The Barometric Formula: Pressure vs. Altitude (a) Derive a general formula for the pressure P(z) as a function of the altitude z, if the pressure at sea level (i.e., at z = 0). Your formula may involve the temperature T and the molar mass of air (Mair = 0.0290 kg/mol). We're talking about reasonably small changes in altitude here, so you can assume that temperature is essentially independent of z. Hint: the differential form of the pressuredepth relation might be useful. (b) If the pressure at sea level is P0 = 1 atm at T = 25° C, what would the pressure be at this same temperature in Colorado Springs, where the elevation is roughly 1839 m above sea level? Hot-Air Balloon The gondola of a hot-air balloon has a mass of 50 kg. If it carries two passengers, each of whom has a mass of 75 kg. The radius of the balloon itself is 10 m and it's a sunny, 30° C day where the atmospheric pressure is roughly 1 atm at ground level. What temperature must the air inside the balloon be in order for it to attain a height of 500 m above the ground? Gas Expansion (a) Find the fractional change ΔV/V in the volume of an ideal gas when it is raised from 20° C to 80° C at constant pressure. (b) Find the fractional change ΔV/V in the volume of a block of iron when it is raised from 20° C to 80° C at constant pressure. How does this compare to your result in part (a)? Energy Conservation For each of the situations described on the next slide, use your intuition to explain the energy flow – i.e. where the energy comes from and where it is going. Then identify a “system” and use your intuitive explanation to set up a conservation of energy equation in words (such as “work,” “heat,” or “change in internal energy”) for that system. ● Example: Hitting a nail with a hammer The energy from your body is transferred into the movement of the hammer. The kinetic energy of the moving hammer is used to move the nail into the wood. After everything is stationary, the energy is stored in the increased temperature of the wood and nail. Thus if “wood and nail” is our system, we can write: (chemical energy used by your body to swing the hammer) = (kinetic energy of hammer just before it hits the nail) = (work done on the system moving nail into wood) = (energy stored in the increased internal energy of the wood and nail) ● Situations: (a) You compress the air in a bicycle pump by pushing down on the handle very rapidly. (b) You hold a nail over a bunsen burner. (c) High pressure gas in a cylinder pushes a piston outward very rapidly. (d) Steam contacts a cold surface and condenses.
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