Zeroth Law of Thermodynamics Physics 2A Chapter 12 - 14: Heat Transfer & the Ideal Gas Zeroeth Law of Thermodynamics Thermal Expansion Unusual Behavior of Water Heat Convection Zeroth Law of Thermodynamics ⇒ If the zeroth law of thermodynamics were not true, than on object could have many different temperatures depending on what objects were in thermal equilibrium with it. How can we use object T as a thermometer? Measure some change in its physical properties. thermometric property ⇒ a physical property that changes with temperature T A T B A B zeroth law of thermodynamics ⇒ if bodies A and B are each in thermal equilibrium with a third body T, then they are in equilibrium with each other This allows us to define temperature as a property of an object and use T to measure temperature. Thermometers ⇒ For example, most gases, liquids, and solids expand when heated so their volume changes common thermometer ⇒ temperature measured by looking at changes in the volume of mercury or alcohol ⇒ thermometers are calibrated by placing them in thermal contact with objects at two calibration temperatures, usually the ice point (0 oC) and the steam point (100 oC) 1 Thermal Expansion Thermal Expansion ⇒ Extreme heat caused these railroad tracks to buckle ⇒ To compensate for thermal expansion, bridges have expansion joints and one end of the bridge rides on rockers (the other end is fixed). because of thermal expansion. The Unusual Behavior of Water The Unusual Behavior of Water ⇒ Although most materials expand when heated, a few do not. ⇒ For example, if water at 0oC is heated, its volume actually decreases until its temperature reaches 4oC. ⇒ Above 4oC water behaves normally, and its volume increases as the temperature increases. ⇒ The unusual behavior of water is very important to ⇒ As the temperature of water decreases below 4oC, the aquatic life on this planet. Why? volume of water increases so the density of water decreases. 2 The Unusual Behavior of Water ⇒ Because of this, ice is less dense than water and therefore floats. Because of this, ponds and lakes freeze from the top down. ⇒ If water behaved like most liquids, its volume would decrease as its temperature decreased. Ice would then be more dense than water and would sink. ⇒ Bodies of water would then freeze from the bottom up and many bodies of water would remain frozen all year round – aquatic life as we know it could not exist! Heat ⇒ When hot and cold water are mixed together, they will eventually reach the same temperature. Energy is transferred from the hot object to the cold object. heat ⇒ energy transferred between objects because of a temperature difference Heat ⇒ Two objects are said to be in thermal contact if they can exchange heat. ⇒ Two objects in thermal contact will eventually reach thermal equilibrium. The flow of heat ceases because there is no temperature difference (they have reached the same temperature). 3 Convection Convection ⇒ When part of a fluid (liquid or gas) is warmed, such as the air above a fire, the volume of the fluid expands and therefore the density of the fluid decreases. ⇒ As the warmer fluid rises, the surrounding fluid replaces it. The cooler fluid, in turn, is warmed and pushed upward. ⇒ The surrounding fluid is cooler and more dense. ⇒ This process continues, and a continuous flow called a convection current is established, which transfers heat. ⇒ Because of this, the surrounding cooler fluid exerts a buoyant force on the warmer fluid and pushes it upward. convection ⇒ the process in which heat is carried from place to place by the bulk movement of a fluid. Convection Examples of Convection Currents ⇒ Because of convection, hot air rises and creates updrafts or thermals. 4
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