THE ASTROPHYSICAL JOURNAL, 544 : 508È521, 2000 November 20 ( 2000. The American Astronomical Society. All rights reserved. Printed in U.S.A. IDENTIFICATION OF SPECTRAL LINES IN THE 500È1600 A WAVELENGTH RANGE OF HIGHLY IONIZED Ne, Na, Mg, Ar, K, Ca, Ti, Cr, Mn, Fe, Co, AND Ni EMITTED BY FLARES (T º 3 ] 106 K) e AND THEIR POTENTIAL USE IN PLASMA DIAGNOSTICS U. FELDMAN,1 W. CURDT,2 E. LANDI,2 AND K. WILHELM2 Received 2000 April 6 ; accepted 2000 June 29 ABSTRACT On 1999 May 9 the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) spectrometer on the Solar and Heliospheric Observatory (SOHO) recorded spectra from a high-temperature region located in the solar corona above the west limb. These spectra contain lines from rather less-abundant elements in solar plasmas. In this paper we present identiÐcations of the high-temperature (T º 3 ] 106 K) Ne, e Na, Mg, Ar, K, Ca, Ti, Cr, Mn, Fe, Co, and Ni lines that were detected in the 500È1600 A spectral range of SUMER. In addition, accurate wavelength measurements have been obtained with uncertainties varying between 0.015 and 0.040 A (1 p). Making use of the newly measured wavelengths, we derive energy levels in the ground conÐguration of a number of highly charged ions. We present intensity ratio calculations of lines in the SUMER range that could be used to measure electron densities in hightemperature solar plasmas. We also provide emissivities for Ca XIIIÈCa XV and Fe XVIIIÈFe XXIII lines that could be used to determine emission measures and electron temperatures of high-temperature plasmas. We discuss a method for measuring elemental abundance variations in high-temperature solar plasmas using lines presented in the paper. A list of spectral lines spanning the 300È30000 A wavelength range and their branching ratios that are suitable for efficiency calibration of space-borne spectrographs is provided. Subject headings : line : identiÐcation È Sun : abundances È Sun : corona È Sun : Ñares È Sun : UV radiation 1. INTRODUCTION to determine the electron densities, electron temperatures, emission measure distributions, mass motions, and the state of ionization equilibrium of the plasmas. The lines emitted by ions from many di†erent elements can also be used to determine the relative elemental abundances in hot astrophysical plasmas. The scope of this paper is to derive analysis methods for plasma diagnostics. A future paper will apply these methods to the 1999 May 9 Ñare. In ° 2 of the paper we brieÑy discuss the SUMER instrument, and in ° 3 data acquisition and reduction are described. The identiÐcations of the hightemperature lines, their wavelengths, and the energy levels inferred from them are discussed in ° 4. In ° 5 we discuss line intensity ratios, which could be used to derive electron densities. Section 6 deals with emission measure determinations, and ° 7 with electron temperature determinations and the state of ionization equilibrium using hightemperature lines emitted in the 500È1600 A range. Elemental abundance determinations are discussed in ° 8, and in ° 9 we explore the possibility of using sets of the forbidden lines for efficiency calibration of spectrometers. On 1999 May 9 the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) spectrograph on the Solar and Heliospheric Observatory (SOHO) recorded farultraviolet spectra from a bright region of the corona located above the west limb. During the 6 hours and 40 minutes of observations the instrument obtained two complete spectra spanning the entire SUMER wavelength range from 500 to 1610 A . The spectral recordings were done in sections of 43 A , where for each section the start wavelength was advanced by B 20 A relative to the preceding section. The integration time at each 43 A section was 300 s. The tenth Geostationary Operational Environmental Satellite (GOES 10) records show the eruption of several Ñares of di†erent sizes on the Sun from about 12 : 00 UT. In a companion paper based on images from SUMER, EIT, Y ohkohSXT, and the MICA coronagraph data, D. E. Innes (2000, private communication) have demonstrated that the Ñare onset occurred on the sunward side of the SUMER slit position from where it rapidly expanded to the site observed by the spectrometer. While the recording of the Ðrst spectra was underway, a M7.6 Ñare erupted in the observed active region. As a result, the spectra that were acquired during this Ñare contain the hottest high-resolution astrophysical spectral recordings ever made in the 500È1600 A range. Although resonance lines emitted from the hightemperature (T º 3 ] 106 K) astrophysical plasmas have e wavelengths shorter than 500 A , the SUMER instrument could record many bright forbidden lines also emitted by Ñare plasmas. The intensity of many of the lines can be used 2. THE SUMER INSTRUMENT The SUMER instrument is composed of a telescope and a spectrometer capable of producing stigmatic highresolution spectra. The telescope consists of an o†-axis parabolic mirror that can image any region within a 64 ] 64 arcmin2 Ðeld of view centered on the Sun. (The solar diameter as seen from SOHO is B32@.) The spectrometer entrance slit is placed in the focal plane of the telescope. The spectrometer consists of the entrance slit, an o†-axis parabolic mirror which collimates the light leaving the slit, a Ñat mirror which deÑects the light onto a concave grating in a Wadsworth conÐguration, and two imaging detectors. The two detectors, aligned with the grating focal plane, can be used alternatively to collect stigmatic images 1 E. O. Hulbert Center for Space Research, Naval Research Laboratory, Washington, DC 20375-5352. 2 Max-Planck-Institut fur Aeronomie (MPAE), Max-Planck-Strae 2, D-37191 Katlenburg-Lindau, Germany. 508 SPECTRAL LINES AND THEIR POTENTIAL USE IN PLASMA DIAGNOSTICS of the slit. Detector A, which was used during our observations, covers the 780È1610 A range in Ðrst order. Secondorder lines are superposed on the Ðrst-order spectrum. The detector has an array of 1024 (spectral) ] 360 (spatial) pixels each on average 26.5 ] 26.5 km2 in size and covers a spectral range of 43 A in Ðrst order. The angular scale of a pixel at 800 A is 1A. 03, while at 1600 A it is 0A. 95. In the Ðrst-order spectrum a pixel corresponds to 45.0 mA at 800 A and 41.8 mA at 1600 A . With SOHO in its nominal attitude the SUMER instrument is oriented with its slit aligned along the north-south direction. During the observations a 1 ] 300 arcsec2 slit was used. The SUMER optics are made of silicon carbide, which is a fairly good reÑector for radiation with wavelengths longer than 500 A . Each photon recorded by SUMER is reÑected by three normal incidence and one grazing incidence silicon carbide surfaces before reaching the detector. The secondorder spectrum superimposed on the Ðrst order should cover the 390È805 A range. However, as the radiation wavelength approaches 500 A from the long wavelength side, the reÑective properties of the SUMER optics diminish rapidly. The detector photocathode surface is divided into a number of sections. Two small sections of 55 pixels at both extremes of the detector are covered with a grid that transmits only 10% of the incident light. The next 210 pixels on both sides of the microchannel plate detector are uncoated, while the center 490 pixels are coated with potassium bromide (KBr). The efficiency of the detector section coated with KBr is higher than the efficiency of the uncoated parts over most of the wavelength range. Therefore, a comparison of the intensity of a particular line recorded on the KBr with its intensity obtained from the uncoated part of the detector can reveal unambiguously if a line is seen in Ðrst or second order. The details of the SUMER instrument and its modes of operation are described in Wilhelm et al. (1995). Wilhelm et al. (1997) provide an account of the actual performance of SUMER under operational conditions. 3. DATA ACQUISITION AND REDUCTION On May 9, SUMER observed an o†-limb postÑare site above the active region NOAA 8537, which was approaching the solar west limb. SUMER was in the so-called reference spectrum mode, in which the instrument scanned with some overlap the entire wavelength range in D 43 A sections. This operation lasted from 15 : 24 to 18 : 38 UT and was repeated from 18 : 44 to 21 : 57 UT. A Ñare of size C5.1 occurred at 16 : 09 UT, when the instrument recorded the spectrum around 980 A . At about 17 : 53 UT, a solar Ñare of size M7.6 erupted. The X-ray Ñux from the Ñare, as monitored by the GOES 8 satellite, peaked at about 18 : 07 UT, and since then it began its decay. By 19 : 00 UT the X-ray Ñux had dropped by over 1 order of magnitude from its maximum, and by 21 : 00 UT it dropped another factor of 2 to 3 until it could not be distinguished from the solar X-ray background. At Ñare onset the detector recorded spectra near 1395 A while advancing toward longer wavelengths. At the time of peak X-ray Ñux the detector recorded the spectrum around 1450 A . The bright region in the corona, which the SUMER slit was pointed at during the 1999 May 9 observations is shown in Figure 1. The observed region was the site of continuous Ñare activity. Therefore even prior to the onset of the main Ñare emission from hot plasma was detected, 509 although some of the hottest lines are only observed later during the main phase of the M Ñare. Standard procedures have been applied to the basic data processing, i.e., decompression, Ñat-Ðeld correction, and geometrical distortion corrections. The pixel-to-wavelength relation in SUMER spectra is wavelength dependent and very sensitive to mechanism slack. Therefore it needs to be calibrated for each exposure. This is achieved by a correlation of the entire 43 A window with all known reference lines in this window. Assuming that the dispersion is known very accurately from the optical design, this correlation leads to a constant o†set for each exposure. The method leads to a pixel-to-wavelength calibration with systematic uncertainties from 10 to 50 mA , depending on the quality of the wavelength standards in the exposure. Another error source comes from the determination of the line centroids. Centroiding can be difficult for blends or non-Gaussian line proÐles, but normally the uncertainty is better than 4 mA for isolated lines. The sum of both contributions yields the uncertainty of each individual measurement. Most of the lines have been observed twice during each of the spectral scans, so that in most cases four measurements are available. Their weighted averages are listed in Table 1. 4. HIGH-TEMPERATURE SPECTRAL LINES IN THE SUMER RANGE AND INFERRED ENERGY LEVELS The spectra recorded on 1999 May 9 contain a large number of spectral lines emitted by hot (T º 3 ] 106 K) e plasmas. Some of the recorded lines were previously observed in solar spectra (e.g., Doschek et al. 1975 ; Sandlin, Brueckner & Tousey 1977 ; Feldman & Doschek 1991 ; Feldman et al. 1998a ; Kucera et al. 2000). A number of additional lines were previously observed in spectra emitted by tokamak plasmas and by beam-foil sources (e.g., Denne & Hinnov 1984 ; Hinnov & Suckewer 1980 ; Hinnov et al. 1982 ; Peacock, Stamp, & Silver 1984). A list of the hightemperature lines detected in the 1999 May 9 spectra is given in Table 1. Some of the Ñare lines have never been identiÐed before. The table includes the line identiÐcations, if available, their previously most accurately derived wave- FIG. 1.ÈEIT images taken before and after the Ñare onset. The SUMER slit position is superimposed on the Ðeld of view. 510 2s22p5 2P È2s22p5 2P 1@2 3@2 2s22p3 2P È2s22p3 2D 1@2 3@2 2p 2P È2p 3P 3@2 1@2 2s22p3 2D È2s22p3 4S 3@2 3@2 1s2p 3P È1s2s 3S 0 1 2s22p3 2D È2s22p3 4S 5@2 3@2 2s22p2 3P È2s22p2 3P 1 0 2s22p4 1D È2s22p4 3P 2 2 2s22p3 2D È2s22p3 4S 3@2 3@2 2s22p3 2D È2s22p3 4S 5@2 3@2 2s22p23p4D È2s22p23s 4P 7@2 5@2 2s22p3 2P È2s22p3 2D 3@2 3@2 2s22p5 2P È2s22p5 2P 1@2 3@2 2s22p3 2D È2s22p3 4S 3@2 3@2 1s2p 3P È1s2s 3S 2 1 2p 2p È2p 2P 1@2 3@2 2s22p3 2D È2s22p3 4S 5@2 3@2 3s23p2 1S È3s23p2 3P 0 1 3s23p3 2P È3s23p3 4S 3@2 3@2 1s2p 3P È1s2s 3S 0 1 2s22p3 2D È2s22p3 4S 3@2 3@2 Co XIX . . . . . . . Fe XX . . . . . . . . Fe XXII . . . . . . Ti XVI . . . . . . . Si XIII . . . . . . . . Ca XIV . . . . . . . Ni XXIII . . . . . . Ti XV . . . . . . . . Ca XIV . . . . . . . K XIII . . . . . . . . S X ........... Ti XVI . . . . . . . Fe XVIII . . . . . . K XIII . . . . . . . . Mg XI . . . . . . . Mn XXI . . . . . . Ar XII . . . . . . . . Ni XV . . . . . . . . Ni XIV . . . . . . . Mg XI . . . . . . . Ar XII . . . . . . . . ? ............. ? ............. Fe XXIII . . . . . . Ca XIV . . . . . . . 2s2p 3P È2s2p 3P 2 1 2s22p3 2P È2s22p3 4S 3@2 3@2 2s22p3 2D È2s22p3 4S 3@2 3@2 2s22p53s3P È2s22p53s 3P 0 1 1s2p 3P È1s2s 3S 2 1 Transition Cr XVIII . . . . . . Ni XIX . . . . . . . Si XIII . . . . . . . . Linea TABLE 1 1054.585 ^ 0.015 (bl) 1062.450 ^ 0.040 1077.172 ^ 0.025 1079.415 ^ 0.025 1090.450 ^ 0.030/2 \ (545.225) 1005.862 ^ 0.020 1018.790 ^ 0.020 1033.041 ^ 0.015 1034.485 ^ 0.020 1043.282 ^ 0.020 (bl) 994.442 ^ 0.020 997.456 ^ 0.015 880.401 ^ 0.015 910.855 ^ 0.028 919.730 ^ 0.019 943.585 ^ 0.020 945.880 ^ 0.020 946.307 ^ 0.020 968.868 ^ 0.015 (bl) 974.850 ^ 0.020 820.019 ^ 0.025 821.706 ^ 0.030 845.570 ^ 0.020 861.799 ^ 0.020 878.690 ^ 0.040 793.160 ^ 0.021 794.605 ^ 0.025 814.715 ^ 0.025 Flare j (A ) 1079.3 ^ 0.3 545.26^0.02 1018.87 1033.04 1034.48 1043.29 ^ 0.08 1043.314 ^ 0.08 1054.62 997.38 ^ 0.084 997.451 ^ 0.019 946.29 968.8 ^ 0.3 974.86 ^ 0.02 974.86^0.02 821.74^0.05 845.55 ^ 0.1 861.8 ^ 0.1 878.85 878.684 ^ 0.029 884.43 911.0 919.73 ^ 0.08 943.61^0.62 814.71 ^ 0.02 814.729 ^ 0.024 793.3 ^ 0.3 Previously Measured j (A ) 6.3 [6.2 [6.2 7.1 6.45 6.95 6.3 6.35 6.3 6.8c 6.35 6.8 6.45 7.05 6.5 6.45 6.35 [6.2 6.6 6.7 6.65 6.9 7.05 6.6 6.95c 6.6 B6.6 6.95c log T b e (K) HOT (T [ 2 ] 106 K) EMISSION LINES OBSERVED IN 1999 MAY 9 FLARE SPECTRA e Hinnov et al. 1982 Feldman et al. 1998a Feldman et al. 1998a Feldman et al. 1998a Feldman et al. 1998a Klein et al. 1985 Curdt et al. 2000 Feldman et al. 1998a Klein et al. 1985 Curdt et al. 2000 Kink & Engrsom 1999 E. Hinnov, unpublished 1986 Peacock et al. 1984 Feldman et al. 1998a Kucera et al. 2000 Hinnov & Suckewer 1980 E. Hinnov, unpublished 1986 Howie et al. 1994 Curdt et al. 2000 Feldman et al. 1998a Hinnov et al. 1982 Peacock et al. 1984 Feldman et al. 1998a Howie et al. 1994 Curdt et al. 2000 Hinnov et al. 1982 References to Previous Measurements 2 5 5 3 5 5 5 5 5 5 3 5 7 5 Cross Reference to Other Tables 511 2s22p3 2P Ca XIV . . . . . . . . . ? ................ Mn XVII . . . . . . . . Fe XXI . . . . . . . . . . Ni XIV . . . . . . . . . . 1s2p 3P È1s2s 3S 0 1 2s22p3 2P È2s22p3 2D 3@2 3@2 2s22p4 1S È2s22p4 3P 0 1 2s22p3 2P È2s22p3 4S 3@2 3@2 Ne IX . . . . . . . . . . . Ca XIV . . . . . . . . . Ca XIII . . . . . . . . . Ar XII . . . . . . . . . . ? ................ ? ................ Ar XIII . . . . . . . . . . ? ................ ? ................ Cr XVIII] . . . . . . 2s22p3 2D È2s22p3 4S 5@2 3@2 2s22p2 1S È2s22p2 3P 0 1 2s22p4 1D È2s22p4 3P 2 2 3s23p4 1S È3s23p4 3P 0 1 2s22p 2P È2s22p 2P 3@2 1@2 1s2p 3P È1s2s 3S 2 1 2s22p4 1D È2s22p4 3P 2 2 2s22p5 2P È2s22p5 2P 1@2 3@2 2s22p2 1D È2s22p2 3P 2 1 3s23p3 2P È3s23p3 4S 1@2 3@2 K XII . . . . . . . . . . . Ni XIII . . . . . . . . . . Fe XIX . . . . . . . . . . ? ................ ? ................ ? ................ Cr XX . . . . . . . . . . Ne IX . . . . . . . . . . . 2s22p53s 3P È2s22p53s 3P 0 1 Fe XVII . . . . . . . . . È2s22p3 4S 3@2 2s22p2 1D È2s22p2 3P 2 1 2s22p2 1S È2s22p2 3P 0 1 1s2p 3P È1s2s 3S 2 1 2s22p4 3P È2s22p4 3P 1 2 2s22p4 1D È2s22p4 3P 2 2 2s22p3 2D È2s22p3 4S 5@2 3@2 Ca XV . . . . . . . . . . Ca XV . . . . . . . . . . Na X . . . . . . . . . . . Fe XIX . . . . . . . . . . Ca XIII . . . . . . . . . Fe XX . . . . . . . . . . 1@2 Transition Linea 1277.790 ^ 0.050 (bl) 1291.607 ^ 0.030 1297.398 ^ 0.030/2 \ (648.699) 1298.186 ^ 0.040/2 \ (649.093) 1308.146 ^ 0.030/2 \ (654.073) 1309.752 ^ 0.030/2 \ (654.876) 1313.344 ^ 0.020/2 \ (656.672) 1314.650 ^ 0.040/2 \ (657.325) 1320.402 ^ 0.025/2 \ (660.201) 1325.901 ^ 0.030/2 \ (662.951) 1256.484 ^ 0.025 1277.204 ^ 0.025 1184.467 ^ 0.030/2 \ (592.234) 1188.108 ^ 0.025 1192.978 ^ 0.040 1201.192 ^ 0.035 1205.728 ^ 0.025 1248.088 ^ 0.015 1159.706 ^ 0.030/2 \ (579.853) 1164.813 ^ 0.040 1167.760 ^ 0.015 1171.531/2 ^ 0.030 \ (585.766) 1174.656 ^ 0.020 1153.151 ^ 0.025 1098.484 ^ 0.040 1110.764 ^ 0.040/2 \ (555.382) 1111.754 ^ 0.030 1118.078 ^ 0.015 1133.756 ^ 0.020 1135.650 ^ 0.025/2 \ (567.825) Flare j (A ) 663.1 ^ 0.3 656.69^0.02 1277.23 1277.22^0.02 1277.71 ^ 0.02 1291.61^0.02 648.68^0.02 1205.9 ^ 0.3 1248.07 ^ 0.02 1248.097 ^ 0.014 585.8 ^ 0.3 1174.65 1174.65^0.02 592.234 ^ 0.006 1111.759 ^ 0.017 1118.060 ^ 0.01 1133.79 567.76 567.84^0.02 1153.20 1153.16 579.85 1098.44 Previously Measured j (A ) TABLE 1ÈContinued 6.5c 6.45 6.35 6.3 [6.2 [6.2 6.4 [6.2 [6.2 6.75 6.3 6.25 6.8 [6.2 [6.2 [6.2 6.9 6.5c 6.45 [6.2 6.55 6.95 6.3 6.45 6.55 6.55 6.7c 6.8 6.35 6.9 log T b e (K) Denne & Hinnov 1984 Feldman et al. 1998a Sandlin et al. 1977 Feldman et al. 1998a Brown et al. 1985 Feldman et al. 1998a Feldman et al. 1998a Hinnov et al. 1982 Beyer et al. 1986 Curdt et al. 2000 Hinnov et al. 1982 Sandlin et al. 1977 Feldman et al. 1998a Peacock et al. 1984 Curdt et al. 2000 Peacock et al. 1984 Feldman et al. 1998a Widing 1978 Kucera et al. 2000 Feldman et al. 1985 Feldman et al. 1998a Feldman et al. 1998a Feldman et al. 1998a References to Previous Measurements 5 5 5 3 6 7 4 5 6 Cross Reference to Other Tables 1410.584 ^ 0.025 1432.228 ^ 0.050 1435.705 ^ 0.040/2 \ (717.853) 1443.107 ^ 0.025/2 \ (721.554) 1452.655 ^ 0.040 1460.877 ^ 0.030/2 \ (730.439) 1472.980 ^ 0.040/2 \ (736.490) 1481.479 ^ 0.020/2 \ (740.740) 1491.605 ^ 0.020/2 \ (745.803) 1504.275 ^ 0.032 1515.190 ^ 0.060 1517.180 ^ 0.040/2 \ (758.590) 1558.901 ^ 0.030/2 \ (779.451) 1572.061 ^ 0.030/2 \ (786.031) 1586.309 ^ 0.028 bl with 1586.309/2 \ (793.155) 1589.256 ^ 0.035/2 \ (794.628) 1392.095 ^ 0.017 1328.791 ^ 0.030 1330.532 ^ 0.030 1331.503 ^ 0.021 1340.603 ^ 0.020/2 \ (670.302) 1354.064 ^ 0.020 1354.892 ^ 0.025 1358.537 ^ 0.029/2 \ (679.269) 1375.959 ^ 0.035 730.41 736.55 740.75 ^ 0.03 717.88 721.55 1410.62 ^ 0.02 1392.12 679.29 1375.98 1330.54^0.02 1331.48^0.02 670.34^0.02 1354.1 ^ 0.1 Previously Measured j (A ) 6.45 6.45 6.2 6.9 6.2 6.2 6.2 6.6 6.2 6.45 6.2 6.9 6.9 6.95 6.9 6.75 B6.6 6.2 6.75 6.8 6.4 [6.2 6.3 6.95 6.75 6.9 6.55 log T b e (K) Kink 1999 Kink 1999 Peacock et al. 1984 Kink 1999 Kucera et al. 2000 Kucera et al. 2000 Feldman & Doschek 1977 Sandlin et al. 1977 Feldman & Doschek 1977 Sandlin et al. 1977 Peacock et al. 1984 Feldman et al. 1998a Feldman et al. 1997 Feldman et al. 1998a Doschek et al. 1975 References to Previous Measurements 2s22p3 2D È2s22p3 4S 3@2 3@2 2s22p4 3P È2s22p4 3P 779.5 ^ 0.3 Hinnov et al. 1982 1 2 2s22p2 1D È2s22p2 3P 786.1 ^ 0.3 Hinnov et al. 1982 2 2 2s22p3 2P È2s22p3 2P 1586.29^0.03 Kucera et al. 2000 3@2 1@2 2s22p3 2D È2s22p3 4S 793.3 ^ 0.3 Hinnov et al. 1982 3@2 3@2 2s22p53s 3P È2s22p53s 3P 0 1 a UnidentiÐed lines are noted by question marks or by temperature classiÐcation of Feldman et al. 1997, if available. Second-order lines are marked by /2. b In all other than the He-like ions the temperature of maximum fractional abundance is given. c For all He-like lines the given values represent the temperature at which the contribution function reaches maximum. 2s22p33p 5P È2s22p33s 5S 2 2 2s22p33p 5P È2s22p33s 5S 1 2 2s22p4 1D È2s22p4 3P 2 2 2s22p4 1S È2s22p4 3P 0 1 2s22p3 2P È2s22p3 2D 1@2 3@2 2s22p5 2P È2s22p5 3P 1@2 3@2 2s22p3 2P È2s22p3 2D 3@2 5@2 2s22p33p 5P È2s22p33s 5S 3 2 2s22p3 2D È2s22p3 4S 3@2 3@2 Cr XVI . . . . . . . . Ca XIV . . . . . . . . Ar XI . . . . . . . . . . Fe XX . . . . . . . . . ? .............. Ar XI . . . . . . . . . . Ar XI . . . . . . . . . . Cr XVII . . . . . . . Ar XI . . . . . . . . . . Ca XIV . . . . . . . . ? .............. Mn XIX . . . . . . . Ni XXI . . . . . . . . Fe XXI . . . . . . . . Fe XX] . . . . . . Cr XVIII . . . . . . . Ni XIX . . . . . . . . 2P È2s22p3 4S 1@2 3@2 3P È2s22p2 3P 1 0 3P È2s22p4 3P 1 2 2P È2s22p3 2D 3@2 5@2 1D È2s22p2 3P 2 2 2s22p4 1D È2s22p4 3P 2 2 2s22p3 2s22p2 2s22p4 2s22p3 2s22p2 2s22p4 1D È2s22p4 3P 2 2 2s22p4 3P È2s22p4 3P 0 2 2s22p2 1D È2s22p2 3P 2 1 Transition Ar XI . . . . . . . . . . Mn XVIII . . . . . . Fe XIX . . . . . . . . Ar XIII . . . . . . . . (f) . . . . . . . . . . . . . . Ar XII . . . . . . . . . Fe XXI . . . . . . . . Mn XVIII . . . . . . Fe XX . . . . . . . . . Ca XV . . . . . . . . . Linea Flare j (A ) TABLE 1ÈContinued 5 4 5 5 4 6 Cross Reference to Other Tables SPECTRAL LINES AND THEIR POTENTIAL USE IN PLASMA DIAGNOSTICS TABLE 2 lengths and references to the quoted wavelengths. The temperatures at which the ions emitting the Ñare lines attain their highest fractional abundance under coronal equilibrium conditions are also listed. Our wavelength measurements are given with uncertainty estimates. In the following we discuss the high temperature lines that are listed in Table 1. The discussion is arranged according to isoelectronic sequences. 4.1. He-like L ines Transitions between levels belonging to the He-like 1s2p 3P and 1s2s 3S terms in all ions from Ne8` to Ca19` fall in 1 the 500È1600 A range. Therefore, in principle, all lines originating from the transitions 1s2p 3P ] 1s2s 3S , 1s2p 3P ] 1s2s 3S , and 1s2p 3P ] 1s2s 3S2 should be1detect1 1 0 1 able in the SUMER range. However, because of the much larger spontaneous decay rate of 1s2p 3P to the 1s2 1S 1 0 ground level than to 1s2p 3S , it is expected that the emis1 sivities of the 1s2p 3P ] 1s2s 3S lines is very low. They are 1 solar Ñare 1 spectra. indeed not visible in the The 1999 May 9 spectra contain the 1s2p 3P ] 1s2s 3S 2 The Ñare 1 transitions of Ne IX, Na X, Mg XI, and Si XIII. spectra also include the much fainter 1s2p 3P ] 1s2s 3S 1 transitions of Ne IX, Mg XI, and Si XIII. Lines0 from other fairly abundant elements S, Ar, and Ca that also fall in the SUMER range have not been observed. The reason for not detecting these lines is most likely due to the fact that the temperature that existed in the plasma during the observations was not high enough to populate substantially the 1s2p 3P levels in S, Ar, and Ca. Accurate wavelength measurements of the 1s2p 3P ] 1s2s 3S transitions are used as benchmarks for 0,2 1 calculations of relativistic and quantum comparisons with electrodynamic (QED) e†ects in many body systems (Drake 1988 ; Plante, Johnson, & Sapirstein 1994). 1s2p 3P ] 1s2s 3S He-like transitions of Ne IX, Mg XI, Al XII, 0,2Si XIII were1 measured in the laboratory by beam-foil and techniques (e.g., Beyer, Folkmann, & Schartner 1986 ; Brown et al. 1985 ; Howie et al. 1994 ; Klein et al. 1985). We believe that our measurements of these wavelengths are the Ðrst to be done from collisional astrophysical plasmas. The actual wavelength determinations using the 1999 May 9 Ñare spectra and other solar spectra were described in more detail by Curdt et al. (2000). 4.2. Be-like L ines The Be-like spin forbidden transitions of the type 2s2p 3P ] 2s2 1S of solar abundant elements with Z º 14 are 1,2 0 in spectra emitted by quiet and active commonly seen region plasmas (for details on such spectra see Curdt et al. 1997 ; Feldman et al. 1997). Be-like transitions of the type 2s2p 3P ] 2s2p 3P in ions with 24 ¹ Z ¹ 30 are also expected2 to appear1 in the SUMER wavelength range. Among the elements in the 24 ¹ Z ¹ 30 range, only Fe and possibly Ni have solar abundances high enough to justify expectations that their lines might be visible in the Ñare 513 ENERGY LEVELS IN Be-LIKE Fe XXIII ConÐguration Term J Level (cm~1) 2s2 . . . . . . . . . . . . 2s2p . . . . . . . . . . . 2s2p . . . . . . . . . . . 2s2p . . . . . . . . . . . 1S 3P 3P 3P 0 0 1 2 0 348238a 379125b 471768 a Predicted by Edlen 1983. b Sugar & Rowan 1995. spectra. In the 1999 May 9 Ñare only the 1079.415 A Fe XXIII line was detected presumably because the plasma temperature was not sufficiently high for a signiÐcant population of Be-like Ni ions to exist. This line was not seen before in solar plasmas. Hinnov et al. (1982) detected this line in tokamak spectra at 1079.3 A using a spectrometer with modest resolution. The energy level derived from our measurement is given in Table 2. 4.3. B-like L ines The SUMER wavelength range contains a large number of B-like lines associated with transitions of the type 2s2p2 ] 2s22p from elements with Z ¹ 16. Many of these lines are very prominent in quiet region, coronal hole, and active region spectra (see Curdt et al. 1997 ; Feldman et al. 1997). The only bright lines from B-like ions that are associated with high-temperature plasmas (T º 2 ] 106 K) and e are expected to appear in the SUMER spectral range belong to the 2s22p 2P ] 2s22p 2P forbidden tran1@2Fe XXII forbidden sition in elements with 243@2¹ Z ¹ 29. The transition was Ðrst observed in solar Ñare spectra obtained with the OSO 6 spectrometer (Doschek et al. 1975). Hinnov & Suckewer (1980) also detected the same line in tokamak spectra with a wavelength of 845.55 ^ 0.1 A . Hinnov et al. (1982) measured a line at 1205.9 ^ 0.3 A in tokamak spectra and a second line at 609.9 ^ 0.3 A , which they identiÐed as the 2s22p 2P ] 2s22p 2P forbidden transition in Cr XX and Ni XXIV,3@2 respectively. 1@2 We have measured in our spectra the very bright Fe XXII 2s22p 2P ] 2s2 2P forbidden line at 845.570 A . In addition, 3@2 we detected1@2the much fainter Cr XX line at 1205.728 A and newly identiÐed the Mn XXI line at 1005.862 A . The Ni XXIV line is predicted to appear in close wavelength proximity to the very bright Mg X 609 A resonance line. It is likely that because of the overwhelming brightness of the Mg X line, the Ni XXIV line could not be resolved from it with certainty. The energy levels within the ground conÐguration of Cr XX, Mn XXI, and Fe XXII resulting from our measurements are given in Table 3. 4.4. C-like L ines The SUMER spectral range contains lines that originate in transitions between the Ðrst excited conÐguration 2s2p3 TABLE 3 2s22p ENERGY LEVELS IN B-LIKE Cr XX, Mn XXI, AND Fe XXII ConÐguration Term J Cr XX level (cm~1) Mn XXI level (cm~1) Fe XXII level (cm~1) 2s22p . . . . . . . . . . 2s22p . . . . . . . . . . 2P 2P 1/2 3/2 0 82937.4 ^ 1.7 0 99417.2 ^ 2.0 0 118263.4 ^ 2.8 514 FELDMAN ET AL. Vol. 544 TABLE 4 TABLE 6 2s22p2 ENERGY LEVELS IN C-LIKE Fe XXI 2s22p4 ENERGY LEVELS IN O-like Fe XIX ConÐguration 2s22p2 2s22p2 2s22p2 2s22p2 2s22p2 Term J Level (cm~1) 3P 3P 3P 1D 1S 0 1 2 2 0 0 73851.8 ^ 1.1 117347.0 ^ 6.0 244568.4 ^ 5.0 371954a ........ ........ ........ ........ ........ ConÐguration 2s22p4 2s22p4 2s22p4 2s22p4 2s22p4 a Predicted by Edlen 1985. ........ ........ ........ ........ ........ Term J Level (cm~1) 3P 3P 3P 1D 1S 2 0 1 2 0 0 75256.4 ^ 1.7 89439.2 ^ 4.3 168852.3 ^ 4.3 325140 ^ 5a a Widing 1978. and the ground conÐguration 2s22p2 in elements with Z \ 15. In addition our range contains forbidden lines of Ar XIII, Ca XV, Cr XIX, Fe XXI, and Ni XXIII that arise from transition within the 2s22p2 ground conÐguration. All transitions that were detected in the 1999 May 9 Ñare with the exception of Ca XV 555.382 A have already been seen before either in solar spectra (e.g., Doschek et al. 1975 ; Feldman et al. 1998a) or in tokamak plasma (Hinnov et al. 1982). However, we signiÐcantly improved on the wavelength determinations of two of the Fe XXI lines and the Ni XXIII line. The resulting energy levels of Fe XXI are given in Table 4. 4.5. N-like L ines We expect in our spectra bright lines from elements with Z \ 18 that originate from transitions between the 2s22p3 ground conÐguration and the Ðrst excited conÐguration 2s2p4. The lines, which originate from such transitions, are emitted by relatively low-temperature astrophysical plasmas. N-like transition that originate within the 2s22p3 ground conÐguration in elements with 18 º Z º 30 also appear in high-temperature SUMER spectra. The Ðve levels in the N-like ground conÐguration produce nine di†erent forbidden transitions. In an earlier publication (Feldman et al. 1998a) we presented identiÐcations of Ar XII and Ca XIV lines that were recorded from a hot active region. In a second publication Kucera et al. (2000) presented a comprehensive list of Fe XX forbidden lines that were based on solar Ñares and on tokamak spectra. Because of the very high brightness of the 1999 May 9 Ñare, we also succeeded in measuring the previously undetected 649.093 A Ar XII line and the 1432.228 and 1504.275 A Ca XIV lines. We also measured the two previously unidentiÐed K XIII lines and a Co XXI line also belonging to the N I isoelectronic sequence. In addition, we improved the wavelengths of Ti XVI and Cr XVIII lines previously measured in tokamak spectra. Energy levels within the ground conÐguration in Ðve di†erent ions are listed in Table 5. 4.6. O-like L ines The SUMER Ñare spectra contain a number of forbidden lines that arise from transitions within the ground conÐguration 2s22p4 in O-like Ar, Ca, Ti, Cr, Mn, Fe, and Ni ions. Four of the lines, the Ar XI line at 745.803 A , the two Mn XVIII lines at 1354.892 and 662.951 A , and the Fe XIX line at 1328.791 A , were observed for the Ðrst time in the Ñare spectra. The other lines have already been seen in solar (e.g., Feldman & Doschek 1977 ; Sandlin et al. 1977 ; Feldman et al. 1998a) and in tokamak spectra (Hinnov et al. 1982 ; Peacock et al. 1984). We used the newly measured Fe XIX line at 1328.791 A to improve the energy levels of the ground conÐguration given in Table 6. 4.7. F-like L ines The SUMER wavelength range contains the 2s22p5 2P ] 2s22p5 2P transition from elements with 3@2 et al. (1975) Ðrst reported the pres24 1@2 ¹ Z ¹ 30. Doschek ence of the Fe XVIII line in solar coronal spectra. Subsequently, measurements of the Fe XVIII, together with Cr XVI and Ni XX, were reported in tokamak spectra. Peacock et al. (1984) claimed the most accurate measurement so far of the 2s22p5 2P ] 2s22p5 2P transition in Cr XVI 1410.62 A , 1@2 A , and in 3@2 Fe XVIII 974.86 Ni XX 694.64 A . We have detected 2s22p5 2P ] 2s22p5 2P transition in Cr XVI and Fe 3@2 We could not detect the Ni XX XVIII in the1@2 1999 May 9 Ñare. transition possibly because of its blend with a bright Si IX line. However, we detected for the Ðrst time the 2s22p5 2P ] 2s22p5 2P transition in Mn XVII at 1167.760 A 1@2in Co XIX at 820.019 3@2 and A . The newly determined energy levels of Mn XVII and Co XIX are given in Table 7. 4.8. Ne-like L ines Ne-like resonance transitions between the ground conÐguration 2s22p6 1S and the Ðrst excited conÐguration 0 2s22p53s in all ions other than Ne I have wavelengths too short to fall in the SUMER spectral range. The 2s22p53s conÐguration consists of the four levels, 3P , 3P , 3P , and 2 1 0 TABLE 5 2s22p3 ENERGY LEVELS IN N-like Ar XII, K XIII, Ca XIV, Ti XVI, AND Cr XVIII ConÐguration 2s22p3 2s22p3 2s22p3 2s22p3 2s22p3 ........ ........ ........ ........ ........ Term J Ar XII Level (cm~1) K XIII Level (cm~1) Ca XIV Level (cm~1) Ti XVI Level (cm~1) Cr XVIII Level (cm~1) 4S 2D 2D 2P 2P 3/2 3/2 5/2 1/2 3/2 0 94824.0 ^ 1.3 98155.7 ^ 1.9 149186.5 ^ 2.2 154061.1 ^ 4.7 0 100558.9 ^ 2.0 105721.7 ^ 2.2 160640b 168084b 0 105978.8 ^ 2.2 113584.6 ^ 1.9 172457.5 ^ 4.5 183408.0 ^ 5.0 0 116036.3 ^ 2.7 130701a 197668c 219249.5 ^ 4.0 0 126078.0 ^ 3.3 150840.7 ^ 3.4 226193d 264550d a Predicted by Edlen 1984. b Predicted by Edlen 1985. c E. Hinnov, unpublished 1986. d Denne & Hinnov 1984. No. 1, 2000 SPECTRAL LINES AND THEIR POTENTIAL USE IN PLASMA DIAGNOSTICS 515 TABLE 7 2s22p5 ENERGY LEVELS IN F-like Mn XVII AND Co XIX ConÐguration Term J Mn XVII Level (cm~1) Co XIX Level (cm~1) 2s22p5 . . . . . . . . 2s22p5 . . . . . . . . 2P 2P 3/2 1/2 0 85634.0 ^ 1.1 0 121948.3 ^ 3.7 1P , where 3P has the lowest energy and 1P the highest. 1 2 1 At solar densities the main depopulation mechanism of 3P , 2 3P , and 1P is via radiative decay into the ground level. 1 1 Since a direct radiative decay from the 3P level to the 1S 0 primarily as 0a ground level is strictly forbidden, it decays forbidden (M1) transition to the 3P level at solar electron 1 densities. Using Skylab Ñare spectra, Feldman, Doschek, & Seely (1985) measured a line at 1135.20 A which they identiÐed as the Fe XVII 2s22p53s 3P ] 2s22p53s 3P transition. 0 1 Using the 1999 May 9 Ñare we also measured a hightemperature line at 794.605 A , which we identiÐed as the Ni XIX 2s22p53s 3P ] 2s22p53s 3P transition (see Table 1). 0 1 This newly identiÐed line establishes the energy separation between the 3P and 3P levels as 125849 cm~1. 1 0 5. HIGH-TEMPERATURE, DENSITY-SENSITIVE LINE RATIOS The SUMER spectral range contains a number of line ratios suitable for determining the density of hightemperature solar plasmas. A list of the line ratios, the electron density range over which each intensity ratio is sensitive and the temperature at which the ions emitting the lines reach their maximum fractional abundances is given in Table 8. Figure 2 displays line ratios as a function of electron density for several of the Ar XII, K XIII, and Ca XIV line pairs. (The intensity ratios are displayed in energy units and not in photon units.) As seen from the Ðgure the intensity ratios, typically emitted by 2 ] 106 to 4 ] 106 K plasmas, could be used to derive electron densities in the 1 ] 109 to 1 ] 1013 cm~3 ranges. These ratios have been calculated using the data of the CHIANTI database (Dere et al. 1997 ; Landi et al. 1999). High-temperature Fe line ratios, of which the Fe XXI shown in Figure 3 is a typical example, are sensitive to plasmas with densities higher than 1 ] 1011 cm~3. Important exceptions to the rule are Fe XIX line ratios involving the 2s22p4 3P ] 2s22p4 3P transition. As seen from 2 are sensitive to densities of Figure 4, the Fe0 XIX line ratios 1 ] 109 cm~1 and higher. 6. TABLE 8 HIGH-TEMPERATURE DENSITY-SENSITIVE LINE RATIOS IN THE SUMER WAVELENGTH RANGE Line 1 (A ) Line 2 (A ) log density (cm~3) XII . . . . . . . XII . . . . . . . XII . . . . . . . XII . . . . . . . XII . . . . . . . 1018 1054 1054 1018 1018 1054 670 649 670 649 9È11.5 9È13 10È12.5 9È12 8.5È12.5 log T (K)a e 6.3 6.3 6.3 6.3 6.3 Ar XIII . . . . . . 1330 656 [10.5 6.4 K XIII . . . . . . . 945 994 9È12 6.35 Ca XIII . . . . . . 1133 648 [11 6.35 XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 545 545 880 580 580 880 880 943 880 944 580 944 1291 944 1291 1291 10È13 10È13 10È13 10È13 10È13 10È12 10È13 10È13 6.45 6.45 6.45 6.45 6.45 6.45 6.45 6.45 Ca XV . . . . . . Ca XV . . . . . . 1098 1375 555 555 [11 [11 6.55 6.55 Fe XIX . . . . . . Fe XIX . . . . . . 1329 1329 1118 592 [9 [9 6.8 6.8 Fe XXI . . . . . . 786 1354 [11 6.95 Line Ar Ar Ar Ar Ar Ca Ca Ca Ca Ca Ca Ca Ca a Temperature of maximum fractional abundance of the ion. EMISSIVITIES OF HIGH-TEMPERATURE LINES The SUMER wavelength range includes lines that could be used to determine emission measure distributions as well as the plasma temperatures in the 2 ] 106È2 ] 107 K range. In particular, lines of Ca XIII, Ca XIV, Ca XV, which have their maximum fractional abundances at log T of 6.35, e Fe XX, 6.45, 6.55, respectively, and lines of Fe XVIII, Fe XIX, Fe XXII, Fe XXIII, which have their maximum fractional abundance at log T /k of 6.7, 6.8, 6.9, 6.95, 7.05, 7.1 (Arnaud e respectively, can be used for emission & RothenÑug 1985), measure and plasma temperature determinations. Table 9 provides emissivities of Ca lines in the log T \ 6.2È6.8 e range and log N in the 9È13 range. Table 10 provides emise sivities of Fe lines in the log T \ 6.6È7.3 range and log N e calculations given in thee in the 9È13 range. The emissivity tables are based on cross sections stored in the CHIANTI FIG. 2.ÈIntensity ratios (in energy units) vs. electron density for Ar XII, K XIII, and Ca XIV lines. FIG. 3.ÈIntensity ratios (in energy units) vs. electron density for the 786/1354 Fe XXI lines. FIG. 4.ÈIntensity ratios (in energy units) vs. electron density for the 1328/1118 Fe XIX lines. TABLE 9 EMISSIVITIES FOR Ca XIII, Ca XIV, AND Ca XV LINES APPEARING IN 500È1600 A RANGE LINE log EMISSIVITY1 (ergs cm~3 s~1) VERSUS log T (K) e j (A ) log N e (cm~3) 6.2 6.3 6.4 6.5 6.6 6.7 6.8 Ca Ca Ca Ca Ca XIII . . . . . . XIII . . . . . . XIII . . . . . . XIII . . . . . . XIII . . . . . . 1133 1133 1133 1133 1133 9 10 11 12 13 15.810 15.812 15.836 16.025 16.663 15.219 15.222 15.244 15.422 16.037 14.962 14.965 14.986 15.152 15.743 15.136 15.140 15.160 15.314 15.880 15.692 15.695 15.715 15.858 16.396 16.589 16.594 16.613 16.745 17.256 17.841 17.846 17.865 17.987 18.470 Ca Ca Ca Ca Ca XIII . . . . . . XIII . . . . . . XIII . . . . . . XIII . . . . . . XIII . . . . . . 648 648 648 648 648 9 10 11 12 13 16.502 16.487 16.438 16.307 16.457 15.511 15.896 15.848 15.710 15.835 15.655 15.640 15.592 15.448 15.547 15.832 15.817 15.770 15.621 15.692 16.392 16.376 16.331 16.178 16.219 17.295 17.279 17.236 17.079 17.090 18.544 18.358 18.495 18.336 18.316 Ca Ca Ca Ca Ca XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 943 943 943 943 943 9 10 11 12 13 16.721 16.731 16.805 17.193 18.016 15.551 15.559 15.624 15.992 16.795 14.817 14.822 14.879 15.225 16.005 14.595 14.598 14.646 14.969 15.724 14.814 14.816 14.856 15.156 15.884 15.423 15.423 15.455 15.733 16.432 16.423 16.421 16.446 16.701 17.371 Ca Ca Ca Ca Ca XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 880 880 880 880 880 9 10 11 12 13 16.922 17.071 17.646 18.491 19.389 15.749 15.890 16.448 17.282 18.166 15.012 15.143 15.684 16.507 17.376 14.786 14.908 15.430 16.242 17.094 15.002 15.115 15.617 16.418 17.253 15.608 15.712 16.193 16.983 17.800 16.604 16.699 17.159 17.938 18.738 Ca Ca Ca Ca Ca XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 579 579 579 579 579 9 10 11 12 13 17.314 17.286 17.222 17.266 17.828 16.144 16.115 16.044 16.069 16.608 15.411 15.381 15.304 15.309 15.820 15.190 15.159 15.077 15.062 15.541 15.413 15.382 15.294 15.259 15.704 16.025 15.994 15.901 15.847 16.256 17.030 16.999 16.901 16.829 17.199 Ca Ca Ca Ca Ca XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 1504 1504 1504 1504 1504 9 10 11 12 13 18.197 18.169 18.105 18.149 18.711 17.027 16.998 16.927 16.952 17.491 16.294 16.264 16.187 16.192 16.703 16.073 16.043 15.960 15.945 16.424 16.296 16.265 16.177 16.142 16.587 16.909 16.877 16.784 16.730 17.139 17.913 17.882 17.784 17.712 18.082 Ca Ca Ca Ca Ca XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 545 545 545 545 545 9 10 11 12 13 17.138 17.067 16.946 16.910 17.306 15.965 15.892 15.762 15.713 16.086 15.227 15.154 15.016 14.952 15.299 15.003 14.929 14.784 14.706 15.023 15.221 15.147 14.995 14.903 15.188 15.829 15.756 15.598 15.493 15.743 16.828 16.757 16.592 16.474 16.690 SPECTRAL LINES AND THEIR POTENTIAL USE IN PLASMA DIAGNOSTICS 517 TABLE 9ÈContinued LINE log EMISSIVITY1 (ergs cm~3 s~1) VERSUS log T (K) e j (A ) log N e (cm~3) 6.2 6.3 6.4 6.5 6.6 6.7 6.8 Ca Ca Ca Ca Ca XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 1291 1291 1291 1291 1291 9 10 11 12 13 17.846 17.775 17.654 17.618 18.014 16.673 16.600 16.470 16.421 16.794 15.935 15.862 15.724 15.660 16.007 15.711 15.637 15.492 15.414 15.731 15.929 15.855 15.703 15.611 15.896 16.537 16.464 16.306 16.201 16.451 17.536 17.465 17.300 17.182 17.398 Ca Ca Ca Ca Ca XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . XIV . . . . . . 1432 1432 1432 1432 1432 9 10 11 12 13 18.264 18.192 18.071 18.035 18.432 17.090 17.017 16.887 16.838 17.212 16.353 16.279 16.141 16.078 16.425 16.128 16.054 15.909 15.831 16.148 16.346 16.273 16.121 16.029 16.313 16.954 16.882 16.723 16.618 16.868 17.954 17.882 17.717 17.600 17.815 Ca Ca Ca Ca Ca XV XV XV XV XV ...... ...... ...... ...... ...... 1098 1098 1098 1098 1098 9 10 11 12 13 17.492 17.473 17.438 17.571 18.130 16.218 16.195 16.147 16.265 16.803 15.537 15.510 15.448 15.552 16.071 15.361 15.330 15.253 15.343 15.846 15.621 15.585 15.493 15.570 16.058 16.310 16.269 16.162 16.226 16.698 Ca Ca Ca Ca Ca XV XV XV XV XV ...... ...... ...... ...... ...... 1375 1375 1375 1375 1375 9 10 11 12 13 17.420 17.401 17.366 17.499 18.058 16.146 16.123 16.075 16.193 16.731 15.465 15.438 15.376 15.480 15.999 15.289 15.258 15.181 15.271 15.774 15.549 15.513 15.421 15.498 15.986 16.238 16.197 16.090 16.154 16.626 Ca Ca Ca Ca Ca XV XV XV XV XV ...... ...... ...... ...... ...... 555 555 555 555 555 9 10 11 12 13 17.680 17.671 17.630 17.493 17.619 16.383 16.374 16.334 16.195 16.300 15.678 15.670 15.632 15.491 15.576 15.476 15.469 15.436 15.294 15.358 15.707 15.703 15.677 15.533 15.578 16.367 16.365 16.346 16.203 16.228 a Data for the CHIANTI calculations was taken from the following sources : Ca XIII : Radiative data from unpublished SUPERSTRUCTURE calculations by A. K. Bhatia 1996, private communication ; collisional data taken from unpublished distorted wave calculations by A. K. Bhatia 1996, private communication. Ca XIV : Radiative and collisional data from Bhatia & Mason 1980a. Ca XV : Radiation data from Froese Fischer & Saha 1985 ; collisional data from Aggarwal, Berrington & Keenan 1991 ; Bhatia & Doschek 1993. database, on the fractional ionization calculations of Mazzotta et al. (1998), and on photospheric abundances given in Grevesse & Sauval (1998). 7. TEMPERATURE DIAGNOSTICS Plasma temperatures could be determined using the lines in the SUMER wavelength range. Assuming that the Ñaring plasma is in a steady state coronal equilibrium, the temperature of the plasma could be derived as follows : In one approach the determination is based on intensity ratios of lines emitted by the same ion. At Ðrst, the electron density is determined using the line ratios described in ° 4. Given the electron density, the plasma temperature could be determined by comparing measured intensity ratios of lines belonging to the same ion with calculations at a number of temperatures. In particular, the intensity ratios of the Fe XIX 1328/592 and 1118/592 and the intensity ratios of the Ca XV 1098/555 and 1375/555 could be used for the purpose. In a second method calculated line emissivities versus temperature are divided by the measured line intensities. Using the derived values, curves representing the ratios as a function of temperature are generated for the measured lines. (Emissivities as a function of temperature and density for Ca XIIIÈCa XV and Fe XVIIIÈFe XXIII are listed in Tables 9 and 10.) In cases where the plasma under consideration is isothermal, the curves from each of the lines, independent of their degree of ionization, should cross each other in nearly the same point. The point of intersection could be considered as the plasma temperature. For illustration of this approach, see Figure 4 in Feldman et al. (1999). A third method for determining the plasma temperature involves a comparison of intensity ratios of lines originating from very highly excited levels with lines originating in lowexcitation levels. In particular, this technique could work well in comparing the intensity of the 1153 A Fe XVII line that originates in a level which is 725 eV above the ground state with Fe XVIIIÈFe XXII lines originating from levels in the ground conÐguration. A second interesting system involves a comparison of the 1248 A Ne IX line which originates in a level that is 915 eV above the ground state, with Ar XIIÈAr XIV lines originating in the ground conÐguration. Since both Ne and Ar are high Ðrst ionization potential (FIP) elements (see ° 8) their abundances are expected, anywhere in the solar upper atmosphere, to be photospheric. TABLE 10 EMISSIVITIES FOR FeE XVIIIÈFe XXXI LINES APPEARING IN 500È1600 A RANGE LINE log EMISSIVITY1 (ergs cm~3 s~1) VERSUS log T (K) e j (A ) log N e (cm~3) 6.6 6.7 6.8 6.9 7.0 7.1 7.2 7.3 974 974 974 974 974 9 10 11 12 13 14.259 14.259 14.260 14.266 14.322 13.926 13.926 13.927 13.933 13.991 13.746 13.746 13.747 13.753 13.812 13.813 13.813 13.813 13.820 13.880 14.256 14.256 14.257 14.264 14.325 15.125 15.125 15.125 15.132 15.193 16.341 16.341 16.342 16.348 16.409 17.690 17.690 17.691 17.697 17.757 7.4 Fe Fe Fe Fe Fe XVIII . . . . . . XVIII . . . . . . XVIII . . . . . . XVIII . . . . . . XVIII . . . . . . Fe Fe Fe Fe Fe XIX XIX XIX XIX XIX ....... ....... ....... ....... ....... 1328 1328 1328 1328 1328 9 10 11 12 13 16.216 16.986 17.954 18.951 19.956 15.576 16.339 17.306 18.303 19.307 15.150 15.905 16.871 17.867 18.870 15.009 15.755 16.719 17.716 18.718 15.270 16.007 16.970 17.966 18.967 15.972 16.699 17.659 18.655 19.655 17.029 17.745 18.703 19.698 20.698 18.225 18.928 19.884 20.879 21.877 19.407 20.098 21.051 22.045 23.043 Fe Fe Fe Fe Fe XIX XIX XIX XIX XIX ....... ....... ....... ....... ....... 1118 1118 1118 1118 1118 9 10 11 12 13 15.323 15.318 15.318 15.334 15.468 14.694 14.688 14.688 14.703 14.832 14.277 14.270 14.270 14.284 14.408 14.145 14.136 14.136 14.150 14.268 14.415 14.405 14.405 14.417 14.530 15.124 15.114 15.113 15.125 15.233 16.190 16.179 16.178 16.189 16.292 17.394 17.383 17.381 17.392 17.489 18.586 18.573 18.572 18.582 18.674 Fe Fe Fe Fe Fe XIX XIX XIX XIX XIX ....... ....... ....... ....... ....... 592 592 592 592 592 9 10 11 12 13 15.354 15.355 15.356 15.363 15.426 14.730 14.731 14.731 14.738 14.798 14.316 14.316 14.317 14.323 14.380 14.185 14.185 14.186 14.192 14.245 14.458 14.457 14.458 14.463 14.513 15.170 15.170 15.170 15.175 15.222 16.241 16.240 16.240 16.245 16.288 17.450 17.449 17.449 17.454 17.493 18.647 18.646 18.646 18.650 18.687 Fe Fe Fe Fe Fe XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . 721 721 721 721 721 9 10 11 12 13 16.520 16.520 16.521 16.535 16.641 15.514 15.514 15.516 15.528 15.627 14.780 14.780 14.781 14.792 14.884 14.369 14.369 14.370 14.380 14.466 14.387 14.387 14.388 14.397 14.478 14.866 14.866 14.867 14.876 14.952 15.719 15.719 15.720 15.728 15.799 16.727 16.727 16.728 16.735 16.802 17.734 17.734 17.735 17.741 17.804 Fe Fe Fe Fe Fe XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . 567 567 567 567 567 9 10 11 12 13 16.734 16.734 16.743 16.817 17.211 15.731 15.732 15.739 15.809 16.190 14.999 15.000 15.007 15.073 15.441 14.590 14.590 14.597 14.660 15.016 14.609 14.610 14.617 14.676 15.020 15.090 15.090 15.096 15.153 15.486 15.943 15.944 15.950 16.003 16.325 16.952 16.952 16.958 17.009 17.318 17.960 17.960 17.965 18.013 18.311 Fe Fe Fe Fe Fe XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . 821 821 821 821 821 9 10 11 12 13 18.111 18.110 18.108 18.088 18.032 17.105 17.105 17.103 17.082 17.021 16.369 16.369 16.366 16.346 16.283 15.954 15.954 15.952 15.932 15.867 15.968 15.967 15.965 15.947 15.882 16.442 16.442 16.440 16.422 16.358 17.290 17.290 17.288 17.272 17.209 18.294 18.294 18.292 18.276 18.215 19.297 19.297 19.295 19.281 19.220 Fe Fe Fe Fe Fe XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . 679 679 679 679 679 9 10 11 12 13 18.095 18.094 18.085 18.015 17.833 17.097 17.097 17.088 17.018 16.828 16.373 16.372 16.363 16.294 16.098 15.971 15.971 15.962 15.893 15.692 16.000 15.999 15.990 15.923 15.717 16.489 16.489 16.480 16.414 16.204 17.352 17.351 17.343 17.278 17.066 18.370 18.369 18.361 18.297 18.083 19.386 19.385 19.377 19.315 19.100 Fe Fe Fe Fe Fe XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . XX . . . . . . . . 1586 1586 1586 1586 1586 9 10 11 12 13 19.374 19.373 19.363 19.294 19.112 18.376 18.375 18.336 18.297 18.107 17.651 17.651 17.642 17.573 17.377 17.250 17.249 17.241 17.172 16.971 17.279 17.278 17.269 17.202 16.996 17.768 17.767 17.759 17.693 17.483 18.631 18.360 18.622 18.557 18.345 19.648 19.648 19.640 19.576 19.362 20.665 20.664 20.656 20.594 20.379 Fe Fe Fe Fe Fe XXI XXI XXI XXI XXI ....... ....... ....... ....... ....... 1354 1354 1354 1354 1354 9 10 11 12 13 15.834 15.835 15.581 15.964 16.383 14.591 14.593 14.607 14.711 15.111 13.741 13.743 13.755 13.852 14.233 13.380 13.381 13.392 13.481 13.845 13.527 13.528 13.538 13.620 13.967 14.088 14.089 14.098 14.173 14.504 14.836 14.837 14.845 14.914 15.229 15.608 15.609 15.617 15.680 15.979 Fe XXI . . . . . . . Fe XXI . . . . . . . Fe XXI . . . . . . . 585 585 585 9 10 11 17.034 17.026 16.965 15.797 15.791 15.736 14.954 14.948 14.899 14.601 14.596 14.551 14.759 14.754 14.713 15.332 15.328 15.289 16.094 16.090 16.053 16.881 16.877 16.843 SPECTRAL LINES AND THEIR POTENTIAL USE IN PLASMA DIAGNOSTICS 519 TABLE 10ÈContinued LINE j (A ) log N e (cm~3) Fe XXI . . . . . . . Fe XXI . . . . . . . 585 585 log EMISSIVITY1 (ergs cm~3 s~1) VERSUS log T (K) e 6.7 6.8 6.9 7.0 7.1 7.2 7.3 7.4 12 13 16.713 16.538 15.496 15.306 14.669 14.464 14.330 14.110 14.499 14.265 15.081 14.833 15.851 15.588 16.646 16.369 17.182 17.174 17.112 16.861 16.686 15.945 15.939 15.884 15.644 15.453 15.101 15.096 15.046 14.817 14.612 14.749 14.744 14.699 14.478 14.258 14.907 14.902 14.861 14.647 14.413 15.480 15.475 15.437 15.229 14.981 16.241 16.238 16.201 15.999 15.736 17.029 17.025 16.991 16.793 16.517 15.468 15.468 15.469 15.482 15.598 14.238 14.238 14.239 14.252 14.361 13.547 13.548 13.549 13.561 13.665 13.405 13.405 13.406 13.417 13.516 13.705 13.705 13.706 13.717 13.810 14.215 14.215 14.216 14.226 14.314 14.770 14.771 14.772 14.781 14.863 16.172 16.172 16.173 16.185 16.287 15.136 15.136 15.137 15.148 15.246 14.697 14.697 14.698 14.709 14.802 14.741 14.741 14.742 14.752 14.841 15.029 15.029 15.030 15.039 15.123 15.387 15.387 15.388 15.397 15.477 Fe Fe Fe Fe Fe XXI XXI XXI XXI XXI ....... ....... ....... ....... ....... 786 786 786 786 786 9 10 11 12 13 Fe Fe Fe Fe Fe XXII XXII XXII XXII XXII ...... ...... ...... ...... ...... 845 845 845 845 845 9 10 11 12 13 Fe Fe Fe Fe Fe XXIII . . . . . . XXIII . . . . . . XXIII . . . . . . XXIII . . . . . . XXIII . . . . . . 1079 1079 1079 1079 1079 9 10 11 12 13 6.6 a Data for the CHIANTI calculations was taken from the following sources : Fe XVII : Radiative and collisional data from Bhatia & Doschek 1992. Fe XVIII : Radiative data from Sampson et al. 1991 ; Blackford & Hibbert 1994 ; Cornille et al. 1992. Collisional data from Sampson et al. 1991. Fe XIX : Radiative and collisional data from Lolergue et al. 1985 ; Bhatia et al. 1989a. Fe XX : Radiative data from Bhatia et al. 1989b ; collisional data from B. McLaughlin 2000, private communication ; Bhatia & Mason 1980b. Fe XXI : Radiative data from Young (1996, unpublished) ; Collisional data from Aggarwal 1991. Fe XXII : Radiative data from Dankwort & Tre†tz 1978 ; Nussbaumer & Storey 1981 ; Lennon et al. 1985 ; Collisional data from Zhang, Graziani & Pradhan 1994. Fe XXIII : Radiative and collisional data from Zhang & Sampson 1992. LINES SUITABLE FOR DETERMINING ELEMENTAL ABUNDANCES IN HIGH-TEMPERATURE PLASMAS 8. During the last three decades instruments mounted on a variety of spacecrafts gathered a large body of data regarding the properties of the solar wind. In analyzing the data it was found that the composition of the solar wind is not always identical to the composition of the solar photosphere. While the composition in some solar wind streams (fast speed solar wind) resembles photospheric composition, in other locations (in particular, in the slow speed solar wind) it is modiÐed (e.g., von Steiger, Geiss, & Gloeckler 1997). The modiÐcation patterns were such that in general, elements (excluding He) with FIP larger than 11.5 eV have abundances similar to those in the photosphere. On the other hand, the abundances of elements having FIP \ 10 eV in general are increased by factors of 4È5 relative to the photospheric abundance. Elements having FIP [ 11.5 eV were named high-FIP elements and those with FIP \ 10 eV were named low-FIP elements. The factor by which the low-FIP elements are modiÐed relative to the photosphere was deÐned as the FIP bias. The literature contains well-documented examples of plasmas with low-FIP/high-FIP composition ratios that very between photospheric and 15 times photospheric. Assuming that the modiÐcation occurs in the low-FIP elements while the high FIP elements stay unchanged, a question that is not yet completely settled, the FIP-bias can vary between 1 and 15. A summary of the latest results regarding elemental abundance modiÐcations in various solar regions is presented in a number of review papers (e.g., Feldman 1992 ; Saba 1995 ; Meyer 1996 ; Feldman & Laming 2000). Using SUMER spectra, Feldman et al. (1998b) derived the abundance in the coronal plasma above a quiet region (1.3 ] 106 K) and above a coronal hole region (9 ] 105 K). They found that at heights of 30@@ above the limb in coronal holes the composition of elements is very similar to the composition of the solar photosphere. In contrast at 30@@ above the limb in quiet regions the low-FIP elements were enhanced relative to their abundance in the photosphere by a factor of 3È4. Dwivedi, Curdt, & Wilhelm (1999) found that the FIP bias across an active region is increasing with height, a trend that is confused by local excursions in the active region loops. All earlier measurements were done by X-ray instruments that were unable to image particular solar regions ; instead they collected radiation from the entire Sun. Using such an instrument, McKenzie & Feldman (1992) derived the elemental abundance in a large number of Ñares. According to them, Ñaring plasmas have FIP biases that vary between 1 and 4. In general, the McKenzie & Feldman (1992) results were conÐrmed by most subsequent studies, although in few cases somewhat di†erent conclusions were made (for more details see the above referenced review papers). SUMER is the Ðrst instrument providing sufficient number of lines that could be used to determine abundances of well-deÐned high-temperature solar plasmas. A very important issue regarding elemental abundances is the dependence of the FIP bias on the FIP, i.e., do all low-FIP elements get enriched in equal proportions or are they being enriched in proportion to the magnitude of their FIPs ? The high-temperature SUMER spectra contains forbidden lines from elements spanning a wide FIP range, in particular, lines emitted by the following ions : Ar10`, 520 FELDMAN ET AL. Vol. 544 TABLE 11 N-LIKE LINES WITHIN 2s22p3 GROUND CONFIGURATION IN Ar XII, Ca XIV, AND Fe XX SUITABLE FOR SPECTROMETER CALIBRATIONS RESPONSIVITY OVER WIDE VACUUM WAVELENGTH RANGES Ar XII UPPER LEVEL LOWER LEVEL 2P . . . . . . 3@2 2P . . . . . . 3@2 2P . . . . . . 3@2 2P . . . . . . 3@2 2P . . . . . . 1@2 2P . . . . . . 1@2 Ca XIV Fe XX j (A ) Aa (s~1) j (A ) Aa (s~1) j (A ) Aa (s~1) 2P 1@2 2D 5@2 2D 3@2 4S 3@2 20585b 1789.29b 1688.76b 649.093 0.924 240 476 1170 9138b 1432.228 1291.607 545.225 10.1 725 1620 3230 1586.309 679.269 541.35 309.32 1600 12800 44900 27300 2D 3@2 2S 3@2 1839.69b 670.302 241 549 1504.275 579.853 666 1730 821.706 384.22 6170 31500 0.377 2.17 13153b 880.401 4.19 13.5 2665.1 567.825 417 1240 2D . . . . . . 2D 30057b 5@2 3@2 2D . . . . . . 4S 1018.790 5@2 3@2 a Spontaneous decay rate. b Line not yet observed. Ar11`, Ar12` (FIP \ 15.8 eV) ; Fe11` (FIP \ 7.9 eV) ; Ni12`, Ni13`, Ni14` (FIP \ 7.6 eV) ; Ti14` (FIP \ 6.8 eV) ; Cr15`, Cr16` (FIP \ 6.7 eV) ; Ca11`, Ca12`, Ca13`, Ca14` (FIP \ 6.1 eV) ; and K12` (FIP \ 4.3 eV). As was described in ° 6, lines from the Ca ions could be used to derive emission measure distribution over the 1 ] 106 \ T \ 5 ] 106 K. Similarly, the electron density and teme perature in the emitting plasma could also be derived using the available SUMER line ratios (see °° 5 and 7). With the emission measure, electron density, and temperature known, the elemental abundance relative to Ca of the high FIP Ar, the low FIP Fe, Ni, and the very low FIP K could be derived. Similarly, as a check on the determination, elemental abundances of Cr and Ti that have FIP similar to Ca could also be derived. In doing so the two questions of ““ What are the elemental abundances in Ñares ? ÏÏ and ““ Do FIP bias levels depend on the size of the FIP ? ÏÏ could be answered. Previous attempts to determine the dependence of the FIP bias levels on the size of the FIP were attempted. Although they appeared to show such a trend, the results were inconclusive (Feldman 1992). 9. SETS OF SPECTRAL LINES ORIGINATING FROM COMMON UPPER LEVELS WITH VASTLY DIFFERENT WAVELENGTHS The responsivity calibration of a space spectrometer that operates over a wide wavelengths range is quite difficult. Even in cases when the responsivity as a function of wavelength could be established on the ground, once in space the calibration needs to be checked or reestablished from time to time. A common technique of such a calibration utilizes sets of lines with known branching ratios that originate from the same upper level and have largely di†erent wavelengths. For such lines to be useful, their branching ratios should not be too di†erent, resulting in intensity ratios that are not too di†erent. Unfortunately, the task of Ðnding sets of lines fulÐlling the above requirement is often difficult because in most cases allowed lines of comparable branching ratios appear in close wavelength proximities. An interesting case are the nine forbidden lines that result from transitions between the 4S , 2D , 2D , 2P , and 3@2 conÐguration 3@2 5@2 in1@2N-like 2P levels of the 2s22p3 ground 3@2 ions. As a result of the unique distribution of ““ j ÏÏ values within levels of the ground conÐguration, the highest level 2P decays into all four lower levels, resulting in lines of 3@2di†erent wavelengths. The second highest level 2P very 1@2 decays into the 2D , and 4S , and the third highest level 3@2 3@2 2D level decays into either 2D , and 4S . Table 11 5@2 the wavelengths and spontaneous 3@2 gives decay3@2rates of forbidden lines that arise from levels within the ground conÐguration of Ar11`, Ca13` and Fe19` that could be used to calibrate the efficiency of spectrographs spanning a very wide wavelength range. Mason & Bhatia (1983) and Kaufman & Sugar (1986) published spontaneous decay rates for the Fe XX forbidden transitions. The agreement between the two sets of calculations was better than 15%. Recently, Bhatia (1999, private communication) recalculated the Fe XX spontaneous decay rates using the latest experimental energy level values. His newly calculated values that almost always fell in between values from the previous two calculations are shown in the last column of TABLE 12 C-LIKE LINES WITHIN THE 2s22p3 GROUND CONFIGURATION IN Ar XIII, Ca XV, AND Fe XXI SUITABLE FOR SPECTROMETER RESPONSIVITY CALIBRATIONS Ar XIII UPPER LEVEL LOWER LEVEL j (A ) 1D . . . . . . 3P 1330.532 2 1 1D . . . . . . 3P 1583.36b 2 2 a Spontaneous decay rate. b Line not yet observed. Ca XV Fe XXI Aa (s~1) j (A ) Aa (s~1) j (A ) Aa (s~1) 150 266 1098.484 1375.959 551 810 585.766 786.031 15900 15100 No. 1, 2000 SPECTRAL LINES AND THEIR POTENTIAL USE IN PLASMA DIAGNOSTICS Table 11. The spontaneous decay rates of Ar XII and Ca XIV, taken from Kaufman & Sugar (1986), are also given in the table. The 2s22p2 ground conÐguration in C-like ions and the 2s22p4 ground conÐguration in O-like ions each contains line pairs that arise from transitions between 1D ] 3P 2 2 and 1D ] 3P that in principle could be used for efficiency 2 1 calibration. Unfortunately, the 1D È3P transitions in O-like Ar XI, Ca XIII, and Fe XIX are2very1weak and probably would not be useful in most instances. Table 12 provides the wavelengths and spontaneous decay rates of the set of lines in the C-like Ar, Ca, and Fe ions that are useful for efficiency calibration. The wavelengths displayed in Table 11 span a very wide range. The Fe XX lines span the 300È2660 A range, Ca XIV span the 550È13000 A range, and the Ar XII lines span 650È 30000 A . All together the table displays 24 lines that are divided among six pairs and three sets of four lines each that 521 together span the 300È30000 A wavelength range. Notice that the ratios of the spontaneous decay rates within each pair and within three lines from the sets of four are within 1 order of magnitude of each other. As a result, the number of photons that would be emitted in lines with vastly di†erent wavelengths that belong to the same set would not be too di†erent. The work of U. 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