SAFETY DATA SHEET
ALPHA COATING TECHNOLOGIES, LLC
SECTION 1 - IDENTIFICATION
PRODUCT CODE/IDENTITY: ACT S0-659
PRODUCT TRADE NAME: RAL 6011 RESEDA GREEN
USE OF SUBSTANCE: COATINGS
SUPPLIER:
ALPHA COATING TECHNOLOGIES
EMERGENCY MEDICAL/SPILL INFO: (630) 268-8787
TECHNICAL INFORMATION: (630) 268-8787
PRODUCT SAFETY/MSDS INFORMATION: 1735 W Cortland court Addison Il 60101
DATE OF MSDS PREPARATION: 8/23/2016
SECTION 2:
HAZARD IDENTIFICATION
OSHA/HCS STATUS: This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200)
CLASSIFICATION OF THE MIXTURE:
Combustible Dust
Acute Toxicity: Category 3
Skin Sensistization: category 1
Germ Cell Mutagenity: Category 1B
Carcinogenity: Category 2
Specific Target organ toxicity: Respiratory tract irritation (single exposure)
category 3
Specific Target organ toxicity: Respiratory tract irritation (repeated
exposure) category 2
Percentage of the mixture consisting of ingredients of unknown toxicity: 80%
Hazard Pictograms
Signal Word: Danger
Hazard Statements: May form combustible dust in air
Toxic if swallowed.
May cause allergic skin reaction.
May cause genetic defects
May cause respiratory irritation
May cause damage to organs through prolonged or repeated exposure
Precautionary Statements: Dusts generated during application of powder coatings
harmful if inhaled. May be harmful if swallowed. May cause slight skin
irritation. Causes severe eye irritation. Prolonged or repeated contact may
cause an allergic skin reaction.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS
PERCENT
CAS NUMBER
--- ---------------------------------------- ------- --------------- ----------POLYESTER RESIN
≥50-<75
BARIUM SULFATE
≥10-<20
7727-43-7
TRIGLYCIDYL ISOCYANURATE
≥1 -<5
2451-62-9
TITANIUM DIOXIDE
≥20- <30
13463-67-7
There are no additional ingredients present which within the current knowledge
of the supplier and in the concentrations applicable are classified as hazardous
to health or environment and hence require reporting in this section
SECTION 4 - FIRST AID MEASURES
INGESTION: If swallowed, give one to two eight ounce glasses of water, but do
not induce vomiting. Gently wipe out inside mouth to remove any residual
material.
EYE CONTACT: In case of eye contact, remove contact lenses and flush eyes
immediately with a gentle stream of lukewarm water for at least 15 minutes.
SKIN CONTACT: In case of skin contact, flush immediately with plenty of water
for at least 15 minutes followed by washing with soap and water.
INHALATION: If affected by inhalation of powder coating dust, remove to fresh
air. Apply artificial respiration and other support measures as required.
OTHER: If ingestion, any type of overexposure or symptoms of overexposure occur
during or following the use of this product, contact a poison control center,
emergency room or physician immediately; have Material Safety Data Sheet
information available.
SECTION 5 - FIRE FIGHTING MEASURES
FLASHPOINT: Not applicable
FLAMMABLE LIMITS: Lower explosion limit (LEL): 1.5
Upper explosion limit (UEL): Not available
EXTINGUISHING MEDIA: Use extinguishers appropriate for surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Dust can form explosive mixture in air.
SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Water spray
may be used to cool closed containers that are exposed to extreme heat. If water
is used, fog nozzles are preferable. Firefighters should wear self-contained
breathing apparatus and full protective clothing.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Return material to
container.
WASTE DISPOSAL METHOD: Waste material must be disposed of in accordance with
federal, state, provincial, and local environmental control regulations. Empty
containers should be recycled or disposed of through an approved waste
management facility.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES: Put on appropriate personal protective equipment (see
section 8). Persons with a history of skin sensitization problems should not be
employed in any process in which this product is used. Do not use until all
safety precautions are read and understood.
HANDLING AND STORAGE PRECAUTIONS: For better shelf life, do not store above 80
degrees Fahrenheit (26 degrees C.).
OTHER PRECAUTIONS: Store in cool dry place.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS
INGREDIENT NAME
POLYESTER RESIN
BARIUM SULFATE
Triglycidyl Isocyanourate
Titanium Dioxide
EXPOSURE LIMITS
NONE
ACGIH TLV (United States 4/2014)
TWA: 5 mg/m3 8 hours. Form: inhalable
fraction
OSHA PEL (United States 2/2013)
TWA: 5 mg/m3 8 hours Form: Inhalable
fraction
TWA 15 mg/m3 8 hours Form: Total dust
ACGIH TLV (United States 4/2014)
TWA: 0.05 mg/m3 8 hours
OSHA PEL (US 2/2013)
TWA 15 mg/m3 8 hours Form: Total dust
ACGIH TLV (US 4/2014)
TWA: 10 mg/m3 8 hours
PERSONAL PROTECTIVE EQUIPMENT FOR:
EYE PROTECTION: Wear sufficient eye protection to prevent contact with powdered
materials.
SKIN PROTECTION: Chemically resistant impervious gloves should be worn at all
times when handling chemical products.
RESPIRATORY PROTECTION: Use an appropriate NIOSH-approved particulate filter
respirator. Read the respirator manufacturer's instructions and literature
carefully to determine the type of airborne contaminants against which the
respirator is effective, its limitations, and how it is to be properly fitted
and used.
OTHER EQUIPMENT: Clean contaminated clothing and shoes.
VENTILATION REQUIREMENTS: Overexposure to powder coatings dust may be prevented
by ensuring ventilation controls, dust exhaust, or fresh air entry. Provide
general dilution or local exhaust ventilation in volume and pattern to keep the
concentration of ingredients listed in Section 2 below the lowest suggested
exposure limits, the LEL below the stated limit, and to remove decomposition
products during welding or flame cutting.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
% VOLATILE/VOLUME: .090
% SOLIDS BY WEIGHT: 99.95
SPECIFIC GRAVITY: 1.50 +/- 0.05
EVAPORATION RATE(BuOAc=100): 37
ODOR/APPEARANCE: Free flowing powder with minimal odor.
SECTION 10 - STABILITY AND REACTIVITY
This product is normally stable and will not undergo hazardous reactions.
INCOMPATIBILITY (MATERIALS AND CONDITIONS TO AVOID): High concentrations of
airborne dust may ignite explosively. All ignition sources should be eliminated
when this product is dispersed in air. Avoid contact with strong alkalies,
strong mineral acids, or strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: May produce the following hazardous
decomposition products when exposed to extreme heat: carbon monoxide ; carbon
dioxide ; lower molecular weight polymer fractions; oxides of nitrogen ; Extreme
heat includes, but is not limited to, flame cutting, brazing, and welding.
SECTION 11: TOXICOLOGICAL INFORMTAION
INGREDIENT
RESULT
SPECIES
TRIGLYCIDYL
LC 50
Rat – female
ISOCYANOURATE
Inhalation
dust and mists
Ld 50 oral
Rat
Titanium
dioxide
LD 50 oral
Rat
DOSE
650 mg/m3
138mg/m3
>10g/kg
EXPOSURE
4 hours
IRRITATION: SKIN EYES AND RESPIRATORY:
mixture itself.
SENSITIZATION:
There are no data available on the
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
MUTAGENITY: There are no data available on the mixture itself.
CARCINOGENITY: There are no data available on the mixture itself
CLASSIFICATION
INGREDIENT
Titanium dioxide
OSHA
-
IARC
2B
NTP
-
IARC:1, 2A, 2B,3,4
NTP: Known to be a human carcinogen; reasonably anticipated to be a human
carcinogen
OSHA: +
Not listed /Not regulated: REPRODUCTIVE TOXICITY: There are no data available on the mixture itself
SPECIFIC TARGET ORGAN TOXICITY (Single exposure)
Name
Category
polyester
3
SPECIFIC TARGET ORGAN TOXICITY (REPATED EXPOSURE)
NAME
CATEGORY
Triglycidyl isocyanourate
2
Target organs:
Contains material which causes damage to the following organs:
upper respiratory tract, skin, eyes
Contains material which may cause damage to the following
organs: kidneys, lungs, the reproductive system, testes
Potential acute health effects
Eye contact: may cause eye irritation
Inhalation: may cause respiratory irritation
Skin contact: may cause allergic skin reaction
Ingestion: toxic if swallowed
SHORT TERM EXPOSURE: There are no data available on the mixture itself
LONG TERM EXPOSURE: There are no data available on the mixture itself
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: May cause damage to organs through prolonged exposure. Repeated or
prolonged exposure may lead to respiratory irritation. Severe allergic reaction
may occur when exposed low levels
Carcinogenity: Suspected of causing cancer
Mutagenity: May cause genetic defects
Tetragenity: No known effects
Developmental effects: No known effects
Acute Toxicity estimates
Route
oral
ATE value
219.9 mg/kg
Toxicity
ingredient
Titanium dioxide
result
Acute LC50>100
mg/l fresh water
species
Daphnia – Daphnia
magna
Exposure
48 hours
SECTION 13: DISPOSAL CONSIDERATION:
The disposal of this product should comply with the requirements of
environmental protection and waste disposal legislation and any regional and
local authority requirements.
SECTION 14: TRANSPORT INFORMATION
UN NUMBER
UN PROPER SHIPPING
NAME
TRANSPORT HAZARD
CLASS
PACKING GROUP
EVVIRONMENTAL
HAZARD
MARINE POLLUTANT
SUBSTANCES
DOT
NOT REGULATED
-
IMDG
NOT REGULATED
-
IATA
NOT REGULATED
-
-
-
-
NO
NO
NO
NA
NA
NA
SECTION 15: REGULATORY INFORMATION
United States: (TSCA 8b : All components are listed or exempted
SARA 302/304:
Not applicable
SARA 311/312
Classification:
Fire Hazard
Immediate acute health hazard
Delayed chronic health hazard
INFORMATION ON INGREDIENTS
NAME
FIRE HAZARD
SUDDEN
RELEASE OF
PRESSURE
REACTIVE
NO
IMMEDIEATE
ACUTE
HEALTH
HAZARD
YES
DELAYED
CHRONIC
HEALTH
HAZARD
NO
POLYESTER
RESIN
Triglycidyl
isocyanourate
YES
NO
Yes
No
No
Yes
Yes
Titanium
dioxide
no
no
no
no
yes
SECTION 16: OTHER INFORMATION
Hazardous Materials Identification System (HMIS) and National Fire Protection
Association (NFPA) Ratings:
HMIS Rating
NFPA Rating
--------------------------------------------HEALTH
2*
HEALTH
2
FLAMMABILITY
1(a)
FLAMMABILITY
1(a)
REACTIVITY
0
INSTABILITY
0
Rating System:0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic
Effects.
(a) The flammability rating printed above applies to this product during normal
transportation and storage. However, theoretically, this product can form
explosive mixtures at high concentrations of airborne dust. Per NFPA 704 (1996
edition) criteria, such products would be assigned a "flammability" hazard
rating of "3" if they are "readily dispersed in air".
Safe handling of this product requires that all of the information on the SDS
be evaluated for specific work environments and conditions of use.
THIS IS THE END OF THE SDS FOR: ACT S0-659
Manufactured and Supplied by:
Alpha Coating Technologies, LLC.
1735 W.CORTLAND COURT ADDISON IL 60101