Practice Homework 24: Solubility Practice Definitions/Helpful Info You will have access to the full rules for determining solubility. Do not think that – just because you are getting the solubility rules – you don’t have to practice. The test is long, and you do not need to waste time flipping through the rules for the first time. You will run out of time. As a result, you might want to memorize the first two rules. The Solubility Rules are located on the website as Appendix 09 - Solubility Rules - NVC Fall 2015 students: I apologize for not having 10 practice sets for this problem. My mind is swiss cheese right now. Instructions Circle the substances that are soluble in water. Underneath each substance, indicate the rule number that tells you that the substance is soluble. You will not have to indicate the rule number (reasoning) on Exam 4. You will need your own paper for this set of problems. Problem Set 1 PbSO4 calcium acetate Na2CO3 chromium(III) nitrate LiOH iron(II) dichromate BaCl2 zinc sulfide KI Page 1 of 6 Problem Set 2 ammonium iodate TiO2 calcium nitride AgBr potassium persulfate Cu(OH)2 lithium arsenide ZnSO4 lead(II) chromate BaI2 nickel(III) acetate Li3P magnesium nitride K2SO3 aluminum fluoride Ca(NO2)2 sodium hydrogen carbonate SnCO3 Problem Set 3 Page 2 of 6 Answers Problem Set 1 – Answer Keys PbSO4 calcium acetate Na2CO3 Rule 3 Rule 2 Rule 1 chromium(III) nitrate LiOH iron(II) dichromate Rule 2 Rule 1 Rule 7 BaCl2 zinc sulfide KI Rule 4 Rule 5 (S2−) Rule 1 ammonium iodate TiO2 calcium nitride Rule 1 Rule 5 Rule 7 AgBr potassium persulfate Cu(OH)2 Rule 3 Rule 1 Rule 5 lithium arsenide ZnSO4 lead(II) chromate Rule 1 Rule 6 Rule 7 Problem Set 2 Page 3 of 6 Problem Set 3 BaI2 nickel(III) acetate Li3P Rule 5 Rule 2 Rule 1 magnesium nitride K2SO3 aluminum fluoride Rule 7 Rule 1 Rule 7 Ca(NO2)2 sodium hydrogen carbonate SnCO3 Rule 7 Rule 1 Rule 5 Page 4 of 6 166.00 g/mol 7) 6 KI(aq) 18.02 g/mol + 6 H2O(l) 158.03 g/mol + 253.80 g/mol 2 KMnO4(aq) 3 I2(s) 86.97 g/mol + MnO2(s) 56.11 g/mol + 8 KOH(aq) 7a) Calculate the mass of manganese(IV) oxide that can be synthesized from 15.00 grams of potassium iodide. 7b) Calculate the percent yield of this experiment if a mass of 1.982 grams of manganese(IV) oxide is produced. 394.72 g/mol 8) 2 NI3(s) 28.02 g/mol 1 N2(g) 253.80 g/mol + 3 I2(s) 8a) Calculate the theoretical yield of iodine, assuming an initial mass of 80.00 g of nitrogen triiodide. 8b) Calculate the percent yield, if a mass of 70.00 grams of iodine is obtained in an experiment. Question 9 277.13 g/mol Reaction 9a) 2 C7H5N3O6(s) 28.02 g/mol 277.13 g/mol Reaction 9b) 2 C7H5N3O6(s) 3 N2(g) 18.02 g/mol + 28.02 g/mol 3 N2(g) 5 H2O(g) 28.01 g/mol + 2.02 g/mol + H2(g) 7 CO(g) 12.01 g/mol + 28.01 g/mol + 12 CO(g) 7 C(s) 12.01 g/mol + 2 C(s) The compound C7H5N2O6 is trinitrotoluene (TNT). TNT can explosively decompose from either of the reactions above. Under controlled conditions, 5.00 grams actually yielded 2.97 grams of carbon monoxide gas. Question 9a: Calculate the theoretical yield of carbon monoxide gas by through both reactions. Question 9b: Determine whether the reaction occurred by Reaction 9a or Reaction 9b. Question 9c: Determine the theoretical yield of this reaction. Answer Key will be up by tomorrow afternoon. Page 5 of 6 Answers 1a) 32.95 g AlCl3 1b) 76.58%-yield AlCl3 2a) 4.30 g HClO4 2b) 94.9%-yield HClO4 3a) 60.58 g CO2 3b) 91.96%-yield CO2 4a) 32.11 g F2 4b) 75.43%-yield F2 5a) 294.23 g V2O3 5b) 62.265%-yield V2O3 6a) 5.972 g PH3 6b) 103%-yield PH3 6c) The extra mass is probably due to unreacted water still in the product. 7a) 77.16 g MnO2 7b) 90.72%-yield MnO2 8a) 2.620 g I2 8b) 75.66%-yield I2 9a) Reaction 9a produces 2.16 g CO. Reaction 9b produces 3.70 g CO 9b) As 2.97 g CO was produced experimentally, the reaction most likely proceeded through Reaction 9b. 9c) As the reaction proceeded through Reaction 9b, the percent yield of CO would be 85.5% Page 6 of 6
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