Szechuan Peppercorn Supercritical Extract SDS Safety Data Sheet 1. PRODUCT NAME AND COMPANY IDENTIFICATION Product Name: Szechuan Peppercorn Supercritical Extract Product Use: Flavor and fragrance component. Product Number: 2002201 Supplier: Blue Marble Biomaterials 5840 Expressway Missoula, MT 59808 USA Date Issued: 04/01/2013 Prepared by: Michaela Finnegan Emergency Telephone Number: US & Canada: +1 (800) 255-3924 International: +1 (813) 248-0585 Contract #: MIS0007457 National Response Center: +1 (800) 424-8802 2. HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards: Combustible liquid, skin sensitizer, irritant GHS Classification: Flammable liquids (Category 4) Acute toxicity, Oral (Category 5) Skin irritation (Category 2) Eye irritation (Category 2A) Skin sensitization (Category 1) Specific target organ toxicity – single exposure (Category 3) GHS Label Elements, including precautionary statements Pictogram: Signal Word: Warning Hazard Statement(s): H227 – Combustible liquid. H303 – May be harmful if swallowed. Page 1 of 8 Blue Marble Biomaterials Szechuan Peppercorn Supercritical Extract ≥95% 20022-01 H315 – Causes skin irritation. H317 – May cause an allergic skin reaction. H319 – Causes serious eye irritation. H335 – May cause respiratory irritation. Precautionary Statement(s): P261 – Avoid breathing dust/fume/gas/mist/vapors/spray. P280 – Wear protective gloves. P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. HMIS Classification: Health Hazard: Flammability: Physical Hazards: NFPA Rating: Health Hazard: Fire: Reactivity Hazard: Potential Health Effects 2 2 0 2 2 0 Eyes: May cause eye irritation. Skin: May be harmful if absorbed through skin. May cause skin irritation. Inhalation: May be harmful if inhaled. May cause respiratory tract irritation. Ingestion: May be harmful if swallowed. Potential environmental effects: No data available. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: No data available. Formula: No data available. Molecular Weight: No data available. Component Classification Concentration - - Szechuan Peppercorn Supercritical Extract CAS No.: N/A EC No.: N/A 4. FIRST AID MEASURES General Advice: Consult a physician if irritation persists. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. Inhalation: If inhaled, move person into fresh air. If not breathing, give artificial respiration. Consult a physician if irritation persists. Page 2 of 8 Blue Marble Biomaterials Szechuan Peppercorn Supercritical Extract ≥95% 20022-01 Skin contact: Wash off with soap and plenty of water. Consult a physician if irritation persists. Wash contaminated clothing before reusing. Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician if irritation persists. Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician if irritation persists. 5. FIREFIGHTING MEASURES Extinguishing media: For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Special protective equipment for firefighters: Wear self-contained breathing apparatus for fire fighting if necessary. Hazardous combustion products: No data available. Further information: Use water spray to cool unopened containers. 6. ACCIDENTAL RELEASE MEASURES Personal Protection Measures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Remove all sources of ignition. Environmental Protection Measures: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleanup: Absorb with inert material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Dispose of according to local regulations (see section 13). 7. HANDLING AND STORAGE Safe Handling: Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking. Do not breathe gas/fumes/ vapor/spray. Safe Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Containers that are opened must be carefully resealed and kept upright to prevent leakage. Store in a cool place. Page 3 of 8 Blue Marble Biomaterials Szechuan Peppercorn Supercritical Extract ≥95% 20022-01 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal Protective Equipment Respiratory: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand: Handle with chemically resistant gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Eye: Wear tightly fitting safety goggles and Face shield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and Body: Wear complete suit protecting against chemicals and flame retardant antistatic protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state: Color: Odor: Safety Data Liquid Dark yellow/light brown Spicy, camphor, pepper pH: No data available. Melting point/Freezing point: No data available. Boiling point: No data available. Flash point: No data available. Ignition temperature: No data available. Autoignition No data available. Page 4 of 8 Blue Marble Biomaterials Szechuan Peppercorn Supercritical Extract ≥95% 20022-01 temperature: Lower explosion limit: No data available. Upper explosion limit: No data available. Vapor pressure: No data available. Density: No data available. Water solubility: No data available. Relative vapor density: No data available. Odor threshold: No data available. Evaporation rate: No data available. Specific Gravity: No data available. Molecular Weight, g/mol: No data available. Refractive Index, at 20°C: No data available. Viscosity, cP at 20°C No data available. 10. STABILITY AND REACTIVITY Chemical stability: Stable under recommended storage conditions. Possibility of hazardous reactions: No data available. Conditions to Avoid: Heat, flames, and sparks. Materials to Avoid: Strong oxidizing agents. Hazardous Decomposition or Byproducts: No data available. Hazardous Polymerization: No data available. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Oral LD50: No data available. Inhalation LC50: No data available. Dermal LD50: No data available. Other information on acute toxicity: No data available. Skin corrosion/irritation: No data available. Serious eye damage/eye irritation: No data available. Page 5 of 8 Blue Marble Biomaterials Szechuan Peppercorn Supercritical Extract ≥95% 20022-01 Respiratory or skin sensitization: No data available. Germ cell mutagenicity: No data available. Carcinogenicity IARC: No data available ACGIH: No data available NTP: No data available. OSHA: No data available. Reproductive Toxicity: No data available. Teratogenicity: No data available. Specific target organ toxicity – single exposure (GHS): No data available. Specific target organ toxicity – repeated exposure (GHS): No data available. Aspiration hazard: No data available. Potential health effects Eyes: Skin: May cause eye irritation. May be harmful if absorbed through skin. May cause skin irritation. May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. Inhalation: Ingestion: Signs and symptoms of exposure: To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects: No data available. Additional information: No data available. 12. ECOLOGICAL INFORMATION Toxicity Toxicity to fish: No data available. Toxicity to daphnia and other aquatic invertebrates: No data available. Persistence and degradability: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. PBT and vPvB assessment: No data available. Other adverse effects: No data available. Page 6 of 8 Blue Marble Biomaterials Szechuan Peppercorn Supercritical Extract ≥95% 20022-01 13. DISPOSAL CONSIDERATIONS Product: Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Contaminated Packaging: Dispose of as unused product. 14. TRANSPORT INFORMATION DOT No data available. IMDG No data available. IATA No data available. 15. REGULATORY INFORMATION OSHA Hazards Irritant SARA 302 Components No data available. SARA 313 Components No data available. SARA 311/312 Hazards No data available. Massachusetts Right To Know Components No data available. Pennsylvania Right To Know Components No data available. New Jersey Right To Know Components No data available. California Prop. 65 Components No data available. TSCA 8(b) Inventory: No data available. Health & Safety Reporting List: No data available. Chemical Test Rules: No data available. TSCA Section 12(b) Export Notification: No data available. TSCA Significant New Use Rule: No data available. CERCLA Hazardous Substances and Corresponding RQs: No data available. Clean Air Act: No data available. Page 7 of 8 Blue Marble Biomaterials Szechuan Peppercorn Supercritical Extract ≥95% 20022-01 Clean Water Act: No data available. Connecticut hazardous material survey: No data available. Massachusetts spill list: No data available. WGK (Water Danger/Protection): No data available. Canada – DSL/NDSL: No data available. Canada – WHMIS: This product is not classified according to the EU regulations. Canadian Ingredient Disclosure List: No data available. European Labeling in Accordance with EC Directives Hazard Symbols: Xi Risk Phrases: R10 – Flammable liquid. R43 – May cause sensitization by skin contact. Safety Phrases: S24 – Avoid contact with skin. S37 – Wear suitable gloves. 16. ADDITIONAL INFORMATION This information is provided for documentation purposes only. The complete range of conditions or methods of use are beyond our control therefore we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate however, all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user. This safety sheet cannot cover all possible situations, which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary. All health and safety information contained in this bulletin should be provided to your employees or customers. Page 8 of 8
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