Particles with a Charge Did you know that there are charged particles in your body that conduct electricity? These charged particles are called ions. What is an electrolyte? Electrolyte is a compound that produce solutions of ions that conduct electricity in water (conduct an electric current) Give an example of an electrolyte. NaCl, Acetic Acid What is a nonelectrolyte? Nonelectrolytes are substances that do not form ions in water and cannot conduct electricity. Give an example of a nonelectrolyte. Organic molecules like ethyl alcohol and sucrose. Ionic Solutions form in two ways Ionization and Dissociation Ionization What is ionization? Water pulls apart the molecules of neutral atoms (polar covalent compound) forming ions. Draw of diagram of ionization (figure 10). HCl Dissociation + H2O H3O+ + Cl- What is dissociation? Ions already exist in the ionic compound. The compound is pulled apart into positive and negative ions by the attraction of surrounding polar water molecules. Draw a diagram of dissociation (figure 11 and 12). NaCl is pulled apart. Water molecules surround and separate the Na+ ions from the Cl- ions. Reading check: What are the differences and similarities between dissociation and ionization? Big difference is that ionization occurs with covalent compounds whereas dissociation occurs with ionic compounds. With dissociation the ions already exist in the compound. Big Similarity is that they both produce an electric current. Effects of Solute Particles Briefly describe each of the following effects: Lowering Freezing Point Adding a solute like antifreeze lowers the freezing point. (The added particles interfere with the formation of the pattern necessary for freezing.) Animal Antifreeze Body substances, like glycoprotein, prevent ice crystals from forming in moist tissues. (caribou-lower legs and fish) Raising Boiling Point Solute particles interfere with the evaporation of solvent particles. More energy is needed for the solvent to evaporate, therefore the boiling point will be higher. Car Radiators Solute particle block the surface making in more difficult for the solvent to vaporize. It takes a higher temp to make the radiator boil over. Reading check: Determine what has taken place, ionization or dissociation, if calcium phosphate Ca3(PO4)2 breaks in Ca+ and PO4. Dissociation (ionic compound) Think about it: In the Midwest, we put salt on ice that forms on sidewalks and driveways. The salt helps melt the ice, forming a saltwater solution. Explain why this solution may not refreeze. The salt acts like antifreeze. The ions from the salt interfere with the pattern necessary for freezing. When Water Won’t Work Why is water referred to as the universal solvent? Water can dissolve many things. Quick review: Water is polar because it has separated positive and negative areas What is a nonpolar substance? Nonpolar materials do not have positive & negative areas. Does water (which is polar) attract nonpolar substances? No Nonpolar Solutes Figure 15: Why don’t vinegar and oil mix? Vinegar is polar and oil is nonpolar. Is vinegar polar or nonpolar? Would it mix with water? Polar. Yes, it would mix with water. Is oil polar or nonpolar? Would it mix with water? Nonpolar. No, it would not mix with water. Vaersatile Alcohol Can a substance be both polar and nonpolar? Explain. Yes. For example, ethanol has a polar end and a nonpolar end. Useful Nonpolar Molecules Drawbacks of Nonpolar Solvents Mineral Oil is a solvent that can dissolve? Candle wax, bubble gum Turpentine is a solvent that can dissolve? Oil-based paint What are two drawbacks to using nonpolar solvents? They are flammable, some are toxic, some produce harmful vapor How soap works? Is soap a polar or nonpolar substance? Both polar and nonpolar How does soap work? The ionic end of soap will dissolve in water and the hydrocarbon portion (nonpolar side) will dissolve in oils and dirt. The hydrocarbon side removes the dirt/oil and then the water will wash it away. The nonpolar end will dissolve the oil/dirt Soap has a polar end and a nonpolar end. and the polar end will be attracted to the water (wash it away) Reading Check: Why doesn’t water alone clean oily dirt? Water is polar and can’t dissolve oil and dirt because they are nonpolar substances. Polarity and Vitamins Are vitamins polar or nonpolar compounds? Depends on the vitamin. Vitamin A is nonpolar, Vitamins B & C are polar Reading check: Explain the phrase “like dissolves like” and give an example of two polar “like” substances. Polar substance can mix/dissolve other polar substances and nonpolar can mix/dissolve other nonpolar. Examples: salt and water are both polar (salt will dissolve in the water to form a salt water solution); mineral oil and candle wax are both nonpolar Think about it: What might happen to your skin if you washed with soap too often? Because soap dissolves oil, washing with soap too often can strip your skin of natural oils.
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