Use carbonated soda to explore solubility of a gas Jean Weaver, Ph.D.< [email protected]> The Prairie School Racine WI 53402 Purpose bottles and their contents (are the bottles the same size, is there the same amount of soda in each, are there bubbles present in either bottle, etc.). Write down your observations in the table below. To illustrate the effect of temperature and pressure on the solubility of a gas in a liquid. Applications 2. Slowly open each bottle, one at a time. Observe and compare what you hear and see happen in each bottle. Write down your observations. 3. Slowly pour a little of each soda into your cups. Again, observe and compare. Write down your observations. 4. Finally, taste the warm and the cold soda and record your observations. Solubility, gases, solutions, Henry’s Law Materials ∙ two identical, unopened 20 oz sodas in plastic bottles per lab group (any kind will work, but colas and root beer produce the most noticeable effects) ∙ drinking cups ∙ cooler containing an ice-water slurry ∙ lab oven or food service warming oven Homework Questions 1. Which soda, the warm or the cold one, had more dissolved carbon dioxide? List all the ways that you know. Do not perform this experiment in a lab; try a classroom or a cafeteria. 2. What is the best way to store an opened bottle of soda so that is doesn’t go flat quickly? Preparation 3. In order to make electricity, many power plants condense steam by pumping cool river or lake water around the steam pipes. The steam cools and condenses as its heat is transferred to the water, which is then returned to the river or lake. What impact does this warm water have on the fish in the lake or river? (Hint: think about the solubility of gases and what gas fish need to survive.) Safety Precautions Each lab group should bring in two sodas and drop them off well before class (the day before you do this activity, or during the morning). At least an hour before class, your teacher will place one of the bottles in the cooler, the other in the oven. He or she will heat the sodas gently so as not to rupture the plastic bottles. Student Directions 1. Without opening the bottles, observe and compare the Disposal Pour any remaining soda down the sink. Observations Before Opening While Opening After Opening 12 Chem 13 News/October 2007 Warm Soda Cold Soda Outcomes for soda lab (for the teacher) Teacher comments The way I do this experiment with my students is as an inquirybased lab where the kids follow my brief directions and have to think about their own observations in order to draw their conclusions. Explaining the Theory section to them beforehand would spoil all the fun — they would already know what is supposed to happen and their conclusions would lack authenticity. Students enjoy this lab; having soda in class is a bonus. 20th Biennial Conference on Chemical Education, July 27 – 31, 2008 Theory The solubility of a gas in a liquid, such as CO2 in soda, is proportional to the external pressure. Once the seal on a soda bottle has been broken, the pressure decreases to match the atmospheric pressure and gaseous CO2 begins to escape from the solution as evidenced by bubbles and fizz. The solubility of the CO2 is also inversely dependent on the temperature. A warm bottle of soda has a larger “air” space at its top and bubbles and fizzes more than a cold bottle of soda. Once opened and at atmospheric pressure, a cold soda maintains its carbonation longer than an identical warm soda. Observations that your students might make include: Observations Before Opening While Opening After Opening Warm Soda - Bottle bulged outward - More “air” space above soda - Loud, long “whssssh” sound - Lots of bubbles rising to the top - Had to close bottle to keep it from overflowing - While pouring: lots of fizzing and foam, tall head - Tastes flat, “bad” Cold Soda - No apparent change - Short, soft “whsssh” sound - Some bubbles, not many - While pouring: soft fizz, small amount of foam in cup - Tastes tangy, fizzy, “good” Answers to homework questions 1. The cold soda had more dissolved carbon dioxide. Proof: the warm soda bottle bulged outward but the cold one maintained its shape; the cold soda had a softer fizzing sound and less gas was released when the bottle was opened; the cold one produced less fizz when the soda was poured into cups; and the cold soda did not taste flat but the warm one did. 2. Sealed, in a cool place such as a refrigerator. 3. The temperature of the river or lake water increases which causes the solubility of oxygen to decrease. As a result, the fish have difficulty breathing and may die or at least relocate. ∎ The Biennial Conferences on Chemical Education (BCCEs), which are sponsored by the ACS Division of Chemical Education, are the largest gathering of chemical educators in the world and are designed for middle school science teachers, secondary school chemistry teachers, and college chemistry instructors. This conference emphasizes the improvement of chemistry education at all levels, the modern developments in chemistry and chemical education, and is highly respected in the chemical education community. Claire Baker, secondary education program chair, is putting together a wonderful series of symposia for high school teachers. Topics include Advanced Placement Chemistry, Chemical Demonstrations, Before Five Years of Experience, and Overview of College Credit Programs for High School Students to name a few. There will also be symposia focused on teacher preparation, continuing education, and building bridges between secondary education and college programs. In addition to all of the symposia, there will be hands-on workshops and plenty of time to network with your colleagues. More information about the conference is available at http://bcce2008.indiana.edu. There is still time if you are interested in organizing and submitting a symposium proposal — the deadline is November 2, 2007. Since the BCCE is a time for professional development, you should consider presenting a paper or poster. Abstract submission opens November 15, 2007. If you have any suggestions, ideas or questions about the conference, please contact the organizers through our email address, [email protected]. We look forward to seeing YOU at the 20th BCCE in Bloomington, Indiana!! ∎ October 2007/Chem 13 News 13
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