Stock System.notebook Cations with multiple charges January 17, 2011 Monoatomic Ions on p.205 Transition metals on the bottom table Exceptions: Ag+ and Zn2+ These ions only support one charge and do not need a Roman numeral pblock metals Lead (II) (Pb2+) and Lead (IV) (Pb4+) Tin (II) (Sn2+) and Tin (IV) (Sn2+) Mostly transition metals Some pblock metals Use a Roman numeral to state the positive charge for the cation in the name. Examples: FeCl2 iron (II) chloride FeCl3 iron (III) chloride Determining Formulas How to determine the Roman numeral in the name. Same process as monoatomic ion nomenclature. Roman numeral tells to the charge of the cation. Example: 1. Start with formula. CuF2 2. "Reverse cross over" subscritps. Subscript becomes charge value on opposite ion. Cu2+ F 3. Value of the positive charge (cation) becomes the Roman numeral in the name. Iron (III) Chloride Fe3+ Cl FeCl3 1 Ionic Nomenclature copper (II) fluoride Identify the correct formula for chromium (II) oxide. A Cr2O B CrO2 C Cr2O2 D CrO Grade: «grade» Subject: «subject» Date: «date» 1 Stock System.notebook 2 4 Identify the correct formula for copper (I) oxide. 3 What is the correct formula for lead (IV) sulfide? A CuO A PbS B Cu2O B Pb2S4 C CuO2 C PbS2 D Cu2O2 D Pb2S What is the name of the compound with the formula Fe2O3? A 6 January 17, 2011 iron (II) oxide B iron (III) oxide C iron (IV) oxide D iron oxide (II) 5 What is the name of the compound with the formula CrBr3? A chromium bromide B chromium bromide (III) C chromium tribromide D chromium (III) bromide What is the name of the compound with the formula MnO2? A manganese oxide B managanese dioxide C manganese (II) oxide D manganese (IV) oxide 2
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