Mechanism of Carbylamine reaction
Carbylamine reaction
When a primary amine ( Aliphatic or Aromatic ) is warmed with chloroform or alcoholic KOH it forms
an isocynide or carbylamines having offensive smell. This reaction is called carbylamines reaction .
Reaction
1. CH3CH2NH2 + CHCl3 + 3KOH
Ethyl Amine
alcoholic
CH3CH2NC + 3KCl + 3H2O
Ethyl isocyanide
+
N
NH2
CH
+ CHCl3 + 3KOH
2.
Aniline
+ 3KCl + 3H2O
Phenyl isocyanide
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