Silane cross-linked polyethylene
pipe INTERSOL PEX-b
Main characteristics
®
Use of INTERSOL PEX-b offers the
following advantages:
• Resistance to electrochemical and chemical
corrosion
• Long life in relation to temperature and pressure
• Resistance to chemicals
• Resistance to high temperature peaks
(up to 110°C)
• Low noise level
• Resistance to plastic creep
• Low pressure drop
• Low formation of deposits
• Resistance to low temperatures
• Flexibility
A Division of Watts Water Technologies Inc.
SILANE CROSS-LINKED POLYETHYLENE PIPE
Piping of the INTERSOL®PEX-b series is made from cross-linked polyethylene, available in versions with or
without oxygen diffusion barrier, and suitable for pipes used for supplying the heat carrier fluid in
heating/plumbing systems.
2
TPR
INTERSOL®
Cross-linked polyethylene pipe. Can be used as a viable alternative to
conventional piping (copper - steel - iron). Suitable for heating and plumbing
systems as it is non toxic.
Easy to install. Low pressure drops. Age and corrosion resistant.
Max. temperature: 100 °C.
Conforms with UNI 9338. Approved according to UNI 315 IIP no. 206.
Type
TPR
TPR
TPR
TPR
TPR
TPR
TPR
Part number
1001112
1001115
1001118
1001120
1001122
1001128
1001132
Dimensions
12 x 2,0
15 x 2,5
18 x 2,5
20 x 2,0
22 x 3,0
28 x 3,0
32 x 3,0
TPRUV
INTERSOL®
Cross-linked polyethylene pipe resistant to the aging action of UV rays.
Characteristics like TPR, but suitable above all for outdoor sections exposed to
sunlight.
Conforms with UNI 9338. Approved according to UNI 315 IIP no. 206.
Type
TPRUV
TPRUV
TPRUV
TPRUV
TPRUV
TPRUV
Part number
1001512
1001515
1001518
1001522
1001528
1001532
Dimensions
12 x 2,0
15 x 2,5
18 x 2,5
22 x 3,0
28 x 3,0
32 x 3,0
VPESR
INTERSOL®
Cross-linked polythene pipe enclosed in corrugated polyethylene sheath.
Characteristics like TPR.
Black sheath.
Conforms with UNI 9338. Approved according to UNI 315 IIP no. 206.
(does not include the sheath).
Type
VPESR
VPESR
Part number
1001905
1001909
Dimensions
15 x 2,5
18 x 2,5
SILANE CROSS-LINKED POLYETHYLENE PIPE
VPEED
INTERSOL®
Cross-linked polythene pipe with oxygen diffusion barrier to prevent oxygen
in the air from penetrating inside the water circuit.
Suitable for building radiant panel systems.
Other characteristics like TPR.
Conforms with DIN 16892/16898.
Approved according to DIN 4726/4729.
Type
Part number
VPEED
1001165
VPEED
1001166
VPEED
1001175
VPEED
1001176
VPEED
1001185
VPEED
1001186
VPEED
1001205
VPEED
1001206
Dimensions
16 x 2,0
16 x 2,0
17 x 2,0
17 x 2,0
18 x 2,0
18 x 2,0
20 x 2,0
20 x 2,0
TPRR
INTERSOL®
Like VPEDD but without the oxygen diffusion barrier.
Conforms with DIN 16892/16893 - UNI 9338.
Type
TPRR
TPRR
TPRR
TPRR
TPRR
TPRR
TPRR
TPRR
Part number
1001160
1001161
1001170
1001171
1001180
1001181
1001200
1001201
Dimensions
16 x 2,0
16 x 2,0
17 x 2,0
17 x 2,0
18 x 2,0
18 x 2,0
20 x 2,0
20 x 2,0
1 - PLASTICS USED IN HOT /COLD WATER PRESSURE PIPING
INTERSOL®PEX-b is a cross-linked polyethylene pipe obtained via the silane method, starting from high density
polyethylene. It finds application in the heating and plumbing sector.
In this sector (floor heating, radiator pipe connecting, plumbing systems) it is possible to use the following plastic
materials instead of conventional metal ones:
- Polyethylene (PE)
- Chlorinated polyvinyl chloride (PVC-C)
- Cross-linked polyethylene (PEX)
- Polypropylene random copolymer (PP-R)
- Polybutylene (PB)
Table 1 shows the fields of application of plastics in the pressure pipe sectors.
Table 1
Application
Domestic cold water
Domestic hot water (60°C)
Floor heating
Radiator pipe connecting
Legend
Yes = used
(Yes) = used less frequently
No = not used
PE
Yes
No
No
No
PVC-C
Yes
Yes
No
No
PEX
Yes
Yes
Yes
Yes
PP-R
Yes
Yes
(Yes)
No
PB
Yes
Yes
Yes
(Yes)
3
SILANE CROSS-LINKED POLYETHYLENE PIPE
2 - CROSS-LINKING METHOD
4
High density polyethylene is a thermoplastic macromolecular component, obtained from the polymerization of the
ethylene monomer (CH2 = CH2).
Its chemical formula can be represented as: - (CH2 - CH2) - n
where n defines the length of the macromolecular chain (the average value of n can also lie between
10,000 – 16,000). From now onwards we shall represent such chain as:
Hence polyethylene consists of various macromolecular (polymer) chains, whose cohesion forces cannot strictly
be considered to be true chemical bonds, rather they are electrical in nature and are commonly known as “Van
der Waals” forces. Although such cohesion forces are low, the high number of intramolecular bonds favours
obtaining of certain properties for the product.
However the low energy of the cohesion forces makes the thermoplastic materials highly sensitive to temperature,
which causes considerable decay of the properties.
Suppose in addition to the “Van der Waals” forces, we introduce intramolecular chemical bonds (the so-called
cross-linking bonds), the thermal properties of the product will be considerably improved.
Cross-linking is a process which modifies the chemical structure of the material, by creating a three dimensional
“network” structure thanks to links between the polymer chains. The new structure determines certain special
characteristics, namely:
•
•
•
•
•
•
•
•
an increase in the maximum operating temperature
a reduction in creep deformation (creep)
improved chemical resistance
improved resistance to UV rays
improved abrasion resistance
greater impact strength
less notch sensitivity and abrasion
thermal memory characteristics are conferred to the material (“thermoelastic polymer”)
2.1 - Classification of the cross-linked polyethylene
Cross-linked polyethylene is classified according to the methods used to perform the cross-linking as summed up
in the following table:
Table 2
a
b
c
d
Type of cross-linking
Chemical
Chemical
Physical
Chemical
Cross-linking agent
Peroxides
Silanes
Electronic rays (beta)
Azo compounds
Product symbol
PEX-a
PEX-b
PEX-c
PEX-d
Processes a, b and c are the most frequent ones and they will be described in the following pages.
2.2 - Chemical cross-linking with peroxides (PEX-a)
In the Engel method, the peroxide (chemical formula ROOR) is added to polyethylene during the extrusion phase.
The process consists of two steps, namely:
• formation of free radicals
+ ROOR
+ ROH
• cross-linking
+
Special machines that allow reaching of pressures up to 2000 bar are required to complete such process.
SILANE CROSS-LINKED POLYETHYLENE PIPE
2.3 - Physical cross-linking with radiation, beta rays (PEX-c)
As in the previous situation, likewise here, cross-linking depends on the formation of free radicals, in this case
generated by beta radiation. Such technology is based on the method of cross-linking the finished polyethylene
product by radiating with a high energy electron beam, generated by a particle accelerator. The cross-linking
process can be represented as follows:
• formation of free radicals
ray
• cross-linking
+
The processes based on peroxides and radiation generate a bond of the carbon-carbon type between the chains.
2.4 - Chemical cross-linking with silanes INTERSOL® PEX-b
We shall now go into greater depth as regards the chemical silane cross-linking which, as will be seen below,
creates a carbon-silicon-oxygen-silicon-carbon bond between the chains.
In such process polyethylene is added to a silane, a small quantity of peroxide, acting as an initiator, and an
organometallic catalyst. Cross-linking is performed in two steps: grafting and cross-linking.
Grafting takes place via the extrusion process, which is then followed by cross-linking in water, accelerated by
the catalyst.
The following is a representation of the chemical reaction mechanism with silanes (e.g. vinyl trimethoxysilane
contains a small quantity of dicumyl peroxide):
• grafting
takes place inside the extruder at high temperature (140°C – 190°C)
+ CH2=CH-Si-(OCH3)3
ROOR’
CH30-Si-OCH3
OCH3
• cross-linking
(takes place in contact with water, normally hot between 80°C – 85°C)
+ 3 H 2O
CH30-Si-OCH3
+ 3 CH3OH
HO-Si-OH
OCH3
OH
Cross-linked polyethylene INTERSOL® PEX-b
condensation
catal.
+
HO-Si-OH
O
HO-Si-OH
HO-Si-OH
OH
OH
+ H 2O
HO-Si-OH
The intramolecular bond that is generated is of the type - Si - HO - Si – possessing an energy comparable to the
- C - C - bond.
5
SILANE CROSS-LINKED POLYETHYLENE PIPE
3 - MANUFACTURING PROCESSES INVOLVING SILANE CROSS-LINKING
The use of silanes as cross-linking agents is based mainly on two industrial methods:
6
1) A TWO-STEP PROCESS (SIOPLAS)
2) A ONE-STEP PROCESS (MONOSIL)
3.1 - Two-step Sioplas method
The Sioplas method was developed in 1968 and consists of two steps (see figure 2):
-) step 1
Polyethylene, silane and a small quantity of peroxide plus further additives (anti-oxidants) are processed in a
single or twin-screw extruder. They are blended at temperatures such as to “graft” the polyethylene with the
silane. Such cross-linkable product is granulated and stored in air-tight containers.
-) step 2
The cross-linkable polyethylene with the addition of a catalyst masterbatch is melted and reblended in a second
extruder, then converted into the final product (pipe).
These two steps are followed by cross-linking in hot water (normally 80 to 85°C) for a time depending on the pipe
wall thickness.
Diagram of the two-step Sioplas method
Grafting step
Silane+
peroxide
Polyethylene+
pellets
Liquid of
the pump
Step 1
Grafting extrusion
(typically L/D=25)
Pelletizing unit
Ppackaging and
storage in dry
conditions of the
grafted polymer
Shaping step
Grafted pellets
Additives
Anti-oxidant +
Catalyst
Step 2
Shaping
extrusion
Finished product
Cross-linking in water
Fig.2
SILANE CROSS-LINKED POLYETHYLENE PIPE
3.2 - One-step Monosil method
The Monosil method was introduced by Dow Chemical in 1974 and thanks to the development of special
extruders (special screw profiles) by the company Maillefer (see figure 3).
In such process, polyethylene, silane, a small quantity of peroxide, catalyst and further additives are introduced
in a single-screw extruder.
Blending of the products, grafting reactions and formation of the pipe are completed in just one extrusion and
drawing line.
Cross-linking is performed in hot water as in the previous case.
The INTERSOL® PEX-b pipe is manufactured with the latter technology, starting directly from the raw materials
purchased from manufacturers with consequent advantages of 100% quality control over all the pipe
manufacturing phases as it is not necessary to depend on intermediate manufacturers as would be required by
the Sioplas method.
Diagram of the one-step Monosil process
Polyethylene
pellets
Anti-oxidants
Silane+
peroxide+
catalyst
Finished product
Grafting and shaping extrusion
(typically L/D=30)
Cross-linking in water
Fig.3
7
SILANE CROSS-LINKED POLYETHYLENE PIPE
4 - MANUFACTURING PROCESS AND TESTING OF INTERSOL®PEX-b
Silane + liquid
8
Anti-oxidant
Non cross-linked
polyethylene
RAW MATERIAL
Testing (organoleptic
melt index, etc.)
EXTRUSION
Anti-diffusion barrier
Process control
(temperature-screw revs., etc.)
FORMING
Inspection (appearance, centering, wall thickness,
O.D., marking)
CROSS-LINKING
Process control
(bath temperature, duration)
FINISHED PRODUCT
Final testing
(degree of cross-linking,
resistance to internal
pressure Vs. temperaturecold rupture tests,
tensile tests)
INTERSOL-iip 206-UNI-315-PE-X 15x2.5-PN 16 10bar/80°C
Cross-linked
polyethylene
5 - PROPERTIES OF INTERSOL®PEX-b
Use of INTERSOL®PEX-b offers various advantages, above all:
1)
2)
3)
4)
5)
6)
7)
8)
9)
10)
Resistance to electrochemical and chemical corrosion
Long life in relation to temperature and pressure
Resistance to elevated temperature peaks (up to 100°C)
Resistance to chemicals
Low noise level
Resistance to plastic creep
Low pressure drop
Low formation of deposits
Resistance to low temperatures
Flexibility
SILANE CROSS-LINKED POLYETHYLENE PIPE
5.1 - Technical data of INTERSOL®PEX-b
Table 3
Mechanical properties
Specific gravity
Tensile strength (20°C)
Elongation at break (20°C)
Tensile modulus of elasticity (20°C)
Impact strength (20°C)
Moisture absorption (100°C)
Standard
DIN 53479
DIN 53455
DIN 53455
DIN 53457
DIN 53453
DIN 53472
Unit
gr/cm3
MPa
%
MPa
KJ/m2
%
Value
0,95
22 - 27
350 - 550
> 550
No breakage
0,05
Thermal properties
Operating temperature
Softening point
Coefficient of linear expansion (20°C)
Coefficient of linear expansion (100°C)
Impact strength (20°C)
Moisture absorption (100°C)
DIN 52612
°C
°C
°C-1
°C-1
KJ/Kg°C
W/m°C
-100 / +100
125
1,4*10-4
2,0*10-4
2,0
0,35 - 0,41
Electrical properties
Specific internal resistance (20°C)
Dielectric constant (20°C)
Dielectric strength (20°C)
-
m
KV/mm
1015
2,2
20
6 - STANDARD SIZES OF INTERSOL®PEX-b
Standard pipe dimensions depend on the field of application and typical standards of each nation.
Above all, distinction can be made between two sectors, namely:
-Floor heating and connection of radiators
-Plumbing systems
6.1 - Floor heating and connection of radiators
Two types of pipe can be used, namely:
a) with oxygen diffusion barrier, consisting of a film of coextruded ethylene vinyl alcohol (EVOH)
Table 4
O.D. - for wall thickness
14 x 2 DD
16 x 2 DD
17 x 2 DD
18 x 2 DD
20 x 2 DD
Typical Countries
Germany
Italy
Germany
Italy
Italy - Germany
Weight (Kg/m)
0,083
0,097
0,102
0,109
0,122
Capacity (l/m)
0,074
0,109
0,126
0,148
0,193
Weight (Kg/m)
0,065
0,092
0,104
0,119
0,042
0,072
0,112
0,167
Capacity (l/m)
0,048
0,108
0,150
0,194
0,073
0,128
0,201
0,318
Standard length: 100 - 120 - 200 - 240 metres
b) without anti-oxygen barrier
Table 5
O.D. - for wall thickness
12 x 2
16 x 2
18 x 2
20 x 2
12 x 1,1
16 x 1,5
20 x 1,9
25 x 2,3
Typical Countries
Italy
Italy
Italy
Italy
France
France
France
France
Standard length: 100 - 120 - 200 - 240 metres
9
SILANE CROSS-LINKED POLYETHYLENE PIPE
6.2 - Plumbing systems
Table 6
10
Dimensions - For wall thickness
12 x 2
15 x 2,5
18 x 2,5
22 x 3
28 x 3
32 x 3
16 x 2,2
20 x 2,8
25 x 3,5
32 x 4,4
12 x 1,1
16 x 1,5
20 x 1,9
25 x 2,3
Typical Countries
Italy
Italy
Italy
Italy
Italy
Italy
Germany
Germany
Germany
Germany
France
France
France
France
Weight (Kg/m)
0,065
0,100
0,124
0,181
0,231
0,274
0,098
0,153
0,233
0,382
0,042
0,072
0,112
0,167
Capacity (l/m)
0,048
0,076
0,127
0,193
0,376
0,521
0,102
0,156
0,251
0,410
0,073
0,128
0,201
0,318
Standard length: 50 - 75 - 100 metres
7 - STANDARDS AND RECOMMENDATIONS
Table 7
GERMANY
STANDARD
DIN 16892
Pipes made from high density, cross-linked polyethylene (VPE),
general requirements, testing.
DIN 16893
Pipes made from cross-linked polyethylene (VPE), dimensions.
DIN 4726
Plastic pipes used in hot water floor heating systems,
general requirements.
DIN 4729 (*)
High density, cross-linked polyethylene pipes for use in hot water floor
heating systems, general requirements and testing
DIN 4725
Hot water floor heating systems;
thermal tests (design)
DIN 8076/1
Fittings for floor heating systems
DIN 1988 + KTW Code of practice for drinking water supply systems
DVGW - W531
Manufacture, safety and testing of cross-linked polyethylene pipes
(HDPE) for drinking water in home installations
DVGW - W532
Metal fittings for cross-linked polyethylene pipes (HPDE)
used in drinking water installations
Heating
system
Plumbing
system
X
X
X
X
X
X
X
X
X
X
X
(*) related to and cited in DIN 4726.
Table 8
ITALY
STANDARD
UNI 9338
UNI 9349
Recommendation
IIP n°16
High density, cross-linked polyethylene pipes (VPE),
general requirements, testing.
Cross-linked polyethylene pipes (VPE), dimensions.
Plastic pipes used in hot water floor heating systems,
general requirements.
Heating
system
Plumbing
system
X
X
X
X
X
X
SILANE CROSS-LINKED POLYETHYLENE PIPE
Table 9
FRANCE
STANDARD
NFT 54-085
NFT 54-026
NFT 54-021
NFT 54-025
Heating
system
Plumbing
system
X
X
X
X
X
X
X
X
Cross-linked polyethylene pipes (PEX) for transport of fluids under
pressure; requirements
Thermoplastic pipes used for transport of fluids;
determination of tensile properties.
Thermoplastic pipes used for transport of fluids;
determination of longitudinal shrinkage Vs. increase in temperature
Thermoplastic pipes used for transport of fluids; determination of
pressure resistance at constant temperature
8 - FACTORY TESTS CONDUCTED ON INTERSOL®PEX-b
Table 10
TEST
STANDARD
MAIN REQUIREMENTS
Dimensional checking
UNI 9338
DIN 16893
NFT 54-085
O.D.
UNI 9338
DIN 16892
UNI 9338
DVGW-W531
UNI 9338
DIN 16892
NFT 54-085
> 65%
Degree of cross-linking
Thermoxidation
Pressure resistance at constant temperature
Cold rupture test
Tensile properties
NFT 54-026
Linear shrinkage Vs. increase in temperature
NFT 54-021
Microstructural analysis
UNI 4729
DVGW-W531
Wall thickness
- 0
+ 0,3
-0
+ 0,3
No surface alteration
Temperature = 95°C
Stress = 4,8MPa
time ≥ 1h
Stress = 4,7MPa
time ≥ 170h
Stress = 4,4MPa
time ≥ 1000h
Yield stress
≥ 20 MPa
Stress to rupture
20 MPa
Elongation at break
≥ 20 MPa
Shrinkage 2,5 %
(120°C - 1h)
9 - LONG-TERM PROPERTIES OF INTERSOL®PEX-b
For determination of permissible stress levels in long-term operation, the mechanical behaviour of the pipe was
evaluated experimentally (minimum resistances) by submitting it to pressure at different temperatures for long
periods of time. The regression curves of the INTERSOL®PEX-b pipe at various temperatures (see figure) were
derived from these tests. In the case of very long times, resistances were calculated by extrapolation.
For a pipe under pressure the equivalent stress generated by the internal pressure is calculated using the
following formula:
e =
where
P x (de - s)
20 x s
e is the equivalent stress in N/mm
P is the pressure in bar
de is the outer diameter of the pipe in mm
s is the wall thickness of the pipe in mm
2
11
SILANE CROSS-LINKED POLYETHYLENE PIPE
We shall show an example of calculating the factor of safety :
12
Suppose we have a pipe with dimensions 16 x 2 - Max. operating pressure = 3 bar
Max. operating temperature = 70°C - Required duration = 50 years
On the basis of the above data, we can deduce the equivalent force:
e =
P x (de - s) = 3 x (16 - 2)
20 x 2
20 x s
= 1,05
N
mm2
from the regression curve at 70°C it can be seen that max. stress for the period of 50 years is equal to:
max
= 5,4 N/mm2
hence the factor of safety is as follows:
fs =
max
e
=
5,4
1,05
= 5,1
For example, in accordance with UNI 9338 standard, two classes of nominal pressure are defined (max. permissible
pressure for continuous duty with water at 20°C), namely PN10 and PN16, depending on the dimensions, as given
table 11. Therefore having defined a factor of safety equal to 1.3, table 12 shows the safety operating pressures for
different temperature and time ranges.
Table 11
Table 12
Nominal
O.D.
Average
O.D.
10
12
14
15
16
17
18
20
22
25
28
32
10+0,3
12+0,3
14+0,3
15+0,3
16+0,3
17+0,3
18+0,3
20+0,3
22+0,3
25+0,3
28+0,3
32+0,3
Wall thickness
PN 10
2,0+0,2
2,0+0,2
2,0+0,2
2,0+0,2
2,0+0,2
2,0+0,2
2,3+0,2
3,0+0,3
3,0+0,3
PN 16
1,8+0,1
2,0+0,2
2,0+0,2
2,5+0,2
2,5+0,2
2,3+0,2
2,5+0,2
2,8+0,2
3,0+0,3
3,5+0,3
4,0+0,3
4,4+0,4
Temperature (°C)
up to 60°C
over 60°C
up to 80°C
over 80°C
up to 95°C
Factor Duration Max.permissible Max. permissible
of safety (years) safety force
operating pressure
(MPa)
(bar)
PN 10
PN 16
1,3
50
5,0
10
16
1,3
50
3,8
6
10
1,3
10
3,2
6
10
SILANE CROSS-LINKED POLYETHYLENE PIPE
REGRESSION CURVE
13
20 °C
10
30 °C
Hydrostatic stress (MPa)
40 °C
50 °C
60 °C
70 °C
80 °C
90 °C
95 °C
110 °C
0
0,1
1,0
10,0
100,0 1000,0 10000,0 100000,0 1000000,0
50 years
Time to fracture (h)
SILANE CROSS-LINKED POLYETHYLENE PIPE
10 - LINEAR THERMAL EXPANSION OF INTERSOL® PEX-b
The variation in pipe length against rise in temperature can be calculated using the following formula:
ΔL = ∂ x L x ΔT
where
ΔL
ΔT
L
∂
=
=
=
=
variation in length (mm)
variation in temperature (°C)
pipe length (m)
coefficient of linear expansion = (average value 1,8 x 10-4 )
Example:
ΔT = 50°C
L =6m
ΔL = 54 mm
(see graph)
Linear expansion Vs. increase in temperature
180
10
9
160
Pipe lenght (m)
8
140
7
120
Variation in lenght (mm)
14
6
100
5
80
4
60
3
40
2
20
1
0
0
20
40
60
80
Variation in temperature (°C)
100
SILANE CROSS-LINKED POLYETHYLENE PIPE
11 - OTHER PROPERTIES OF INTERSOL® PEX-b
11.1 - Two-step Sioplas method
Thanks to its flexibility, INTERSOL® PEX-b can be “cold” bent up to bend radii equal to 5 times the outer diameter.
For smaller bend radii, it is necessary to heat the pipe using hot air at 130 – 150°C (never use a direct flame).
Table 13
Outer diameter
12
14
15
16
17
18
20
25
Cold bending
60
70
75
80
85
90
100
125
Hot bending
27
31
34
36
38
40
45
56
11.2 Behaviour on exposure to light
INTERSOL® PEX-b should be stored and installed away from direct exposure to sunlight. The UV rays would
cause aging of the material, thus impairing the chemical-physical and mechanical properties.
11.3 Behaviour at low temperature
The water contained in the pipe must not freeze because the variation in phase would cause an increase in
volume with risk of the pipe caving in.
Anti-freeze substances can be used for applications below 0°C.
11.4 Pressure drop
The advantage of INTERSOL® PEX-b is that it has an internal surface free from roughness. Therefore it will
remain free from encrustations during the years of service and with very low coefficient of friction. The pressure
drops for transport of water at 20°C are given in the following graph where the correction factors associated with
the different water temperatures are given. N.B. where anti-freeze substances are present, due account should
be taken of the variation in viscosity of such solutions.
Pressure drop per metre of pipe (Water temperature = 20°C)
Conversion temperatures for other temperatures: 30°C=0,95 40°C=0,92 50°C=0,88 60°C=0,85 80°C=0,82
Pressure drop/metre (mm CA/m)
10000
1000
4,0m/s
3,5m/s
3,0m/s
2,5m/s
2,0m/s
1,5m/s
100
1,0m/s
0,9m/s
0,8m/s
0,7m/s
0,6m/s
0,5m/s
0,4m/s
0,3m/s
10
8
1
10
Inner diameter (mm)
12 13
0,2m/s
14
16 18
20 22 24
26 0,1m/s
0,1
10
100
Flow rate (lt/h)
1000
10000
15
SILANE CROSS-LINKED POLYETHYLENE PIPE
11.5 Behaviour to chemical agents
16
Cross-linked polyethylene exhibits good resistance to chemical agents. The following table shows the behaviour
of INTERSOL® PEX-b in relation to the substance and temperature where there is no external stress.
SUBSTANCE
20°C 60°C SUBSTANCE
20°C 60°C SUBSTANCE
acetic acid 10%
formaldehyde 40%
polyglycols
acetone
formic acid
potassium chloride (wat. sol.)
acrylonitrile
frigene
potassium dichromate 40%
aliphatic esters
fuel oil
potassium hydroxide 30%
allyl alcohol
glycerine
propanol
aluminium sulphate (wat.sol.)
glycol
propionic acid 50%
ammonia (wat. sol.)
hexane
propyl alcohol
ammonium sulphate (wat.sol.)
hydrofluoric acid 70%
pure aniline
aromatic esters
hydrogen peroxide 30%
pyridine
beer
hydrogen peroxide 100%
silicone oil
benzene
hydrogen sulphide
sodium hydroxide
benzoic acid (wat. sol.)
linseed oil
sodium hypochloride
bitumen
liquid soap
sulphur trioxide
bleach liquor
magnesium salts (wat.sol.)
sulphuric acid 50%
bromium
maleic acid
sulphuric acid 98%
butanol
mercury
synthetic detergents
butter
methanol
tetrahydrofuran
butyl acetate
methyl ethyl ketone
tetralin
butyne diol
methyl phenol
tincture of iodine
butyric acid
methylene chloride
toluene
carbon dioxide
milk
transformer oil
carbon tetrachloride
motor lubricants
trichloroethylene
chloroform
naphtha
turpentine
chromic acid 50%
naphthalene
vaseline
citric acid
nitric acid 30%
vegetable oils
conc. hydrochloric acid
nitric acid 50%
washing detergents
cyclanone
nitrobenzene
water
cyclohexanol
oleum
wine
cyclohexanone
oxalic acid 50%
xylene
decalin
ozone
dibutyl phthalate
paraffin oil
dichlorobenzene
petrol
dichloroethylene
petroleum
diesel oil
petroleum ether
diethyl ether
phenol
ethyl acetate
phosphates (water.sol.)
ethyl alcohol
phosphoric acid 95%
ethylene glycol
phthalic acid 50%
Legend :
Resistant
Fairly resistant
Non resistant
20°C 60°C
SILANE CROSS-LINKED POLYETHYLENE PIPE
12 - APPROVALS FOR INTERSOL® PEX-b
As the pipe manufacturing system is certified to ISO 9002, there are certain receiving, in-process and final
test/inspection procedures, as already mentioned previously. Consequently all INTERSOL® PEX-b pipes are
submitted to in-house final testing, in accordance with the requirements of European standards in the sector,
which differ according to the country of destination (e.g. UNI 9338/9349, DIN 16892/16893, DIN 4726/4729, UNE
53-381-89/53-023-86-53133-82, see previous table). Furthermore there are various product certifications,
entrusted to officially recognized testing body which can be summed up as follows:
Table 15
Country
ITALY
GERMANY
Approval Body
I I P – Istituto Italiano Plastici
SKZ
Süddeutsche
Kunstoff Zentrum
GERMANY
DVGW - Igiene Institut
GERMANY
MPA - NRW
Materialprufungsamt
Nord-RheinWstfalen
C.S.T.B. Centre Scientifique et
Technique du Batiment
LNCE National Civil Engineering
Laboratory
EMI - TÜV
Hungarian Section of German TÜV
AENOR Spanish Standards Institute
FRANCE
PORTUGAL
HUNGARY
SPAIN
U.S.A.
Floor heating
Plumbing
X
X
X
X
(only chemical (only chemical
physical tests) physical tests)
X
(oxygen
diffusion)
X
NSF International
Body Certification
X
(migration)
Main captions
UNI 315 IIP 206
DIN GEPRUEFT
DIN 4726
DIN 16892
DIN 4726
DIN 16892
DVGW
DW 8306 AL 2002
Diffusionsdicht
X
X
X
X
X
X
X
X
X
Standard 14
product standard
ASTM F876-877,
included chlorine,
CSA 137.5.
Standard 61
13 - COMPARISON OF DFFERENT PLASTICS USED IN HOT WATER PIPING
Table 16 shows different behaviours of cross-linked polyethylene (PEX), polybutylene (PB) and polypropylene
random copolymer (PP/R) materials with reference to certain important properties for applications in the heating
and plumbing industries.
Table 16
Property
Stability in hot water (95°C)
Long-term behaviour (up to 95°C)
Flexibility
Impact strength (also at low temperatures)
Elongation (longitudinal tensile test)
Toxicity
Creep properties
Thermal conductivity
Surface
A = very good
B = good
C = sufficient
PEX
A
A
A
A
C
A
A
B
A
PP-R
C
C
B
C
B
A
C
B
A
PN
B
B
A
B
C
A
B
B
A
17
SILANE CROSS-LINKED POLYETHYLENE PIPE
Table 17 is compiled from literature data and gives a detailed survey of typical values for certain characteristics
compared to those of INTERSOL® PEX-b
18
Table 17
Property
Standard
Unit
PEX-a
INTERSOL® PEX-b
PEX-c
PP-R
PB
Specific gravity
Ultimate tensile strength
Elongation
Tensile modulus of elasticity
(20°)
Coefficient of linear expansion
(20°C)
Thermal conductivity
Coefficient of linear expansion
(20-100°C)
Degree of cross-linking
DIN 53479
DIN 53455
DIN 53455
G/cm3
N/mm2
%
0,94
26-30
350-550
0,95
22-27
350-550
0,94
22-25
350-450
0,90
40
800
0,93
33
300
DIN 53457
N/mm2
>550
>550
>550
>800
>350
-
°C
°C
1,4.10-4
2,0.10-4
1,4.10-4
2,0.10-4
1,4.10-4
2,0.10-4
1,5.10-4
-
1,5.10-4
-
DIN 16892
W/mk
%
0,38
>75
0,35-0,41
>65
0,35
>60
0,24
-
0,23
-
The descriptions and photographs contained in this product specification sheet are supplied by way of information only and are not binding.
Watts Industries reserves the right to carry out any technical and design improvements to its products without prior notice.
SILANE CROSS-LINKED POLYETHYLENE PIPE
WARRANTY FOR CROSS-LINKED POLYETHYLENE (PEX)
PIPE FOR HOT FLUID PRESSURE PIPING
TUBO INTERSOL®
The pipe is produced within a certified quality management system in accordance with UNI EN
ISO 9001:2000. The INTERSOL® pipe is produced using top quality raw materials and a high
technology production cycle.
Product quality is guaranteed by strict control plans in every phase of the transformation, from
the raw materials to the process to the finished product. In addition, all coils produced are
subject to a final hydraulic test.
The specific tests for the INTERSOL®, pipe, performed in-house, comply with sector
regulations that vary based on the country for which the pipe is intended (for example UNI
9338/9349 - DIN 16892/16893 - DIN 4726/4729 - NFT 54085 - UNE 53381).
As a result, Watts Industries Italia S.r.l. warrants the INTERSOL® pipe as indicated below :
1) INTERSOL® pipes will be replaced free of charge up to 10 years after the date of supply if
damage is caused by manufacturing defects (note: “Manufacturer's warranty provided
based on technical experience in product obsolescence”)
2) damage to third parties due to manufacturing defects in the INTERSOL® pipe based on
current provisions of law (Presidential Decree 224 of May 24, 1988), will be indemnified
through insurance coverage pursuant to product liability policy VO 100008604 from
Winterthur Assicurazioni.
There is a single maximum coverage per claim per year, of €453,780.00.
Points 1) and 2) above will be valid provided the following conditions are met :
a) The INTERSOL® dpipe must be stored, handled and installed according to the instructions
reported in our technical specifications
b) Operating conditions (pressure and temperature) must comply with the limits reported in our
technical specifications
c) The product must bear our fully intact identification mark.
The customer must provide the following information when requesting warranty service :
-
place and date of installation
the pipe's identifying data and mark
information on conditions of pipe installation and operation (temperature and pressure)
sample on which the breakage occurred (preferably at least 1 meter long with the break in
the middle)
Watts Industries Italia S.r.l. reserves the right to examine the cause of the break on site before
initiating the warranty procedures.
A Division of Watts Water Technologies Inc.
19
Product range Watts Industries
Re-order no. 90-0005-UK-IT/1-07-06-Rev.0
-
System disconnectors
Backflow protection devices
Check valves
Safety units
Safety relief valves
Pressure reducing valves
Automatic control valves
Butterfly valves
Shut off valves
Measuring gauges
-
Temperature control
Expansion vessels
Process switches
Fuel products
Gas products
Electronic controls
Installation protection products
Radiator valves
System products
Manifolds and fittings
A Division of Watts Water Technologies Inc.
Watts Industries Italia S.r.l.
Via Brenno, 21 - 20046 Biassono (MI), Italy
Ph. +39 039 49.86.1 - Fax +39 039 49.86.222
e-mail : [email protected] - www.wattsindustries.com