7/8/2015 Reduce these to proper empirical formulas: C8H18 ______________ Na2C2O4 ______________ C7H12 ______________ CH3COOH ______________ C6H2CH3(NO2)3 ______________ C3H6N3(NO2)3 ______________ Practice Problems: Determine the empirical and molecular formulas for an unknown compound based on the information provided below: • Mass Composition Data from Elemental Analysis: • 51.28 % Carbon • 9.40 % Hydrogen • 27.35 % Oxygen • 11.97 % Nitrogen • Molar Mass from Mass Spectrometry Data: 234 g/mol Practice Problems: Determine the empirical and molecular formulas based on the information provided below: • 11.800 grams of an unknown sample containing only C, H, & N is found to have 7.200 g of carbon, & 4.198 g of nitrogen. • Molar Mass from Mass Spectrometry Data: 354.3 g/mol 1 7/8/2015 iClicker Participation Question: Predicting Solubility from Experimental Obsercations Consider the experimental observations below: Reaction 1 forms ppt.: MgCrO4(aq) + KF(aq) Reaction 2 does not form ppt.: NH4Cl(aq) + NaF(aq) Reaction 3 does not form ppt: (NH4)2CrO4(aq) + K2SO4(aq) A. F2CrO4(s) B. MgK2(s) C. K2CrO4(s) Based on these observations, what is the likely identity of the precipitate from Observation 1 above? D. MgF2(s) E. (NH4)2SO4(s) Practice Problems: Write the balanced chemical equations for the reactions below: • Combustion of butane, C4H10 • Combustion of sucrose, C12H22O11 • Aluminum metal reacts with manganese (IV) oxide to produce aluminum oxide and manganese metal • Ammonium phosphate reacts with iron (II) nitrate to produce a precipitate • Making potassium nitride from its component elements • Uranium (VI) fluoride reacts with magnesium metal Practice Problems: Write the decomposition for ammonium dichromate to produce nitrogen gas, water vapor and chromium (III) oxide. Hint: Dichromate = Cr2O72How many grams of ammonium dichromate would be needed to generate 400. grams of water from this decomposition? 2 7/8/2015 Stoichiometry Practice Problems: Write the balanced chemical equation describing copper (I) oxide reacting with carbon atoms to form copper metal and carbon dioxide. • How much copper metal could be produced from 100.0 grams of copper (I) oxide & 30. grams of carbon? 3
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