entropy Article Thermoeconomic Optimization of an Irreversible Novikov Plant Model under Different Regimes of Performance Juan Carlos Pacheco-Paez 1, *, Fernando Angulo-Brown 1 and Marco Antonio Barranco-Jiménez 2 1 2 * Escuela Superior de Física y Matemáticas del Instituto Politécnico Nacional, Ciudad de México 07738, Mexico; [email protected] Escuela Superior de Cómputo del Instituto Politécnico Nacional, Ciudad de México 07738, Mexico; [email protected] Correspondence: [email protected]; Tel.: +52-55-5527-6000 (ext. 52069) Academic Editor: Milivoje M. Kostic Received: 1 February 2017; Accepted: 10 March 2017; Published: 15 March 2017 Abstract: The so-called Novikov power plant model has been widely used to represent some actual power plants, such as nuclear electric power generators. In the present work, a thermo-economic study of a Novikov power plant model is presented under three different regimes of performance: maximum power (MP), maximum ecological function (ME) and maximum efficient power (EP). In this study, different heat transfer laws are used: The Newton’s law of cooling, the Stefan–Boltzmann radiation law, the Dulong–Petit’s law and another phenomenological heat transfer law. For the thermoeconomic optimization of power plant models, a benefit function defined as the quotient of an objective function and the total economical costs is commonly employed. Usually, the total costs take into account two contributions: a cost related to the investment and another stemming from the fuel consumption. In this work, a new cost associated to the maintenance of the power plant is also considered. With these new total costs, it is shown that under the maximum ecological function regime the plant improves its economic and energetic performance in comparison with the other two regimes. The methodology used in this paper is within the context of finite-time thermodynamics. Keywords: thermo-economics optimization; irreversible heat engine; Novikov model 1. Introduction During more than four decades, a branch of irreversible thermodynamics called finite-time thermodynamics (FTT) has been developed [1–5]. Within the context of FTT, it has been possible to elaborate detailed models of heat engines working at finite-time and with entropy production [6–10]. One of the applications of FTT has been in the field of thermoeconomics [11–14]. In 1995, Alexis De Vos introduced for the first time a thermoeconomic study for the Novikov plant model [15]. In his study, De Vos takes into account two costs: a cost related to the investment and another cost associated to the fuel consumption. From his thermoeconomic study, De Vos found that the optimal thermoeconomic efficiency under maximum power conditions is between the Curzon–Ahlborn (CA) efficiency and Carnot efficiency [16]. Here, De Vos refers to the power production rate W of the Novikov plant model. Later, Barranco-Jiménez and Angulo-Brown [17,18] extended the De Vos thermoeconomic approach, but using the so-called ecological function [19,20], and they also showed that the economical efficiency under this regime of performance lies between the CA efficiency and the Carnot efficiency. In 2009, Barranco-Jiménez [21] studied the thermoeconomics of a nonendoreversible Novikov engine. He used different heat transfer laws: The Newton’s law of cooling, the Stefan–Boltzmann radiation law [22], the Dulong–Petit’s law of cooling [23] and a phenomenological heat transfer law [24,25] (the usage Entropy 2017, 19, 118; doi:10.3390/e19030118 www.mdpi.com/journal/entropy Entropy 2017, 19, 118 2 of 15 engine model to describe [22–27]). He calculated the thermoeconomic optimal efficiencies under two regimes of performance, Entropy 2017, 19, 118 namely, the maximum power regime and the ecological regime, and 2 of 15he found that when the Novikov model maximizes the ecological function, it reduces the rejected heat to the environment down to about 50% with respect to the heat rejected under maximum power conditions. of each transfer law depends on the kind of heat engine model to describe [22–27]). He calculated Recently,the Pacheco-Paez et al. [28,29] made under a thermoeconomic analysis ofnamely, a Novikov plant following thermoeconomic optimal efficiencies two regimes of performance, the maximum power regime and the ecological and he found that when the Novikov model maximizes the to the the De Vos approach (with a linearregime, heat transfer law) but including a new cost associated ecological function, it reduces the rejected heat to the environment down to about 50% with respect maintenance of the power plant. The aim of this paper is to extend the thermoeconomic analysis of the to the heat rejected under maximum power conditions. Recently, Pacheco-Paez et al. [28,29] made a Novikovthermoeconomic plant model analysis (see Figure 1) by considering different heat transfer laws. Besides, in the of a Novikov plant following the De Vos approach (with a linear heat transfer optimization of the benefit functions, we take into account aofnew cost associated to the maintenance of law) but including a new cost associated to the maintenance the power plant. The aim of this paper the power In our study, we of also considerplant three regimes of performance: maximum is toplant extend[28,29]. the thermoeconomic analysis the Novikov model (see Figure 1) by considering different heat transfer laws. Besides, in the optimization of the benefit functions, we take into account power (MP) [3], maximum efficient power (EP) [30,31] and maximum ecological function (ME) [19,20]. a new cost associated to the maintenance of the power plant [28,29]. In our study, we also consider The methodology used in this paper is within the context of finite-time thermodynamics. Apart from three regimes of performance: maximum power (MP) [3], maximum efficient power (EP) [30,31] and the De Vos method, there exist other approaches for the thermoeconomic analysis of power plant maximum ecological function (ME) [19,20]. The methodology used in this paper is within the context models. Interestingly, the thermoeconomic analysis based on exergy hasother played an important of finite-time thermodynamics. Apart from the De Vos method, there exist approaches for the role in this discipline [32–36]. The work organized as follows: In Section 2, we present analysis the thermoeconomic thermoeconomic analysis of is power plant models. Interestingly, the thermoeconomic based on exergy has played an important role in this discipline [32–36]. The work is organized as follows: analysis of the Novikov power plant under different criteria of performance. In Section 3, we analyze In Section 2, we present the thermoeconomic analysis of the Novikov power plant under different the environmental impact of the thermoeconomic model, and finally in Section 4, we present our criteria of performance. In Section 3, we analyze the environmental impact of the thermoeconomic conclusions. model, and finally in Section 4, we present our conclusions. Figure 1. Novikov’s model for a thermal power plant.QQ H,, Q W are per unit per time.unit time. Figure 1. Novikov’s model for a thermal power plant. and Wquantities are quantities QLLand H 2. Thermoeconomic Analysis 2. Thermoeconomic Analysis Applying the first law of thermodynamics to Figure 1, the power output is given by, Applying the first law of thermodynamics to Figure 1, the power output is given by, W = Q −Q , (1) W = QH − HQL , L (1) QH Q and Q theheat heat transfers between the thermal baths and the working fluidworking (W, Q H and where Qwhere and are the transfers between the thermal baths and the fluid ( W , L are H L Q L are quantities per cycle’s period). On the other hand, the internal efficiency of the engine is given are quantities per cycle’s period). On the other hand, the internal efficiency of the QH andbyQ[21], L engine is given by [21], η= W τ1 = 1− , QH Rθ (2) W τ 1 η =the parameter = 1 − R , = ∆S1 /|∆S2 | is the non-endoreversibility where τ = TL /TH , θ = T3 /TH and QH Rθ where (2) parameter [37,38] (which characterizes the degree of internal irreversibility that comes from the , θ = T3∆ST1Hbeing and parameter R =entropy ΔS1 Δalong S2 the is hot theisothermal non-endoreversibility the the change of the internal branch τClausius = TL THinequality), parameter [37,38] (which characterizes the degree of internal irreversibility that comes from the Clausius inequality), ΔS1 being the change of the internal entropy along the hot isothermal branch and ΔS2 the entropy change corresponding to the cold isothermal compression. This parameter in principle is within the interval 0 < R ≤ 1 ( R = 1 for the endoreversible limit). If we consider that the Entropy 2017, 19, 118 3 of 15 and ∆S2 the entropy change corresponding to the cold isothermal compression. This parameter in principle is within the interval 0 < R ≤ 1 (R = 1 for the endoreversible limit). If we consider that the heat transferred between the hot source and the working fluid obeys a generalized law of the type, Q H = gTH n (1 − θ )n , (3) where the exponent n can be any real number different from zero and it takes the values n = 1 for a Newtonian heat transfer law (N) and n = 5/4 for a Dulong–Petit heat transfer law (DP) [23,27] and g is the thermal conductance (see Figure 1). From Equations (2) and (3), the power output (W = ηQ H ) results in n τ n (4) W = gTH η 1− R (1 − η ) The De Vos thermoeconomical analysis considers a profit function F, which is maximized [11]. This profit function is given by the quotient of the power output W (that is, the power production rate W of the Novikov plant model) and the total costs involved in the performance of the power plant, that is W F= (5) C Apart from this De Vos method, there exist other approaches for the thermoeconomic analysis of power plant models. Significantly, the thermoeconomic analysis based on exergy has played an important role in this matter [32–36]. In his study, De Vos assumed that the running costs of the plant consist of two parts: a capital cost which is proportional to the investment and, therefore, to the size of the plant, and a fuel cost that is proportional to the fuel consumption and, therefore, to the heat input rate. In this work, we also take into account a cost associated to the maintenance of the power plant which is taken as proportional to the power output of the plant. This choice is based on an intuitive idea that has to do with the wheatering of the engine depending on its excessive usage. Therefore, the running costs of the plant exploitation are now defined as, C = aQmax + bQ H + cW, (6) where the proportionality constants a, b and c have units of $/Watt, and Qmax = gTH n (1 − τ )n is the maximum heat that can be extracted from the heat reservoir without supplying work in the same manner previously considered by De Vos [11] (see Figure 1). Equation (6) is taken as a linear relation inspired in the linear character of the first law of thermodynamics [39]. Using Equations (3) and (4), the running costs of the plant are given by, C = agTH n (1 − τ )n + β 1 − τ R (1 − η ) n + γη 1 − τ R (1 − η ) n , (7) where β = b/a and γ = c/a (0 ≤ β < ∞ and 0 ≤ γ). After substituting Equations (4) and (7) into Equation (5), the dimensionless objective profit function is given by, N − DP aFMP = η 1− (1 − τ ) n + β 1 − τ R (1− η ) n τ R (1− η ) n + γη 1 − τ R (1− η ) n , (8) which is valid for the transfer laws of Newton (N), and Dulong–Petit (DP). Now, we define two additional objective functions, one in terms of the so-called modified ecological function (E ≡ W − ∈ TL σ, with σ the rate of total entropy production of the Novikov model and ∈ a parameter which depends on the heat transfer law used in the Novikov model [19,20]). This function is a slight modification of the former ecological function [19], which preserves the original physical meaning of that function; that is, it represents a good trade-off between high power output and low dissipation. C C respectively. Analogously to Equation (8), by using Equations (4), (5) and (7), FEP and FME are given by, τ η 1 − R(1 − η ) Entropy 2017, 19, 118 n 4 of 15 2 N − DP = aFEP , (9) n n τ τ On the other hand, we also use a profit function based on the efficient power [30,31] P ≡ ηW , ( ) EP (1 − τ ) + β 1 − R(1 − η ) + γη 1 − R(1 − η ) which is an objective function of the class of compromise for a good trade-off functions looking and,between power output and efficiency. Both objective functions are divided by the total costs involved ηW T σ n L , respectively. Analogously to in the performance of the plant, that is, FEP = C and FME = W −∈ C τ ( 1 (5) η − ε(7), + ε )and (1 −FτEP) and Equation (8), by using Equations (4), are given by, 1 − FRME (1 − η ) N − DP . aFME = (10) n n n τ 2 n τη 1 − τ (1− N − DP( 1 − τ ) + β 1 − + Rγη 1η )− R(1 (9) aFEP = − η ) n , n R(1 − η ) τ n (1 − τ ) + β 1 − R(1−η ) + γη 1 − R(1τ−η ) The maximization of the objective functions given by Equations (8)–(10) by means of n d ( aFand, ) dη n τ = 0 gives the corresponding[(optimal taking the derivatives of 1 + ε)η − efficiencies. ε(1 − τ )] 1 − Therefore, R (1− η ) N − DP aFME = η∗ (1 − τ ) n + β 1 − τ R (1− η ) n + γη 1 − τ R (1− η ) n . (10) N − DP N − DP N − DP aFMP , aFPE and aFME with respect to η and setting them equal to zero, we obtain the ( ) d( aF ) The maximization of the objective functions given by Equations (8)–(10) by means of dη ∗ = 0 optimal efficiency η ∗ that maximizes Equations (8)–(10), respectively. In Figure 2, for the η case of a gives the corresponding optimal efficiencies. Therefore, taking the derivatives of aF N − DP , aF N − DP MP threePE Newton heat transfer law ( n = 1 in Equation (3)), we show the behavior of the objective N − DP and aFME with respect to η and setting them equal to zero, we obtain the optimal efficiency (η ∗ ) functions versus the internal efficiency η for the following arbitrary values R = 1 (endoreversible that maximizes Equations (8)–(10), respectively. In Figure 2, for the case of a Newton heat transfer ( ) in Equation show the the three functions versus the internal η ∗ which 0 1and τ = 0.5 .(3)), Wewe observe in behavior Figure 2ofthat thereobjective exists an efficiency value case),lawβ (n= = efficiency η for the following arbitrary values R = 1 (endoreversible case), β = 0 and τ = 0.5. depends on the parameter γ . The benefits function diminishes as the parameter γ increases. We observe in Figure 2 that there exists an efficiency value (η ∗ ) which depends on the parameter aF Nofismaximum γ. The function diminishes as the conditions, parameter γ the increases. Besides, for the obtained for Besides, forbenefits the case of maximum power maximum value of case N is obtained for practically the same value of η for the power conditions, the maximum value of aF practically the same value of η for the two values of γ considered. two values of γ considered. Figure 2. Comparison between the three thermoeconomic objective functions with respect to the internal efficiency for a Newton heat transfer law for two values of the parameter γ (F represents the internal for a Newton heat transfer law for threeefficiency objective functions with a Newtonian heat transfer law).two values of the parameter γ ( Figure 2. Comparison between the three thermoeconomic objective functions with respect to the N FN represents the three objective functions with a Newtonian heat transfer law). In Figure 3, we can observe for the three benefit functions how the optimal efficiency tends to the In Figurevalue 3, we(Carnot can observe for the three benefit functions howinthe efficiency tends to the reversible efficiency) when β→ ∞ , such as it occurs theoptimal De Vos approach [11,21]. reversible value (Carnot efficiency) when β → ∞ , such as it occurs in the De Vos approach [11,21]. Entropy 2017, 19, 118 Entropy 2017, 19, 118 5 of 15 5 of 15 Figure 3. 3. Comparison thermoeconomic objective to the the Figure Comparison between between the the three three thermoeconomic objective functions functions with with respect respect to internal efficiency, efficiency,taking taking into account the maintenance costs of theforplant for two values of the internal into account the maintenance costs of the plant two values of the parameter β . ( Fthe three represents the three objective withheat a Newtonian heat transfer law). parameter β. (F N represents objective functions with functions a Newtonian transfer law). N The optimal optimalefficiencies efficiencies obtained in terms the dimensionless parameter , but this The areare obtained in terms of theof dimensionless parameter β, but thisβ parameter is not easy is to not evaluate [11] and it is more to work in to terms ofinthe so-called fractional parameter easy to evaluate [11] andconvenient it is more convenient work terms of thefuel so-called fuel f ) [11,17], cost ( f ) [11,17], as the ratio between thebetween fuel costthe andfuel the cost totaland costs oftotal the plant, is,plant, fractional cost (defined defined as the ratio the costs that of the that is, bQ H f = , (11) bQH aQ + bQ H +, cW f= max (11) aQmax + bQH + cW which is in the interval 0 ≤ f < 1. From the previous equation and by using Equations (2)–(4), we get which is in the interval 0 ≤ f < 1 . From the previous equation and by using Equations (2)–(4), we get n (1 − τ )n + γη 1 − τ n f R (1− η ) β= (12) . ( 1− τ )n + γη 1 − τ n 1 − f τ f R (1 ) η − 1 − R (1− η ) β = (12) . n 1− f τ efficiencies by solving polynomial From Equations (8)–(10), we can numerically 1 − Rfind (1 − ηthe ) optimal equations of the form: H (τ, f , γ, R, η ) = 0. However, some analytical expressions can be obtained we can numerically the optimal bypreviously solving polynomial for γFrom = 0 inEquations the cases (8)–(10), of both Newton (n = 1) andfind Dulong–Petit (nefficiencies = 5/4) laws reported in [21]. Forofthe of maximum power the optimal efficiencies are given can by [20] equations thecase form: H (τ , f , γ , R ,η ) = 0output, . However, some analytical expressions be obtained for p γ = 0 in the cases of both Newton ( n = 1 ) and Dulong–Petit ( n = 5 4 ) laws previously reported in [21]. 4(1 − f ) Rτ + f 2 τ 2 f N η τ, f , R = 1 − τ − . (13a) ( ) MP For the case of maximum power output, the optimal efficiencies 2R 2Rare given by [20] 4(1 −10f()R f τ−+1)f τ2τ 2 f N DP (13a) q η MP f, R = 1 − . (13b) (τ,ηMP ) τ , f , R = 1 − τ − . ( ) (5 f 2−R1)τ + 80(21R− f ) Rτ + (1 − 5 f )2 τ 2 10 ( f − 1)τ DP ηMP f , R ) = 1 − under the maximum power conditions, . the optimum value(13b) (τ ,mentioned, As it was previously of η 2 2 5 f − 1 τ + 80(1 − f ) R τ + 1 − 5 f τ ( ) ( ) does not appreciably change the maximum of the benefit function, that is, the optimal efficiency is practically independent of the parameter γ, which is associated to the maintenance costs of the plant As it was previously mentioned, under the maximum power conditions, the optimum value of (see Figure 2). Interestingly, the inclusion of this new parameter has a remarkable effect on the optimal η does not appreciably change the maximum of the benefit function, the optimal efficiency ∗ andthat ∗ is, efficiencies for the cases of ME and EP maximizations. In fact, η ME ηEP increase with respect to γ , which is is, associated to the maintenance costs of the is practically independent of thecosts parameter the results without maintenance (see Figure 2); that better maintenance is reflected as better plant (see Figure Interestingly, theefficient inclusion of this new parameter has a remarkable effectγon=the efficiency. For the2). case of maximum power and maximum ecological function (with 0), * * the optimal efficiencies optimal efficiencies for are the given cases by, of ME and EP maximizations. In fact, ηME and ηEP increase with respect to the results without maintenance costs (seeq Figure 2); that is, better maintenance is reflected 8(1 power − f ) Rτand + (1maximum + f )2 τ 2 ecological function as better efficiency. For the case of maximum efficient 1 + f ( ) N ηEP τ− , (14a) (τ, f , R) = 1 − (with γ = 0 ), the optimal efficiencies are given 4R by, 4R Entropy 2017, 19, 118 6 of 15 10( f − 1)τ DP ηEP (τ, f , R) = 1 − q 160(1 − f ) Rτ + (3 + 5 f )2 τ 2 q 4(1 − f ) Rτ 3/2 + f 2 τ 2 f N η ME τ− , (τ, f , R) = 1 − 2R 2R (3 + 5 f ) τ + DP η ME (τ, f , R) = 1 − where Λ = τ + p , 100(1 − f )τ (1 − 5 f ) Λ + q 800Λ(1 − f ) R + [(1 − 5 f )Λ]2 (14b) (15a) . (15b) τ (80 + τ ). For the cases f = 0 and R = 1, from Equations (13a), (14a) [8τ (1+τ )]1/2 and (15a), we obtain the optimal efficiencies ηCA = 1 − τ 1/2 , ηEP = 1 − τ4 − and 4 η ME = 1 − τ 3/4 previously reported by Curzon-Ahlborn [16], Yilmaz [30] and Arias-Hernández and Angulo-Brown [20], for the Curzon-Ahlborn heat engine under maximum power output, maximum efficient power and maximum ecological function conditions, respectively. Now, we consider two other heat transfer laws between the hot source and the working fluid as follows, Q H = gTH n (1 − θ n )Sign(n), (16) Qmax = gTH n (1 − τ n )Sign(n), (17) Here, the exponent n takes the values of n = −1 for a phenomenological heat transfer law (Ph) [24,25] and n = 4 for a Stefan–Boltzmann (SB) radiation law ([22,26]) and the Sign function leads to Sign(n) = 1 if n > 0, and Sign(n) = −1 if n < 0. In this case, the objective functions under the three regimes considered result in, SB− Ph aFMP h n i η 1 − R(1τ−η ) = h n i h n i , + γη 1 − R(1τ−η ) (1 − τ n ) + β 1 − R(1τ−η ) (18) SB− Ph aFEP h n i η 2 1 − R(1τ−η ) = h n i h n i , + γη 1 − R(1τ−η ) (1 − τ n ) + β 1 − R(1τ−η ) (19) SB− Ph aFME n i h [2η − (1 − τ )] 1 − R(1τ−η ) = h n i h n i . + γη 1 − R(1τ−η ) (1 − τ n ) + β 1 − R(1τ−η ) (20) and, SB− Ph SB− Ph SB− Ph In Figures 4 and 5, we show the behavior of aFMP , aFEP and aFME for the case of a phenomenological (Ph) heat transfer law (n = −1 in Equations (18)–(20)) versus the internal efficiency for R = 1, β = 0 and τ = 0.5 (a similar behavior is found for the benefit functions for the case of the Stefan–Boltzmann law). We can see in Figures 5 and 6 that these profit functions have a similar behavior to the Newton and the Dulong–Petit cases; that is, the benefits function also diminishes as the parameter γ increases. In [11], it was shown that the maxima points of the MP profit function tend to the reversible limit (Carnot point) when the parameter β tends to infinite. This same behavior occurs for the EP and ME profit functions. In Figure 6 we only show, as an example, the case of the EP profit function for several increasing values of the parameter β, and it is clear how the curve that contains the maxima points tend to the Carnot efficiency (ηC = 0.5, in this case). In a similar way to the Newton and the Dulong–Petit cases, we can obtain the optimal efficiencies in terms of the parameter β (or f ). In a similar way to the Newton and the Dulong–Petit cases, we can obtain the optimal efficiencies in terms of the parameter β (or f ). Analogously to Newton and Dulong–Petit laws, we can also obtain some analytical expressions for γ = 0 for both Ph ( n = −1 ) and SB radiation ( n = 4 ) laws. Therefore, under maximum power Entropy 2017, 19, 118 7 of 15 output, maximum efficient power and maximum ecological function conditions, we obtain, respectively, Analogously to Newton and Dulong–Petit laws,Rwe − τcan also obtain some analytical expressions for Ph η radiation , (τ , f , R(n) ==R4)(2laws. (21a) γ = 0 for both Ph (n = −1) and SB MP − f ) Therefore, under maximum power output, maximum efficient power and maximum ecological function conditions, we obtain, respectively, Ph ηEP (τ , f , R ) = τ ( f − 3) , R( f − 1) R− − 2τ τ Ph η MP (τ, f , R) = Ph η ME (τ , f , R ) = R ( f − 3) − ( f − 1)τ + 2τ Ph ηEP (τ, and, R (2 − f ) (21b) , 2R( fτ−( f2)− 3) f , R) = R( f − 1) − 2τ (21a) , , R[( f − f τ− 1)τ ] + 2τ 8(3f)−−1)(R Ph S− B , = 1(−τ, f , R) = η MP , (τ , f , R η) ME 2R( f − 2) (4 f − 3)τ + (4 f − 3)2τ 2 + 16 R(1 − f )τ and, ( ) 2( f − 1)τ − 8(1 −8(f f)τ−R1+) Rτ (1 − 2 f )τ 2 −B S −SB , R)==1 − 1− ηηEP MP τ(,τ,f ,f R , , 2(R 4 f − 3)2 τ 2 + 16R(1 − f )τ p2τ 2 + 8 R( f − 1)(1 + τ )τ (4 f − 3)τ + (4 f − 3) S− B 2 ( f − 1 ) τ − 8(1 − f )τR + (1 − 2 f )τ.2 ηME τ , f , R = 1 − ( ηEP S− B ) , (τ, f , R) = 1 − 2R 2R (4 f − 3) τ + q (21c) (21b) (21c) (22a) (22a)(22b) (22c) (22b) q Similarly as for the Newton heat(4transfer law,(4for f − 3) τ + τ )τ transfer law when f −a3phenomenological )2 τ 2 + 8R( f − 1)(1 +heat S− B η τ, f , R = 1 − . ( ) f = 0 and R = 1 , ME from Equation (21a–c), we obtain 2R the optimal efficiencies ηMP = (22c) (1 − τ ) 2 Similarly as for the Newton heat transfer 3τ law, for a phenomenological heat transfer law when η = and η ME =efficiencies 3 (1 − τ ) 4η (these last two expressions previously reported by De Vos [24], EP f = 0 and R = 1, from Equation (21a–c), we obtain MP = (1 − τ ) /2 previously 1 + 2τ the optimal 3τ by Depublished Vos [24], ηEPby=Barranco-Jiménez − τ )/4 (these two expressions were 1+2τ and η ME = 3(1[21]), werereported previously for the last Curzon-Ahlborn heat previously engine under published by Barranco-Jiménez [21]), for the Curzon-Ahlborn heat engine under maximum power maximum power output, maximum efficient power and maximum ecological function conditions, output, maximum efficient power and maximum ecological function conditions, respectively. respectively. Figure 4. Comparison between thethree threethermoeconomic thermoeconomic objective with respect to the Figure 4. Comparison between the objectivefunctions functions with respect to the internal efficiency for two values of the parameter γ. F Ph represents the three objective functions with internal efficiency for two values of the parameter γ . F Ph represents the three objective functions a phenomenological heat transfer law. with a phenomenological heat transfer law. Entropy 2017, 19, 118 8 of 15 Entropy 2017, 19, 118 8 of 15 Entropy 2017, 19, 118 8 of 15 Figure 5. Comparison between thermoeconomic objectivefunctions functions with respect to the Figure 5. Comparison betweenthe thethree three thermoeconomic thermoeconomic objective with respect to the Figure 5. Comparison between the three objective functions with respect to the internal efficiency, taking into account the maintenance costs of the plant for two values of the internal efficiency, taking into account the maintenance costs of the plant for two values of the internal efficiency, taking into account the maintenance costs of the plant for two values of the parameter Ph Ph Frepresents represents three objective functions with heatheat transfer law. law. parameter β . βF . the thethe three objective functions witha aphenomenological phenomenological β. F Phparameter represents three objective functions with a phenomenological heat transfer law.transfer Figure 6. Thermoeconomic objective function under efficient power (EP) conditions with respect to the internal efficiency, taking into account the maintenance costs of the plant for several values of the Figure 6. Thermoeconomic Thermoeconomic objective under efficient (EP) conditions respect β . We observe how thefunction maxima points to thepower reversible that is, with the Carnot parameter Figure 6. objective function undertend efficient power (EP)value; conditions with respect to to the efficiency, taking costs of of thethe plant forfor several values of the the internal internal efficiency, takinginto intoaccount accountthe themaintenance maintenance costs plant several values of efficiency ( ηC ). β . We observe how the maxima points tend to the reversible value; that is, the Carnot parameter the parameter β. We observe how the maxima points tend to the reversible value; that is, the Carnot ). efficiency ( ηCC).Results: (η 3. Numerical Environmental Impact d ( aFi ) , for i = MP , EP , ME , * d( aFii) aFi ∗ , for i = MP, EP, ME, When we calculate the derivative of Equations (8)–(10), that is, d dη ( ) ∗ ηto When we equations calculate of the that is,we have for inumerically = MP , EP , ME , i ,solve we obtain thederivative form = ( , , , (8)–(10), , ). Therefore, of Equations Environmental WhenResults: we calculate the derivative of Equations (8)–(10), that is, 3. Numerical Environmental Impact dη η ( ) dη * η = H τ, β, γ, R, ηi∗ . Therefore, we have to solve numerically i polynomial equationsofofthe theform form, ( ) = ( , , , , ∗ ). Therefore, we have to solve numerically we obtain equations HiN − DP = HiN − DP (τ , β , γ , R ,ηiN − DP ) = 0 , (23) N − DP N − DP N − DP polynomial equations of the form, Hi =H τ, β, γ, R, ηi = 0, (23) These previous expressions are not ishown in explicit form because they are very large. Finally, we obtain equations of the form d( aFi ) dη polynomial equations of the form, ni ( ) N − DP using the expression for H theN − DP fractional = HiN − DPfuel τ , βcost , γ , Rf,ηi[11,17] = (see 0 , Equation (12)), we obtain the (23) i are not These previous expressions shown in explicit form because they are very large. Finally, numerical optimal efficiencies in terms of the parameter R , the parameter τ and the economic usingparameters the expression for fractional fuelshow cost the f [11,17] (see Equationefficiencies (12)), we obtain the numerical f andexpressions γ .the In Figure we shown optimal form numerical under These previous are7, not in explicit because they are very maximum large. Finally, optimal efficiencies in terms of the parameter R, the parameter τ and the economic parameters f and γ. maximum efficient and maximum ecological function In this the f [11,17] usingpower, the expression for thepower fractional fuel cost (seeconditions, Equationrespectively. (12)), we obtain In Figure 7, (see we show the optimal numerical efficiencies under given maximum power, (13a), maximum efficient Figure solid lines), we also show the optimal efficiencies by Equations (14a) and numerical optimal efficiencies in terms of the parameter R , the parameter τ and the economic power and maximum ecological function conditions, respectively. In this Figure (see solid lines), (15a). parameters f and γ . In Figure 7, we show the optimal numerical efficiencies under maximum we also show the optimal efficiencies given by Equations (13a), (14a) and (15a). power, maximum ecological function conditions, respectively. Inf this Onmaximum the other efficient hand, inpower Figureand 8 we depict the corresponding optimal efficiencies against for Figure (see solid lines), we also show the optimal efficiencies given by Equations (13a), (14a) and the Newtonian case, but with R = 0.9 < 1 (this case is a representative one of any nonendoreversible (15a). Entropy 2017, 19, 118 9 of 15 On the other hand, in Figure 8 we depict the corresponding optimal efficiencies against f for the 9 of 159 of 15 Newtonian case, but with R = 0.9 < 1 (this case is a representative one of any nonendoreversible situation).On Asthe weother can hand, see ininthis case,8 we thedepictoptimal values are optimal all smaller than those corresponding Figure the corresponding efficiencies against f for the N Newtonian case, but with R = 0.9 < 1 (this case is a representative one of any nonendoreversible to Figure 7. behavior for R < 1 the is present for any heat lawthan and those any operating regime situation). AsThis we can see in this case, η optimal values aretransfer all smaller corresponding to situation). As we canfor seeRin<this the for optimal values are all smaller thanoperating those corresponding [21,40]. Figure 7. This behavior 1 iscase, present any heat transfer law and any regime [21,40]. Entropy 19, 118 Entropy 2017, 2017, 19, 118 to Figure 7. This behavior for R < 1 is present for any heat transfer law and any operating regime [21,40]. N represents N Optimal efficiencies versus fractional fuel ηcost. cost. represents the optimal Figure 7.7.Optimal efficiencies versus fractional fuel cost. the three efficiencies Figure 7. Optimal efficiencies versus fractional fuel ηη represents theoptimal threethree optimal with a Newtonian heat transfer law (For R = 1). efficiencies withwith a Newtonian heat R ==1). 1). efficiencies a Newtonian heattransfer transferlaw law (For (For R N N represents Figure 8. Optimal efficiencies versus fractional fuel ηcost. η represents theoptimal three optimal Figure 8. Optimal efficiencies versus fractional fuel cost. the three efficiencies efficiencies with a Newtonian heat transfer law (For R = 0.9). N with a Newtonian heat transfer law (For R = 0.9). Figure 8. Optimal efficiencies versus fractional fuel cost. η represents the three optimal N efficiencies Newtonian heat transfer law (For R =the 0.9).maximum ecological function regime (for We canwith alsoasee that the optimal efficiencies under We can also see that the optimal the maximum function all values of the parameters , and efficiencies for the caseunder of Newton heat transferecological law, see Figures 7 and regime 8) (for all values of the parameters R, γ and f for the case of Newton heat transfer law, see Figures 7 and 8) We can also seethe that the optimal efficiencies under the maximum ecological functionefficient regime (for are greater than optimal efficiencies under both maximum power output and maximum are greater the optimal efficiencies output andsee maximum efficient powerofthan conditions, respectively. For theunder casethe ofboth bothmaximum phenomenological and Stefan–Boltzmann laws, all values the parameters , and for case of Newtonpower heat transfer law, Figures 7 and 8) the optimal efficiencies have a similar behavior with respect to the parameters , and . Besides, alllaws, power conditions, respectively. For the case of both phenomenological and Stefan–Boltzmann are greater than the optimal efficiencies under both maximum power output and maximum efficient of these optimal efficiencies satisfy the following inequality: the optimal efficiencies have a similar behavior with respect to the parameters R, γ and f . Besides, power conditions, respectively. For the case of both phenomenological and Stefan–Boltzmann laws, all these optimal efficiencies satisfy the inequality: theof optimal efficiencies have a similar and . Besides, η behavior > η following > η with > η respect > η , to the parameters , (24) all C ME EP MP CA of these optimal efficiencies satisfy the following inequality: The previous inequality was Barranco-Jiménez et al. for the case of both (24) ηCrecently > η MEobtained > ηEP >byη MP > ηCA , endoreversible and nonendoreversible models ηC > ηME > ηEP of > ηheat >thermal ηCA , engines [21,40]. In addition, we can (24) MP see inprevious Figures 2inequality and 3 howwas the optimal the maximum ecological regime The recentlyefficiency obtainedunder by Barranco-Jiménez et al. function for the case of both The previous inequality was recently obtained by Barranco-Jiménez et al. for the case of both leads to a high reduction on the profits in comparison with those at maximum power output. endoreversible and nonendoreversible models of heat thermal engines [21,40]. In addition, we can see endoreversible andreduction nonendoreversible models heatefficiency thermal for engines [21,40]. the In addition, However, this is concomitant with aof better each value parameterwe can in Figures 2 and 3 how the optimal efficiency under the maximum ecological of function regime leads Table 12 in [11] fractional fuel costs for several kinds fuels). Thisecological value of the efficiency see in(see Figures and 3 for how the optimal efficiency under theofmaximum function regime to a high reduction on the profits in comparison with those at maximum power output. However, leads to a high reduction on the profits in comparison with those at maximum power output. this reduction is concomitant with a better efficiency for each value of the parameter f (see Table 1 However, this reduction is concomitant with a better efficiency for each value of the parameter in [11] for fractional fuel costs for several kinds of fuels). This value of the efficiency provides a (see Table 1 in [11] for fractional fuel costs for several kinds of fuels). This value of the efficiency diminution of the energy rejected to the environment by the power plant. Therefore, the ecological criterion becomes an appropriate procedure for the search for insight into an engine’s performance for Entropy 2017, 19, 118 10 of 15 providing a less aggressive interaction with the environment. Therefore, we propose the following simplified analysis: Entropy 2017, 19, 118 10 of 15 From the first law of thermodynamics we get, provides a diminution of the energy rejected to the environment by the power plant. Therefore, the Q L procedure = Q H − W, ecological criterion becomes an appropriate for the search for insight into an engine’s (25) performance for providing a less aggressive interaction with the environment. Therefore, we where Q L isthe thefollowing heat rejected to theanalysis: environment by the power plant. For the cases of heat transfer of propose simplified the Newton and Dulong–Petit types, when the plant works under maximum power conditions From the first law of thermodynamics we power get, by using Equations (3), (4) and (25), we get = − , (25) !n where is the heat rejected bynthe power plant.τFor the cases of heat transfer of ∗ to the environment n . Q L (η MP , τ, R) = gTH (26) (1 − η MP ) 1− ∗ under the Newton and Dulong–Petit types, when the power plant works maximum power R 1− η MP conditions by using Equations (3), (4) and (25), we get In a similar way, the expressions when the power plant works under maximum ecological function ∗ (26) , , = are, 1 respectively, − 1− . and maximum efficient power conditions 1− ∗ In a similar way, the expressions when the power plant works undern maximum ecological τ ∗ n n , Qefficient R) =conditions gTH 1− (27) (1 − ηare, function and maximum power L ( η ME , τ, ME )respectively, ∗ ! R 1 − η ME ∗ , , = 1− 1− 1− ∗ , τ ∗ n n Q L (η∗EP , τ, R) = gTH (1 − ηEP ) 1− ∗ , , = 1− 1− R∗ 1 − .ηEP (27) !n . 1− (28) (28) The solutions were obtained obtainedinina anumerical numerical manner similarly to the The solutionsofofEquations Equations (26)–(28) (26)–(28) were manner similarly to the equations inin Section we consider considerdifferent different values maintenance of the equations Section2.2.InInour ouroptimization, optimization, we values forfor thethe maintenance of the power plant (parameter for each eachthermodynamic thermodynamic regime while and we we can can observe observe for regime thatthat while the the γ power plant (parameterγ)) and parameter increases, thethe heat rejected to the environment slightly diminishes, as itasis itshown in Figure parameter increases, heat rejected to the environment slightly diminishes, is shown in 9. Figure 9. (a) (b) (c) Figure 9. Heat rejected for two values of the parameter under: (a) maximum power conditions; (b) Figure 9. Heat rejected for two values of the parameter γ under: (a) maximum power conditions; maximum ecological function conditions; (c) maximum efficient power conditions (b) maximum ecological function conditions; (c) maximum efficient power conditions. In Figure 9, we show the amount of heat rejected to the environment for each one of the three regimes of performance. As we can see, the heat rejected to the environment under the maximum Entropy 2017, 19, 118 11 of 15 Entropy 2017, 118 Entropy 19,19, 118 In2017, Figure 9, we 11 of 15 of 15 show the amount of heat rejected to the environment for each one of the11three regimes of performance. As weless canaggressive see, the heat rejected to environment the environment under thewith maximum ecologicalfunction functionpresents presents aa less impact to the inincomparison thethe ecological aggressive impact to the environment comparison with ecological function a less10a,b). aggressive impact to the environment comparison other other two regimespresents (see Figure We can also observe in Figure 10inthat when thewith cost the of the other two regimes (see10a,b). FigureWe 10a,b). Weobserve can also observe inthat Figure 10 that when the cost of the two regimes (see Figure can also in Figure 10 when the cost of the maintenance maintenance is taken into account, the rejected heat slightly diminishes in the three regimes of is maintenance is taken into account, the rejected heatinslightly diminishes the three regimes of taken into account, the rejected heat slightly diminishes the three regimes of in performance considered. performance considered. performance considered. (a) (b) (b) maximum power Figure 10. Ratio of(a) heats rejected between: (a) ecological function conditions and Figure 10. Ratio of heats rejected between: (a) ecological function conditions and maximum power conditions for two valuesrejected of the parameter ; (b) efficientfunction power conditions and maximum power Figure 10. Ratio of values heats between: (a) ecological conditions conditions for two of the parameter γ; (b) efficient power conditions and maximum power conditions for two values of the parameter . conditions for two two values valuesof ofthe theparameter parameterγ. ; (b) efficient power conditions and maximum power conditions for two values of the parameter . In Figure 11, we show the ratio between the amounts of heat rejected for a heat transfer law of Figure 11, we show the ratio between the amounts of heat rejected for a heat transfer law of the theIn Dulong–Petit type. In Figure 11, we show the ratio between the amounts of heat rejected for a heat transfer law of Dulong–Petit type. the Dulong–Petit type. Figure 11. Ratio of heat rejected between efficient power and maximum power conditions and ecological function and maximum power conditions for a heat transfer of the Dulong–Petit type and for two theheat parameter Figure 11.values Ratioofof rejected. between efficient power and maximum power conditions and Figure 11. Ratio of heat rejected between efficient power and maximum power conditions and ecological function and maximum power conditions for a heat transfer of the Dulong–Petit type and ecological function and maximum powerlaw conditions for a heat transfer of the Dulong–Petit type Furthermore, by applying the second of thermodynamic (see Figure 1) we get, for values of the . γ. andtwo for two values ofparameter the parameter = − . (29) Furthermore, by applying the second law of thermodynamic (see Figure 1) we get, Furthermore, by applying the (4) second law of thermodynamic (see Figure 1) Using Equations (1), (3) and and after some algebraic manipulations, forwe theget, cases of heat = − . (29) transfer of the Newton and Dulong–Petit types, the entropy production under maximum power QH − W QH conditions can be calculated by the following σ = expression: − . (29) Using Equations (1), (3) and (4) and after Tsome algebraic manipulations, for the cases of heat TH L transfer of the Newton and Dulong–Petit ∗ ∗the entropy production under maximum power (30)heat , , (4) and = 1after −types, −some 1− . ∗ Using Equations (1), (3) and algebraic for the cases of 1− manipulations, conditions can be calculated by the following expression: transfer of the Newton and Dulong–Petit types, the entropy production under maximum power Similarly to Equation (30), the expressions when the power plant works under maximum conditions can be calculated by ∗ the following expression: ∗ (30) , , efficient = 1− − conditions 1 − are, respectively, . ecological function and maximum power 1− ∗ !n τ ∗∗ ∗ ∗ Similarly to Equation theR)=expressions under maximum (31)(30) , , ,τ, 1 −the power ,plant works σMP ((30), η MP = 1(1−− τ−− ηwhen . MP ) 1 −1− ∗ ∗ R 1 − η ecological function and maximum efficient power conditions are, respectively, MP ∗ , , = 1− − ∗ 1− 1− ∗ , (31) Entropy 2017, 19, 118 12 of 15 Similarly to Equation (30), the expressions when the power plant works under maximum ecological function and maximum efficient power conditions are, respectively, τ ∗ ∗ σME (η ME , τ, R) = (1 − τ − η ME ) 1− ∗ R 1 − η ME Entropy 2017, 19, 118 τ ∗ ∗ σEP (ηEP , τ, R) = (1 − τ − ηEP ) 1− ∗ ∗ ∗ R 1 − ηEP , , = 1− − 1− . ∗ !n , (31) 12 of 15 !n . 1− (32) (32) It is thatthat all of were made a numerical form. The behavior is important importanttotomention mention allthe of calculations the calculations were in made in a numerical form. The of the above equations can be observed in Figurein12.Figure As can the 12b, entropy behavior of the above equations can be observed 12.be Asseen can in be Figure seen in12b, Figure the production of the power when it iswhen working under maximum ecologicalecological conditions is less than entropy production of theplant power plant it is working under maximum conditions is when it is working under maximum power conditions. less than when it is working under maximum power conditions. between the the amounts amounts of of entropy entropy production production for for two two regimes: regimes: In Figure 13a, we show the ratio between maximum ecological function and maximum power. In a similar manner, in Figure 13b, we show maximum ecological function and maximum power. In a similar manner, in Figure 13b, we show the the ratio between the amounts of entropy production for maximum efficient power conditions ratio between the amounts of entropy production for maximum efficient power conditions and maximum power conditions. conditions. In In addition, addition, in in Figure Figure14, 14,we weshow showthe theratios ratiosofofentropy entropyproduction productionfor fora heat transfer of the Dulong–Petit type. In all of our numerical calculations we have attempted to use a heat transfer of the Dulong–Petit type. In all of our numerical calculations we have attempted to for the involved parameters onlyonly typical values reported in the literature. use for distinct the distinct involved parameters typical values reported in FTT the FTT literature. (a) (b) (c) Figure 12.Entropy Entropyproduction production under: (a) maximum conditions twoofvalues of the Figure 12. under: (a) maximum powerpower conditions for two for values the parameter parameter ; (b) maximum ecological function conditions for two values of the parameter ; (c) γ; (b) maximum ecological function conditions for two values of the parameter γ; (c) maximum efficient maximum efficientfor power conditions two values power conditions two values of thefor parameter γ. of the parameter . (a) (b) Figure 13. Ratio of entropy production between: (a) ecological function conditions and maximum (c) Figure 12. Entropy production under: (a) maximum power conditions for two values of the ; (c) 13 of 15 maximum efficient power conditions for two values of the parameter . parameter Entropy 2017, 19, 118; (b) maximum ecological function conditions for two values of the parameter (a) (b) Figure 13. Ratio of entropy production between: (a) ecological function conditions and maximum Figure 13. Ratio of entropy production between: (a) ecological function conditions and maximum power conditions for two values of the parameter ; (b) ecological function conditions and power conditions for two values of the parameter γ; (b) ecological function conditions and maximum maximum power conditions for two values of the parameter . Entropy 2017, 19, 118 13 of 15 power conditions for two values of the parameter γ. Figure 14. 14. Ratio Ratio of of entropy entropy production production between between efficient efficient power power and and maximum maximum power power and and ecological ecological Figure function and maximum power conditions, respectively, for a heat transfer of the Dulong–Petit function and maximum power conditions, respectively, for a heat transfer of the Dulong–Petit type. type. 4. Conclusions Conclusions 4. In this made a thermoeconomic study of anofirreversible simplified thermal power In this work, work,we wehave have made a thermoeconomic study an irreversible simplified thermal plant model so-called NovikovNovikov engine). engine). This irreversible model modifies the results power plant (the model (the so-called This irreversible model modifies theobtained results by meansby ofmeans an endoreversible one due to the inclusion of the engine’s internal dissipation through obtained of an endoreversible one due to the inclusion of the engine’s internal dissipation the lumped R (see Figures and 8). 7Inand our8). study, westudy, use different transfer the through the parameter lumped parameter R (see7Figures In our we use heat different heatlaws: transfer Newton’s law of cooling, the Stefan–Boltzmann radiation law, the Dulong–Petit’s law and another laws: the Newton’s law of cooling, the Stefan–Boltzmann radiation law, the Dulong–Petit’s law and phenomenological heat transfer We also take into account a costaccount associated to the maintenance of another phenomenological heatlaw. transfer law. We also take into a cost associated to the the power plant which weplant assume as proportional the power output the plant. inclusion maintenance of the power which we assume astoproportional to the of power outputThe of the plant. of this new cost has a noticeable impact on the improvement of the optimal efficiencies of the plant The inclusion of this new cost has a noticeable impact on the improvement of the optimal efficiencies model, nevertheless, the benefit functions diminish. This effect isThis onlyeffect relevant when the plant model of the plant model, nevertheless, the benefit functions diminish. is only relevant when the worksmodel underworks ME and EP regimes; when the plant model maximum regime, plant under ME andhowever, EP regimes; however, when theworks plant at model workspower at maximum the benefits diminish and the optimaland efficiency practically does not change.does We found that when power regime, the benefits diminish the optimal efficiency practically not change. We the Novikov model the ecological function, it remarkably reduces the rejected heatthe to found that when the maximizes Novikov model maximizes the ecological function, it remarkably reduces the environment in comparison to the rejected heat in the case of a power plant model working rejected heat to the environment in comparison to the rejected heat in the case of a power plant under the maximum regime (see Figures 9–11). InFigures addition, we analyzed the we effect of internal model working underpower the maximum power regime (see 9–11). In addition, analyzed the irreversibilities on the reduction of power and on total entropy the model. In effect of internal irreversibilities on theoutput reduction ofthe power output production and on theoftotal entropy summary, we have shown that the maximum ecological regime has more advantages in the way of production of the model. In summary, we have shown that the maximum ecological regime has thermoeconomic the other mentioned operating regimes. more advantages performance in the way ofthan thermoeconomic performance than the other mentioned operating regimes. Acknowledgments: The authors acknowledge CONACYT, EDI-IPN, and COFAA-IPN for supporting this work. Author Contributions: All three authors contributed equally to the present work. All authors have read and approved the final manuscript. Conflicts of Interest: The authors declare no conflict of interest. Entropy 2017, 19, 118 14 of 15 Acknowledgments: The authors acknowledge CONACYT, EDI-IPN, and COFAA-IPN for supporting this work. Author Contributions: All three authors contributed equally to the present work. All authors have read and approved the final manuscript. Conflicts of Interest: The authors declare no conflict of interest. References and Notes 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. Andresen, B.; Salamon, P.; Berry, S. Thermodynamics in finite time. Phys. Today 1984, 37, 62–70. [CrossRef] Bejan, A. Entropy generation, minimization: The new thermodynamic of finite-size devices and finite-time processes. J. Appl. Phys. 1996, 79, 1191–1218. [CrossRef] Hoffmann, K.H.; Burzler, J.M.; Schubert, S. Endoreversible thermodynamics. J. Non-Equilib. Thermodyn. 1997, 22, 311–355. Chen, L.; Sun, F. (Eds.) Advances in Finite Time Thermodynamics, Analysis and Optimization; Nova Science Publichers, Inc.: New York, NY, USA, 2004. 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