1 2 Exam Grading Lecture 10 • I try to “clean up” scan-sheets as best I can • Follow directions: mark what test you have! • If the class average is lower than about a B-, I adjust the grades upward. • Exam 1 median & average: 191 (B-) Matter and its interactions with light. Hmwk 3 opens this week, due 3/15 (Th). 3 5th Most Difficult Question 4 4th Most Difficult Question What direction does the Sun set in Amherst during summertime? 1. Southwest (tied with 3) 2. Due west 3. Northwest (tied with 3) 4. Due East A lunar eclipse would coincide with a 1. Low tide. 2. Spring tide. 3. Neap tide. (favorite ~ 47%) 4. Ultra Tide® Part 2: 39 57 Part 2: 36 64 5 3rd Most Difficult Question You have been drugged and kidnapped….You notice a star our of the cell window and through the night it traces the following pattern on the sky: You must be looking… 1. north, from somewhere in the Northern hemisphere (favorite, ~ 40%) 2. north, from somewhere in the Southern hemisphere 3. south, from somewhere in the Southern hemisphere 4. south from somewhere in the Northern hemisphere Part 2: 32 48 6 2nd Most Difficult Question From a city at latitude 40 degrees, the highest above the horizon that the Sun can ever get in the sky is 1. 23.5 degrees 2. 50 degrees (favorite choice 35%) 3. 66.5 degrees 4. 73.5 degrees 5. 90 degrees Part 2: 28 47 1 7 8 Matter and Light Most Difficult Question Saturn’s mass is about 100 times larger than the mass of the Earth. What is the ratio of the gravitational force of the Earth on Saturn to the gravitational force of Saturn on the Earth? 1. 10000 to 1 2. 100 to 1 3. 1 to 1 4. 1 to 100 (favorite choice ~ 35%) 5. 1 to 10000 • What is matter made of? – Nucleus: massive, p and n, p determines what the atom is – Electrons: stuck in discrete energy orbitals, equal # to protons • Temperature: – How fast things are moving – What phase matter is in – What kind of light comes out • Electrons’ orbitals: – – – – Changes in electrons’ states makes or absorbs light (EM energy) Quantized: only specific energies! Each atom has it’s own specific lines Ionization: electrons escape for ANY energies above the minimum • Molecules: – Overlapped orbitals hold them together – Stretching, vibrating and motion of bonds can produce lines too. Part 2: from 26 35 9 PRS: Suppose an atomic nucleus contains 64 protons+neutrons. About how many times bigger in diameter would it be than a hydrogen nucleus containing just 1 proton? (1) (2) (3) (4) 4 8 16 64 V ∝ r3 V ↑ 64 x r ↑ 3 64 x = 4 x Answer: 1 10 Isotopes Same number of protons but differing numbers of neutrons. 11 Molecules • Atoms can join together by sharing electrons to make molecules. These chemical bonds hold the molecules together. 12 Phases of Matter • Matter can take many forms depending mostly on its temperature or internal energy. • As temperature climbs, the strength of bonding of the particles to each other grows weaker, while the kinetic energy grows larger. 2 Temperature Scales 13 • Fahrenheit scale – zero at freezing saltwater – 100 at body (whose?!) temperature • Kelvin scale – zero at zero energy – step size same as Celsius − only scale with temperature proportional to kinetic energy: T goes as KE = ½ mv2, v=avg. velocity of particles Electron orbitals are quantized 14 PRS: The LN2 in the beaker is boiling at 77K, that’s about 1/3 of room temperature (303 K). The molecules of nitrogen in the air are therefore moving with velocities ____ on average compared to the beaker. (1) (2) (3) (4) 27 x lower 9 x lower 3 x lower √3 x lower (5) 27 x higher (6) 9 x higher (7) 3 x higher (8) √3 x higher Answer: 8 15 16 Atomic Excitation and Ionization • As the energy increases, electrons go into more energetic orbits. • Electron orbitals depend on the energy of the electron • Only certain energies work— complete “wavelengths” • The energies depend on what kind of atom it is (nucleus) and how many electrons are present. This is important! • At high enough energies the electrons are stripped off -- Plasma. 17 Analyzing Spectra: Gratings and prisms 18 Spectra • Get out your diffraction grating. • The diffraction grating is like a prism--it splits up light into its component frequencies when it goes through the grating at an angle. • You can see a source of light directly but off to its left and right you will see all of its component colors. 3 19 20 Atoms in a Gas or Plasma Atomic Spectra • When we look at light generated by isolated atoms, the appearance of the spectrum is different. • Use your diffraction grating to compare several sources of light. • Note the individual colors that are present— these are called “spectral lines • Isolated atoms or molecules absorb and emit at specific wavelengths characterized by the particular type of atom or molecule. • The only possible wavelengths are those that correspond to the energy changes for electrons shifting between orbitals. • The wavelengths of spectral lines can tell us what the composition of a gas is. Photon Energies and Atomic Structure • Particles of light 21 (photons) have energies inversely proportional to their wavelength. • The colors emitted by an atom are related to the energies of atomic orbits. 23 22 Interactions of Light and Matter • Atoms can absorb a photon, raising an electron to a higher energy orbit. • Atoms emit a photon when an electron drops to a lower energy orbit. • If an atom absorbs enough energy, the electron flies off (ionization). What you are seeing with the Hydrogen Tube: 24 Hydrogen Spectrum 4
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