Johann Marinsek 2015 Refutation of binding energy formula EB = ∆ mc2 1: Uranium fission violates energy conservation 2: Impossibility: Alteration from C+-12.00 to H+-1.00 scale results in altered binding energies Ontological excursus: Atoms are not comprised of a nucleus and extra nuclear electrons in orbitals! In the course of fission the artful uranium electron orbital structure must implode. When the first fragmentation is finalized the electrons reside at the surfaces of Xe-140 and Sr-94.Then two reactions proceed with β- radiation 1: Xe-140 → Cs-140 → Ba-140 → La-140 → Ce-140; 2: Sr-94 → Y-94 → Zr-94 These intermediate fragments are not considered further... Imagine the supernatural resurrection of Ce and Zr orbital shells: Ce and Zr allegedly possess after fission of U-235 their artful particular electron orbital structures... Obviously, this is physically impossible. Any electron must know where to go: 58 electrons must pilot to Ce and 40 electrons must pilot to Zr... An invisible hand must pilot them. But there is no invisible hand in physics... Uranium fission demonstrates the failure of the Bohr atom: There are no extra nuclear electrons! U –235 + n → intermediate fragments... → Ce-140 + Zr-94 + 2n + Q (Figures from wikipedia show the old-fashioned electron shells. But electron orbitals also cannot solve the problem.) Uranium fission is not an empirical confirmation of binding energy formula EB = Δ mc2 According to relativistic formula EB = Δ mc2 uranium fission shows a wonderfull proliferation of energy! The nuclear reaction is: 235 U + n → 140Ce + 94Zr + 2n + Q (energy released) [MeV] The recipe to calculate the binding energy of an element A Z XN is: 1: Calculate the sum of inert masses of electrons and protons: Z × 1,007825 2: Calculate inert mass of all neutrons: N × 1,008665 3: Add both numbers and subtract inert mass of the element. Obtain ∆m (mass defect) 4: Multiply mass defect ∆m with 931.49 and you get binding energy. Example 235U: Q [MeV] = (m[235U] + m[n] – m[140Ce] – m[94Zr] - 2m[n]) × 931.49 = 208.2 Element A ZXN ∑me + mp = Z ×1,007825 ∑ mN = N × 1.008665 ∑ me+mp+mN mi me+mp+mN- mi = ∆m 235 92 235.043933 92.7199 144.23695 236.95685 1.913 U143 ∆m × 931.49 MeV/c2 1782 EB = Δ mc2 delivers invalid binding and nuclear reaction energies. Why? Under the line of the nuclear reaction we insert the binding energies [in MeV ] according to formula E = ∆ mc2. Note that we took into consideration only binding energies, not rest energies. (The Q-value is approximately confirmed experimentally.) 235 U 1782 + n +? → ≠ 140 Ce + 94Zr 1173 + 815 + 2n + Q + ? + 208 Result: After fission the calculated binding energies of the fragments Ce and Zr add up to 173 + 815 = 1988 MeV. The source of fission energies (kinetic energies and binding energies of the fragments) is the binding energy of the parent uranium atom = 1782 MeV Surprisingly the binding energies of the fragments plus the kinetic enrgy (208 MeV) of the fragments surmount the binding energy of the parent uranium atom! For energies there is a huge imbalance: 1782 ≠ 2196 [MeV]. A wonderfull proliferation of 414 MeV energy discredits relativistic binding energy calculation! Graph of Finkelnburg (1956): Binding energy as a function of mass number A. Assumption: U-240 decays into 2 fragments with A = 120. Binding energies of fragments = 2000 MeV, binding energy of uranium = 1800 MeV. Finkelnburg did not realize this impossibiity and therefore the obvious refutation of EB = Δ mc2 . EB=1000 +1000 Uranium fission: Binding energies of fragments greater than binding energy of uranium EB=1800 Current physics does not attribute a binding energy to n. Even a correction due to (low) neutron binding energy cannot solve the problem. The neutron is not an elementary particle but a composed one. The formula EB = Δ mc2 for binding energy is based on the mass/energy conversion formula E = mc2 that relates energy to rest mass. Here it is shown that EB = Δ mc2 is mistaken because applied to fission it violates the energy conservation bookkeeping rule! All particles of U (92 electrons and protons, 143 neutrons) plus the neutron that causes the reaction remain conserved. Cigar-shaped 235U decays into two pieces. During the break, if uranium electrons are arranged in orbital’s, must crash into the disintegrating nucleus. Electrons of the fragments, do they undergo a resurrection into the predetermined orbital’s of quantum mechanics? Only a part of the binding energy of 235U is transformed into radiation energy, namely the binding energy that glues Ce and Zr together. The alleged mass-energy conversion formula E = mc2 cannot provide a recipe to calculate 1: the binding energy for the fission fragments; 2: kinetic energies of fragments; 3: radiation energy. (Intermediate fragments of the fission process are not considered here.) The source of the binding energies of Ce and Zr as well for the released energy is the binding energy of uranium! The uranium binding energy minus 208 MeV energy release (= kinetic energy of fragments) = = roughly the binding energy of fragments Ce + Zr. The necessity of this energy balance shows the analogue in macrophysics: A body consists of 4 masses each m. They are connected by 4 constrained strings. The potential energies of springs are 100 and 900 MeV, respectively, see their locations. Unfix now the horizontal strings with 100 MeV energy each! Left and right part of the body drift apart. Each fragment possesses now a kinetic energy of 100 MeV and a binding energy of 900MeV. Energy conservation before and after fission: binding energy: 2×900 +2×100 —> 2×100 kinetic energy + 2×900 binding energy. Relativistic uranium binding energy calculation violates energy conservation rule! Wechsel der Ionen-Bezugsmasse: statt C+= 12.00 auf H+ = 1.00 Dadurch ergäbe sich eine Vergrößerung der Bindungsenergie. Bindungsenergie somit nicht eindeutig, Formel EB = Δ mc2 somit falsch. Element Ion! H-1 = p D-2 He-4 C-12 Ni-58 U-235 MS Referenzmasse C+ = 12.000 Referenzmasse p + = 1.00 1.0072764668 2.0135532 4.0026 12.000 57.935342 235.043933 1.000 1.999 3.974 11.913 57.51682 233.345976 Bindungsenergie von U-235; A = 235, Z = 92, N = 143 EB= (Z mp+ Z me+(A-Z) mn – m(A, Z)) × 931,5 (MeV) EB = 92.05047 +144,23908 - 233.345976 = = (236.28955 – 233.345976) × 931,5 = = 2.943574× 931.5 = 2741.939 MeV ! Bindungsenergie Ni-58= 896 MeV = 15 MeV per Nukleon Vergleiche Theorie-Experiment Measurements of released energies: (rough) kinetic energies of fragments: source [kik] Fragment amu Kinetic energy MeV Nd-142 79,5 Nb-93 106 Ce-140 80.5 Zr-90, Zr-94 104.5 Kr-89 102.5 Ba-144 77.5 Comparison: measured energies versus energies according to E = mc2 calculation 142 140 140 144 Reaction: measured Nd+90Zr = Ce+93Nb = Ce +94Zr = Ba +89Kr = kinetic energy MeV = 184 = 186.5 = 185 = 180 Kinetic energy neutrons 6 5 5 5 measured kinetic energy + = 220 = 221 220 = 215 30 MeV radiation E = mc2 calculation: = 196 = 187 = 208 = 177 kinetic energy + radiation Energy (MeV) distribution in fission reactions www.science.uwaterloo.ca/~cchieh/cact/nuctek/fissionenergy Kinetic energy of fission fragments Kinetic energy of fission neutrons -6 Prompt (< 10 s) gamma ray energy Gamma ray energy from fission products Beta decay energy of fission products Energy as antineutrinos (ve) 167 MeV 8 8 7 7 7 Energy From Uranium Fission according to hyperphysics (Mulligan) Form of Energy Released Kinetic energy of two fission fragments Immediate gamma rays Delayed gamma rays Fission neutrons Energy of decay products of fission fragm. rays Gamma Beta particles Neutrons Average total energy released Energy Released (MeV) 168 7 3-12 5 ... 7 8 12 215 MeV According to Bogdansky [bog] kinetic energy of fragments is 173 and radiation is 34 MeV. For comparisons we take for kinetic energy of fragments and neutrons 184 + 6 = 190 MeV 30 MeV is taken as the median energy of radiation. (Radiation energy is probably for any reaction in the same range.) So 30 + 190 = 220 MeV is a reasonable approximate energy release of U-235 fission reactions. Computed values for reaction energies differ in a larger range of 177 - 208 MeV (mean 192)! One cannot say that fission measurements are an experimental confirmation of EB = Δ mc2 ! And different sources offer different magnitudes... Apropos: U-235 + n U-238 + n Why? → fission of U → no fission of U Conjecture: Of course, low energy neutrons cannot split neither 235U nor 238U atoms. Neutrons simply bounce off from 238U. Why can a low energy neutron activate the fission process of 235U ? Every atom is an oscillator with many Eigen frequencies. 235U and 238U possess different Eigen frequencies. In the case of 235U the oscillating neutron incorporates into 235U and „pitches“ at once a resonance frequency that excites the emerging 236U atom: 235 U + n → 236 U* → .... fragments + radiation The excited 236U* agitates the aether, that is radiation. Intermediate fragments decay and are β–emitters. Source of radiation is potential energy stored in 235U. In principle, it is possible to split also 238U. But a resonance frequency to start the process must be known. Did Nobel price winners Cockcroft and Walton confirm experimentally E = Δ mc2 ? No! Cockcroft and Walton: The first alleged experimental validation of E = Δ mc2 according to: http://chem.chem.rochester.edu/~chm132tr/lectures/lecture_16.pdf Cockroft and Walton in 1932 took a beam of protons accelerated to high energy by a particle accelerator... and bombarded lithium nuclei: The nuclear reaction considered was: p + 7 Li → 2 α + Q (released energy). From the masses of the reactants and products, due to E = ∆ mc2 it is allegedly possible to calculate the energy liberated in the splitting process: Calculation of Cockcroft with recent values for masses: Masses: 7 3Li = 7.016005, p = 1.00727647, 4 2He = 4.0026033 Mass defect Δm = 7.016005 + 1.00727647 - 2×(4.0026033) = 0.01807547 amu. This corresponds to 0.01807547 amu × 931,49 MeV/amu = 16.84 MeV. The claim is that the formula EB = Δ mc2 is confirmed because the calculated Qvalue is in good agreement with the observed 17,2 MeV of Cockcroft and Walton. But this no a proof for the relativistic Q-value because Cockcroft ignored the kinetic energy of the proton in order to calculate the Q-value! Secondly, energy conservation of binding energies and released energy not shown! If we assume that the observed kinetic energy for alpha particles (17 MeV) is approximately accurate, then we can calculate the energy balance for binding energies in order to estimate the kinetic energy of the proton. Cockcroft in his Nobel lecture mentioned protons with 280 kilovolt energy. Binding and kinetic energies considered: The main source of the released energy is the binding energy of Li. Regarding estimated binding energies of both the reactants and the products as well as the kinetic energies of p and the 2α’s we get the following result for the energy imbalance: p p Kinetic energy Binding energy MeV ? 10 MeV ? 7 → 2α +Q Binding energy → Binding energy Released energy 39 MeV ? → 56 MeV ? 17 MeV Li But this calculation is fictitious because it was shown that relativistic binding energies are meaningless. The main experimental problem is the measurement of kinetic energies. References [eon] Einstein, A., Times, Space and Gravitation. In Out of my Later Years, N.Y. 1950 [bog] Bogdansky, D., Nuclear energy..., 2nd ed. N.Y. 2004 [fin] Finkelnburg, W. Einführung in die Atomphysik, Berlin 1956 [lei] Leibniz, Neues System der Natur: Fünf Schriften zur Logik und Metaphysik, Reclam, Stuttgart 1975 [rob] Roboz, John, Introduction to Mass Spectrometry, Wiley, New York, 1968 [pau] Paus, H., Physik, München 1995 [kik] Kiker, W.E., Correlated Energy and Time-of-Flight Measurements of Fission Fragments. Thesis. OAK RIDGE NATIONAL LABORATORY U. S. ATOMIC ENERGY COMMISION http://www.ornl.gov/info/reports/1964/3445604514693.pdf [lea] Leachman R., B., Velocities of Fragments from Fission of U-233, U-235, and Pu-239 Phys. Rev. 87, 444–447 (1952) [spi] Spiering, Ch., Auf der Suche nach der Urkraft. Frankfurt/M 1986 [coc] Cockcroft, John. Nobel lecture 1951 http://nobelprize.org/nobel_prizes/physics/laureates/1951/cockcroft-lecture.pdf
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