The Islamic University of Gaza Chemistry Department Chemical Engineering (CHEM 1301) Time: 1 hour الرقم :الشعبة 30 ........................................ ................. :الجامعي ......................................................................... :االسم ..................................................................... ............................................................ .:المدرس Q1- Choose the correct answer: 1- Which is the formula for copper(I) phosphate? a) Cu3PO4 b) Cu2(PO4)3 c) Cu(PO4)2 2- Which one of the following is named correctly? a) Ca(HS)2, calcium sulfide c) AlN, aluminum nitride b) HBrO2, bromic acid d) FeO, iron(III) oxide 3- Which statement is false for the balanced equation given below? (Atomic weights: N = 14.0, H = 1.00, O = 16.00). 4NH3 + 5 O2 4 NO + 6 H2O a) The reaction of 4 molecules of NH3 requires 5 molecules O2. b) The reaction of one mole of NH3 requires 40 g of O2. c) The reaction of 4 moles of NH3 produces 30 g of NO. d) The reaction of 10 molecules of NH3 produces 15 molecules of H2O. 4- Which of the following compounds contains the largest mass of carbon atoms? (At. Wt.: C = 12.01, O = 16.00, H = 1.008). a) 0.10 mole C6H12O6 c) 0.07 mole C8H18 b) 0.25 mole C2H6 d) 0.50 mole CH4 5- Which combination will produce a precipitate? a) NH4OH (aq) and HCl (aq) b) AgNO3 (aq) and Ca(C2H3O2)2 (aq) c) NaCl (aq) and HC2H3O2 (aq) d) NaOH (aq) and Fe(NO3)2 (aq) 6- Write the net ionic reaction for the neutralization of HF(aq) by NaOH(aq). a) H+(aq) + OH−(aq) H2O(l) b) HF(aq) + NaOH(aq) NaF(aq) + H2O(l) c) HF(aq) + NaOH(aq) Na+(aq) + F−(aq) + H2O(l) d) HF(aq) + OH−(aq) F−(aq) + H2O(l) 7- Which of the following reactions is an oxidation reduction reaction? a) 2Fe(s) + 6HCl(aq) → 2FeCl3(aq) +3 H2 (g) c) Pb2+(aq) + 2Cl- (aq) → PbCl2(s) b) Pb2+(aq) + S2-(aq) → PbS(s) d) HCl(aq) + NH3(aq) →NH4Cl(aq) 1 d) Cu(PO3)2 اسم 8- For which one of the following reactions does the enthalpy change represent a standard enthalpy of formation? a) N2 (g) + 3H2 (g) → 2NH3 (g) b) 1/2N2 (g) + O2 (g) → NO2 (g) c) 6C (s) + 6H (g) → C6H6 (l) d) 12C (g) + 11H2 (g) + 11O (g) → C12H22O11 (g) 9- The reaction of cyanamide NH2CN(s), with oxygen was run in a bomb calorimeter, and ∆E was found to be −742.7 kJ/mol of NH2CN(s) at 298 K. Calculate ∆Hºrxn (in kJ) at 298 K for the reaction: NH2CN(s) + 3/2 O2 (g) → N2 (g) + CO2 (g) + H2O (l) a) −741.5 c) −743.9 b) 741.5 10- Consider the following reaction: 2 CH3OH(g) (Given that: R = 8.314 J/mol.K) 2 CH4(g) + O2(g) d) 743.9 ΔH = + 252.8 kJ How many kilojoules of heat are released when 48 g of CH4(g) (M.Wt = 16) reacts completely with O2(g) to form CH3OH(g) at constant pressure? a) −379.2 kJ b) 379.2 kJ c) 168.5 kJ d) − 168.5 kJ Q2- Answer the following questions: 1- The combustion of a 0.1000 g sample of a compound containing carbon, hydrogen and oxygen produced 0.1910 g CO2 (M. Wt. = 44) and 0.1172 g H2O (M. Wt. = 18). What is the empirical formula for the compound? C2H6O 2 2- Calculate the concentration of each ion present in the solution formed by mixing 3.60 g KCl (F.Wt. = 74.55) in 75.0 mL of 0.250 M CaCl2 solution. 1.144 M Cl-, 0.644 M k+, 0.250 M Ca2+ 3- What is the mass of the precipitate formed when 12.0 mL of 0.150 M NaCl is added to 25.00 mL of a 0.0500 M AgNO3 solution? (At. Wt.: Cl = 35.45, O = 16, N = 14, Ag = 107.87, Na = 23) 0.179 g 4- Ethylene (C2H4) (M. Wt. = 28) can be prepared by heating hexan (C6H14) (M. Wt. = 86) according to the following reaction? C6H14 C2H4 + other products If the yield of ethylene is 42.5%, what is the mass of hexane must react to produce 481 g of ethylene? 3.48 103 g 3 5- Given the experimental information below: 2 Sr(s) + O2(g) 2 SrO(s) SrCO3(s) CO2(g) + SrO(s) 2 O2(g) + 2 C(graphite) 2 CO2(g) ΔH = ─ 1180 kJ ΔH = + 234 kJ ΔH = ─ 788 kJ Determine ΔH for the reaction: Sr(s) + 3/2O2(g) + C(graphite) SrCO3(s) − 1218 kJ/mol 6- Consider the following reaction: 2 CH3OH(l) + 3O2(g) 2 CO2(g) + 4H2O(l) ΔH = ─ 1453 kJ a) Calculate the heat produced by combustion per liter of methanol (M. Wt = 32). Methanol has a density of 0.791 g/ml. d) Calculate the mass of CO2 produced per kJ of heat emitted. a) ─ 1.7958 X 104 kJ/ L b) 0.0606 g CO2 / kJ Good Luck 4
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