MATERIAL SAFETY DATA
SHEET
Page : 4
Revision nr : 3
Date : 7/3/2007
Supersedes : 4/3/2003
SULPHURIC ACID 94/98%
Code : 2802
www.Lisam.com
13. DISPOSAL CONSIDERATIONS
Waste from residues/Unused products
Removal contaminated packaging
: The product has to be destroyed according to national or local legislation, by a
company specialised in handling hazardous waste products.
: Packing is to be used exclusively for the packing of this product.
After use, empty and close the packing very carefully.
In case of returned packing, the empty packing can be offered back to the supplier.
14. TRANSPORT INFORMATION
*
*
Land (Road/Railroad, ADR/RID)
- ADR Name
- ADR Division
- Hazard Label(s)
- Danger number
- Substance Ident. Number (UN-n°)
Sea Transport (IMDG)
- Product Name
- Class
- Hazard Label(s)
- UN Number
- Packaging Group
- EmS-N°
- Marine pollutant
:
:
:
:
:
UN 1830 Sulphuric acid, 8, II
8 , II
8
80
1830
:
:
:
:
:
:
:
UN 1830 Sulphuric acid , 8, II
8
8
1830
II
F-A, S-B
NO
15. REGULATORY INFORMATION
Name dangerous component(s)
EC Number
Symbol(s)
R-Phrases
S-Phrases
:
:
:
:
:
Sulphuric acid .
231-639-5
Corrosive (C).
R35 - Causes severe burns.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S30 - Never add water to this product.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (
show the label when possible).
16. OTHER INFORMATION
This safety data sheet has been drawn up in accordance with the Directive 2001/58/EC.
This safety data sheet is exclusively made for industrial/professional use.
* Has changed compared to previous revision.
*
Changes
R-phrases
Sources of used key data
: Change of product name , General revision .
: R35 - Causes severe burns.
: The information contained herein is based on the present state of our knowledge (
Producer , Chemical cards , ...).
This information is to our knowledge correct and complete on the date of issue of this safety data sheet. The information only
concerns the product and does not give any guarantee for the quality and the completeness of the properties of the product, or in
case of mixing or using in any other process. It remains the responsibility of the user to assure himself that the information is
suitable and complete concerning the special use he makes of the product.
BRENNTAG denies all responsibility for loss or damage resulting from the use of these data.
End of document
BRENNTAG NV
B-8540 DEERLIJK TEL.: 056/77.69.44
Antipoison Center Tel. nr. : 070/245.245
Rabbasol
Rabbaflor 8-8-6 Liquid Fertilizer
Material Safety Data Sheet
ln accordance with the order 19O72O06lEG(Reach)
Date issued:.1'1.02.20'l0
page 1 of 3
Fallerslebenweg 9-1 3, 42719 Solingen, Germany
Emergency Phone: Rabbasol: 0049 212312053
I Product lnformation
Product: Rabbaflor 8-8-6 / Rabbasol Liquid Fertilizer
chemical Family. inorganic salts
Chemical Name/Synonyms: None
ll Product lnformation: Ingredients
CAS#
TLV/TWA
%(by wt.)
Ghemical Name
NA
57-13-6
8
Urea
7329-34-5
8
Tetrapotassium Pyrophosphate NA
10294-66-3
6,5
NA
Potassicoxyd
NA
0,01
Chelated lron
0,01
NA
Chelated Copper
NA
0,01
Chelated Boracic
0,05
NA
Chelated Manganese
NA
0,01
Chelated Ferric
0,005
NA
Chelated Molybdenum
0,005
NA
Chelated Zinc
NA
68
Water
Less than 0,2 o/o biuret
lll Physical And Chemical Characteristics
: 100
Boiling Point: oC
Vapor Density: g/ml(2O"C) '. ca. 1,2 D1N51757
D|N51640
Vapor Pressure: mbar(2O'C) :23
D1N19261
PH, non-diluted (20'C) :ca. 5
(20'C)
:
ca.
6
PH 5o/o
Solubility in water: Complete
NA
Bulk Density:
Evaporation Rate: ND
Percent Volatile. ND
Viridiscent, light
Appearance and Odor:
lV Fire And Explosion Hazard Data
NA Auto lgnition Temperature: NA
Flash Pont (method Used):
NA
Upper Explosion Limis:
NA
Lower Explosion Limis:
Special Fire-Fighting Procedures: Wear NIOSH approved positive pressure, self
contained
breathing apparatus. Foam system is preferred because uncontrolled water can spread
possible contamination. Prevent run-off from entering drains, sewers or bodies of water.
Rabbasol
Rabbaflor 8-8-6 Liquid Fertilizer
Material Safety Data Sheet
In accordance with the order 19072006/EG(Reach)
Date issued= 11.02.2010
page 2 of 3
Unusual Fire and Explosion Hazards: Containers exposed to fire may rupture violently
Use water spray to keep exposed containers cool.
V
Health Hazards
Primary Route(s) of Entry: Skin, eyes, inhalation, ingestion.
Signs & Symptoms of Exposure
Acute: Eye contact with product solution or spray mist cause irritation or burning
Sensation. Prolonged or repeated contact may cause skin irritation. lnhalation of
spray mist may irritate the respiratory tract. lngestion may irritate the
gastrotestinaltract, however, product is considered to have low mammalian
toxicity.
Ghronic: None known
Emergency First-Aid Procedures
Eyes: lmmediately flush eyes with large quantities of water for at least 15
minutes. Hold eyetids apart during rinsing to ensure thorough flushing of eye and
eyelids with water. Get medical attention if irritation develops.
Skin. Remove any contaminated clothing. Flush affected area with mild soap
and water. Get medical assistance if irritation develops. Launder contaminated
clothing before reuse.
lnhalation: Remove to fresh air
lngestion: lf victim is conscious, give 2-3 glasses of water to drink and induce
vomiting by touching back of throat with finger" Get immediate medical attention.
Notes to Physician: No specific antidote. Treat symptomatically.
Toxicity lnformation: Persons with existing lesions should use care when using
this oroduct.
Positive Teratogen od Mutagen Carcinogen(NTP): No Potential Carcinogen (IARC or
OSHA): No
Vl Reactivity
Stability: stable
Conditions to avoid: avoid storage temperatures above 100 'C.
lncompatibility: Not known
Hazardous Decomposition Products: Not known
Hazardous Polymerization: Will not occur
Vll Disposal Procedures
Waste Disposal Method. Dispose according to state and local guidelines. Triple rinse
and
puncture containers as required.
VlllStorage and Handling
Precautions: Store in a cool, dry place, out or rech of children and animals
Other Precautions: Practice good care and good safety precautions when handling this
product. Avoid contact with eye, skin and clothing. Wash thoroughly after handling.
Rabbasol
Rabbflor 8-8-6 Liquid Fertilizer
Material Safety Data Sheet
ln accordance with the order 19O72O06lEG(Reach)
Date issued:1'1.02.2010
Page 3 of 3
lX Federal Regulatory lnformation:
According to the rules of the European Community
Symbols of danger: None
Rsponsibility. This product is not classified according to the legalization of the
Eurpean Community.
Utilization of the product: The classification and the labelling are accomplished
by virtue of the European Directives 67l548lCEE and 1999/45lCE an its amendments
Preparation and distribution of this Material Data Sheet done by Rabbasol Chemie GmbH,
Fallerslebenweg 9-1 3, 427 19 Solingen, Germany.
The information contained herein is based on available data. However, no warranty is expressed or
implied regarding the accuracy of this data or the results to be obtained from the use thereof; and you
should make your investigation to determine safety for the use you contemplate. Rabbasol Chemie
GmbH makes no warranty of merchantability of fitness for a particular use, nor is there any other
express or implied warranty except as may be specifically provided otherwise on product.
Rabbasol Chemie GmbH assumes no responsibility or liability for any incidental or consequential
damages whether related to personal injury or property damage, to vendees, users or third parties,
caused by the material; and Rabbasol Chemie GmbH 's responsibility is limited to replacement of, or
repayment of, the purchase price for the material which respect to which any damages are claimed. All
vendess or users assume all risk associated with the use of the material.
For further information, contact: Rabbasol Chemie GmbH, Fallerslebenweg 9-13, 427119
Solingen, Germany, Tel. 0049 (01212312053
SIGMA-ALDRICH
sigma-aldrich.com
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Version 5.2 Revision Date 16.04.2012
Print Date 21.08.2014
GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA
1.
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1
Product identifiers
Product name
:
Alkaline buffer solution, 1.5 M
Product Number
Brand
:
:
A9226
Sigma
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
1.3
1.4
:
Laboratory chemicals, Manufacture of substances
Details of the supplier of the safety data sheet
Company
:
Sigma-Aldrich Química, S.L.
Sucursal em Portugal
Caixa Postal 131
Av. Almirante Gago Coutinho,
132-134,
P-2711 901 SINTRA
Telephone
Fax
E-mail address
:
:
:
+351219242555
+351219242610
[email protected]
Emergency telephone number
Emergency Phone #
:
+44 1235 239 670
2.
HAZARDS IDENTIFICATION
2.1
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Skin irritation (Category 2)
Eye irritation (Category 2)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Irritating to eyes and skin.
2.2
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Warning
Hazard statement(s)
H315
H319
Causes skin irritation.
Causes serious eye irritation.
Precautionary statement(s)
P305 + P351 + P338
Supplemental Hazard
Statements
Sigma - A9226
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
none
Page 1 of 7
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R36/38
S-phrase(s)
S26
Irritating to eyes and skin.
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
2.3
Other hazards - none
3.
COMPOSITION/INFORMATION ON INGREDIENTS
3.2
Mixtures
Component
2-Amino-2-methylpropanol
CAS-No.
124-68-5
EC-No.
204-709-8
Index-No.
603-070-00-6
Classification
Concentration
Eye Irrit. 2; Skin Irrit. 2;
Aquatic Chronic 3; H319,
H315, H412
Xi, R36/38 - R52/53
10 - 20 %
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16
4.
FIRST AID MEASURES
4.1
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2
Most important symptoms and effects, both acute and delayed
4.3
Indication of any immediate medical attention and special treatment needed
no data available
5.
FIREFIGHTING MEASURES
5.1
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
5.3
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4
Further information
no data available
Sigma - A9226
Page 2 of 7
6.
ACCIDENTAL RELEASE MEASURES
6.1
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
6.2
Environmental precautions
Do not let product enter drains.
6.3
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4
Reference to other sections
For disposal see section 13.
7.
HANDLING AND STORAGE
7.1
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
7.2
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage temperature: 2 - 8 °C
7.3
Specific end uses
no data available
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1
Control parameters
Components with workplace control parameters
8.2
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Sigma - A9226
Page 3 of 7
9.
PHYSICAL AND CHEMICAL PROPERTIES
9.1
Information on basic physical and chemical properties
a)
Appearance
Form: liquid
b)
Odour
no data available
c)
Odour Threshold
no data available
d)
pH
no data available
e)
Melting point/freezing
point
no data available
f)
Initial boiling point and
boiling range
no data available
g)
Flash point
no data available
h)
Evaporation rate
no data available
i)
Flammability (solid, gas) no data available
j)
Upper/lower
flammability or
explosive limits
no data available
k)
Vapour pressure
no data available
l)
Vapour density
no data available
m) Relative density
no data available
n)
Water solubility
no data available
o)
Partition coefficient: noctanol/water
no data available
p)
Autoignition
temperature
no data available
q)
Decomposition
temperature
no data available
r)
Viscosity
no data available
s)
Explosive properties
no data available
t)
Oxidizing properties
no data available
9.2
Other safety information
no data available
10.
STABILITY AND REACTIVITY
10.1
Reactivity
no data available
10.2
Chemical stability
no data available
10.3
Possibility of hazardous reactions
no data available
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
Sigma - A9226
Page 4 of 7
10.6
Hazardous decomposition products
11.
TOXICOLOGICAL INFORMATION
11.1
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
May be harmful if inhaled. Causes respiratory tract irritation.
May be harmful if swallowed.
May be harmful if absorbed through skin. Causes skin irritation.
Causes eye burns.
Additional Information
RTECS: Not available
12.
ECOLOGICAL INFORMATION
12.1
Toxicity
no data available
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Results of PBT and vPvB assessment
no data available
12.6
Other adverse effects
no data available
Sigma - A9226
Page 5 of 7
13.
DISPOSAL CONSIDERATIONS
13.1
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14.
TRANSPORT INFORMATION
14.1
UN number
ADR/RID: -
IMDG: -
IATA: -
14.2
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG:
Not dangerous goods
IATA:
Not dangerous goods
14.3
Transport hazard class(es)
ADR/RID: -
IMDG: -
IATA: -
Packaging group
ADR/RID: -
IMDG: -
IATA: -
Environmental hazards
ADR/RID: no
IMDG Marine pollutant: no
IATA: no
14.4
14.5
14.6
Special precautions for user
no data available
15.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2
Chemical Safety Assessment
no data available
16.
OTHER INFORMATION
Text of H-code(s) and R-phrase(s) mentioned in Section 3
Aquatic Chronic
Eye Irrit.
H315
H319
H412
Skin Irrit.
Xi
R36/38
R52/53
Chronic aquatic toxicity
Eye irritation
Causes skin irritation.
Causes serious eye irritation.
Harmful to aquatic life with long lasting effects.
Skin irritation
Irritant
Irritating to eyes and skin.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Further information
Copyright 2012 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.
Sigma - A9226
Page 6 of 7
Sigma - A9226
Page 7 of 7
Page 1/6
Safety data sheet
according to 1907/2006/EC
Printing date 20.07.2012
Version number 5
Revision: 20.07.2012
1 Identification of the substance/mixture and of the company/
undertaking
· 1.1 Product identifier
· Trade name: Struktol SB 2031
· Article number: 02009
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the preparation Anti-foaming agent
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Schill+Seilacher "Struktol"
GmbH
Moorfleeter Str. 28
D-22113 Hamburg
Phone: +49 / (0)40 / 73362-0
Fax: +49 / (0)40 / 73362-194
· Further information obtainable from:
QW Gefahrgut / -stoffe
E-Mail: [email protected]
· 1.4 Emergency telephone number:
GIZ-Nord
Phone: +49 / (0)551 / 19240
2 Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Not applicable.
· Information concerning particular hazards for human and environment:
The product does not have to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
· 2.2 Label elements
· Labelling according to EU guidelines:
Observe the general safety regulations when handling chemicals.
The product is not subject to identification regulations under EU Directives and the
Ordinance on Hazardous Materials (German GefStoffV).
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· 3.2 Chemical characterization: Mixtures
· Description: Combination of fatty acid esters and special alcohols.
(Contd. on page 2)
GB
35.0.6
Page 2/6
Safety data sheet
according to 1907/2006/EC
Printing date 20.07.2012
Version number 5
Revision: 20.07.2012
Trade name: Struktol SB 2031
(Contd. of page 1)
· Dangerous components:
CAS: 27458-94-2
Alkyl alcohol
EINECS: 248-471-3
Xi R36/38
Skin Irrit. 2, H315; Eye Irrit. 2, H319
· Additional information:
This information refers to the product in concentrated form only.
2.5-10%
For the wording of the listed risk phrases refer to section 16.
4 First aid measures
· 4.1 Description of first aid measures
· General information: No special measures required.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Wash off with water and soap.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a
doctor.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
· 5.3 Advice for firefighters
· Protective equipment: Do not inhale explosion gases or combustion gases.
6 Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Not required.
· 6.2 Environmental precautions:
The product should not be released into the aquatic environment without preliminary
treatments (purification plant).
Do not allow to enter sewers/ surface or ground water.
Do not allow to penetrate the ground/soil.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,
sawdust).
(Contd. on page 3)
GB
35.0.6
Page 3/6
Safety data sheet
according to 1907/2006/EC
Printing date 20.07.2012
Version number 5
Revision: 20.07.2012
Trade name: Struktol SB 2031
(Contd. of page 2)
· 6.4 Reference to other sections
No dangerous substances are released.
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
*
7 Handling and storage
· 7.1 Precautions for safe handling
The usual precautionary measures are to be adhered to when handling chemicals.
· Information about fire - and explosion protection: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Store in dry conditions.
· 7.3 Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that
have to be monitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
· Respiratory protection: Not necessary if room is well-ventilated.
· Protection of hands:
Protective gloves or protective skin cream.
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion
and the degradation.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product is a
preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective
gloves and has to be observed.
· Eye protection: Goggles recommended during refilling
(Contd. on page 4)
GB
35.0.6
Page 4/6
Safety data sheet
according to 1907/2006/EC
Printing date 20.07.2012
Version number 5
Revision: 20.07.2012
Trade name: Struktol SB 2031
(Contd. of page 3)
· Body protection: Protective work clothing
9 Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Fluid
Colour:
Yellowish
· Odour:
Aromatic
· Odour threshold:
Not determined.
· pH-value:
Not determined.
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Not determined.
Not determined.
· Flash point:
> 130°C (DIN EN ISO 2592)
· Flammability (solid, gaseous):
Not applicable.
· Ignition temperature:
200°C
· Decomposition temperature:
Not determined.
· Self-igniting:
Product is not selfigniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits:
Lower:
Upper:
Not determined.
Not determined.
· Vapour pressure:
Not determined.
· Density at 20°C:
· Relative density
· Vapour density
· Evaporation rate
0.86 g/cm³ (DIN 53479)
Not determined.
Not determined.
Not determined.
· Solubility in / Miscibility with
water:
Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic at 25°C:
Kinematic:
· 9.2 Other information
20 mPas (DIN 51550)
Not determined.
No further relevant information available.
10 Stability and reactivity
· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
(Contd. on page 5)
GB
35.0.6
Page 5/6
Safety data sheet
according to 1907/2006/EC
Printing date 20.07.2012
Version number 5
Revision: 20.07.2012
Trade name: Struktol SB 2031
(Contd. of page 4)
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
No dangerous decomposition products known.
11 Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
27458-94-2 Alkyl alcohol
Oral LD50 2830 mg/kg (rat)
· Primary irritant effect:
· on the skin: With longer skin contact irritation possible!
· on the eye: With longer contact eye-irritation possible!
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product is not subject to classification according to the calculation method of the
General EU Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any
harmful effects to our experience and the information provided to us.
12 Ecological information
· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
The product should not be released in concentrated form into the aquatic environment
without preliminary treatments (purification plant).
Negative ecological effects are, according to the current state of knowledge, not
expected.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
13 Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Disposal must be made according to official regulations.
Must not be disposed together with household garbage. Do not allow product to reach
sewage system.
(Contd. on page 6)
GB
35.0.6
Page 6/6
Safety data sheet
according to 1907/2006/EC
Printing date 20.07.2012
Version number 5
Revision: 20.07.2012
Trade name: Struktol SB 2031
(Contd. of page 5)
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· 14.6 Special precautions for user
Not applicable.
· 14.7 Transport in bulk according to
Annex II of MARPOL73/78 and the IBC
Code
Not applicable.
· Transport/Additional information:
Not dangerous according to the above
specifications.
15 Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
· National regulations:
· Breakdown regulations:
· Breakdown regulations, Annex II, No.:
None of the ingredients is listed.
· 15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16 Other information
This information refers to the product in concentrated form only.
This information is based on our present knowledge. However, this shall not constitute a
guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
· Relevant phrases
H315 Causes skin irritation.
H319 Causes serious eye irritation.
R36/38 Irritating to eyes and skin.
· Department issuing MSDS: QW Gefahrgut / -stoffe
· Abbreviations and acronyms:
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered.
GB
35.0.6
BIO-INDUSTRIES LTD©2010
CLEANING THE ENVIRONMENT NATURALLY
Email: [email protected] Web: www.bio.ie
SAFETY DATA SHEET
BIOACTIVATOR
Page 1 of 5
Issued: 01/11/2010
Revision No. 1
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKE
Product name: Bioactivator
CAS number: N/A
EINECS number: N/A
Log number: N/A
Product code: N/A
Use of substance / preparation: Waste Water Treatment, anaerobic digesters ,
pharmaceutical/paper waste treatment plants and oil Remediation. Trace elements ( chelated) and
seaweed plant extract.
Company name: Bio Industries Ltd, 66D Heather Road, Sandyford Business Park, Dublin 18,
Ireland,
Tel. (+353)12941025, Fax (+353)12941027, Emergency Tel: (+353)12941025
2. HAZARDS IDENTIFICATION
Main hazards:
Xn R 22 - Harmful if swallowed
Xi R 38 - Irritating to skin
Xi R 36 - Irritating to eyes
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients: Proprietary Mixture of Selected micro-nutrients, (trace elements)
Seaweed plant extract, in chelated buffered Suspension.
4. FIRST AID MEASURES
Skin contact: Remove any contaminated clothing. Wash the affected area thoroughly with copious
amounts of fresh water.
Eye contact: Wash eyes with flowing water for ten minutes gentle prising open eyelids to ensure
efficient washing.
All eye injuries should be seen by a doctor.
Ingestion: Do NOT induce vomiting except in the presence of, or on the orders of a doctor. Seek
medical help and take this data sheet. If chemical is confined to the mouth then wash out mouth and
do not allow patient to swallow mouth wash.
Inhalation: Inhalation is not normally a problem because of the low vapour pressure. Treat by normal
first-aid procedures.
5. FIRE-FIGHTING MEASURES
Extinguishing media: When mixed with flammable substances apply appropriate procedures: Water
Spray, Foam, Carbon Dioxide, and Dry Powder
Exposure hazards: Non Flammable
Protection of fire-fighters: Wear protective clothing to prevent contact with skin and eyes.
BIO-INDUSTRIES LTD©2010
CLEANING THE ENVIRONMENT NATURALLY
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SAFETY DATA SHEET
BIOACTIVATOR
Page 2 of 5
Issued: 01/11/2010
Revision No. 1
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: N/A
Environmental precautions: N/A
Clean-up procedures: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust) or dilute with water and flush to sewer.
7. HANDLING AND STORAGE
Handling requirements: Ensure there is sufficient ventilation of the area. Smoking is forbidden. Use
non-sparking tools.
Storage conditions: Keep containers tightly closed. Keep in properly labelled, containers.
Suitable packaging: Plastic or stainless steel containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Hazardous ingredients: No
Respiratory protection: None
Hand protection: gloves are required, PVC, Rubber or Latex.
Eye protection: Protective glasses should be worn when handling the concentrated product.
Skin protection: Protective equipment or clothing is not normally necessary.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Appearance
Physical State:
Liquid Suspension
Colour:
Brown
Odour:
Natural
Clarity:
Opaque to Clear
9.2 Safety Related Information
Specific Gravity: 2.0-.3
pH: 4.0-6.0
Percent Volatile: N /A
Viscosity: Viscose
Solubility in Water : Miscible/complete
Boiling Point (deg C): 110 oC
Melting point/melting range: NA
Flashpoint: NA
Flammability (solid, gas) : Not determined
Autoflammability : Not determined
BIO-INDUSTRIES LTD©2010
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SAFETY DATA SHEET
BIOACTIVATOR
Page 3 of 5
Issued: 01/11/2010
Revision No. 1
Explosive Properties: Not determined
Oxidising properties: Not determined
Vapour pressure: Not determined
Solubility in fat: Not determined
Oil/water partition coefficient: Not determined
Vapour density: (air=1)
evaporation rate (ethyl ether= 1): Not determined
% Volatile: Not determined
Molecular Weight: Not determined
11. TOXICOLOGICAL INFORMATION
Stability: Stable under normal condition
Conditions to avoid: None Known
Materials to avoid: Strong oxidising agents (Chlorine)
Hazardous Decomposition Products: None
Toxicity value(s): ORL RAT LD50 >2000mg/kg
Acute effects: N/A
11. TOXICOLOGICAL INFORMATION (SYMPTOMS)
Skin contact: Wash with water and consult a physician if irritation develops
Eye contact: Flush with water
Ingestion: Do not induce vomiting
Inhalation: No significant effect. See other health hazard information
12. ECOLOGICAL INFORMATION
Persistence and degradability: Readily biodegradable, according to appropriate OECD test
PBT identification: N/A
13. DISPOSAL CONSIDERATIONS
Disposal operations: No special precautions, domestic sewer.
Disposal of packaging: Packaging should be disposed of in accordance with regional and/or
national regulations.
NB: The user’s attention is drawn to the possible existence of regional or national regulations
regarding disposal.
14. TRANSPORT INFORMATION
ADR /RID
UN no: No special packaging or labelling requirements
Packing group: No special packaging or labelling requirements
Shipping name: No special packaging or labelling requirements
BIO-INDUSTRIES LTD©2010
CLEANING THE ENVIRONMENT NATURALLY
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SAFETY DATA SHEET
BIOACTIVATOR
Page 4 of 5
Issued: 01/11/2010
Revision No. 1
Labelling: No special packaging or labelling requirements
ADR Class: No special packaging or labelling requirements
Classification code: No special packaging or labelling requirements
Hazard ID no: No special packaging or labelling requirements
IMDG / IMO
UN no: No special packaging or labelling requirements
Packing group: No special packaging or labelling requirements
Labelling: No special packaging or labelling requirements
Class: No special packaging or labelling requirements
EmS: No special packaging or labelling requirements
Labelling: No special packaging or labelling requirements
IATA / ICAO
UN no: No special packaging or labelling requirements
Packing group: No special packaging or labelling requirements
Labelling: No special packaging or labelling requirements
Class: No special packaging or labelling requirements
Packing instructions: No special packaging or labelling requirements
15. REGULATORY INFORMATION
Hazards symbols:.
Risk phrases:
R36 – Irritating to eyes.
R38 – Irritating to skin
Safety phrases:
S24 – Avoid contact with skin.
S26 – In case of contact with eyes, rinse immediately with plenty of water and
seek medical
S37/39 – Wear suitable gloves and eye/face protection
Note: Ozone depleting chemicals: No ozone depleting chemicals are present or used in manufacture.
EINECS: All ingredients listed or exempt
TSCA: All ingredients listed or exempt
MITI: Not determined
DSL: All ingredients listed or exempt
AICS: All ingredients listed or exempt
(1) According to 93/18/EEC as adapted for the 3rd time to technical progress commission directive
88/379/EEC.
16. OTHER INFORMATION
Other information: This product safety data sheet was prepared in compliance with European
directive 91/155 as amended by Directive 2001/58 and on the approximation of laws, regulations and
administrative provisions relative to the classification, packaging and labelling of dangerous
substances and preparations.
BIO-INDUSTRIES LTD©2010
CLEANING THE ENVIRONMENT NATURALLY
Email: [email protected] Web: www.bio.ie
SAFETY DATA SHEET
BIOACTIVATOR
Page 5 of 5
Issued: 01/11/2010
Revision No. 1
It is the responsibility of persons in receipt of the product safety data sheet to ensure that the
information contained herein is properly read and understood by all people who may use, handle, and
dispose of or in any way come in contact with the product. If the recipient subsequently produces a
formulation containing the product it is the recipient’s sole responsibility to ensure the transfer of all
relevant information from Product safety data sheet to their own Product safety data sheet in
compliance European directive 91/155 as amended by Directive 2001/58
All information and instruction provide in this safety data sheet (SDS) are based on the current state
scientific and technical knowledge at the date indicated on the present SDS. Bio-Industries shall not
be held responsible for any defect
in the product covered by this SDS should the existence of such defect not be detectable considering
the current state of scientific and technical knowledge
Legal disclaimer: N/A
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
Material Name:
REACH Registration No.:
Synonyms:
Diesel (CAS 68334-30-5)
01-2119484664-27-0159
Fuel oil light, E10, E32, EN590 diesel, EN590 ULSD, ULSD 10, E10F,
E32F, Diesel AGO, Gasoil IGO, Diesel D-10/D-32, Marine gas oil,
Fuel oil environmental
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product Use:
Heating, marine fuels, fuel.
Distribution of substance, industrial
Formulation & (re) packing of the substances and mixtures,
industrial
Use as a fuel, industrial
Use as a fuel, professional
Uses Advised Against:
Applications that are not registered and risk assessed.
1.3 Details of the supplier of the substance or mixture
Manufacturer/Supplier:
St1 Refinery AB
Box 8889
402 72 Gothenburg, Sweden
Telephone:
+46 (0) 31 744 6000
Email Contact for MSDS:
[email protected] or [email protected]
1.4 Emergency Telephone
Number:
112 SOS Alarm, Swedish Poisons Information Centre: +46 (0)8
331231
+46 (0)31 744 6253
2. HAZARDS IDENTIFICATION
2.1 Classification of substance or mixture
Product definition
:
Substance
1
Diesel (CAS 68334-30-5)
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Regulation 1907/2006/EG
Safety Data Sheet
Regulation (EC) No 1272/2008 (CLP)
Hazard classes / Hazard categories
Flammable liquids, Category 3
Aspiration hazard, Category 1
Skin corrosion/irritation, Category 2
Acute toxicity, Category 4; Inhalation
Carcinogenicity, Category 2
Specific target organ toxicity - repeated exposure,
Category 2; Blood.; Liver.; Thymus.
Chronic hazards to the aquatic environment,
Category 2
Hazard Statement
H226
H304
H315
H332
H351
H373
H411
67/548/EEC or 1999/45/EC
Hazard Characteristics
Harmful. Irritant. Dangerous for the environment.
Hazard Statement
R20; R38; R40; R51/53; R65
Classification triggering components:
Contains petroleum distillates.
2.2 Label Elements
Labeling according to Regulation (EC) No 1272/2008
Symbol(s):
Signal Words:
Danger
CLP Hazard Statements:
PHYSICAL HAZARDS:
H226: Flammable liquid and vapor.
HEALTH HAZARDS:
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H332: Harmful if inhaled.
H351: Suspected of causing cancer.
H373: May cause damage to organs through prolonged or
repeated exposure.
ENVIRONMENTAL HAZARDS:
H411: Toxic to aquatic life with long lasting effects.
2
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Safety Data Sheet
CLP Precautionary statements
Prevention:
P210: Keep away from heat/sparks/open flames/hot
surfaces. – No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapor/spray.
P280: Wear protective gloves/protective clothing/eye
protection/face protection.
Response:
P301+P310: IF SWALLOWED: Immediately call a POISON
CENTER or doctor/physician.
P331: Do NOT induce vomiting.
Disposal:
P501: Dispose of contents and container to appropriate
waste site or reclaimer in accordance with local and national
regulations.
2.3 Other Hazards
Safety Hazards:
May ignite on surfaces at temperatures above auto-ignition
temperature. Vapour in the headspace of tanks and containers may
ignite and explode at temperatures exceeding auto ignition
temperature, where vapour concentrations are within the
flammability range. Electrostatic charges may be generated during
pumping. Electrostatic discharge may cause fire.
Other information:
This product is intended for use in closed systems only.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substance
Cas nr.
68334-30-5
Preparation Description:
A complex combination of hydrocarbons produced by the distillation
of crude oil. It consists of hydrocarbons having carbon numbers
predominantly in the range of C9 through C25 and boiling in the
range of approximately 160 to 400oC.
Product is not a mixture according regulation 1907/2006/EC.
3
Diesel (CAS 68334-30-5)
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Safety Data Sheet
Hazardous Components
Classification of components according to Regulation (EC) No 1272/2008
Chemical Name
Fuels, diesel
CAS No.
68334-30-5
EINECS
REACH Registration No.
269-822-7 05-2114290161-57
Chemical Name
Fuels, diesel
Hazard Class & Category
Flam. Liq., 3; Asp. Tox., 1; Acute Tox., 4;
Skin Corr., 2; Carc., 2; STOT RE, 2;
Aquatic Chronic, 2
Conc. vol%
100
Hazard Statement
H226; H304; H315; H332;
H351; H373; H411
Classification of components according to 67/548/EEC
Chemical Name
CAS No.
EINECS
Fuels, diesel
68334-30-5
REACH
Registration
No.
269-822-7 05211429016157
Symbol(s)
R-phrase(s)
Conc.
vol %
Xn, Xi, N
R20, R38, R40,
R51/53, R65
100
3.2 Mixtures:
Not applicable.
Additional Information:
Colours and markers can be used to indicate tax status and prevent fraud.
4. FIRST AID MEASURES
4.1 Description of First Aid Measures
Inhalation:
Remove to fresh air. If rapid recovery does not occur, transport to
nearest medical facility for additional treatment.
Skin contact:
Remove contaminated clothing. Immediately flush skin with large
amounts of water for at least 15 minutes, and follow by washing
with soap and water if available. If redness, swelling, pain and/or
blisters occur, transport to the nearest medical facility for additional
treatment.
Eye contact:
Flush eye with copious quantities of water. If persistent irritation
occurs, obtain medical attention.
Ingestion:
If swallowed, do not induce vomiting: transport to nearest medical
facility for additional treatment. If vomiting occurs spontaneously,
keep head below hips to prevent aspiration. If any of the following
delayed signs and symptoms appear within the next 6 hours,
4
Diesel (CAS 68334-30-5)
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Safety Data Sheet
transport to the nearest medical facility: fever greater than 37 °C,
shortness of breath, chest congestion or continued coughing or
wheezing. Give nothing by mouth.
4.2 Most important
symptoms/effects,
acute & delayed:
If material enters lungs, signs and symptoms may include coughing,
choking, wheezing, difficulty in breathing, chest congestion,
shortness of breath, and/or fever. The onset of respiratory
symptoms may be delayed for several hours after exposure.
Defatting dermatitis signs and symptoms may include a burning
sensation and/or a dried/cracked appearance.
4.3 Indication of immediate
medical attention and special
treatment needed:
Treat symptomatically.
5. FIRE FIGHTING MEASURES
Clear fire area of all non-emergency personnel.
5.1 Extinguishing Media:
Foam, water spray or fog. Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
Unsuitable Extinguishing
Media:
Do not use water in a jet. Simultaneous use of foam and water on
the same surface is to be avoided as water destroys the foam.
5.2 Special hazards arising from
substance or mixture:
Hazardous combustion products may include: A complex mixture of
airborne solid and liquid particulates and gases (smoke). Carbon
monoxide. Oxides of sulphur. Unidentified organic and inorganic
compounds. Carbon monoxide may be evolved if incomplete
combustion occurs. Will float and can be reignited on surface water.
Flammable vapours may be present even at temperatures below
the flash point.
5.3 Advice for fire-fighters:
Wear full protective clothing and self-contained breathing
apparatus.
Additional Advice:
Keep adjacent containers cool by spraying with water.
6. ACCIDENTAL RELEASE MEASURES
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal.
Observe the relevant local and international regulations. Evacuate the area of all non-essential
personnel. Ventilate contaminated area thoroughly.
5
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Safety Data Sheet
6.1 Personal Precautions,
Protective Equipment and
Emergency Procedures:
Do not breathe fumes, vapour. Do not operate electrical
equipment.
6.2 Environmental
Precautions:
Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use
appropriate containment (of product and fire fighting water) to
avoid environmental contamination. Prevent from spreading or
entering drains, ditches or rivers by using sand, earth, or other
appropriate barriers. Attempt to disperse the vapour or to direct its
flow to a safe location for example by using fog sprays. Take
precautionary measures against static discharge. Ensure electrical
continuity by bonding and grounding (earthing) all equipment.
6.3 Methods and Material for
Containment
For small liquid spills, transfer by mechanical means to a
labelled, sealable container for product recovery or safe disposal.
Absorb with a suitable absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely. Place in a suitable
container with clearly marked container for disposal or recovery in
accordance with local regulations.
For large liquid spills, transfer by mechanical means such as vacuum
truck to a salvage tank for recovery or safe disposal. Do not flush
away residues with water. Absorb with a suitable absorbent
material and dispose of safely. Remove contaminated soil and
dispose of safely. Shovel into a suitable clearly marked container for
disposal or reclamation in accordance with local regulations.
Additional Advice:
Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities should be
advised if significant spillages cannot be contained. Maritime
spillages should be dealt with using a Shipboard Oil Pollution
Emergency Plan (SOPEP), as required by MARPOL Annex 1
Regulation 26.
7. HANDLING AND STORAGE
General Precautions:
Avoid breathing vapours or contact with material. Only use in well
ventilated areas. Wash thoroughly after handling. For guidance on
selection of personal protective equipment see Chapter 8 of this
Material Safety Data Sheet. Use the information in this data sheet
as input to a risk assessment of local circumstances to help
determine appropriate controls for safe handling, storage and
disposal of this material. Air-dry contaminated clothing in a wellventilated area before laundering. Contaminated leather articles
including shoes cannot be decontaminated and should be
6
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Safety Data Sheet
destroyed to prevent reuse. Properly dispose of any contaminated
rags or cleaning materials in order to prevent fires. Use local
exhaust ventilation if there is risk of inhalation of vapours, mists or
aerosols. Prevent spillages. For comprehensive advice on handling,
product transfer, storage and tank cleaning refer to the product
supplier.
7.1 Precautions for Safe
Handling:
Avoid inhaling vapour and/or mists. Electrostatic charges may be
generated during pumping. Electrostatic discharge may cause fire.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks. Earth all equipment. Avoid prolonged or
repeated contact with skin. When using do not eat or drink. The
vapour is heavier than air, spreads along the ground and distant
ignition is possible.
7.2 Conditions for safe storage,
including any incompatibilities:
Tank storage: Tanks must be specifically designed for use with this
product. Bulk storage tanks should be diked (bunded). Locate tanks
away from heat and other sources of ignition. Must be stored in a
diked (bunded) well-ventilated area, away from sunlight, ignition
sources and other sources of heat. The vapour is heavier than air.
Beware of accumulation in pits and confined spaces.
Keep in a bunded area with a sealed (low permeability) floor, to
provide containment against spillage. Prevent ingress of water.
7.3 Specific End Uses:
Please refer to Ch16 and/or the annexes for the registered uses
under REACH.
Additional Information:
Exposure to this product should be reduced as low as reasonably
practicable. Ensure that all local regulations regarding handling and
storage facilities are followed.
Product Transfer:
Avoid splash filling. Wait 2 minutes after tank filling (for tanks such
as those on road tanker vehicles) before opening hatches or
manholes. Wait 30 minutes after tank filling (for large storage
tanks) before opening hatches or manholes. Keep containers closed
when not in use. Do not use compressed air for filling, discharging
or handling. Contamination resulting from product transfer may
give rise to light hydrocarbon vapour in the headspace of tanks that
have previously contained gasoline. This vapour may explode if
there is a source of ignition. Partly filled containers present a
greater hazard than those that are full, therefore handling, transfer
and sampling activities need special care.
Recommended Materials:
For containers, or container linings use mild steel, stainless steel.
7
Diesel (CAS 68334-30-5)
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Unsuitable Materials
:
Some synthetic materials may be unsuitable for containers or
container linings depending on the material specification and
intended use Compatibility should be checked with the
manufacturer.
Container Advice:
Containers, even those that have been emptied, can contain
explosive vapours. Do not cut, drill, grind, weld or perform similar
operations on or near containers.
Other Information:
Ensure that all local regulations regarding handling and storage are
followed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Read in conjunction with the Exposure Scenario for your specific use contained in the Annex.
8.1 Control Parameters
Occupational Exposure Limits
Not established
Biological Exposure Index (BEI)
No biological limit allocated.
Derived No Effect Levels (DNEL)
Component
Exposure Route
Fuels, diesel
Exposure Type
Long/short
Acute, systemic effects
Application
Area
Worker
Long term, systemic
effects
Long term, systemic
effects
Worker
Inhalation
Acute, systemic effects
Consumer
Dermal
Long term, systemic
effects
Long term, systemic
effects
Consumer
Inhalation
Dermal
Inhalation
Inhalation
PNEC (Predicted No-Effect
Concentration) related
information:
Worker
Consumer
Value
4300 mg/m3/
15 min (aerosol)
2,9 mg/kg 8 h
68 mg/m3/8 h
(aerosol)
2600 mg/m3/15 min
(aerosol)
1,3 mg/kg 24 h
20 mg/m3/24 h
(aerosol)
Substance is a hydrocarbon with a complex, unknown or variable
composition. Conventional methods of deriving PNECs are not
appropriate and it is not possible to identify a single
representative PNEC for such substances.
8
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8.2 Exposure Controls
General Information:
The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances. Appropriate
measures include: Use sealed systems as far as possible. Adequate
ventilation to control airborne concentrations below the exposure
guidelines/limits. Local exhaust ventilation is recommended. Eye
washes and showers for emergency use.
Occupational Exposure Controls
Personal Protective
Equipment:
Personal protective equipment (PPE) should meet recommended
national standards. Check with PPE suppliers.
Eye Protection:
Chemical splash goggles (chemical monogoggles). Approved to EU
Standard EN166.
Hand Protection:
Personal hygiene is a key element of effective hand care. Gloves
must only be worn on clean hands. After using gloves, hands should
be washed and dried thoroughly. Application of a non-perfumed
moisturizer is recommended. Suitability and durability of a glove is
dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, and
dexterity. Always seek advice from glove suppliers. Contaminated
gloves should be replaced.
Select gloves tested to a relevant standard (e.g. Europe EN374 for
chemical resistance and EN407 for heat resistance). For prolonged
or repeated contact, use nitrile gloves. (Breakthrough time of > 240
minutes.) For incidental contact/splash, use Neoprene/PVC gloves.
Body protection:
Chemical resistant gloves/gauntlets, boots, and apron (where risk of
splashing).
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a
level which is adequate to protect worker health, select respiratory
protection equipment suitable for the specific conditions of use and
meeting relevant legislation. Check with respiratory protective
equipment suppliers. Where air-filtering respirators are unsuitable
(e.g. airborne concentrations are high, risk of oxygen deficiency,
confined space) use appropriate positive pressure breathing
apparatus. All respiratory protection equipment and use must be in
accordance with local regulations. Select a filter suitable for organic
gases and vapours [boiling point >65 °C] meeting EN14387.
Monitoring Methods:
Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be
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appropriate.
Environmental Exposure Controls
Environmental exposure
control measures:
Local guidelines on emission limits for volatile substances must be
observed for the discharge of exhaust air containing vapour.
Consumer Exposure Controls
Exposure Control
Measures for Consumers:
If repeated and/or prolonged skin exposure to the substance is
likely, then wear suitable gloves tested to EN374 and provide
employee skin care programmes. Do not ingest. If swallowed then
seek immediate medical assistance.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
According to Swedish Standard SS EN 590:2009 and SS 15 54 10:2011.
Appearance
Odour
Initial Boiling Point and Boiling
Range
Flash point
Vapour pressure
Explosions limits
Density, 15oC
Kinematic viscosity, 40oC
Auto-ignition temperature
Clear liquid, colourless, yellow or green
Characteristic
160 – 370oC
> 56oC
<0,5 kPa
0,6 - 7,5 % (V)
820 - 845 kg/m3
1,5 - 4,5 mm2/s
>225oC
9.2 Other Information
Other Information
:
Not applicable.
10. STABILITY AND REACTIVITY
10.1 Reactivity:
The product is not considered to be reactive.
10.2 Chemical Stability:
Stable under normal conditions of use.
10.3 Possibility of Hazardous
Reactions:
Under normal conditions of storage and use, there are no
dangerous reactions.
10.4 Conditions to Avoid:
Avoid heat, sparks, open flames and other ignition sources.
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10.5 Incompatible Materials:
Strong oxidising agents.
10.6 Hazardous Decomposition
Product:
Hazardous decomposition products are not expected to form during
normal storage. Thermal decomposition is highly dependent on
conditions. A complex mixture of airborne solids, liquids and gases,
including carbon monoxide, carbon dioxide and other organic
compounds will be evolved when this material undergoes
combustion or thermal or oxidative degradation.
11. TOXIKOLOGISK INFORMATION
11.1 Information on Toxicological effects
Basis for Assessment:
Information given is based on product data, a knowledge of the
components and the toxicology of similar products.
Acute Oral Toxicity:
Acute Dermal Toxicity:
Acute Inhalation Toxicity:
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory Irritation:
Low toxicity: LD50 >5000 mg/kg, Rat.
Low toxicity: LD50 >2000 mg/kg, Rabbit.
Harmful by inhalation: LC50> 1.0 - ≤ 5.0 mg/l/4 h, Rat.
Irritating to skin.
Expected to be slightly irritating.
Inhalation of vapours or mists may cause irritation to the
respiratory system.
Not a skin sensitizer.
Respiratory or Skin
Sensitisation:
Aspiration Hazard:
Germ Cell Mutagenicity:
Carcinogenicity:
Reproductive and
Developmental Toxicity:
Specific target organ toxicity single exposure:
Specific target organ toxicity repeated exposure:
Aspiration into the lungs when swallowed or vomited may cause
chemical pneumonitis which can be fatal.
Positive in in-vitro, but negative in in-vivo mutagenicity assays.
Limited evidence of carcinogenic effect. Repeated skin contact has
resulted in irritation and skin cancer in animals.
Not expected to impair fertility. Not classified as a developmental
toxicant.
Not classified.
May cause damage to organs through prolonged or repeated
exposure. Blood. Thymus. Liver.
12. ECOLOGICAL INFORMATION
Basis for Assessment:
12.1 Acute Toxicity
Acute Toxicity
Information given is based on knowledge of the components and
the ecotoxicology of similar products.
Expected to be toxic: LL/EL/IL50 1-10 mg/l (LL/EL50 expressed as
the nominal amount of product required to prepare aqueous test
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Fish
Aquatic Invertebrates
Algae
Microorganisms
Chronic Toxicity
Fish
Aquatic Invertebrates
12.2 Persistence and
degradability:
12.3 Bioaccumulative
Potential:
12.4 Mobility:
12.5 Results of PBT and vPvB
assessment:
12.6 Other adverse effects:
extract).
Expected to be toxic: LL/EL/IL50 1-10 mg/l
Expected to be toxic: LL/EL/IL50 1-10 mg/l
Expected to be toxic: LL/EL/IL50 1-10 mg/l
Expected to be practically non-toxic: LL/EL/IL50 > 100 mg/l
NOEC = No Observable Effect Concentration
NOEL = No Observable Effect Level
NOEC/NOEL expected to be > 0.01 - <= 0.1 mg/l (based on modelled
data)
NOEC/NOEL expected to be > 0.1 - <= 1.0 mg/l (based on modelled
data)
Readily biodegradable in water.
Contains constituents with the potential to bioaccumulate.
Partly evaporates from water or soil surfaces, but a significant
proportion will remain after one day. If product enters soil, one or
more constituents will be mobile and may contaminate
groundwater. Floats on water. Large volumes may penetrate soil
and could contaminate groundwater.
The substance does not fulfill all screening criteria for persistence,
bioaccumulation and toxicity and hence is not considered to be PBT
or vPvB. PBT =Persistent, Bioaccumulative, Toxic.
vPvB = very Persistent, very Bioaccumulative.
Films formed on water may affect oxygen transfer and damage
organisms.
13. DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Material Disposal:
Recover or recycle if possible. It is the responsibility of the waste
generator to determine the toxicity and physical properties of the
material generated to determine the proper waste classification
and disposal methods in compliance with applicable regulations. Do
not dispose into the environment, in drains or in water courses. Do
not dispose of tank water bottoms by allowing them to drain into
the ground. This will result in soil and groundwater contamination.
Waste arising from a spillage or tank cleaning should be disposed of
in accordance with prevailing regulations, preferably to a
recognised collector or contractor. The competence of the collector
or contractor should be established beforehand.
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Container Disposal:
Send to drum recoverer or metal reclaimer. Drain container
thoroughly. After draining, vent in a safe place away from sparks
and fire. Residues may cause an explosion hazard if heated above
the flash point. Do not puncture, cut or weld uncleaned drums. Do
not pollute the soil, water or environment with the waste container.
Comply with any local recovery or waste disposal regulations.
Local Legislation:
EU Waste Disposal Code (EWC):
13 07 01 Fuel oil and diesel
13 07 03 Other fuels (including mixtures)
The number given to waste is associated with the appropriate
usage. The user must decide if their particular use results in another
waste code being assigned. Disposal should be in accordance with
applicable regional, national, and local laws and regulations. Local
regulations may be more stringent than regional or national
requirements and must be complied with.
14. TRANSPORT INFORMATION
ADR/RID
UN No:
UN Proper Shipping Name:
Transport Hazard Class:
Packing group:
Environmental Hazard:
Land transport
1202
GAS OIL, DIESEL FUEL, FUEL OIL LIGHT
3
III
Yes
ADN
UN No:
UN Proper Shipping Name:
Transport Hazard Class:
Packing group:
Environmental Hazard:
Inland waterways transport
1202
GAS OIL, DIESEL FUEL, FUEL OIL LIGHT
3
III
Yes
IMDG
UN No:
UN Proper Shipping Name:
Transport Hazard Class:
Packing group:
Environmental Hazard:
Sea transport
1202
GAS OIL, DIESEL FUEL, FUEL OIL LIGHT
3
III
Yes
IATA
UN No:
UN Proper Shipping Name:
Transport Hazard Class:
Packing group:
Air transport
1202
GAS OIL, DIESEL FUEL, FUEL OIL LIGHT
3
III
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Environmental Hazard:
Yes
15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
15.1 Safety, health and
environmental
regulations/legislation specific
for the substance or mixture
EU Regulation (EC) No 1907/2006 (REACH).
KIFS 2005:7 Classification and labelling of chemical products.
EU Regulation (EC) No 1272/2008 Classification, labelling and
packaging of chemical substances and mixtures (CLP).
15.2 Chemical Safety
Assessment
A Chemical Safety Assessment was performed for this substance.
16. OTHER INFORMATION
R-phrase(s):
R20 Harmful by inhalation
R38 Irritating to skin.
R40 Limited evidence of carcinogen effect.
R51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
CLP Hazard Statements
H226: Flammable liquid and vapor.
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H332: Harmful if inhaled.
H351: Suspected of causing cancer.
H373: May cause damage to organs through prolonged or repeated
exposure.
H411: Toxic to aquatic life with long lasting effects.
Recommended Restrictions on
Use (Advice Against):
This product must not be used in applications other than those
recommended in Section 1, without first seeking the advice of the
supplier. This product is not to be used as a solvent or cleaning
agent; for lighting or brightening fires; as a skin cleanser.
Additional Information:
This document contains important information to ensure the safe
storage, handling and use of this product. The information in this
document should be brought to the attention of the person in your
organisation responsible for advising on safety matters.
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Further Information
This product is intended for use in closed systems only.
MSDS Distribution:
The information in this document should be made available to all
who may handle the product.
MSDS Version Number:
1
MSDS Effective Date:
2014-01-07
Disclaimer:
This information is based on our current knowledge and is intended
to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.
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Table of Contents exposure scenarios
Identified Uses according to the Use Descriptor System
Uses – Worker
Title
Uses – Worker
Title
Uses – Worker
Title
Uses – Worker
Title
Uses – Worker
Title
Uses – Worker
Title
Use – Consumer
Title
1. Manufacture of substance
- Industrial
2. Use as an intermediate
- Industrial
3. Distribution of substance
- Industrial
4. Formulation & (re)packing of substances and mixtures
- Industrial
5. Use as a fuel
- Industrial
6. Use as a fuel
- Professional
7. Use as a fuel
- Consumer
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Abbreviation:
SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites
SU8 - Manufacture of bulk, large scale chemicals (including petroleum products)
SU9 - Manufacture of fine chemicals
SU 10 - Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
SU21 - Consumer uses: Private households (= general public = consumers)
SU22 - Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
PC21 - Laboratory chemicals
PROC1 - Use in closed process, no likelihood of exposure
PROC2 - Use in closed, continuous process with occasional controlled exposure
PROC3 - Use in closed batch process (synthesis or formulation)
PROC4 - Use in batch and other process (synthesis) where opportunity for exposure arises
PROC5 - Mixing or blending in batch processes for formulation of preparations and articles (multistage
and/or significant contact)
PROC8a - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at
non-dedicated facilities
PROC8b - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at
dedicated facilities
PROC9 - Transfer of substance or preparation into small containers (dedicated filling line, including
weighing)
PROC14 - Production of preparations or articles by tableting, compression, extrusion, pelletisation
PROC15 - Use as laboratory reagent
PROC16 - Using material as fuel sources, limited exposure to unburned product to be expected
ERC1 - Manufacture of substances
ERC2 - Formulation of preparations
ERC3 - Formulation in materials
ERC4 - Industrial use of processing aids in processes and products, not becoming part of articles
ERC5 - Industrial use resulting in inclusion into or onto a matrix
ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b - Industrial use of reactive processing aids
ERC6c - Industrial use of monomers for manufacture of thermo-plastics
ERC6d - Industrial use of process regulators for polymerisation processes in production of resins,
rubbers, polymers
ERC7 - Industrial use of sub-stances in closed systems
ERC9a - Wide dispersive indoor use of substances in closed systems
ERC9b - Wide dispersive outdoor use of substances in closed systems
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Exposure Scenario – Worker
SECTION 1
EXPOSURE SCENARIO TITLE
Title
1. Manufacture of substance
- Industrial
Use Descriptor
Sector of Use: SU 3, SU8, SU9
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4, PROC 8a,
PROC 8b, PROC 15
Environmental Release Categories: ERC1, ERC4, ESVOC SpERC 1.1.v1
Scope of process
Manufacture of the substance or use as a process chemical or
extraction agent. Includes recycling/ recovery, material transfers,
storage, maintenance and loading (including marine vessel/barge,
road/rail car and bulk container), sampling and associated laboratory
activities.
SECTION 2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES
Section 2.1
Control of Worker Exposure
Product Characteristics
Liquid, vapour pressure < 0.5 kPa at STP
Physical form of product
Concentration of substance in
Covers percentage substance in the product up to 100% (unless
product.
stated differently).
Frequency and Duration of Use
Covers daily exposures up to 8 hours (unless stated differently).
Other Operational Conditions affecting Exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature).
Assumes a good basic standard of occupational hygiene has been implemented.
Contributing Scenarios
General measures applicable to
all activities.
Risk Management Measures
Control any potential exposure using measures such as contained
systems, properly designed and maintained facilities and a good
standard of general ventilation. Drain down systems and transfer
lines prior to breaking containment. Drain down and flush equipment
where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are
informed of exposure potential and aware of basic actions to
minimise exposures; ensure suitable personal protective equipment
is available; clear up spills and dispose of waste in accordance with
regulatory requirements; monitor effectiveness of control measures;
provide regular health surveillance as appropriate; identify and
implement corrective actions.
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General measures (skin
irritants)
General exposures (closed
systems)
General exposures (open
systems)
Process sampling
Bulk closed loading and
unloading
Bulk open loading and
unloading
Equipment cleaning and
maintenance
Laboratory activities
Bulk product storage
Avoid direct skin contact with product. Identify potential areas
for indirect skin contact. Wear gloves tested to EN374 (nitrile gloves
have the best protection for diesel), if hand contact with substance
likely. Clean up contamination/spills as soon as they occur. Wash off
any skin contamination immediately. Provide basic employee training
to prevent / minimise exposures and to report any skin problems that
may develop.
No other specific measures identified.
Wear suitable gloves tested to EN374 (nitrile).
No other specific measures identified.
Wear suitable gloves tested to EN374 (nitrile).
Wear suitable gloves tested to EN374 (nitrile).
Drain down system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (nitrile) in combination with ‘basic’
employee training.
No other specific measures identified.
Store substance within a closed system.
Section 2.2
Control of Environmental Exposure
Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region:
0.1
Regional use tonnage (tonnes/year):
2.8E+07
Fraction of Regional tonnage used locally:
0.021
Annual site tonnage (tonnes/year):
6.0E+05
Maximum daily site tonnage (kg/day):
2.0E+06
Frequency and Duration of Use
Continuous release.
Emission Days (days/year):
300
Environmental factors not influenced by risk management
Local freshwater dilution factor:
10
Local marine water dilution factor:
100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM):
1.0E+02
Release fraction to wastewater from process (initial release prior to 3.0E-05
RMM):
Release fraction to soil from process (initial release prior to RMM):
1.0E-04
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
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Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to
soil
Risk from environmental exposure is driven by freshwater sediment.
Prevent discharge of undissolved substance to or recover from onsite wastewater.
Treat air emission to provide a typical removal efficiency of (%)
90
Treat onsite wastewater (prior to receiving water discharge) to
90.3
provide the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, provide the
0
required onsite wastewater removal efficiency of (%)
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Estimated substance removal from wastewater via domestic sewage 94.1
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 94.1
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release
3.3E+06
following total wastewater treatment removal (kg/d):
Assumed domestic sewage treatment plant flow (m3/d)
10000
Conditions and measures related to external treatment of waste for disposal
During manufacturing no waste of the substance is generated.
Conditions and measures related to external recovery of waste
During manufacturing no waste of the substance is generated.
SECTION 3
EXPOSURE ESTIMATION
Section 3.1 - Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
Section 3.2 - Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model.
SECTION 4
GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO
Section 4.1 - Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk Management Measures are based on qualitative risk characterisation.
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Section 4.2 -Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either
alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
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Exposure Scenario – Worker
SECTION 1
Title
EXPOSURE SCENARIO TITLE
2. Use as an intermediate
- Industrial
Use Descriptor
Sector of Use: SU3, SU8, SU9
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC8a,
PROC8b, PROC15
Environmental Release Categories: ERC6A, ESVOC SpERC 6.1a.v1
Scope of process
Use of substance as an intermediate within closed or contained
systems (not related to Strictly Controlled Conditions). Includes
incidental exposures during recycling/ recovery, material transfers,
storage, sampling, associated laboratory activities, maintenance and
loading (including marine vessel/barge, road/rail car and bulk
container).
SECTION 2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES
Section 2.1
Control of Worker Exposure
Product Characteristics
Physical form of product
Liquid, vapour pressure > 0,5 kPa at STP
Concentration of substance in
Covers percentage substance in the product up to 100% (unless
product.
stated differently).
Frequency and Duration of Use
Covers daily exposures up to 8 hours (unless stated differently).
Other Operational Conditions affecting Exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature).
Assumes a good basic standard of occupational hygiene has been implemented.
Contributing Scenarios
General measures applicable to
all activities
Risk Management Measures
Control any potential exposure using measures such as contained
systems, properly designed and maintained facilities and a good
standard of general ventilation. Drain down systems and transfer
lines prior to breaking containment. Drain down and flush equipment
where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are
informed of exposure potential and aware of basic actions to
minimise exposures; ensure suitable personal protective equipment
is available; clear up spills and dispose of waste in accordance with
regulatory requirements; monitor effectiveness of control measures;
provide regular health surveillance as appropriate; identify and
implement corrective actions.
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General measures (skin
irritants)
General exposures (closed
systems)
General exposures (open
systems)
Process sampling
Bulk closed loading and
unloading
Bulk open loading and
unloading
Equipment cleaning and
maintenance
Laboratory activities
Bulk product storage
Avoid direct skin contact with product. Identify potential areas
for indirect skin contact. Wear gloves tested to EN374 (nitrile gloves
have the best protection for diesel), if hand contact with substance
likely. Clean up contamination/spills as soon as they occur. Wash off
any skin contamination immediately. Provide basic employee training
to prevent / minimise exposures and to report any skin problems that
may develop.
No other specific measures identified.
Wear suitable gloves tested to EN374 (nitrile).
No other specific measures identified.
Wear suitable gloves tested to EN374 (nitrile).
Wear suitable gloves tested to EN374 (nitrile).
Drain down system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (nitrile) in combination with ‘basic’
employee training.
No other specific measures identified.
Store substance within a closed system.
Section 2.2
Control of Environmental Exposure
Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region:
0.1
Regional use tonnage (tonnes/year):
3.5E+05
Fraction of Regional tonnage used locally:
0.043
Annual site tonnage (tonnes/year):
1.5E+04
Maximum daily site tonnage (kg/day):
5.0E+04
Frequency and Duration of Use
Continuous release.
Emission Days (days/year):
300
Environmental factors not influenced by risk management
Local freshwater dilution factor:
10
Local marine water dilution factor:
100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM):
1.0E-03
Release fraction to wastewater from process (initial release prior to
3.0E-05
RMM):
Release fraction to soil from process (initial release prior to RMM):
1.0E-03
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
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Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to
soil
Risk from environmental exposure is driven by freshwater sediment.
Prevent discharge of undissolved substance to or recover from onsite wastewater.
If discharging to domestic sewage treatment plant, no secondary wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%)
80
Treat onsite wastewater (prior to receiving water discharge) to
51.7
provide the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, provide the
0
required onsite wastewater removal efficiency of (%)
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Estimated substance removal from wastewater via domestic sewage
94.1
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite
94.1
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 4.1E+05
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d)
2000
Conditions and measures related to external treatment of waste for disposal
This substance is consumed during use and no waste of substance is generated.
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of substance is generated.
SECTION 3
EXPOSURE ESTIMATION
Section 3.1 - Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
Section 3.2 - Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model.
SECTION 4
GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO
Section 4.1 - Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk Management Measures are based on qualitative risk characterisation.
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Section 4.2 -Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either
alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
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Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Exposure Scenario – Worker
SECTION 1
Title
EXPOSURE SCENARIO TITLE
3. Distribution of substance
- Industrial
Use Descriptor
Sector of Use: SU3
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b,
PROC9, PROC15
Environmental Release Categories: ERC1, ERC2, ERC3, ERC4, ERC5,
ERC6A, ERC6B, ERC6C, ERC6D, ERC7, ESVOC SpERC 1.1b.v1
Scope of process
Loading (including marine vessel/barge, rail/road car and IBC loading)
and repacking (including drums and small packs) of substance,
including its sampling, storage, unloading distribution and associated
laboratory activities.
SECTION 2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT
MEASURES
Section 2.1
Control of Worker Exposure
Product Characteristics
Physical form of product
Liquid, vapour pressure > 0.5 kPa at STP
Concentration of substance in Covers percentage substance in the product up to 100% (unless stated
product.
differently).
Frequency and Duration of Use
Covers daily exposures up to 8 hours (unless stated differently).
Other Operational Conditions affecting Exposure
Assumes use at not more than 20°C above ambient temperature (unless stated differently).
Assumes a good basic standard of occupational hygiene has been implemented.
Contributing Scenarios
General measures applicable to
all activities
Risk Management Measures
Control any potential exposure using measures such as contained
systems, properly designed and maintained facilities and a good
standard of general ventilation. Drain down systems and transfer
lines prior to breaking containment. Drain down and flush equipment
where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are
informed of exposure potential and aware of basic actions to
minimise exposures; ensure suitable personal protective equipment
is available; clear up spills and dispose of waste in accordance with
regulatory requirements; monitor effectiveness of control measures;
provide regular health surveillance as appropriate; identify and
implement corrective actions.
26
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
General measures (skin
irritants)
General exposures (closed
systems)
General exposures (open
systems)
Process sampling.
Bulk closed loading and
unloading
Bulk open loading and
unloading
Drum and small package filling
Equipment cleaning and
maintenance
Laboratory activities
Storage
Avoid direct skin contact with product. Identify potential areas
for indirect skin contact. Wear gloves tested to EN374 (nitrile gloves
have the best protection for diesel) if hand contact with substance
likely. Clean up contamination/spills as soon as they occur. Wash off
any skin contamination immediately. Provide basic employee training
to prevent / minimise exposures and to report any skin problems that
may develop.
No other specific measures identified.
Wear suitable gloves tested to EN374 (nitrile).
No other specific measures identified.
Wear suitable gloves tested to EN374 (nitrile).
Wear suitable gloves tested to EN374 (nitrile).
Wear suitable gloves tested to EN374 (nitrile).
Drain down system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (nitrile) in combination with ‘basic’
employee training.
No other specific measures identified.
Store substance within a closed system.
Section 2.2
Control of Environmental Exposure
Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region:
0.1
Regional use tonnage (tonnes/year):
2.8E+07
Fraction of Regional tonnage used locally:
0.002
Annual site tonnage (tonnes/year):
5.6E+04
Maximum daily site tonnage (kg/day):
1.9E+05
Frequency and Duration of Use
Continuous release.
Emission Days (days/year):
300
Environmental factors not influenced by risk management
Local freshwater dilution factor:
10
Local marine water dilution factor:
100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM):
1.0E-03
Release fraction to wastewater from process (initial release prior to
1.0E-06
RMM):
Release fraction to soil from process (initial release prior to RMM):
1.0E-05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
27
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to
soil
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Prevent discharge of undissolved substance to or recover from onsite wastewater.
If discharging to domestic sewage treatment plant, no secondary wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%)
90
Treat onsite wastewater (prior to receiving water discharge) to provide 9.6
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, provide the
0
required onsite wastewater removal efficiency of (%)
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and Measures related to municipal sewage treatment plant
Estimated substance removal from wastewater via domestic sewage
94.1
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite
94.1
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following
2.9E+06
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d)
2000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or regional
regulations.
SECTION 3
EXPOSURE ESTIMATION
Section 3.1 - Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
Section 3.2 - Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model.
SECTION 4
GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO
Section 4.1 - Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk Management Measures are based on qualitative risk characterisation.
28
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Section 4.2 -Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either
alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
29
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Exposure Scenario – Worker
SECTION 1
Title
EXPOSURE SCENARIO TITLE
4. Formulation & (re)packing of substances and mixtures
- Industrial
Use Descriptor
Sector of Use: SU3, SU10
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a,
PROC8b, PROC9, PROC14, PROC15
Environmental Release Categories: ERC2, ESVOC SpERC 2.2.v1
Scope of process
Formulation, packing and re-packing of the substance and its mixtures
in batch or continuous operations, including storage, materials
transfers, mixing, tableting, compression, pelletisation, extrusion, large
and small scale packing, sampling, maintenance and associated
laboratory activities.
SECTION 2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES
Section 2.1
Control of Worker Exposure
Product Characteristics
Physical form of product
Liquid, vapour pressure > 0.5 kPa at STP
Concentration of substance in Covers percentage substance in the product up to 100% (unless stated
product.
differently).
Frequency and Duration of Use
Covers daily exposures up to 8 hours (unless stated differently).
Other Operational Conditions affecting Exposure
Assumes use at not more than 20°C above ambient temperature (unless stated differently).
Assumes a good basic standard of occupational hygiene has been implemented.
Contributing Scenarios
General measures applicable to
all activities
Risk Management Measures
Control any potential exposure using measures such as contained
systems, properly designed and maintained facilities and a good
standard of general ventilation. Drain down systems and transfer
lines prior to breaking containment. Drain down and flush equipment
where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are
informed of exposure potential and aware of basic actions to
minimise exposures; ensure suitable personal protective equipment
is available; clear up spills and dispose of waste in accordance with
regulatory requirements; monitor effectiveness of control measures;
provide regular health surveillance as appropriate; identify and
implement corrective actions.
30
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
General measures (skin
irritants)
General exposures (closed
systems)
General exposures (open
systems)
Process sampling.
Drum/batch transfers
Bulk transfers
Mixing operations (open
systems)
Production or preparation or
articles by tableting,
compression, extrusion or
pelletisation
Equipment cleaning and
maintenance
Laboratory activities
Storage
Avoid direct skin contact with product. Identify potential areas for
indirect skin contact. Wear gloves tested to EN374 (nitrile gloves
have the best protection for diesel), if hand contact with substance
likely. Clean up contamination/spills as soon as they occur. Wash off
any skin contamination immediately. Provide basic employee training
to prevent / minimise exposures and to report any skin problems that
may develop.
No other specific measures identified.
Wear suitable gloves tested to EN374 (nitrile).
No other specific measures identified.
Use drum pumps or carefully pour from container. Wear suitable
gloves tested to EN374 (nitrile) in combination with ‘basic’ employee
training.
Handle substance within a closed system. Wear suitable gloves tested
to EN374 (nitrile).
Provide extract ventilation to points where emissions occur. Wear
chemically resistant gloves (nitrile) in combination with ‘basic’
employee training.
Wear suitable gloves tested to EN374 (nitrile).
Drain down system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (nitrile) in combination with ‘basic’
employee training.
No other specific measures identified.
Store substance within a closed system.
Section 2.2
Control of Environmental Exposure
Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region:
Regional use tonnage (tonnes/year):
Fraction of Regional tonnage used locally:
Annual site tonnage (tonnes/year):
Maximum daily site tonnage (kg/day):
Frequency and Duration of Use
Continuous release.
Emission Days (days/year):
Environmental factors not influenced by risk management
Local freshwater dilution factor:
Local marine water dilution factor:
31
0.1
2.8E+07
0.0011
3.0E+04
1.0E+05
300
10
100
Diesel (CAS 68334-30-5)
Version 1.0
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Regulation 1907/2006/EG
Safety Data Sheet
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (after typical onsite RMMs
1.0E-02
consistent with EU Solvent Emissions Directive requirements):
Release fraction to wastewater from process (initial release prior to
2.0E-05
RMM):
Release fraction to soil from process (initial release prior to RMM):
1.0E-04
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to
soil
Risk from environmental exposure is driven by freshwater sediment.
Prevent discharge of undissolved substance to or recover from onsite wastewater.
If discharging to domestic sewage treatment plant, no secondary wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%)
0
Treat onsite wastewater (prior to receiving water discharge) to provide 60.0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, provide the
0
required onsite wastewater removal efficiency of (%)
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and Measures related to municipal sewage treatment plant
Estimated substance removal from wastewater via domestic sewage
94.1
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite
94.1
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following
6.8E+05
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d)
2000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or regional
regulations.
SECTION 3
EXPOSURE ESTIMATION
Section 3.1 - Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
Section 3.2 - Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model.
32
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
SECTION 4
GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO
Section 4.1 - Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk Management Measures are based on qualitative risk characterisation.
Section 4.2 -Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either
alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
33
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Exposure Scenario – Worker
SECTION 1
Title
EXPOSURE SCENARIO TITLE
5. Use as a fuel
- Industrial
Use Descriptor
Sector of Use: SU3
Process Categories: PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC16
Environmental Release Categories: ERC7, ESVOC SpERC 7.12a.v1
Scope of process
Covers the use as a fuel (or fuel additive) and includes activities
associated with its transfer, use, equipment maintenance and handling
of waste.
SECTION 2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES
Section 2.1
Control of Worker Exposure
Product Characteristics
Physical form of product
Liquid, vapour pressure > 0.5 kPa at STP
Concentration of substance in Covers percentage substance in the product up to 100%
product.
(unless stated differently).
Frequency and Duration of Use
Covers daily exposures up to 8 hours (unless stated differently).
Other Operational Conditions affecting Exposure
Assumes use at not more than 20°C above ambient temperature (unless stated differently).
Assumes a good basic standard of occupational hygiene has been implemented.
Contributing Scenarios
General measures applicable
to all activities
Risk Management Measures
Control any potential exposure using measures such as contained
systems, properly designed and maintained facilities and a good
standard of general ventilation. Drain down systems and transfer lines
prior to breaking containment. Drain down and flush equipment where
possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are
informed of exposure potential and aware of basic actions to minimise
exposures; ensure suitable personal protective equipment is available;
clear up spills and dispose of waste in accordance with regulatory
requirements; monitor effectiveness of control measures; provide
regular health surveillance as appropriate; identify and implement
corrective actions.
General measures (skin
irritants)
Avoid direct skin contact with product. Identify potential areas
for indirect skin contact. Wear gloves tested to EN374 (nitrile gloves
have the best protection for diesel) if hand contact with substance
likely. Clean up contamination/spills as soon as they occur. Wash off
any skin contamination immediately. Provide basic employee training
34
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Drum/batch transfers
Bulk transfers
Use as a fuel (closed systems)
Equipment cleaning and
maintenance
Storage
to prevent / minimise exposures and to report any skin problems that
may develop.
Wear suitable gloves tested to EN374 (nitrile).
Wear suitable gloves tested to EN374 (nitrile).
No other specific measures identified.
Drain down system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (tested to EN374) in combination with
‘basic’ employee training.
Handle substance within a closed system.
Section 2.2
Control of Environmental Exposure
Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region:
Regional use tonnage (tonnes/year):
Fraction of Regional tonnage used locally:
Annual site tonnage (tonnes/year):
Maximum daily site tonnage (kg/day):
Frequency and Duration of Use
Continuous release.
Emission Days (days/year):
Environmental factors not influenced by risk management
Local freshwater dilution factor:
Local marine water dilution factor:
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (after typical onsite RMMs
0.1
4.5E+06
0.34
1.5E+06
5.0E+06
300
10
100
5.0E-04
consistent with EU Solvent Emissions Directive requirements):
Release fraction to wastewater from process (initial release prior to
1.0E-07
RMM):
Release fraction to soil from process (initial release prior to RMM):
0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to
soil
Risk from environmental exposure is driven by freshwater sediment.
Onsite waste water treatment required.
Treat air emission to provide a typical removal efficiency of (%)
95
Treat onsite wastewater (prior to receiving water discharge) to provide 97.7
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, provide the
60.4
required onsite wastewater removal efficiency of (%)
Prevent discharge of undissolved substance to or recover from onsite wastewater.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
35
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Sludge should be incinerated, contained or reclaimed.
Conditions and Measures related to municipal sewage treatment plant
Estimated substance removal from wastewater via domestic sewage
94.1
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite
97.7
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following
5.5E+06
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d)
2000
Conditions and Measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls.
Waste combustion emissions considered in regional exposure assessment.
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or regional
regulations.
SECTION 3
EXPOSURE ESTIMATION
Section 3.1 - Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
Section 3.2 - Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model.
SECTION 4
GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO
Section 4.1 - Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk Management Measures are based on qualitative risk characterisation.
Section 4.2 -Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either
alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
36
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Exposure Scenario – Worker
SECTION 1
Title
EXPOSURE SCENARIO TITLE
6. Use as a fuel
- Professional
Use Descriptor
Sector of Use: SU22
Process Categories: PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC16
Environmental Release Categories: ERC9A, ERC9B, ESVOC SpERC
9.12b.v1
Scope of process
Covers the use as a fuel (or fuel additive) and includes activities
associated with its transfer, use, equipment maintenance and handling
of waste.
SECTION 2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES
Section 2.1
Control of Worker Exposure
Product Characteristics
Physical form of product
Liquid, vapour pressure > 0.5 kPa at STP
Concentration of substance in Covers percentage substance in the product up to 100% (unless stated
product.
differently).
Frequency and Duration of Use
Covers daily exposures up to 8 hours (unless stated differently).
Other Operational Conditions affecting Exposure
Assumes use at not more than 20°C above ambient temperature (unless stated differently).
Assumes a good basic standard of occupational hygiene has been implemented.
Contributing Scenarios
General measures applicable
to all activities
Risk Management Measures
Control any potential exposure using measures such as contained
systems, properly designed and maintained facilities and a good
standard of general ventilation. Drain down systems and transfer lines
prior to breaking containment. Drain down and flush equipment where
possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are
informed of exposure potential and aware of basic actions to minimise
exposures; ensure suitable personal protective equipment is available;
clear up spills and dispose of waste in accordance with regulatory
requirements; monitor effectiveness of control measures; provide
regular health surveillance as appropriate; identify and implement
corrective actions.
37
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
General measures (skin
irritants)
Drum/batch transfers
Bulk transfers
Refuelling
Use as a fuel (closed systems)
Equipment cleaning and
maintenance
Storage
Avoid direct skin contact with product. Identify potential areas
for indirect skin contact. Wear gloves tested to EN374 (nitrile gloves
have the best protection for diesel) if hand contact with substance is
likely. Clean up contamination/spills as soon as they occur. Wash off
any skin contamination immediately. Provide basic employee training
to prevent / minimise exposures and to report any skin problems that
may develop.
Wear suitable gloves tested to EN374 (nitrile).
Wear suitable gloves tested to EN374 (nitrile).
Wear suitable gloves tested to EN374 (nitrile).
Provide a good standard of general ventilation (not less than 3 to 5 air
changes per hour), or ensure operation is undertaken outdoors.
Drain down system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (tested to EN374) in combination with
‘basic’ employee training.
Store substance within a closed system.
Section 2.2
Control of Environmental Exposure
Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region:
0.1
Regional use tonnage (tonnes/year):
6.7E+06
Fraction of Regional tonnage used locally:
5.0E-04
Annual site tonnage (tonnes/year):
3.3E+03
Maximum daily site tonnage (kg/day):
9.2E+03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year):
365
Environmental factors not influenced by risk management
Local freshwater dilution factor:
10
Local marine water dilution factor:
100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only):
1.0E-04
Release fraction to wastewater from wide dispersive use:
1.0E-05
Release fraction to soil from wide dispersive use (regional only):
1.0E-05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to
soil
Risk from environmental exposure is driven by freshwater sediment.
If discharging to domestic sewage treatment plant, no secondary wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%)
Treat onsite wastewater (prior to receiving water discharge) to provide 8.3
the required removal efficiency of >= (%)
38
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
If discharging to domestic sewage treatment plant, provide the
0
required onsite wastewater removal efficiency of (%)
Prevent discharge of undissolved substance to or recover from onsite wastewater.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and Measures related to municipal sewage treatment plant
Estimated substance removal from wastewater via domestic sewage
94.1
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite
94.1
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following
1.4E+05
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d)
2000
Conditions and Measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls.
Waste combustion emissions considered in regional exposure assessment.
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or regional
regulations.
SECTION 3
EXPOSURE ESTIMATION
Section 3.1 - Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
Section 3.2 - Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model.
SECTION 4
GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO
Section 4.1 - Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Risk Management Measures are based on qualitative risk characterisation.
39
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Section 4.2 -Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either
alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
40
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Exposure Scenario – Consumer
SECTION 1
Title
EXPOSURE SCENARIO TITLE
7. Use as a fuel
- Consumer
Use Descriptor
Sector of Use: SU21
Process Categories: PC13
Environmental Release Categories: ERC9A, ERC9B, ESVOC SpERC
9.12b.v1
Scope of process
Covers consumer uses in liquid fuels.
SECTION 2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES
Section 2.1
Product Characteristics
Physical form of product
Concentration of substance in
product.
Amounts Used
Unless otherwise stated:
Control of Consumer Exposure
Liquid, vapour pressure > 10 Pa
Unless otherwise stated: Covers concentrations up to 100 %
for each use event, covers amount up to (g):
covers skin contact area (cm2):
37 500
420
Frequency and duration of use
Unless otherwise stated:
covers use up to (times/day of use):
covers use up to (hours/events):
Product Categories
Fuels. Liquid: Automotive
Refuelling.
Fuels. Liquid Garden
Equipment - Use.
0.143
2
OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES
Covers concentration up to (%): 100 %
Covers use up to (days/year): 52 day/year
Covers use up to 1 times/day of use
Covers skin contact area 210 cm2
For each use event, covers amount up to 37,500 g.
Covers outdoor use.
Covers use in room size of 100 m3
Covers exposure up to 0.05 hours/event
Covers concentration up to (%): 100 %
Covers use up to 26 day/year
41
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
Fuels. Liquid: Garden
Equipment - Refuelling.
Covers use up to 1 times/day of use
For each use event, covers amount up to 750 g.
Covers outdoor use.
Covers use in room size of 100 m3
Covers exposure up to 2.00 hours/event
Covers concentrations up to 100 %
Covers use up to 26 day/year
Covers use up to 1 times/day of use
Covers skin contact area 420 cm2
For each use event, covers amount up to 750 g.
Covers use in a one car garage (34 m3) under typical ventilation.
Covers use in room size of 34 m3
Covers exposure up to 0.03 hours/event
Section 2.2
Control of Environmental Exposure
Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region:
0.1
Regional use tonnage (tonnes/year):
1.6E+07
Fraction of Regional tonnage used locally:
5.0E-04
Annual site tonnage (tonnes/year):
8.2E+03
Maximum daily site tonnage (kg/day):
2.3E+04
Frequency and Duration of Use
Continuous release.
Emission Days (days/year):
365
Environmental factors not influenced by risk management
Local freshwater dilution factor:
10
Local marine water dilution factor:
100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only):
1.0E-04
Release fraction to wastewater from wide dispersive use:
1.0E-05
Release fraction to soil from wide dispersive use (regional only):
1.0E-05
Conditions and Measures related to municipal sewage treatment plant
Estimated substance removal from wastewater via domestic sewage
94.1
treatment (%)
Maximum allowable site tonnage (MSafe) based on release following
3.5E+05
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d)
2000
Conditions and Measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls.
Waste combustion emissions considered in regional exposure assessment.
Conditions and measures related to external recovery of waste
42
Diesel (CAS 68334-30-5)
Version 1.0
Effective date 07.01.2014
Regulation 1907/2006/EG
Safety Data Sheet
External recovery and recycling of waste should comply with applicable local and/or regional
regulations.
SECTION 3
EXPOSURE ESTIMATION
Section 3.1 - Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
Section 3.2 - Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model.
SECTION 4
GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO
Section 4.1 - Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Section 4.2 -Environment
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
43
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