2/3/2014 Ch. 4 - Chemical Bonding: Understanding Climate Change Chapter Outline 4.1 Types of Chemical Bonds 4.2 Naming Compounds and Writing Formulas 4.3 Lewis Structures 4.4 Electronegativity, Unequal Sharing, and Polar Bonds 4.5 Vibrating Bonds and the Greenhouse Effect 4.6 Resonance 4.7 Formal Charge: Choosing among Lewis Structures 4.8 Exceptions to the Octet Rule 4.8 The Lengths and Strengths of Covalent Bonds Chemical Bonds Types of Chemical Bonds Ionic Metallic Covalent Types of chemical bonds: • • • Ionic Bonds ∝ Ionic Bond – electrons transferred: chemical bond resulting from the electrostatic attraction of a cation for an anion. Covalent Bond – chemical bond that results from a sharing of outermost electrons. Metallic Bond – chemical bond consisting of the nuclei of metal atoms surrounded by a “sea” of shared electrons. Sample Exercise 4.1: Calculating the electrostatic Potential Energy of an Ionic Bond What is the electrostatic potential energy (Eel) of the ionic bond between a potassium ion and a chloride ion? 2.31 10 ∙ 1 2/3/2014 Covalent Bonds Lattice Energy (U) • The energy released when one mole of an ionic compound forms from its free ions in the gas phase. H2 ∝ • As charges increase, so does the lattice energy • As the distance between ions decreases, the lattice energy increases Metallic Bonds Bond Type Summary Cu = [Ar]3d104s1 3d10 4s1 2
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