Faculty of Environmental Science, Institute of Soil Sience and Site Ecology , Chair of Site Ecology and Plant Nutrition Soils: Soil Physics II Dr. Stefan Julich Tharandt, 15.12.2016 Part I: Allready learned about… •basic physical properties of soils • • • • Bulk density dB Porosity P Soil texture Soil structure / Soil Aggregates • that control behaviour of soils with regard to • • • • plant growth water flow agricultural management engineering use 15.12.2016 Soil physics II Slide 2 Water-Holding Capacity of Soil: Effect of Soil Texture Coarse Sand Silty Clay Loam Dry Soil Gravitational Water Water Holding Capacity Available Water Unavailable Water 15.12.2016 Soil physics II Slide 3 Measurement of soil water content destructive procedure non-destructive procedure Gravimetric method Time-domain Reflectrometry (TDR) (Neutron Scattering) (Gamma-Ray-Absorption) 15.12.2016 Measurement of soil wetness Gravimetric water content ( ω ) Mw ω Ms • Mw = mass of water evaporated, g (24 hours @ 105oC) • Ms = mass of dry soil, g 15.12.2016 Soil physics II Slide 5 Measurement of soil wetness Gravimetric water content ( ω ) Example: •100cm³ soil sample • wet 150g • dry 110g Mw ω Ms • Mw = mass of water evaporated, g (24 hours @ 105oC) • Ms = mass of dry soil, g 15.12.2016 Soil physics II M 40 g g 0.3636 Ms 110 g g Slide 6 Measurement of soil wetness Example: Volumetric water content (v) •100cm³ soil sample • wet 150g • dry 110g Vw v Vb •Density of water 1g/cm³ • Vw = volume of water (cm³) • Vb = volume of soil sample (cm³) 15.12.2016 Vw 40cm ³ cm ³ v 0.4 Vb 100cm ³ cm ³ Soil physics II Slide 7 Measurement of soil wetness Time-Domain reflectrometry Companies (e.g.): • Soil moisture, Ca. • Easy Test, Poland • Imko, Germany • Theta-Probe, U.K. 15.12.2016 Soil physics II Slide 8 Time-domain reflectometry (TDR) Permittivity: a measure of how an electric field affects, and is affected by, a dielectric medium water = 81 Soil = 4 to 8 v air = 1 c v…propagation velocity c…velocity o light in vacuum (3*108 m/s) …permittivity of the medium around 15.12.2016 Soil physics II Slide 9 TDR – Operating principle From Dirksen 1999 15.12.2016 Soil physics II Slide 10 Time-domain reflectometry (TDR) The propagation velocity of an electromagnetic pulse travelling along a wave guide is: 2L v t L…length of sensor t…travel time between A and B Equating this with the electrodynamic pulse velocity: ct 2L 15.12.2016 2 Soil physics II Slide 11 Wave Form dependent on water content 15.12.2016 Soil physics II Slide 12 Site spezific calibration: Organic soil Water content [m · m-3] 0.9 Schwaerzel & Bohl 2003 0.6 0.3 valid for mineral soils 0.0 0 20 40 60 Dielectric number 80 .0393 .0284 4.19 104 2 2.77 106 3 15.12.2016 Soil physics II Slide 13 Terms to know Dielectric (Is a non-conductor of electricity): • Is a dielectric placed between a capacitor, no net flow of electric charge is allowed but only a displacement of charge Relative Permittivity (Dielectric number) : • ratio of the capacitance of a capacitor with the given substance as dielectric to the capacitance of the same capacitor with air as a dielectric water = 81 Soil = 4 to 8 15.12.2016 Soil physics II air = 1 Slide 14 Pine stand, sandy soil: Spatial variation of soil water content at the end of the vegetation period Greiffenhagen & Wolf 2002 15.12.2016 Soil physics II Slide 15 Pine stand, sandy soil: Soil water dynamics in the field Average soil water content at several soil depths and net precipitation during the experiment. From Wessolek, 2008 15.12.2016 Soil physics II Slide 16 Properties of Water - Polarity • atoms in the water molecule not symmetrical arranged • hydrogen atoms attached to oxygen in an 105° angle • charges are not evenly distributed in the molecule • hydrogen end is positive; the oxygen end is negative Source: Brady & Weil 2002 Soil physics II Slide 17 Properties of Water – Hydrogen Bonding • • • • • Hydrogen atom of one molecule is attracted to an oxygen atom of another molecule (low energy bond) process called cohesion Hydrogen bonding accounts for high boiling point, specific heat and viscosity Water molecules also could attach rigidly to soil particles positive charged side of the molecule attracted by negative charged surfaces process called adhesion Attached water molecules hold other water molecules by cohesion Through cohesion and adhesion soil particle retain water or control its movement and use Soil physics II Source: Brady & Weil 2002 Slide 18 Bond Strength of adsorped water dependends on water film thickness 10000 Å = 0.001 mm From: Hartge & Horn Soil physics II Slide 19 Capillarity Source: Flühler et al. 2005 Soil physics II Slide 20 Capillarity • capillary rise due to combined action of cohesion and adhesion • adhesion forces causes water molecules to spread on glass surface low contact angle • cohesion forces among water molecules surface tension on the air-water interface in the glass tube meniscus • because pressure on free water higher than under the meniscus water pushed up • water is rising until weight of water (gravitation) balances pressure difference Soil physics II Source: Brady & Weil 1996 Source: Brady & Weil 2002 Fup Fdown Slide 21 Capillary rise in a soil • capillary rise in soil follow same principles as in glass tube (discusse before) • capillary rise is more irregular due to high variability in shape and size of pores • finer texture more small sized pores higher rise but slower due to higher friction • movement in soil capillaries in all directions Source: Brady & Weil 2002 Soil physics II Slide 22 Soil Water & Energy • retention and movement of water in soils; water uptake by plants; water loss to atmosphere energy related phenomenon In general two kind of energy: Kinetic energy: associated with motion • of minor importance (can be neglected in soils) Potential energy: associated with position • of primary importance in determining the state and movement of water in soil Soil physics II Slide 23 Potential Energy Energy stored by the position of the arrow and the bowstring. No energy is stored. Soil physics II Slide 24 Total Soil Water Potential = the work that is required for moving a quantity of water from a reference state into the desired state within the soil. The performance is reversible and isotherm. = describes the energy density of soil water. Soil physics II Slide 25 Total Soil Water Potential Wet soils: • most water in (large) pores or thick films around soil particles • water molecules not very close to particle surfaces • not tightly held by soil matrix • Water molcules high freedom of movement Dry soils: • small films around particles • water tightly bond (high adhesion) • water molecules low freedom of movement 15.12.2016 Soil physics II Slide 26 Total soil water potential - Reference or Standard State In general states of soil water compared to that of pure water: = pure water, • at atmosphere pressure, • at the same temperature as that of soil and, • constant elevation. • Soil water potential at the reference state is 0 (per definition). Soil water potenrial describes the difference of energy levels between soil water and pure water! Soil physics II Slide 27 Components of Soil Water Potential Ψ Total Soil Water Potential w Gravitational Potential Tensiometer Pressure Potential Osmotic Potential g tp o Pneumatic Potential Hydrostatic Potential a p > 0 Matric Potential m < 0 Ψw Ψg Ψa Ψp Ψm Ψo • All act simultanously to influence water behavior in soils Soil physics II Slide 28 Soil Water Potential versus Soil Water Content Soil water potential Soil water content Intensity Capacity „To what extent is the stored „How much water is stored?“ water available?“ „In which direction does the water move?“ • To determine wheter water will flow from one point to another • Useful for budgeting water, planning drainage lines or irrigation Soil physics II Slide 29 Direct Measurements of Components of Water Potential Gravitational potential • Measure the vertical distance between the reference elevation and the point of interest. Osmotic potential • Extract soil solution, measure its concentration. Pneumatic potential • Measure the soil air pressure with a barometer. Hydrostatic potential • Measure the vertical height of saturated water above the point of interest. Soil physics II Slide 30 Water Retention of Soils • due to electrostatic forces soils retain water against gravity • energy of stored water less than free water • this difference is called total soil water potential • matric potential part of total soil water potential • matric potential is defined as energy required to move water against adsorptive and capillary forces • relationship between matric potential and water content water retention curve Soil physics II Slide 31 Water retention curve http://thealmonddoctor.com/general/irrigati on-scheduling-part-2-determining-waterholding-capacity/ • suction applied incrementally first large pores emptied • increase of suction emptying smaller pores incrementally • increase in suction decrease of thickness around water partcicles • therefore increasing suction means decreasing soil water content • the amount of water remaining in soil function of sizes and volumes of water filled pores and of the amount of water adsorbed to soil particles (matric suction) suction • function called water retention curve measured experimentally 15.12.2016 Soil physics II Slide 32 Classical concept of soil-water availability to plants Soil physics II Slide 33 Available Plant Water & Soil Texture Soil physics II Slide 34 WRC & Soil Texture • Clay few large pores and broad distribution of particle sizes gradual decrease of water content with increasing suction • Sand more larger pores drain at modest suction rapid decrease in capillary region Soil physics II Slide 35 WRC & bulk density Soil Structure & WRC • compaction causes a shift in pore size distribution • increasing bulk density decreasing amount of coarse pores increasing amount of medium and fine pores • low suctions shape of WRC influenced by soil structure • high suctions, the predominant mechanism of water retention is adsorptive shape of the WRC depends on soil texture Soil physics II Slide 36 Progressive draining of water with increasing suction Soil physics II Slide 37 Flow in saturated versus unsaturated soil • all of the pores are water filled and conducting • Flow over the whole cross-sectional area Source: http://www.terragis.bees.unsw.edu.au/terraGIS_soil/ sp_water-water_flow.html • some of the pores air filled • conductive portion of cross-sectional area decreases • Large pores are emptied first flow takes place in the smaller pores • larger pores must be circumvented (increase of tortuosity) • progressive desaturation, the flow path length increases • flow occur either as film creep • tube flow through narrower and more tortuous channels Source: http://www.terragis.bees.unsw.edu.au/terraGIS_soil/ sp_water-water_flow.html Soil physics II Slide 38 Flow in saturated versus unsaturated soil Source: http://www.terragis.bees.unsw.edu.au/terr aGIS_soil/sp_water-water_flow.html Source: http://www.terragis.bees.unsw.edu.au/terr aGIS_soil/sp_water-water_flow.html Saturated flow • Driven by gravitation and by hydrostatic pressure differences. • All pores are water filled and conducting. • Water phase is continuous and the conductivity maximal. Soil physics II Unsaturated flow • Driven by matric forces. • Pores are partially air filled. • occur either as film creep along the walls of wide pores, and as tube flow through narrower channels. • Conductivity is low. Slide 39 Soil hydraulic properties - water retention and conductivity 4 log K(h) [cm d -1] water content [m3 m-3] 0.45 0.3 0.15 Sand Silt 0 -4 Sand Silt -8 0 -2 0 2 log |suction| [cm] -2 4 0 2 log |suction| [cm] 4 • Water retention and soil hydraulic conductivity soil hydraulic properties. • soil hydraulic properties are material characteristic • every soil horizon has a own WRC and a own conductivity curve • Water retention and conductivity are related to each other.. Unsaturated hydraulic conductivity decreases as water content decreases because: 1. 2. 3. Cross sectional area of water flow decreases. Tortuosity (flow path length) increases. Increase of flow resistance in smaller pores. Soil physics II Slide 40 Infiltration http://extension.oregonstate.edu/gardening/soiltexture-determines-how-much-and-how-often-water ... refers to the entry of water into a soil profile from the boundary. The rate of infiltration affects • the water economy of plant communities, • the amount of overland flow and • the soil erosion and stream discharge. Knowledge of infiltration is prerequisite for efficient soil and water management. Soil physics II Slide 41 The process of Infiltration • dry soil, the matrix forces draw water into the soil • water pressure head of 0 cm dry soil negative pressure head a hydraulic gradient between soil surface and top soilwater will move into soil • First soil particles wetted • more water enters soilsurface tension forces cause water to enter most the small pores (forming of meniscii) • more water penetrates into soil force of gravity takes over water moves down • early phase of the infiltration matrix forces are dominant, later, the percolation is driven by the gravity •rain stops and the supply of water decrease, water drains by gravity until the menisci reappear and forces of surface tension again dominate, holding water in pores. Soil physics II Slide 42 Daily Variation of Soil Temperature at different depths Lufttemp. in 2 m Höhe Bodentemp in 5 cm Bodentemp in 10 cm Bodentemp in 15 cm Bodentemp in 30 cm Temperatur [°C] 25 20 15 10 0 4 8 12 Uhrzeit Soil physics II 16 20 24 Slide 43 Course of Soil and Air Temperature over the year 30.0 Lufttemperatur in 2m Höhe Temperatur [°C] Bodentemperatur in 10 cm Tiefe Schneebedeckung 15.0 0.0 -15.0 01.01. 02.03. 01.05. 30.06. 29.08. 28.10. 27.12. Datum Soil physics II Slide 44 Course of soil and air temperature over the year ... Depends under equal climate conditions on: • Texture • Water content • Soil Cover • (Soil Color) • Topography / Exposition Soil physics II Slide 45 Color Soil Color Color after A. Munsell • Hue • Value redness, yellowness lightness, darkness value of 0 = black • Chroma intensity, brightness value of 0 = gray Soil physics II 46 Slide 46 Color Soil Color Soil physics II 47 Slide 47 Soil Color Stagnosol Podzol Soil physics II Slide 48 Text Books •Daniel Hillel (2004) : Introduction to Environmental Soil Physics. Academic Press •Klaus Bohne (2005) An Introduction into Applied Soil Hydrology. Catena Verlag •Don H. Scott (2000) Soil Physics – Agricultural and Environmental Applications. Iowa State University Press • William A. Jury & Robert Horton (2004) Soil Physics. Wiley, Hoboken New Jersey. Soil physics II Slide 49
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