Ambient Air Monitoring Network Plan 2012 This document, a description of the New Jersey Ambient Air Monitoring Network for 2012, is available for public comment. Please e-mail public comments by June 29, 2012 to [email protected],or write to: Chief, Bureau of Air Monitoring New Jersey Department of Environmental Protection Mail Code: 401-07H PO Box 420 Trenton, NJ 08625-0420. NEW JERSEY DEPARTMENT OF ENVIRONMENTAL PROTECTION Bureau of Air Monitoring WWW.NJAQINOW.NET June 2012 Table of Contents Section Page Number EXECUTIVE SUMMARY 3 INTRODUCTION 3 NETWORK DESIGN 4 SITE SELECTION OF NEAR-ROADWAY NO2 STATION 9 MONITORING SITE DESCRIPTION OF NEAR-ROADWAY NO2 STATION 14 THE NEW JERSEY MONITORING NETWORK 15 CHANGES TO THE NETWORK 18 NEW JERSEY AIR MONITORING SITE DESCRIPTIONS 19 GLOSSARY OF ABBREVIATIONS AND TERMS 62 REFERENCES 64 APPENDIX A: VOLATILE ORGANIC COMPOUNDS 65 APPENDIX B: CARBONYLS 67 APPENDIX C: PM2.5 SPECIATION 68 APPENDIX D: OZONE PRECURSORS 70 DISCLAIMER Mention of trade names, manufacturers or commercial products in this document does not constitute New Jersey Department of Environmental Protection endorsement or recommendation for use NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 2 EXECUTIVE SUMMARY As described in the following Ambient Air Monitoring Network Plan, the New Jersey Department of Environmental Protection (NJDEP) has established lead monitoring at the existing Newark Firehouse station, re-established a monitoring station in Camden City, and plans to establish a near-roadway monitoring station in Fort Lee by the end of 2012. In the last 2 years, the U.S. Environmental Protection Agency (USEPA) revised the health-based National Ambient Air Quality Standards (NAAQS) for nitrogen dioxide (NO2) and sulfur dioxide (SO2), and revised minimum requirements for the number and location of monitoring stations for carbon monoxide (CO), lead (Pb), NO2 and SO2 monitoring networks. For NO2, a new 1-hour average NAAQS was established at 100 parts per billion (ppb), and for SO2, a new 1-hour average NAAQS was established at 75 ppb. The revisions to the networks require the establishment of one new Pb monitoring location by January 2012, and a new near-roadway NO2 monitoring location by January 2013, but they allow a significant reduction in the number of monitoring stations that the NJDEP currently operates. The resources saved by further network reductions will be used to implement technology changes that will improve the value of the data and save on the resources needed to collect it, to monitor for new types of pollutants such as air toxics and indicators of diesel exhaust emissions, and to reduce or eliminate the manual sampling of particulates by investing in continuous particulate monitoring analyzers. INTRODUCTION In the Federal Register of October 17, 2006, the USEPA revised “Subpart B – Monitoring Network” of Part 58 – Ambient Surveillance Networks of Title 40 of the Code of Federal Regulations. Specifically, the NJDEP is required by the revised regulations to submit an Annual Monitoring Network Plan to the USEPA Region 2 Regional Administrator by July 1 of every year starting in 2007, and to have the Plan available for public inspection for at least 30 days prior to its submittal to the USEPA. The Plan should describe State and Local Air Monitoring Stations (SLAMS), National Core (NCore) stations, Speciation Trends Network (STN) stations, State speciation stations, Special Purpose Monitor (SPM) stations, and Photochemical Assessment Monitoring Stations (PAMS). The regulations also require the NJDEP to submit an assessment of its Air Monitoring Network every 5 years starting July 1, 2010 and to have all NCore multi-pollutant stations operational by January 1, 2011. This 2012 Network Plan contains all the information required by the regulations, along with an overview of air monitoring network concepts, descriptions of the air monitoring sites, large and small scale maps of the monitoring stations, and a summary of the changes to the Air Monitoring Network that the NJDEP expects to implement in the next two years. It is available for download from the Bureau of Air Monitoring’s website, www.njaqinow.net, or as a hardcopy by calling 609-292-0138. Brigantine air monitoring site located in the Edwin B. Forsythe National Wildlife Refuge near Atlantic City NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 3 NETWORK DESIGN Air monitoring sites are designed to meet one or more of the following objectives: to measure maximum pollutant concentrations, to assess population exposure, to determine the impact of major pollution sources, to measure background levels, to determine the extent of regional pollutant transport, and to measure secondary impacts in rural areas. Summary monitoring data are provided to various public and media outlets, and real-time data is used to update a graphic on the Bureau’s webpage that rates the current air quality throughout the state. The real-time data is also supplied to the USEPA which displays current air quality data from throughout the nation on the webpage, www.airnow.gov. The following is a summary of the federal Ambient Monitoring Network Requirements for carbon monoxide (CO), ozone (O3), fine particles (PM2.5), inhalable particles (PM10), sulfur dioxide (SO2), lead (Pb) and nitrogen dioxide (NO2), including the minimum number of required stations by pollutant for New Jersey. Carbon Monoxide Network Requirements According to the August 2011 revisions to 40 CFR Part 58, Appendix D.4.2 Carbon Monoxide Design Criteria, one CO monitor is required in Core Based Statistical Areas (CBSA) that have a population of 1,000,000 or more, and this monitor shall be collocated with the near-roadway NO2 monitor. The nearroadway CO monitors are to be operational by January 1, 2015. In addition, one trace-level CO monitor is required at the NCore station at the Newark Firehouse. There are currently 6 CO monitors in New Jersey. Table 1: Comparison of Carbon Monoxide Network Requirements with Current Carbon Monoxide Network CBSA Name CBSA Population # of Required # of Current Comment 2006 Stations Stations Allentown110,919 0 0 None required Bethlehem-Easton, PA-NJ Atlantic City, NJ 271,620 0 0 None required New York6,405,615 1 5 4 stations more Northern New than minimum Jersey-Long Island, NY-NJ-PA Ocean City, NJ 97,724 0 0 None required Philadelphia1,316,254 1 1 Meets minimum CamdenWilmington, PANJ-DE-MD Trenton-Ewing, NJ 367,605 0 0 None required Vineland-Millville154,823 0 0 None required Bridgeton, NJ The NJDEP will fulfill the near-roadway CO requirement by adding a CO monitor to the proposed nearroadway NO2 monitoring station in Fort Lee. Ozone Network Requirements For O3, the minimum number of stations is based on the CBSA population and whether the O3 design value is greater than or equal to 85% of the O3 NAAQS or less than 85% of the NAAQS. This is summarized in Table 2. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 4 Table 2: Minimum Network Requirements for Ozone CBSA Population # Stations (Design Value >85% NAAQS) > 10 million 4 4-10 million 3 350,000-<4 million 2 50,000-350,000 1 # Stations (Design Value <85% NAAQS) 2 1 1 0 Since the O3 Design Values for all the CBSAs in New Jersey are above 85% of the NAAQS, Table 9 lists the CBSAs, their respective populations, the minimum number of stations required by the CBSA population based on having a Design Value greater than 85% of the NAAQS, the current number of stations located in each CBSA, and whether each CBSA meets the minimum requirements. The Ocean City and Trenton-Ewing CBSA each need one more O3 monitor. Since these CBSAs are small in population and area, the NJDEP will seek a waiver from the requirement to add additional O3 monitors to these CBSAs. A comparison of requirements with the current network is shown in Table 3. Table 3: Comparison of Ozone Network Requirements with Current Ozone Network CBSA Name CBSA Population # of Required # of Current 2006 Stations (Design Stations Value>85%) Allentown110,919 1 1 Bethlehem-Easton, PA-NJ Atlantic City, NJ 271,620 1 1 New York6,405,615 3 9 Northern New Jersey-Long Island, NY-NJ-PA Ocean City, NJ 97,724 1 0 Philadelphia1,316,254 2 3 CamdenWilmington, PANJ-DE-MD Trenton-Ewing, NJ 367,605 2 1 Vineland-Millville154,823 1 1 Bridgeton, NJ Comment Meets minimum Meets minimum 6 stations more than minimum Requesting waiver 1 station more than minimum Requesting waiver Meets minimum PM2.5 Network Requirements Like ozone, the minimum number of stations for PM2.5 is based on the CBSA population and whether the PM2.5 Design Value is greater than or equal to 85% of the PM2.5 NAAQS or less than 85% of the NAAQS. This is summarized in Table 4. Table 4: Minimum Network Requirements for PM2.5 Population # Stations (Design Value>85% NAAQS) > 1 million 3 500,000-1 million 2 50,000-<500,000 1 # Stations (Design Value<85% NAAQS) 2 1 0 There are many more currently operating PM2.5 stations in the New York-Northern NJ CBSA than required by the regulations. Considering that the population of this CBSA is more than six times the NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 5 lower limit of the highest population category, the number of PM2.5 stations in the New York-Northern NJ-Long Island CBSA is reasonable. The Allentown-Bethlehem-Easton, Atlantic City and the TrentonEwing CBSAs have more than the minimum required number of stations, while the PhiladelphiaCamden-Wilmington CBSA meets the minimum. The Vineland-Millville CBSA needs 1 station, and the NJDEP plans to fulfill this requirement by adding a Federal Equivalent Method real-time PM2.5 analyzer at the Millville station. Table 5 illustrates the comparison of the PM2.5 network requirements with the current network. Table 5: Comparison of PM2.5 Network Requirements with Current PM2.5 Network CBSA Name CBSA Population # of Required # of Current 2006 Stations (Design Stations Value>85%) Allentown110,919 0 2 Bethlehem-Easton, PA-NJ Atlantic City, NJ 271,620 1 2 New YorkNorthern New Jersey-Long Island, NY-NJ-PA Ocean City, NJ PhiladelphiaCamdenWilmington, PANJ-DE-MD Trenton-Ewing, NJ Vineland-MillvilleBridgeton, NJ Comment 2 stations more than minimum 1 station more than minimum 8 stations more than minimum 6,405,615 3 12 97,724 1,316,254 0 3 0 3 None required Meets minimum 367,605 1 2 154,823 1 0 1 station more than minimum 1 station proposed PM10 Network Requirements The minimum number of required PM10 stations is based on CBSA Population and category of PM10 Concentration. High concentration category are for those samplers which measure ambient PM10 concentrations that exceed either the 24-hour or annual NAAQS by 20% or more. Medium concentration values are those that are 80% or more of either NAAQS. The low concentration category is for PM10 values that are less than 80 percent of the NAAQS. These requirements are summarized in Table 6. All PM10 samplers in New Jersey are currently measuring concentrations of PM10 less than 80% of the NAAQS, thereby placing New Jersey in the Low PM10 Concentration category. Table 6: Minimum Network Requirements for PM10 Population High PM10 Concentration > 10 million 6-10 4-10 million 4-8 350,000-<4 million 3-4 50,000-350,000 1-2 Medium PM10 Concentration 4-8 2-4 1-2 0-1 Low PM10 Concentration 2-4 1-2 0-1 0 All the CBSAs in New Jersey currently meet the minimum required number of PM10 stations as shown in Table 7. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 6 Table 7: Comparison of PM10 Network Requirements with Current PM10 Network CBSA Name CBSA Population # of Required # of Current 2006 Stations (Low PM10 Stations Concentration) Allentown110,919 0 0 Bethlehem-Easton, PA-NJ Atlantic City, NJ 271,620 0 0 New York6,405,615 1-2 1 Northern New Jersey-Long Island, NY-NJ-PA Ocean City, NJ 97,724 0 0 Philadelphia1,316,254 0-1 1 CamdenWilmington, PANJ-DE-MD Trenton-Ewing, NJ 367,605 0-1 0 Vineland-Millville154,823 0 0 Bridgeton, NJ Comment None required None required Meets minimum None required Meets minimum None required None required SO2 Network Requirements On June 2, 2010, the USEPA revised the NAAQS for SO2 by adding a new 1-hour primary standard of 75 ppb, revoking the existing 24-hour and annual NAAQS for SO2, and by revising the existing network design requirements. The final network design revisions established minimum number of stations based on a population weighted emissions index in CBSAs that fall in specified index values. According to this index, for New Jersey, a minimum of 3 SO2 stations are required in the New York-Northeast New JerseyLong Island CBSA, 2 stations are required in the Philadelphia-Camden-Wilmington CBSA, and 1 station is required in the Trenton-Ewing MSA. These requirements are summarized in Table 8. Table 8: 2010 Minimum Monitoring Network Requirements for SO2 Monitor Type Number of CBSA in New Jersey SO2 Stations CBSAs with Index values >1,000,000 3 New York-Northern New Jersey-Long Island, NY-NJ-PA CBSAs with Index values <1,000,000 and 2 Philadelphia-Camden>100,000 Wilmington, PA-NJDE-MD CBSAs with Index values >5,000 1 Trenton-Ewing, NJ Areas With SO2 Sources Not Conducive To Modeling, Areas With Multiple SO2 Sources With Overlapping Plumes, Or Areas With Susceptible And Vulnerable Populations Comment 2 stations more than minimum Meets minimum Requesting waiver (EPA discretion) Under the new monitoring regulations, NJDEP will designate existing SO2 monitoring stations in Bayonne, Elizabeth Lab and Newark Firehouse as meeting the revised minimum network requirements for the New York-Northeast New Jersey-Long Island CBSA. The NJDEP has established 1 new monitor in the Philadelphia-Camden-Wilmington CBSA at the new Camden Spruce Street station, and the minimum number of stations for the CBSA is met with existing SO2 stations in Philadelphia. The NJDEP NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 7 is seeking a waiver from SO2 monitoring requirements in the Trenton-Ewing CBSA because an updated calculation of the population weighted index based on the most recent SO2 emissions inventory for the Trenton-Ewing CBSA would fall under 5,000, which eliminates the monitoring requirement. The USEPA provided a deadline of July 1, 2011 to submit a revised SO2 monitoring network plan, and January 1, 2013 to establish additional required monitoring stations. Pb Network Requirements On November 12, 2008, the USEPA revised the NAAQS for lead by lowering the primary standard to 0.15 micrograms per cubic meter (μg/m3), and by including new network design requirements for sourceoriented and non-source-oriented lead monitoring stations. Initially, the regulations required the establishment of source-oriented lead monitors for each lead source that emits one or more tons per year of lead, and the establishment of at least one lead monitor for each CBSA that has a population of 500,000 or more. On December 14, 2010, the USEPA revised the Pb network design requirements for the establishment of source-oriented Pb monitors by lowering the lead source threshold to 0.50 tons per year, and by requiring lead monitoring at NCore monitoring stations. The NJDEP has installed 1 lead monitor at its NCore station at the Newark Firehouse on January 4, 2012. Currently, there are no sources in New Jersey that emit more than 0.50 tons per year of Pb. NO2 Network Requirements When 40 CFR Part 58, Appendix D was revised in 2006, the minimum requirements for the number of NO2 monitoring sites were revoked. On January 22, 2010, the USEPA revised the NAAQS for NO2 by adding a new 1-hour primary standard of 100 ppb, and by revising the existing network design requirements. Under the new rules, one to two near-roadway NO2 monitoring stations are required in CBSAs having a population of 500,000 or more. Also, at least one community-based NO2 monitoring station is required in such CBSAs, and the USEPA Regional Administrator, working with the states, will site additional NO2 monitoring stations to help protect communities that are susceptible and vulnerable to NO2-related health effects. These requirements are summarized in Table 9. The USEPA provided a deadline of July 1, 2012 to submit a revised NO2 network plan, and January 2, 2013 to establish any additional required monitoring stations. Table 9: 2010 Minimum Monitoring Network Requirements for NO2 Monitor Type Near Major Road in Urban Area >500,000 Near Major Road In Urban Area >2.5 Million, Or >250,000 AADT Community Monitor In Urban Area >1 Million (NCore Site) To Help Protect Communities That Are Susceptible And Vulnerable To NO2-Related Health Effects Number of NO2 Stations 1 1 1 (EPA discretion) At first glance, only the New York-Northern NJ-Long Island and the Philadelphia-Camden-Wilmington CBSAs would require monitors. Also, a new NO2 monitor can easily be installed at Newark Firehouse, New Jersey’s NCore station. However, the regulations also require that “Near Major Road” NO2 stations should be placed within 50 meters of the roadway, and no current New Jersey monitoring station is situated that close to a major road. The NJDEP has already established an NO2 monitor at a community based site, the NCore station at Newark Firehouse, and the NJDEP is planning to establish 1 near-roadway NO2 station in Fort Lee which is in the New York-Northeast New Jersey-Long Island CBSA. The NJDEP plans to designate, with EPA approval, existing NO2 stations that meet the criteria for “Monitors To Help Protect Communities That Are Susceptible and Vulnerable to NO2-Related Health Effects.” The next sections provide the rationale for selecting the Fort Lee near-roadway NO2 monitoring station. The rationale follows the guidance in the Near-Road NO2 Monitoring Technical Assistance Document prepared by the USEPA. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 8 SITE SELECTION OF NEAR-ROADWAY NO2 STATION In New Jersey, there are six CBSAs, which are made up of one or more contiguous counties: the Allentown-Bethlehem-Easton, the Atlantic City, the New York-Northern New Jersey-Long Island, the Ocean City, the Philadelphia-Camden-Wilmington, the Trenton-Ewing, and the Vineland-MillvilleBridgeton CBSAs. A map of these counties is shown in Figure 1, and a summary of the populations of these CBSAs is found in Table 10. Figure 1: Core-Based Statistical Areas in New Jersey (also Metropolitan Statistical Areas) NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 9 Table 10: Core-Based Statistical Areas in New Jersey and Population CBSA Name CBSA Population 2009 Counties in CBSA AllentownBethlehemEaston, PA-NJ Atlantic City, NJ New YorkNorthern New Jersey-Long Island, NY-NJPA 109,638 Warren County Population 2009 109,638 271,712 Atlantic 271,712 6,386,082 Middlesex Monmouth Ocean Somerset Essex Hunterdon Morris Sussex Union Bergen Hudson Passaic Cape May 790,738 644,105 573,678 326,869 769,644 130,034 488,518 151,118 526,426 895,250 597,924 491,778 96,091 366,222 Burlington Camden Gloucester Salem Mercer 446,108 517,879 289,920 66,342 366,222 157,745 Cumberland 157,745 Ocean City, NJ PhiladelphiaCamdenWilmington, PA-NJ-DE-MD TrentonEwing, NJ VinelandMillvilleBridgeton, NJ 96,091 1,320,249 With over six million in population covering twelve counties, the New York-Northern New Jersey-Long Island, NY-NJ-PA CBSA requires 2 near-road NO2 monitoring stations. The Philadelphia-CamdenWilmington CBSA has greater than 500,000 in population, but less than 2,500,000, and is required to have 1 near-road NO2 monitoring station. The other areas are not required to have NO2 stations since their populations are less than 500,000. A map of the New Jersey highway system is shown in Figure 2, and Table 11 lists the top 60 roadway segments that were measured to have the highest total AADT as measured by the New Jersey Department of Transportation. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 10 Figure 2: Map of Major Roadways in New Jersey NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 11 Table 11: Top 60 Roadway Segments in NJ with the Highest Total AADT CMSNUM RT_LTR 3581 I-95 5670 I-95 5672 I-95 5662 I-95 5661 I-95 5673 I-95 3579 I-95 5038 I-95 3767 GARDEN STATE PARKWAY 3765 GARDEN STATE PARKWAY 5699 GARDEN STATE PARKWAY 5042 GARDEN STATE PARKWAY 3766 GARDEN STATE PARKWAY 5656 I-95 5660 I-95 3555 I-95 3556 I-95 3557 I-95 5663 I-95 3560 I-95 3772 GARDEN STATE PARKWAY 5705 GARDEN STATE PARKWAY 5045 GARDEN STATE PARKWAY 5706 GARDEN STATE PARKWAY 3775 GARDEN STATE PARKWAY 5709 GARDEN STATE PARKWAY 5707 GARDEN STATE PARKWAY 5704 GARDEN STATE PARKWAY 5708 GARDEN STATE PARKWAY 3783 GARDEN STATE PARKWAY 3784 GARDEN STATE PARKWAY 3785 GARDEN STATE PARKWAY 5711 GARDEN STATE PARKWAY 5703 GARDEN STATE PARKWAY 3778 GARDEN STATE PARKWAY 3779 GARDEN STATE PARKWAY 3777 GARDEN STATE PARKWAY 3552 I-95 5658 I-95 3553 I-95 5653 I-95 5710 GARDEN STATE PARKWAY 3780 GARDEN STATE PARKWAY 3782 GARDEN STATE PARKWAY 3781 GARDEN STATE PARKWAY 5659 I-95 5654 I-95 5715 GARDEN STATE PARKWAY 5044 GARDEN STATE PARKWAY 5700 GARDEN STATE PARKWAY 3762 GARDEN STATE PARKWAY 3763 GARDEN STATE PARKWAY 5698 GARDEN STATE PARKWAY 3761 GARDEN STATE PARKWAY 3067 I-76 3066 I-76 3068 I-76 3769 GARDEN STATE PARKWAY 5043 GARDEN STATE PARKWAY 3062 I-76 3065 I-76 COUNTY SUMOFVOL24 Rank BERGEN 311,234 BERGEN 275,088 BERGEN 264,557 UNION 252,656 UNION 252,653 BERGEN 248,687 BERGEN 248,687 ESSEX 247,556 MIDDLESEX 244,501 MIDDLESEX 244,495 MIDDLESEX 244,494 MIDDLESEX 244,493 MIDDLESEX 244,490 MIDDLESEX 240,173 UNION 240,168 MIDDLESEX 240,164 MIDDLESEX 240,156 UNION 240,154 UNION 236,506 UNION 236,493 MIDDLESEX 234,649 UNION 234,641 MIDDLESEX 234,630 UNION 228,252 UNION 228,243 UNION 228,243 UNION 223,907 UNION 223,900 UNION 221,262 ESSEX 218,378 ESSEX 218,378 ESSEX 218,378 ESSEX 218,378 MIDDLESEX 212,117 UNION 207,587 UNION 207,580 UNION 207,578 MIDDLESEX 205,145 MIDDLESEX 205,145 MIDDLESEX 205,134 MIDDLESEX 205,134 ESSEX 202,011 UNION 198,302 ESSEX 198,298 UNION 198,296 MIDDLESEX 196,521 MIDDLESEX 196,505 ESSEX 194,647 MIDDLESEX 193,571 MIDDLESEX 189,628 MONMOUTH 189,521 MIDDLESEX 189,514 MIDDLESEX 189,514 MONMOUTH 189,505 CAMDEN 189,328 CAMDEN 189,322 CAMDEN 189,322 MIDDLESEX 186,719 MIDDLESEX 186,719 CAMDEN 183,245 CAMDEN 183,245 1 2 3 4 5 6 6 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 25 27 28 29 30 30 30 30 34 35 36 37 38 38 40 40 42 43 44 45 46 47 48 49 50 51 52 52 54 55 56 56 58 58 60 60 SUMOFTRK24 Rank FE-AADT FE-Rank 33,442 30 612,212 11 29,559 35 541,119 16 28,449 38 520,598 27 47,752 1 682,424 1 47,751 2 682,416 2 26,761 55 489,536 29 26,747 56 489,410 30 46,565 3 666,641 3 1,222 3571 255,499 189 1,221 3576 255,484 192 1,222 3571 255,492 190 1,222 3571 255,491 191 1,221 3576 255,479 193 45,738 4 651,815 4 45,392 5 648,694 5 45,391 6 648,683 6 45,389 7 648,661 7 45,389 8 648,656 8 44,700 9 638,803 9 44,697 10 638,768 10 1,171 3685 245,188 221 1,172 3679 245,189 220 1,171 3685 245,169 222 1,142 3741 238,530 242 1,142 3741 238,521 243 1,142 3741 238,521 244 1,122 3784 234,005 264 1,121 3788 233,989 265 1,106 3825 231,216 273 1,090 3863 228,188 285 1,090 3863 228,188 286 1,090 3863 228,188 287 1,090 3863 228,188 288 1,062 3964 221,675 296 1,040 4010 216,947 307 1,038 4014 216,922 309 1,040 4010 216,938 308 39,068 19 556,757 12 39,068 19 556,757 13 39,068 19 556,746 14 39,068 19 556,746 15 1,006 4093 211,065 320 994 4117 207,248 338 994 4117 207,244 339 996 4110 207,260 337 37,427 24 533,364 25 37,427 24 533,348 26 974 4155 203,413 353 970 4162 202,301 371 952 4199 198,196 398 2,845 1806 215,126 310 948 4208 198,046 402 948 4208 198,046 403 2,845 1806 215,110 311 16,146 168 334,642 98 16,149 166 334,663 96 16,149 166 334,663 97 936 4236 195,143 413 936 4236 195,143 414 15,625 185 323,870 109 15,625 185 323,870 110 Source: New Jersey Department of Transportation NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 12 The top 58 segments by AADT are all in the New York CBSA, and 15 of the top 20 segments are on portions of the New Jersey Turnpike in Bergen, Essex, Middlesex and Union counties. The location with the highest AADT in the state is at the approach to the toll booths for the George Washington Bridge in Fort Lee. This location also ranked 30th overall in terms of truck traffic. In terms of the Fleet Equivalent Annual Average Daily Traffic, (a statistic that considers the emissions of 1 heavy duty truck as equivalent to 10 regular-duty motor vehicle) this roadway segment is 11th highest in New Jersey. The NJDEP already operates a site near the segments with the highest truck counts which are near Exit 13 of the New Jersey Turnpike in Union County. While this site does not meet all siting criteria for a near roadway monitoring site, the NJDEP believes that it adequately represents near road exposures near roadway segments of this type. For this and other reasons, the NJDEP is proposing to locate one near-road site in Fort Lee adjacent to the highest AADT road segment. In addition to having the highest overall traffic, it has very heavy truck traffic and is located in a community with pedestrian overpasses, residences, and businesses in immediate proximity to the road. The proposed Fort Lee near-roadway NO2 monitoring station is identified by a red circle in the satellite photograph of Fort Lee shown in Figure 3. Figure 3: Proposed Fort Lee Near-Roadway NO2 station Address: Corner of Hoyt Avenue & Central Road, Fort Lee, NJ Latitude: 40.85355 Longitude: -73.9661 NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 13 MONITORING SITE DESCRIPTION OF NEAR-ROADWAY NO2 STATION The proposed Fort Lee station is located in a maintenance yard owned by the Port Authority of New York and New Jersey. Access to the maintenance yard is limited to Port Authority and NJDEP staff only. This area, which overlooks the George Washington Bridge Tollbooths, is adjacent to a commercial and retail area that is interspersed with tall office and residential towers. There is a high amount of pedestrian activity due to the proximity of shopping and dining establishments and bus stops. A photograph of the immediate area of the proposed station is presented in Figure 4. The NJDEP will employ an Ekto shelter to house the NO2 analyzer and related equipment. The sample inlet is 1 meter above the roof of the shelter, and will be within 50 meters from the nearest traffic lane of the New Jersey Turnpike. Figure 4: Immediate Vicinity of Proposed Fort Lee Station NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 14 THE NEW JERSEY AIR MONITORING NETWORK The NJDEP is currently operating 38 air monitoring sites. Table 11 lists all the current monitoring sites along with the pollutants, categories of pollutants or meteorological parameters that are measured at each site. Figure 5 shows the locations of the monitoring sites across New Jersey. Several parameters, including carbon monoxide (CO), nitrogen dioxide (NO2), ozone (O3), sulfur dioxide (SO2), particulate matter, and meteorological parameters, are measured by instruments that automatically collect and analyze data instantaneously and continuously. The data is transmitted to a centralized computer system in Trenton, New Jersey, once every minute, thus providing near realtime data. For fine particles (particles smaller than 2.5 micrometers in diameter or PM2.5) and inhalable particles (particles smaller than 10 micrometers in diameter or PM10), their respective instruments collect a sample over a 24-hour period. These samples are subsequently manually retrieved and then analyzed in a laboratory several days to a few weeks following their sample collection. PM2.5 concentrations are determined by both real-time analyzers and manual samplers. The real-time PM2.5 analyzers measure PM2.5 levels every minute, and the data is used, along with data from the other continuous pollutants, to generate a rating of air quality called the Air Quality Index, which is updated hourly on the Bureau of Air Monitoring’s webpage. The manual PM2.5 sampler collects particles on a filter over a 24-hour period. The filter is retrieved following the completion of the sampling period and weighed in a laboratory. Data used for comparison to the NAAQS must be measured by USEPA-approved manual samplers or USEPA-approved real-time analyzers. The NJDEP uses USEPA-approved manual samplers for comparison to the NAAQS. USEPA-approved manual PM2.5 sampler on the roof of the Union City Health Department building in Hudson County The NJDEP also monitors many other pollutants which are grouped together into categories by their method of sampling or analysis. These categories are listed in the headings of Table 12. Sites that monitor for ozone precursors, pollutants that affect ozone formation and destruction in the atmosphere, are part of the national Photochemical Assessment Monitoring Station (PAMS) program. Ozone precursors are frequently referred to as PAMS pollutants. Pollutants in the PM2.5-Speciation category include trace elements, heavy metals, and carbon compounds that are analyzed from PM2.5 particles. VOCs and Carbonyls refer to selected carbon-based air pollutants that are analyzed from whole air samples or adsorbent media. The PM2.5-Speciation, VOC, and Carbonyls samples are collected by the NJDEP and are sent to USEPA-approved contract laboratories for analysis. Finally, the NJDEP also measures acid deposition, mercury, and two surrogates for particle pollution: smoke shade and visibility as measured by a nephelometer. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 15 Temperature Wind Direction Wind Speed X Solar Radiation X Relative Humidity P Barometric Pressure Carbonyls P Mercury VOCs P Acid Deposition O3 Precursors Lead X P PM-coarse Nephelometer X P PM10 Real-Time PM2.5 PM2.5 Smoke Shade SO2 O3 NOy PM2.5-Speciation Ancora State Hospital Atlantic City Bayonne Brigantine Camden Spruce Street Camden RRF Chester Clarksboro Colliers Mills Columbia WMA East Orange Elizabeth Elizabeth Lab Elizabeth Mitchell Bldg Ewing Flemington Fort Lee Fort Lee Library Gibbstown Jersey City Jersey City Firehouse Leonia Millville Monmouth University Morristown Amb Squad New Brunswick Newark Firehouse Paterson Pennsauken Phillipsburg Rahway Ramapo Rider University Rutgers University South Camden Toms River Trenton Union City Washington Crossing TOTAL (Current only) NO2 CO TABLE 12: SUMMARY OF CURRENT AND PROPOSED NEW JERSEY AIR MONITORING SITES P P P P P P X X X X X X X X X X X X X X P X X X X X X X X X X X X X X X X X X X X X X X X X P X X X X X X X X X X X X X X X X X P X X X X X X X X X X X X X X X X X X X 4 5 4 5 5 5 P X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X P X X X X X X X X X X 6 9 1 16 9 3 X X X X 21 4 11 1 2 0 1 1 3 3 X 1 4 X - Current Site and Parameter P - Proposed Site and Parameter NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 16 FIGURE 5: MAP OF THE CURRENT AND PROPOSED NEW JERSEY AIR MONITORING SITES NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 17 CHANGES TO THE NETWORK, 2011-2012 In January 2012, a Pb monitor was added to the Newark Firehouse station to satisfy the requirements for NCore monitoring stations. In April 2012, the NJDEP re-established a monitoring station in Camden and plans to establish a near-road NO2 monitoring station in Fort Lee by the end of 2012. The proposed Fort Lee station, which is in close proximity to the previous station, will measure NO2, CO, and a real-time PM2.5. Table 13 summarizes the monitors that the NJDEP established and proposes to establish through December 2012. Table 13: Monitors Established or Proposed, July 2011 – December 2012 Date Site Monitors Established/Proposed January 4, 2012 Newark Firehouse Pb April 9, 2012 Camden Spruce Street CO, NO2, O3, SO2, PM2.5 December 31, 2012 Fort Lee CO, NO2, PM2.5 The revisions to the networks require the establishment of a new Pb monitor, and a new near-road NO2 monitoring location, but they allow a significant reduction in the number of monitoring stations that the NJDEP currently operates. The resources saved will be used to implement technology changes that will improve the value of the data and save on the resources needed to collect it. In addition, monitoring for new types of pollutants such as air toxics and indicators of diesel exhaust emissions will be initiated in place of some of the current measurements. These pollutants now seem to be of greater importance from a public health perspective. Of particular interest is providing information on the health impacts of motor vehicles, both gas and diesel powered, and other pollutants that are likely to affect urban populations in the state. Most of the monitoring at urban sites at this time is for CO and SO2. This results in air quality ratings in cities that are based on pollutants that are only present at very low levels. To meet this challenge, the NJDEP plans to establish monitors that measure real-time benzene, toluene, ethylbenzene, xylene and black carbon at existing monitoring stations in Bayonne, Elizabeth Lab, Newark Firehouse, Camden Spruce Street and at the proposed station in Fort Lee. Although these pollutants do not have federal standards, they are indicators of diesel particulate matter or measurements of air toxic pollutants that are prevalent in the highly urbanized areas. This effort will provide the air quality data in these urbanized areas that are not currently being measured by the criteria pollutant network. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 18 NEW JERSEY AIR MONITORING SITE DESCRIPTIONS According to 40 CFR 58.10, the following elements for each existing and proposed air monitoring station must be included in New Jersey’s Network Plan: 1. 2. 3. 4. 5. the Air Quality Subsystem (AQS) site identification number, the location, including street address and geographical coordinates, the sampling and analysis methods for each measured parameter, the operating schedules for each monitor, any proposals to remove or move a monitoring station within a period of 18 months following Plan submittal, 6. the monitoring objective and spatial scale of representativeness for each monitor as defined in Appendix D to Part 58, 7. the identification of any sites that are suitable and sites that are not suitable for comparison against the annual fine particle (PM2.5) National Ambient Air Quality Standards (NAAQS) as described in 40 CFR Part 58.30, and 8. the Metropolitan Statistical Area (MSA), Core-Based Statistical Area (CBSA), Combined Statistical Area (CSA) or other area represented by this monitor. The next pages supply the above information for current and proposed New Jersey air monitoring sites. All abbreviations and terms are defined and explained in the Glossary following this section, and Appendices A through D provide additional information on Volatile Organic Compounds, Carbonyls, PM2.5 Speciation and ozone precursors. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 19 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Latitude Longitude Date Established Suitable for Comparison to PM2.5 NAAQS? Ancora Ancora State Hospital, 202 Spring Garden Road Ancora, NJ 08037 34 007 1001 Camden Philadelphia-Camden-Wilmington CSA 39.684250 -74.861491 1/1/1966 Not Applicable PARAMETER SUMMARY Parameter Ozone (O3) AQS Parameter Code 44201 Sampling Instrument Dasibi 1008 Method of Analysis Ultraviolet AQS Method Code 056 AQS Sample Frequency Continuous Site Purpose To measure background concentrations for the southern part of New Jersey. May also measure maximum ozone concentrations downwind from the Philadelphia metropolitan area. Plans for the next No changes. 18 months Other Comment Acid Deposition shut down December 31, 2011. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 20 AQS Spatial Scale Urban AQS Monitoring Objective Population Exposure SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Latitude Longitude Date Established Suitable for Comparison to PM2.5 NAAQS? Atlantic City 1535 Bacharach Blvd Atlantic City, NJ 08401 34 001 1006 Atlantic Atlantic City MSA 39.363528 -74.431219 7/27/2001 Yes PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure fine particle concentrations in the commercial area of Atlantic City. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 21 SITE INFORMATION Site Name Bayonne Veterans Park on Newark Bay, 25th St. near Park Address Road City, State, Zip Bayonne, NJ 07002 AQS Code 34 017 0006 NJ County Hudson MSA/CSA New York-Northeast New Jersey-Connecticut CSA Latitude 40.670250 Longitude -74.126081 Date Established 1/1/1983 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Ozone (O3) Sulfur Dioxide (SO2) Site Purpose Plans for the next 18 months Other Comment AQS Parameter Code 42601 42602 AQS Method Code 074 074 AQS Sample Frequency Continuous Continuous AQS Spatial Scale Urban Urban AQS Monitoring Objective Population Exposure Population Exposure Sampling Instrument TECO 42 TECO 42 Method of Analysis Chemiluminescence Chemiluminescence 42603 TECO 42 Chemiluminescence 074 Continuous Urban Population Exposure 44201 42401 Dasibi 1008 TECO 43A Ultraviolet Pulsed fluorescence 056 060 Continuous Continuous Neighborhood Neighborhood Population Exposure Population Exposure To measure population exposure in the Hudson County area. Existing SO2 monitor is designated as meeting revised 2010 SO2 monitoring network requirements, plan to add measurement of benzene, toluene, ethylbenzene, xylene (BTEX) and black carbon. Nitric Oxide data (NO) and Oxides of Nitrogen (NOx) data are not submitted to USEPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 22 SITE INFORMATION Site Name Brigantine Edwin B. Forsythe National Wildlife Refuge Visitor Address Center, Great Creek Road City, State, Zip Oceanville, NJ 08231 AQS Code 34 001 0006 NJ County Atlantic MSA/CSA Atlantic City MSA Latitude 39.464872 Longitude -74.448736 Date Established 1/1/2007 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) Sulfur Dioxide (SO2) AQS Parameter Code 44201 42401 Fine Particles (PM2.5) 88101 Real-time PM2.5 88500 Real-time PM2.5 88502 Real-time PM2.5 Mercury (Hg) Sampling Instrument TECO 49i TECO 43iTLE R&P 2025 Lov-volume sequential sampler R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Nephelometer Tekran 2537A Method of Analysis Ultraviolet Pulsed fluorescence Gravimetric Gravimetric, Total Atmospheric PM2.5 Gravimetric, Acceptable PM2.5 Light-scattering CVAF Spectrometry AQS Method Code 047 560 AQS Sample Frequency Continuous Continuous AQS Spatial Scale Urban Urban AQS Monitoring Objective Background Background 118 Every 3 days Urban Background 760 Continuous Urban Background 703 Continuous Urban Background Continuous Hourly Urban Urban Background Background Site Purpose To measure pollutant concentrations and visibility in Class I areas. Plans for the next No changes. 18 months Other Comment SO2 is measured by a “trace-level” analyzer. Also an IMPROVE station, part of NESCAUM visibility network, Real-time PM2.5 data by Nephelometer and Mercury data not submitted to USEPA’s AQS database, the US Fish & Wildlife Service collects a weekly Acid Deposition sample which is sent to the National Atmospheric Deposition Program (NADP) for analysis. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 23 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Latitude Longitude Date Established Suitable for Comparison to PM2.5 NAAQS? Camden RRF (Resource Recovery Facility) Morgan Blvd., & I-676 entrance ramp Camden, NJ 08104 34 007 0009 Camden Philadelphia-Camden-Wilmington CSA 39.912431 -75.116864 5/8/1994 Not Applicable PARAMETER SUMMARY Parameter Inhalable Particles (PM10) AQS Parameter Code 81102 Sampling Instrument SierraAnderson Highvolume sampler Method of Analysis Gravimetric AQS Method Code 063 AQS Sample Frequency Every 6 days Site Purpose To measure the impact of mobile sources in heavily used roadways in southern Camden. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 24 AQS Spatial Scale AQS Monitoring Objective Middle Source Oriented SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Camden Spruce Street 266 Spruce Street Camden, NJ 34 007 0002 Camden Philadelphia-Camden-Wilmington CSA 39.934446 -75.125291 4/11/12 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter Carbon Monoxide (CO) Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Ozone (O3) Sulfur Dioxide (SO2) Fine Particles (PM2.5) AQS Parameter Code 42101 42601 42602 AQS Method Code 054 074 074 AQS Sample Frequency Continuous Continuous Continuous AQS Spatial Scale Neighborhood Neighborhood Neighborhood AQS Monitoring Objective Population Exposure Population Exposure Population Exposure Sampling Instrument TECO 48C TECO 42i TECO 42i Method of Analysis Nondispersive-infrared Chemiluminescence Chemiluminescence 42603 TECO 42i Chemiluminescence 074 Continuous Neighborhood Population Exposure 44201 42401 TECO 49i TECO 43iTLE R&P 2025 Low-volume sequential sampler Ultraviolet Pulsed fluorescence 047 560 Continuous Continuous Neighborhood Neighborhood Population Exposure Population Exposure Gravimetric 118 Every 3 days Neighborhood Population Exposure 88101 Site Purpose Comprehensive air monitoring station in the Philadelphia-Camden metro area of southern New Jersey. Plans for the next Add meteorological parameters, real-time PM2.5, PM2.5 Speciation, Volatile Organic Compounds, 18 months BTEX and black carbon. Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 25 SITE INFORMATION Site Name Chester Bldg # 1, Department of Public Works, Chester Address Borough, off Route 513 City, State, Zip Chester, NJ 07930 AQS Code 34 027 3001 NJ County Morris MSA/CSA New York-Northeast New Jersey-Connecticut CSA Latitude 40.787628 Longitude -74.676301 Date Established 1/1/1978 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Ozone (O3) Sulfur Dioxide (SO2) Fine Particles (PM2.5) PM2.5 Speciation Volatile Organic Compounds Carbonyls Mercury (Hg) Solar Radiation AQS Parameter Code 42601 42602 AQS Method Code 074 074 AQS Sample Frequency Continuous Continuous AQS Spatial Scale Urban Urban AQS Monitoring Objective Background Background Sampling Instrument TECO 42 TECO 42 Method of Analysis Chemiluminescence Chemiluminescence 42603 TECO 42 Chemiluminescence 074 Continuous Urban Background 44201 44201 Ultraviolet Pulsed fluorescence 047 060 Continuous Continuous Urban Urban Background Background Gravimetric 118 Every 3 days Urban Population Exposure Appendix A Dasibi 1008RS TECO 43A R&P 2025 Low-volume sequential sampler Met One XRF, IC, TOA App. A Every 3 days Neighborhood Population Exposure Appendix B Canister TO-15 App. B Every 6 days Neighborhood Population Exposure Appendix C DNPH cartridge Tekran 2537A Qualimetrics TO-11A CVAF Spectrometry Pyrometer App. C Every 6 days Hourly Continuous Neighborhood Neighborhood Neighborhood Population Exposure Population Exposure 88101 63301 011 Continued on next page NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 26 PARAMETER SUMMARY (Chester, continued) Site Purpose To measure background concentrations in northern New Jersey. Plans for the next No changes. 18 months Other Comment Oxides of Nitrogen (NOx) data and Mercury data are not submitted to USEPA’s AQS database, See Appendices A, B and C for more information on PM2.5 Speciation, Volatile Organic Compounds and Carbonyls. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 27 SITE INFORMATION Site Name Clarksboro Clarksboro Shady Rest Home, Address Shady Lane and County House Road City, State, Zip Clarksboro, NJ 08020 AQS Code 34 015 0002 NJ County Gloucester Philadelphia-Camden-Wilmington MSA/CSA CSA Latitude 39.800339 Longitude -75.212119 Date Established 1/1/1981 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) AQS Parameter Code 44201 Sampling Instrument TECO 49 Method of Analysis Ultraviolet AQS Method Code 047 AQS Sample Frequency Continuous Site Purpose To measure highest concentrations of ozone downwind from Philadelphia metropolitan area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 28 AQS Spatial Scale Urban AQS Monitoring Objective Highest Concentration SITE INFORMATION Site Name Colliers Mills Colliers Mills Wildlife Management Address Area City, State, Zip Colliers Mills, NJ AQS Code 34 029 0006 NJ County Ocean New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.064847 Longitude -74.444058 Date Established 1/1/1985 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) AQS Parameter Code 44201 Sampling Instrument TECO 49 Method of Analysis Ultraviolet AQS Method Code 047 AQS Sample Frequency Continuous Site Purpose To measure highest concentrations for ozone downwind from the Philadelphia metropolitan area and central New Jersey. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 29 AQS Spatial Scale Urban AQS Monitoring Objective Highest Concentration SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Columbia WMA Delaware Rd, Knowlton Township Columbia, NJ 07832 34 041 0007 Warren Allentown-Bethlehem-Easton-PANJ MSA 40.924600 -75.067800 9/23/2010 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Ozone (O3) Sulfur Dioxide (SO2) AQS Parameter Code 42601 42602 AQS Method Code 074 074 AQS Sample Frequency Continuous Continuous AQS Spatial Scale Neighborhood Neighborhood AQS Monitoring Objective Population Exposure Population Exposure Sampling Instrument TECO 42i TECO 42i Method of Analysis Chemiluminescence Chemiluminescence 42603 TECO 42i Chemiluminescence 074 Continuous Neighborhood Population Exposure 44201 42401 TECO 49i TECO 43iTLE R&P 2025 Low-volume sequential sampler R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Ultraviolet Pulsed fluorescence 047 060 Continuous Continuous Neighborhood Neighborhood Population Exposure Highest Concentration Gravimetric 118 Daily Neighborhood Population Exposure 760 Continuous Neighborhood Population Exposure 703 Continuous Neighborhood Population Exposure Fine Particles (PM2.5) 88101 Real-time PM2.5 88500 Real-time PM2.5 88502 Gravimetric, Total atmospheric PM2.5 Gravimetric, Acceptable PM2.5 Continued on next page NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 30 PARAMETER SUMMARY (Columbia, continued) Parameter Barometric Pressure Relative Humidity Temperature Wind Direction Wind Speed AQS Parameter Code 64101 62201 62101 61102 61101 Sampling Instrument Vaisala WXT Vaisala WXT Vaisala WXT Vaisala WXT Vaisala WXT Method of Analysis Capacitive sensor Capacitive sensor Capacitive sensor Ultrasonic sensor Ultrasonic sensor AQS Method Code 060 060 060 060 060 AQS Sample Frequency Continuous Continuous Continuous Continuous Continuous Site Purpose To measure population exposure for NO2, O3 and PM2.5; and highest concentrations for SO2. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 31 AQS Spatial Scale Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood AQS Monitoring Objective SITE INFORMATION Site Name East Orange Engine No. 2, Main Street & Address Greenwood Avenue City, State, Zip East Orange, NJ 07018 AQS Code 34 013 1003 NJ County Essex New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.757501 Longitude -74.200500 Date Established 1/1/1980 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Carbon Monoxide (CO) Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Relative Humidity Temperature AQS Parameter Code 42101 42601 42602 Sampling Instrument TECO 48 TECO 42 TECO 42 Method of Analysis Nondispersive-infrared Chemiluminescence Chemiluminescence 42603 TECO 42 Chemiluminescence 62201 62101 Qualimetrics Qualimetrics Capacitive sensor Thermistor AQS Method Code 054 074 074 074 AQS Sample Frequency Continuous Continuous Continuous AQS Spatial Scale Neighborhood Neighborhood Neighborhood AQS Monitoring Objective Highest Concentration Highest Concentration Highest Concentration Continuous Neighborhood Highest Concentration Continuous Continuous Neighborhood Neighborhood Site Purpose To measure population exposure in the East Orange and Newark areas. Plans for the next No changes. 18 months Other Comment The CO, NO, NOx, Relative Humidity and Temperature data are not submitted to USEPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 32 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Elizabeth 7 Broad St. Elizabeth, NJ 07201 34 039 0003 Union New York-Northeast New JerseyConnecticut CSA 40.662451 -74.214745 1/1/1970 Latitude Longitude Date Established Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Carbon Monoxide (CO) Sulfur Dioxide (SO2) Smoke Shade AQS Parameter Code 42101 42401 11201 Sampling Instrument TECO 48 TECO 43A Wallace Fisher Method of Analysis Nondispersive-infrared Pulsed fluorescence Tape sampler AQS Method Code 054 060 081 AQS Sample Frequency Continuous Continuous Hourly Site Purpose To measure the highest concentrations in the central commercial area of Elizabeth. Plans for the next No changes. 18 months Other Comment Smoke Shade data is not submitted to USEPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 33 AQS Spatial Scale Micro Middle Neighborhood AQS Monitoring Objective Highest Concentration Population Exposure Population Exposure SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Elizabeth Lab Interchange 13, NJ Turnpike Elizabeth, NJ 07206 34 039 0004 Union New York-Northeast New JerseyConnecticut CSA 40.641440 -74.208365 1/1/1970 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter Carbon Monoxide (CO) Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Sulfur Dioxide (SO2) Smoke Shade AQS Parameter Code 42101 42601 42602 AQS Method Code 054 074 074 AQS Sample Frequency Continuous Continuous Continuous AQS Spatial Scale Neighborhood Neighborhood Neighborhood AQS Monitoring Objective Highest Concentration Highest Concentration Highest Concentration Sampling Instrument TECO 48 TECO 42 TECO 42 Method of Analysis Nondispersive-infrared Chemiluminescence Chemiluminescence 42603 TECO 42 Chemiluminescence 074 Continuous Neighborhood Highest Concentration 42401 11201 TECO 43A Wallace Fisher R&P 2025 Low-volume sequential sampler R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Met One Pulsed fluorescence Tape sampler 060 081 Continuous Hourly Neighborhood Neighborhood Highest Concentration Population Exposure Gravimetric 118 Daily Neighborhood Population Exposure 760 Continuous Middle Scale Highest Concentration 703 Continuous Middle Scale Highest Concentration App. A Every 3 days Neighborhood Highest Concentration Fine Particles (PM2.5) 88101 Real-time PM2.5 88500 Real-time PM2.5 88502 PM2.5 Speciation Appendix A Gravimetric, Total atmospheric PM2.5 Gravimetric, Acceptable PM2.5 XRF, IC, TOA Continued on next page NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 34 PARAMETER SUMMARY (Elizabeth Lab, continued) Parameter Volatile Organic Compounds Carbonyls Mercury (Hg) Wind Direction Wind Speed Site Purpose Plans for the next 18 months Other Comment AQS Parameter Code Sampling Instrument Appendix B Canister Appendix C DNPH cartridge Tekran 2537A Qualimetrics Qualimetrics 61102 61101 AQS Method Code AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective TO-15 App. B Every 6 days Neighborhood Population Exposure TO-11A CVAF Spectrometry Wind vane Anemometer App. C Every 6 days Hourly Continuous Continuous Neighborhood Neighborhood Neighborhood Neighborhood Population Exposure Population Exposure Method of Analysis 020 020 The comprehensive air monitoring site in the northeast metropolitan region of New Jersey. Existing SO2 monitor is designated as meeting revised 2010 SO2 monitoring network requirements, plan to add measurement of benzene, toluene, ethylbenzene, xylene (BTEX) and black carbon. PM2.5 is collocated for precision. CO, Nitric Oxide (NO), Oxides of Nitrogen (NOx), Smoke Shade, Wind Direction and Wind Speed data are not submitted to USEPA’s AQS database; See Appendices A, B and C for more information on PM2.5 Speciation, Volatile Organic Compounds and Carbonyls. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 35 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Elizabeth Mitchell Bldg Mitchell Bldg., 500 N. Broad St. Elizabeth, NJ 07208 34 039 0006 Union New York-Northeast New JerseyConnecticut CSA 40.673406 -74.213889 1/1/1983 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure population exposure in the Elizabeth area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 36 SITE INFORMATION Site Name Ewing Bureau of Air Monitoring Technical Address Center, 380 Scotch Road City, State, Zip West Trenton, NJ 08628 AQS Code 34 021 0010 NJ County Mercer MSA/CSA Trenton-Ewing MSA Latitude 40.287530 Longitude -74.807770 Date Established 1/1/2009 Suitable for Comparison to No PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Real-time PM2.5 88500 Real-time PM2.5 88502 Sampling Instrument R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Method of Analysis Gravimetric, Total Atmospheric PM2.5 Gravimetric, Acceptable PM2.5 AQS Method Code AQS Sample Frequency AQS Monitoring Objective 760 Continuous Neighborhood Population Exposure 703 Continuous Neighborhood Population Exposure Site Purpose To measure population exposure in the Mercer County area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 AQS Spatial Scale 37 SITE INFORMATION Site Name Flemington Raritan Township Municipal Address Utilities Authority, 365 Old York Rd City, State, Zip Flemington, NJ 08822 AQS Code 34 019 0001 NJ County Hunterdon New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.515253 Longitude -74.806753 Date Established 1/1/1980 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) AQS Parameter Code 44201 Real-time PM2.5 88500 Real-time PM2.5 88502 Barometric Pressure Relative Humidity Solar Radiation Temperature Wind Direction Wind Speed 64101 62201 63301 62101 61102 61101 Sampling Instrument Dasibi 1008RS R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Qualimetrics Qualimetrics Qualimetrics Qualimetrics Qualimetrics Qualimetrics Method of Analysis Ultraviolet Gravimetric, Total Atmospheric PM2.5 Gravimetric, Acceptable PM2.5 Pressure transducer Capacitive sensor Pyrometer Thermistor Wind vane Anemometer AQS Method Code 056 AQS Sample Frequency Continuous AQS Spatial Scale Urban AQS Monitoring Objective Highest Concentration 760 Continuous Neighborhood Population Exposure 703 Continuous Neighborhood Population Exposure 011 013 011 020 020 020 Continuous Continuous Continuous Continuous Continuous Continuous Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Site Purpose To measure ozone concentrations in the northwestern region of New Jersey. Plans for the next No changes. 18 months Other Comment Barometric Pressure, Relative Humidity, Solar Radiation, Temperature, Wind Direction, and Wind Speed data are not submitted to USEPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 38 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Fort Lee Library Fort Lee Library, 320 Main St. Fort Lee, NJ 07024 34 003 0003 Bergen New York-Northeast New JerseyConnecticut CSA 40.852256 -73.973314 1/23/1986 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure the population exposure in the Fort Lee area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 39 SITE INFORMATION Site Name Gibbstown Address Municipal Maintenance Yard, North School St., North of Morse Ave. City, State, Zip Gibbstown, NJ 08027 AQS Code 34 015 0004 NJ County Gloucester Philadelphia-Camden-Wilmington MSA/CSA CSA Latitude 39.830809 Longitude -75.284720 Date Established 2/2/2007 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure population exposure in the Gibbstown area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 40 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Jersey City 2828 Kennedy Blvd. Jersey City, NJ 07306 34 017 1002 Hudson New York-Northeast New JerseyConnecticut CSA 40.731690 -74.066566 1/1/1970 Latitude Longitude Date Established Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Carbon Monoxide (CO) Sulfur Dioxide (SO2) Smoke Shade AQS Parameter Code 42101 42401 11201 Sampling Instrument TECO 48 TECO 43A Wallace Fisher Method of Analysis Nondispersive-infrared Pulsed fluorescence Tape sampler AQS Method Code 054 060 081 AQS Sample Frequency Continuous Continuous Hourly Site Purpose To measure highest concentrations in the central commercial area of Jersey City. Plans for the next No changes. 18 months Other Comment Smoke Shade data is not submitted to USEPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 41 AQS Spatial Scale Micro Neighborhood Neighborhood AQS Monitoring Objective Highest Concentration Highest Concentration Population Exposure SITE INFORMATION Site Name Jersey City Firehouse Consolidated Firehouse, 355 Address Newark Ave. City, State, Zip Jersey City, NJ 07302 AQS Code 34 017 1003 NJ County Hudson New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.725454 Longitude -74.052290 Date Established 1/1/1967 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Real-time PM2.5 88500 Real-time PM2.5 88502 Inhalable Particles (PM10) 81102 Sampling Instrument R&P 2025 Low-volume sequential sampler R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS SierraAnderson HighVolume Sampler Method of Analysis Gravimetric Gravimetric, Total Atmospheric PM2.5 Gravimetric, Acceptable PM2.5 Gravimetric AQS Method Code AQS Sample Frequency AQS Monitoring Objective 118 Daily Neighborhood Population Exposure 760 Continuous Neighborhood Population Exposure 703 Continuous Neighborhood Population Exposure 063 Every 6 days Neighborhood Highest Concentration Site Purpose To measure population exposure in the Jersey City area. Plans for the next No changes. 18 months Other Comment PM2.5 and PM10 are collocated for precision measurements; daily sampling began in 2007 for Fine Particles (AQS code 88101); prior to 2007, every 3 day sampling. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 AQS Spatial Scale 42 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Leonia Overpeck Park, 40 Fort Lee Road Leonia, NJ, 07605 34 003 0006 Bergen New York-Northeast New JerseyConnecticut CSA 40.870422 -73.992053 12/7/2007 Latitude Longitude Date Established Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) AQS Parameter Code 44201 Sampling Instrument Dasibi 1008 Method of Analysis Ultraviolet AQS Method Code 056 AQS Sample Frequency Continuous Site Purpose To measure population exposure in the Leonia and Teaneck areas. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 43 AQS Spatial Scale Neighborhood AQS Monitoring Objective Population Exposure SITE INFORMATION Site Name Millville Lincoln Ave. & Route 55, Northeast Address of Millville City, State, Zip Millville, NJ 08332 AQS Code 34 011 0007 NJ County Cumberland MSA/CSA Vineland-Millville-Bridgeton MSA Latitude 39.422273 Longitude -75.025204 Date Established 1/1/1983 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Ozone (O3) AQS Parameter Code 42601 42602 AQS Method Code 074 074 AQS Sample Frequency Continuous Continuous AQS Spatial Scale Neighborhood Neighborhood AQS Monitoring Objective Population Exposure Population Exposure Sampling Instrument TECO 42 TECO 42 Method of Analysis Chemiluminescence Chemiluminescence 42603 TECO 42 Chemiluminescence 074 Continuous Neighborhood Population Exposure 44201 Dasibi 1008 R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Ultraviolet Gravimetric, Total Atmospheric PM2.5 Gravimetric, Acceptable PM2.5 056 Continuous Neighborhood Population Exposure 760 Continuous Neighborhood Population Exposure 703 Continuous Neighborhood Population Exposure Real-time PM2.5 88500 Real-time PM2.5 88502 Site Purpose To measure population exposure in the Vineland and Millville areas. Plans for the next No changes. 18 months Other Comment NO, NO2, and NOx data are not submitted to USEPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 44 SITE INFORMATION Site Name Monmouth University Edison Science Bldg., 400 Cedar Address Ave. City, State, Zip West Long Branch, NJ 07764 AQS Code 34 025 0005 NJ County Monmouth New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.278461 Longitude -74.005343 Date Established 5/13/1989 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) AQS Parameter Code 44201 Sampling Instrument TECO 49 Method of Analysis Ultraviolet AQS Method Code 047 AQS Sample Frequency Continuous Site Purpose To measure highest concentrations of ozone in the eastern Monmouth County area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 45 AQS Spatial Scale Neighborhood AQS Monitoring Objective Highest Concentration SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Morristown Ambulance Squad 16 Early St. Morristown, NJ 07960 34 027 0004 Morris New York-Northeast New JerseyConnecticut CSA 40.801211 -74.483433 5/30/1989 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure population exposure in the Morristown area. Plans for the next No changes. 18 months Other Comment PM2.5 was proposed to be shut down in 2010 Network Plan, but not approved by USEPA. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 46 SITE INFORMATION Site Name New Brunswick Cook College, Log Cabin Rd. near Address Horticulture Lab City, State, Zip New Brunswick, NJ 08901 AQS Code 34 023 0006 NJ County Middlesex New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.472786 Longitude -74.422515 Date Established 1/1/1981 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Real-time PM2.5 88500 Real-time PM2.5 88502 PM2.5 Speciation Volatile Organic Compounds Carbonyls Mercury (Hg) Appendix A Sampling Instrument R&P 2025 Low-volume sequential sampler R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Met One Appendix B Appendix C Method of Analysis Gravimetric AQS Method Code AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective 118 Every 3 days Neighborhood Population Exposure 760 Continuous Neighborhood Population Exposure Gravimetric, Total Atmospheric PM2.5 Gravimetric, Acceptable PM2.5 XRF, IC, TOA 703 Continuous Neighborhood Population Exposure App. A Every 3 days Neighborhood Population Exposure Canister TO-15 App. B Every 6 days Neighborhood Population Exposure DNPH cartridge Tekran 2537A TO-11A CVAF Spectrometry App. C Every 6 days Hourly Neighborhood Neighborhood Population Exposure Population Exposure Site Purpose To measure population exposure in the New Brunswick area. Plans for the next No changes. 18 months Other Comment PM2.5 Speciation is collocated for precision. See Appendices A, B and C for more information on PM2.5 Speciation, Volatile Organic Compounds and Carbonyls. Mercury data not submitted to EPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 47 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Newark Firehouse 360 Clinton Avenue Newark, NJ 07108 34 013 0003 Essex New York-Northeast New JerseyConnecticut CSA 40.721019 -74.192808 5/1/2009 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter Carbon Monoxide (CO) Nitric Oxide (NO) NOy-NO Difference Total ReactiveOxides of Nitrogen (NOy) Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Ozone (O3) Sulfur Dioxide (SO2) AQS Parameter Code 42101 42601 42612 AQS Method Code 554 574 574 AQS Sample Frequency Continuous Continuous Continuous AQS Spatial Scale Neighborhood Neighborhood Neighborhood AQS Monitoring Objective Population Exposure Population Exposure Population Exposure Sampling Instrument TECO 48iTLE TECO 42CY TECO 42CY Method of Analysis Nondispersive-infrared Chemiluminescence Chemiluminescence 42600 TECO 42CY Chemiluminescence 574 Continuous Neighborhood Population Exposure 42601 42602 TECO 42i TECO 42i Chemiluminescence Chemiluminescence 074 074 Continuous Continuous Neighborhood Neighborhood Population Exposure Population Exposure 42603 TECO 42i Chemiluminescence 074 Continuous Neighborhood Population Exposure 44201 42401 TECO 49i TECO 43iTLE R&P 2025 Low-volume sequential sampler R&P 2000 Low-volume single sampler Ultraviolet Pulsed fluorescence 047 560 Continuous Continuous Neighborhood Neighborhood Population Exposure Highest Concentration Gravimetric 118 Every 3 days Neighborhood Population Exposure XRF with PM10 817 Every 6 days Neighborhood Population Exposure Fine Particles (PM2.5) 88101 Lead (Pb) 85128 Continued on next page NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 48 PARAMETER SUMMARY (Newark Firehouse, continued) AQS Parameter Code Parameter Real-time PM2.5 88500 Real-time PM2.5 88502 PM2.5 Speciation Barometric Pressure Relative Humidity Solar Radiation Temperature Resultant Wind Direction Resultant Wind Speed Site Purpose Plans for the next 18 months Other Comment Appendix A 64101 62201 63301 62101 61104 61103 Sampling Instrument R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Met One Qualimetrics Qualimetrics Qualimetrics Qualimetrics Qualimetrics Method of Analysis Gravimetric, Total atmospheric PM2.5 Gravimetric, Acceptable PM2.5 XRF, IC, TOA Pressure transducer Capacitive sensor Pyrometer Thermistor Qualimetrics AQS Method Code AQS Sample Frequency AQS Monitoring Objective 760 Continuous Neighborhood Population Exposure 703 Continuous Neighborhood Population Exposure App. A 011 011 011 020 Every 3 days Continuous Continuous Continuous Continuous Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Population Exposure Wind vane 020 Continuous Neighborhood Anemometer 020 Continuous Neighborhood New Jersey’s NCore site. PM coarse will be established by 12/31/12, plan to add measurement of benzene, toluene, ethylbenzene, xylene (BTEX) and black carbon. CO and SO2 data are measured by “trace-level” analyzers. See Appendix A for more information on PM2.5 Speciation. Pb monitor established on 01/04/12. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 AQS Spatial Scale 49 SITE INFORMATION Site Name Paterson Health Department, 176 Broadway Address Ave. City, State, Zip Paterson, NJ 07505 AQS Code 34 031 0005 NJ County Passaic New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.918381 Longitude -74.168092 Date Established 1/1/1978 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure population exposure in the Paterson area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 50 SITE INFORMATION Site Name Pennsauken Morris Delair Water Treatment Address Plant, off Griffith-Morgan Lane City, State, Zip Pennsauken, NJ 08110 AQS Code 34 007 1007 NJ County Camden Philadelphia-Camden-Wilmington MSA/CSA CSA Latitude 39.989036 Longitude -75.050008 Date Established 9/1/1983 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure population exposure in the Pennsauken area. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 51 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Phillipsburg Municipal Bldg., 675 Corliss Ave. Phillipsburg, NJ 08865 34 041 0006 Warren Allentown-Bethlehem-Easton, PANJ MSA 40.699207 -75.180525 8/10/1999 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure population exposure in the Phillipsburg area, and to measure transported fine particle concentrations. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 52 SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Rahway Fire Dept. Bldg., 1300 Main St. Rahway, NJ 07065 34 039 2003 Union New York-Northeast New JerseyConnecticut CSA 40.603943 -74.276174 12/11/1999 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Real-time PM2.5 88502 Sampling Instrument R&P 2025 Low-volume sequential sampler R&P 1400 TEOM Method of Analysis AQS Method Code AQS Sample Frequency AQS Monitoring Objective Gravimetric 118 Daily Neighborhood Population Exposure Gravimetric, Acceptable PM2.5 711 Continuous Neighborhood Population Exposure Site Purpose To measure population exposure in the Rahway area. Plans for the next No changes. 18 months Other Comment TEOM analyzer is operating without the FDMS at 50o Celsius. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 AQS Spatial Scale 53 SITE INFORMATION Site Name Ramapo Ramapo Mountain State Forest, Address Access Rd., off Skyline Drive, Wanaque Borough City, State, Zip Wanaque, NJ 07465 AQS Code 34 031 5001 NJ County Passaic New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 41.058572 Longitude -74.255419 Date Established 6/5/1998 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) AQS Parameter Code 44201 Sampling Instrument Dasibi 1008 Method of Analysis Ultraviolet AQS Method Code 056 AQS Sample Frequency Continuous Site Purpose To measure background, transport and upwind concentrations of ozone. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 54 AQS Spatial Scale Urban AQS Monitoring Objective Background SITE INFORMATION Site Name Rider University Athletic Fields, Route 206 South, Address Lawrence Township City, State, Zip Lawrenceville, NJ 08648 AQS Code 34 021 0005 NJ County Mercer MSA/CSA Trenton-Ewing MSA Latitude 40.283092 Longitude -74.742644 Date Established 6/1/1981 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Ozone (O3) Barometric Pressure Relative Humidity Solar Radiation Temperature Wind Direction Wind Speed AQS Parameter Code 44201 64101 62201 63301 62101 61102 61101 Sampling Instrument Dasibi 1008 Qualimetrics Qualimetrics Qualimetrics Qualimetrics Qualimetrics Qualimetrics Method of Analysis Ultraviolet Instrumental aneroid Hydrothermograph Pyrometer Thermistor, spot rdg. Wind vane, spot rdg. Anemometer, spot rdg. AQS Method Code 056 011 013 011 020 020 020 AQS Sample Frequency Continuous Continuous Continuous Continuous Continuous Continuous Continuous Site Purpose To measure population exposure and ozone precursors. Plans for the next None. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 55 AQS Spatial Scale Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood AQS Monitoring Objective Population Exposure SITE INFORMATION Site Name Rutgers University Horticultural Farm #3, off Ryder's Address Lane City, State, Zip New Brunswick, NJ 08901 AQS Code 34 023 0011 NJ County Middlesex New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 40.462182 Longitude -74.429439 Date Established 10/1/1994 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter Nitric Oxide (NO) Nitrogen Dioxide (NO2) Oxides of Nitrogen (NOx) Ozone (O3) Ozone Precursors AQS Parameter Code 42601 42602 42603 44201 Appendix D Sampling Instrument TECO 42 TECO 42 Method of Analysis Chemiluminescence Chemiluminescence TECO 42 Chemiluminescence Dasibi 1008 Perkin Elmer Ultraviolet Auto GC-FID AQS Method Code 074 074 AQS Sample Frequency Continuous Continuous AQS Spatial Scale Neighborhood Neighborhood AQS Monitoring Objective Population Exposure Population Exposure 074 Continuous Neighborhood Population Exposure 056 App. D Continuous Hourly Neighborhood Urban Population Exposure Background Site Purpose To measure population exposure and ozone precursors – downwind for Philadelphia metropolitan area and upwind for New York metropolitan area. Plans for the next No changes. 18 months Other Comment Upper air and lower air meteorological measurements are collected at this site by Rutgers University; see Appendix D for more information on Ozone Precursors, also known as PAMS. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 56 SITE INFORMATION Site Name South Camden Camden County Municipal Utilities Address Authority, 1645 Ferry Ave City, State, Zip Camden, NJ 08104 AQS Code 34 007 0010 NJ County Camden Philadelphia-Camden-Wilmington MSA/CSA CSA Latitude 39.923969 Longitude -75.122317 Date Established 11/20/2003 Suitable for Comparison to Not Applicable PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Real-time PM2.5 88500 Real-time PM2.5 88502 Sampling Instrument R&P 1400 TEOMFDMS R&P 1400 TEOMFDMS Method of Analysis Gravimetric, Total Atmospheric PM2.5 Gravimetric, Acceptable PM2.5 AQS Method Code AQS Sample Frequency AQS Monitoring Objective 760 Continuous Neighborhood Highest Concentration 703 Continuous Neighborhood Highest Concentration Site Purpose To measure population exposure in the South Camden area. Plans for the next No changes. 18 months Other Comment Real-time PM2.5 data is not submitted to USEPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 AQS Spatial Scale 57 SITE INFORMATION Site Name Toms River Hooper Avenue Elementary Address School, 1517 Hooper Avenue City, State, Zip Toms River, NJ 08753 AQS Code 34 029 2002 NJ County Ocean New York-Northeast New JerseyMSA/CSA Connecticut CSA Latitude 39.994908 Longitude -74.170447 Date Established 2/11/1999 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency Daily Site Purpose To measure population exposure in the Toms River area. Plans for the next No changes. 18 months Other Comment Daily sampling began in 2007; prior to 2007, every 3 day sampling. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 58 AQS Spatial Scale AQS Monitoring Objective Neighborhood Population Exposure SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Latitude Longitude Date Established Suitable for Comparison to PM2.5 NAAQS? Trenton Trenton Library, 120 Academy St. Trenton, NJ 08608 34 021 0008 Mercer Trenton-Ewing MSA 40.222411 -74.763167 9/1/1982 Yes PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis Gravimetric AQS Method Code 118 AQS Sample Frequency Daily Site Purpose To measure population exposure in the downtown commercial district of Trenton. Plans for the next No changes. 18 months Other Comment Daily sampling began in 2007 for Fine Particles (AQS code 88101); prior to 2007, every 3 day sampling. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 59 AQS Spatial Scale AQS Monitoring Objective Neighborhood Population Exposure SITE INFORMATION Site Name Address City, State, Zip AQS Code NJ County MSA/CSA Union City Health Department, 714 31st St. Union City, NJ 07087 34 017 2002 Hudson New York-Northeast New JerseyConnecticut CSA 40.772793 -74.031718 1/1/1983 Latitude Longitude Date Established Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Sampling Instrument R&P 2025 Low-volume sequential sampler Method of Analysis AQS Method Code Gravimetric 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Site Purpose To measure population exposure in the Union City and Hudson County areas. Plans for the next No changes. 18 months Other Comment NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 60 SITE INFORMATION Site Name Washington Crossing Washington Crossing State Park, Address near 66 Church Rd. City, State, Zip Titusville, NJ 08560 AQS Code 34 021 8001 NJ County Mercer MSA/CSA Trenton-Ewing MSA Latitude 40.315350 Longitude -74.853617 Date Established 1/1/1989 Suitable for Comparison to Yes PM2.5 NAAQS? PARAMETER SUMMARY Parameter AQS Parameter Code Fine Particles (PM2.5) 88101 Acid Deposition Acid Deposition Sampling Instrument R&P 2025 Low-volume sequential sampler Bucket Bucket Method of Analysis Gravimetric Ion Chromatography Ion Chromatography AQS Method Code 118 AQS Sample Frequency AQS Spatial Scale AQS Monitoring Objective Every 3 days Neighborhood Population Exposure Weekly Event Neighborhood Neighborhood Population Exposure Population Exposure Site Purpose To measure population exposure and transported fine particle concentrations. Plans for the next The collection and analysis of Event Acid Deposition samples shutdown on December 31, 2011. 18 months Other Comment The Weekly Acid Deposition samples are sent to the National Atmospheric Deposition Program (NADP) for analysis, the Event Acid Deposition samples are analyzed by the Bureau of Air Monitoring, the Weekly and Event Acid Deposition data are not submitted by NJDEP or NADP to EPA’s AQS database. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 61 GLOSSARY OF ABBREVIATIONS AND TERMS ABBREVIATIONS AQI – Air Quality Index, a national air quality rating system based on the National Ambient Air Quality Standards AQS – Air Quality Subsystem, USEPA’s database for air quality data nationwide BTEX – benzene, toluene, ethylbenzene and xylene; analyzer that measures all 4 chemicals CSA – Combined Statistical Area, defined by U.S. Office of Management and Budget as a geographic area having 2 or more Metropolitan Statistical Areas, also Core-Based Statistical Area (CBSA) CFR – Code of Federal Regulations CO – Carbon monoxide CVAF Spectrometry – Cold Vapor Atomic Fluorescence Spectrometry, method for analyzing Mercury DNPH cartridge – Di-Nitro-Phenyl-Hydrazine, an adsorbent for trapping carbonyls in air auto GC-FID – automated Gas Chromatograph Flame Ionization Detection Hg – Mercury IC – Ion Chromatography, a method for analyzing for ionic compounds from Fine Particles IMPROVE – Interagency Monitoring of Protected Visual Environments MSA – Metropolitan Statistical Area, 1 or more counties having a population greater than 50,000 NAAQS – National Ambient Air Quality Standard NCore – National Core, a monitoring site having a group of parameters specified by the USEPA NJDEP – New Jersey Department of Environmental Protection NO – Nitric Oxide NO2 – Nitrogen Dioxide NOx – Oxides of Nitrogen NOy – Total Reactive Oxides of Nitrogen O3 – Ozone PAMS – Photochemical Assessment Monitoring Station, sites which measure ozone precursors Pb – Lead PM2.5 – Fine Particles, particles 2.5 micrometers in aerodynamic diameter or smaller PM10 – Inhalable Particles, particles 10 micrometer in aerodynamic diameter or smaller PM10-2.5 – Coarse Particles, particles between 10 and 2.5 micrometers in aerodynamic diameter PM2.5-Speciation – a group of elements, ionic compounds and carbon compounds that are analyzed from Fine Particles R&P 1400 – the instrument manufactured by Rupprecht and Pattashnik to measure real-time PM2.5 R&P 2025 – the instrument manufactured by Rupprecht and Pattashnik to measure PM2.5, data from this instrument can be used for comparison to the NAAQS RRF – Resource Recovery Facility, trash incineration facility SLAMS – State and Local Air Monitoring Station, designation for monitoring sites or samplers, the data from which can be used for comparison to the National Ambient Air Quality Standards SO2 – Sulfur Dioxide SPM – Special Purpose Monitor, designation for monitoring sites or samplers, the data from which are not used for comparison to the National Ambient Air Quality Standards STN – Speciation Trends Network TEOM-FDMS – Tapered Element Oscillating Microbalance with Filter Dynamic Measurement System, the analytical method used by an R&P 1400 to measure real-time PM2.5 TECO 42 – the instrument manufactured by Thermo Environmental Corp. to measure nitrogen dioxide, nitric oxide and oxides of nitrogen TECO 43A – the instrument manufactured by Thermo Environmental Corp. to measure sulfur dioxide TECO 48 – the instrument manufactured by Thermo Environmental Corp. to measure carbon monoxide TECO 49 – the instrument manufactured by Thermo Environmental Corp. to measure ozone TLE – Trace Level Enhanced, type of analyzer which measures very low concentrations TO-11A – a standard method approved by the USEPA to analyze carbonyls TO-15 – a standard method approved by the USEPA to analyze Volatile Organic Compounds TOA – Thermal Optic Analysis, a method for analyzing carbon compounds from Fine Particles NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 62 Total NMOC – Non-methane Organic Compound, all compounds except Methane TSP – Total Suspended Particles, all particles that are captured by a high-volume sampler USEPA – United States Environmental Protection Agency VOC – Volatile Organic Compound, a carbon-based chemical that is gaseous XRF – X-ray Fluorescence, a method for analyzing elements from Fine Particles TERMS Acid Deposition – acid rain, the phenomenon where air pollutants raise the acidity of rain and snow Ambient air – air in areas that are accessible to the general public Anemometer – an instrument used for measuring wind speed Atomic Absorption – the method used for analyzing for lead from Total Suspended Particles Background – a monitoring site in an area which is not affected by air pollution sources Canister – a stainless steel container used for collecting an air sample to be analyzed for VOCs Capacitive Sensor – an instrument used for measuring relative humidity Carbonyls – a group of aldehydes, or a carbon chain with an oxygen molecule at one end Chemiluminescence – the method used for analyzing for NO, NO2 and NOx Coarse Particles – also PM10-2.5, particles between 10 and 2.5 micrometers in aerodynamic diameter Collocated – operating two samplers side by side in order to collect data used for precision statistics Continuous – an instrument that collects data instantaneously, without stopping, throughout the year, and transmits the data to a central data acquisition system every minute Fine Particles – also PM2.5, particles 2.5 micrometers in aerodynamic diameter or smaller Gravimetric – weighing a filter in a controlled environment by a highly accurate balance High-volume Sampler – an instrument used to collect Total Suspended Particles Highest Concentration – a monitoring instrument or site which is designated to measure the maximum concentration of a pollutant in a given area Inhalable Particles – also PM10, particles 10 micrometers in aerodynamic diameter or smaller Ion Chromatography – also IC, a method used for analyzing for ionic compounds Manual – an instrument that collects an air sample over a 24-hour filter on a filter, adsorbent cartridge or canister which is then manually retrieved for subsequent analysis Met One – a manufacturer of PM2.5 Speciation samplers Micro Scale – the spatial scale of a monitoring site, from 10 – 100 meters around the monitor Middle Scale – the spatial scale of a monitoring site, from 100 –1000 meters around the monitor Neighborhood Scale – the spatial scale of a monitoring site, from 1 km to 10 kms around the monitor Nephelometer – an instrument that measures fine particles by light scattering Nondispersive-infrared – the method used for analyzing for carbon monoxide Ozone Precursors – a group of 55 volatile organic compounds that affect ozone formation and destruction in the atmosphere, also called PAMS pollutants PerkinElmer – the manufacturer of an automated GC-FID Population Exposure – a monitoring instrument or site that is designated to measure the concentrations of a pollutant in a highly populated area Pressure Transducer – an instrument used for measuring barometric pressure Pulsed fluorescence – the method used for analyzing for sulfur dioxide Pyrometer – the method used for measuring solar radiation Qualimetrics – the manufacturer of meteorological instruments Real-time PM2.5 – PM2.5 concentrations that are measured continuously Regional Scale – the spatial scale of a monitoring site, from 100 kms to 1000 kms around the monitor SierraAnderson – the manufacturer of PM10 samplers Smoke Shade – an index of TSP by the measurement of light diminishment due to particles Solar Radiation – the intensity of energy from sunlight Tape Sampler – an instrument that measures TSP by collecting particles on a roll of filter paper which is automatically forwarded hourly Thermistor – an instrument that measures temperature Ultraviolet – the method used for analyzing ozone Urban Scale – the spatial scale of a monitoring site, from 10 kms to 100 kms around the monitor Wallace Fisher – the manufacturer of smoke shade analyzers NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 63 REFERENCES “2010 Network Summary,” 2010 Air Quality Report, URL: http://www.njaqinow.net/. “About AIRNow,” URL: http://www.airnow.gov/index.cfm?action=topics.about_airnow. “Combined Statistical Areas And Component Core Based Statistical Areas”, November 2004, http://www.census.gov/population/estimates/metro-city/List6.txt. “Fact Sheet: Final Revisions To The National Ambient Air Quality Standards For Nitrogen Dioxide,” January 2010, URL: http://www.epa.gov/air/nitrogenoxides/pdfs/20100122fs.pdf. “Fact Sheet: National Ambient Air Quality Standards For Carbon Monoxide – Final Rule,” August 2011, URL: http://www.epa.gov/airquality/carbonmonoxide/pdfs/COFactSheetAugust12v4.pdf “Fact Sheet: Proposal To Revise The National Ambient Air Quality Standards For Ozone,” January 2010, URL: http://www.epa.gov/air/ozonepollution/pdfs/fs20100106std.pdf. “Fact Sheet - Revisions to Lead Ambient Air Monitoring Requirements,” December 2010, URL: http://www.epa.gov/airquality/lead/pdfs/Leadmonitoring_FS.pdf. “Fact Sheet: Revisions To The Primary National Ambient Air Quality Standards, Monitoring Network, and Data Reporting Requirements For Sulfur Dioxide,” June 2010, http://www.epa.gov/air/sulfurdioxide/pdfs/20100602fs.pdf. "Guidance for Network Design and Optimum Site Exposure for PM2.5 and PM10", EPA-454R-99-022, December 1997, URL: http://www.epa.gov/ttn/amtic/files/ambient/pm25/network/r-99-022.pdf. "Guideline on Ozone Monitoring Site Selection, EPA-454/R-98-002, August 1998, URL: http://www.epa.gov/ttnamti1/archive/files/ambient/criteria/reldocs/r-98-002.pdf. “IMPROVE Monitoring Program”, URL: http://vista.cira.colostate.edu/improve/Overview/Overview.htm. “Lead Monitoring,” URL: http://www.epa.gov/ttn/amtic/pb-monitoring.html. “Metropolitan Statistical Areas And Components”, November 2004, URL: http://www.census.gov/population/estimates/metro-city/List4.txt. “National Ambient Air Quality Standards for Particulate Matter, Part 50”, 71 Federal Register 61224, October 17, 2006, URL: http://www.epa.gov/ttn/amtic/files/ambient/pm25/pt5006.pdf. “Near-Road NO2 Monitoring Technical Assistance Document, DRAFT,” December 21, 2011, URL: http://www.epa.gov/ttn/amtic/files/nearroad/20111221tad.pdf “Quality Assurance Handbook for Air Pollution Measurement Systems, Volume II, Ambient Air Quality Monitoring Program”, EPA-454/B-08-003, URL: http://www.epa.gov/ttn/amtic/files/ambient/pm25/qa/QAHandbook-Vol-II.pdf. “Technical Assistance Document (TAD) for Sampling and Analysis of Ozone Precursors”, EPA/600-R98/161, September 1998, URL: http://www.epa.gov/ttn/amtic/files/ambient/pams/newtad.pdf. “Valid Protocols with Sampling Methodologies”, November 11, 2007, URL: http:www.epa.gov/ttn/airs/airsaqs/manuals/Protocols%20Sampl%20Meth%20-%20all.xls. NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 64 APPENDIX A: VOLATILE ORGANIC COMPOUNDS Parameter 1,1,1-Trichloroethane 1,1,2,2Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,4-Trichlorobenzene 1,2,4Trimethylbenzene 1,2-Dibromoethane 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5Trimethylbenzene 1,3-Butadiene Acetonitrile Acetylene Acrolein Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon Disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloromethylbenzene Chloroprene AQS Parameter Code 43814 AQS Method Code 101 Sampling Instrument Canister Method of Analysis TO-15 43818 Canister TO-15 101 43820 43813 43826 45810 Canister Canister Canister Canister TO-15 TO-15 TO-15 TO-15 101 101 101 101 45208 Canister TO-15 101 43843 43815 43829 Canister Canister Canister TO-15 TO-15 TO-15 101 101 101 45207 Canister TO-15 101 43218 43702 43206 43505 43704 45201 43836 43828 43806 43819 42153 43804 45801 43812 43803 43801 45809 43835 Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 65 APPENDIX A: VOLATILE ORGANIC COMPOUNDS Parameter cis-1,2-Dichloroethylene cis-1,3-Dichloropropene Dibromochloromethane Dichlorodifluoromethane Dichloromethane Dichlorotetrafluoroethane Ethyl Acrylate Ethyl tert-Butyl Ether Ethylbenzene Hexachloro-1,3Butadiene m,p-Xylene m-Dichlorobenzene Methyl Ethyl Ketone Methyl Isobutyl Ketone Methyl Methacrylate Methyl tert-Butyl Ether n-Octane o-Dichlorobenzene o-Xylene p-Dichlorobenzene Propylene Styrene tert-Amyl Methyl Ether Tetrachloroethylene Toluene trans-1,2Dichloroethylene trans-1,3Dichloropropene Trichloroethylene Trichlorofluoromethane Trichlorotrifluoroethane Vinyl Chloride AQS Parameter Code 43839 43831 43832 43823 43802 43208 43438 43396 45203 (Continued) AQS Method Code 101 101 101 101 101 101 101 101 101 Sampling Instrument Canister Canister Canister Canister Canister Canister Canister Canister Canister Method of Analysis TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 43844 Canister TO-15 101 45109 45806 43552 43560 43441 43372 43233 45805 45204 45807 43205 45220 43373 43817 45202 Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister Canister TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 TO-15 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 43838 Canister TO-15 101 43830 Canister TO-15 101 43824 43811 43821 43860 Canister Canister Canister Canister TO-15 TO-15 TO-15 TO-15 101 101 101 101 NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 66 APPENDIX B: CARBONYLS Parameter 2,5-dimethylbenzaldehyde Acetaldehyde Acetone Benzaldehyde Butyraldehyde Crotonaldehyde Formaldehyde Hexaldehyde Isovaleraldehyde Propionaldehyde Tolualdehydes Valeraldehyde AQS Parameter Code Sampling Instrument Method of Analysis AQS Method Code 45503 DNPH Cartridge TO-11A 202 43503 43551 45501 43329 43528 43502 43517 43513 43504 45504 43518 DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge DNPH Cartridge TO-11A TO-11A TO-11A TO-11A TO-11A TO-11A TO-11A TO-11A TO-11A TO-11A TO-11A 202 202 202 202 202 202 202 202 202 202 202 NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 67 APPENDIX C: PM2.5 SPECIATION Parameter Aluminum Ammonium Antimony Arsenic Barium Bromine Cadmium Calcium Cerium Cesium Chlorine Chromium Cobalt Copper Elemental Carbon Improve TOR Elemental Carbon Improve TOT Indium Iron Lead Magnesium Manganese Nickel Nitrate Organic Carbon Improve TOR Organic Carbon Improve TOT Organic & Elemental Carbon Improve OP TOR Organic & Elemental Carbon Improve OP TOT Particulate matter 2.5u Phosphorus Phosphorus AQS Parameter Code Method of Analysis AQS Method Code 88104 88301 88102 88103 88107 88109 88110 88111 88117 88118 88115 88112 88113 88114 88380 88357 88131 88126 88128 88140 88132 88136 88306 88370 88355 Sampling Instrument Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS URG 3000N URG 3000N Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS URG 3000N URG 3000N Energy Dispersive XRF Ion Chromatography Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Thermal Optic Analysis Thermal Optic Analysis Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Ion Chromatography Thermal Optic Analysis Thermal Optic Analysis 811 812 811 811 811 811 811 811 811 811 811 811 811 811 831 840 811 811 811 811 811 811 812 838 839 88378 URG 3000N Thermal Optic Analysis 842 88388 URG 3000N Thermal Optic Analysis 826 88502 88152 88152 Met One SASS Met One SASS Met One SASS Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF 810 811 811 NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 68 APPENDIX C: PM2.5 SPECIATION (Continued) Parameter Potassium Potassium Rubidium Selenium Silicon Silver Sodium Sodium Strontium Sulfate Sulfur Tin Titanium Vanadium Zinc Zirconium AQS Parameter Code 88180 88303 88176 88154 88165 88166 88184 88302 88168 88403 88169 88160 88161 88164 88167 88185 Sampling Instrument Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS Met One SASS NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 Method of Analysis Energy Dispersive XRF Ion Chromatography Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Ion Chromatography Energy Dispersive XRF Ion Chromatography Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF AQS Method Code 811 812 811 811 811 811 811 812 811 812 811 811 811 811 811 811 69 APPENDIX D: OZONE PRECURSORS Parameter Sum Of PAMS Total NMOC N-Dodecane Ethane Ethylene Propane Propylene Acetylene N-Butane Isobutane Trans-2-Butene Cis-2-Butene N-Pentane Isopentane 1-Pentene Trans-2-Pentene Cis-2-Pentene 2-Methyl-2-Butene 3-Methylpentane N-Hexane N-Heptane N-Octane 4-Methyl-1-Pentene N-Nonane N-Decane Cyclopentane Isoprene 2,2-Dimethylbutane 1-Hexene 2-Methyl-1-Pentene 2,4-Dimethylpentane Cyclohexane 3-Methylhexane 2,2,4-Trimethylpentane 2,3,4-Trimethylpentane AQS Parameter Code 43000 43102 43141 43202 43203 43204 43205 43206 43212 43214 43216 43217 43220 43221 43224 43226 43227 43228 43230 43231 43232 43233 43234 43235 43238 43242 43243 43244 43245 43246 43247 43248 43249 43250 43252 Sampling Instrument PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 Method of Analysis Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID AQS Method Code 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 70 APPENDIX D: OZONE PRECURSORS (Continued) Parameter 3-Methylheptane Alpha.-Pinene Beta.-Pinene Methylcyclohexane Methylcyclopentane 2-Methylhexane 1-Butene 3-Methyl-1-Butene Cyclopentene 2,3-Dimethylbutane 2-Methylpentane Trans-2-Hexene Cis-2-Hexene 2,3-Dimethylpentane N-Undecane 2-Methylheptane Isomers Of Ethyltoluene M/P Xylene M/P Ethyltoluene Benzene Toluene Ethylbenzene O-Xylene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene N-Propylbenzene Isopropylbenzene O-Ethyltoluene M-Ethyltoluene P-Ethyltoluene M-Diethylbenzene P-Diethylbenzene Styrene 1,2,3-Trimethylbenzene AQS Parameter Code 43253 43256 43257 43261 43262 43263 43280 43282 43283 43284 43285 43289 43290 43291 43954 43960 45104 45109 45116 45201 45202 45203 45204 45207 45208 45209 45210 45211 45212 45213 45218 45219 45220 45225 Sampling Instrument PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer PerkinElmer NEW JERSEY AMBIENT AIR MONITORING NETWORK PLAN 2012 Method of Analysis Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID Auto-GC-FID AQS Method Code 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 078 71
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