MADRAS FLUORINE
PRIVATE LTD
MFPL
Safety Data Sheet POTASSIUM ZIRCONIUM FLUORIDE
SECTION 1 : CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
:
Potassium Zirconium Fluoride
OTHER/GENERIC NAMES:
Potassium Fluorozirconate, Potassium Hexafluorozirconate,
Dipotassium Zirconium Hexafluoride.
PRODUCT CODES
:
878 001
PRODUCT USE
:
Constituent in aluminium master alloys, Special fluxes , Laboratory chemicals,
Manufacture of substances
UN NO
:
3288
Packing Group
:
III
Contact Information
OFFICE :
Madras Fluorine Private Ltd
No.71, 4th Main Road
Gandhi Nagar, Adyar
Chennai 600 020, India
E-mail : [email protected]
FACTORY
Madras Fluorine Private Ltd
Express Highway
Manali
Chennai – 600 068, India
Emergency Telephone No:
+91 44 2442 6830 / 2442 0654
+91 44 3290 0358 / 2901 1768
MON – FRI : 9.30 AM – 6.00 PM
MON – SAT : 9.00 AM – 5.30 PM
SECTION 2 : HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 3), H301
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
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Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word
Hazard statement(s)
H301
H315
H319
H335
Precautionary statement(s)
P261
P301 + P310
P305 + P351 + P338
Supplemental Hazard
Statements
Danger
Toxic if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Avoid breathing dust.
IF SWALLOWED: Immediately call a POISON CENTER/doctor.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
None
Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic
(PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Strong hydrogen fluoridereleaser
SECTION 3 : COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT NAME:
Potassium Fluorozirconate
FORMULA
K2ZrF6
WT.PERCENT
97.0
CAS #
16923-95-8
Trace impurities and additional material names not listed above may also appear in Section 15 towards the end of the
MSDS. These materials may be listed for local “Right-to-Know” compliance and for other reasons.
OSHA Hazard Communication Standard: This product is considered hazardous under the OSHA Hazard
Communication Standard
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SECTION 4 : FIRST AID MEASURES
Inhalation:
• Remove the subject from the contaminated area as soon as possible; transport him/her lying down, with the
head higher than the body, to a quiet, uncontaminated and well-ventilated location.
• Administer oxygen or cardiopulmonary resuscitation if necessary.
• Keep warm (blanket).
• Consult a physician in all cases. / Take to a hospital
Eyes:
• Flush eyes as soon as possible with running water for 15 minutes, while keeping the eyelids wide open.
• Consult an ophthalmologist immediately in all cases.
• Take to a hospital immediately.
• Rinse the eyes with calcium gluconate (1% solution in physiological serum) (10 ml of calcium gluconate
10% in 90 ml of physiological serum).
• In case of difficulty opening the lids, administer an analgesic eyewash (oxybuprocaine).
Skin:
• Remove contaminated shoes, socks and clothing, under the shower if necessary; wash the affected skin with
running water.
• Immediately apply calcium gluconate gel (2.5%) and massage into the affected area using rubber gloves;
continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
• If fingers/fingernails are touched, even if there is no pain, dip them in a bath of 5% calcium gluconate for 15 to
20 minutes.
• Keep warm (blanket); provide clean clothing.
• Consult a physician in all cases.
Ingestion:
General recommendations:
• Consult a physician immediately in all cases
• Take to a hospital immediately
• Do not induce vomiting
If the subject is completely conscious:
• Rinse mouth with fresh water
• Give a 1% aqueous calcium gluconate solution to drink
• Do not induce vomiting
• If the subject presents nervous, respiratory or cardiovascular disorders
administer oxygen
If the subject is unconscious:
• NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
• Administer classical resuscitation measures.
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SECTION 5 : FIRE-FIGHTING MEASURES
FLAMMABLE PROPERTIES :
Flash point
: Not Flammable
Auto-ignition Temperature
: Not applicable
Flammability Limits
: Not applicable.
Unusual Fire and Explosion Hazards : None.
Extinguishing Methods:
Common: In case of fire in close proximity, all means of extinguishing are acceptable (subject to section
below).
Inappropriate extinguishing means: No restriction.
Fire Fighting Procedures:
Specific hazards:
• Non-combustible/non-flammable, but may produce dangerous fumes if involved in fire.
• Formation of dangerous gas/vapors in case of decomposition (see section 10).
• Formation of flammable gas on contact with certain metals (see section 10).
Protective measures in case of intervention:
• Evacuate all non-essential personnel.
• Intervention only by capable personnel who are trained and aware of the hazards of the product.
• In all cases wear self-contained breathing apparatus.
• When intervention in close proximity, wear full protective acid-resistant suit.
• Protect intervention team with water spray when approaching the fire.
• After intervention, take a shower, remove clothing carefully, clean and check equipment.
Other precautions:
• If safe to do so, remove the exposed containers, or cool with large quantities of water.
• Approach from upwind.
• Disperse gas/vapors with water spray.
• After the fire, proceed rapidly to clean the surfaces exposed to the fumes in order to limit the damage to the
equipment.
• As for any fire, ventilate and clean the rooms before reentry.
SECTION 6 : ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate
ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
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SECTION 7 : HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate
exhaust ventilation at places where dust is formed.Normal measures for preventive fire
protection.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
SECTION 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use (EN 143) respirator
cartridges as a backup to engineering controls. If th full-face supplied air respirator. Use respirators
and components tested and approved under appropriate government standards such as NIOSH
(US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
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SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
PHYSICAL STATE
MOLECULAR WEIGHT
CHEMICAL FORMULA
ODOR
SPECIFIC GRAVITY (H2O = 1)
SOLUBILITY IN WATER (weight %)
White Powder.
Solid.
283.4
K2ZrF6
Odorless
1100-1200 kg/m3 (bulk density)
12.7 g/l @ 68oF (20oC)
PH
4-5 (saturated solution)
BOILING POINT
Not applicable
MELTING POINT
1436 oF (780 oC)
VAPOR PRESSURE
Not applicable.
VAPOR DENSITY(air= 1.0)
Not applicable.
EVAPORATION RATE
Not applicable
COMPARED TO
Not Applicable
% VOLATILES
Not applicable.
FLASH POINT
Not applicable.
(Flash point method and additional flammability data are found in Section 5.)
SECTION 10 : STABILITY AND REACTIVITY
NORMALLY STABLE/(CONDITIONS TO AVOID):
Stable under normal conditions.
INCOMPATIBILITIES:
Contact with strong acids liberates hydrogen fluoride.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition may generate oxides of potassium, titanium and hydrogen fluoride.
HAZARDOUS POLYMERIZATION:
Will not occur.
SECTION 11 : TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LD50 Oral - mouse - 98 mg/kg
Remarks: Behavioral:Muscle contraction or spasticity. Lungs, Thorax
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
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Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
This product is or contains a component that is not classifiable as to its carcinogenicity based on its
IARC, ACGIH, NTP, or EPA classification.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
May be harmful if inhaled. Causes respiratory tract irritation.
Toxic if swallowed.
May be harmful if absorbed through skin. Causes skin irritation.
Causes serious eye irritation.
Additional Information
RTECS: ZH702840
SECTION 12 : ECOLOGICAL INFORMATION
Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available(Dipotassium hexafluorozirconate)
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other adverse effects
No data available
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SECTION 13 : DISPOSAL CONSIDERATIONS
Waste treatment: Consult current federal, state and local regulations regarding the proper
disposal of this material.
Packaging treatment:
• Consult current federal, state and local regulations regarding the proper disposal of emptied containers.
• Rinse the empty containers with alkaline water and treat the effluent in the same way as waste.
• Dispose of the containers by dispatching them to an approved incineration facility for hazardous waste.
RCRA Hazardous Waste: Listed as D002 (Corrosive).
SECTION 14 : TRANSPORT INFORMATION
UN number
ADR/RID: 3288
IMDG: 3288
IATA: 3288
UN proper shipping name
ADR/RID:
TOXIC SOLID, INORGANIC, N.O.S. (Dipotassium hexafluorozirconate)
IMDG:
TOXIC SOLID, INORGANIC, N.O.S. (Dipotassium hexafluorozirconate)
IATA:
TOXIC SOLID, INORGANIC, N.O.S. (Dipotassium hexafluorozirconate)
Transport hazard class(es)
ADR/RID: 6.1
IMDG: 6.1
IATA: 6.1
Packaging group
ADR/RID: III
IMDG: III
IATA: III
Environmental hazards
ADR/RID: no
IMDG Marine pollutant: no
IATA: no
Special precautions for user
No data available
SECTION 15 : REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006
Chemical safety assessment
For this product a chemical safety assessment was not carried out
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SECTION 16 : OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
H301
Toxic if swallowed.
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H335
May cause respiratory irritation.
References: Not available.
Other Special Considerations: Not available.
Creation Date :
18.9.2000
Revision Date :
25.7.2006
Disclaimer:
MADRAS FLUORINE PRIVATE LTD provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is intended
only as a guide to the appropriate precautionary handling of the material by a properly trained
person using this product. Individuals receiving the information must exercise their independent
judgment in determining its appropriateness for a particular purpose. Madras Fluorine Private Ltd
MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING
WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR
PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO
WHICH THE INFORMATION REFERS. ACCORDINGLY, MADRAS FLUORINE PRIVATE LTD WILL
NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION
REVISION : 3 15/02/2016 Page 9 of 9