Hummel Croton Inc.
10 Harmich Rd.
South Plainfield, NJ 07080
www.HummelCroton.com
Phone: 908-754-1800
Fax: 908-754-1815
In Case Of Emergency Call Chemtrec®
(U.S.) (800) 424-9300
(International) (703) 527-3887
Ammonium Nitrate
Safety Data Sheet
1. Product and Company
Product name:
Ammonium Nitrate
HMIS Rating
Synonym:
Ammonium Saltpeter, Ammonium Salt
of Nitric Acid
Health
1
Flammabilitiy
0
CAS-No.:
6484-52-2
Reactivity
3
Personal Protection
C
Company:
Hummel Croton Inc.
10 Harmich Rd.
South Plainfield, NJ 07080
Telephone:
Fax:
908-754-1800
908-754-1815
Emergency telephone number
Emergency Phone #:
Chemtrec US: 800-424-9300
Chemtrec International: 703-527-3887
2. Hazards
GHS Classification
Oxidizing solids (Category 3), H272
Skin irritation (Category 2), H315
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory
system, H335
GHS Label elements
Pictogram(s)
Signal word
WARNING
Hazard statement(s)
H272 May intensify fire; oxidizer.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P210 Keep away from heat.
P220 Keep/Store away from clothing/ combustible materials.
P221 Take any precaution to avoid mixing with combustibles.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352
IF ON SKIN: Wash with plenty of soap and water.
P304 + P340
IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P321 Specific treatment (see supplemental first aid instructions on this label).
P332 + P313
If skin irritation occurs: Get medical advice/ attention.
P337 + P313
If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for
extinction.
P403 + P233
Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS
None.
3. Composition/Ingredients
Substance
Formula:
Molecular weight:
CAS-No.:
Material
Ammonium
Nitrate
4. First Aid
NH4NO3
80.05 g/mol
6484-52-2
CAS
6484-52-2
%
99-100%
OSHA
Not Established
ACGIH
Not Established
First Aid For Eye: In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Call a physician.
First Aid For Skin: In case of contact, flush skin with water. Wash clothing before reuse. Call a
physician if irritation occurs.
First Aid For Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Call a physician.
First Aid For Ingestion: If swallowed, call a physician immediately.
5. Fire Data
Flammability: Non-Flammable
Flash Point: Not Applicable
Auto Ignition: Not Applicable
Flammable Limits: Not Applicable
Extinguishing Media: Water spray
Fire Fighting Procedure: Wear self-contained breathing apparatus and protective clothing to
prevent contact with skin and eyes. OXIDIZER. May explode when heated.
Fire/Explosion Hazards: Contact with other material may cause fire. Emits toxic fumes under fire
conditions. Container explosion may occur under fire conditions.
6. Accidental Release
Spill Or Leak Procedures: Utilize recommended protective clothing and equipment. Clean spills
in a manner that does not disperse dust into the air. Spill area can be washed with water.
Collect wash water for approved disposal. Keep from entering water or ground water.
7. Handling And Storage
Storage Temperatures: Store at ambient temperature
Shelf Life: Unlimited in tightly sealed container
Special Sensitivity: Ammonium nitrate decomposes at about 210oC. The presence of impurities
markedly lowers the decomposition temperature, e.g. chloride salts, metal oxides. The
following powdered metals react violently or explosively with fused ammonium nitrate below
200oC: aluminum, antimony, bismuth, cadmium, chromium, cobalt, copper, iron, lead,
magnesium, manganese, potassium, sodium, nickel, tin,zinc, titanium, as well as brass and
stainless steel. Ignites or reacts on contact with: phosphorous, urea, sulfur, potassium nitrite,
sawdust, sugar, trinitroanisole, charcoal, cyanoguanidine, potassium permanganate, acetic acid,
acetic anhydride. Hot aqueous solutions of ammonium nitrate above 50% concentration may
decompose explosively under adiabatic conditions and confinement.
Handling/Storage Precautions: Avoid breathing dust. Avoid getting in eyes or on skin. Wash
thoroughly after handling. Store in a dry place away from direct sunlight, heat and incompatible
materials. Reseal containers immediately after use. Store away from food and beverages.
8. Exposure Controls/Personal Protection
Eye Protection: Safety glasses or goggles.
Skin Protection: PVC gloves with impervious boots, apron or coveralls. Wash hands and face
before eating, drinking or using tobacco.
Respirator: Work ambient concentrations should be monitored and if the recommended
exposure limit is exceeded, a NIOSH/MSHA approved dust respirator must be worn.
Ventilation: Use local ventilation if dusting is a problem, to maintain air levels below the
recommended exposure limit.
Additional Measures: Emergency showers and eye wash stations should be available. Educate
and train employees in the safe handling of hazardous chemicals.
9. Physical And Chemical Properties
Physical Form: Solid Crystals or Prills
Color: White
Odor: Odorless
Molecular Weight: 80.05
Boiling Point: Decomposes at 210oC
Melting/Freezing Point: Decomposes at 210oC
Solubility In Water: 2 grams per mL water
Specific Gravity: 1.72
10. Stability And Reactivity
Stability: Stable.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong reducing agents, strong acids, finely powdered metals.
Instable Conditions: Excessive temperatures (see incompatibilities).
Decomposition Temperature: Decomposes at 210oC
Decomposition Products: Oxides of Nitrogen and Ammonia
11. Toxicological Information
RTECS Number: BR 9050000
Routes Of Exposure: Eye contact. Ingestion. Inhalation. Skin contact.
Toxicity Data: LD50: Oral-Rat 2217 mg/kg
Chronic Toxic Effects: This product has no known chronic effects. Repeated or prolonged
exposure to this compound is not known to aggravate medical conditions.
Acute Toxic Effects: Irritating to the skin and eyes on contact. Inhalation will cause irritation to
the lungs and mucus membrane. Irritation to the eyes will cause watering and redness.
Reddening, scaling, and itching are characteristics of skin inflammation. Follow safe industrial
hygiene practices and always wear protective equipment when handling this compound.
12. Ecological Information
Ecotoxicity: Not available at this time.
13. Disposal Considerations
Waste Disposal Method: Waste disposal should be in accordance with existing federal, state and
local environmental regulations.
14. Transportation Information
Proper Shipping Name: Ammonium Nitrate
UN Number: 1942
Class: 5.1
P.G.: III
Label Code: 5.1
15. Regulatory Information
OSHA Status: This product is hazardous under the criteria of the Federal OSHA Hazard
Communication Standard 29 CFR 1910.1200.
TSCA Chemical Inventory: This compound is on the EPA Toxic Substance Control Act (TSCA)
Inventory List
California Proposition 65: To the best of our knowledge, this product contains no levels of listed
substances, which the State of California has found to cause cancer, birth defects or other
reproductive effects.
SARA 313 Title III:
Section 320 Extremely Hazardous Substances: None
Section 311/312 Hazardous Categories: None
Section 313 Toxic Chemicals: None
16. Other Information
Prepared By: Michael Richard
Date: June 3, 2015
Reason For Issue: GHS Compliance
No warranty, expressed or implied, or merchantability, fitness for a particular purpose or otherwise is made, except that the products herein
discussed comply with the chemical description on the labels. Buyer assumes risks of the use, storage and handling. Hummel Croton shall not
be liable for any incidental or consequential damages arising directly or indirectly in connection with the purchase, use, storage or handling of
this product. The information contained herein is, to the best of our knowledge, true and accurate. However, all recommendations or
suggestions are made without guarantee, since the conditions of use are beyond our control. We disclaim any liability incurred in connection
with the use of these data or suggestions. This information is not to be taken as a license to operate under, or a recommendation to infringe
any patent(s). The observance of all regulations and patents is the responsibility of the user. No agent, representative or employee of this
company is authorized to vary any items of this notice.
SAFETY DATA SHEET
1. Identification
Product identifier
ATOMIZED ALUMINUM POWDER (SPHERICAL)
Other means of identification
SDS number
566
Chemical formula
Al
Revision date
05
April 6, 2015.
Other means of identification
Synonyms
All non-alloyed spherical aluminum powder
Recommended use
Rocket motors, automotive paints, refractories
Recommended restrictions
None known.
Version #
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Alcoa Inc.
201 Isabella Street
Pittsburgh, PA 15212-5858 US
Health and Safety Email: [email protected]
Health and Safety Fax: 1-412-553-4822
Health and Safety Tel: 1-412-553-4649
Poços de Caldas
Rodovia Poços de Caldas/Andradas, km 10
CEP 37.719-900
Poços de Caldas, Minas Gerais
Tel.: (+55 35) 2101-5000
E-mail: [email protected]
1(e) Product Identifier
Emergency Information
Website
CHEMTREC: +1-703-527-3887 +1-800-424-9300 (24 Hour Emergency Telephone, multiple
languages spoken); ALCOA: +1-412-553-4001 (24 Hour Emergency Telephone, only English
spoken)
For a current Safety Data Sheet, refer to Alcoa websites: www.alcoa.com or internally at
my.alcoa.com EHS Community
2. Hazard(s) identification
Classification
This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Physical hazards
Not classified.
Health hazards
Not classified.
Environmental hazards
Not classified.
OSHA defined hazards
Combustible dust
Label elements
Hazard symbol
None.
Signal word
Warning
Hazard statement
The mixture does not meet the criteria for classification. May form combustible dust
concentrations in air.
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
SDS US
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Precautionary statement
Prevention
Use only non-sparking tools and natural bristle brushes. Alcoa aluminum powders were tested by
the United States Department of Interior Bureau of Mines in 1991, under UN criteria and found not
to meet the definition of a hazard class 4. Care should be taken during bulk handling to prevent
accumulation/generation over time of 75 micron or finer particles. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving
equipment. Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
measures against static discharge. Prevent dust accumulation to minimize explosion hazard.
Response
In case of fire: Use appropriate media for extinction.
Storage
Store in a dry place and/or in closed container. Keep away from heat, sparks and open flame - No
smoking.Do not allow chips, fines or dust to contact water, particularly in enclosed areas.
Disposal
Reuse or recycle material whenever possible. Material that cannot be reused may be sent to a
metals reclamation facility that is able to handle fines. Waste material that cannot be reclaimed for
metal value should be rendered non-reactive prior to disposal.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information
None.
Powder may ignite readily.
Dust or fines dispersed in the air can be explosive.
Explosion/fire hazards may be present when:
• Dust or fines are dispersed in air.
• Powder or dusts in contact with water can generate flammable/explosive hydrogen gas. These
gases could present an explosion hazard in confined or poorly ventilated spaces.
• Powder or dusts are in contact with certain metal oxides (e.g., rust, copper oxide).
Specific hazards
3. Composition/information on ingredients
Mixtures
Chemical name
Common name and synonyms
Aluminum
CAS number
%
7429-90-5
97
4. First-aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Most important
symptoms/effects, acute and
delayed
Dust from processing: Rinse eyes with plenty of water or saline for at least 15 minutes. Consult a
physician.
Dust from processing: Wash with soap and water for at least 15 minutes. Get medical attention if
irritation develops or persists.
Dust from processing: Remove to fresh air. Check for clear airway, breathing, and presence of
pulse. If breathing is difficult, provide oxygen. Loosen any tight clothing on neck or chest. Provide
cardiopulmonary resuscitation for persons without pulse or respirations. Consult a physician.
If swallowed, dilute by drinking water. Recommend quantities up to 30 mL (~1 oz.) in children and
250 mL (~9 oz.) in adults. Never give anything by mouth to a victim who is unconscious or is
having convulsions. Do NOT induce vomiting. Consult a physician.
Dust from processing: Can cause irritation of the upper respiratory tract. See Section 11 of the
SDS for additional information on health hazards.
Medical conditions aggravated
by exposure
Asthma, chronic lung disease, and skin rashes.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. In case of shortness of breath,
give oxygen.
General information
If exposed or concerned: Get medical advice/attention. In case of shortness of breath, give
oxygen.
5. Fire-fighting measures
Suitable extinguishing media
Use Class D extinguishing agents on fines, dust or molten metal.
Unsuitable extinguishing
media
DO NOT USE water, halogenated agents, or ABC dry chemical agents. These fire extinguishing
agents will react with the burning material.
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
SDS US
2/9
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
General fire hazards
Alcoa aluminum powders were tested by the United States Department of Interior Bureau of Mines
in 1991, under UN criteria and found not to meet the definition of a hazard class 4. Care should be
taken, however, during bulk handling to prevent accumulation/generation over time of 75 micron or
finer particles.
May be a potential hazard under the following conditions:
• Dust clouds may be explosive. Even a minor dust cloud can explode violently. Dust accumulation
on the floor, ledges and beams can present a risk of ignition, flame propagation and secondary
explosions.
• Powder or dusts in contact with water can generate flammable/explosive hydrogen gas. These
gases could present an explosion hazard in confined or poorly ventilated spaces.
• Powder or dusts are in contact with certain metal oxides (e.g., rust, copper oxide).
Firefighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus
and full protective clothing when appropriate.
Use gentle surface application of Class D extinguishing agent or dry inert granular material (e.g.,
sand) to cover and ring the burning material. Avoid mixing of the extinguishing agent with the
burning material. Apply extinguishing media carefully to avoid creating airborne dust. Do not
disturb the material until completely cool. If possible, isolate the burning material to prevent fire
spread, and allow the material to burn itself out. Move undamaged containers away from heat or
flame, if possible.
Dust and fines from processing may ignite readily. Dust or fines dispersed in the air can be
explosive.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Avoid contact with skin and eyes. Use personal protection recommended in Section 8 of the SDS.
Evacuation procedures
Keep people away from and upwind of spill/leak. Keep unnecessary personnel away.
Methods and materials for
containment and cleaning up
Isolate area. Avoid the generation of dusts during clean-up. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Use only non-sparking tools and natural
bristle brushes. Use dry cleanup procedures.
Environmental precautions
Keep material dry. Place carefully in dry, water-tight containers. Seal containers. After complete
clean-up by sweeping, area may be washed with large amounts of water if necessary. Material that
cannot be reused may be sent to a metals reclamation facility that is able to handle fines. Waste
material that cannot be reclaimed for metal value should be rendered non-reactive prior to
disposal. For waste disposal, see section 13 of the SDS.
No specific precautions.
7. Handling and storage
Handling
Storage
Requirements for Processes
Which Generate Dusts or Fines
Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Care should
be taken during bulk handling to prevent accumulation/generation over time of 75 micron or finer
particles. Keep material dry.
Keep dry. Storage rooms must be of fire-resistant construction. Do not store powder in same room
as other combustible materials.
Obtain and follow the safety procedures and equipment guides contained in Aluminum Association
Bulletin TR-2 and National Fire Protection Association (NFPA) brochures listed in Section 16. Use
non-sparking handling equipment, tools and natural bristle brush. Cover and reseal partially empty
containers. Provide grounding and bonding where necessary to prevent accumulation of static
charges during metal dust handling and transfer operations (See Section 15).
Local ventilation and vacuum systems must be designed to handle explosive dusts. Dry vacuums
and electrostatic precipitators must not be used, unless specifically approved for use with
flammable/explosive dusts. Dust collection systems must be dedicated to aluminum dust only and
should be clearly labeled as such. Do not co-mingle fines of aluminum with fines of iron, iron oxide
(rust) or other metal oxides.
Process equipment, storage containers, vessels and buildings should be equipped with
explosion/pressure relief valves, panels and windows. Precautions must also be taken to prevent
water leakage or seepage which could contact the powder. Refer to NFPA 484.
Avoid all ignition sources. Good housekeeping practices must be maintained. Dust accumulation
on the floor, ledges and beams can present a risk of ignition, flame propagation and secondary
explosions. Do not use compressed air to remove settled material from floors, beams or equipment
. Do not allow fines or dust to contact water, particularly in enclosed areas.
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
SDS US
3/9
8. Exposure controls/personal protection
Occupational exposure limits
U.S. - OSHA
Components
Type
Aluminum (CAS 7429-90-5)
TWA
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Material
Type
Value
Form
15 mg/m3
(total dust)
Value
Form
ATOMIZED ALUMINUM
POWDER (SPHERICAL)
PEL
5 mg/m3
Respirable dust.
Components
Type
15 mg/m3
Value
Total dust.
Form
Aluminum (CAS 7429-90-5)
TWA
5 mg/m3
Respirable dust.
US ACGIH Threshold Limit Values: Time Weighted Average (TWA): mg/m3, non-standard units
Material
Type
Value
Form
ATOMIZED ALUMINUM
POWDER (SPHERICAL)
Components
TWA
1 mg/m3
Respirable fraction.
Type
Value
Form
Aluminum (CAS 7429-90-5)
TWA
1 mg/m3
Respirable fraction.
Alcoa
Material
Type
Value
Form
ATOMIZED ALUMINUM
POWDER (SPHERICAL)
TWA
3 mg/m3
Respirable fraction
Components
Type
10 mg/m3
Value
Total dust
Form
Aluminum (CAS 7429-90-5)
TWA
3 mg/m3
10 mg/m3
Respirable fraction
Total dust
General
Use personal protective equipment as required.
Appropriate engineering
controls
Dust from processing: Use with adequate explosion-proof ventilation designed to handle
particulates to meet the limits listed in Section 8, Exposure Guidelines.
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields.
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear impervious gloves to avoid direct skin contact.
Recommend fire resistant cotton or equivalent full-length fire resistant pants and jackets along with
electrically conductive safety shoes or grounding straps. Great caution is required to avoid contact
with unprotected electrical devices when wearing conductive safety shoes or grounding straps.
Use NIOSH-approved respiratory protection as specified by an Industrial Hygienist or other
qualified professional if concentrations exceed the limits listed in Section 8. Suggested respiratory
protection: N95.
Not applicable.
Handle in accordance with good industrial hygiene and safety practice. When using, do not eat,
drink or smoke. Wash hands before breaks and immediately after handling the product.
9. Physical and chemical properties
Form
Solid, powder.
Color
Silvery to gray.
Odor
Odorless
Odor threshold
Not applicable
pH
Not applicable
Melting point/freezing point
1194.8 - 1214.6 °F (646 - 657 °C)
Initial boiling point and boiling
range
Not determined
Flash point
Not applicable
Evaporation rate
Not applicable
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
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Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive limits
Not determined
Flammability limit - upper
(%)
Flammability limit - lower
(%)
Explosive properties
40 mg/l
Dust can form an explosive mixture in air. Dust accumulation from this product may present an
explosion hazard in the presence of an ignition source.
Dust explosion properties
St class
Ignition of a dust cloud produces a very strong explosion.
Vapor pressure
Not applicable
Vapor density
Not applicable
Relative density
Not determined
Solubility(ies)
Insoluble
Insoluble
Partition coefficient
(n-octanol/water)
Not applicable.
Not applicable
Auto-ignition temperature
1202 °F (650 °C) layered
Decomposition temperature
Not applicable
Viscosity
Not applicable
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Stable under normal conditions of use, storage, and transportation as shipped.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid
• Water: Slowly generates flammable and explosive hydrogen gas and heat. Generation rate is
greatly increased with smaller particles (e.g., fines and dusts). Water/aluminum mixtures may be
hazardous when confined.
• Heat: Oxidizes at a rate dependent upon temperature and particle size.
• Acids and alkalis: Reacts to generate flammable/explosive hydrogen gas. Generation rate is
greatly increased with smaller particles (e.g., fines and dusts).
• Strong oxidizers: Violent reaction with considerable heat generation. Can react explosively with
nitrates (e.g., ammonium nitrate and fertilizers containing nitrate) when heated or molten.
• Halogenated compounds: Many halogenated hydrocarbons, including halogenated fire
extinguishing agents, can react violently with finely divided or molten aluminum.
• Iron oxide (rust) and other metal oxides (e.g., copper and lead oxides): A violent thermite reaction
generating considerable heat can occur. Reaction with aluminum fines and dusts requires only
very weak ignition sources for initiation.
• Iron powder and water: Explosive reaction forming hydrogen gas when heated above 1470°F
(800°C).
No hazardous decomposition products are known.
Incompatible materials
Hazardous decomposition
products
11. Toxicological information
Health effects associated with ingredients
Aluminum dust/fines and fumes: Low health risk by inhalation. Generally considered to be biologically inert.
Health effects associated with compounds formed during processing
No new/additional compounds are expected to be formed during processing.
Information on likely routes of exposure
Can cause mechanical irritation.
Eye contact
Skin contact
Dust from processing: Can cause mechanical irritation.
Inhalation
Dust from processing: Can cause irritation of the upper respiratory tract.
Ingestion
Can cause irritation of the gastrointestinal tract.
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
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Symptoms related to the
physical, chemical and
toxicological characteristics
Dust from processing: Can cause mechanical irritation. Dust: Can cause irritation of the upper
respiratory tract.
Information on toxicological effects
Acute toxicity
Not classified. Based on available data, the classification criteria are not met.
Skin corrosion/irritation
Non-corrosive.
Serious eye damage/eye
irritation
Can cause mechanical irritation.
Respiratory or skin
sensitization
Not a skin sensitizer.
Respiratory sensitization
Not a respiratory sensitizer.
Skin sensitization
Mild skin irritation.
Germ cell mutagenicity
Not available.
Neurological effects
Not classified. Based on available data, the classification criteria are not met.
Pre-existing conditions
aggravated by exposure
Asthma, chronic lung disease, and skin rashes.
Carcinogenicity
Does not present any cancer hazards.
Reproductive toxicity
Does not present any reproductive hazards.
Routes of exposure
Inhalation. Skin contact. Eye contact.
Specific target organ toxicity single exposure
Not classified. Based on available data, the classification criteria are not met.
Specific target organ toxicity repeated exposure
Not classified. Based on available data, the classification criteria are not met.
Aspiration hazard
Not an aspiration hazard.
Chronic effects
Not classified.
Further information
None known.
12. Ecological information
Ecotoxicity
Not expected to be harmful to aquatic organisms.
Persistence and degradability
The product is not biodegradable.
Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
Mobility in soil
Not considered mobile.
Mobility in general
Not considered mobile.
Other adverse effects
Not available.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Reuse or recycle material whenever possible. Material that cannot be reused may be sent to a
metals reclamation facility that is able to handle fines. Waste material that cannot be reclaimed for
metal value should be rendered non-reactive prior to disposal.
Dispose in accordance with all applicable regulations.
Waste from residues / unused
products
RCRA Status: Not federally regulated in the U.S. if disposed of "as is."
RCRA waste codes other than described here may apply depending on use of the product. Status
must be determined at the point of waste generation. Refer to 40 CFR 261 or state equivalent in
the U.S.
If reuse or recycling is not possible, disposal must be made according to local or governmental
regulations.
Contaminated packaging
Dispose of in accordance with local regulations.
Waste codes
14. Transport information
General Shipping Information
Basic Shipping Information
ID number
Proper shipping name
Hazard class
Packing group
Not regulated
-
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
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General Shipping Notes
• This material has been tested under UN criteria and found not to meet the definition of a hazard class 4 and does not meet the
definition of any other hazard class.
• Standard Transportation Commodity Code: 33-991-19.
• HTS (Harmonized Tariff Schedule) code: 7603.10.0000.
• The import/export HTS (Harmonized Tariff Schedule) code given above is the United States HTS code provided by Alcoa's
Customs Compliance Office in Knoxville, TN. Other country specific HTS codes may apply. If available, more information on the
HTS codes will be provided on country specific Material Safety Data Sheets.
• When "Not regulated", enter the proper freight classification, SDS Number and Product Name onto the shipping paperwork.
Disclaimer
This section provides basic classification information and, where relevant, information with respect to specific modal regulations,
environmental hazards and special precautions. Otherwise, it is presumed that the information is not available/not relevant
15. Regulatory information
US federal regulations
All electrical equipment must be suitable for use in hazardous atmospheres involving aluminum
powder in accordance with 29 CFR 1910.307. The National Electrical Code, NFPA 70, contains
guidelines for determining the type and design of equipment and installation which will meet this
requirement.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 hazard
Immediate Hazard - No
categories
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
If dust clouds are generated
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Chemical name
Aluminum
No
CAS number
% by wt.
7429-90-5
97
US state regulations
US - New Jersey RTK - Substances: Listed substance
Aluminum (CAS 7429-90-5)
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Aluminum (CAS 7429-90-5)
US. Massachusetts RTK - Substance List
Aluminum (CAS 7429-90-5)
US. New Jersey Worker and Community Right-to-Know Act
Aluminum (CAS 7429-90-5)
US. Pennsylvania RTK - Hazardous Substances
Aluminum (CAS 7429-90-5)
US. Pennsylvania Worker and Community Right-to-Know Law
Aluminum (CAS 7429-90-5)
US. Rhode Island RTK
Aluminum (CAS 7429-90-5)
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
SDS US
7/9
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region
Australia
Inventory name
Australian Inventory of Chemical Substances (AICS)
On inventory (yes/no)*
Yes
Canada
Domestic Substances List (DSL)
Canada
Non-Domestic Substances List (NDSL)
China
Inventory of Existing Chemical Substances in China (IECSC)
Yes
Europe
European Inventory of Existing Commercial Chemical
Substances (EINECS)
Yes
Europe
European List of Notified Chemical Substances (ELINCS)
Japan
Inventory of Existing and New Chemical Substances (ENCS)
Korea
Existing Chemicals List (ECL)
Yes
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Yes
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
Yes
Yes
No
No
No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
SDS Status
April 6, 2015: Change(s) in Section: 1, 2, 5 and 15.
October 7, 2010: New format.
September 11, 2007: Reviewed on a periodic basis in accordance with Alcoa policy. Change(s) in
Section: 1, 2, 3, 4, 5, 7, 8, 11, 14 and 15
May 10, 2004: Reviewed on a periodic basis in accordance with Alcoa policy. Change(s) in
Section: 1, 3, 14 and 15
Hazardous Materials Control Committee
Preparer: Jim Perriello, +1-865-977-2051.
Origination date: December 18, 1985
Revision date
Version #
Revision Information
Disclaimer
SDS System Number: 146311
April 6, 2015.
05
Product and Company Identification: Synonyms
Transport Information: Agency Name, Packaging Type, and Transport Mode Selection
Regulatory Information: United States
GHS: Classification
The information in the sheet was written based on the best knowledge and experience currently
available.
Other information
• Aluminum Association Bulletin TR-2, "Recommendations for Storage and Handling of Aluminum Pigments and Powders." The
Aluminum Association, 1525 Wilson Boulevard, Suite 600, Arlington, Virginia 22209, www.aluminum.org.
• Aluminum Association, "Guidelines for Handling Molten Aluminum, The Aluminum Association, 1525 Wilson Boulevard, Suite
600, Arlington, Virginia 22209, www.aluminum.org.
• NFPA 484, Standard for Combustible Metals (NFPA phone: 800-344-3555)
• NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of
Combustible Particulate Solids
• NFPA 70, Standard for National Electrical Code (Electrical Equipment, Grounding and Bonding)
• NFPA 77, Standard for Static Electricity
• Guide to Occupational Exposure Values 2010, Compiled by the American Conference of Governmental Industrial Hygienists
(ACGIH).
• NIOSH Pocket Guide to Chemical Hazards, U.S. Department of Health and Human Services, September 2005.
• expub, Expert Publishing, LLC., www.expub.com
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
SDS US
8/9
Key/Legend:
ACGIH American Conference of Governmental Industrial Hygienists
AICS
Australian Inventory of Chemical Substances
CAS
Chemical Abstract Services
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
CFR
Code of Federal Regulations
CPR
Cardio-pulmonary Resuscitation
DOT
Department of Transportation
DSL
Domestic Substances List (Canada)
EC
Effective Concentration
ED
Effective Dose
EINECS European Inventory of Existing Commercial Chemical Substances
ENCS
Japan - Existing and New Chemical Substances
EWC
European Waste Catalogue
EPA
Environmental Protective Agency
IARC
International Agency for Research on Cancer
LC
Lethal Concentration
LD
Lethal Dose
MAK
Maximum Workplace Concentration (Germany) "maximale Arbeitsplatz-Konzentration"
NDSL
Non-Domestic Substances List (Canada)
NIOSH National Institute for Occupational Safety and Health
NTP
National Toxicology Program
OEL
Occupational Exposure Limit
OSHA
Occupational Safety and Health Administration
PIN
Product Identification Number
PMCC
Pensky Marten Closed Cup
RCRA
Resource Conservation and Recovery Act
SARA
Superfund Amendments and Reauthorization Act
SIMDUT Système d'Information sur les Matières Dangereuses Utilisées au Travail
STEL
Short Term Exposure Limit
TCLP
Toxic Chemicals Leachate Program
TDG
Transportation of Dangerous Goods
TLV
Threshold Limit Value
TSCA
Toxic Substances Control Act
TWA
Time Weighted Average
WHMIS Workplace Hazardous Materials Information System
m meter, cm centimeter, mm millimeter, in inch,
g gram, kg kilogram, lb pound, µg microgram,
ppm parts per million, ft feet
*** End of SDS ***
Material name: ATOMIZED ALUMINUM POWDER (SPHERICAL)
566 Version #: 05 Revision date: 04-06-2015 Issue date: 04-06-2015
SDS US
9/9
ATOMIZED ALUMINUM POWDER (SPHERICAL)
Hazard statement
Warning
May form combustible dust concentrations in air.
Precautionary statement
Prevention
Care should be taken during bulk handling to prevent accumulation/generation over time of 75 micron
or finer particles. Keep away from heat/sparks/open flames/hot surfaces - No smoking. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment.
Prevent dust accumulation to minimize explosion hazard. Take precautionary measures against static
discharge. Use only non-sparking tools and natural bristle brushes.
Response
In case of fire: Use appropriate media for extinction.
Storage
Store in a dry place and/or in closed container. Keep away from heat, sparks and open flame - No
smoking. Do not allow chips, fines or dust to contact water, particularly in enclosed areas.
Disposal
Reuse or recycle material whenever possible. Material that cannot be reused may be sent to a metals
reclamation facility that is able to handle fines. Waste material that cannot be reclaimed for metal value
should be rendered non-reactive prior to disposal.
Supplemental information
Powder may ignite readily. Powder or dusts dispersed in the air can be explosive when:
• Powder or dust are dispersed in air.
• Powder or dusts are in contact with water.
• Powder or dusts are in contact with certain metal oxides (e.g., rust, copper oxide).
FIRE FIGHTING MEASURES: Use gentle surface application of Class D extinguishing agent or dry inert
granular material (e.g., sand) to cover and ring the burning material. Avoid mixing of the extinguishing
agent with the burning material. If possible, isolate the burning material to prevent fire spread, and allow
the material to burn itself out. Do not disturb the material until completely cool. Move undamaged
containers away from heat or flame, if possible.
DO NOT USE water, halogenated agents, or ABC dry chemical agents. These fire extinguishing agents
will react with the burning material.
IN CASE OF SPILL: Avoid dusting of powder to the greatest extent possible. Use only non-sparking
tools and natural bristle brushes. Use natural bristle broom and non-sparking shovel. Eliminate ignition
sources including sources of electrical, static or frictional sparks. Prohibit smoking.
Use dry cleanup procedures. Place carefully in dry, water-tight containers. Seal containers. After
complete clean-up by sweeping, area may be washed with large amounts of water if necessary.
See Alcoa SDS Number 0566.
USA: Chemtrec: +1-703-527-3887 +1-800-424-9300 (24 Hour Emergency Telephone, multiple languages spoken)
Alcoa Inc., 201 Isabella Street, Pittsburgh, PA 15212-5858 United States +1-412-553-4001 (24 Hour Emergency Telephone, English only)
Alcoa Health and Safety Email: [email protected] Tel: +1-412-553-4649 and Fax: +1-412-553-4822