TAIKO CLAY MARKETING SDN. BHD (429100-K) (Incorporated in Malaysia) Business Address: B2-05-01, Block B2, Meritus @ Oasis Corporate Park, No. 2, Jalan PJU 1A/2, Ara Damansara, 47301 Petaling Jaya, Selangor Darul Ehsan, Malaysia. Tel No. 603-7660 7716 Fax No. 603-7660 9913 Email: [email protected] www.taikogroup.net SAFETY DATA SHEET Section 1 – Identification of the hazardous chemical and of the supplier Product identifier Product name: Activated Bleaching Earth. Trade name: TAIKO®. IUPAC name: Not Applicable. CAS number: 70131-50-9. Other means of identification Chemical name: Bentonite, acid activated. Synonym: Activated clays. Recommended use of the As adsorbent (processing aids) in refining edible oils and fats. chemical and restrictions on use Details of principal supplier Supplier Name: Taiko Clay Marketing Sdn. Bhd. Address: B2-05-01, BLOK B2, MERITUS @ OASIS, CORPORATE PARK (PUSAT KORPORAT OASIS), NO.2 JALAN PJU 1A/2, ARA DAMANSARA, 47301 PETALING JAYA, SELANGOR, MALAYSIA. Phone number: +603 7660 7716 Fax number: +603 7660 9913 Email: [email protected] Section 2 – Hazard Identification Classification of the substance Not classified as a hazardous chemical. and any nation or regional information Label elements Hazard pictogram: Signal word: Warning. Hazard statement: May cause skin, eye and respiratory irritation and harmful if inhaled. 1. 2. 3. 4. 5. Other hazards which do not result in classification or are not covered by the Regulations Precautionary statement: Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. Do not eat or drink when using this product. Avoid breathing dust. Use only outdoors or in a well-ventilated area. Not Applicable. This information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process. Such information is, to the best of our knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself/herself as to the suitability of such information for his/her own particular use. TAIKO CLAY MARKETING SDN. BHD (429100-K) (Incorporated in Malaysia) Business Address: B2-05-01, Block B2, Meritus @ Oasis Corporate Park, No. 2, Jalan PJU 1A/2, Ara Damansara, 47301 Petaling Jaya, Selangor Darul Ehsan, Malaysia. Tel No. 603-7660 7716 Fax No. 603-7660 9913 Email: [email protected] www.taikogroup.net Section 3 – Composition and information of the ingredients of the hazardous chemical Chemical identity Bentonite, acid activated Common name, synonyms Activated Bleaching Earth CAS Number 70131-50-9 EINECS number 274-324-8 Chemical composition Typical chemical composition SiO2 55 – 80 Al2O3 5 – 20 Fe2O3 2 – 10 MgO 0–8 CaO 0–5 Na2O 0–2 K2O 0–2 Note (Nota): 1. Analysis may vary with clay sources and is quoted as % dry weight. 2. Elements present in the clay have been expressed as their oxides. 3. Typical analysis is available at Technical Data Sheet. Not Applicable. Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance Section 4 – First-aid measures Description of necessary measures, subdivided according to the different routes of exposure, i.e. inhalation, skin and eye contact and ingestion Most important symptoms/effects, acute and delayed Identification of immediate medical attention and special treatment, if necessary Inhalation Movement of the exposed person to fresh air, loosen clothing and seek medical attention. Skin Irrigate thoroughly with cold water. Seek medical attention if symptoms persist. Eye Irrigate thoroughly with cold water. Seek medical attention if symptoms persist. Ingestion If small amounts, drink copious amounts of water. If large amounts are ingested seek medical attention. Not applicable. Not applicable. This information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process. Such information is, to the best of our knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself/herself as to the suitability of such information for his/her own particular use. TAIKO CLAY MARKETING SDN. BHD (429100-K) (Incorporated in Malaysia) Business Address: B2-05-01, Block B2, Meritus @ Oasis Corporate Park, No. 2, Jalan PJU 1A/2, Ara Damansara, 47301 Petaling Jaya, Selangor Darul Ehsan, Malaysia. Tel No. 603-7660 7716 Fax No. 603-7660 9913 Email: [email protected] www.taikogroup.net Section 5 – Fire-fighting measures Suitable (and unsuitable) Products are non-combustible. extinguishing media Use extinguisher to suit the cause of fire. Products may be a slip hazard when wet. Specific hazards arising from the Not applicable. chemical (e.g. nature of any combustion hazardous products) Special protective equipment and Not applicable. precautions for fire-fighters. Section 6 – Accidental release measures Personal precautions, protective Avoid generating excessive dust and if necessary wear protective clothing. equipment and emergency Refer to Section 8. procedures Environmental precautions Not applicable. Methods and material for Sweep up or vacuum spilled products and dispose off in accordance with containment and cleaning local regulations. Contact Taiko Clay Marketing Sdn. Bhd. (TCM) to activate emergency respond procedures (ERP), if necessary. Section 7 – Handling and storage Precautions for safe handling Handle using methods, which minimize generation and dispersion of dust. Ensure adequate ventilation at point of use. Avoid breathing dust. Use NIOSH/DOSH approved respirator where the dust level is above Permissible Exposure Limit (PEL). Advice on personal hygiene: 1. 1. Do not eat or drink when using this product. 2. 2. Wash hands after use. Conditions for safe storage, Store in a dry environment and covered warehouse. High humidity causes including any incompatibilities caking of the powder. Storage of product in bulk silo is highly recommended. Isolate from toxic substances to avoid contamination. Avoid unsegregated storage with incompatible materials, which decompose in the presence of dusts and weak acid such as cyanides, sulphates and peroxides. Avoid long term contact with galvanized or mild steel surfaces under damp conditions. Avoid storage with unsaturated organic compounds. This information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process. Such information is, to the best of our knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself/herself as to the suitability of such information for his/her own particular use. TAIKO CLAY MARKETING SDN. BHD (429100-K) (Incorporated in Malaysia) Business Address: B2-05-01, Block B2, Meritus @ Oasis Corporate Park, No. 2, Jalan PJU 1A/2, Ara Damansara, 47301 Petaling Jaya, Selangor Darul Ehsan, Malaysia. Tel No. 603-7660 7716 Fax No. 603-7660 9913 Email: [email protected] www.taikogroup.net Section 8 – Exposure controls and personal protection Control parameters e.g. Maximum Permissible Exposure Limits (PEL) permissible exposure limit and in terms of respirable crystalline silica:biological limit values WEL/OES HSE (UK) : 0.3mg/m3 TWA ACGIH (USA) : 0.05mg/m3 TWA MAC- MSZW (Netherlands) : 0.075mg/m3 TWA Due to variation in PEL, users are advised to refer to the relevant PEL adopted in the countries concerned. Appropriate engineering controls Individual protection measures, such as personal protective equipment PEL is expressed as a Time-Weighted Average (TWA) concentration of that product over an 8-hour working shift. Note: The typical respirable crystalline silica (RCS) for fresh bleaching earth of ≤ 1%, is compliable for respirable fraction < 5 µm. Maintain air concentration below PEL, using engineering controls if necessary. Use only in well-ventilated area. Eye/face protection Wear safety glasses with side shields. Eye wash bottles should be provided at places where accidental exposure may be possible. Contact lenses should not be worn. Skin protection Normal work wears. Wear PVC or rubber gloves. No further skin protection is required unless there is a possibility of prolonged personal contact, and then appropriate protective skin cover is recommended. Respiratory protection NIOSH/DOSH approved respirators should be used if the PEL cannot be met even after instituting engineering controls. Thermal hazards Not Applicable. This information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process. Such information is, to the best of our knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself/herself as to the suitability of such information for his/her own particular use. TAIKO CLAY MARKETING SDN. BHD (429100-K) (Incorporated in Malaysia) Business Address: B2-05-01, Block B2, Meritus @ Oasis Corporate Park, No. 2, Jalan PJU 1A/2, Ara Damansara, 47301 Petaling Jaya, Selangor Darul Ehsan, Malaysia. Tel No. 603-7660 7716 Fax No. 603-7660 9913 Email: [email protected] www.taikogroup.net Section 9 – Physical and chemical properties Appearance Free flowing powder. Odour Earthly smell. Odour threshold Not applicable. pH Mildly acidic in suspension. Melting point/freezing point Not applicable. Initial boiling point and boiling Not applicable. range Flash point Not applicable. Evaporation rate Not applicable. Flammability (solid/gas) Not applicable. Upper/lower flammability or Not applicable. explosive limits Vapour pressure Not applicable. Vapour density Not applicable. Relative density 350-1000kg/m3. Solubility(ies) Negligible solubility in water, solvents and oils. Partition coefficient: nNot applicable. octanol/water Auto-ignition temperature Not applicable. Decomposition temperature Not applicable. Viscosity Not applicable. Section 10 – Stability and reactivity Reactivity Product may cause polymerization with generation of heat when contacted with unsaturated organic materials. Chemical stability Product is chemically stable under ambient conditions. Possibility of hazardous Hydrogen gas may be liberated (explosion hazard) when product is contacted reactions with metals in wet conditions. Polymerization with generation of heat may occurred when product is contacted with unsaturated organic materials. Condition to avoid (e.g. static Avoid exposure to water. discharge, shock or vibration) Incompatible materials Avoid metals especially when wet since hydrogen gas may be liberated (explosion hazard). Avoid contact with unsaturated organic materials as product may cause polymerization with generation of heat. Hazardous decomposition Dry products – None. products The product saturated with oxidisable liquid can lead to spontaneous heating effects, which may result in a fire. This information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process. Such information is, to the best of our knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself/herself as to the suitability of such information for his/her own particular use. TAIKO CLAY MARKETING SDN. BHD (429100-K) (Incorporated in Malaysia) Business Address: B2-05-01, Block B2, Meritus @ Oasis Corporate Park, No. 2, Jalan PJU 1A/2, Ara Damansara, 47301 Petaling Jaya, Selangor Darul Ehsan, Malaysia. Tel No. 603-7660 7716 Fax No. 603-7660 9913 Email: [email protected] www.taikogroup.net Section 11 – Toxicological information Information on the likely routes of Inhalation exposure (inhalation, ingestion, May be harmful if inhaled. skin and eye contact) Skin May cause skin irritation. Eye May cause eye irritation. Ingestion May be harmful if swallowed. Symptoms related to the Not Available. physical, chemical and toxicological characteristics Delayed and immediate effects Long-term exposure to dust in excess of the PEL may result in fibrosis of the and also chronic affects from lung tissue. short and long term exposure Numerical measures of Not Available. toxicology (such as acute toxicity estimates) Section 12 – Ecological information Ecotoxicity (aquatic and There is no known ecological problem associated with this product. terrestrial, where applicable) Persistence and degradability Not applicable. Bioaccumulative potential Not applicable. Mobility in soil Not applicable. Other adverse effects Not applicable. Section 13 – Disposal information Description of waste residues Dispose off in accordance with local and federal regulations, using an approved waste disposal contractor. Information on safe handling and Spent bleaching earth should be stored in dedicated and well-ventilated method of disposal, including the storage area. disposal of any contaminated packaging This information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process. Such information is, to the best of our knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself/herself as to the suitability of such information for his/her own particular use. TAIKO CLAY MARKETING SDN. BHD (429100-K) (Incorporated in Malaysia) Business Address: B2-05-01, Block B2, Meritus @ Oasis Corporate Park, No. 2, Jalan PJU 1A/2, Ara Damansara, 47301 Petaling Jaya, Selangor Darul Ehsan, Malaysia. Tel No. 603-7660 7716 Fax No. 603-7660 9913 Email: [email protected] www.taikogroup.net Section 14 – Transportation information UN number Not applicable. UN proper shipment name Not applicable. Transport hazard class(es) Not applicable. Packing group, if applicable Not applicable. Environmental hazards (e.g. Not applicable. marine pollutant, Yes/No) Transport in bulk (according to There is no specific transportation precautions required. However, open Annex II of MARPOL 73/78 and vehicles should be covered to prevent products from being wetted. This the IBC code) product is not classified as a hazardous chemical under MALAYSIA Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013. Section 15 – Regulatory information Safety, health and environmental International agreements of Montreal Protocol (Ozone Depleting regulations specific for the Substances), Stockholm Convention (Persistent Organic Pollutants), product in question Rotterdam Convention (Prior Informed Consent) and Basel Convention (Hazardous Waste) do not apply to this product. This product complies with: 1. MALAYSIA Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013. 2. MALAYSIA Occupational Safety and Health Act 1994. 3. FEDIOL Guidelines (Latest Revision). Section 16 – Other information Date of preparation of the SDS Date of revision of the SDS Key literature references and sources for data used to compile the SDS 13th February 2017. 7th Issue. 1. MALAYSIA Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013. 2. MALAYSIA Occupational Safety and Health Act 1994. Key/legend to the abbreviations and acronyms used in the SDS Other information deems necessary by a supplier 3. FEDIOL Guidelines (Latest Revision). Not Available. Not Available. This information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process. Such information is, to the best of our knowledge and belief, accurate and reliable as of the date indicated. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself/herself as to the suitability of such information for his/her own particular use.
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