Isotopes Isotopes are different forms of an element having the SAME atomic number, meaning the same number of protons. Isotopes DIFFER in the amount of neutrons. Isotopes, Radioisotopes and Atomic Mass 35 37 Cl 17 1 Cl 17 3 4 Medical Uses of Isotopes 2 Medical Uses of Isotopes Iodine in nature is 100% iodine-127 (stable) Iodine-131 is formed in nuclear reactions, it is unstable and undergoes radioactive decay Because these isotopes are absorbed by the thyroid virtually the same way a doctor can use in diagnostic test Sodium iodide, made with iodine-131, is administered and instruments are used to detect radioactive emissions detecting the levels and locations in patients body 6 Thyroid diseases The thyroid controls how quickly the body burns energy, makes proteins, and controls how sensitive the body should be to other hormones. 5 1 Isotopic Abundance Different elements have different numbers of isotopes These elements exist in different relative abundances For example, natural magnesium is a mixture of three isotopes: Mg-24, Mg-25, and Mg-26 On average, a sample of natural magnesium consists of 78.7% Mg-24,10.1% Mg-25 and 11.2 % Mg-26 7 8 Average Atomic Mass Calculating Relative Atomic Mass The atomic mass of an element is determined by calculating the weighted average of the masses of all isotopes of that element A weighted average considered not only the values but also the relative abundance of each value 9 Calculate the relative atomic mass of chlorine if the relative abundance of Cl-35 is 75.43% and Cl-37 is 24.47%. mCl = (percent abundance of Cl-35 x atomic mass Cl-35) + (percent abundance of Cl-37 X atomic mass Cl-37) mCl = (0.7543 X 35 u) + (0.2447 X 37 u) = 26.40 + 9.05 u = 35.45 u Radioisotopes Table 1: Relative Atomic Masses Atom Atomic Mass Oxygen 16.00 u Iron 55.85 u Tin 118.71 u Aluminum 26.98 u Nitrogen 14.01 u Cobalt 58.93 u 10 Atoms with an unstable nucleus, characterized by excess energy imparted to newly-created radiation particle in nucleus or to an electron Because radioisotopes decay by emitting nuclear radiation in the form of tiny particles or energy, therefore they are called radioactive 11 2 Radioisotopes Radioisotopes Three main types: Alpha ( ), Beta ( ), Gamma ( ) Alpha radiation = emission of alpha particles (2p+, 2n0 same as He nucleus) Beta radiation = emission of beta particles (high energy electrons) Gamma radiation = emission of high energy electromagnetic waves (have no mass and travel at the speed of light) 13 14 Radiation have different penetrating abilities Radioisotope HALF-LIFE HALF-LIFE refers to the time for ½ of the original number of radioactive atoms to decay Example: The half-life of cesium-137 is 30a. What mass of cesium-137 would remain from a 12 gram sample after 30a? After 60a? 15 Radioisotope Half-Life Practice Radioisotope HALF-LIFE 1 half-life 2 half-lives 30 a 60 a 16 Polonium-216 has a half-life of 0.16 seconds. What mass of Polonium-216 would remain from a 16 g sample after 0.96 seconds? 0.25 g after 6 half-lives 12 g 6g 3g Cesium-137 17 18 3
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