How Do You Hold a Molecule? - the element & its bonding - Carbon is the sixth element. Its most common isotope has an atomic mass of 12 amu. This means it contains 6 protons, 6 neutrons and 6 electrons. C14 is radioactive. It is used in carbon dating, and it has 2 extra neutrons. 1 1 18 2 1.0079 H HYDROGEN 3 6.941 Li LITHIUM 11 22.990 9.0122 12 39.098 37 85.468 20 40.078 Ca CALCIUM 38 87.62 44.956 4 22 47.867 87 (223) Fr FRANCIUM 88 (226) Ra RADIUM 63.546 12 30 C CARBON 14 26.982 65.39 Cr Mn Fe Co Ni Cu Zn MANGANESE IRON COBALT NICKEL COPPER ZINC 39 88.906 40 91.224 57-71 La-Lu Lanthanide 72 41 92.906 42 95.94 73 178.49 180.95 MOLYBDENUM 43 (98) 74 183.84 47 107.87 48 112.41 49 Cd In SILVER CADMIUM INDIUM 75 76 186.21 Re RHENIUM 107 (264) 190.23 77 108 (277) 192.22 Ir Os OSMIUM IRIDIUM 109 (268) 78 195.08 79 196.97 Pt Au PLATINUM GOLD 110 (281) 111 80 200.59 Hg MERCURY (272) 112 81 14.007 72.64 N NITROGEN 15 30.974 33 10 20.180 F Ne FLUORINE NEON 16 32.065 17 34 78.96 35.453 18 39.948 Cl Ar CHLORINE ARGON S SULPHUR 35 79.904 36 83.80 As Se Br Kr SELENIUM BROMINE KRYPTON 118.71 51 207.2 114 121.76 Sb ANTIMONY 83 Pb LEAD (285) 18.998 O ARSENIC 82 204.38 HELIUM Ge TIN Tl 74.922 15.999 17 9 OXYGEN P PHOSPHORUS Sn THALLIUM 16 8 GERMANIUM 50 114.82 Ag W (266) 106.42 Pd TUNGSTEN 106 46 PALLADIUM Ta (262) 102.91 Rh RHODIUM TANTALUM 105 45 Ru Hf (261) 101.07 32 69.723 Ga RUTHENIUM HAFNIUM 89-103 104 44 SILICON GALLIUM TECHNETIUM Nb Mo NIOBIUM 31 28.086 15 7 Si ALUMINIUM CHROMIUM Zr 137.33 58.693 11 29 V ZIRCONIUM Ba 58.933 10 28 VANADIUM Y BARIUM 55.845 9 27 Ti YTTRIUM 56 54.938 8 26 TITANIUM Sr 132.91 51.996 7 25 Sc STRONTIUM Cs 50.942 6 24 SCANDIUM Rb CAESIUM 5 23 12.011 B Al 3 21 RUBIDIUM 55 14 6 BORON 13 24.305 Mg MAGNESIUM K 10.811 Be Na POTASSIUM 13 5 BERYLLIUM SODIUM 19 4.0026 He 2 4 208.98 52 127.60 53 84 (209) 126.90 54 131.29 I Xe IODINE XENON Te TELLURIUM 85 (210) 86 (222) Bi Po At Rn BISMUTH POLONIUM ASTATINE RADON 69 70 (289) Ac-Lr Actinide DUBNIUM RUTHERFORDIUM SEABORGIUM BOHRIUM HASSIUM MEITNERIUM UNUNNILIUM UNUNUNIUM UNUNBIUM 63 65 UNUNQUADIUM LANTHANIDE 57 138.91 58 140.12 59 140.91 60 144.24 La Ce Pr Nd LANTHANUM CERIUM PRASEODYMIUM NEODYMIUM 61 (145) 62 150.36 Sm PROMETHIUM SAMARIUM 151.96 Eu EUROPIUM 64 157.25 158.93 66 67 162.50 164.93 68 167.26 Gd Tb Dy Ho Er GADOLINIUM TERBIUM DYSPROSIUM HOLMIUM ERBIUM 168.93 Tm THULIUM 173.04 71 174.97 Yb Lu YTTERBIUM LUTETIUM ACTINIDE 89 (227) 90 232.04 Ac Th ACTINIUM THORIUM 91 231.04 Pa PROTACTINIUM 92 238.03 93 (237) 94 (244) 95 (243) 96 (247) 97 (247) 98 99 (251) (252) 100 (257) 101 (258) 102 (259) 103 (262) U URANIUM NEPTUNIUM PLUTONIUM AMERICIUM CURIUM BERKELIUM CALIFORNIUM EINSTEINIUM FERMIUM MENDELEVIUM NOBELIUM LAWRENCIUM The four electrons in the outer shell of the carbon atom (1s and 3p) can exist in three different configurations (hybridisation states) 2s 2p 2s 2p formal electronic state actual electronic state x 4 equivalent sp3 y z 3 equivalent sp2 2 equivalent sp 2pz 2pz 2py o 109 o 120 90 e.g. diamond, methane, paraffin e.g. graphite, fullerene, nanotube & benzene o e.g. carbon dioxide, cyanide & acetylene Depending on hybridisation, a C-atom can form either four (sp3), three (sp2) or two bonds (sp) with other atoms: sp3 hybridisation sp2 hybridisation sp hybridisation All four valence electrons of carbon are locked in four chemical bonds Three valence electrons are locked in chemical bonds and one can be delocalised within the molecule Two valence electrons are locked in chemical bonds and two can be delocalised within the molecule © 2008 University of Nottingham. All rights reserved. Permission is granted to make copies of this document for educational purposes only, provided that this copyright notice is reproduced in full. Carbon, C 1 Contact Information: www.nottingham.ac.uk/nanocarbon www.qipirc.org Design by Dan Marsh, 2008
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