Stoichiometry Problems Problem 1 One way to remove NO from smokestack emissions is to react it with ammonia: 4 NH3 + 6 NO → 5 N2 + 6 H2O Fill in the blanks: 16.5 mol NO reacts with ___ mol NH3 9.30 mol NO yields ___ mol N2 0.772 mol N2 requires ___ mol NO Problem 2 The combustion of butane gas, C4H10, in air, yields CO2 and H2O. Write a balanced equation for the reaction. How many moles of butane are required to form 11.6 mol CO2? Problem 3 A tool set contains 4 wrenches, 3 screwdrivers, and 2 pliers. The manufacturer has in stock 1000 pliers, 2000 screwdrivers, and 1500 wrenches. Can an order for 500 tool sets be filled? Problem 4 Chlorine and fluorine react to form gaseous chlorine trifluoride, ClF3. You start with 3.40 mol Cl2 and 7.16 mol F2. Write a balanced equation for the reaction. What is the limiting reactant? What is the theoretical yield of ClF3? Balance C6H14 + O2 → CO2 + H2O Al + HCl → AlCl3 + H2 KClO3 → KClO4 + KCl Problem 5 Determine the mass percentages of the compound ammonium dichromate. Problem 6 Determine the simplest formula of a compound with the following composition: 43.2% K, 39.1% Cl, 17.7% O Problem 7 Determine the simplest formula of a compound with the following composition: 62.1% C, 5.21% H, 12.1% N, 20.7% O Problem 8 Iron reacts with sulfur to form a sulfide. If 2.561 g of iron reacts with 2.206 g of sulfur, what is the simplest formula of the sulfide? Problem 9 The insecticide DDD contains only C, H, and Cl. When a 3.200 gram sample is burned in oxygen, 6.162 gram CO2 and 0.9008 gram H2O are formed. What is the simplest formula of DDD? Problem 11 Caffeine contains C, H, O and N. Combustion of 1.000 mg of caffeine produces 1.83 mg CO2, 0.4639 mg H2O and 0.2885 mg N2. Estimate the molar mass of caffeine, which lies between 150 and 200 g/mol. Problem 12 Consider separate 100.0 gram samples of each of the following: H2O N2O C3H6O2 CO2 Rank them from greatest to least number of oxygen atoms. Objectives 1. Convert mass quantities to atoms (or molecules) using FLC 2. Solve mass-mass problems using stoichiometry, theoretical and % yield 3. Use mass %’s to find empirical, molecular formulas
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