate magmatism at the craton margin, central Finland (O. Äikäs, L.S. Lauri) 3.5.1. Introduction The western marginal zone of the Archean craton and the overlying Proterozoic supracrustal rocks are cut by a texturally, structurally, and compositionally diate rocks, provisionally referred to as microtonalites (Huhma, 1981) form one distinct group among these. The microtonalites occur mainly as dikes, but also as larger intrusions in a relatively narrow zone from the line Leppävirta–Tuusniemi–Kaavi up to the area west of Oulujärvi (Fig. 22) (see also Rautiainen, 2000). One of the most numerous sets of SE– NW-trending microtonalite dikes occurs within the Archean paragneisses between the lakes Vuotjärvi, near Juankoski and Syväri, near Nilsiä (Paavola, 1984). The location and direction of these microtonalite dikes coincide with a number of presumably younger lamprophyre dikes (Huhma, 1981). Occasional observations and descriptions of these dikes farther south and southeast are from Kangaslampi (map sheet 3234 in Fig. 22) and from Juojärvi (Koistinen, 1993). Larger occurrences include the horizontal and gently dipping microtonalite sheets around Talvisalo, near Nilsiä, and in Kuopio (Äikäs, 2000). Some other intrusive bodies, e.g., the diorites close to the Kuopio (Rissala) airport (Äikäs, 2000; Lukkarinen, 2000) and the composite intrusion of Kaarakkala farther north at Vieremä (Paavola, 2001, 2003), may also be related to the microtonalite magmatism. The age of the microtonalite magmatism is poorly constrained because of zircon inheritance (Huhma, 1981; Paavola, 2003). Crosscutting relations indicate the presence of several pulses of microtonalite dikes, although the emplacement ages of different pulses may be close to each other. Huhma (1981) reported a titanite age of 1850 Ma from a dike in Kaavi, but it is not clear whether this age marks the emplacement of the dike. A dike at Murtolahti, Nilsiä, yielded discordant zircon ages between 1939 Ma and 1835 Ma and a titanite age of 1829 ± 13 Ma (Irmeli Mänttäri, personal communicathe Kaarakkala intrusion was dated at 1864 ± 8 Ma (Ruotoistenmäki et al., 2001; Paavola, 2003). The 1869 ± 5 Ma (Hannu Huhma, personal communication, 2005) Juurus tonalite is intruded by at least 36 one pulse of microtonalite dikes. According to the primary concept of microtonalite dikes by Huhma (1981), the microtonalites crosscut the 1857 ± 8 Ma (Huhma, 1986) Maarianvaara granite, but at present this granite and its western counterparts are also known to crosscut some microtonalite dikes. The probable age span for microtonalite magmatism extends at least from 1890 Ma to 1830 Ma and it is possible that some conformable, deformed dikes occurring within the Archean rocks are themselves also Archean. 3.5.2. Field geology and petrography can be divided into several groups: (1) dikes that occur within the Archean rocks as conformable or semi-conformable fragments; (2) dikes that crosscut the Proterozoic mica gneisses but have been fragmented and deformed after emplacement; (3) less deformed or undeformed dikes that crosscut both Archean and Proterozoic rocks and are in turn cut by ~1860-Ma granites; and (4) dikes that crosscut the ~1860-Ma granites and other microtonalite dikes. Dike widths vary from a few centimeters to several meters and maximum length is probably only some tens of meters, as the dikes usually cannot be traced between outcrops. According to Rautiainen (2000), to dark gray and homogeneous in appearance. They have sharp, often jagged contacts to the wall rock and commonly form intrusive breccias (e.g., Paavola, 1984). Apophyses and weak magmatic banding are also common. Some dikes show evidence of Cloudy inclusions and net vein breccias between ocellar texture is found in some places (e.g., Rautiainen, 2000). Major minerals in the microtonalite dikes are subhedral plagioclase (>50 vol.%), biotite, and quartz (~1–30 vol.%). Some dikes also contain hornblende. Accessory minerals include titanite, apatite, epidote, zircon, rutile, chlorite, microcline, and oxide minerals (Huhma, 1975; Rautiainen, 2000). Grain size is small, between 0.05 and 0.5 cm. Dikes that Archean bedrock shown in gray (Geological Survey of Finland GIS data, based on Korsman et al., 1997). Inset on the left: bedrock geology in the area north of Kuopio, extracted from the 1:1,000,000 bedrock map of Finland (Korsman et al., 1997). The area was mapped by J. Paavola, H. Lukkarinen, A. Kontinen, and O. Äikäs. Map sheet numbers of the Finnish grid 1:100,000 are shown; the height of each sheet is 30 km. Raster images of the 1:100,000 geological maps can be downloaded at the GTK 37 lack hornblende resemble mica schists in the outcrop and— in some cases— can only be recognized as microtonalites from thin sections. 3.5.3. Geochemistry Rautiainen (2000) summarized the geochemical data for the microtonalite dikes and concluded that they were most probably generated by mixing and to Rautiainen (op. cit.), the microtonalites can be between 45 2 wt.% and 55 wt.%, a felsic group with SiO2 between 61 wt.% and 74 wt.%, and a hybrid group that falls between the two end-members. All three groups are metaluminous and I-type with A/CNK under 1.1 (Fig. 23). All microtonalite groups cross the magnesian-ferroan border in the FeOtot / (FeOtot + MgO) vs. SiO2 diagram of Frost et al. (2001) (Fig. 24). Microtonalites are enriched in the LREE compared Fig. 23. SiO2 (wt.%) vs. A/CNK [molar Al2O3/ (CaO+Na2O+K2O)] diagram showing the composition of microtonalite samples depicted in Fig. 22. Data by the courtesy of the Geological Survey of Finland (O. Äikäs). ples commonly show a small negative Eu anomaly, probably caused by hybridization. In felsic samples the negative Eu anomaly is more pronounced. According to Rautiainen (2000), the microtonalites Irvine and Baragar (1971). He also concluded that gin arc basalts in trace element composition. 3.5.4. Concluding remarks Fig. 24. FeOtot/(FeOtot + MgO) vs. SiO2 (wt.%) diagram of microtonalite samples in Fig. 22. Data by the courtesy of the Geological Survey of Finland (O. Äikäs). Microtonalite dikes and related larger intrusive bodies occur at the Archean craton margin in a geographically narrow zone. However, the time interval of the microtonalite magmatism is long, at least 60 m.y., and possibly more, if some dikes occurring within the Archean rocks are themselves Archean. Although the absolute ages of the microtonalite dikes are still largely unknown, the magmatic episode seems to consist of several pulses. It may be argued that the microtonalite magmatism is a typical feature of the Karelian craton margin and, for some reason, the source was periodically tapped during Paleoproterozoic. The presence of two intermingled magma observations, petrography, and geochemistry. Further isotope geochemical data would be needed in order to constrain the age and origin of these dikes. 38 Fig. 25. Chondrite-normalized REE patterns of microtonalite samples: (A) Kivennapa area, Juankoski; (B) Honkamäki area, Nilsiä. Normalizing values (C1 chondrite) from Sun and McDonough (1989). Data by the courtesy of the Geological Survey of Finland (O. Äikäs). 3.6. Proterozoic synorogenic granitoids (M. Nironen) 3.6.1. Distribution and age Synorogenic granitoids, 1.89–1.87 Ga in age, are ubiquitous in southern and central Finland and are especially abundant in the ~40,000 km2 Central Finland granitoid complex (Fig. 26; see also inside front cover). The synorogenic rocks are subdivided into synkinematic (1.89–1.87 Ga) and postkinematic (1.88–1.86 Ga) with reference to prominent deformation in the area in question. In central Finland, the prominent deformational event has been dated at 1885–1880 Ma (Nironen, 1989; Hölttä, 1995; Mäkitie, 1999; Mouri et al., 1999). The overlapping ages of the two groups show that, at 1.88–1.87 Ga, some parts of the Svecofennian crust were subjected to penetrative deformation and synkinematic magmatism, whereas in other areas the postkinematic stage had already been reached. granodiorites and granites with abundant subhedral to anhedral potassium feldspar phenocrysts 1–4 cm in diameter are located in the central and northeastern parts of the complex. The granites contain biotite are hornblende, titanite, apatite, magnetite, and zircon. Both hornblende and biotite are found as and the tonalites may also contain clinopyroxene or orthopyroxene. Typical accessory minerals are titanite, apatite, magnetite, and zircon. Abundant suggest that mixing and mingling processes were The felsic to intermediate synkinematic intrusive rocks grade in places into subvolcanic quartz– feldspar and feldspar porphyries. Synkinematic granitoids of the supracrustaldominated belts surrounding the Central Finland granitoid complex are generally granodiorites and tonalites. They are usually oval or roundish intrusions and exhibit a foliation that is locally conformable with the country rock contacts. Most of the plutons are multiphase and show normal zoning with tonalitic marginal parts and granodioritic to granitic central parts; reversely zoned plutons are also found (Nironen, 1989; Nironen and Bateman, 3.6.2. General mode of occurrence Synkinematic rocks of the Gentral Finland granitoid complex are typically medium-grained granodiorites and granites (Fig. 27), but mediumgrained tonalites are also found, especially along the western margin of the complex. The granitoids exhibit a foliation that varies from slight orientation to pervasive gneissic foliation. Coarse-porphyritic 39 Nironen, 2005). Abbreviations for crustal units (arc complexes) as in Fig. 1. Postorogenic intrusions are marked by stars: 1— Lemland, 2— Mosshaga, 3— Seglinge, 4— Åva, 5— Turku, 6— Renko, 7— Parkkila, 8— Luonteri, 9— Eräjärvi, 10— Pirilä. the Archean craton. Microtonalite dikes (Section 3.5) are found west of the dashed line. 40 Fig. 27. Total alkali vs. SiO2 (TAS) diagram for Proterozoic synorogenic (synkinematic and postkinematic) granitoids in Finland (after Le Maitre et al., 1989). 1— trachybasalt, 2— basaltic trachyandesite, 3— trachyandesite (monzonite), 4— trachydacite (quartz monzonite), 5— basalt, 6— basaltic andesite, 7— andesite (quartz diorite, tonalite), 8— dacite (granodiorite), 9— rhyolite (granite). interstitial and thus rather late in the crystallization sequence. Fluorite is a characteristic accessory mineral of the Type 2 plutons. Other accessory minerals include apatite, zircon, titanite, and allanite. The Type 3 plutons either have a pyroxenebearing margin or contain pyroxene throughout. Large orthoclase megacrysts mantled by plagioclase are typical of the Type 3 quartz monzonites. Especially the Type 2 granites in the western part of the Central Finland granitoid complex resemble the rapakivi granites in their mineralogy and geochemical characteristics (Nironen et al., 2000). A couple of small monzodioritic to gabbroic bodies are associated with the postkinematic plutons of the Central Finland granitoid complex. Magma 1989). Biotite is generally more common than hornblende, and accessory clinopyroxene occurs in some phases. Other accessory minerals are titanite, magnetite, apatite, and zircon. The granitoids dioritic or dioritic phases. These features suggest magma mixed producing a variety of hybrid rocks (Nironen and Bateman, 1989; Lahtinen, 1996). Within the Central Finland granitoid complex, there is a suite of 1.88–1.87-Ga quartz monzonitic, granodioritic, and granitic plutons that crosscut the 1.89–1.88-Ga synkinematic rocks (Fig. 27; Elliott et al., 1998; Nironen, 2003). These are considered postkinematic because they are usually unoriented or only slightly oriented and truncate the foliation of the synkinematic rocks. They are found all over the Central Finland granitoid complex and also outside the complex. The postkinematic plutons are multiphase intrusions that can be divided into three types (Elliott et al., 1998; Elliott, 2003). The Type 1 plutons are coarse-porphyritic biotite granodiorites and granites with abundant orthoclase megacrysts and are found along the southern margin of the Central Finland coeval with the felsic rocks. The postkinematic plutons are located at or close to major crustal shear zones. These plutons were emplaced within an extensional or transtensional environment and shear zones controlled their emplacement. The postkinematic plutonic event shifted from northeast toward west during 1885– 1870 Ma (Rämö et al., 2001a). 3.6.3. Geochemical constraints on origin zircon, apatite, and ilmenite. The Type 2 plutons are coarse-porphyritic or equigranular granites that vary in grain size from medium to coarse. The Geochemically, the granitoids show a shift 41 Fig. 28. Variation diagrams for Proterozoic synorogenic (synkinematic and postkinematic) granitoids in Finland. Fields in the K2O vs. SiO2 diagrams after Rickwood (1989). Boundary of I-type and S-type granitoids in the molar Al2O3 / (CaO + Na2O + K2O) [A/CNK] vs. SiO2 from Frost et al. (2001). 42 granitoid complex area (cf. Fig. 28); probably both have a prominent arc-related source component. Nironen et al. (2000) proposed that K-rich calcalkaline volcanic rocks were subducted beneath the older nucleus and that partial melting of these rocks in the lower crust, triggered by heat and magmatic addition from the mantle, produced synkinematic magmatism in the central Finland granitoid complex. The synkinematic rocks show a typical shift from the I-type to the S, but the rocks of 2 the supracrustal belts are generally more S-type and more peraluminous than the rocks of the Central Finland granitoid complex suggesting a sedimentary component in the source area. The postkinematic rocks are in general higher in Fe, K, Ba, Zr, and Fe/Mg and lower in Mg and Ca than the synkinematic rocks at similar SiO2 contents. Overall, the postkinematic rocks are more alkaline and evolved than the synkinematic rocks (Figs. 27 and 28). The composition and similarity to rapakivi granites of the postkinematic plutons were derived from a granulitic residue left in the lower crust after the extraction of the synkinematic addition also contributed to the generation of the postkinematic magmas. According to Elliott (2003), the postkinematic magmas may consist of crust with minor incorporation of restitic material from lower crust. The granitoids of the Central Finland granitoid complex and granitoids of the supracrustal belts in southernmost Finland have εNd (at 1880 Ma) values from –1.5 to +1.1 and TDM model ages (DePaolo, 1981) from 2.05 Ga to 2.41 Ga, indicating that these areas probably contain an older (~2.0 Ga) nucleus (Lahtinen and Huhma, 1997; Rämö et al., 2001a). The εNd (at 1880 Ma) values of the postkinematic granitoids within the Central Finland granitoid complex constitute a tight range of –1.1 to +0.5 and TDM model ages of the rocks vary from 2.11 Ga to 2.27 Ga (Rämö et al., 2001a). The homogeneity of the Nd isotope composition implies a homogeneous source over the Central Finland granitoid complex and that the crust-forming process was quite rapid (Rämö et al., 2001a). of relatively dry magmas derived from deep crust (Elliott et al., 1998; Nironen et al., 2000). Nironen et al. (2000) proposed that the postkinematic rocks 3.7. Proterozoic lateorogenic granites (M.I. Kurhila) 3.7.1. Introduction The lateorogenic granite zone of southern Finland extends from the archipelago of southwestern Finland east–northeast to Russia, forming a semicontinuous belt about 500 km long and 150 km wide (Fig. 29; see also inside front cover). The zone is characterized by migmatizing, high-K granites. The lateorogenic granites of the Arc complex of southern Finland mostly do not form batholiths sensu stricto, but usually there is a gradual transition from microcline granites through migmatites to subvolcanic and metasedimentary rocks. The Puruvesi area in eastern Finland (Fig. 29) is somewhat of an exception in this respect, as it is a clearly intrusive batholith with concentric lithological variation. Although the lateorogenic granites occupy large areas, their vertical thickness seems to be rather limited. It is generally thought that they form relatively thin undulating sheets within the country rocks, at least in the western part of the zone (e.g., Ehlers et al., 1993; Selonen et al., 1996). Petrographically, the granites are quite similar throughout the belt, the major minerals being quartz, microcline, biotite, plagioclase, cordierite, and garnet. Modal compositions plot within alkali feldspar granite and syenogranite show more variation, but they commonly include apatite, muscovite, chlorite, monazite, zircon, and rutile or anatase. At outcrop scale, these granites are commonly heterogeneous: grain size and distribution and the amount of garnet and biotite decimeter-scale compositional layering. 3.7.2. Geochemical features Geochemically, the lateorogenic granites of southern Finland are rather heterogeneous. Their SiO2 content varies from about 65 wt.% 43 3.7.3. Nd isotopes to over 77 wt.%. They are peraluminous, but the variation in A/CNK is relatively large, from 1.02 Along with the elemental geochemical composition, whole-rock Nd isotope composition varies substantially along the zone. The least radiogenic initial Nd isotope compositions ( Nd values around –6) are found in the east, around Lake Puruvesi near the Archean Karelian craton (Fig. 29). Such low Nd variation; for example, the Eu anomaly ranges from slightly positive to strongly negative. The HREE are enriched in some samples but, generally, the REE diagrams of these granites are smoothly descending (Fig. 30). Variation in (La/ Yb)N different amounts of residual garnet. The commonly expressed notion that the late Svecofennian granites are S-type (e.g., Ehlers et al., 1993; Johannes et al., 2003) is not strictly correct, as some of the rocks within the zone do not meet with the criteria of the classic S-type probe U–Pb data (Matti Kurhila, unpublished data) that have revealed abundant inherited Archean and older Paleoproterozoic zircons. In the northwestern part of the lateorogenic granite zone, positive initial Nd values dominate, indicating a rather juvenile source in that part of the zone. The majority of the lateorogenic granites, however, have initial Nd values around –1. All granitoid rocks in the southern (1974). Some of the granites of the belt have virtually no garnet or monazite, their A/CNK value may be below 1.1 and the Na content up to 5%. Also, muscovite is not always present. less radiogenic initial Nd isotope composition than den in the west and to Russia in the east. Generally, the lateorogenic granites are migmatizing and have gradational contacts margins. 44 Fig. 30. Chondrite-normalized REE composition of a selection of lateorogenic granites across the Arc complex of southern Finland, displaying considerable heterogeneity. Normalization values from Boynton (1984). Unpublished data by Mikko Nironen and Matti I. Kurhila. Fig. 31. Geological map of southwesternmost Finland showing the geographic position and initial genic granites from Kurhila et al. (in press). 45 Nd values of eight lateoro- Fig. 32. Distribution of U–Pb ages obtained from zircons and monazites throughout the lateorogenic granite zone. Error bars are at 2 level. Unpublished data by Matti I. Kurhila. between otherwise indistinguishable granites less than 10 km apart has been documented (Kurhila et al., in press). Also, the amount and ages of inherited zircons vary a great deal. In the eastern part of the granite zone, Archean and older Paleoproterozoic zircons are fairly common, whereas in the west and south, virtually no inherited zircons with preserved U–Pb isotope ratios have been recorded (Kurhila et al., in press). those in the northern part of the Arc complex of southern Finland (cf. Fig. 31), where the granites record initial Nd values close to zero. This might indicate an EW-trending terrane boundary within the Arc complex of southern Finland. 3.7.4. U–Pb ages Traditionally, the lateorogenic granites have been considered to be 1.84–1.82 Ga in age (e.g., Korsman et al., 1997, 1999). However, we have recently made numerous, mostly still unpublished U–Pb age determinations of these granites, using both zircon and monazite. Commonly, both minerals display similar ages for individual samples. The collective results are shown in chronological order in Fig. 32. The age range of the lateorogenic granites is at least from ~1.80 Ga to 1.85 Ga, i.e., clearly larger than previously thought. On a broad scale, the ages show a notable younging trend towards the east, but adjacent samples within the zone may show considerably different ages. For example, a ~25–30-Ma gap 3.7.5. Sources and origin of the lateorogenic granites The available elemental geochemical data, Nd isotopes, and detailed U–Pb geochronology show that the lateorogenic granites of southern Finland were derived from varying sources. The wide age range of inherited zircons, abundant garnet and cordierite, and negative initial Nd values of some of the granites indicate a major sedimentary source component, whereas the lack of preserved inherited zircons, positive Nd values, and extremely 46 granites is associated with local generation of melt, possibly connected with formation of pressure minima after the cessation of the main phase of the orogeny (Kurhila et al., in press). The various Svecofennian crustal terranes (cf. Lahtinen and Huhma, 1997; Rämö et al., 2001a) were already amalgamated by ~1.87 Ga and, subsequently, high-grade metamorphism took place throughout southern Finland over a period of ~50 m.y.. The ages of the lateorogenic granites record roughly the same time span as the granulite facies metamorphism within the arc complex of southern Finland (Suominen, 1991; Van Duin, 1992; Väisänen et al., 2002; Kurhila et al., in press). However, this possible link between metamorphism and granite magmatism needs further research. leucocratic mineralogy in others are in favor of an igneous source. Selonen et al. (1996) proposed that the lateorogenic granites were emplaced at middle crustal levels but the tectonic regime under which this took place is still subject to controversy. The granites are thought to record either a transpressional intraplate environment (Ehlers et al., 1993) or an extensional zone after orogenic collapse (Korja and Heikkinen, 1995; Lahtinen et al., 2003). The typical features of the granites, i.e., generally low-angle layering, preferred magmatic orientation, migmatization, and melt segregation, could be attributed to both environments (Solar et al., 1998). In any case, considering the capricious distribution of their ages, it seems that the emplacement of the lateorogenic 3.8. Postorogenic intrusions (M. Nironen, O.T. Rämö) phase and younger granodiorite and granite The postorogenic rocks of southern Finland are found as ten relatively small intrusions that roughly follow the northern boundary of the of lateorogenic granite zone to Russia (Fig. 26). These intrusions cut sharply the surrounding Paleoproterozoic metamorphic crust and their U–Pb zircon ages range from 1815 Ma to 1760 Ma (Vaasjoki and Sakko, 1988; Suominen, 1991; Vaasjoki, 1996; Väisänen et al., 2000; Eklund and Shebanov, 2005). hornblende is abundant in some of the granodioritic varieties. Typical accessory minerals are titanite, apatite, magnetite, zircon, and allanite. Chlorite and Lamprophyric dikes are associated with the Åva and Seglinge ring complexes. Bimodal lamprophyre– granite magmatism has resulted in magma mixing and mingling structures (Hubbard and Branigan, 1987; Branigan, 1989; Eklund et al., 1998; Eklund 3.8.1. Mode of occurrence The intrusions are generally rounded with a diameter of 2−15 km. In the far southwest part of the country (Åland Islands), the Åva, Seglinge, and Mosshaga intrusions are ring complexes and the Lemland intrusion also has concentric compositional and structural features (Eklund and Shebanov, 2005). In contrast to the other intrusions, the Parkkila and Eräjärvi (Nykänen, 1988) plutons in southeastern Finland are dike-like bodies with lengths of several kilometers. All intrusions sharply crosscut their host rocks. Large compositional variations (monzodiorite to granite) are present in the intrusions of the Åland Islands and at Luonteri whereas the others are more homogeneous— Renko is quartz monzodioritic, Parkkila granodioritic, and Pirilä and Eräjärvi granitic. The Luonteri intrusion is a funnel-shaped multiphase pluton that consists of an early tonalitic Fig. 33. Total alkali versus SiO2 (TAS) diagram for postorogenic intrusions in southern Finland (after Le Maitre et al., 1989). Fields are as in Fig. 27. Data from Eräjärvi are marked by heavy dots. 47 Fig. 34. Variation diagrams for the postorogenic intrusions in southern Finland. Fields in the K2O vs. SiO2 diagrams are after Rickwood (1989). Boundary of I- and S-type granitoids in the A/CNK [molar Al2O3 / (CaO + Na2O + K2O)] vs. SiO2 (wt.%) from Eräjärvi are marked by heavy dots. 3.8.2. Geochemical constraints on origin and Shebanov, 2005). Lindberg and Eklund (1988) compared the geochemical features and contact Geochemically, the postorogenic rocks of southern Finland cover a wide range in SiO2 (from 32 wt.% to 78 wt.%; Eklund et al., 1998) and they rocks in the Lemland area and considered that both chemical and mechanical mixing occurred at several stages in a zoned magma chamber during upward movement. Prior to emplacement, the magmatic evolution of the complex may have been controlled by fractionation processes in a midcrustal chamber (Eklund and Shebanov, 2005). According to Bergman (1986), the Åva monzonite intruded a previously emplaced lateorogenic granite as branching concentric dikes by stoping, and the subsequent granite widened the funnel laterally. The intrusion mechanism of the Åva ring complex have high K, Ti, and Ba contents and are strongly enriched in the incompatible elements; the more and the REE (Fig. 34; Nurmi and Haapala, 1986; the postorogenic rocks of southern Finland as shoshonitic, largely on the basis of their high K, Ba, and Sr contents. However, the Ti contents of these rocks are high for typical shoshonitic rocks and indeed high compared to other orogenic rocks (cf. Figs. 28 and 34). Lahtinen (1994) proposed fractional crystallization and assimilation of mantle-derived alkali basaltic magmas as the primary processes that controlled the evolution of these rocks, and favored an enriched subcontinental lithospheric mantle source. Eklund et al. (1998) suggested carbonate metasomatism as the reason for enrichment of 1987) imply emplacement of these ∼1800-Ma rocks into rigid country rocks at a shallow depth (a few km). In contrast, a thermobarometric study of the 1815-Ma postorogenic rocks in the Turku area indicates an emplacement pressure of ~4 kbar, corresponding to a minimum depth of 14−15 km (Väisänen et al., 2000). 48 the lithospheric mantle source and concluded that metasomatism was more extensive in the east. Nd isotope data on the postorogenic granitoids are relatively few. The εNd (at 1800 Ma) value of the granite of the Åva ring complex is +0.2 and the depleted mantle model age is 2.02 Ga (Patchett and Kouvo, 1986). The εNd (at 1800 Ma) values of the Parkkila granodiorite and the Pirilä granite (Patchett and Kouvo, 1986; Lahtinen and Huhma, 1997) are +0.5 and +0.7, respectively. Our recent (still unpublished) data on the Renko quartz monzodiorite stock and the Eräjärvi granite indicate that the former is more juvenile [with an εNd (at 1815 Ma) value of +1.3] than Åva, Parkkila, and Pirilä, whereas the latter is quite similar [with an εNd (at 1800 Ma) value of +0.4; see description of Stop 2/5] with them. 3.9. Rapakivi granites (O.T. Rämö) The Finnish word “rapakivi”means disintegrated or crumbly rock and illustrates the tendency of the rapakivi granites to weather more easily than the other granitic rocks of Finland. In 1891, J.J. Sederholm introduced rapakivi granite in international geological literature in his pioneering paper on the rapakivi granites of southern Finland. Since then, southern Finland has been regarded as the type area of rapakivi granite. In the 20th century, a steadily increasing number of rapakivi granites were described from around the world, especially the Ukraine, South Greenland, eastern Canada, mid-continental and southwestern United States, and Brazil. Rapakivi granites are now known from all continents (see reviews in Rämö and Haapala, 1995, and Haapala and Rämö, 1999). As currently perceived, the majority of rapakivi granites are mid-Proterozoic (1.8–1.0 Ga), but also some welldocumented Phanerozoic (cf. Calzia and Rämö, 2005; Haapala et al., 2005) and Archean (Sibiya, 1988; Moore et al., 1993) examples are known. alkali feldspar megacrysts mantled by sodic plagioclase, two generations of alkali feldspar and quartz; Vorma, 1976) is ubiquitous especially in voluminous batholiths. In order to take into account these rapakivi granites as “A-type granites characterized by the presence, at least in the larger batholiths, of granite varieties showing the rapakivi texture”. This sitional peculiarities, and magmatic association of the rapakivi granites, but does not restrict their age. 3.9.2. Distribution and age The classic rapakivi granites of Finland form a substantial part of the Fennoscandian rapakivi association. Overall, the Fennoscandian intrusions are mid-Proterozoic (1.67–1.47 Ga) and fall into four age zones with a gross east–west pattern (Fig. 36). The Wiborg batholith and associated plutons and dike swarms in southeastern Finland and Estonia are 1.67–1.62 Ga old. Those in southwestern Finland, Latvia (the huge Riga batholith), and west-central Sweden (the Nordingrå complex) are dated at 1.59– 1.54 Ga. The rapakivi granites in central Sweden (west of Nordingrå) are 1.53–1.47 Ga, and those in Russian Karelia (the Salmi complex) 1.56–1.53 Ga. 3.9.1. General mode of occurrence, geochemistry, The rapakivi granites are typically found as discordant plutons that were intruded into a metamorphic crust that was differentiated from the mantle a few hundred Ma earlier. Geochemically, the rapakivi granites are subaluminous A-type (Fig. 35, Table 5), with high contents of the HFSE and LREE (except Eu), and a marginally metaluminous to peraluminous and reduced to oxidized character. Some complexes include volcanic rock types and minor peralkaline lithologic units. The magmatic association of rapakivi granites is bimodal, as featured by AMCG (anorthosite–mangerite–charnockite–granite) complexes and spatially and temporally asso- scarce at the present Precambrian erosional sur- of the Wiborg batholith (the Ahvenisto complex), in Russian Karelia, and in central Sweden (the Ragunda complex) (Fig. 36). Geophysical studies (e.g., Elo and Korja, 1993; Korja et al., 1993; Luosto, 1997; Korsman et al., 1999) show that (1) the Fennoscandian rapakivi granite batholiths are found as relative thin (~5– 10 km) sheet-like bodies in the upper part of the 49 Table 5 Representative chemical composition of the Finnish rapakivi granites: Wiborgite and pyterlite from the Wiborg batholith (southeastern Finland) and topaz-bearing granite from the Eurajoki stock (southwestern Finland). Data from Haapala et al. (2005) sample SiO2 Wiborgite Pyterlite Topaz granite 1A/IH/2001 2A/IH/2001 5/IH/2001 69.9 76.70 75.78 TiO 2 0.42 0.18 0.02 Al2O 3 13.41 11.70 13.62 FeO W 3.35 1.53 0.65 Fe2O 3 0.45 0.31 0.19 MnO 0.06 0.02 0.05 MgO 0.35 0.09 0.00 CaO 2.16 0.80 0.64 Na2O 3.09 2.49 3.70 K2 O 5.46 5.59 4.35 0.11 0.02 0.02 P 2 O5 H2 O + 0.31 0.17 0.24 FW 0.24 0.43 1.19 Total 99.37 100.03 100.43 -O=F2 0.18 0.50 Total 99.27 99.85 Cl (ppm) 800 300 100 Rb 271 349 1050 crust, and (2) that the crust shows particularly steep ovoid thinnings associated with the rapakivi intrusions. For example, beneath the Wiborg batholith, the crust is ~40 km thick— 15–20 km thinner than in the surrounding areas (Fig. 36). A further typical feature is that the crust underlying the rapakivi inand thinned lower crust (Korja et al., 2001). 3.9.3. Petrology All the large Finnish rapakivi batholiths and most of the stocks are multiple intrusions consisting of several granite types. Minor anorthositic and gabbroic bodies are found in several of the complexes. The contact relations suggest that they are older than the associated rapakivi granites, but there is no siget al., 1991; Suominen, 1991). The rapakivi granite types differ from each other in texture, mineral composition, and chemical composition. Among the oldest rapakivi varieties are fayalite-bearing biotite–hornblende granites. The major intrusive phases are commonly represented by wiborgite (a biotite–hornblende granite that contains oligoclasemantled K-feldspar ovoids) and pyterlite (biotite granite with unmantled ovoids) (Fig. 37). They are not, however, invariably present in all the rapakivi intrusions. The relative amounts of various evengrained and porphyritic biotite granites vary widely. The youngest intrusive phases are topaz-bearing microcline–albite granites that contain lithian siderophyllite (or protolithionite) as the dark mica (Haapala, 1997). Typical accessory minerals in the granites of the early and main intrusion phases are 99.93 Sr 155 69 8 Ba 1144 541 28 Ga 27 24 60 Be 5 5 16 Zn 125 86 197 Sc 8 3 12 Zr 459 304 51 Hf 12.7 10 5.7 110 Sn 8 9 W 3 3 9 Nb 26.4 25.8 69.8 Ta 2.3 2.41 22.6 Th 24.7 38.6 27.6 U 8.08 14.7 6.34 Pb 38 55 88 Y 63 75 55 La 95.9 99 47.4 Ce 182 182 97.2 Pr 21.5 21.2 11.1 Nd 80.6 76.2 37.3 Sm 14.6 13.7 9.26 Eu 2.56 1.26 1.18 Gd 12.6 12.2 7.77 Tb 2.14 2.2 1.84 Dy 12.7 13.8 12.7 Ho 2.67 2.98 2.71 Er 7.26 8.51 8.6 Tm 1.07 1.3 1.77 Yb 7.31 8.56 15 Lu 1.05 1.23 2.3 and ilmenite (see Vorma, 1971, 1976). In the biotite granites, monazite is found instead of allanite. In the late-stage granites, topaz, monazite, bastnaesite, ilmenite, cassiterite, and columbite are typical heavy accessory minerals (Haapala, 1974). The rarity of pegmatites and miarolitic cavities, late crysreactions, and scarcity of hydrothermal veins and mineral alterations indicate that the early intrusive phases crystallized generally from water-undersaturated melts. The last intrusive phases crystallized from water-saturated magmas (Haapala, 1997; Haapala and Lukkari, 2005). The bimodal magmatic association of the rapakivi granites (granites, silicic dikes, anorthosites 50 ers to advocate magmatic underplating as the probable mechanism for the generation of these rocks (Haapala and Rämö, 1999, and references therein). This involves partial melting of the lower crust in response to thermal perturbations associated with the underplating. Petrologic studies of rapakivi complexes in Finland and Sweden (Rämö, 1991; Andersson, 1997; Kosunen, 1999, 2004) have favored dehydration melting of quartzofeldspathic been discussed (Eklund et al., 1994; Salonsaari, 1995; Kosunen, 2004). Overall, the rapakivi granites and the associated of the composition of the unexposed lithosphere in any one area. This is illustrated in Fig. 36 that shows variation in the initial Nd isotope composidian rapakivi complexes. The Finnish, Estonian, and Latvian complexes and the Nordingrå pluton in Sweden (age groups 1.67–1.62 Ga and 1.59–1.54 Ga) have initial εNd values of –3 to 0. This is compatible with their derivation from the 1.9-Ga Svecofennian crust. The Salmi batholith in Russian Karelia is quite different in having initial εNd values of –9 to –5.5. This indicates a substantial Archean component in the source and complies with the position of the complex between the Archean and Proterozoic crustal domains (Fig. 36). Similar, yet quite surprising, is the Nd isotope composition of the rapakivi complexes in central Sweden (Fig. 36; see also Andersson et al., 2002). The initial εNd values (–10 to –4.5) point to a considerable Archean domain at the lower crust–uppermost mantle level in central Sweden. No Archean crust has been demonstrated from the exposed parts of the Precambrian in this area. Fig. 35. Composition of the Finnish rapakivi granites (Rämö and Haapala, 1995) in (A) FeOtot/(FeOtot + MgO) vs. SiO2 (B) (Na2O + K2O) / CaO vs. Zr + Nb + Ce + Y diagram of Whalen et al. (1987); and (C) Chondrite-normalized REE diagram. Composition range of ~500 A-type granites (as referred to in Frost et al., 2001) is shown in (A). In (B) OGT is unfractionated granites and FG is fractionated granites (Whalen et al., 1987). 51 Fig. 36. (A) Map showing the distribution and ages of the rapakivi granite complexes and diabase dikes as well as contours of crustal thickness in the south-central part of the Fennoscandian shield. The gray lines outline three rapakivi age zones (1.59– 1.54 Ga, 1.67–1.62 Ga, and 1.55–1.54 Ga). The inset shows the area in relation to the major crustal domains in the shield. TIB is the Transscandinavian igneous belt. The map is from Rämö and Korja (2000) and Rämö et al. (2000), where the pertinent references are given. (B) Diagram showing variation of initial Nd isotope composition (εNdi) in the rapakivi granites (open(DePaolo, 1981), the ~1.9-Ga Svecofennian rocks (Huhma, 1986; Patchett and Kouvo, 1986), and the Archean crust of the Fen- 52 Fig. 37. Photographs of two main textural types of rapakivi granite from the Wiborg batholith: (A) wiborgite, (B) pyterlite. Adopted from Rämö and Haapala (1990). 53 4. Tectonic evolution: the granitoid perspective (M. Nironen, P. Sorjonen-Ward, L.S. Lauri, O.T. Rämö, A. Käpyaho, J. Halla, M.I. Kurhila) 4.1. Introduction of granitoids. Moreover, Frosterus and Wilkman some plutonic rocks in southern Finland as synkinematic, latekinematic, and postkinematic (with respect to the Svecofennian orogeny), based on degree of deformation, as well as compositional differences. At the same time, Sederholm (1932) divided the Precambrian rocks of Fennoscandia into four sedimentation cycles, each related to a distinct plutonic event. The plutonic rocks of the the basement gneisses within the cover rocks, and Wegmann (1927) presented a tectonic synthesis in terms of Alpine collisional tectonics which remains essentially valid. These studies formed the basis for (1949), which considered the thermal and rheological aspects of orogenic processes and granite genesis through the concept of mantle gneiss domes. Here we present a current overview of the tectonic setting of the granitoid rocks in the Fennoscandian shield and their relation to the evolution of the craton (see Fig. 38). This will hopefully provide a synkinematic rocks of Eskola (1932). Some granite stocks in southern Finland and Lapland belong to the third cycle, and the rapakivi granites in southern Finland are part of the fourth cycle. Sederholm was a strong advocate of actualist principles, yet it must be understood that prior to the advent of isotopic dating trip, particularly in comparing and contrasting Archean and Proterozoic granitoids within their respective orogenic frameworks, and whether or not the sequential magmatic evolution in Finland is cycles were regarded as Archean. Following the pioneering isotopic studies of Kouvo and Gast structure and boundary conditions peculiar to the by Simonen (1960) distinguished a belt of latekinematic microcline granites in southern Finland; he later divided the Svecofennian plutonic rocks into synorogenic, lateorogenic, and postorogenic and considered that the rapakivi granites are anorogenic (Simonen, 1980). Later still, in a review of granitoid petrogenesis and metallogeny, Nurmi and Haapala generic processes applicable to other terrains. Terminology for the structural and lithic units issue complicated by the need to standardize names derived from diverse linguistic backgrounds! It is Gorbatschev (1987), to consider the Archean and Paleoproterozoic history of the Finnish part of the Fennoscandian shield in terms of three large crustal domains— the Kola, Karelian and Svecofennian domains (Fig. 1). These three crustal units have shared a common history since amalgamation at about 1.8 Ga. The Karelian domain is the largest unit, forming a coherent Archean (3.5–2.6 Ga) cratonic nucleus exceeding 200,000 km2 in area in eastern Finland and adjacent Russia (Figs. 1 and latekinematic, postkinematic, and anorogenic. Meanwhile, in eastern Finland, which will form Frosterus and Wilkman (1920, 1924) had implicitly and correctly recognized the presence of two superimposed orogenic cycles, separated by a major unconformity. The older granitoid group, which is truly Archean granitoids and gneisses, together with remnants of even older low-grade supracrustal by the Kola domain, which represents a complex tectonic collage of Archean and early Proterozoic terranes, and to the southwest by the essentially Paleoproterozoic Svecofennian domain. basement to the overlying (Paleoproterozoic) sedimentary sequences, which were in turn deformed and metamorphosed and intruded by a younger suite 54 Fig. 38. Time scale for the main tectonic events and associated lithologic units in Finland. 55 4.2. Archean The Karelian domain in Finland is characterized by a number of narrow northerly trending low-pressure greenstone and metasedimentary belts, intruded by discrete plutons of dominantly granodioritic to monzogranitic compositions. Higher grade mediumpressure metasedimentary gneiss complexes are also present, some of which represent older relict enclaves with younger migmatites, while others appear to be coeval with the greenstone sequences. The Kola domain is only represented in Finland by a small, but complex area in the far northeast of the country, including granitoid gneisses, migmatites, charnockites, aluminous metasedimentary rocks, and iron formations (Meriläinen, 1976; Gaál et al., 1989; Kesola, 1995). The Kola and Karelian domains are separated in Finland by the Paleoproterozoic Lapland granulite belt, which was tectonically emplaced over the Karelian domain some time after 1.9 Ga (cf. Gaál et al., 1989). In the adjacent Kola Peninsula, there shows both greater complexity and diversity, as indicated for example, by a distinctive suite of Neoarchean alkaline intrusions and gabbro– anorthosite intrusions (Zozulya et al., 2001). However, relationships between major crustal units are also somewhat better constrained by detailed structural analysis and careful isotopic dating and recent studies have demonstrated (Daly et al., 2001) that the correlatives of the Lapland granulite belt can also be traced across the Kola Peninsula towards the White Sea, where they merge with a highly complex gneiss terrain, along the northern margin of this Belomorian province have long been controversial, but recent studies have demonstrated that while there is a strong thermal overprint of Svecofennian age (Bibikova et al., 2001; Skiöld et al., 2001), it originated as a Neoarchean collisional the discovery of Archean eclogite facies gneisses at Gridino on the White Sea coast (Volodichev et al., 2004) provides evidence of the ability of Archean lithosphere to sustain lithospheric loading. Moreover, the presence of the intervening Inigora ophiolitic assemblage (Shchipansky et al., 2004), and the similarity in age (2.74–2.72 Ga) between the Gridino eclogites and granitoid magmatism in 56 eastern Finland provides a new basis for assessing the timing and nature of Archean crustal formation processes. The Archean history of the Fennoscandian shield in Finland extends back into the Paleoarchean with gneisses of trondhjemitic composition (Mutanen and Huhma, 2003). Isolated occurrences of 3.0–3.2Ga tonalitic gneisses (Kröner et al., 1981; Paavola, 1986) or xenocrystic zircon grains in younger plutons (Sorjonen-Ward and Claoué-Long, 1993) are known from a number of locations throughout the shield. However, much of crustal growth and subsequent tectonic and thermal reworking of the Archean of Finland can be constrained to within the interval 2.88–2.63 Ga (e.g., Vaasjoki et al., 1993, 1999, and references therein; Hölttä et al., 2000a; Evins et al., 2002; Lauri et al., 2005). So far it between discrete terrains, whether on the basis of age, metamorphic grade, or intensity and polarity of deformation, although a general subdivision is possible (cf. Sorjonen-Ward and Luukkonen, be made between greenschist to lower amphibolite facies supracrustal terrains, characterized by steep structural enveloping surfaces of fabric lineations, intruded by discrete plutons, which contrast with generally gently to moderately dipping higher grade gneiss terrains. This may represent a fundamental rheological decoupling between upper and lower crust, as observed in geological and seismic interpretations of other late Archean terrains (Drummond et al., 2000; Sorjonen-Ward et al., 2002), but it is still unclear whether the high-grade terrains record an extensional as well as contractional kinematic history (cf. Sandiford, 1989). Recent characterization of the thermal history of medium-pressure (8–11 kbar) granulites in central Finland (Hölttä, 1997; Hölttä and Paavola, 2000; Hölttä et al., 2000a), combined with data from lower crustal and mantle xenolith suites accessed by Neoproterozoic kimberlites (Hölttä et al., 2000b; Lehtonen et al., 2004), marks important progress in constraining the lateorogenic thermal regime and timing of crustally derived granite genesis and mantle depletion events. Enderbitic rocks are dated to 2.68 Ga, somewhat younger than the predominant 2.74–2.72 Ga ages for tonalitic to granodioritic et al., 1999; Lauri et al., 2005; Käpyaho et al., in review). Sanukitoid attributes are increasingly recognized in plutonic rocks in the Archean of eastern Finland, with varying modal compositions and host-rock metamorphic grade (Halla, 1998; Käpyaho et al., in review), as well as in adjacent Russia (Lobach-Zhuchenko et al., 2000a, b, 2005). In some places, such as the Hattu schist belt, in easternmost Finland, a close spatial and temporal relationship between felsic volcanism, sedimentation, deformation, and emplacement of these granitoids has been demonstrated (O’Brien et al., 1993; Sorjonen-Ward, 1993). Although there rocks emplaced at higher crustal levels, whereas some high-grade gneisses record ages as young as 2.63 Ga. The timing of postorogenic exhumation is not constrained, except that the 2.61-Ga Siilinjärvi carbonate complex, representing the youngest Archean magmatic event and having been emplaced in a brittle–ductile transitional environment, appears to be discordant with respect to country rock isograd trends, implying that metamorphic zonation at the present erosion level is a latest Archean, rather than younger phenomenon. Chemical characteristics of volcanic sequences in greenstone belts and granitoids intruding them have been used for comparison with modern arc magmatism (Martin et al., 1984; O’Brien et al., 1993) and for proposing plate tectonic models (Taipale, 1983, 1988; Martin et al., 1984; Piirainen, 1988). Martin (1986, 1987a,b) modeled source compositions and melting processes for tonalites and trondhjemites intruding and adjacent to the Kuhmo greenstone belt, to support the hypothesis that partial melting of amphibolite in subducting slabs was feasible under an Archean geotherm. In general, granitoid magmatism in the Kuhmo region record a systematic evolution from tonalites to high-Mg/Fe granitoid rocks and are followed by leucogranites (Querré, 1985; Martin, 1985; Vaasjoki distribution and polarity of supposed subduction zones, the data are certainly consistent with rapid crustal growth through construction of volcanic compelling evidence for eruption of greenstones in proximity to an older substrate is indicated by the abundance of partially assimilated granitic 1999; Halkoaho et al., 2000), and the presence of komatiitic dikes and layered sills in migmatites adjoining the Kuhmo greenstone belt (Luukkonen, 1992). 4.3. Proterozoic 4.3.1. Rifting of the Archean craton Rifting of the Archean craton continued intermittently to ~1.98 Ga as shown by a spread of high precision ages for sills and dike swarms between 2.3–1.98 Ga ages (e.g., Vuollo, 1994; Vuollo et al., 2000). At 2.1–2.0 Ga, rifting of the Archean craton In the early Proterozoic (commencing from ~2.44 Ga), the Fennoscandian Archean craton experienced a period of extension that was possibly initiated by a mantle plume (e.g., Huhma et al., 1990). The extension resulted in widespread incipient rifting and faulting of the craton and created pathways for sporadically felsic volcanism and deposition within a marine setting. Final breakup occurred, probably diachronously from north to south along the present western margin of the Karelian craton, between 2.0–1.95 Ga, culminating in the formation of the Jormua ophiolite complex (Kontinen, 1987; Peltonen et al., 1998) and coeval picritic continental ~2.44 Ga age have been found scattered throughout the northern Fennoscandian shield in Sweden, Finland, and northern Russia (e.g., Alapieti et al., 1990, mas also resulted in generation of felsic magmas by partial melting of the lower crust and, possibly, by an AFC process (Lauri et al., 2005). The 2.44-Ga silicic intrusions typically show little or no deformation during emplacement and are geochemically of A-type (Luukkonen, 1988; Lauri and Mänttäri, 2002; Lauri et al., 2005; Section 3.4). plume-related magmatism likely accompanied, if not initiated continental breakup. ration in that Archean zircons have recently been tle section of the Jormua ophiolite complex (Pel57 tonen et al., 2003). By implication, the mantle rocks represent late Archean subcontinental lithosphere, exhumed from beneath the Karelian craton during continental breakup. Accordingly, their highly depleted nature (Peltonen et al., 1998) is consistent with their being complementary reservoirs to crust formed during the late Archean, and also with the depleted character of Paleoproterozoic tholeiitic dike swarms. ary, partially melted the lower crust, and generated the synkinematic magmas by mixing and mingling of the crustal and mantle magmas. The thick, derplate generated high-temperature low-pressure metamorphism that culminated coevally with the emplacement of the synkinematic magmas. The hot underplate subsequently triggered partial melting of the lower crustal granulite that was left after the extraction of the synkinematic magmas, thus generating the postkinematic magmas of central Finland. 4.3.2. Proterozoic orogenic granitoids The Svecofennian orogeny oid rocks of Finland (Nironen, 2005) is based on new geochronological data and recent concepts of the evolution of the Svecofennian but retains the general terminology of Simonen (1980): In Finland, the Svecofennian crust has three main features that need attention when attempting to explain the tectonic evolution: (1) the magmatic rocks have a narrow age range of 1.90–1.87 Ga, excepting the 1.93–1.92-Ga tonalitic gneisses; (2) the metamorphism is of the high-temperature low-pressure type which culminated at 1.88 Ga in central Finland and at 1.82 Ga in southern Finland; and (3) the crust is anomalously thick, ~60 km in central Finland, diminishing to 50 km toward southern and western Finland. The generation and emplacement of Paleoproterozoic Svecofennian granitoids in Finland has been attributed to the progressive accretion of at least three arc complexes against the Archean craton (Lahtinen, 1994; Nironen, 1997; Korsman et al., 1999). According to these models, the oldest granitoids, the 1.93–1.92-Ga tonalitic gneisses, were probably generated when a rather primitive island arc accreted to a more evolved arc with a ~2.0-Ga nucleus in an oceanic environment. These arcs accreted to the Archean margin ~1.91 Ga ago; now they form the Primitive arc complex and Arc complex of western Finland (see Figs. 1 and 26). According to the models of Lahtinen (1994) and Nironen (1997), another arc complex approached from the (present) south where an oceanic basin was narrowing by subduction in opposite directions (Fig. 39). By 1.89 Ga, this basin had closed by subduction, and the arc complex (Arc complex of southern Finland) accreted to the previously accreted one (Arc complex of western Finland). Continued convergence caused thickening of the lithosphere which became gravitationally unstable. The base of the lithosphere was delaminated and compensated by hot asthenosphere. Decompression melting of the asthenospheric material produced (1) Preorogenic rocks were generated in an island arc environment and were placed in their present location during the Svecofennian orogeny. Preorogenic (1.93–1.92 Ga) granitoid rocks are found within the Primitive arc complex. (2) The synorogenic stage lasted from 1.89 Ga to 1.87 Ga as deduced from zircons dated from rocks of southern Finland (Vaasjoki, 1996). The emplacement and deformation of the synorogenic rocks is assigned to the accretion of three arc complexes to the Archean craton. Field studies have shown that some synorogenic rocks in central Finland crosscut their host (synorogenic) plutonic rocks. These rocks have been divided into syn- and postkinematic groups with respect to prominent deformation within the area in question. (3) The lateorogenic granites of southern Finland are located within the southern Finland arc complex and are associated with metamorphism and low-angle crustal movements 1.84–1.82 Ga (or 1.85–1.80 Ga; see Section 3.6) ago. The granites and associated migmatites form the Late Svecofennian granite–migmatite zone. (4) The postorogenic plutons of southern Finland are located within the late Svecofennian granitemigmatite zone but, contrary to the lateorogenic granites, these rocks were emplaced along faults and shear zones within a largely stabilized crust at 1.81–1.76 Ga. 58 Initial accretion of two amalgamated arc complexes 1.91 Ga ago to the Archean craton margin caused thickening of the crust and the underlying mantle lithosphere. Collision of another arc complex against the accreted ones 1.89 Ga ago caused continued lithospheric thickening and eventually led to delamination of the base of the lithosphere and compensation by hot asthe- prisms and caused subsequent partial melting of these rocks (lateorogenic magmatism). Thick, dense lower crust maintained the thickened crust in isostatic balance. CFGC— Central Finland granitoid complex. Zircon data from plutonic rocks indicate an age gap at 1.86–1.85 Ga (Vaasjoki, 1996) and the youngest detrital zircons in quartzites of southern Finland are around 1.87 Ga (Lahtinen et al., 2002). Ehlers et al. (1993) concluded that the lateorogenic granites of southwestern Finland were emplaced at 1.84–1.83 Ga during transpressional deformation with thrusting from the south–southeast, whereas Korja and Heikkinen (1995) presented an extensional model for the lateorogenic granites. craton (Karelian and Belomorian provinces) collided with the Archean Kola province, producing the high-grade Lapland granulite belt in the suture zone and inducing extensive melting in the central Lapland area. It has also been proposed that the northwestern part of the Karelian province was previously (before 2.0 Ga) rifted from the main continent and collided back to the present location slightly before the collision with the Kola province occurred (see, e.g., Lehtonen et al., 1998). The granitoids of northern Finland can also be divided into preorogenic, presumably preorogenic, synorogenic, lateorogenic, and postorogenic groups, although the age groups differ from those in the Svecofennian domain: Collisional tectonics in northern Finland While the Svecofennian arc accretion was taking place in the present central and southern Finland, the present northeastern part of the Archean 59 greenstone belt and the exposed Archean rocks of the Ranua and Kianta terrains of the Karelian craton. It is apparent from isotopic studies (Lauerma, 1982; Huhma, 1986) that there is an Archean source component to these rocks, whereas emplacement ages may be as young as 1.82 Ga, comparable with extensive granitoid complexes in adjacent Sweden (Ahtonen and Mellqvist, 1997; Sorjonen-Ward and Luukkonen, 2005). Potassic to monzogranitic dike networks within an Archean substrate are typical, and recent studies have focused on attempting to characterize chemical compositions with petrophysical attributes (Airo and Ahtonen, 1999). Similarly Puranen (1989) speculated that the ubiquitous ferromagnetic magnetite, and relatively low Fe contents of these granitoids hinted at a distinctly oxidized source terrain. (with respect to Svecofennian orogeny) are found in both the Lapland granulite belt, which is in large part derived from Paleoproterozoic sources (Meriläinen, 1976; Sorjonen-Ward et al., 1994), as well as within the adjacent Neoarchean Inari terrain. This plutonic activity, dated at around 1.95–1.91 Ga, has been interpreted as a magmatic arc recording closure of an ocean basin, although opinions concerning polarity, precise timing and relationships between formation and exhumation of the Lapland granulite belt diverge widely (Hörmann et al., 1980; Barbey et al., 1984; Gaál et al., 1989; Daly et al., 2001). (2) In northwestern Finland, in the Kittilä–Enontekiö area, the so-called Hetta complex includes a range of rock types and represent the rifted part of the northwestermost Karelia. The intrusive (5) Plutonic complexes that are clearly discordant and postorogenic with respect to deformation in Lapland include the 1.78-Ga Nattanen suite and Vainospää granite (Haapala et al., 1987). These although the most common rock types are tonalplutons. Very little is known of their tectonic setting but the heterogeneity of zircon populations and diverse nature of country rocks suggests that widespread inheritance frustrates the determination of precise emplacement ages (cf. Huhma, partial derivation from Archean lithosphere and were emplaced at high crustal levels, effectively delineating the distribution of Archean rocks at depth and providing a constraint on rates of postorogenic denudation, including exhumation of the Lapland granulite belt. (3) Synorogenic rocks are characterized by the 1.89–1.86-Ga Haaparanta suite. They are found in western Lapland on both sides of the Finnish–Swedish national border. The Haaparanta suite consists of two groups, monzonitic (gabbro, quartz monzodiorite, monzodiorite, monzonite, and quartz monzonite) and trondhjemitic (quartz diorite, tonalite, trondhjemite, and granodiorite; Lehtonen, 1984). Although emplacement ages are well constrained, both isotopically and from Mid-Proterozoic rifting Another rifting event of the Fennoscandian shield at ~1.65–1.57 Ga, long after the tectonics of the Svecofennian orogeny had ceased, resulted in the emplacement of voluminous rapakivi granites in southern Finland (e.g., Rämö and Haapala, 1995, and references therein). This process was related to a long-lasting magmatic underplating episode in the subcontinental mantle involving generation of both mantle and crustal melts. The ultimate tectonic cause of the magmatic underplating remains controversial, however. Plausible mechanisms include active or passive rifting, extensional collapse of orogen, and deep mantle plumes. Petrologically unstable domains in the lithospheric mantle (related to earlier or contemporaneous distant subduction zones) could also have controlled the loci of magmatism (Haapala and Rämö, 1992; Rämö and Haapala, 1995). The Fennoscandian rapakivi granites have recently been related to intermittent strong isotopic evidence of derivation from an Archean source (Hiltunen, 1982; Lehtonen, 1984; Huhma, 1986; Perttunen, 1991; Väänänen, 1998; Perttunen and Vaasjoki, 2001; Väänänen and Lehtonen, 2001). These rocks therefore have evidence for calc-alkaline magmatism within the former Karelian cratonic margin in northern Finland, in contrast to the situation farther south. (4) Lateorogenic granites are present throughout much of southern Lapland, between the Lapland 60 Fennoscandian shield (Åhäll et al., 2000). Roughly north–south trending magmatic arcs related to this postulated mechanism are located on the eastern Fennoscandian rapakivi granite complexes (Fig. 36). Thus a model of extensive long-time mantle upwelling and resultant periodic, migrating melting Fig. 36). This “inboard model”is, however, unable to account for the non-linear age distribution of the and deep crustal structures, remains the most plausible scenario (cf. Haapala et al., 2005). 61 62 PART II: FIELD TRIP STOP DESCRIPTIONS 63 64 DAY 1 (Monday September 12, 2005) Guide: O.T. Rämö Rämö, 1991; Vaasjoki et al., 1991; Jaala–Iitti— Salonsaari and Haapala, 1994; Salonsaari, 1995; Ahvenisto— Alviola et al., 1999). The Wiborg batholith itself (Fig. 40) is key rock types in the classic Wiborg rapakivi granite batholith of southeastern Finland. The batholith covers circa 19,000 km2 and forms a relatively thin of the crust. Roughly two-thirds of the batholith is situated in the Finnish territory, the remainder is in northwesternmost Russia, including the town of Vyborg (or Wiborg) according to which the batholith was originally named. Roughly one third of the batholith is located beneath the Gulf of Finland (Fig. 2; Koistinen, 1994). The Finnish mainland part of the batholith was mapped on 1:100,000 scale in the 1960’s and 1970’ s by the Geological Survey of Finland (e.g., Vorma, 1972; Simonen, 1987) and is currently the petrologically best-known part of it. Subsequently, detailed petrographic and geochemical studies have been carried out on three separate rapakivi complexes on rocks (gabbroids, anorthosite, diabase dikes), of the rapakivi association are subordinate. Roughly 80% of the Finnish part consists of wiborgite (or dark wiborgite). The remainder is pyterlite, porphyritic granite (biotite granite with angular alkali feldspar megacrysts), equigranular fayalite–biotite granite (tirilite), equigranular hornblende, hornblende– biotite, and biotite granite, porphyry aplite (leucocratic granite with occasional alkali feldspar megacrysts), and topaz-bearing alkali feldspar granite. On this trip, we will examine four rock types in the central part of the batholith: a topaz-bearing alkali feldspar granite and associated pegmatite, wiborgite, pyterlite, and anorthosite and leucogabbronorite including iridescent plagioclase (spectrolite). Stop 1/1: Topaz-bearing alkali feldspar granite and associated marginal pegmatite least slightly) older than the marginal equigranular granite and stockscheider pegmatite (Haapala and Lukkari, 2005). In terms of Nd isotope composition (Rämö, 1991), the granites are identical: εNd (at 1640 Ma) values are –0.2 ± 0.5 (porphyritic granite) and –0.3 ± 0.6 (equigranular granite). These initial ratios Kymi stock ~10 km north of the town of Kotka (Fig. 40). The Kymi stock is an oval, relatively small (6 km by 2.5 km) cupola-shaped intrusion of topaz-bearing alkali feldspar granite that sharply cuts the wiborgite, pyterlite, and porphyry aplite of the Wiborg batholith. The stock (Fig. 41) consists of two rock types (Haapala, 1977; Haapala and Lukkari, 2005): a porphyritic central granite and an equigranular marginal granite. Both are leucocratic alkali feldspar granites with Li-enriched dark mica and accessory topaz; the tin content of the micas is 250–300 ppm (Haapala, 1977). Accessory minerals include monazite, columbite, bastnaesite, thorite, molybdenite, and pyrochlore. Geochemically, the two granites are peraluminous and anomalously high in F, Li, Be, Ga, Rb, Sn, and Nb and low in Ti, Fe, Mg, Ba, Sr, and Zr (Haapala, 1977; Rieder et al., 1996; Haapala and Lukkari, 2005), with the equigranular granite showing a clearly more anomalous character than the porphyritic granite. The two granites do show a sharp mutual contact and the central porphyritic granite appears to be (at been measured for wiborgite in the south-central part of the batholith (e.g., Rämö, 1991). At the contact between the Kymi stock and the surrounding wiborgite and pyterlite, a <5m-thick zone of topaz-rich pegmatite granite and pegmatite (stockscheider) is present (Haapala, 1977; Kaartamo, 1996; Kaartamo et al., 1996). The main minerals in the stockscheider are K-feldspar (often amazonitic), quartz, albite (in two generations), biotite (mainly as extensive dendritic clusters), topaz, tourmaline, pegmatite belongs to the NYF-class of erný (1991) (Kaartamo et al., 1996) and has been quarried for gem-quality topaz. Both the granites of the Kymi stock and the 65 The Suomenniemi (Rämö, 1991), Ahvenisto (Alviola et al., 1999), Jaala–Iitti (Salonsaari, 1995), and Onas complexes are also 66 with the most intensively mineralized veins farthest away from the stock (e.g., Haapala, 1977). On the trip we will examine both granites and the stockscheider that are quarried in the southeastern part of the stock just east of highway 357. surrounding older rapakivi granites host greisen and quartz veins as well as irregular greisen bodies. The veins and bodies are associated with arsenopyrite, wolframite, beryl, genthelvite, as well as Pb, Zn, and Cu sulphides, and show sings of lateral zoning Stop 1/2: Wiborgite at Summa, Vehkalahti, south-central part of the Wiborg batholith A glacially-polished outcrop of wiborgite (the rapakivi granite proper) by a freeway ramp 3 km east of downtown Hamina. The rock is loaded with alkali feldspar megacrysts 1 cm to 10 cm in diameter; most of them are mantled by an oligoclase rim. There is, however, a tendency for the largest ovoids to lack mantles. Some megacrysts show multiple rims and, occasionally, oligoclase mantles are also found around rounded microgranite fragments. Quartz occurs in two generations: (1) short-prismatic small phenocrysts (pseudomorphs after high quartz) and silicates are hornblende and biotite. The wiborgite also contains narrow pegmatitic veins and vugs (~15 cm in diameter) with coarse quartz, alkali feldspar, The rock is fresh and good for sampling, yet the glacially-polished surface displays the rapakivi texture in a superb way as the oligoclase mantles have turned white owing to post-glacial weathering. Stop 1/3: Pyterlite at Virolahti, south-central part of the Wiborg batholith Extensive dimension stone quarry (Haikanvuori) in pyterlite by the Bay of Virolahti ~5 km west of the Russian border (Fig. 42). This pyterlite is texturally similar to the wiborgite inasmuch as the size and form of the alkali feldspar ovoids and the conspicuous drop quartz; only some of the alkali feldspar 67 Fig. 42. Geological sketch map of the Virolahti area in the southeastern part of the Wiborg batholith. Pyterlite quarries (including the target of STOP 1/3) are indicated. megacrysts are mantled by oligoclase, however. The rock is also more silicic than the wiborgite Kinnunen et al., 1987). The pyterlite is also cut by pegmatitic dikes (a couple of meters wide) with secondary calcite. Pyterlite at Virolahti has been quarried for dimension stone purposes since the 16th century; in the 19th century much of the rock was shipped to St. Petersburg. The current commercial name for the Virolahti pyterlite is Carmen Red. Characteristic features of the Virolahti pyterlite include pegmatite bodies and miarolitic cavities that contain, besides alkali feldspar and quartz, and some topaz and beryl but no muscovite (e.g., Stop 1/4: Anorthositic raft in wiborgite at Ylijärvi, Ylämaa, east-central part of the Wiborg batholith In the east central part of the Wiborg batholith at Ylämaa, a couple of large anorthosite rafts are found in wiborgite (Fig. 43). The rafts consist of anorthosite and leucogabbronoritic rock types and characteristically contain spectrolite (iridescent lab- radorite; e.g., Lahti, 1989), currently exploited as gem stone and facing stone material. We will examine a spectrolite quarry in the westernmost raft (please exercise extreme caution— the quarry walls are very loose). In the quarry, three gabbroic/an68 Fig. 43. Geological sketch map of the Ylämaa area in the east-central part of the Wiborg batholith. Ylijärvi anorthositic raft (the target of STOP 1/4) is indicated. orthositic rock types are present: coarse-grained anorthosite (plagioclase adcumulate) with minor orthopyroxene, clinopyroxene, oxide, and apatite is cut by (1) a coarse-grained leucogabbronorite and (2) a plagioclase-porphyritic leu- U–Pb zircon age of the anorthosite is 1633 ± 2 Ma (Suominen, 1991; Vaasjoki et al., 1991) and the initial εNd value is –0.4 ± 0.6 (Rämö, 1991), the associated granite has been dated at 1633 ± 5 Ma (Suominen, 1991) and it has an initial εNd value of –2.0 ± 0.4. After examination of the quarry, we will stop at the Ylämaa gem museum by highway 387 to take a closer look at spectrolite and different commercial brands of wiborgite. groudmass including late K-feldspar replacing plagioclase. The gabbroic and anorthositic rocks are cut by granite pegmatite dikes presumably related to the surrounding rapakivi granite. The 69 70 DAY 2 (Tuesday September 13, 2005) Guides: M.I. Kurhila, M. Nironen, O.T. Rämö tion in the physical appearance of the lateorogenic the granites of the easternmost part of the lateorogenic granite zone (Fig. 44). In this part the youngest intrusions of the whole belt are present; the emplacement ages are about 1.80 Ga or even younger (cf. Fig. 45). The granites illustrate well the varia- the geochemical and isotopic characteristics (cf. Figs. 46 through 48). The last stop of the day will be a ~1.79-Ga postorogenic monzogranitic dike in Ruokolahti. Stop 2/1: Keittomäki lateorogenic granite, Juva A roadcut about 20 km west of Sulkava town along highway 436. This is a grayish garnet-bearing microcline granite. Mineralogically, the Keittomäki granite deviates from other lateorogenic microcline granites in that it has no monazite and only a little zircon. It is richer in plagioclase and its microcline structure is less organized than in the other granites of the group. Anatase and spinel group oxides are abundant accessory minerals. However, the compositional, essentially low-angle layering is very characteristic of the lateorogenic granites, as are the abundant stratiform aggregates of relatively large garnet grains. Orientation (due to biotite and cordierite lineation) is generally weak and varying. The granite contains gneissic xenoliths and garnet clusters, and the grain size ranges from small to very coarse. There are also cross-cutting pegmatite dikes. Source rock attributes cannot be unequivocally determined on the basis of geochemical and mineral data alone. Although the rock has many features typical of S-type granites (e.g., A/CNK value 1.13, high SiO2 content, abundant garnet and muscovite), many features militate against a metapelitic origin (absence of monazite, low Th, elevated Ni and V content). An ion microprobe study of the zircons from this granite (Matti Kurhila, unpublished data) shows bimodality in terms of age. The majority of the spots form a somewhat scattered cluster between 1.87 Ga and 1.86 Ga. The younger population yields an age of about 1.79 Ga, which we interpret as the cooling age of the batholith. The granite is associated with widespread high-temperature, low-pressure metamorphism at 1.80–1.79 Ga and it is probable that the older U–Pb zircon age represents the main phase of the Svecofennian orogeny. The detrital zircons in the Svecofennian metasedimentary rocks typically show a wide age range extending into the Archean (e.g., Claesson et al., 1993; Lahtinen et al., 2002), whereas zircons from the Keittomäki granite do not display such a broad range of ages. Whole-rock Nd isotope compositions of the granite (O. Tapani Rämö, unpublished data) accord with those of the lateorogenic granites farther to the west. The TDM model age (DePaolo, 1981) of the rock is 2.19 Ga and the initial Nd (at 1790 Ma) value –0.9. Stop 2/2: The marginal phase of the Puruvesi granite, Herttuansaari, Kerimäki Outcrop on the shore of Lake Puruvesi near a dirt road. The Puruvesi granite batholith is located between the Archean Karelian craton and the Arc complex of southern Finland (labeled K and SAC, respectively, in the inset of Fig. 44). The batholith has a concentric structure, the margin being quite leucocratic and inhomogeneous compared to the granite of the central type (see description of Stop 2/3). The granite is very felsic, consisting mainly of quartz and microcline. The rock is generally me- dium-grained, but in places gradually coarsens into pegmatite grade; i.e., the pegmatite does not form distinct cross-cutting dikes. Mica gneiss forms patchy inclusions, with a preferred northwest orientation. Garnet is scarse, but locally forms rather dense aggregates; biotite and muscovite are also present. As much as 78% of the rock consists of SiO2, and surprisingly, Na level is elevated, which cordingly, there is a weak positive Eu anomaly (Fig. 71 47). The rock is only slightly peraluminous and its Fe/Mg ratio is extremely high for an orogenic granite (Fig. 46). Both the zircons and monazites record a ~1.80 Ga age for this granite. The zircons have inherited cores with a variety of Neoarchean and Paleoproterozoic ages, which indicate that the granite (or its precursor) was derived from a sedimentary source. However, the prominent 2.0–1.9-Ga population of many Svecofennian metasediments (Lahtinen et al., 2002) is almost totally absent. crustal origin for this granite. The initial Nd value er crustal material. The TDM model age (DePaolo, 1981) is 2.53 Ga (Fig. 48). of Day 2 are labeled with stars. The letters in the index map are: SAC— Arc complex of southern Finland, WAC— Arc complex al. (1997). Stop 2/3: The central phase of the Puruvesi granite, Rastiniemi, Kesälahti A small outcrop on the east coast of Lake Puruvesi, next to a ferryboat wharf. The granite is grayish, slightly porphyritic, homogeneous, fresh and undeformed. The K-feldspar megacrysts display a weak magmatic orientation. Two micas are present, biotite in much larger quantities. Garnet is virtually absent, although some of it is found in the each other and with the granite of the marginal type (Stop 2/2), i.e., 1.80 Ga. Again, the inherited zircons display Archean and Paleoproterozoic ages. The inheritance pattern is very similar to that of the granite at Stop 2/2, which, together with the same emplacement age, indicates that the granites were derived essentially from the same source. The Nd isotopes tell the same story. Initial εNd values are on the order of –6.2, complying with the marginal phase. The TDM model age (DePaolo, 1981) is 2.49 Ga, suggesting that Archean basement lies beneath the Proterozoic Puruvesi granite area. fairly rich in alkalis, A/CNK ratio being 1.08 (Fig. 46). There is a strong HREE depletion and a negative Eu anomaly, suggesting that both garnet and plagioclase were retained in the source. The zircon and monazite ages are identical with 72 Fig. 45. U–Pb ages of the granites of Day 2. Open symbols mark ion microprobe data and closed symbols multigrain isotope dilution data. Error bars are at 2 level. Unpublished data by Matti I. Kurhila. Fig. 46. FeOtot/(FeOtot+MgO) vs. SiO2 (wt.%) and A/CNK vs. SiO2 (wt.%) variation diagrams of the granites of Day 2. The postorogenic Eräjärvi granite is petrologically clearly different from the lateorogenic granites. A/CNK is molar Al2O3 / (CaO + Na2O + K2O). Unpublished data by Mikko Nironen and Matti I. Kurhila. Boundary of I- and S-type granitoids in the A/CNK [molar Al2O3 / (CaO + Na2O + K2O)] vs. SiO2 (wt.%) diagrams after Chappell and White (1974). Line separating the ferroan 73 Fig. 47. Chondrite-normalized REE diagram for the granites of Day 2. Unpublished data by Mikko Nironen and Matti I. Kurhila. Stop 2/4: The Valkamo layered granite, Imatra A roadcut near the Russian border showing a good example of a layered lateorogenic granite with alternating leucocratic and darker parts. There are pegmatite dikes that deflect the weak foliation in the granite, but the dikes are crosscutting rather than gradational in character. In addition there are abundant garnet aggregates, both stratiform and randomly dispersed. The grain size varies along with the composition. The darker layers show a preferred orientation caused by pinitized cordierite grains, and the leucocratic vein-like banding is often parallel to the orientation. The veins themselves have no orientation. On the basis of field observations it seems that the leucocratic parts represent low-temperature in situ melting of the parent granite. Geochemical evidence supports this, as the veins are very poor in REE (Fig. 47) and have a more evolved major element composition (Fig. 46). The monazites of the leucocratic parts record an age of 1.80 Ga, similar to the granites of the Lake Puruvesi (Stops 2/2 and 2/3). A bulk TIMS U–Pb analysis of the zircons is to some extent in accordance with this, although the results are very discordant and some fractions indicate zircon inheritance with 207Pb/ 206Pb ages over 1.9 Ga. The initial εNd value of the melanocratic granite is –1.4, and thus, the source rock was obviously different from that of the Puruvesi granites. Although the zircon U–Pb heterogeneity clearly indicates inheritance, the initial Nd isotope composition implies only a moderate input of older crustal material. Due to a rather high Sm/Nd ratio, the TDM model age (DePaolo, 1981) of the granite is also relatively high, 2.48 Ga. 74 Stop 2/5: The Eräjärvi postorogenic granite dike, Ruokolahti 46 and 47). It is slightly peraluminous and enriched in Ti and P (Nykänen, 1988). The bimodal magmatism commonly associated with postorogenic intrusions (Eklund et al., 1998) is also prominent in the area. Numerous small cogenetic lamprophyre dikes cross-cut the gneissic country rocks, but we will not Ourcrops and a roadcut by a sealed road number 438. In the early 1940’s, this rock was quarried for anti-tank barriers. The intrusion is a small sheetlike body that cuts the synorogenic gneissic rocks sharply; both the dike and the country rocks can be examined at this stop. The dike is ~4.5 km long and 300 m wide and trends northeast. The only sign of deformation is minor faulting perpendicular to strike. On aeromagnetic images, the dike appears as a distinct positive anomaly. The contact with the country rock is visible, and a ~0.5 m wide darker, biotite- and plagioclase-rich contact variety can be seen. The rock is medium-grained and in places there are scattered alkali feldspar and plagioclase phenocrysts. The color of the rock varies between red and gray. Locally, small (2–5 cm in diameter) garnet– cordierite gneiss xenoliths may be observed. Plagioclase (An20), alkali feldspar, quartz and biotite are the main minerals, chlorite, muscovite, apatite, A zircon age of 1792 ± 5 Ma (Nykänen, 1988; recalculated by M. Vaasjoki) has been obtained for this granite. The result partly overlaps with the ages of the lateorogenic granites further northeast. A whole-rock Nd isotope analysis gave an Nd (at 1792 Ma) value of +0.3 (Fig. 48). This demonstrates that the postorogenic magmatism within the arc complex of southern Finland is slightly more juvenile compared to the lateorogenic one in the same area. The host rock is a migmatitic gneiss that has been metamorphosed in high-T, low-P granulite facies. The assemblage with abundant sillimanite and corgarnet = cordierite + K-feldspar + melt. The folding in the gneiss has deformed at least one foliation, porphyroblasts, and leucosome veins. Geochemically, the Eräjärvi granite displays typical features of the postorogenic granites (Figs. Fig. 48. Nd isotope evolution trends of the granites of Day 2. The depleted mantle line is from DePaolo (1981), CHUR denotes Chondritic Uniform Reservoir (DePaolo and Wasserburg, 1976). Unpublished data by O. Tapani Rämö. 75 76 DAY 3 (Wednesday September 14, 2005) Guides: M. Nironen, B.A. Elliott, O.T. Rämö pyroxene-free hornblende quartz monzonite/granite forming the bulk of the interior part of the pluton (Fig. 49). In the east-central part of the pluton, evolved, relatively felsic granite is found and cut by aplitic microgranite dikes. The U–Pb age of the Jämsä pluton is 1878 ± 15 Ma (Rämö et al., 2001a), the εNd (at 1875 Ma) values range from –0.1 to –0.4, and the TDM model ages (DePaolo, 1981) from 2.18 to 2.22 Ga. Rb–Sr data on four samples from the pluton (two from the margin, two from the center) indicate a remarkably low initial 87Sr/86Sr of 0.7030 ± 0.0009 (Fig. 50). Furthermore, Rb–Sr data on the aplitic microgranite cutting the monzogranite in the central part of the pluton suggest that the Rb–Sr isotopic system was stabilized ~1810 Ma ago. ine various types of synorogenic rocks in the Central Finland granitoid complex: one synkinematic, intensely foliated granodiorite, and two postkinematic intrusions. In particular, we will study the petrographic and geochemical changes in the postkinethe Central Finland granitoid complex (see Elliott et al., 1998; Rämö et al., 2001a; Elliott, 2003; Fig. 49). The synkinematic country rock granitoid of the monzonites and granites that constitute the pluton itself thereafter from margin to center. The Jämsä pluton covers an area of ~50 km2 and consists of a 0.5–1 km wide margin of pyroxenebearing quartz monzonite that grades into coarse Stop 3/1: Type 2 Puula pluton at Sokkasenmäki The outcrop is a dimension stone quarry 200 m east of a dirt road in the southeastern part of the Island of Väisälänsaari. It represents the relatively large (~450 km2) and homogeneous Puula pluton dikes as well as relatively large plutonic bodies of intermediate composition are found on the glacially polished outcrops. The main minerals are alkali feldspar, plagioclase, quartz, and biotite, with accessory hornblende, apatite, and zircon. The SiO 2 of the Puula pluton is from 62 wt.% to 65 wt.%, A/CNK ranges from 1.02 to 1.03 and Fe/(Fe+Mg) from 0.82 to 0.85, the εNd (at 1875 Ma) value is –0.5, and the TDM model age (DePaolo, 1981) is 2.17 Ga. The pluton has a heterogeneous zircon polulation, and has yielded a 207Pb/206Pb age of 1891 ± 1 Ma (Rämö et al., 2001a). granitoid complex. The gray, coarse-porphyritic granite is non-foliated and contains abundant subhedral to anhedral alkali feldspar megacrysts 1–4 cm in diameter, and smaller (1–2 cm) plagioclase megacrysts. Some of the alkali feldspar megadiate enclaves, schist xenoliths, and intermediate Stop 3/2: Synkinematic granodiorite at Kollinkangas The outcrop that has been quarried for road construction material is along a dirt road 2 km north from Road 6031, 5 km west of the town of Jämsä. The gray, medium-grained granodiorite is a typical representative of a synkinematic rock of the CFGC rock is strongly foliated and small shear zones deform the foliation. The main minerals are plagioclase, quartz, hornblende, and biotite, with accessory titanite, opaque minerals, apatite, and zircon. The εNd (at 1875 Ma) value of the granodiorite is –1.6 and the TDM model age (DePaolo, 1981) is 2.29 Ga. these are clearly xenoliths of volcanic rock. The 77 Stop 3/3: Type 3 Jämsä pluton, margin A roadcut by Road 604 just north of downtown Jämsä showing the marginal assemblage of the Jämsä pluton, a dark brown, slightly porphyritic quartz monzonite. The main minerals include perthitic or- single grain plagioclase mantles have been observed as in the classic rapakivi granites of southern Finland. The contact between the marginal assemblage and the central Jämsä granite is gradational over a small area (within meters), gradually losing olivine and pyroxene to amphibole, and marked by a distinct decrease in magnetic susceptibility from the margin towards the center. The SiO2 content of the margin of the Jämsä pluton is from 58 wt.% to 64 wt.%, the A/ CNK value is from 0.88 to 0.94, and the Fe/(Fe+Mg) ratio is from 0.90 to 0.93. The εNd (at 1875 Ma) value of this marginal quartz monzonite is –0.1 and the TDM model age is 2.18 Ga. silicates: ferro-edenitic to hastingsitic hornblende, annite biotite, ferrosilite orthopyroxene, fayalitic olivine, and ferro-augite clinopyroxene. Olivine and pyroxene are commonly seen as relicts surrounded or being replaced by amphibole, but are also found as independent grains. Biotite and amphibole are commonly interstitial, and sometimes found as small inclusions in larger alkali feldspar and plagioclase. Alkali feldspars are sometimes rimmed by a composite 78 Stop 3/4: Type 3 Jämsä pluton, center in the marginal assemblage. Small aggregates of A roadcut by Highway 9 ~5 km northeast of downtown Jämsä. The central Jämsä granite is a leucocratic (white to pink), porphyritic granite. The main minerals are microcline, plagioclase, quartz, ferro-edenitic to hastingsitic hornblende, and annite biotite, with accessory titanite. Amphi- out the central assemblage, becoming more common toward the evolved quartz-rich phase of the pluton. The foliated central granite (presumably magmatic foliation) is cut by aplitic microgranite dikes probably related to the pluton. The SiO 2 of the central granite ranges from 63 wt.% to 66 wt.%, the A/CNK value is from 0.90 to 1.01, and the Fe/(Fe+Mg) ratio is from 0.88 to 0.89. The εNd (at 1875 Ma) values of the central granite and microgranite are –0.4 and –0.6, respectively. out the central granite, but biotite becomes more common toward the center. Alkali feldspars surrounded by composite mantles of quartz and plagioclase are also found in the central granite, and myrmekitic intergrowths are more common than Fig. 50. Rb–Sr isochron diagram for the Jämsä postkinematic pluton. See text for details. Data from Rämö et al. (2001a). Stop 3/5: Type 3 Jämsä pluton, evolved center An outcrop in the forest in the east-central part of the pluton south of Juoksulahti, east of Highway 9. The evolved central assemblage of the pluton is a leucocratic, coarse grained, quartz-rich granite. The main minerals include microcline, plagioclase, quartz, biotite, and minor amounts of hornblende, with accessory titanite, and allanite and epidote associated with late stage fracturing. Feldspars are heavily sericitized, biotites are highly altered, and myrmekitic intergrowths central assemblage. These bands are rich in amphibole and biotite, and contain more zircon, apatite, and Fe–Ti oxides than the other rock types of the Jämsä granite. have separated from the quartz-rich evolved granite through local differentiation. 79 80 DAY 4 (Thursday September 15, 2005) Guides: J. Halla, P. Sorjonen-Ward, O. Äikäs Fennoscandian shield in east-central Finland and Archean sanukitoid-type granitoids on the western amine Paleoproterozic tonalitic dikes at the border zone of the Proterozoic and Archean domains of the Stop 4/1: Microtonalite dikes at Kivennapa The bedrock exposures at Kivennapa provide an insight into the complex setting of the microtonalite dikes (Figs. 51 and 52). Typical composite dike lithologic units ranging from migmatitic and folded/boudinaged Paleoproterozoic mica schist to late granite pegmatite with successive intrusive phases of Juurus tonalite, microtonalites, granodiorite, and granite. A large erratic boulder of microtonalite shows porphyritic texture typical of numerous dikes in the Juankoski map sheet area. parts, intruding and brecciating the Juurus tonalite. A later dike of the leucotonalitic material crosscuts the darker microtonalite. Complex outcrop with Fig. 51. Detailed map of a microtonalite outcrop in Kivennapa (Juankoski). Map: Olli Äikäs (2003). 81 Fig. 52. Typical composite dike of microtonalite intruding the Juurus tonalite at Kivennapa, Juankoski. Photo: Olli Äikäs. Stop 4/2: The Pisa augen gneisses— Paleoproterozoic deformation of K-feldspar megacrystic Neoarchean sanukitoids General description gray or white K-feldspar megacrysts. In places the megacrysts are abundant and form aggregates. Particularly in the northern part of the area, typically reddish megacrysts often form aggregates that may change gradually to more homogeneous, coarsegrained granite dikes or lenses. Occasionally the augen are completely absent, especially near the Säyneinen schist belt, in which case the rock is a banded gneiss. Recent studies (Halla, 2002, 2005) have shown that these gneisses are deformed Neoarchean sanukitoid series granodiorites and monzodiorites. The petrographic features and Pb isotopic composition of the megacrysts indicate that they are porphyroclasts representing deformed Neoarchean phenocrysts of magmatic origin. The geochemical and isotopic features and the genesis of sanukitoids are discussed in Section 3.2 in this volume. Archean K-feldspar megacrystic gneisses are found in the southern part of the Karelian Domain in the Rautavaara Archean area of the Iisalmi terrain (Fig. 53). These gneisses have been traditionally termed as the Pisa augen gneisses due to their appearance and because they are found mainly in the area (~20 km by 10 km) around the Paleoproterozoic Pisa schist belt. On the northern and western borders of the area the augen gneisses change more or less gradually to basement gneisses. Towards the eastern border of the area they change in appearance to banded hornblende- and mica-bearing Säyneinen schist belt. The gneisses vary considerably in appearance but are typically schistose, dark gray rocks containing diverse amounts of red, light 82 K-feldspar porphyroclasts sion indicate lower recrystallization rates with respect to strain rate compared with the eastern part. Based on this observation, the Nilsiä augen gneisses are roughly divided into two groups: western group with lower recrystallization rates and eastern group with higher recrystallization rates with respect to strain rate. The western group includes also reddish augen gneisses from the northern part of the area with indications of local granitization and alteration processes. The variable appearance of the Nilsiä augen gneisses is due to the different types of porphyroclasts developed in response to shear strain (Fig. 54). In the northern and western parts (Stop 2), the larger augen commonly represent θ-type porphyroclasts without real wings, or incipient overall δ-type porphyroclasts with relatively short and narrow, curved wings suggesting slow recrystallization rates with respect to strain rate (Fig. 55A). Smaller porphyroclasts show more developed σ-types of wings. Some of the large megacrysts have retained their original rectangular shape. In the eastern part of the Nilsiä area, the porphyroclasts represent overall δ-type and, more commonly, overall σ- and φ-types with longer and thicker wedge-shaped wings indicating faster recrystallization rates with respect to strain rate compared with porphyroclasts in northern Microstructures Large porphyroclasts of the western group (Stop 4/2) of the Nilsiä augen gneisses are K-feldspar megacrysts of Carlsbad-twinned perthitic microshowing sharp contacts between the core and the mantle (Fig. 55C). Small myrmekitic intergrowths of oligoclase and quartz along the margins of the megacrysts are common. Relatively slow, smallscale grain boundary migration (GBM) recrystallization (for more detailed description of deformation mechanisms, see Passchier and Trouw, 1996) in the temperature regime 1 of Hirth and Tullis (1992) along the margins of the original megacrysts has produced an incipient core-and-mantle gen-like appearance is outlined by granoblastic quartz–feldspar aggregates of the recrystallized mantle extending away from the core. The types of K-feldspar porphyroclasts in the northern and western part of the Nilsiä intru- Fig. 53. Geological map showing the location of the Nilsiä and Lieksa sanukitoids. Inset: map of southern Finland showing the Paleoproterozoic Svecofennian domain (gray), the Archean Karelian domain (white). 83 high 208Pb/204 Pb ratios with respect to 206Pb/204Pb ratios, developed in response to long term enrichment of Th over U in the rocks, and (2) low 207 Pb/204Pb and 206Pb/204Pb ratios due to the prolonged period of time that has elapsed since the U-depletion. K-feldspars in the Nilsiä sanukitoids have high 208 Pb/204Pb ratios with respect to the 206Pb/204 Pb ratios. The enrichment of 208Pb is thought not to be an initial feature of the K-feldspars; instead it seems to be a feature related to deformation. The 232Th–208Pb model ages calculated for K-feldspar–whole rock pairs of the Nilsiä eastern group range from 2.25 Ga to 1.84 Ga and include the oldest model ages in the Nilsiä area. The youngest model age of 1.72 Ga is found in the western part of the area where recrystallization rates are slower and Paleoproterozoic local granitization and alteration is a common feature, especially in the north. The 232 Th–208Pb model ages for the Nilsiä western group range from 1.93 Ga to 1.72 Ga. structure with a sharp boundary around the core without transitional zones showing subgrain structures. Microcline is also abundant in the matrix, where it occurs in recrystallized aggregates and as recrystallized matrix consists of microcline, plagioclase, quartz, chloritized biotite, and minor hornblende and epidote. In the northern part, where local granitization is common, the matrix contains also muscovite and the K-feldspar megacrysts are reddish in colour due to alteration processes. More deformed porphyroclasts, especially of the eastern group, have thicker recrystallized mantles indicating higher recrystallization rates with respect to strain rate. The cores of the porphyroclasts are Carlsbad-twinned, perthitic microcline grains. The margins of the original K-feldspar grains and internal zones of deformation have commonly undergone extensive GBM recrystallization in the temperature regime 1 of Hirth and Tullis (1992) leading to the formation of thick, recrystallized mantles around the original grains (Fig. 55D). The recrystallized mantle extends away from the core forming tails or wings in the matrix of microcline, plagioclase, quartz, chloritized biotite, and minor hornblende and epidote. In the most deformed parts of the rock, altered ghosts of completely re- Concluding remarks The microstructural evidence for the Nilsiä sanukitoids indicate that the K-feldspars have recrystallized by GBM (grain boundary migration) in the low temperature regime of recrystallization-accommodated dislocation creep (Regime 1 of Hirth and Tullis, 1992), indicating deformation temperatures of 400−500 °C. At 1.9 Ga, 208Pb-rich lead evolved in high Th/U sites (probably grain boundaries and fractures), entered feldspar by GBM recrystallization of the original magmatic K-feldspar grains during retrograde metamorphism related to the Paleoproterozoic Svecofennian orogeny. matrix. Pb isotopes Previous studies (Halla, 2005, 2002) have shown that the Nilsiä and Lieksa granitoids have distinctive whole-rock Pb isotopic characteristics with (1) θ) type porphyroclasts have round to elliptic mantles but no real wings. Phi (φ) type porphyroclasts have straight centerlines and the wings are symmetrical with respect to the porphyroclast. Sigma (σ) type porphyroclasts have wide mantles near the porphyroclast and parallel wings. The wings have gently curved centerlines and they are asymmetric; the wing extends from the top of one side and from the bottom of the opposite side (known as stair-stepping). Delta (δ) type porphyroclasts have narrow, strongly curved wings that are asymmetric with respect to the porphyroclasts. Complex porphyroclasts develop several sets of wings. 84 grained matrix. The wings of the porphyroclasts, which commonly represent overall θ- or incipient δ-type, are poorly developed indicating slow recrystallization rates with respect to strain rate. (B) The porphyroclasts in the eastern part of the area are more developed winged porphyroclasts of overall δ-, σ-, or φ–types indicating faster recrystallization rates relative to strain rate. (C) K-feldspar megacryst from the western part of the area with relatively thin recrystallized margin. Note the sharp boundary around the core. (D) Porphyroclast showing a more developed mantle-and-core structure. Fine-grained recrystallized wings extend away from the microcline core parallel to the matrix foliation. The matrix foliation wraps around the porphyrorecrystallization-accommodated dislocation creep (Regime 1 of Hirth and Tullis, 1992) indicating a deformation temperature of 400–500 °C (low- to medium-grade conditions). 85 Stop 4/3: Neoarchean sanukitoids of the Lieksa complex in the Ilomantsi terrain (Fig. 56D) are commonly Carlsbad-twinned perthitic orthoclase, occasionally microcline, containing euhedral inclusions of plagioclase and hornblende. Smaller grains are antiperthitic subhedral plagiocla- General description The eastern part of the Lieksa complex of the western Ilomantsi terrain (Fig. 53) includes undeformed porphyritic high-grade granodiorites (charno-enderbites) containing orthoclase megacrysts and pyroxenes (Stop 4/3) and protomylonitic to mylonitic gneisses that have undergone deformation and retrograde metamorphism. Porphyritic granodiorites are especially abundant around Lake Koitere and are therefore also known as the Koitere granodiorites. Granulite-facies supracrustal enclaves and very low U-content of both the granodiorites and gneisses indicate the presence of an extensive highgrade terrain. The undeformed orthopyroxene-bearing granodiorites (charno-ederbites) and retrograde gneisses exhibit similar geochemical characteristic, which supports the assumption that undeformed high-grade charno-enderbites represent the protolith of the retrograde gneisses. The geochemical features of the Lieksa granitoids are similar to those of the Nilsiä sanukitoid series granodiorites (Halla, 2005) indicating that both the Lieksa granodiorites and gneisses belong to the sanukitoid-series granitoids. The geochemical and isotopic features and the genesis of sanukitoids are discussed in Section 3.2. green clinopyroxene and in places also orthopyroxene. Incipient recrystallization along grain boundaries of the megacrysts is common, but mantle-andcore structures are not developed yet. Deformed granitoids of the protomylonitic stage (Fig. 556E) contain Carlsbad-twinned perthitic microcline megacrysts and smaller, antiperthitic plagioclase megacrysts showing simple twinning and containing abundant small epidote grains. In protomylonitic gneisses, the feldspar grains are separated axes of recrystallized porphyroclasts. The matrix consists of feldspars, quartz, dark green and often chloritized biotite, epidote, chlorite, and hornblende. along original grain boundaries and along internal deformation bands, progressively replacing original grains. Progressive strain resulted in grains exhibiting a core-and-mantle structure. The mantle forms by small-scale grain boundary migration (GBM) recrystallization of the K-feldspar rim in the temperature regime 1 of Hirth and Tullis (1992), possibly with incorporation of matrix material (by grain boundary sliding and diffusion). With increasing deformation and the resulting recrystallization-accommodated dislocation creep in the temperature regime 1 of Hirth and Tullis (1992), the original grains gradually decrease in size and K-feldspar porphyroclasts The dark-colored, undeformed charno-enderbites of the Lieksa area (Fig. 56A) containing well-preserved, undeformed orthoclase megacrysts represent the protolith of the adjacent variably deformed, lighter-colored gneisses. In the less deformed parts of the shear zone between the high-grade blocks, granitoids show abundant σ-type porphyroclasts and S–C fabrics indicating a protomylonitic stage of deformation (Fig. 56B). The more deformed parts of the shear zone show strongly elongated recrystallized quartzo-feldspathic ribbons (Fig. 56C). crystallized grains. In the more advanced stage of deformation (Fig. 56F), the granitoids show strongly elongated recrystallized quartzo-feldspathic ribbons containing small cores of the original feldspar grains. The size of the original grains has been further reduced by progressive recrystallization of the porphyroclasts. Recrystallization-accommodated dislocation creep produces strain softening of initially coarsegrained aggregates, and tends to partition strain Microstructures Three main stages of deformation can be distinguished in the progressive development of porphyritic granodiorites into strongly deformed gneisses: (1) the initial stage, (2) the protomylonitic stage, and (3) the advanced stage. The megacrysts in the initial undeformed stage 86 Fig. 56. Hand specimens and photomicrographs of the Lieksa sanukitoids. (A) Undeformed high-grade charno-enderbite with well-preserved orthoclase megacrysts. (B) Retrograde gneiss showing S–C fabrics and abundant overall σ-type porpyroclasts tened quartz–feldspar ribbons indicating a more advanced stage of deformation. (D) Undeformed porphyritic granitoid. The large grain is a Carlsbad-twinned perthitic orthoclase phenocryst containing euhedral inclusions of plagioclase and hornblende. Smaller grains are antiperthitic plagioclase. (E) Deformed granitoid of the protomylonitic stage of deformation showing incipigrains are further reduced in size by progressive recrystallization of the porphyroclasts with increasing deformation and the resulting recrystallization-accommodated dislocation creep (Regime 1 of Hirth and Tullis, 1992). 87 ratios due to the long period of U-depletion. 232 Th–208Pb model ages of 2.73 Ga and 2.71 Ga calculated for the Lieksa K-feldspar megacrysts of the initial undeformed stage (Stage 1) are consistent with the U–Pb zircon age of 2733 ± 29 Ma (Halla, 2002) obtained for the Lieksa granitoids. The protomylonitic gneisses (Stage 2) have mixed model ages of 2.22–2.16 Ga, and the sample showing most advanced deformation (Stage 3) has a model age of 1.85 Ga, which coincides with the timing of the Paleoproterozoic Svecofennian orogeny. The Th–Pb model ages for the Lieksa granitoids seem to correlate with this stage of deformation. grains enhances the access of water and progression of the replacement and softening reactions. Original grains are gradually reduced in size by progressive recrystallization. Strain softening may continue until the aggregate is completely recrystallized and the rock appears as a banded gneiss. All the variably deformed granitoids in the Nilsiä and Lieksa areas show recrystallization in the temperature regime 1 of Hirth and Tullis (1992) indicating deformation temperatures of 400−500 °C. The existence of undeformed granulitic protoliths between zones of intensively deformed gneisses in Archean high-grade terrains may well be explained by strain softening processes (e.g., grain-size reduction, rotation of grains, formation Concluding remarks ening). The balance between strain softening and strain hardening, controlled by strain rate and temperature, determines whether a shear zone develops as a thin zone of very strained rocks or a wider zone of less deformed rocks. The microstructural evidence for the Lieksa sanukitoids indicate that the K-feldspars have recrystallized by GBM (grain boundary migration) in the low temperature regime of recrystallization-accommodated dislocation creep (Regime 1 of Hirth and Tullis, 1992) indicating deformation temperatures of 400−500 °C (similar to the Nilsiä augen gneisses). At 1.9 Ga, 208Pb-rich lead evolved in high Th/U sites (probably grain boundaries and fractures) in the rock entered the feldspar by GBM recrystallization of the original magmatic K-feldspar grains during retrograde metamorphism related to the Paleoproterozoic Svecofennian orogeny. Pb isotopes The Lieksa granitoids have whole-rock Pb isotopic characteristics similar to those of the Nilsiä augen gneisses with (1) high 208 Pb/204 Pb ratios with respect to 206Pb/204Pb ratios, developed in response to long term enrichment of Th over U in the rocks, and (2) low 207 Pb/204 Pb and 206 Pb/204Pb 88 DAY 5 (Friday September 16, 2005) Guides: A. Käpyaho, L.S. Lauri, O.T. Rämö Since the classic work of Kouvo (1958), several radiogenic isotopic methods have been applied to solve the ages and origin of the crust in eastern Finland. These include Rb–Sr (e.g., Martin and Querré, 1984), Sm–Nd (e.g., Gruau et al., 1992), Lu–Hf (Patchett et al., 1981), U–Pb (e.g., Hyppönen, 1983; Luukkonen, 1988, 2001), and K–Ar (Kontinen et al., 1992) determinations. Some con- ent plutonic phases determined on both methods appears to be somewhat similar. Recently, the zircon ages and sources of some plutons have been studied by using the secondary-ion mass spectrometry (SIMS) and Nd isotopes (Käpyaho et al., ages on plutonic rocks from Kuhmo district have caused controversy and presently the U–Pb dat- of the Neoarchean plutonism of the Kuhmo district from >2.8 Ga to 2.44 Ga will be outlined and the similarities and contrasts between the modern and Archean granitoid rocks will be discussed. In addition, we will examine a 2.43-Ga A-type granite that geochemically and petrographically resembles the classic mid-Proterozoic rapakivi granites of southern Finland. sources have contributed to the plutonic rocks in the Kuhmo district. method for solving the actual crystallization and source ages of the plutons, whereas the Rb–Sr method in most cases records secondary effects (Vaasjoki, 1988; Halliday et al., 1988). Nevertheless, the sequence of emplacement of the differ- Stop 5/1: Arola leucogranite Ion microprobe dating has revealed a heterogeneous zircon population and therefore only a rough age estimate of 2.69 Ga is available (Käpyaho et al., in review). The initial εNd value of this leucogranite is ~ –1. As demonstrated by Querré (1985), this granite closely resembles the Himalayan leucogranites. The Arola granite is pink, medium-grained and equigranular leucogranite composed of quartz, microcline, oligoclase, muscovite, and biotite. Accessories are zircon, rutile, magnetite, epidote, and calcite. This granite is slightly peraluminous, relatively high in silica (up to 76 wt.%; Querré 1985), and very depleted in the HREE (see Section 3.3). Stop 5/2: Arola granodiorite The Arola granodiorite is a microcline-porphyritic granodiorite that typically contains LILE- elevated LILE contents as well. This intrusion has been dated by using the conventional multigrain U–Pb zircon method and the age of 2734 ± 3 Ma is considered to represent the emplacement age of this pluton (Hyppönen, 1983), whereas concordant titanites register an age of ~2.69 Ga. The initial εNd value of this pluton is around +1. On the basis of geochemical data (Querré, 1985), Moyen et al. (2001) suggested that this intrusion belongs to the sanukitoid suite. microcline grains (sometimes megacrysts) are often oriented and the groundmass that consists of biotite and plagioclase shows a prominent schistosity. The granodiorite is metaluminous and the Mg number [Mg/(Mg + Fe tot)×100] is generally over 50. The silica range is typically between 66 wt.% and 69 wt.% and the rock shows generally 89 tive to the belt. In (B), three early Paleoproterozoic anorogenic A-type granite plutons (Tuliniemet, Kikonvaara, Iso-Kyllönen) Stop 5/3: Kuusamonkylä tonalitic gneiss Kuusamonkylä tonalitic gneiss is gray and equigranular. It comprises quartz, plagioclase, and biotite and accessory zircon, apatite, allanite, and epidote. On this outcrop, schistosity and felsic dikes are folded and leucosome formation is in progress. The Kuusamonkylä gneiss is slightly peraluminous (A/CNK 1.0 to 1.1) and the silica ranges from 69 wt.% to 72 wt.% (Martin, 1987a). This tonalite is depleted in HREE and, as concluded by Martin (1985, 1987a), garnet in the residue is likely. The pluton has been dated by ion microprobe (dating location 5 km north from the present outcrop) and has a U–Pb age of 2.74 Ga (Käpyaho et al., in review), age of 2.65 ± 0.3 Ga (Martin, 1985). The initial εNd value of the gneiss is +1. 90 Stop 5/4: ~2.43-Ga A-type granite at Tuliniemet The Tuliniemet granite belongs to a series of small early Paleoproterozoic K-rich granite intrusions (Tuliniemet, Kyllönen, and Kikonvaara plutons) that cut sharply the Archean metamorphic bedrock just east of the Kuhmo–Suomussalmi greenstone belt (Fig. 57). These plutons are associated with granite porphyry dikes that cut both the granites and the surrounding Archean rocks. U–Pb mineral data, however, indicate similar crystallization ages for both, on the order of 2430–2420 Ma (Luukkonen, 1988; Irmeli Mänttäri, unpublished data). This felsic magmatism is roughly The Tuliniemet granite is a porphyritic, coarse- Some of the alkali feldspar megacrysts (diameter 2–5 cm) are mantled by plagioclase (rapakivi texture). The marginal part of the Tuliniemet intrusion is characterized by an equigranular, mediumgrained biotite granite that is enriched in certain trace elements (e.g., Rb, Th, U). The Nd isotope systematics of these A-type plutons and the associated felsic dikes have been affected by a rather strong Proterozoic (Svecofennian) overprint; initial (magmatic) εNd values of the coarse-grained granites, however, probably range from –2.5 to +0.7, averaging –1.3 ± 1.2 (1σ). trusions farther to the north (Fig. 16) and may be related to the rifting of the Archean craton (cf. Iljina and Hanski, 2005). Stop 5/5: Kaihlankylä migmatite and contains 72 wt.% silica; the Mg number is 49. Both leucosome and mesosome are depleted in the HREE. Coarse-grained massive amphibole batches contain 48 wt.% silica and their Mg number is 73. Unpublished ion-probe U–Pb data from a nearby locality show an age of 2.94 Ga for the mesosome. Migmatite in Kaihlankylä quarry is polydeformed and metatexitic. Dark gray mesosome consists of biotite and amphibole and the thickness of the layers varies from a few mm to several tens of cm. The mesosome has 60 wt.% silica and an A/CNK value of 0.85. The leucosome is leucogranodioritic or leucogranitic and peraluminous 91 92 DAY 6 (Saturday September 17, 2005) Guides: P. Sorjonen-Ward, O.T. Rämö back to Helsinki from the Kuhmo area, stopping on the way at the Kuopio airport for participants with described (Kontinen, 1987) and remains to serve as a genuine example of the outcome of Precambrian plate tectonic processes. We will also have ample time for discussion on the bus as we drive south. The estimated time of arrival in Helsinki is 6 PM on Saturday evening. stops will be in the program. However, if desired and time permits, we may stop by the ~1.95-Ga Jormua mantle section peridotites at Kontiomäki. Jor- 93 94 PART III: ACKNOWLEDGMENTS AND REFERENCES 95 96 ACKNOWLEDGMENTS We are thankful to the Coordinator of Eurogranites, Professor Bernard Bonin, for the opportunity of aremy of Finland, the Geological Survey of Finland, the University of Helsinki, Palin Granit Oy, and IGCP Project 510 (A-type Granites and Related Rocks through Time)— this is gratefully acknowledged. We are obliged to Drs. Hannu Huhma and Irmeli Mänttäri of the Geological Survey of Finland for sharing unpublished Nd and U–Pb isotope data with us, to Professor Martti Lehtinen of the Geological Museum, University of Helsinki for XRD determinations, and to Dr. Pentti Hölttä (Geological Survey of Finland), Dr. Annakaisa Korja (Institute of Seismology, University of Helsinki), Ms. Elina Arponen,, and Mr. Hannu Lauri for comments and discussions. We thank Dr. Tapio Ruotoistenmäki of the Geological Survey of A. Elliott (University of North Alabama) for volunteering to act as a guide on Day 3. Mr. Jukka Lehtinen assisted with photography, which is gratefully acknowledged. The late Matti Vaasjoki1 participated in the team. This guide is a contribution to IGCP Project 510. 1 As a Geological Survey of Finland geochronologist, Matti Vaasjoki’ s contribution was instrumental in acquiring and interpret- 97 98 REFERENCES the Royal Society of Edinburgh: Earth Sciences 92, 201–228. Artemenko, G.V., Lobach-Zhuchenko, S.B., Krylov, I.N., Orsa, V.I., 2003. Archean high-Mg granitoids (sanukitoids) in the Ukrainian Shield and its comparison with rocks of TTG suite. Geophysical Research Abstracts 5. Abstracts of the Contributions of the EGS-AGU-EUG Joint Assembly, Nice, France, 06-11 April 2003 (CD-ROM). European Geophysical Society. Balashov, Yu.A., Bayanova, T.B., Mitrofanov, F.P., 1993. 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(Eds.), Fourth 109 110 PART IV: APPENDIX 111 112 Field trip stop coordinates Stop # Finnish National Grid Northing Finnish National Grid Easting Latitude [oN] Longitude [oE] 1/1 6717.500 3493.600 60.56804o 26.88019o 1/2 6717.569 3507.226 60.56865o 27.12867o 1/3 6715.250 3538.000 60.54612o 27.68935o 1/4 6740.800 3546.250 60.77454o 27.84566o 2/1 6854.152 3561.457 61.78950o 28.16166o 2/2 6867.137 4472.389 61.90999o 29.47154o 2/3 6874.914 4485.405 61.98049o 29.71857o 2/4 6787.269 4442.539 61.19006o 28.92861o 2/5 6817.708 4434.642 61.46192o 28.77117o 3/1 6850.011 3492.114 61.75717o 26.84747o 3/2 6864.565 2558.019 61.88338o 25.09969o 3/3 6863.697 2564.262 61.87460o 25.21805o 3/4 6869.450 2571.508 61.92492o 25.35801o 3/5 6869.139 2570.780 61.92226o 25.34402o 4/1 6996.705 3550.566 63.06995o 27.99693o 4/2 7017.319 4413.580 63.24803o 28.27659o 4/3 7019.072 4519.735 63.27366o 30.38993o 5/1 7151.051 4450.780 64.45454o 28.97409o 5/2 7150.469 4452.564 64.44958o 29.01132o 5/3 7147.564 4464.578 64.42499o 29.26155o 5/4 7164.892 4468.259 64.58077o 29.33417o 5/5 7143.947 4475.220 64.39349o 29.48300o 113 114 PART V: NOTES 115 116 Day 1 117 118 Day 2 119 120 Day 3 121 122 Day 4 123 124 Day 5 125 126 Day 6 127 128
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