Acids and Bases Practice Problems Auto-Ionization of Water and Calculating [H3O+] and [OH-] Classwork: 1) If we have a solution with a hydronium concentration of 7.81x10-11M, what is the hydronium concentration? 2) If we have a solution with a hydroxide concentration of 5.61x10-5M, what is the hydronium concentration? 3) Given two beakers, one with pure water and the other with a hydroxide concentration of 2.16x10-3M: a. Which solution has more Hydronium? b. Assuming each beaker contains 500.mL of solution, calculate the difference in [OH-]. c. Assuming each beaker contains 500.mL of solution, calculate the difference in [H3O+]. d. Assuming each beaker contains 500.mL of solution, calculate the difference in moles of Hydronium. 4) Given two beakers, one with pure water and the other with a hydronium concentration of 4.78x10-9M: a. Which solution has more Hydroxide? b. Assuming each beaker contains 650.mL of solution, calculate the difference in [H3O+]. c. Assuming each beaker contains 650.mL of solution, calculate the difference in [OH-]. d. Assuming each beaker contains 650.mL of solution, calculate the difference in moles of Hydroxide. Homework: 5) Water has a disassociation constant (Kw) of 1x10-14. Explain why this tells us that water is not likely to disassociate. Use calculations to support your answer. 6) If we have a solution with a hydroxide concentration of 7.10x10-9M, what is the hydronium concentration? 7) If we have a solution with a hydroxide concentration of 1.23x10-8M, what is the hydronium concentration? 8) Given two beakers, one with pure water and the other with a hydroxide concentration of 5.67x10-10M: a. Which solution has more Hydronium? b. Assuming each beaker contains 250.mL of solution, calculate the difference in [OH-]. c. Assuming each beaker contains 250.mL of solution, calculate the difference in [H3O+]. d. Assuming each beaker contains 250.mL of solution, calculate the difference in moles of Hydronium. 9) Given two beakers, one with pure water and the other with a hydronium concentration of 8.93x10-3M: a. Which solution has more Hydroxide? b. Assuming each beaker contains 750.mL of solution, calculate the difference in [H3O+]. c. Assuming each beaker contains 750.mL of solution, calculate the difference in [OH-]. d. Assuming each beaker contains 750.mL of solution, calculate the difference in moles of Hydroxide. Identifying Acids and Bases Classwork: 10) A Sodium Hydroxide solution has a [OH-] of 2.67x10-2M. a. Write the disassociation equation of solid Sodium Hydroxide in water. b. Based on the disassociation equation and Arrhenius’s definitions of acids and bases, is the solution an acid or a base? Explain c. Based on the disassociation equation and the Bronsted and Lowery definitions of acids and bases, is the solution an acid or a base? Explain d. Based on the disassociation equation Lewis’s definitions of acids and bases, is the solution an acid or a base? Explain 11) A Vinegar (CH3COOH) solution has a [H3O+] of 9.76x10-4M. a. Write the disassociation equation of solid Sodium Hydroxide in water. b. Based on the disassociation equation and Arrhenius’s definitions of acids and bases, is the solution an acid or a base? Explain c. Based on the disassociation equation and the Bronsted and Lowery definitions of acids and bases, is the solution an acid or a base? Explain d. Based on the disassociation equation Lewis’s definitions of acids and bases, is the solution an acid or a base? Explain Homework: 12) A Sodium Hydroxide solution has a [OH-] of 2.67x10-2M. a. Write the disassociation equation of solid Sodium Hydroxide in water. b. Based on the disassociation equation and Arrhenius’s definitions of acids and bases, is the solution an acid or a base? Explain c. Based on the disassociation equation and the Bronsted and Lowery definitions of acids and bases, is the solution an acid or a base? Explain d. Based on the disassociation equation Lewis’s definitions of acids and bases, is the solution an acid or a base? Explain 13) An Ammonia (NH3) solution has a [H3O+] of 3.14x10-9M. a. Write the disassociation equation of solid Sodium Hydroxide in water. b. Based on the disassociation equation and Arrhenius’s definitions of acids and bases, is the solution an acid or a base? Explain c. Based on the disassociation equation and the Bronsted and Lowery definitions of acids and bases, is the solution an acid or a base? Explain d. Based on the disassociation equation Lewis’s definitions of acids and bases, is the solution an acid or a base? Explain Identifying Conjugate Acids and Bases Classwork: 14) For Sodium Hydroxide a. Write the reaction Sodium Hydroxide undergoes in water b. Identify which reactants act as an acid or a base c. Identify which products are the conjugate bases and acids 15) For Ammonia a. Write the reaction Ammonia undergoes in water b. Identify which reactants act as an acid or a base c. Identify which products are the conjugate bases and acids 16) For Hydrochloric Acid a. Write the reaction Hydrochloric Acid undergoes in water b. Identify which reactants act as an acid or a base c. Identify which products are the conjugate bases and acids 17) For the auto-ionization of water a. Write the reaction water undergoes when it auto-ionizes b. Identify which reactants act as an acid or a base c. Identify which products are the conjugate bases and acids Homework: 18) For Hydrobromic Acid a. Write the reaction Hydrobromic Acid undergoes in water b. Identify which reactants act as an acid or a base c. Identify which products are the conjugate bases and acids 19) For Vinegar d. Write the reaction Vinegar undergoes in water e. Identify which reactants act as an acid or a base f. Identify which products are the conjugate bases and acids 20) For Potassium Ion g. Write the reaction Potassium Ions undergo in water h. Identify which reactants act as an acid or a base i. Identify which products are the conjugate bases and acids Calculating pH Classwork: 21) If the H+ concentration is 0.0001 mol/L , what is the pH? 22) If the H+ concentration is 0.00000001M , what is the pH? 23) If the H+ concentration is 0.00024 mol/L , what is the pH? 24) If the pH is 2.00, what is the H+ concentration ? 25) If the pH is 10.00, what is the H+ concentration ? 26) If the pH is 4.30, what is the H+ concentration ? 27) If the pH is 9.10, what is the H+ concentration ? Homework: 28) If the H+ concentration is 0.089 mol/L , what is the pH? 29) If the H+ concentration is 8.4 x10-11M , what is the pH? 30) If the H+ concentration is 2.1 x 10-4 mol/L , what is the pH? 31) If the H+ concentration is 6.7 x10-8M , what is the pH? 32) If the pH is 6.34, what is the H+ concentration ? 33) If the pH is 3.89, what is the H+ concentration ? 34) If the pH is 5.712, what is the H+ concentration ? Calculating pOH Classwork: 35) If the H+ concentration is 0.0001 mol/L , what is the pOH? 36) If the H+ concentration is 0.00000001M , what is the pOH? 37) If the H+ concentration is 0.00024 mol/L , what is the pOH? 38) If the [H+] of a solution is 5.43x10-4M calculate the pOH. 39) If the [H+] of a solution is 9.37x10-11M calculate the pOH. Homework: 40) If the H+ concentration is 0.089 mol/L , what is the pOH? 41) If the H+ concentration is 8.4 x10-11M , what is the pOH? 42) If the H+ concentration is 2.1 x 10-4 mol/L , what is the pOH? 43) If the H+ concentration is 6.7 x10-8M , what is the pOH? 44) What is the pOH of a solution with a hydronium concentration of 3.14x10-5M? 45) What is the pH of a solution with a Hydroxide concentration of 6.71x10 -13M?
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