SECTION 1 PRODUCT AND COMPANY INFORMATION Lead (II

 SECTION 1
PRODUCT AND COMPANY INFORMATION
PRODUCT NAME:
Lead (II) Chromate
PRODUCT NUMBER:
2227
CAS NUMBER:
7758-97-6
MANUFACTURER:
Prochem, Inc.
826 Roosevelt Road
Rockford, IL 61109
PHONE:
FAX:
TOLL FREE:
815-398-1788
815-398-1810
800-795-8788
IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300
SECTION 2
HAZARDS IDENTIFICATION
CLASSIFICATION OF SUBSTANCE OR MIXTURE
Pictogram
Danger
Signal Word
Hazard Statements
H315
H320
H335
H350
H360
H373
H400
H411
Causes skin irritation
Causes eye irritation
May cause respiratory irritation
May cause cancer
May damage fertility or the unborn child
May cause damage to organs through prolonged or repeated exposure
Very toxic to aquatic life
Toxic to aquatic life with long lasting effects
Precautionary Phrases
P201
P273
P308 + P313
Obtain special instructions before use
Avoid release to the environment
IF exposed or concerned: Get medical/attention
HMIS CLASSIFICATION:
Health: 0
Flammability: 3
NFPA RATING:
Health: 0
Fire: 0
Physical Hazard: 3
Reactivity Hazard: 0
EYE CONTACT: Causes irritation of the eyes.
SKIN CONTACT: Causes skin irritation. LEAD (II) C HROMATE PAGE 1 SECTION 2
HAZARDS IDENTIFICATION (Cont.)
INHALATION: May cause irritation to the respiratory tract.
INGESTION: May cause gastrointestinal irritation with nausea, vomiting, and diarrhea. Can cause toxic effects in the blood-forming
organs, kidneys, and central nervous system. May be harmful if swallowed.
SECTION 3
COMPOSITION / INFORMATION ON INGREDIENTS
Formula: PbCrO4
Molecular Weight: 323.22
CHEMICAL NAME
CAS#
Lead (II) Chromate
SECTION 4
%
7758-97-6
TWA
100
0.05 mg/m
3
FIRST AID MEASURES
EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under
eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention.
SKIN EXPOSURE: Immediately flush with plenty of soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get immediate medical attention.
INHALATION: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
in breathing, coughing, wheezing, or pain. Give oxygen if deemed necessary. Get immediately medical attention.
INGESTION: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
SECTION 5
FIREFIGHTING MEASURES
FLASH POINT: Not flammable or combustible
AUTO IGNITION TEMPERATURE: No data
EXPLOSION LIMITS: No data
EXTINGUISHING MEDIUM: Use water only. Cool containers with flooding quantities of water. Do NOT use dry chemicals or foam.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus that is NIOSH approved.
HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Lead oxides and chromium oxides
SECTION 6
ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS: Wear appropriate respiratory and protective equipment to avoid all exposure to with the material.
ENVIRONMENTAL PRECAUTIONS: Do not let enter drains or allow to be released into environment.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Avoid generating dust. Ensure adequate ventilation.
Carefully pick up material and place in a clean dry container and cover for disposal. Keep spilled material away from combustibles.
SECTION 7
HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Avoid contact with skin. Avoid formation of dust. Wear proper protective equipment. Ensure
adequate ventilation.
CONDITIONS FOR SAFE STORAGE: Store in a tightly sealed container. Store in cool, dry, and well-ventilated conditions. Store away
from combustibles. Store away from incompatible materials.
SECTION 8
EXPOSURE CONTROLS AND PERSONAL PROTECTION
Components
Lead Chromate
LEAD (II) C HROMATE CAS#
7758-97-6
Value
TWA
TWA
TWA
CEIL
CEIL
TWA
Control Parameters
3
0.012 mg/m
3
0.05 mg/m
3
0.0050 mg/m
3
0.0010 mg/m
3
0.1 mg/m
3
0.075 mg/m
Basis
USA.ACGIH (TLV)
USA.ACGIH (TLV)
USA (OSHA)
USA (OSHA)
USA (OSHA)
USA (OSHA)
PAGE 2 SECTION 8
EXPOSURE CONTROLS AND PERSONAL PROTECTION (Cont.)
EYE PROTECTION: Always wear approved safety glasses with side shields, or safety goggles, face shield when handling a chemical
substance in the laboratory.
SKIN PROTECTION: Chemical resistant gloves.
VENTILATION: Handle in an efficient chemical fume hood.
RESPIRATOR: Approved NIOSH dust respirator.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
COLOR AND FORM: Yellow to Orange Powder
MOLECULAR WEIGHT: 323.1936
BOILING POINT: Decomposition
MELTING POINT: 844° C
SPECIFIC GRAVITY: 6.123 gm/ml
VAPOR PRESSURE: Not applicable
SOLUBILITY: Insoluble
SECTION 10
STABILITY AND REACTIVITY
STABILITY: Stable
HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID: Dust generation and excess heat.
INCOMPATIBILITY: Reducing agents, active metals, hydrazine, potassium, hydrogen peroxide, sodium, azodye stuffs, sulfur
tantalum, iron (III) hexacyanoferrate (4-)
DECOMPOSITION PRODUCTS: Lead oxides and chromium oxides
SECTION 11 TOXICOLOGICAL DATA
ACUTE TOXICITY: LD50 Oral – mouse - > 12,000 mg/kg
CARCINOGENIC EFFECTS: Carcinogenicity – rat - Intramuscular. Tumorigenic: Neoplastic by RTECS criteria. Kidney, ureter,
bladder, kidney tumors. Tumorigenic: Tumors at site or application. Carcinogenicity – rat – Subcutaneous. Tumorigenic: Neoplastic by
RTECS criteria. Tumorigenic: Tumors at site of application. Carcinogenicity – rat – Subcutaneous. Tumorigenic: Equivocal
tumorigenic agent by RTECS criteria. Tumorigenic: Tumors at site or application. Human Carcinogen.
IARC: 1-Group 1: Carcinogenic to humans (Lead chromate). 2A- Group 2A: Probably carcinogenic to humans.
NTP: Known to be human carcinogen (Lead chromate). Reasonably anticipated to be a human carcinogen. Known to be human
carcinogen.
OSHA: 1910.1025 (Lead chromate)
MUTAGENIC EFFECTS: No data
TETRATOGENIC EFFECTS: Known human reproductive toxicant
RTECS: GB2975000
To the best of our knowledge the toxicological effects of this compound have not been fully investigated.
SECTION 12
ECOLOGICAL DATA
Chromium in soil can be transported to the atmosphere by way of aerosol formation. Chromium is also transported from soil through
runoff and leaking of water. Runoff could remove both chromium ions and bulk precipitates of chromium, with final deposition on either
a different land area or a water bod. Chromium is removed from air through wet and dry depositions. Terrestrial Fate: Lead in soil is
relatively immobile and can persist for long periods of time, whether added to the soil as halides, hydroxides, oxides, carbonates, and
sulfates.
LEAD (II) C HROMATE PAGE 3 SECTION 13
DISPOSAL CONSIDERATIONS
Dispose of in according to local, state, and federal regulations.
SECTION 14
TRANSPORTATION DATA
UN1479
Oxidizing solid, n.o.s. (Lead Chromate)
Class 5.1
PG II
SECTION 15
REGULATORY INFORMATION
SARA 302 COMPONENTS: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA (TITLE 313): Lead Chromate
SARA 311/312: Chronic Health Hazard
MASSACHUSETTS RIGHT TO KNOW: Lead Chromate
PENNSYLVANIA RIGHT TO KNOW: Lead Chromate
NEW JERSEY RIGHT TO KNOW: Lead Chromate
CALFORNIA PROP. 65: WARNING! This product contains a chemical known to the State of California to cause cancer, birth defects,
or other reproductive harm.
SECTION 16
OTHER INFORMATION
DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc.
makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the
product based on the information.
DATE PREPARED: 06/14
LEAD (II) CHROMATE PAGE 3