1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product name:
Product code:
Synonyms:
Use of substance/preparation:
Company name:
Rock
Stone stain removal poultice
Stone Tech (Cleveland) Ltd
Lee Road,
Bolckow Industrial Estate
Grangetown
North Yorkshire
TS6 7BB
Tel: 01642 430099
Fax: 01642 462877
Emergency (24hr):
01642 430099
2. HAZARDS IDENTIFICATION
Main Hazards:
Xn Harmful
R10 Flammable, R20 Harmful by inhalation, R36/37 36/38 Irritating to the eyes and respiratory
system. R65 Harmful may cause lung damage if swallowed. H304 may be fatal if swallowed and
enters airways. H226 Flammable liquid and vapour
3. COMPOSITION/INFORMATION ON INGREDIENTS
• Tetraethyl Silicate
Hazardous ingredients:
CAS: 78-10-4
EINECS:201-083-8
HEALTH: Xn, Xi,
RISK: R10-20 36/37
•
Solvent Naptha (petroleum), medium aliph
CAS:64742-88-7
EINECS:265-191-7
HEALTH: [Xn]
RISK: R10-65
4. FIRST AID MEASURES: SYMPTOMS
Skin contact:
There may be irritation and redness at the site of contact.
Eye contact:
There may be irritation and redness. The eyes may water profusely.
Ingestion:
There may be soreness and redness of the mouth and throat. Nausea and stomach pain may
occur.
Inhalation:
There may be irritation of the throat with a feeling of tightness in the chest.
4.1. FIRST AID MEASURES: ACTION
Skin contact:
Remove contaminated clothing. Rinse skin with water or shower
Eye contact:
Bathe the eye with running water for 10 minutes and seek medical advice
Ingestion:
Seek immediate medical attention, hospital or poisons center.
Inhalation:
Remove casualty into fresh air, if breathing difficulties persist, seek medical advice
5. FIRE FIGHTING MEASURES
Extinguishing media:
CO2, sand and extinguishing powder
Exposure hazards:
Protection of fire-fighters:
Not suitable for extinguishing with water jets
Wear protective clothing and respiratory protection
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Personal protective equipment
Environmental precautions:
Clean up procedures:
Do not allow to enter sewers, surface or ground water.
Absorb with a liquid binding material, sand, diatomite, acid binders or sawdust
7. HANDLING AND STORAGE
Handling requirements:
Storage conditions:
As per exposure controls-provide adequate ventilation .Prevent formation of aerosols.
Do not smoke
No special requirements, keep container tightly sealed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Workplace exposure limits
The product does not contain any relevant quantities of materials with critical values that have to
be monitored in the workplace
WEL (8hr TWA):
WEL (15 min STEL):
Engineering measures:
Respiratory protection:
Ensure there is sufficient ventilation of the area.
Brief exposure use respiratory filter device. Longer exposure use self-contained respiratory
device.
Hand protection:
Eye protection:
Skin protection:
Good quality rubber gloves
Tightly sealed goggles.
Protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
State:
Colour:
Odour:
PH:
Solubility in water:
Also soluble in:
Viscosity:
Boiling point/range ºC:
Liquid
Clear
Characteristic
Not miscible or difficult to mix
153
Melting point/range ºC:
Danger of Explosion:
Auto Ignition temp:
Flash point ºC:
Explosive limits:
Relative density:
Vapour pressure:
Organic Solvents:
VOC (EC):
Undetermined
The product is not explosive, formulation of air/vapour mixtures are possible
The product is not self-igniting
40
Lover 0.6 vol % Upper 23.0 vol%
0.959 g/cm3
6.6hpa
58.5%
58.54
10. STABILITY AND REACTIVITY
Stability:
Stable under normal conditions.
Conditions to avoid:
Materials to avoid:
None Known
Haz. decomp. products:
None Known
11. TOXICOLOGICAL INFORMATION
•
Hazardous ingredients:
•
Routes of exposure:
Tetraethyl Silicate
CAS: 78-10-4
EINECS:201-083-8
HEALTH: Xn, Xi,
RISK: R10-20 36/37
Oral:LD50 6270mg/kg (rat)
Dermal: LD50 5878 mg/kg (rabbit)
Solvent Naptha (petroleum), medium aliph
CAS:64742-88-7
EINECS:265-191-7
HEALTH: [Xn]
RISK: R10-65
Oral: LD50 >6500mg/kg (rat)
Dermal: LD50 >3000 mg/kg (rabbit)
Inhalative:LC50/4h 14mg/I (rat)
Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
12. ECOLOGICAL INFORMATION
•
Tetraethyl Silicate
CAS: 78-10-4
EINECS:201-083-8
HEALTH: Xn, Xi,
RISK: R10-20 36/37
Oral:LD50 6270mg/kg (rat)
Dermal: LD50 5878 mg/kg (rabbit)
•
Solvent Naptha (petroleum), medium aliph
CAS:64742-88-7
EINECS:265-191-7
HEALTH: [Xn]
RISK: R10-65
Oral: LD50 >6500mg/kg (rat)
Dermal: LD50 >3000 mg/kg (rabbit)
Inhalative:LC50/4h 14mg/I (rat)
Hazardous ingredients:
General:
Slightly hazardous for water
Persistence and degradability:
Biodegradable
Bio accumulative potential:
Aquatic Toxicity:
Do not allow large quantities of undiluted product to reach ground water or sewerage system.
13. DISPOSAL CONSIDERATIONS
Disposal of packaging:
Must not be disposed of in household garbage
NB:
The user’s attention is drawn to the possible existence of regional or national regulations
regarding disposal.
14. TRANSPORT INFORMATION
ADR/RID
PACKAGING GROUP
IMDG CLASS
UN NO
3 Flammable Liquids
III
1292
15. REGULATORY INFORMATION
Hazard symbols:
Xn Harmful
Risk phrases:
R10 Flammable R20 Harmful by inhalation R36/37 36/38 Irritating to eyes and respiratory
system. R65 Harmful: may cause lung damage if swallowed.
Safety phrases:
S2: Keep out of the reach of children. S9 Keep container in a well ventilated place.
Note:
The regulatory information given above only indicates the principal regulations specifically
applicable to the product described in the safety data sheet. The user’s attention is drawn to the
possible existence of additional provisions which complete these regulations. Refer to all
applicable national, international and local regulations or provisions.
16. OTHER INFORMATION
Other information:
Risk phrases used in s.3:
Legal disclaimer:
The safety data sheet is prepared in accordance with Regulation (EC) No 1907/2006.
The above information is believed to be correct but does not purport to be all inclusive and shall
be only used as a guide. This company shall not be held liable for any damage resulting from
handling or from contact with the above product.