SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Lead (II) Chromate PRODUCT NUMBER: 2227 CAS NUMBER: 7758-97-6 MANUFACTURER: Prochem, Inc. 826 Roosevelt Road Rockford, IL 61109 PHONE: FAX: TOLL FREE: 815-398-1788 815-398-1810 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Danger Signal Word Hazard Statements H315 H320 H335 H350 H360 H373 H400 H411 Causes skin irritation Causes eye irritation May cause respiratory irritation May cause cancer May damage fertility or the unborn child May cause damage to organs through prolonged or repeated exposure Very toxic to aquatic life Toxic to aquatic life with long lasting effects Precautionary Phrases P201 P273 P308 + P313 Obtain special instructions before use Avoid release to the environment IF exposed or concerned: Get medical/attention HMIS CLASSIFICATION: Health: 0 Flammability: 3 NFPA RATING: Health: 0 Fire: 0 Physical Hazard: 3 Reactivity Hazard: 0 EYE CONTACT: Causes irritation of the eyes. SKIN CONTACT: Causes skin irritation. LEAD (II) C HROMATE PAGE 1 SECTION 2 HAZARDS IDENTIFICATION (Cont.) INHALATION: May cause irritation to the respiratory tract. INGESTION: May cause gastrointestinal irritation with nausea, vomiting, and diarrhea. Can cause toxic effects in the blood-forming organs, kidneys, and central nervous system. May be harmful if swallowed. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: PbCrO4 Molecular Weight: 323.22 CHEMICAL NAME CAS# Lead (II) Chromate SECTION 4 % 7758-97-6 TWA 100 0.05 mg/m 3 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Immediately flush with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. INHALATION: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. Give oxygen if deemed necessary. Get immediately medical attention. INGESTION: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical attention immediately. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Not flammable or combustible AUTO IGNITION TEMPERATURE: No data EXPLOSION LIMITS: No data EXTINGUISHING MEDIUM: Use water only. Cool containers with flooding quantities of water. Do NOT use dry chemicals or foam. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus that is NIOSH approved. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Lead oxides and chromium oxides SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear appropriate respiratory and protective equipment to avoid all exposure to with the material. ENVIRONMENTAL PRECAUTIONS: Do not let enter drains or allow to be released into environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Avoid generating dust. Ensure adequate ventilation. Carefully pick up material and place in a clean dry container and cover for disposal. Keep spilled material away from combustibles. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Avoid contact with skin. Avoid formation of dust. Wear proper protective equipment. Ensure adequate ventilation. CONDITIONS FOR SAFE STORAGE: Store in a tightly sealed container. Store in cool, dry, and well-ventilated conditions. Store away from combustibles. Store away from incompatible materials. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION Components Lead Chromate LEAD (II) C HROMATE CAS# 7758-97-6 Value TWA TWA TWA CEIL CEIL TWA Control Parameters 3 0.012 mg/m 3 0.05 mg/m 3 0.0050 mg/m 3 0.0010 mg/m 3 0.1 mg/m 3 0.075 mg/m Basis USA.ACGIH (TLV) USA.ACGIH (TLV) USA (OSHA) USA (OSHA) USA (OSHA) USA (OSHA) PAGE 2 SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION (Cont.) EYE PROTECTION: Always wear approved safety glasses with side shields, or safety goggles, face shield when handling a chemical substance in the laboratory. SKIN PROTECTION: Chemical resistant gloves. VENTILATION: Handle in an efficient chemical fume hood. RESPIRATOR: Approved NIOSH dust respirator. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: Yellow to Orange Powder MOLECULAR WEIGHT: 323.1936 BOILING POINT: Decomposition MELTING POINT: 844° C SPECIFIC GRAVITY: 6.123 gm/ml VAPOR PRESSURE: Not applicable SOLUBILITY: Insoluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Dust generation and excess heat. INCOMPATIBILITY: Reducing agents, active metals, hydrazine, potassium, hydrogen peroxide, sodium, azodye stuffs, sulfur tantalum, iron (III) hexacyanoferrate (4-) DECOMPOSITION PRODUCTS: Lead oxides and chromium oxides SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: LD50 Oral – mouse - > 12,000 mg/kg CARCINOGENIC EFFECTS: Carcinogenicity – rat - Intramuscular. Tumorigenic: Neoplastic by RTECS criteria. Kidney, ureter, bladder, kidney tumors. Tumorigenic: Tumors at site or application. Carcinogenicity – rat – Subcutaneous. Tumorigenic: Neoplastic by RTECS criteria. Tumorigenic: Tumors at site of application. Carcinogenicity – rat – Subcutaneous. Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Tumorigenic: Tumors at site or application. Human Carcinogen. IARC: 1-Group 1: Carcinogenic to humans (Lead chromate). 2A- Group 2A: Probably carcinogenic to humans. NTP: Known to be human carcinogen (Lead chromate). Reasonably anticipated to be a human carcinogen. Known to be human carcinogen. OSHA: 1910.1025 (Lead chromate) MUTAGENIC EFFECTS: No data TETRATOGENIC EFFECTS: Known human reproductive toxicant RTECS: GB2975000 To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA Chromium in soil can be transported to the atmosphere by way of aerosol formation. Chromium is also transported from soil through runoff and leaking of water. Runoff could remove both chromium ions and bulk precipitates of chromium, with final deposition on either a different land area or a water bod. Chromium is removed from air through wet and dry depositions. Terrestrial Fate: Lead in soil is relatively immobile and can persist for long periods of time, whether added to the soil as halides, hydroxides, oxides, carbonates, and sulfates. LEAD (II) C HROMATE PAGE 3 SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. SECTION 14 TRANSPORTATION DATA UN1479 Oxidizing solid, n.o.s. (Lead Chromate) Class 5.1 PG II SECTION 15 REGULATORY INFORMATION SARA 302 COMPONENTS: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA (TITLE 313): Lead Chromate SARA 311/312: Chronic Health Hazard MASSACHUSETTS RIGHT TO KNOW: Lead Chromate PENNSYLVANIA RIGHT TO KNOW: Lead Chromate NEW JERSEY RIGHT TO KNOW: Lead Chromate CALFORNIA PROP. 65: WARNING! This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 06/14 LEAD (II) CHROMATE PAGE 3
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