Plasticizers and Solvents - daihachi

Plasticizers and Solvents
Phthalic Acid Esters
《 》: Measurement condition
Products
Formula
Appearance
DMP
C6H4(COOCH3)2
Dimethyl phthalate
Colorless
clear liquid
Colorless
clear liquid
Typical Properties
Freezing Point
Flash
˚C
Point
Viscosity [ mPa・s /25˚C ] ˚C
Heating Loss
%
105˚C ×5hrs
Boiling
Point
˚C
0
[13]
Description
Uses
156
220kg
Drum
G o o d co m p at i b i l i t y w i t h n i t ro ce l l u l o s e a n d
acetylcellulose resin.
High performance for light resistance.
High volatility.
Slightly soluble in water.
Plasticizer for nitrocellulose, acetylcellulose and
rubber.
Diluent for organic peroxides.
Insect repellant.
162
220kg
Drum
Good compatibility with nitrocellulose resin.
High performance for light resistance.
Good compatibility with general synthetic resins.
Hardly soluble in water.
Plasticizer for lacquer and ceramics binder.
Polyvinylacetate type adhesives.
Fragrance retainer.
197
220kg
Drum
Good compatibility with acetylcellulose.
Bringing high performance for light resistance, moisture
Plasticizer for cellulose, lacquer and synthetic leather.
resistance and elasticity to films.
Good compatibility with polyvinylchloride, polyvinylacetate.
Odorless.
≦30
1.192±
0.003
≦0.05
≦1.0
282
《101kPa》
≦30
1.120±
0.003
≦0.05
≦1.0
298
《101kPa》
-5
[11]
≦30
1.180 ~
1.187
《20/4˚C》
≦1.0
310
《101kPa》
13
[74]
Ester
Content
%
Volume
resistivity
30˚C・Ω cm
Boiling
Point
˚C
—
145
《0.53kPa》
-22
[4.9]
—
134
《0.4kPa》
-22
[5.3]
194
DEP
C6H4(COOC2H5)2
Diethyl phthalate
222
#10
―
C6H4
―
Ethylphthalyl ethyl
glycolate
COOC2H5
COOCH2COOC2H5
Colorless
clear liquid
280
≦0.05
Flame Retardants
Containers
Plasticizers
and Solvents
mol.weight
Specifications
Specific
Acid
Color
Gravity
value
APHA
20/20˚C KOH mg/g
Dibasic Carboxylic Acid Esters
Colorless
to light
yellowish
435 clear liquid
≦50
1.021±
0.005
Colorless
to light
Bis
[2-(2-butoxyethoxy) CH2COOC2H4OC2H4OC4H9 yellowish
ethyl]adipate
n-C4H9(OCH2CH2)2OH 15% clear liquid
≦100
Appearance
mol.weight
DBA
Dibutyl adipate
DIBA
Diisobutyl adipate
BXA
CH2COOC4H9
Colorless
to light
yellowish
258 clear liquid
|
(CH2)2
|
CH2COOC4H9
CH2COOCH2CH(CH3)2
Colorless
to light
yellowish
258 clear liquid
|
(CH2)2
|
CH2COOCH2CH(CH3)2
CH2COOC2H4OC2H4OC4H9
|
2)2
Bis
[2-(2-butoxyethoxy) (CH
|
ethyl]adipate
CH2COOC2H4OC2H4OC4H9
BXA-R
Bis(2-ethylhexyl)
azelate
DBS
Dibutyl sebacate
DOS
Bis(2-ethylhexyl)
sebacate
DESU
Diethyl succinate
|
(CH2)2
|
≦0.05
≦1.0
—
≧99.0
≧99.0
|
(CH2)5
|
CH2COOC8H17
161
Various rubbers.
Excellent compatibility and plasticity with Printing inks.
polyvinylchloride, polyvinylacetate resins and P l a s t i c i z e r fo r p o l y v i ny l c h l o r i d e, a n d
various rubbers.
polyvinylacetate resins.
Resin paints and lacquer.
158
190kg
Drum
Excellent compatibility and plasticity with
polyvinylchloride, polyvinylacetate resin, butyl
rubber, nitrile rubber and neoprene rubber, etc.
Maintaining the plasticity under low
temperature.
-19
[18]
207
200kg
Drum
|
(CH2)6
|
CH2COOC4H9
314
CH2COOC8H17
|
(CH2)6
|
CH2COOC8H17
427
CH2COOC2H5
|
CH2COOC2H5
Packaging film for frozen food.
Adhesives.
Various rubbers.
Printing inks.
—
≦1.0
≦0.5
1.447±
0.005
—
—
230 ~ 240
《0.27kPa》
1.014±
0.010
≦1.0
≦2.5
1.445±
0.005
—
—
—
-24
[15]
145
200kg
Drum
≦80
0.918±
0.003
≦0.08
≦0.10
—
—
≧1.0x1012
220 ~ 245
《0.53kPa》
-60
[16]
211
180kg
Drum
High cold resistance.
Low volatility.
Plasticizer with cold resistance for polyvinylchloride
High performance for heat resistance.
film and leather.
Improves touch when added in polyvinylchloride.
≦30
0.938±
0.003
—
345
《101kPa》
-9
[7.5]
190
190kg
Drum
Tasteless and odorless.
Plasticizer for food packaging material such as
High performance for cold resistance.
polyvinylidenechloride.
Bringing higher processability of polyvinylchloride.
High grade insulating oil.
Good compatibility with synthetic rubber.
Colorless
clear
liquid
≦30
0.915±
0.003
≦0.05
≦0.10
—
—
≧1.0x1012
377
《101kPa》
-62
[18]
222
180kg
Drum
Higher performance for cold resistance than DOZ.
Low volatility.
High performance for migration resistance
and electrical properties.
Compatibility with synthetic rubber, too.
Plasticizer with cold resistance for
polyvinylchloride such as electric wire
covering material and films.
High grade lubricating oil.
Colorless
clear
liquid
≦20
1.042±
0.003
≦0.2
—
—
≧99.0
—
217.7
《101kPa》
—
[2.5]
105
200kg
Drum
Excellent solvent for resins and fragrances.
Fragrance retainer.
Colorless
to light
yellowish
413 clear liquid
CH2COOC4H9
Uses
190kg
Drum
394
CH2COOC8H17
Description
≦1.0
85%
174
5
≦0.05
Containers
CH2COOC2H4OC2H4OC4H9 DOZ
25
Colorless
clear
liquid
≦0.05
≦0.20
—
≧99.0
Good compatibility with natural and synthetic
rubber.
Maintaining plasticity under low temperature.
Low volatility.
Plasticizer with cold resistance for natural and
High performance for heat resistance.
synthetic rubber and vinyl-type resins.
Plasticizer for polyurethane elastomer.
Good compatibility with natural and synthetic Especially, highly suitable plasticizer for nitrile
rubber.
rubber.
Maintaining plasticity under low temperature.
Especially, high per for mance for cold
resistance and gasoline resistance.
Others
≦40
0.955±
0.003
Formula
Typical Properties
Freezing Point
Flash
˚C
Point
˚C
[ Viscosity mPa・s /25˚C ]
Resin Modifiers
≦50
0.962±
0.003
Products
Specifications
Heating Loss Refractive
Acid
%
value
KOH mg/g 125˚C ×3hrs Index n D
Metal Extractants
Color
APHA
Specific
Gravity
20/20˚C
6
Plasticizers and Solvents
Phosphoric Acid Esters
Products
Formula
《 》: Measurement condition
Appearance
TMP
Trimethyl phosphate
Colorless
clear liquid
O=P(OCH3)3
≦20
1.071±
0.003
≦30
0.978±
0.003
≦70
0.925±
0.003
—
≦0.05
—
1.403±
0.002
≦0.07
≦1.50
《105˚C x3hrs》
≦0.2
140
TEP
Triethyl phosphate
Colorless
clear liquid
O=P(OC2H5)3
[ mPa・s /25˚C ]
P%
≧21.0
180 ~ 195
《101kPa》
≦-70
[2.0]
—
216
《101kPa》
-56
[1.6]
—
289
《101kPa》
≦-80
[3.3]
≦-70
[12]
25
1.395±
0.002
Water
Content
%
≦0.2
—
Typical Properties
Freezing Point
P
˚C
Viscosity %
Boiling
Point
˚C
22.1
17.0
Flash
Point
˚C
Containers
—
220kg
Drum
Relatively low boiling point.
A n t i - c o l o r i n g a g e n t , fo r p o l y e t hy l e n e
Completely soluble in water.
terephthalate fiber (resin).
Low viscosity.
Polymerization control agent.
Good compatibility with various synthetic Solvent for acetylcellulose resin.
resins.
Catalyst for polymerization of maleic acid.
111
210kg
Drum
A n t i - c o l o r i n g a g e n t fo r p o l ye t hy l e n e
Soluble in organic solvents as well as water.
terephthalate fiber (resin).
Low viscosity and effective as viscosity Polymerization control agent.
reducing agent.
Viscosity reducing agent of polyol as raw
material of rigid polyurethane.
160
180kg
Drum
Good compatibility with synthetic resins and rubbers.
High performance for light resistance and cold
resistance.
Effective in anti-foaming and extraction of metal
salt.
204
180kg
Drum
Plasticizer with cold resistance for synthetic
Bringing cold resistance and plasticity to
rubber and polyvinylchloride.
polyvinylchloride, polyvinylacetate and
Plasticizer as well as flame retardant for plastisol.
synthetic rubber.
Solvent for the manufacturing of hydrogen
High performance for flame retarding.
peroxide.
225
25kg
Paper bag
*500kg
182
TBP
Tributyl phosphate
Colorless
clear liquid
O=P(OC4H9)3
—
—
11.6
266
TOP
Tris(2-ethylhexyl)
phosphate
435
White
flake
≦0.15
—
—
—
Chloride
Not cause
turbidness
Melting
Point
˚C
≧48.5
399
《101kPa》
—
Color after
heated
150˚C ×1hr・APHA
≦60
Volume
resistivity
30˚C・Ω cm
≧5x109
241 ~ 255
《0.53kPa》
-35
[58]
8.4
240
220kg
Drum
—
—
240 ~ 260
《0.27kPa》
-15
[172]
7.6
253
220kg
Drum
—
245
《0.53kPa》
-30
[36]
240
220kg
Drum
—
Colorless
to light
O=P(OC6H4CH3)3
yellowish
368 clear liquid
≦50
1.170±
0.010
≦0.05
≦0.10
1.557±
0.003
Colorless to
yellowish
O=P[OC6H3(CH3)2]3
clear
Trixylenyl phosphate
liquid
410
≦200
1.145±
0.025
≦0.1
≦0.15
1.552±
0.003
≦50
1.210±
0.005
Triphenyl phosphate
326
TCP
Tricresyl phosphate
TXP
―
Cresyl diphenyl
phosphate
O=P
―
CDP
Colorless to
light
yellowish
OC6H4CH3
clear liquid
340
(OC6H5)2
≦0.05
≦0.15
—
—
7.1
9.5
9.1
Flaky solid material.
Good compatibility with various synthetic
resins and polyvinylchloride.
Low volatility.
Bringing water resistance and oil resistance.
High performance for flame retarding due to
high phosphorus content.
Flame retarding plasticizer for phenolic resin,
epoxy resin, various engineering plastics,
acetate plastics and synthetic rubber.
Flame retarding.
Bringing heat resistance and high insulation
property.
Plasticizer with flame retarding for agricultural
High lubricating property, especially for polyvinylchloride film, phenolic resin, epoxy
extreme pressure.
resin and various engineering plastics.
Non-flammable hydraulic oil.
Low volatility.
Additive for extreme pressure lubricating oil.
High performance for water resistance.
Flame retarding.
Good extreme pressure lubrication same as
TCP.
Effective in gelling for polyvinylchloride
Bringing cold resistance and stain resistance.
Lower viscosity and better flame retarding than TCP.
Effective in gelling for polyvinylchloride
Bringing cold resistance and stain resistance.
Lower viscosity and better flame retarding than TCP.
Plasticizer with flame retarding for
polyvinylchloride, phenolic resin, epoxy resin
and various engineering plastics.
Others
*Flexible container bag
7
Additive for rubber.
A n t i - fo a m i n g a g e n t fo r p a i n t / p a p e r
manufacturing.
Extraction and refinement of rare earth metal
and uranium.
Resin Modifiers
—
≦0.8
—
O=P(OC6H5)3
≦0.03
—
220 ~ 250
《0.67kPa》
Uses
Metal Extractants
TPP
O=P(OC8H17)3
Colorless
to light
yellowish
liquid
Description
Flame Retardants
≦30
1.215±
0.005
Specifications
Heating Loss Refractive
Acid
%
value
KOH mg/g 125˚C ×3hrs Index n D
Plasticizers
and Solvents
mol.weight
Color
APHA
Specific
Gravity
20/20˚C
8
Plasticizers and Solvents
Ricinolic Acid Ester
Products
《 》: Measurement condition
Formula
Color
APHA
Colorless to
yellowish
clear liquid
≦250
0.938±
0.005
mol.weight
Methyl acetyl
ricinoleate
OCOCH3
|
HC-CH2CH(CH2)5CH3
=
MAR-N
HC-(CH2)7COOCH3
355
Specifications
Heating Loss Refractive
Acid
%
value
KOH mg/g 125˚C ×3hrs Index n D
Refractive
Index n D
Boiling
Point
˚C
≦0.2
—
—
Ester
Content
%
Water
Content
%
Boiling
Point
˚C
≧99.0
≦0.15
258
《101kPa》
Ester
Content
%
Boiling
Point
˚C
-30
[15]
198
190kg
Drum
Uses
High performance for cold resistance, and improving
Most suitable for plastisol and organosol.
film properties Slow gelling in spite of outstanding
Plasticizer for synthetic rubber.
plasticizing efficiency.
Adipic Acid Polyester
Products
Formula
Color
APHA
Colorless to
yellowish
brown clear
liquid
≦500
mol.weight
BAA-15
Poly(1,3-butanediol
adipate)
—
av.1500
1.126±
0.003
≦2.0
25
Typical Properties
Freezing Point
Flash
˚C
Point
˚C
[ Viscosity mPa・s /25˚C ]
-23
[4,250]
283
Containers
220kg
Drum
Description
Uses
High performance for cold resistance, oil resistance
Plasticizer for polyvinylchloride such as packaging
and migration resistance.
film for food.
Low toxicity.
Metal Extractants
Appearance
Specifications
Heating Loss
Specific
Acid
%
Gravity
value
20/20˚C KOH mg/g 125˚C ×3hrs
Acetic Acid Ester
Products
Formula
Appearance
Color
APHA
Colorless
clear
liquid
≦20
1.160±
0.003
≦0.05
Color
APHA
Specific
Gravity
20/20˚C
mol.weight
TRIACETIN
Glyceryl triacetate
CH2OOCCH3
|
CHOOCCH3
|
CH2OOCCH3
218
Specifications
Heating Loss Refractive
Acid
%
value
KOH mg/g 125˚C ×3hrs Index n D
Specific
Gravity
20/20˚C
25
—
—
Typical Properties
Freezing Point
Flash
˚C
Point
˚C
[ Viscosity mPa・s /25˚C ]
-62
[17]
144
Containers
220kg
Drum
Description
Uses
Plasticizer for acetylcellulose,
Good compatibility with acetylcellulose.
Lacquer.
Soluble in water partially as well as in organic
Inkpad seal stamp.
solvent.
Fragrance retainer.
Adipic Acid Ester
Products
Formula
Appearance
mol.weight
DAIFATTY-101
Adipic acid ester
9
—
Colorless to
light
yellowish
clear liquid
≦100
—
Specifications
Heating Loss Refractive
Acid
%
value
KOH mg/g 125˚C ×3hrs Index n D
25
≦0.5
—
—
—
—
Typical Properties
Freezing Point Containers
Flash
˚C
Point
Viscosity ˚C
[ mPa・s /25˚C ]
218
—
[19]
200kg
Drum
Description
Uses
Others
190 ~ 220
《0.67kPa》
Description
Resin Modifiers
—
1.453±
0.003
≦0.35
Containers
Flame Retardants
Boiling
Point
˚C
25
≦5
Typical Properties
Freezing Point
Flash
˚C
Point
Viscosity [ mPa・s /25˚C ] ˚C
Ester
Content
%
Plasticizers
and Solvents
Appearance
Specific
Gravity
20/20˚C
Very good compatibility with poly-lactic acid.
High performance for plasticity, bleeding resistance
Plasticizer for poly-lactic acid mainly.
and water resistance.
Crystallization accelerating agent in poly-lactic acid.
Good compatibility with other biodegradable
plastics, too.
10