Journal of Sedimentary Research, 2010, v. 80, 666–677 Research Article DOI: 10.2110/jsr.2010.061 APPLICATION OF QUARTZ SAND MICROTEXTURAL ANALYSIS TO INFER COLD-CLIMATE WEATHERING FOR THE EQUATORIAL FOUNTAIN FORMATION (PENNSYLVANIAN–PERMIAN, COLORADO, U.S.A.) DUSTIN E. SWEET* AND GERILYN S. SOREGHAN Conoco-Phillips School of Geology and Geophysics, University of Oklahoma, 100 East Boyd Street, Norman, Oklahoma 73019, U.S.A. e-mail: [email protected] ABSTRACT: Climatic interpretations of the upper Paleozoic (Permo-Pennsylvanian) Fountain Formation, a coarse-grained fan-delta system that formed in western equatorial Pangea, are difficult to constrain owing to a general lack of climatic indicators so typical of coarse clastic systems. We applied scanning electron microscopy (SEM) to analyze quartz grains in this system in an attempt to test the hypothesis of a glacial influence on these strata. SEM observations of first-cycle quartz grains from these strata reveal microtextures formed from fracturing during grain transport, even after diagenetic overprinting occurred under moderate burial conditions (up to 3.5 km depth and 100uC). Transport-induced microtextures can be grouped based on inferred fracture process into: (1) high-stress fractures, consisting of fractures created through sustained high shear stress, such as grooves, deep troughs, and gouges, and are inferred to occur predominantly during glacial transport; (2) percussion fractures, consisting of fractures created by grain-to-grain contact during saltation or traction flow, such as randomly oriented v-shaped cracks and edge rounding; and (3) polygenetic fractures, such as conchoidal fractures, arc-shaped steps, linear steps, and linear fractures, that occur under a wide range of transport processes and thus possess no environmental significance. Delineation of high stress, percussion, and polygenetic fracture types demonstrate that the Fountain Formation quartz grains exhibit microtextures similar to both till and glaciofluvial deposits, suggesting that periods of upland glaciation occurred in the source region of the Fountain Formation (Ute Pass uplift). The abundance of high-stress fractures peaks at two stratigraphic intervals. These intervals are inferred to record the presence of ice in the Ute Pass uplift and are correlative with polygonally fractured paleosurfaces in the Fountain Formation that are interpreted to reflect cold-temperature weathering. Moreover, the peak intervals are approximately coeval with inferred episodes of ice maxima from high-latitude localities, as well as other low-latitude localities. Geologically reasonable stream gradients and estimated transport distance suggest a best-estimate elevation of the ice terminus of , 1500 m, but possibly ranging to 3000 m. These data suggest that upland glaciers episodically existed within this equatorial setting and that further use of this technique may reveal more evidence of ice in other proximal deposits of the ancestral Rocky Mountains, as well as other systems of various geologic ages. INTRODUCTION Scanning electron microscopy (SEM) analysis of microtextures on quartz grains has long been used to attempt interpretation of depositional environments within Neogene deposits (e.g., Krinsley and Takahashi 1962; Krinsley and Donahue 1968; Krinsley and Doornkamp 1973). Nonetheless, a variety of processes in a wide range of depositional environments can produce similar types of microtextures—a concept known as equifinality. Recent work, however, indicates that wet-based glacial environments tend to produce a unique suite of microtextures, as a result of the extraordinary stress imparted to grains in a subglacial environment (e.g., Mahaney 2002; Mahaney and Kalm 2000). Despite advances in SEM microtextural characterization of sediments from glacial environments, such analysis has not been applied widely to preNeogene strata presumably owing in part to the overprinting effects of diagenesis and sediment recycling. * Present Address: Chevron Energy Technology Company, 1400 Smith #38079, Houston, Texas 77002, U.S.A. Copyright E 2010, SEPM (Society for Sedimentary Geology) Recently, Soreghan et al. (2008a) proposed episodic and widespread cold conditions, including glaciation, within the Ancestral Rocky Mountains (ARM) of Pennsylvanian–Permian tropical Pangea. Additionally, Sweet and Soreghan (2008) have suggested a cold-weathering origin for paleosurfaces exhibiting polygonal fractures within the Fountain Formation of the ARM. Here, we present SEM microtextural analysis of quartz grains recovered from the Pennsylvanian–Lower Permian(?) Fountain Formation deposited on the northern flank of the ancestral Ute Pass uplift of the ARM to assess: (1) the application of SEM microtextural analysis to climate interpretation in ancient strata and (2) the hypothesis of low-latitude glaciation within western equatorial Pangea. The results of this study are consistent with the hypothesis of episodic influxes of grains exhibiting glacially induced microtextures in this equatorial setting. GEOLOGIC BACKGROUND The ARM form an intraplate collage of basement-cored uplifts and intervening sedimentary basins (Fig. 1; Kluth and Coney 1981) that 1527-1404/10/080-666/$03.00 JSR COLD-CLIMATE WEATHERING IN EQUATORIAL PANGEA 667 FIG. 1.—Late Pennsylvanian paleogeography of the southern ancestral Front Range and Ute Pass uplifts. Manitou Springs study area shown as outlined area on northeastern margin Ute Pass uplift. Latitudinal position is estimated from Scotese (1997). Inset: Displays outline of Colorado in the United States interior and location of ARM uplifts (in gray; modified from Kluth and Coney 1981). The black box is the approximate area of the enlarged view. developed within western equatorial Pangea in late Paleozoic time. Mantling the basement-cored uplifts are coarse-grained wedges of firstcycle arkosic sediments. In the study area, the coarse clastic wedge shed eastward from the ancestral Front Range uplift is represented by the Fountain Formation (Fig. 1; e.g., Hubert 1960; Mallory 1972, 1975). The Fountain Formation records coarse-grained fan-delta and braided-river deposition (Suttner et al. 1984; Maples and Suttner 1990; Sweet and Soreghan 2010). Despite numerous studies of the Fountain Formation, interpretations of the climate that prevailed during deposition are conflicting. Early workers interpreted a warm-humid climate on the basis of an inferred lateritic paleosol, local coaly layers, and scattered plant fragments (Wahlstrom 1948; Hubert 1960), all restricted to the lower 150 m of the 900-m-thick formation. Mack and Suttner (1977) demonstrated that the compositional maturity of the first-cycle sediments composing the lower Fountain Formation exceeds that of first-cycle sediments from modern drainages in the region, and used these results to advocate warm-humid (tropical) conditions for the lower part of the Fountain Formation. Conversely, Raup (1966) and Walker (1967) cited the interstitial clay composition and hematite content of the Fountain Formation as evidence for a warm-arid climate. More recently, Suttner and Dutta (1986) and Dutta and Suttner (1986) suggested that an upward increase in mineralogical immaturity, together with the decrease in inferred neoformed kaolinite upward in the Fountain Formation reflect a change from warm-humid to warm-semiarid conditions. All previous researchers favor a warm climate; yet none of the indicators used bear solely on temperature. For instance, coal reflects high effective moisture under a wide range of temperatures (Parrish 1998; Begossi and Della Fávera 2002; Barber et al. 2003). Additionally, Suttner and Dutta (1986) noted that compositional immaturity characterizes both cool and warm-arid climates. Sweet and Soreghan (2008) documented polygonally fractured bedding surfaces in the Fountain Formation inferred to record repeated thermal contraction of frozen ground. The only proxies that bear exclusively on temperature conditions during deposition of the Fountain Formation are those of Dutta and Suttner (1986) (d18Ovalues of neoformed clays) and Sweet and Soreghan (2008), both of which indicate anomalously cool equatorial temperatures. The Fountain Formation consists of three tectonostratigraphic units (lower, middle, and upper) separated by unconformities of varied duration (Fig. 2; Sweet and Soreghan 2010). These tectonostratigraphic units are defined by a combination of variations in facies, sedimentology, structure, paleocurrents, and paleohydraulics and provide a framework that enables relative dating in the poorly dated Fountain Formation (Sweet and Soreghan 2010). Morrowan–Atokan (Bashkirian) marine invertebrate and plant fossils occur in the basal Glen Eyrie Member of the lower Fountain Formation (Chronic and Williams 1978; Suttner et al. 1984). The middle Fountain Formation bears no age-diagnostic fossils, but records the same depositional system (i.e., fan delta) as the lower unit and thus is considered only slightly younger than the lower unit. The upper Fountain Formation has no age control in the study area except through relative stratigraphic position. In northern Colorado, the uppermost Fountain Formation is tightly constrained by Virgilian fusulinids recovered 4 m below the contact with the overlying Ingleside Formation which includes Wolfcampian fusulinids (Maughan and Ahlbrandt 1985). Sweet and Soreghan (2010) provide an overview of the age of the upper part of the Fountain Formation and propose that it is latest Pennsylvanian to possibly earliest Permian in age; thus the unconformity separating the upper and middle units ranges from Desmoinesian to latest Pennsylvanian (Fig. 2). METHODS Samples were collected from strata that represent three depositional environments or processes (fluvial, debris flow, and marine shoreface). For each of the 15 samples, 10–55 individual quartz grains were analyzed using the SEM; however, only those grains that exhibited microtextures considered mechanical, rather than diagenetic, were used in analyses presented herein. Samples were disaggregated for microtextural analyses by removing iron oxide cement with the citrate–bicarbonate–dithionite (CBD) method 668 JSR D.E. SWEET AND G.S. SOREGHAN to estimate percentage of grain covered or relative importance of particular microtextures. Quantitative summary analyses were plotted following methods outlined in Mahaney and Kalm (2000) and Mahaney et al. (2001). DIAGENESIS AND ANTIQUITY OF MICROTEXTURES The Fountain Formation is a first-cycle arkose, as evinced by its textural and compositional immaturity and its paleogeographic context adjacent to the Precambrian basement (granitoid) source (Suttner et al. 1984; Kairo et al. 1993). Burial depth is constrained to , 3.5 km based on vitrinite reflectance (Ro 5 0.61%, hvBb 5 100uC) analysis on coal recovered from the lower Fountain Formation and employing a modern geothermal gradient of 30uC/ km for the Denver Basin (Raynolds et al. 2001). The Fountain Formation was exhumed at Manitou Springs during Laramide-age shortening, thus maximum burial and temperature conditions most likely occurred in the latest Cretaceous to early Paleogene. The grains of the Fountain Formation are composed predominantly of quartz and feldspar with varying amounts of muscovite and biotite. Primary diagenetic products formed during burial consist of authigenic clay, quartz overgrowths and ‘‘turtle-skin’’ quartz as described by Folk (1978) (Fig. 3). At least one of these precipitation features are found on each quartz grain analyzed, and commonly precipitation completely obscures the grain surface. However, of the 542 quartz grains analyzed, 330 (61%) exhibit fracture surfaces that pre-date diagenesis, as indicated by: (1) precipitation of ‘‘turtle-skin’’ quartz on the fracture surface, (2) partial encroachment of quartz overgrowths onto fracture surfaces, or (3) presence of dissolution pits on fracture surfaces. Thus, the pre-diagenetic fractures must have formed during the late Paleozoic because the Fountain Formation consists of first-cycle sediments derived directly from the adjacent Precambrian basement (Hubert 1960) and reexposed as a result of Laramide orogenesis. On a few grains, pristine fracture surfaces cut across precipitation features, indicating new fracturing induced during disaggregation, the sampling process, or regional stress in situ. Such fractures were ignored during analyses. FIG. 2.—Fountain Formation stratigraphy of the Manitou Springs region, after Sweet and Soreghan (2010). The upper Fountain Formation is gradational with either the Lyons or Ingleside formations, such that A) indicates the stratigraphic relationships of the upper Fountain Formation if the overlying unit is Ingleside and B) indicates stratigraphic relationships of the upper Fountain Formation if the overlying unit is Lyons. Note that only one of the overlying eolian units is present in any given region; see Sweet and Soreghan (2010) for further discussion. Vertical black lines represent inferred time missing at unconformities; however, the duration of individual unconformities is weakly constrained. Time scale is from Gradstein et al. (2004). IPlf 5 lower Fountain Formation; IPmf 5 middle Fountain Formation; IPuf 5 upper Fountain Formation. (Mehra and Jackson 1960; Janitzky 1986). The sand + gravel fraction was wet-sieved and the 3–1.5 mm, 1.5–0.7 mm, and 0.7–0.3 mm fractions were analyzed. To avoid introduction of laboratory-induced fracturing, samples were not sonicated. Quartz grains were randomly selected with a binocular microscope for SEM analysis as outlined by Mahaney et al. (1988). Individual grains were placed on an aluminum SEM stub and sputter coated with a gold–palladium mixture. Grains were examined with a Zeiss 960 SEM, tungsten filament and 15 kV accelerating potential. All grains were individually verified as quartz by energy-dispersive spectrum (EDS) analysis. The atlases of Krinsley and Doornkamp (1973) and Mahaney (2002) were used to identify microtextures, following the characteristics listed in Table 1 (see also Acknowledgments section for URL of supplemental Table). Each microtexture evaluated was recorded as either present or not present following the methods of Mahaney (2002); no attempt was made CHARACTERISTICS OF MICROTEXTURES Quartz grains display a wide variety of textural characteristics. Grain rounding ranges widely from angular to well rounded, and sorting is typically poor to very poor. Overall, the most abundant microtextures are conchoidal fractures, subparallel linear fractures, and edge-rounding fractures (Figs. 4, 5). Microtextural variance based on grain size was not observed. Because the samples represent various facies, it is useful to examine and compare data both from similar facies and similar stratigraphic levels. Facies Trends Marine shoreface facies occur in the lower and middle Fountain Formation and typically exhibit more mineralogical and textural maturity than the other facies. SEM analysis indicates that nearly 60% of the grains contain edge rounding and low relief (Fig. 5A). Breakage blocks, randomly oriented v-shaped cracks, arc-shaped steps, conchoidal fractures, and subparallel linear fractures occur on 20–30% of the grains (Figs. 4, 5A). Grooves, gouges, and troughs are relatively rare. Only debris flows in the middle Fountain Formation were sampled for this study. Quartz grains from the debris flow facies exhibit a relatively high percentage (30–50%) of breakage blocks, conchoidal fractures, and edge rounding (Fig. 5B), whereas 15–25% of the grains show subparallel linear fractures, arc-shaped steps, and linear steps (Fig. 4). Grains are characterized predominantly as having medium relief, commonly associated with sharp angular features. Gouges, grooves, and troughs are least abundant in this facies. JSR COLD-CLIMATE WEATHERING IN EQUATORIAL PANGEA 669 TABLE 1.— SEM microtexture nomenclature and characteristics. Microtexture Characteristics(1) A. Grain fracturing microtextures Edge rounding Rounded edges on grains V-shaped cracks Abrasion features Arc-shaped steps Breakage blocks Conchoidal fractures Fracture faces Linear steps Sharp angular features Subparallel linear fractures Crescentic gouges V-shaped fractures of variable size and depth on grain surfaces Rubbed or worn down grain surfaces Arcuate fractures on grain surfaces, typically depths greater than micrometers Space represented by removal of block of variable size on grain, typically on grain edge Smooth curved fractures with ribbed appearance Large, smooth, and clean fractures of at least 25% of grain surface Widely spaced (. 5 mm) linear fractures on grain surface Distinct sharp edges on grain surface Deep troughs Mechanically upturned plates Straight grooves Linear fractures on grain surface, typically less than , 5 mm spacing Crescent-shaped gouges on grain surface, typically . 5 mm deep Grooves . 10 mm Partially torn loose plates from the mineral surface Linear grooves on mineral surface , 10 mm Curved grooves Curved grooves on mineral surface , 10 mm B. Diagenetic microtextures Dissolution etching Grain surface with a net of pits or cavities Weathered surface Mechanically and/or chemically altered surface containing preexisting microtextures Precipitation features Coatings or euhedral growth of SiO2 or Fe2O3 on grain surface C. Grain relief(2) Low relief Nearly smooth surface without topographic irregularities Medium relief Semi-smooth surface with topographic irregularities High relief Topographically irregular surface with pronounced swells and swales (1) (2) Process of microtexture formation Percussion (fracturing) Percussion (fracturing) Polygenetic (fracturing) Polygenetic (fracturing) Polygenetic (fracturing) Polygenetic (fracturing) Polygenetic (fracturing) Polygenetic (fracturing) Polygenetic (fracturing) Polygenetic (fracturing) Sustained high-stress (fracturing) Sustained high-stress (fracturing) Sustained high-stress (fracturing) Sustained high-stress (fracturing) Sustained high-stress (fracturing) Chemical dissolution (diagenesis) Weathering (diagenesis) Mineral growth (diagenesis) Entire history of grain Entire history of grain Entire history of grain Selected reference(s) Campbell and Thompson 1991; Mahaney and Kalm 1995, 2000; Mahaney 2002 Campbell and Thompson 1991; Mahaney and Kalm 1995, 2000; Mahaney 2002 Mahaney and Kalm 1995, 2000; Mahaney 2002; Mazzullo and Ritter 1991 Campbell and Thompson 1991; Mahaney and Kalm 1995, 2000; Mahaney 2002 Campbell and Thompson 1991; Helland and Diffendal 1993 Campbell and Thompson 1991; Mahaney and Kalm 1995; Mahaney 2002 Mahaney 2002 Campbell and Thompson 1991; Mahaney and Kalm 1995; Mahaney 2002 Campbell and Thompson 1991; Mahaney and Kalm 1995; Mahaney 2002 Helland and Diffendal 1993; Mahaney and Kalm 1995, 2000; Mahaney 2002 Campbell and Thompson 1991; Mahaney et al. 1988; Mahaney 2002 Mahaney and Kalm 1995, 2000; Mahaney 2002 Mahaney and Kalm 2000; Mahaney 2002 Helland and Diffendal 1993; Mahaney and Kalm 1995, 2000; Mahaney 2002 Helland and Diffendal 1993; Mahaney and Kalm 1995, 2000; Mahaney 2002 Mahaney and Kalm 1995; Mahaney 2002 Helland and Diffendal 1993; Mahaney and Kalm 1995; Mahaney 2002; Mazzullo and Ritter 1991 Folk 1978; Helland and Diffendal 1993; Mahaney 2002; Mazzullo and Ritter 1991 Campbell and Thompson 1991; Mahaney and Kalm 1995; Mahaney 2002 Campbell and Thompson 1991; Mahaney and Kalm 1995; Mahaney 2002 Campbell and Thompson 1991; Mahaney et al. 1988; Mahaney and Kalm 1995; Mahaney 2002 Descriptions predominantly synthesized from Mahaney (2002) Relief is defined as the difference between high and low points on grain surface The fluvial facies are ubiquitous throughout the lower, middle, and upper Fountain Formation (Sweet and Soreghan 2010). Quartz grains from the fluvial facies display the widest variation in microtextures. Edgerounding fractures are the most common, found on nearly 60% of the examined grains (Fig. 5C). Other prominent microtextures are conchoidal and subparallel linear fractures, arc-shaped and linear steps, randomly oriented v-shaped cracks, and breakage blocks. Relative to the debrisflow and shoreface facies, grooves, troughs, and gouges occur in highest abundance in the fluvial facies. Mechanically upturned plates occur uniquely in this facies (Fig. 4H). Similar to the debris-flow facies, grains typically exhibit medium relief, although many display high relief. Interpretation.—The textural and mineralogical maturity enhancement of marine facies relative to other facies has been interpreted as an environmental effect attributable to wave action in the shoreface (Kairo et al. 1993). The high percentage of edge rounding and low relief probably record this shoreface environmental effect; however, nearshore eolian processes may also account for some these microtextures. The presence of grooves, troughs, and gouges in the marine facies are inferred to reflect nonmarine transport because these microtextures require considerable and sustained pressure (e.g., Mahaney and Kalm 2000; Mahaney 2002), conditions atypical of the marine realm. Quartz grains from debris-flow facies are commonly partially encased by clay minerals that were not completely removed by the CBD process, and also exhibit the precipitated quartz common to other facies. These two factors resulted in a relatively low population (14 of 22) of grains with observable ancient microtextures. The debris-flow grains preserve a higher proportion of angular grains than the other facies, presumably because the laminar flow typical of debris flows inhibits the mechanical interaction of grains necessary to abrade edges. Overall, variation in microtextural attributes of grains amongst the studied facies is subtle, suggesting that environment of deposition did not impart a dramatic signal in overall microtextural character. However, the lack of v-shaped cracks on grains in the debris-flow facies and the wide diversity of fractures observed in grains from fluvial facies probably reflect processes intrinsic to these environments that partially controlled 670 JSR D.E. SWEET AND G.S. SOREGHAN grooves, troughs, and gouges, all reflecting considerable and sustained pressure (Mahaney and Kalm 2000), are unlikely to be a result of fluvial processes. Instead, they suggest the influence of process(es) within a different environment that affected grain microtextures previous to fluvial entrainment, as discussed below. DISCUSSION FIG. 3.—SEM image showing common diagenetic features exhibited on Fountain Formation quartz grains. Qog 5 quartz overgrowth; Cc 5 clay coating; Ts 5 turtle-skin silica coating. for those microtextures. For example, randomly oriented, v-shaped cracks are thought to record percussion (Campbell and Thompson 1991; Jackson 1996; Mahaney and Kalm 2000; Mahaney 2002), a process that is rare in debris flows owing to minimal intergranular collisions (e.g., Costa 1988), as noted above. In contrast, percussion is an important process in the saltation transport common to both fluvial and shoreface environments, and the relative abundance of v-shaped cracks in these facies probably reflects that difference. Stratigraphic Trends Samples from different stratigraphic horizons reflect different time horizons, such that grouping facies results in time averaging of the textural data. The Fountain Formation has poor age control, but the tectonostratigraphic units proposed by Sweet and Soreghan (2010; defined earlier) provide a relative chronostratigraphic framework for samples (Fig. 2). Of the three facies, only fluvial facies occur in all three tectonostratigraphic units; hence, samples from this facies were compared with one another to address stratigraphic variation of microtextures. Microtextural frequency plots from fluvial facies of the lower, middle and upper Fountain Formation (Fig. 5D, E, F) all show a predominance of medium-relief grains, edge-rounding fracturing (50–70%), and randomly oriented, v-shaped cracks (20–30%). Conchoidal and subparallel linear fractures are also relatively prominent features, present on 20– 40% of the grains. A notable intersample difference is the higher percentage of gouges, grooves, and troughs observed on grains of the middle Fountain tectonostratigraphic unit relative to those of the other units (Fig. 5D, E, F). Interpretation.—The high frequency of edge-rounding fracturing and vshaped cracks, both thought to record percussion (Mahaney and Kalm 2000; Mahaney 2002), presumably reflect intergranular collision during fluvial transport. However, the stratigraphic variation in frequency of Historically, data on microtextural frequency have been displayed in histogram-type plots (Fig. 5) (Campbell and Thompson 1991; Mahaney et al. 1991; Mahaney 1995; Mahaney and Kalm 1995, 2000; Mahaney 2002). The large number of variables (grain characteristics) in these plots, however, makes it difficult to compare data sets, unless there are very large contrasts in frequency data, such as in Mahaney and Kalm (2000). Therefore comparison of data to assess transport process(es) is facilitated by grouping microtextures created by similar fracturing processes. Whereas many microtextures can be created in various environments through various processes, some are thought to record specific transport processes. Notably, randomly oriented, v-shaped cracks and edgerounding fracturing are commonly interpreted to reflect percussion (saltation) transport (e.g., Campbell and Thompson 1991; Mahaney and Kalm 2000; Mahaney 2002). In contrast, straight and curved grooves, deep troughs, and crescentic gouges are thought to reflect sustained high shear stress (e.g., Mahaney and Kalm 2000; Mahaney 2002). Accordingly, a potentially useful approach involves classifying mechanically induced microfractures into one of three genetic groupings: (1) high-stress fractures, (2) percussion fractures, and (3) polygenetic fractures, or those created through a variety of processes. These groups can then be plotted on a ternary diagram for semiquantitative intersample comparison (Fig. 6). Plotting all of the fluvial samples on a high stress–percussion– polygenetic fracture ternary diagram reveals a first-order trend that is subparallel to the polygenetic–percussion join (Fig. 6), suggesting that grains experienced varying amounts of intergranular collision that resulted in the v-shaped cracks and edge rounding defining the percussion apex. However, all grains except one are shifted from the polygenetic– percussion join, indicating that they experienced sustained high stress at some point during transport, in order to form the textures defining the high-stress apex. High-stress microtextures require grain-to-grain contact under high shear stress and have been reported from grains entrained in highly viscous debris flows, structural shear zones, and glacial environments (Mahaney 2002). Debris flows are an unlikely cause for the high-stress textures present on the grains in the high stress–percussion–polygenetic ternary diagram because only samples from the fluvial facies were used in the analysis and debris flows are an overall minor part of the depositional system (Suttner et al. 1984; Sweet and Soreghan 2010). The major late Paleozoic structures in the study area are the Ute Pass fault and associated folding (Kluth 1997; Suttner et al. 1984; Sweet and Soreghan 2010). Flexural slip along bedding planes associated with these structures could conceivably have produced high-stress textures on syntectonic grains; however, no slip indicators (e.g., slickensides) have been recognized on bedding surfaces in the study area. Late Paleozoic movement on the Ute Pass fault might also have produced high-stress textures on grains in the fault zone, which could have then been incorporated into the depositional system wherever the Ute Pass fault plane breached the surface. However, such grains eroding from the fault zone represent a very small volume relative to the entire system, such that production of high-stress features in this manner should be quite rare overall. More importantly, Sweet and Soreghan (2010) demonstrated that the Ute Pass fault was inactive and thus buried by the time of deposition of the upper Fountain Formation, yet this upper unit contains grains exhibiting high-stress microtextures. Therefore, a structural genesis for JSR COLD-CLIMATE WEATHERING IN EQUATORIAL PANGEA 671 FIG. 4.—SEM images of a variety of microtextures from quartz sand grains from the Fountain Formation. A) Well-rounded quartz grain recovered from marine shoreface facies. This grain displays numerous randomly oriented v-shaped cracks (vc; only a few highlighted for clarity) and is coated with turtle-skin silica and local authigenic clay minerals. B) Angular quartz grain displaying high-relief, subparallel linear fractures (lf) and a deep trough (dt). C) Straight grooves (sg) on a fracture face. D) Straight grooves (sg) and linear steps (ls). A euhedral quartz overgrowth (ov) has formed at the terminus of the grooves. E) Irregularly shaped grain displaying highrelief and arc-shaped steps (as). Grain surface is coated with turtle-skin silica, local clay minerals, and mica grain. F) Fractured grain surface covered with turtle-skin silica displaying remnant crescentic gouges (cg). G) Fracture face (ff) on grain surface shows evidence for edge rounding (er) fracturing including v-shaped cracks (vc). H) Mechanically upturned plate (mup) on grain surface with local pockets of quartz precipitation (qp) on upturned plate. I) Well-rounded grain recovered from marine shoreface facies showing randomly oriented v-shaped cracks (vc). high-stress microtextures recorded in the Fountain Formation is untenable as an explanation for the majority of the grains affected. Most of the Fountain Formation data plot between published data from glacially influenced Quaternary sediments (i.e., till and glaciofluvial) and Devonian fluvial sandstone (Mahaney and Kalm 2000). This observation suggests that the majority of the Fountain Formation samples exhibit a high-stress microtexture occurrence suggestive of glacially influenced sediments (Fig. 6). Accordingly, these high-stress fractures are inferred to be the result of glacial transport, most likely from upland glaciation in the ancestral Ute Pass uplift. However, the samples 672 D.E. SWEET AND G.S. SOREGHAN JSR FIG. 5.—Comparison of SEM microtexture frequency of: A) quartz grains from marine facies; B) quartz grains from debris-flow facies; C) quartz grains from fluvial facies; D) quartz grains from the lower Fountain Formation; E) quartz grains from the middle Fountain Formation; F) quartz grains from the upper Fountain Formation. Quartz grains that exhibited complete diagenetic overprint were not used in the analysis. Percentage values represent the total number of grains in each sample that exhibited the particular microtexture relative to the total grains in the sample. also exhibit percussion fracturing suggesting that grains were entrained fluvially, and in some cases transported to the marine environment, after initial glacial transport. Because the majority of samples exhibit a higher frequency of high-stress fractures than glaciofluvial sediments, it is possible that the Fountain Formation grains were transported a relatively short distance such that high-stress fractures survived complete overprinting in the fluvial environment. In summary, the overall suite of fractures exhibited on grain surfaces is best characterized by a glacially produced high-stress component and a glaciofluvially produced percussion component. In the most distal reaches of the depositional system, marine and nearshore eolian process probably account for some of the percussion fracturing. A plot of relative abundance of high-stress fractures versus stratigraphic level shows two peaks of 22 and 31% with intervening minima of 0% and 4% (Fig. 7). These peaks deviate from the average of 14% with a standard deviation of 8.3, thus these peaks are larger than or equal to 1s. The stratigraphic extent of these peaks is not well constrained due to sample spacing, thus true maximums are unconstrained. Furthermore, timing and duration of the peaks are limited. Nevertheless, the existence of these peaks indicates stratigraphic levels marked by a significant occurrence of high-stress microtextures. Because the microtextures are inferred as glacial in origin, we suggest that the peaks record periods of upland glaciation or perhaps immediate postglacial times, depending on the lag time until final deposition. The majority of samples exhibit highstress microtextures, which could be interpreted to reflect nearly constant presence of ice atop the Ute Pass uplift during deposition of the Fountain Formation. However, given the episodic nature of glaciation, the peaks could approximate presence of ice and the intervening low high-stress intervals could reflect recycling of grains, as discussed below. JSR COLD-CLIMATE WEATHERING IN EQUATORIAL PANGEA 673 FIG. 6.—Ternary diagram illustrating the relative abundances of polygenetic, high-stress, and percussion fractures. Percentages represent the summation of times that microtextures in their respective group (polygenetic, high stress, and percussion) were counted relative to the total counts of mechanical microtextures for the entire sample. Solid black dots are samples used in this study. Each sample consists of 10–32 quartz grains, and the percentage of microtextural occurrence is read from the corresponding axis. Open circle is the average of all samples, consisting of 234 quartz grains. Quartz grains that exhibited complete diagenetic overprint were not used. Polygenetic fracture apex includes fracture faces, subparallel linear fractures, conchoidal fractures, arc-shaped steps, linear steps, and breakage blocks. High-stress fracture apex includes curved grooves, straight grooves, deep troughs, and mechanically upturned plates. Percussion fracture apex includes randomly oriented v-shaped cracks and edge rounding. Note that the data from this study (black circles) are displaced from the polygenetic–percussion join towards the highstress apex. Mahaney and Kalm (2000) and Mahaney et al. (1996) points are a summation of all samples within respective studies: open triangle 5 , 575 quartz grains; black triangle 5 , 350 quartz grains, black cross 5 , 75 quartz grains, , 450 quartz grains. ADDITIONAL EVIDENCE FOR LATE PALEOZOIC EQUATORIAL GLACIATION If SEM microtextural data in the Fountain Formation suggests glacially influenced sediments, then additional evidence consistent with glacial outwash and periodic cool climate should also occur. Indeed, areally extensive, polygonally fractured bedding surfaces occur in at least two discrete stratigraphic intervals of the Fountain Formation (Sweet and Soreghan 2008). These surfaces are inferred to represent thermal contraction of frozen ground and indicate anomalously cool conditions for those times. In addition, one of the most volumetrically significant facies in the entire succession is hyperconcentrated-flood-flow deposits (Sweet and Soreghan 2010). These flood deposits indicate that the system contained abundant water and loose sediment, conditions consistent with proglacial deposition (e.g., Maizels 1993, 1997; Marren 2002). Furthermore, the cobbles of the Fountain Formation are overwhelmingly faceted, a shape more typical of glacial processes, albeit nondiagnostic in isolation. Glacial striae on bedrock or cobbles are often associated with late Paleozoic Gondwanan glacial deposits and commonly considered the ‘‘gold standard’’ in demonstrating the presence of glaciation. Yet, Dowdeswell et al. (1985) demonstrated that the presence of striae in (modern) glacial till varies greatly (, 3% to 65% of clasts), dependent upon lithology. No striae, other than those observed through SEM on grain surfaces, have been observed on Fountain Formation cobbles or subjacent granitic bedrock. However, such macrostriae would be unlikely to be preserved in the Ute Pass uplift bedrock owing to overprinting by Laramide uplift and modern erosion. Furthermore, Fountain Formation cobbles are predominantly coarse-grained granite of the Ute Pass uplift (Trimble and Machette 1979), lithologic types that typically do not yield striae (Dowdeswell et al. 1985). Hence, in such cases, where lithologic control may negatively affect preservation of macrostriae, the use of SEM-based microtextural analyses may be particularly useful in attempting to discern a possible glacial influence on sedimentation. Regionally, evidence for Permo-Pennsylvanian glaciation within equatorial Pangea has been suggested. Soreghan et al. (2009) reinterpreted the Permo-Pennsylvanian Cutler Formation—coarse clastic strata shed from the Uncompahgre uplift—as a product of proglacial deposition, evinced by the presence of features such as dropstones, faceted clasts, and abundant deposits of hyperconcentrated flood flows and large-magnitude floods. Furthermore, Soreghan et al. (2008a, b) inferred late Paleozoic glaciation in western equatorial Pangea on the basis of evidence for a Paleozoic, glacially carved landscape (Unaweep Canyon) and widespread loess deposits of this age. D’Orsay and van de Poll (1985) documented microtextures on quartz grains that they suggested are indicative of glacial transport in the Pennsylvanian Parrsboro Formation of Nova Scotia. All of these studies provide corroborative evidence for the existence of upland glaciation in the late Paleozoic highlands of equatorial Pangea. TRANSPORT DISTANCE AND CONSTRAINTS ON ICE-TERMINUS ELEVATION Glacial meltwater streams should contain a component of grains with high-stress fractures imparted during previous glacial transport. Indeed, Jackson (1996) recognized that, under conditions of low discharge, low velocity, and short transport distances (, 1 km) v-shaped cracks developed atop high-stress microtextures that formed during earlier glacial transport. Thus, fluvial transport will overprint high-stress glacial fractures, but no systematic studies have assessed the fluvial transport distance or other variables necessary to completely obliterate the glacial signal. The Ute Pass uplift was , 70 km wide, which constrains the maximum transport distance for the sediments in the Fountain depositional system. However, because the Ute Pass uplift was structurally bounded on only its northeast margin (Kluth and McCreary 2006; Sweet and Soreghan 2010), the uplift was likely asymmetric, with the topographic crest closer to the faulted margin; hence, transport distances were likely , 35 km (Figs. 1, 8). Stream gradients in glacial systems are quite variable. Exceptionally high gradients commonly prevail proximal to ice hosted on crystalline bedrock, but decrease to gradients of 0.1–0.01 within a few kilometers of the ice terminus, such that most upland systems typically approach 0.05 within 20 km (Table 2). These admittedly broad constraints on stream gradients and transport distances provide a means to estimate the 674 D.E. SWEET AND G.S. SOREGHAN JSR elevation of the ice terminus (Fig. 8). Using a stream gradient of 0.05 and maximum transport distance of 30 km, the estimated ice elevation was 1500 m (Fig. 8) above sea level because the lower and middle Fountain Formation were deposited essentially at sea level, as evidenced by intercalated marine strata (Suttner et al. 1984; Maples and Suttner 1990). However, as Figure 8 shows, selection of a different gradient or transport distance results in quite variable estimates of ice elevation; even given such variation, however, it is unlikely that the elevation of the ice terminus exceeded 3000 m. The upper Fountain Formation, however, lacks intercalated marine strata proximal to the Ute Pass uplift such that arguments relying on stream gradient and transport distance constrain relief only above the elevation of the Fountain depositional slope. Theoretically, glacial ice can occur at any elevation on Earth given a high enough accumulation-to-ablation ratio. During the last glacial maximum (LGM), terminal moraines in equatorial settings reached elevations of 2300–3400 m in Africa (Hastenrath 2009), and the equilibrium line altitude is estimated at 3400 m in the Andes (Lachniet and Vazquez-Selem 2005). Elevation differences reflect local ablation and accumulation conditions. The proposed maximum elevation of 3000 m for the ice terminus of the ancestral Ute Pass uplift (Fig. 8) is within the upper extent of these ranges, but 3000 m is a probable maximum, and elevations may have been significantly lower. Thus, the climatic conditions producing ice in the ancestral Ute Pass uplift were either much colder, or wetter, or both relative to LGM equatorial conditions. Soreghan et al. (2008a) have suggested that ice reached elevations of 1000–1500 m in the Uncompahgre uplift of the ancestral Rocky Mountains, a finding consistent with these results. STRATIGRAPHIC DISTRIBUTION OF INFERRED COLD-WEATHERING PULSES FIG. 7.—Plot of relative abundance of high-stress fractures with stratigraphic position. Quartz grains that exhibited complete diagenetic overprint were not used in the analysis. Relative abundances were estimated by summing all grains that exhibited high-stress fractures within the sample versus the total number of grains that exhibited any mechanical microtextures within the same sample (shown as percentages). Lower (LFF), middle (MFF), and upper (UFF) part of the Fountain Formation are tectonostratigraphic units separated by intraformational unconformities (wavy lines) as defined by Sweet and Soreghan (2010). The labels I and II indicate maxima in frequency of occurrence in high-stress fractures. Constraining the temporal context of these data precisely is difficult owing to lack of absolute dates and the generally barren character of the strata. Age constraints consist of numerous conodonts recovered from marine beds housed in the lower Fountain Formation including Idiognathoides sinuatus (Suttner et al. 1984), which indicates an early Pennsylvanian conodont zone ranging from , 315–317 Ma (Davydov et al. 2004). These conodont-bearing strata occur approximately 75– 100 meters above base and were correlated using a series of unpublished measured sections (Fig. 7; Suttner, unpublished data). The lowest peak (I) in high-stress fractures resides in the middle Fountain Formation. However, the middle Fountain Formation is separated from the lower Fountain Formation by an intraformational unconformity of likely minimal duration (Fig. 9; Sweet and Soreghan 2010); nevertheless the biostratigraphic age control for the lower Fountain Formation yields an approximate age for the middle Fountain Formation. The estimated age for this interval is middle to late Atokan. Peak (I) is roughly coeval with bedding planes that contain polygonal fractures attributed to repeated cooling of frozen ground (Fig. 9; Sweet and Soreghan 2008). The upper Fountain Formation is late Virgilian to early Wolfcampian(?) in age FIG. 8.—Diagram showing the interpreted general structural relationship of the Ute Pass uplift and fan-delta depositional wedge during deposition of the lower and middle parts of the Fountain Formation. Location of cross section (A–A9) is shown in Figure 1. Variable x defines the distance from the Ute Pass crest to the northeastern structural margin and essentially estimates proglacial transport distance. Variable z is the elevation of ice as a function of x and stream gradient. Note that the Ute Pass uplift is , 70 km wide (Kluth and McCreary 2006; Sweet and Soreghan 2010). Inset: Estimates of ice elevation (z) as a function of a variety of x values and stream gradients. JSR COLD-CLIMATE WEATHERING IN EQUATORIAL PANGEA 675 TABLE 2.— Proglacial stream gradients of various upland glaciers. Glacier Name Bedrock type Location Average stream gradient from ice terminus to 10 km Nisqually Soule’ Franz Josef Agassiz Scott Herron Unnamed volcanic granite schist, gneiss and volcanics carbonate granite, volcanic and sedimentary granite and sedimentary volcanic Washington, USA Alaska, USA New Zealand Montana, USA Alaska, USA Alaska, USA Peru 0.1 0.06 0.12 0.09 0.02 0.02 0.08 0.03 n/a 0.08 0.05 0.01 0.01 0.06 0.02 n/a n/a n/a n/a 0.01 0.05 0.07 0.04 0.03 Average (Sweet and Soreghan 2010) and houses the upper (II) peak in high-stress fractures. This peak is also approximately coeval with the coldweathering polygonal fractures reported by Sweet and Soreghan (2008)(Fig. 9). The correspondence of peaks in high-stress fractures with other indicators of cold temperatures in the Fountain depositional system (Fig. 9) reinforces the interpretation of possible upland glaciation. Owing to the low-latitude paleoposition of the Fountain system, episodes of upland glaciation likely correlate to globally cold intervals. Recent work in late Paleozoic strata of the Gondwanan region has demonstrated pulses of glacially influenced sediments separated by inferred nonglacial sediments (Isbell et al. 2003; Fielding et al. 2008). The high-stress peaks (I and II) are broadly coeval with individual glacial episodes from high- Average stream gradient from ice terminus to 20 km Average stream gradient from ice terminus to 20 km latitude Pangea (Fig. 9), suggesting that anomalously cool episodes in equatorial Pangea may correspond with Gondwanan ice maxima. CONCLUSIONS SEM analysis of quartz grains from the Pennsylvanian–Early Permian(?) Fountain Formation demonstrates that glacial-transportrelated fracturing is preserved even through the mask of diagenetic overprinting. Transport-induced microtextures can be grouped into three categories based upon fracture mechanism: (1) high-stress fractures, such as troughs, grooves, and gouges obtained through sustained high shear stress; (2) percussion fractures, such as randomly oriented v-shaped cracks and edge rounding fracturing obtained through saltation and/or FIG. 9.—Chart of Fountain Formation climatic indicators compared to late Paleozoic glacial episodes. SEM microtextural data and polygonal fractures are placed within the respective tectonostratigraphic unit, but age control within the tectonostratigraphic units is crude. See Figure 7 caption for explanation of the calculation of high-stress microtextures percentages and definition of labels (I) and (II). Glacial episodes of: eastern Australia from Fielding et al. (2008), Gondwana from Isbell et al. (2003), and Siberia from Epshtyn (1981a, 1981b) and Chumakov (1994). Vertical lines denote time represented by intraformational unconformities. Time scale is from Gradstein et al. (2004) Ma 5 million years (megaannum). 676 D.E. SWEET AND G.S. SOREGHAN traction flow; and (3) polygenetic fractures, such as steps, conchoidal surfaces, and lineaments obtained in a variety of depositional environments and fracture processes. The nature and abundance of microtextures in the Fountain Formation show similarities to microtextures from Quaternary till and glaciofluvial sediments, suggesting genetic similarities, including an origin from sustained grain-to-grain shear stress in a glacial environment. The glacially imprinted quartz grains subsequently entered the proglacial environment and were subjected to predominantly percussion-related fracturing. The stratigraphic occurrence of high-stress (inferred glacial) fractures exhibit two peaks. Each peak is interpreted to record an interval of upland glaciation in the Ute Pass uplift. Residence time in the drainage basin may effectively time average the high-stress data such that quartz grains exhibiting high-stress fractures were delivered even during times of no upland ice. The complicating effects of crude age constraints in the Fountain Formation and the residence time of the sediments in the drainage basin preclude estimates of durations for the existence of upland glaciers. General constraints on transport distance and possible proglacial stream gradients suggest that the elevation of ice was most likely , 1500 m, although elevations up to 3000 m are possible given exceptionally steep stream gradients. Peak occurrences of high-stress fractures correlate with the presence of polygonally fractured paleosurfaces in the Fountain Formation that are inferred to reflect cold-temperature weathering. Age models for the Fountain Formation are crude, but geologic arguments allow the possibility that the peaks in high-stress fractures correlate with peak Gondwanan glaciations. Hence, these data support the hypothesis that equatorial Pangea was punctuated by anomalously cool conditions, as suggested by Soreghan et al. (2008a), Soreghan et al. (2008b), Soreghan et al. (2009), and Sweet and Soreghan (2008). SEM microtextural analysis may be useful to assess a glacial influence where ice-contact facies are lacking, even in strata that have undergone moderate burial. Furthermore, the use of the classification scheme and associated ternary plot developed here provides a means to assess such data in a semiquantitative manner. ACKNOWLEDGEMENTS This work formed part of D. Sweet’s PhD research and was funded in part by GSA graduate student research grants, Sigma Xi Grants-in-Aid of Research, Colorado Scientific Society Research Grant, J.D. Love Field Geology Fellowship, SEPM Presidential Fund student grant, and NSF grant # EAR-0230332 awarded to Soreghan. Constructive and helpful reviews by John Isbell, Martin Gibling, Eugene Rankey, and an anonymous reviewer greatly improved the manuscript. We thank P. Larson of the Sam Noble Electron Laboratory for Scanning Electron Microscopy technologic training, Z. Reches and M. Soreghan of the University of Oklahoma for numerous discussions, and B. Cardott of the Oklahoma Geological Survey for vitrinite reflectance. Lastly, We thank K. Schroeder of the Colorado Springs Parks Department for access and sampling permission of the study area. A Supplemental Table is available from JSR’s Data Archive, http://www.sepm. org/jsr/jsr_data_archive.asp. 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