1. What would be the expected product(s) of the following reactions?
A)
B)
C)
D)
E)
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2. What would be the MAJOR organic product of the following reaction?
A)
B)
C)
D)
E)
3. What product would you expect from the reaction shown below?
A)
B)
C)
D)
E)
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III and V
II and IV
I, III and V
II and III
I, II and IV
4. Which of the following are E isomers?
A)
B)
C)
D)
E)
K+-OtBu
CH3S- Na+
H2SO4
CH3O- Na+
K+ -CN
5. Which reagent(s) would you expect to give the highest yield of the product shown?
A)
B)
C)
D)
E)
K+-OtBu
NaCN
CH3S-Na+
NaOH
CH3O-Na+
6. What reagent would give the highest yield of the product shown below?
A)
B)
C)
D)
E)
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7. What product, if any, would result from the reaction shown below?
A)
B)
C)
D) both A and B
E) no reaction occurs
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8. Predict the product of the following reaction:
A)
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9. Predict the MAJOR product of the following reaction:
B)
A)
B)
E)
D)
C)
E)
D)
C)
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10. What would be the major organic product of the following reaction?
A)
B)
C)
D)
E)
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11. Predict the MAJOR product of the following reaction:
A)
B)
C)
D)
E)
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12. Predict the MAJOR product of the following reaction:
2,3-dimethylcyclohexanol + H2SO4
A)
B)
C)
D)
E)
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13. Predict the MAJOR product of the following reaction
A)
B)
Which of the following is true of thiols?
They are more acidic than alcohols.
They have lower boiling points than the corresponding alcohol.
Thiol oxidations proceed very differently than alcohol oxidations.
All of these.
Two of these.
C)
D) A and B in equal proportions
E) B and C in equal proportions
14.
A)
B)
C)
D)
E)
15. Which of the following reactions would produce diethyl ether?
A)
B)
C)
D) All of these.
E) Two of these.
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16.
A)
B)
C)
D)
E)
Saytzev's Rule has to do with the following:
Free-radical substitutions
Hydration of double bonds
Bromination of double bonds
Products of elimination reactions
Hydrogenation of double bonds
17. What is the MAJOR product of the following reaction?
A)
B)
C)
D)
E)
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18. What would be the major organic product expected from the following reaction?
A)
B)
C)
D)
E)
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19. What is the MAJOR product of the following reaction?
A)
B)
C)
D)
E)
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20. What is the MAJOR product of the following reaction:
A)
B)
C)
D)
E) none of these
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21. What is the product of the following reaction?
A)
B)
C)
D)
E)
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22. What would be the product of the following reaction?
A)
B)
C)
D)
E)
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23. What would be the product of the following reaction?
A)
B)
C)
D)
E)
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24. Which of the following reactions would be the best for the preparation of anisole
(methoxybenzene)?
A)
B)
C)
D)
E) None of these would work.
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25. What would be the product of the following reaction?
A)
B)
C)
D)
E)
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26. What would be the expected product for the following reaction?
A)
B)
C)
D)
E)
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27. Which alcohol could be prepared by the greatest number of different combinations of
Grignard reagents and carbonyl compounds (aldehydes, ketones and/or esters)? (no
multi-step reactions are intended here)
A)
B)
C)
D)
E)
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28. What would be the expected organic product of the following reaction?
A)
B)
C)
D)
E)
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29. What is the MAJOR product of the following reaction?
A)
B)
C)
D)
E)
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30. Which of the following reactions would produce the alcohol shown below?
A)
B)
C)
D) All of these
E) Two of these
31. What is the MAJOR product of the following reaction?
A)
B)
C)
D)
E) no net reaction occurs
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32. What is the major product of the following reaction?
A)
B)
C)
D)
E)
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33. What is the expected product of the following reaction?
A)
B)
C)
D)
E)
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34. Predict the product of the following reaction:
A)
B)
C)
D)
E)
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35. Which of the sequences below would accomplish the following transformation?
A)
B)
C)
D)
E)
H2SO4, H2O
H 2CrO4
O2 (slow)
HO-, H2O
None of these.
36. Which of the following reagents would accomplish the reaction shown?
A)
B)
C)
D)
E)
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37. Which of the following reactions would produce the alcohol shown?
A)
B)
C)
D) All of these.
E) None of these
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B
B
C
B
D
A
A
D
B
C
D
D
C
D
E
D
D
C
A
B
D
A
A
C
A
B
A
C
A
D
E
A
A
D
B
E
D
Answer Key - Ferret:Exam:chem 109a 2003:quiz 5.qf.ef
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