Chemical properties of the most massive evolved stars G. Quintana-Lacaci1, J. Cernicharo1, C. Sánchez-Contreras1, L.Velilla1, V.Bujarrabal2, J. Alcolea2, A. Castro-Carrizo3, D. Teyssier4, L. Decin5, J. Pearson6 CAB (INTA-CSIC), 2OAN (IGN), 3IRAM, 4ESAC, 5KUL, 6JPL 1 Sevilla 2012 What do we know? Molecular Emisison - RSGs VY Cma NaCl, PN, HNC, HCO+, AlO, AlOH,... ( Tenenbaum & Zyuris, 2010) NML Cyg, Betelgeuse CO (low-J, high-J), OH, H2O, SO, SiO, NH3, H2S,... (Teyssier et al. 2012) S Per, PZ Cas, µ Cep Low-J CO lines (Quintana-Lacaci et al. In prep) - YHGs IRC+10420 , AFGL 2343 CS, HCN, HNC, CN, SiS, SiO, HCO+,... (Quintana-Lacaci et al. 2007) What do we know? Structure: - RSGs NML Cyg VY Cma Betelgeuse S Per PZ Cas µ Cep spherical + outflows ?? spherical + outflows (Muller et al. 2006) spherical (Castro-Carrizo et al.) spherical (Quintana-Lacaci et al. prep) hourglass (Quintana-Lacaci et al.prep) hourglass ?? - YHGs IRC+10420 , AFGL 2343 Spherical + shocks (Castro-Carrizo et al. 2007, Quintana-Lacaci et al. 2008) What do we expect? C/O ratio Chemistry: a) CNO + HBB + dredge up M* < 1.4 M⊙ 1.5 M⊙ < M*< 3 M⊙ 3 M⊙ < M * b) NeNa cycle O-rich and N-rich chemistry O-rich chemistry C-rich chemistry N-rich chemistry K, Mg, Na c) Shock-induced chemistry d) Photo-induced chemistry for YHGs Chemistry in the RSGs: VY CMa Best studied RGS NaCl, PN, HNC, HCO+, AlO, AlOH,... ( Tenenbaum & Zyuris, 2010) Muller et al. 2007 Chemistry in the RSGs: VY CMa IRAM 30m Radiotelescope: Band Freqs (GHz) Status 3mm 83 – 117 Ongoing 2mm 129 – 174 Ongoing 1mm 202 – 274 Ongoing 0.8mm 277 – 358 Ongoing HIFI Band Freqs (GHz) Band Freqs (GHz) 1b 554.5 – 636.5 5a 1108.1 – 1224.0 2a 626.0 – 726.0 6a 1446.2 – 1562.9 3a 799.0 – 856.0 6b 1573.4 – 1702.9 4a 949.0 – 1060.0 7a 1696.4 – 1798.9 4b 1046.6 – 1122.0 7b 1788.5 – 1906.9 Chemistry in the RSGs: VY CMa Chemistry in the RSGs: VY CMa Chemistry in the RSGs: VY CMa Chemistry in the RSGs: VY CMa ~ 1200 lines 52 species identified 12 CO, 13CO, C18O H2O, H218O, H217O, OH SiO, 30SiO, 29SiO, Si17O, Si18O SO2, 34SO2, 33SO2, SO18O, SO17O NaCl, Na37Cl NS, NH3 AlO, AlOH, AlCl HCO+,CH3OH, CS, TiO SO, 34SO, 33SO SiS, 30SiS, 29 SiS, Si34S, Si33S, SiN PN, PO, CCP, 13CCP HCl, H37Cl HCN, H13CN, HNC, CN H2CO, H2C18O H2S, H233S Chemistry in the YHGs: IRC+10420 Prototypical YHG star 1D LVG already used to model IRC+10420 Emission (Teyssier, Quintana-Lacaci et al. 2012) CS, HCN, HNC, CN, SiS, SiO, HCO+,... (Quintana-Lacaci et al. 2007) Chemistry in the YHGs: IRC+10420 Prototypical YHG star 1D LVG already used to model IRC+10420 Emission (Teyssier, Quintana-Lacaci et al. 2012) CS, HCN, HNC, CN, SiS, SiO, HCO+,... (Quintana-Lacaci et al. 2007) No refractory materials Chemistry in the YHGs: IRC+10420 IRAM 30m Radiotelescope: Band Freqs (GHz) Status 3mm 83 – 116.3 reduced 1mm 199.1 – 258.8 reduced Band Freqs (GHz) Status 2mm 202 – 274 Granted 0.8mm 277 – 358 Granted HIFI CO, H2O, OH, 13CO, NH3 Chemistry in the YHGs: IRC+10420 Chemistry in the YHGs: IRC+10420 Chemistry in the YHGs: IRC+10420 12 CO, 13CO, C18O, H2O SO, 34SO, SO2 SiO, 30SiO, 29SiO, SiS, 29SiS CS, C2S HCN, H13CN, HNC, HC3N , CN HCO+ N2H+ CH3OH NO, NS, PN NH3, OH NO, N2H+ OH+231.8 L. Velilla Poster C-rich Massive stars? C-rich stars with high expansion velocity (HVC stars) High expasion velocity High luminosity Dust to gas ratio High HCN abundance C-rich + N-rich Maser Marigo (2008) Under certain conditions HBB stops!! C abundance will raise again These objects might exist C-rich Massive stars? Structure IRC+10401 AFGL2233 C-rich Massive stars? Structure AFGL2233 HVC AFGL2343 YHG HVCs Conclusions - Massive evolved stars show extremely rich chemistry. IRC+10420: O-rich, N-rich, Shocks, PDR VY Cma: O-rich, N-rich, Shocks, Grain formation zone HVCs: C-rich, N-rich O-rich - C-rich Conclusions - Massive evolved stars show extremely rich chemistry. IRC+10420: N-rich, Shocks, PDR VY Cma: O-rich, N-rich, Shocks, Grain formation zone HVCs: C-rich, N-rich O-rich N-rich C-rich
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