Complex Ions 1. Concentrated (15M) ammonia solution is added in excess to a solution of copper(I1) nitrate. 2. An excess of nitric acid solution is added to a solution of tetraaminecopper(I1) sulfate. Y h' + Cu2' 1 4dt14t 3. Dilute hydrochloric acid is added to a solution of diamminesilver(1) nitrate. * 2h-t + 4- c\- 4. Solid aluminum nitrate is 5. A suspension ofcopper(ll) hydroxide is treated with an excess of ammonia water. CJ, + Y M 4 ~ [C,(~H~\J~+ 2o\i ~ 6. A solution of diamminesilver(1) chloride is treated with dilute nitric acid. -.2 N H 4 * 7. An excess of concentrated ammonia freshly precipitated 8. Excess dilute nitric acid is added to a solution containing the ~<traaminecadmium(II)ion. - Yh* -7 N W + -r a solution saturated with silver chloride. 9. An excess of ZN~> cr2+ ASC\ + [4(N~3\~]+ c\- 10. Solid aluminum oxide is added to a solution o sodium hydroxide. A\, 3 - qoh- 11. A concentrated solution of + Vh3 12. An excess of sodium hydroxide chloride. qbh13. A concentrated solution of chloride. 14. Excess concehted sodium hydroxide solution is added tgsofid aluminum hydroxide. OH- 15. Excess silver chloride, 16. Pellets of aluminum metal are added to a solution containing an excess of sodium hydroxide. J - A\ 17. A suspension of zinc I \7- sodium hydroxide solution. [in(n&),-JL7 18. Silver chloride is dissolved in excess ammonia solu ion. , 19. Sodium (3h' 20. A drop of ~ C N - ~e" Z-f FeScf-4 - 21. A concentrated solution of ammonia is added to a suspension of zinc hydroxide. - N N~ &(oh\, 12-(,N~J,,\~' - 22+-/ -4 20. Excess concentrated potassium hydroxide solution is added to a precipitate of zinc hydroxide. zo'q- 21. A solution of ammonium 22. Excess sodium cyanide is added to a solution of silver nitrate.. .-cbJ- + AS - L . Addition 1. The gases boron trifluoride and G o n i a are mixed. - BF, AM^ --t FS6aq3 2. A mixture of solid calcium oxide and solid tetraphosphorus decaoxide is heated. 1'-0 - 3. Solid calcium oxide is Ck0 C,U3 4. Solid calcium oxide is heated in the presence of sulfur trioxide gas. G2 + 5. Calcium metal is 3 L + - 3 G5ay y in nitrogen gas. 2 L3NL 6. Excess chlorine gas is passed over hot iron filings. 7. Powdered magnesium oxide is added to a container of carbon dioxide gas. M3cq -s 8. A piece of lithium metal is dropped into a container of nitrogen gas. (-P L,, + *L -+ 2 L,, 9. Magnesium metal is burned in nitrogen gas. d 10. Sulfur dioxidegas is passed over solid c a l c i h oxide. 20, * L o G S o3 11. Samples of boron trichloride gas and ammonia gas are mixed. B u3 + M q3 C13 Decomposition 1. A solution of hydrogen peroxide is heated. 2f\,oz 8 -M3 4 O z -+2W2b 2. Solid magnesium carbonate is heated. 4 - 3. A solution of hydrogen peroxide is catalytically decomposed. '-'Lo2 O2 -,- h2a 4. Solid potassium chlorate is heated in the presence of manganese dioxide as a catalyst. 2 k c l o'3 b 2kc\ 30, 5. Sodium hydrogen carbonate is dissolved in water. N t , h co 3 ' ' 6. Solid ammonium carbonate is heated. 4- + " kc0 3 -
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