SAFETY DATA SHEET
FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL:
FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®:
FOR ALL SDS QUESTIONS & REQUESTS, CALL:
1-800-654-6911 (OUTSIDE
USA: 1-423-780-2970)
1-800-424-9300 (OUTSIDE
USA: 1-703-527-3887)
1-800-511-MSDS (OUTSIDE
USA: 1-423-780-2347)
PRODUCT NAME: Vanquish SL-10 DOTP
EPA Registration Number: 1258-1285
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Arch Chemicals, Inc.
1200 Bluegrass Lakes Pkwy
Alpharetta, GA 30004
USA
Business Telephone (678) 624-5800
REVISION DATE:
SUPERCEDES:
06/23/2016
MSDS Number:
SYNONYMS:
CHEMICAL FAMILY:
DESCRIPTION / USE
FORMULA:
000000026416
none
Mixture
Industrial biocide
None established
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Acute toxicity (Inhalation)
:
Category 4
Skin irritation
:
Category 2
Eye irritation
:
Category 2A
Skin sensitisation
:
Category 1
Specific target organ toxicity single exposure
:
Category 3 (Respiratory system)
GHS label elements
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H315 Causes skin irritation.
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Page 1 of 11
SAFETY DATA SHEET
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
Precautionary statements
:
Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the
workplace.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS OR CHEMICAL NAME
Zinc Pyrithione
n-Butyl-1,2-benzisothiazolin-3-one
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
CAS #
13463-41-7
4299-07-4
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% RANGE
3- 7
3- 7
SAFETY DATA SHEET
SECTION 4. FIRST AID MEASURES
General Advice:
Call a poison control center or doctor for treatment advice. For 24-hour
emergency medical assistance, call Arch Chemical Emergency Action Network at
1-800-654-6911. Have the product container or label with you when calling a
poison control center or doctor, or going for treatment.
Inhalation:
IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an
ambulance, then give artificial respiration, preferably mouth-to-mouth if possible.
Call a poison control center or doctor for further treatment advice.
IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin
immediately with plenty of water for 15-20 minutes. Call a poison control center or
doctor for treatment advice.
IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first 5 minutes, then
continue rinsing eye. Call a poison control center or doctor for treatment advice.
IF SWALLOWED: Call a poison control center or doctor immediately for treatment
advice. Have person sip a glass of water if able to swallow. Do not induce
vomiting unless told to do so by a poison control center or doctor. Do not give
anything by mouth to an unconscious person.
Skin Contact:
Eye Contact:
Ingestion:
SECTION 5. FIREFIGHTING MEASURES
Flammability Summary (OSHA):
Flammable Properties
Flash Point:
Autoignition Temperature:
Fire / Explosion Hazards:
Extinguishing Media:
Fire Fighting Instructions:
Hazardous Combustion Products:
Upper Flammable / Explosive Limit,
% in air:
Lower Flammable / Explosive Limit,
% in air:
Combustible above 93 deg. C / 200 deg. F.
223 °C / 433 °F Other
380 °C
Material may be ignited only if preheated to high temperatures, for
example in a fire. During a fire, irritating and highly toxic gases may
be generated by thermal decomposition or combustion.
Use dry chemical, water fog, carbon dioxide (CO2), or foam.
In case of fire, use normal fire-fighting equipment and the personal
protective equipment recommended in Section 8 to include a NIOSH
approved self-contained breathing apparatus.
Carbon dioxide (CO2)
no data available no data available
no data available no data available
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Protection for Emergency
Situations:
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Use the personal protective equipment recommended in Section 8
and a NIOSH approved self-contained breathing apparatus.
Page 3 of 11
SAFETY DATA SHEET
Spill Mitigation Procedures
Air Release:
Hazardous concentrations in air may be found in local spill area and
immediately downwind. Vapors may be suppressed by the use of
water fog. Contain all liquid for treatment and/or disposal as a
(potential) hazardous waste.
Notify all downstream users of possible contamination. Divert water
flow around spill if possible and safe to do so. Contain all liquid for
treatment and/or disposal as a (potential) hazardous waste.
Create a dike or trench to contain materials. Absorb spill with inert
material (e.g., dry sand, clay, earth or commercial absorbent), then
place in a chemical waste container. Avoid runoff into storm sewers
and ditches which lead to waterways. Contain all liquid for treatment
and/or disposal as a (potential) hazardous waste.
Remove all sources of ignition. Stop source of spill as soon as
possible and notify appropriate personnel. Utilize emergency
response personal protection equipment prior to the start of any
response. Evacuate all non-essential personnel. Dispose of spill
residues per guidelines under Section 13, Disposal Consideration.
Water Release:
Land Release:
Additional Spill Information :
SECTION 7. HANDLING AND STORAGE
Handling:
Storage:
Incompatible Materials for Storage:
Keep containers tightly closed when not in use. A sensitized
individual should not be exposed to the product which caused the
sensitization. Do not take internally. Avoid contact with skin, eyes
and clothing. Upon contact with skin or eyes, wash off with water.
Use appropriate ventilation/PPE in thermally processed operations
Store in a cool, dry and well ventilated place. Isolate from
incompatible materials.
strong acids and bases, Nitrates, Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation:
Local exhaust ventilation or other engineering controls are normally required
when handling or using this product to keep airborne exposures below the
TLV, PEL or other recommended exposure limit.
Protective Equipment for Routine Use of Product
Respiratory Protection :
Respirator Type :
Skin Protection :
Wear a NIOSH approved respirator if levels above the exposure limits are
possible.
A NIOSH approved air purifying respirator equipped with combination
organic vapor and P100 prefilter. Air purifying respirators should not be
used in oxygen deficient or IDLH atmospheres or if exposure concentrations
exceed ten (10) times the published limit.
Wear impervious gloves to avoid skin contact. When exposure to high
concentrations are prolonged or repeated use protective boots and apron in
addition to gloves.
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Page 4 of 11
SAFETY DATA SHEET
Eye Protection:
Protective Clothing Type:
General Protective
Measures:
Use safety glasses with side shields.
Neoprene, Nitrile, Polyvinyl chloride
An eye wash and safety shower should be provided in the immediate work
area.
Components with workplace control parameters
Components (CAS-No.)
Value
Control
parameters
Basis (Update)
Zinc Pyrithione (13463-41-7)
TWA
0.35 mg/m3
ARCH OEL*
ARCH OEL: Arch Recommended Occupational Exposure Guideline.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Form
Color:
Odor:
Molecular Weight:
Relative density
liquid
liquid
off-white
faint
None established
1.01
pH :
7.4
()
199.99 °F (93.33 °C )
no data available
Boiling Point:
Density:
8.3lb/gal
Vapor Pressure:
Vapor Density:
Viscosity:
Fat Solubility:
Solubility in Water:
Partition coefficient noctanol/water:
Evaporation Rate:
Oxidizing:
Volatiles, % by vol.:
VOC Content
0.007 mmHg
no data available
no data available
no data available
immiscible
no data available
HAP Content
no data available
no data available
no data available
This product does not contain any chemicals listed under the U.S.
Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40
CFR 60.489). This product does not contain any VOC exemptions
listed under the U.S. Clean Air Act Section 450.
no data available
SECTION 10. STABILITY AND REACTIVITY
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Page 5 of 11
SAFETY DATA SHEET
Stability and Reactivity Summary:
Conditions to Avoid:
Chemical Incompatibility:
Hazardous Decomposition Products:
Decomposition Temperature:
Stable under normal conditions. Product will not undergo
hazardous polymerization.
Sparks, open flame, other ignition sources, and elevated
temperatures.
Strong oxidizing agents, Strong acids and strong bases, Nitrates
Carbon monoxide, Carbon dioxide, Oxides of sulfur
no data available
SECTION 11. TOXICOLOGICAL INFORMATION
Component Animal Toxicology
Oral LD50 value:
Zinc Pyrithione
LD50 = 269 mg/kg Rat
n-Butyl-1,2LD50 4,267 - 4,732 mg/kg
benzisothiazolin-3-one
Component Animal Toxicology
Dermal LD50 value:
Zinc Pyrithione
LD50
n-Butyl-1,2LD50
benzisothiazolin-3-one
> 2,000 mg/kg
> 2,000 mg/kg
Rat
Rabbit
Rat
Component Animal Toxicology
Inhalation LC50 value:
Zinc Pyrithione
LC50 4 h (Nose Only), (aerosol dust) =
1.03 mg/l Rat
LC50 1 h (Nose Only), (aerosol dust) =
4.12 mg/l Rat
n-Butyl-1,2benzisothiazolin-3-one
Product Animal Toxicity
Oral LD50 value:
Dermal LD50 value:
Inhalation LC50
value:
Skin Irritation:
Eye Irritation:
Skin Sensitization:
Inhalation LC50 4 h (aerosol), (Nose Only)
0.5 mg/l Rat
LD50 > 2,000 mg/kg Rat
LD50 > 2,000 mg/kg Rat
Inhalation LC50 4 h (Nose Only), (aerosol) >
2.54 mg/l Rat Inhalation LC50
1 h (Nose Only), (aerosol) >
10.16 mg/l Rat
Moderate skin irritation
Moderate eye irritation
Vanquish SL-10 was tested in a guinea pig sensitization study (MagnussonKligman method) and did not cause sensitization. However, one of the biocidal
components is a skin sensitizer and therefore, this product has some potential to
cause a skin sensitization reaction.
Zinc Pyrithione
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
This material tested negative for skin sensitization in
humans and laboratory animals.
Page 6 of 11
SAFETY DATA SHEET
n-Butyl-1,2-benzisothiazolin-3-one
Positive skin sensitizer, guinea pig - MagnussonKligman method.
Moderate Skin Sensitizer
Acute Toxicity:
Subchronic / Chronic
Toxicity:
May cause moderate skin and eye irritation. Inhalation of mist/vapors may cause
mucous membrane irritation (includes upper respiratory tract). Ingestion may
cause gastrointestinal discomfort.
Not known or reported to cause subchronic or chronic toxicity.
n-Butyl-1,2-benzisothiazolin-3-one
Reproductive and
Developmental Toxicity:
Zinc Pyrithione
Toxicological investigation indicates it does not produce
significant effects from chronic exposure.
Not known or reported to cause reproductive or developmental toxicity.
This chemical is not considered to be a reproductive or
developmental hazard. However, this material when
tested in laboratory animals at maternally toxic doses
only was found to cause developmental and/or
reproductive toxicity.
n-Butyl-1,2-benzisothiazolin-3-one
This product has been tested in laboratory animals and
was found to cause developmental toxicity only at
maternally toxic doses. However, no teratogenic effects
were seen at any of the doses tested.
Mutagenicity:
Zinc Pyrithione
Not known or reported to be mutagenic.
This chemical has been shown to be non-mutagenic
based on a battery of assays.
n-Butyl-1,2-benzisothiazolin-3-one
This material has been shown to be non-mutagenic in
the majority of a battery of assays. Not expected to be a
mutagenic hazard.
Carcinogenicity:
Zinc Pyrithione
This product is not known or reported to be carcinogenic by any reference
source including IARC, OSHA, NTP or EPA.
This material did not cause cancer in long-term animal
studies.
SECTION 12. ECOLOGICAL INFORMATION
Overview:
Toxic to fish and other aquatic organisms.
Ecological Toxicity Values for: Zinc Pyrithione
Rainbow trout (Salmo gairdneri), - (measured, flow-through) 96 h LC50 = 0.0032 mg/l
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Page 7 of 11
SAFETY DATA SHEET
Pimephales promelas (fathead
minnow)
Sheepshead minnow
Daphnia magna,
Daphnia magna,
Daphnia magna,
-
(measured, flow-through) 96 h LC50 = 0.0026 mg/l
-
Selenastrum capricornutum
(freshwater algae)
Lemna gibba G3 (Duckweed)
-
(measured, static) 96 h LC50 = 0.4 mg/l
(measured, flow-through) 48 h LC50= 0.0082 mg/l
(measured, flow-through) 48 h EC50= 0.034 mg/l
(measured, flow-through) 21 day EC50 (chronic toxicity)=
0.029 mg/l
(measured, static) 120 h EC50 = 0.028 mg/l
-
(measured, flow-through) 7 day EC50 = 0.0096 mg/l
Ecological Toxicity Values for: n-Butyl-1,2-benzisothiazolin-3-one
Bluegill sunfish - 96 h LC50 = 0.540 mg/l
Rainbow trout (Salmo gairdneri),
- 96 h LC50 = 0.150 mg/l
Daphnia magna, - 48 h EC50= 0.093 mg/l
Green algae, - 72 h LC50 = 0.240 mg/l
Green algae,
- 72 h The No Observable Effect Concentration (NOEC): =
0.099 mg/l
Pseudomonas putida - 6 h IC10 approximately 0.2 mg/l
SECTION 13. DISPOSAL CONSIDERATIONS
CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF
THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF
UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT
LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE
AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.
Waste Disposal Summary :
Spent or discarded material is not expected to be a hazardous
waste.
Disposal Methods :
As a nonhazardous waste, it should be disposed of in accordance
with local, state and federal regulations.
Potential US EPA Waste Codes :
Not applicable
SECTION 14. TRANSPORT INFORMATION
DOT
UN number
Description of the goods
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
: 3082
: Environmentally hazardous substance, liquid, n.o.s.
: (Zinc pyrithione, n-butyl-1,2-benzisothiazolin-3-one)
Page 8 of 11
SAFETY DATA SHEET
Class
Packing group
Labels
Emergency Response
Guidebook Number
TDG
UN number
Description of the goods
Class
Packing group
Labels
IATA
UN number
Description of the goods
Class
Packing group
Labels
Packing instruction (cargo
aircraft)
Packing instruction
(passenger aircraft)
Packing instruction
(passenger aircraft)
IMDG-CODE
UN number
Description of the goods
:
:
:
:
9
III
9
171
: 3082
: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(Zinc pyrithione, n-butyl-1,2-benzisothiazolin-3-one)
: 9
: III
: 9
: 3082
: Environmentally hazardous substance, liquid, n.o.s.
(Zinc pyrithione, n-butyl-1,2-benzisothiazolin-3-one)
: 9
: III
: 9MI
: 964
: 964
: Y964
Class
Packing group
Labels
EmS Number 1
EmS Number 2
: 3082
: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(Zinc pyrithione, n-butyl-1,2-benzisothiazolin-3-one)
: 9
: III
: 9
: F-A
: S-F
Marine pollutant
: yes
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Page 9 of 11
SAFETY DATA SHEET
This material does not contain any components with a section 304 EHS RQ.
SARA 302
No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
SARA 313
The following components are subject to reporting levels established by SARA Title III,
Section 313:
Zinc pyrithione
13463-41-7
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S.
Clean Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section
112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater
Act, Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater
Act, Section 311, Table 117.3.
This product contains the following toxic pollutants listed under the U.S. Clean Water Act
Section 307
Zinc pyrithione
13463-41-7
%
US State Regulations
Massachusetts Right To Know
No components are subject to the Massachusetts Right to
Know Act.
Pennsylvania Right To Know
Zinc pyrithione
13463-41-7
n-butyl-1,2-benzisothiazolin- 4299-07-4
3-one
New Jersey Right To Know
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Page 10 of 11
SAFETY DATA SHEET
Zinc pyrithione
13463-41-7
n-butyl-1,2-benzisothiazolin- 4299-07-4
3-one
California Prop 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
The components of this product are reported in the following inventories:
TSCA
: This is an EPA registered pesticide.
:
n-butyl-1,2-benzisothiazolin-3-one
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
Major References :
Available upon request.
THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA
HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO
ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS
INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT
AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION
TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS.
ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS
CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT. .
Vanquish SL-10 DOTP
REVISION DATE : 06/23/2016
Page 11 of 11