Table of contents Table of Contents Introduction 3 Research 5 Individual Projects 45 Education 151 Publications 173 1 Introduction Introduction by Professor Luuk Rietveld The year 2016 was again successful for the Sanitary Between April-June, 2016 we started the new elective Engineering section of the Faculty of Civil Engineering and course “Industry Water”, comprising internal industrial Geosciences. We managed to consolidate the activities water loops, process water recycling, production of that were started in 2015 and even expanded the scope ultra clean water, and efficient processing of industrial of our work. We managed to obtain new research funding, wastewater. The new educational course resulted from graduated a good number of PhD and MSc students, our increasing research in this field and was selected started a new educational track and extended our staff. by over 40 students who highly ranked this course in Within the partnership program TISCA on Technology their evaluation. As such, “Industry Water” is becoming Innovation for Sewer Condition Assessment, with RIONED, a recognised pillar in our research and educational STOWA, and the Knowledge Program Urban Drainage as curriculum. partners, we managed to get several projects funded. The greatest innovation in education was the start of This has led to an increased consolidation of Urban Water the new Master Track “Environmental Engineering” Infrastructure research in the section, being now even a within our faculty, in which we also cooperate with strategic field of interest for the entire Faculty. the group Environmental Biotechnology, led by prof. In addition, Merle de Kreuk managed to obtain a Mark van Loosdrecht. Environmental Engineering has prestigious VIDI grant from NWO on granular activated two specialisations, i.e. Environmental Science and sludge. This gives here the possibility to further extend Environmental Technology, and fills a clear gap at the here research group on this theme. To support the TU in which fundamentals of chemistry, microbiology, group, Ralph Lindeboom was appointed in a Tenure Track transport phenomena, hydrology, etc., are taught in an position. Ralph graduated at Wageningen University on interdisciplinary manner with the objective to predict e.g. Autogenerative High Pressure Digestion and worked climate changes and to create engineered interventions as a post-doc at Ghent University. In his tenure-track for preventing or restoring degrading environments. position he aims to integrate solar energy into biological Even without active promotion from TU side for this new wastewater treatment systems with the aim of locally master already 10 students subscribed to the first batch, recovering potable water, nutrients, chemicals and which started in September 2016. Recent evaluations energy carriers. were very positive and many potentials new students In total 7 PhD students of our group defended their thesis showed interest. With this new MSc track we managed in 2016. The topics varied from the monitoring of the to attract students with various backgrounds coming condition of sewer systems, to the improvement of slow from all over the world. It is clearly an enrichment of sand filtration in rural Colombia, digestion of sewage fine the offered specialisations in Hydrology, Water Resources sieve fraction for decentralised energy generation, and Engineering and Urban Water Engineering in the Water UV-based treatment for swimming pools. Management Track. Regarding education we are continuously improving our With all these achievements in 2016, we are confident in online lecturing material as well as our online access for a prosperous 2017! education. The trilogy MOOC “Water & Climate” was a We wish the same to all of you…! great success and the split MOOC “Drinking Water” and “Urban Sewage Treatment” was followed by thousands of students worldwide and the Drinking Water MOOC Professor Luuk Rietveld has even been translated into Arab. At present we are Head Water Management department developing online professional education (or ProfEd) Professor Urban Water Cycle courses, which will focus on specified themes, i.e. and Drinking Water Technology Membrane Technology in Water Treatment, Aerobic Granular Sludge Technology, and High-Rate Anaerobic Wastewater Treatment. All three courses will be launched in 2017. 3 4 Annual report 2016 Research 5 Research Mission statement Mission statement Section Sanitary Engineering From urban water chain to urban water cycle Sanitary engineering typically takes place within the More than 50% of humanity lives in urban areas, with urban water cycle, which in itself is part of the greater the largest growth in developing countries. Cities and hydrological cycle. Drinking water is obtained from water are closely linked to each other. A well-functioning groundwater or surface water. The water is treated and water network is essential for a city. Everybody has the subsequently transported to the users, i.e., households right to be supplied by clean and riskless drinking water, and industries, by means of an extensive distribution proper sanitary services, safe and reliable collection and network. Hereafter, the used waters, previously called treatment of the used urban waters, and protection wastewaters, are collected, often together with the of surface water and groundwater bodies. Fresh and drainage water, again via an extensive sewerage system. clean water, however, is scarce and for several cities the Subsequently, the collected sewage is conveyed to the limiting factors for economic growth. Smart technologies sewage treatment plant, where the water is relieved from combined with a robust infrastructure give the opportunity unwanted pollutants. After treatment, the purified water to use the scarce fresh water multiple times. In this way is discharged into open surface waters, after which it is a win-win situation is created where the population, again part of the natural hydrologic cycle. industries and (peri-)urban agriculture are less dependent on imported fresh water. Concomitantly, recovery of the Given the worldwide increasing water scarcity and/ urban water-linked resources such as nutrients but also or costs involved in importing fresh waters from large thermal and chemical energy will be addressed by the distances, a growing interest exists in making short- mentioned technologies. cuts in the urban water cycle, creating possibilities for multiple water use or even partly transforming the urban 6 Mission statement water chain into an urban water cycle. As such, water university and partners not only benefit from the scientific is more and more regarded as a valuable commodity, and professional publications and PhD dissertations, but whereas its polluting constituents are more and more also from patents, practical applications, and knowledge recognized Intervening transfer in open course ware lectures via internet. At technologies are being developed for upgrading water present, about 60 students carry out their PhD research qualities and concomitantly recovering contaminants as and yearly about 20 students finalise their MSc in Sanitary resources turning negatively valued urban streams into Engineering. as recoverable resources. positively valued assets. Traditional conveyance systems for sewage and urban drainage are critically evaluated Education and made fit for the modern urban water cycle approach, In addition to the research, education is the most anticipating on current societal demands and possible important activity of the section Sanitary Engineering. climate changes. Forecasted increase in flood events Apart from two introduction courses in the BSc, specialised will put additional demands on adequate urban drainage courses are given in the MSc-track Water Management. designs. Obviously, reliability, cost-effectiveness, and The philosophy of the section is that these courses must resource efficiency are keywords in present research in be, as much as possible, available for everyone. Therefore sanitary engineering and water treatment technologies. both on-campus and on-line education is provided. The In order to take all benefits from the used urban waters, on-campus education is focussed on the learning-by- profound knowledge is required on physical-chemical doing, involving students, where possible, with practical and biological treatment technologies needed to upgrade assignments (activated learning).In addition, students these waters to agreed standards for subsequent use or are stimulated to have an internship abroad, in order to discharge. broaden their horizon. On-line education is divided into three different categories: (i) Open Course Ware is freely The mission of the research program at the section of available and consists of recorded lectures (collegerama) Sanitary Engineering of TU Delft is to achieve practical and written material; (ii) the on-line master’s programme breakthroughs in these niches by a coordinated approach also makes use of the recorded lectures to stimulate in close cooperation with the Dutch water sector and distant learning, but the content is exactly the same the international scientific community. By working as for on-campus students; (iii) Massive Open On-line together within a well-developed network with the stake Course (MOOC) “Introduction to Water Treatment” is holders from science and industry, we aim to cover the freely available and is especially made to address large complete innovation cycle, from the initial brain wave, groups. The section Sanitary Engineering is front runner through research planning, funding and execution, to in on-line education and the mentioned MOOC was the implementation in practice and possibly valorization and first one of TU Delft. commercialisation. Ambition in research and education Research themes and approach Dutch drinking water is characterized by a very high Research and education of the Sanitary Engineering quality, owing to the high technical standards in Dutch Section is of high societal relevance and technical water companies, resulting in continuous supply of excellence. It serves the current needs of the Dutch safe drinking water at an acceptable price. No chlorine Water sector and outlines present developments and is used during drinking water production, which is future strategies in close cooperation with the sector. In made possible by applying a multiple barrier treatment addition, international developments and our increasing system, producing biologically stable water. Moreover, the participation in the international Water arena increasingly drinking water is soft, has a pleasant taste and colour include research projects of global concern. Our and pipeline leakages are virtually zero. As a result of philosophy results in a balanced combination of societal this, the trust in the drinking water quality is high. The and industrial pull and scientific push. We strongly Dutch drink water from the tap and they do not feel believe that this is in the best interest of our MSc and the need for using bottled water or point-of-use filters. PhD students serving both science and industry. Delft Continuation of the high quality standards in the water 7 Research Mission statement sector requires research on presence and fate of priority To be able to address the research needs of the water pollutants, biological growth (e.g. Legionella) and water sector, our MSc and PhD research is clustered in 6 quality deterioration in the distribution system. thematic research themes: 1. “Emerging Municipalities are responsible for collecting and transporting used waters and managing the rainwater technologies for water treatment” includes solutions for emerging threats, increasing standards, and optimized treatment. and groundwater in urban areas. In the near future they 2. “Reclamation and recovery of water, energy and used are faced with several challenges, e.g. climate change, compounds” deals with technologies for the closing (de-)urbanisation, increased pollution, costs, energy, and resource effectiveness, implementation of sensor networks for process control. These challenges are to be faced in the light of a more intense cooperation with of material cycles in the urban water cycle. 3. “Modeling, sensoring and automation” deals with operational efficiency improvement. 4. “Distribution and discharge networks” investigates other stakeholders, ultimately leading to an increasing the need for knowledge of the involved processes and sound distribution and drainage systems. engineering solutions. water quality and hydraulic aspects in 5. “Sustainable solutions for global development” focuses on improving drinking water supply and Water boards, ultimately responsible for the upgrading sanitation in developing countries. of the used urban waters, are challenged by increasingly 6. “Water and Health” focuses on the relations between stringent effluent criteria and societal concerns on priority technical interventions and related health risks. pollutants and hygienic quality of the produced effluents. Moreover, foreseen shortcuts in the water chain, creating Each of the staff members has its own specialisation to urban water cycles, require effluent qualities meeting the develop research in one or more of the above mentioned demands of the subsequent user, that are often much research more stringent than the emission standards. This logically (anaerobic) membrane bioreactors, (ceramic) membrane results in improved operation of sewage treatment plants, filtration, metallic surfaces in water, characterisation of introduction of new treatment technologies, interactions natural organic matter, soft sensors in water treatment, between sewerage and separation of rain water from monitoring in sewer systems, emerging pathogens and the sewer system. In addition, the water boards are technology selection in relation to water quality. themes. These specialisations include emphasizing the potentials of recovery of resources, such as nutrients, bio-plastics, cellulose fibres, and energy Our research agenda includes a mixture of desk-top from sewage streams. research, laboratory experiments, pilot-plant experiments and full-scale field research. Computer modelling is very important as it enables us to understand the complex reality and limit the number of experiments to achieve an optimal result. Where laboratory experiments test our initial hypothesis under defined conditions, pilot plant and field research includes the specific water quality and reactor operational aspects that cannot be simulated in the lab. Moreover, full-scale investigations at treatment plants and piped/sewerage networks are required in order to study the effects of large scale hydraulics. As such, our research can be characterised as a mixture of water quality, process technology, hydraulics and applied mathematics. A thorough understanding of physical, chemical and biological processes is required to improve the water matrix to the required level. This, combined with a thorough insight in hydraulic aspects, such as 8 Mission statement turbulence, mixing, and uneven flow patterns, will ensure Boulder, Waterloo, Trondheim, Dresden, Poitiers, Rennes, the feasibility of the technology in large scale settings. Toulouse, Zürich, Valencia, Santiago de Compostela, Based on our experience, these mixtures of scales Singapore, Harbin, Beijing, Shanghai, and Xiamen. and sciences provide a total view on sound sanitary Research projects are performed in cooperation with engineering that stimulates new ideas and approaches. Agentschap NL, NWO, Commercial partners, TTIWetsus The professors in our group have a down-to-earth and the European Union. Special agreements for approach and practice ‘management by participation’. research collaboration are made with Waternet, Dunea, They stimulate discussions between PhD students, Oasen, Evides, HWL, Vewin and Rioned. Next to papers staff members and experts from science and industry. and reports, our research is communicated through a Moreover, they frequently participate in national and newsletter. In addition, many ideas are disseminated at international meetings on the research agenda for the our annual ‘Vakantiecursus’ which is acknowledged as the water sector, such as the International Water Association leading Dutch conference on Sanitary Engineering being and KNW, providing additional stimuli to the research. annually first, just after New Years’ eve. The processes of improvement and innovation function primarily through the interaction with the experts from science and industry. Frequent external visitors are invited to participate in meetings and colloquia. Our international network includes a vast number of foreign universities, such as in Duisburg, Leuven, Gent, Sheffield, New South Wales, Bradford, Johannesburg, Professor Jules van LierProfessor Luuk Rietveld Head section Sanitary Engineering Head Water Management department Professor of Environmental Professor Urban Water Cycle and Engineering and WastewaterDrinking Water Technology Treatment 9 Research Mission statement Theme 1: Emerging technologies for water treatment Theme leaders: Bas Heijman & Jules van Lier In recent years it has become clear that the pollution of the effectiveness of different treatment technologies and water sources has become so widespread that traces of treatment combinations in removing these emerging compounds such as endocrine disputers, polar pesticides substances is investigated. Also a modeling approach and pharmaceuticals can even be found in Dutch drinking is developed to predict the removal of new emerging water. Only a few of these emerging substances are substances and to assess the plant performance towards known and measured in our drinking water. To face these organic micro pollutants. new substances application of advanced water treatment Due to the increasing need for protection of water is required. Moreover, due to the scientific progress we resources, the growing environmental awareness, as laid have come to understand that also microbiological threats down in the European Water Framework Directive (WFD), still cannot be ignored, the most relevant being Legionalla and the public inclination to sustainability, the pressure and Cryptosporidium. Fortunately, in recent years we have on water recycling, and the need for improvement of also seen major breakthroughs in new technologies such effluent quality of waste water treatment plants (WWTP) as membrane filtration and disinfection/oxidation with are increased over the past years. Therefore, there is a ozone/UV/H2O2. These technologies can be used both on need for upgrading the WWTPs. This can be done by the drinking water as well as on the waste water side and advanced or tertiary treatment of effluent of conventional an integrated approach has to be developed. Our research WWTP’s by filtration and ultrafiltration; the development in this theme deals with the further development of these of alternatives for conventional treatment processes e.g. technologies and in particular the determination of the the membrane bioreactor either aerobic or anaerobic; practical feasibility including such aspects as efficiency, and the modification of the conventional treatment to costs and operational aspects. In several PhD projects optimize the efficiency. Research projects Decision Support System for controlling emerging substances in the water cycle Astrid Fischer Hybrid Advanced Oxidation and Artificial Recharge to Remove the Organic Micropollutants from Drinking Water Feifei Wang Increasing the utilization of organic waste and low value feeds with the help of lignin degrading fungi DIPOOL Advanced UV-based technology for pool water treatment Anaerobic Membrane Bioreactor Technology for the Treatment of Industrial Effluents Application of Dynamic Membranes in Anaerobic Membrane Bioreactor Systems Emerging substances: Towards an absolute barrier Microbiological safe swimming pools without chlorine Mostafa Zahmatkesh Maarten Keuten Recep Kaan Dereli Mustafa Evren Ersahin Cheryl Bertelkamp Marjolein Peters Cost-Effective Municipal Wastewater Treatment by Coupling of UASB and Hydrodynamic determination of RO membranes using the PIV method BioXtreme treatment of industrial wastewater 10 Amir Haidari Julian Muñoz Sierra Mission statement Theme 2: Reclamation and recovery of water, energy and used compounds Theme leaders: Jules van Lier & Luuk Rietveld Wastewater treatment is needed to full-fill the Water white (rain) streams are (partly) separated. The yellow Framework Directive. However, more and more attention stream can e.g. be used for the production of fertilizer. is paid to the fact that wastewater is also a potential Phosphate recovery is becoming an important issue resource for city water, agriculture and/or industrial since this compound is getting scarce and prices are water. Crucial is treatment at acceptable costs with rising dramatically. Finally, the water of the effluent of the aim of resource recovery at various levels, such as a wastewater treatment plant is a resource for industry energy, fertilizing agents and water. In the Netherlands and agriculture. In the Netherlands e.g., 80% of the fresh specific programmes are developed to increase the water use is industrial and when domestic wastewater energy production at wastewater treatment plants treatment plant effluent is used for industrial application by for example the production of green gas (from less pressure is laid on the precious water sources. sludge) that can be injected in the existing natural Therefore, the Sanitary Engineering section focusses gas distribution system. This could even be applied to on technology development to make reclamation and black water in a decentralized system where the black recovery feasible not only in the Dutch/western context (faeces), yellow (urine), grey (bathing and kitchen) and but also in the context of developing countries. Research projects Organic carbon in demineralized boiler feedwater David Moed Enhanced Enzymatic Anaerobic Fermentation of Organic Residues (EnzyFOR) Steef de Valk Anaerobic digestion (AD) of fine sieve concentrated sewage waste Dara Ghasimi Emission Minimalization of Marine Aquaculture Recirculation Systems Xuedong Zhang OPTIMIX Guido Kooijman Forward Osmosis in Sewer Mining Kerusha Lutchmiah Treatment of Domestic Sewage by Anaerobic Membrane Bioreactor Technology – Anaerobic MBR for Aqua Cleaning and Energy Recovery Hale Ozgun Innovative ceramic ultrafiltration for water reuse: fouling on MF/UF and RO Ran Shang Distinguishing competitive effects from characterized background EFOM isolates on adsorption of trace organic contaminants by typical activated carbons Advanced Oxidation-Electrochemical solutions for water and wastewater treatment Ceramic nanofiltration for sustainable wastewater reclamation Sustainable fresh water supply for Urbanizing Maputo, Mozambique Jingyi Hu Yasmina Bennani Franca Kramer/Ran Shang Noor Gulamussen/Celma Niquice Ceramic nanofilter held by Jiayun Lu at Harnaschpolder 11 Research Mission statement Theme 3: Modeling, sensoring and automation Theme leaders: Luuk Rietveld & Henri Spanjers Water treatment plants consist of numerous treatment long lasting experience in this respect and works closely processes in series and in parallel. The operation of the with industry to develop news tools for modelling and present-day infrastructure is done by operators who monitoring of the Urban Water Cycle, finally resulting in mainly focus on providing the required flow and quality advanced control for automation. at all times. It is obvious that it is possible to achieve better results at lower costs and with less impact on the environment by utilizing available options such as buffer tanks, equal flow distribution over process units, flow control and process control. By using computer models it is now also possible to control the water quality leaving the treatment plant while delivering the required flow and quality. The Sanitary Engineering section has a Research projects Model-based control in the urban water cycle Annelies Aarts Removal of pharmaceuticals by organic coagulants/flocculants in primary settling of wastewater treatment plant Mohamad Mohd Amin Novel monitoring and process control system for efficient production of VFA and biogas in anaerobic digestion plant Broadening and renewal of the Dutch drinking water benchmark Xuedong Zhang Marieke de Goede Optimized mixing for enhanced biomass conversion using CFD modeling of multiphase flow in anaerobic digester 12 Peng Wei Mission statement Theme 4: Distribution and discharge networks Theme leaders: Marie-claire ten Veldhuis, Francois Clemens & Jeroen Langeveld Water infrastructures are a vital support of urban societal and probabilistic methods in support of quantitative risk development: they supply clean drinking water and analysis. We use urban labs to collect experimental data evacuate polluted wastewaters to protect public health from real-life conditions and use data mining techniques and they drain storm waters to prevent flood damage linking multiple data sources to predict failures in support and economic and societal disruption. Quality of service of risk analysis and prevention. Our aim is to provide provided by water infrastructures is under threat as society with effective techniques and strategies to use ageing processes degrade structural and hydraulic ageing water infrastructures while maintaining optimal conditions. Leakages, blockage, pipe blockage, water functionality. quality deterioration are but a few of the detrimental effects ageing processes can generate. Developing better understanding of ageing processes is a prerequisite to be able to predict and prevent harmful effects. Early detection and warning is another essential strategy to cope with failures and to increase understanding of failure conditions. The focus of this research theme is on monitoring, detection and prediction of failures in water infrastructures by a combination of experimental research Research projects Strategic assetmanagement in the water cycle Failure prediction and management of lateral connections in sewer systems Risk-based sewer asset management Decision making and organization of sewer asset management Effective Sewer Asset Management Quality based real time control in wastewater systems Sewer maintenance and hydraulic performance Transportation of domestic slurry in pipeline systems New generic design guidelines for pump sumps of wastewater pumping stations Propagation of uncertainties in integrated catchment models Critical sewers Rian Kloosterman Johan Post Matthijs Rietveld Wouter van Riel (graduated in 2016) Nikola Stanić (graduated in 2016) Petra van Daal-Rombouts Marco van Bijnen Adithya Radhakrishnan Alex Duinmeijer Antonio Manuel Moreno Rodenas Didrik Meijer 13 Research Mission statement Theme 5: Sustainable solutions for global development Theme leaders: Jules van Lier, Bas Heijman & Doris van Halem Safe drinking water and improved sanitation are at and gravel filtration, and wastewater reclamation. present not available for every human being on earth. Appropriate sanitation, in balance with the prevailing The current knowledge on low-cost drinking water socio-economic conditions is of crucial importance for treatment and sanitation is often insufficient to provide (partly) meeting the agreed MDG-7. Sustainability in safe water in remote or densely populated areas. Either terms of cost-effectiveness, technical plain and recovery solutions do not fit within the targeted environment or a of resources are the main drivers for novel developments. scientific approach is not at hand. Energy recovery via anaerobic conversion processes may Research to develop and improve treatment systems for generate direct benefits on household levels meanwhile the poor is the main objective of the work done within basic sanitary requirements are established. A similar this new research theme. The (upcoming) projects in approach will be followed in addressing sanitation at this theme aim at critically evaluating existing treatment community level and/ or city section level, where block options sanitation or satellite sewers are connected to technical and the development of new innovative technologies. The current research focuses on low-cost plain systems which focus on recovery of resources. ceramic filtration, (subsurface) arsenic removal, riverbank Research projects Upflow gravel filtration for multiple uses Luis Dario Sanchez Torres Transport and attenuation of organic compounds and turbidity peaks in subsurface porous media during aquifer passage Juan Pablo Gutierrez Safe drinking water in Bangladesh: feasibility and sustainability of hand-pump subsurface arsenic removal in diverse settings Arsenic removal in Nicaragua Ag and Cu nanoparticles in ceramic pot filters 14 Sandra Borges Freitas Bayardo Gonzalez Katie Camille Friedman Mission statement Theme 6: Water & Health Theme leader: Gertjan Medema Safe water is essential to our society. Water systems These provide new niches for pathogens and new routes should protect society against the spread of infectious of exposure to pathogens. diseases. New pathogens emerge (like SARS, new (avian) influenza viruses). They emphasize the vulnerability The research focus in this theme is: of our densely populated society to infectious diseases ▪▪ Quantitative health impact assessment of water and highlight the importance of knowledge about systems, with an emphasis on risks caused by the pathogens, their possible pathways and effective pathogenic microbes. The results will help to make management. In our densely populated country, the informed risk management decisions in the water burden on the environment with pathogenic microorganisms is high and the possibilities for exposure sector. ▪▪ to these pathogens are also many. The conventional prevent transmission of pathogens through the water exposure through drinking water is well under control, but other water uses (such as bathing) are not. Moreover, we are inventing new concepts for dealing with water Effective (treatment) technologies or strategies to route. ▪▪ Research is a close collaboration with KWR Watercycle Research Institute and the water sector. in our society (wastewater reuse, water in cities, etc.). Research projects Health impact of new urban water concepts Helena Sales Ortells Mechanisms of loose deposits´ microbiota effects on the quality of chlorinated distribution systems water New methods for microbial water quality testing Ana Poças Maja Taucer-Kapteijn Virus control by nanometals Lina Bachert 15 Research Research grants 2016 PS Drink – Priority-setting System to assess emerging risks for safe Drinking water supply During the last decades, new risks for drinking water chemical risks and resource quality frequently emerged. Emerging risks 3) the incorporation of risk perception and risk may be brought about by societal, economic pressure communication in the developed methodology. and climate change and may impose a public health risk. Notification of emerging risks, like the presence of pharmaceuticals in drinking water, often gives rise to public concern. To date, emerging risks are often identified in a non systematic way. As a consequence, emerging risks might be addressed late, thus making expensive control strategies necessary. On the other hand, not all emerging risks may impose a threat to public health. The aim of this project is to develop an integrated approach to systematically identify, assess and prioritize emerging risks to the production and supply of safe drinking water and to develop effective strategies to communicate such risks. Specific research questions are: 1) Which emerging risks for drinking water production can be identified by systematic screening of information from various sources? 2) How can the identified (microbial and chemical) emerging risks be ranked and prioritized? 3) How can the prioritized risks be quantified and what remediation strategies are possible? 4) What are the information needs from the public regarding emerging risks for drinking water production? What are effective strategies to communicate these risks? Novel elements of the project are: 1) the proactive systematic analysis of emerging risks combining literature, research data, information from registration databases and expert opinion, 2) the integrated approach for ranking of microbial and Project partners: Funded by: Project coordinator: Period: 16 TU Delft, Universiteit Utrecht – Institute for Risk Assessment Sciences, RIVM – National Institute for Public Health and the Environment RIVM – National Institute for Public Health and the Environment Jan Peter van der Hoek 2016 - 2020 Research grants 2016 Hydraulic modelling of liquid-solid fluidisation in drinking water treatment processes In the Netherlands annually 400 million m3 drinking The performance of the chemical process in pellet water is softened in treatment plants applying fluidised softening reactors is proven dependent on the state of bed pellet reactors. Generally, sand is used as seeding the fluidised particle bed. material and calcium carbonate pellets are produced as a by-product. To improve sustainability calcite pellets are The aim of the research is to obtain substantial more grained and sieved and re-used as seeding material. knowledge regarding the hydraulics of the liquid-solid fluidisation phenomena which will optimize the softening Theoretical knowledge of perfect round spheres in process in fluid bed reactors, liquids is generally accepted and applied to predict the fluidisation behaviour. Regarding natural particles The research will take place at the Weesperkarspel facility numerous semi-empirical models have been published. in Amsterdam. However, there is no general agreement regarding which equation is the most accurate. In many cases shape factors are introduced for the particle diameter to improve the numerical results. In the transition from a fixed to a fluidised bed state, after increasing the water throughput, the drag force existing on particles increases. This research will show the dependency of the drag on the actual particles size and change in orientation. It will be demonstrated that not the shape of the particle will decline, but the re-orientated will cause the drag force the decrease with 50%. This revised approach will result in a better understanding and prediction of the fluid bed state. In the well know Moody chart the friction factor is plotted against the Reynolds number, in which the emphasis is made on the turbulent flow. In liquid-solid systems the flow regime is in general assumed to be laminar. In an improved approach the friction factor is represented not using the default log-log method. The frequently cited and applied Richardson-Zaki fitting model is revised and replaced by an improved hydraulic model. The improved prediction model is more accurate and based on thoroughly carried out pilot plant experiments. Project partners: Funded by: Project coordinator: Period: TU Delft, Waternet Waternet Jan Peter van der Hoek 2016 - 2020 17 Research Research grants 2016 Integration and optimization of water, energy and material flows to achieve sustainable urban solutions The flows of water, energy and materials have a large 1. Water transport systems: the integration of water, potential to contribute to sustainable solutions in the energy and material flows in an urban metabolism city. The research focuses on the transition from a linear system results in quality and quantity characteristics of metabolism to a circular metabolism in cities to contribute urban water flows, different from the present ones. This to the realization of a circular economy in cities in which requires new and innovative water transport systems. waste and emissions do not longer exist. 2. Smart water technologies: recovery of water, energy Up till now, water, energy and materials are often and materials from urban water flows requires new considered as non-renewables resulting in emissions to and innovative technologies, capable to recover these soil, water and air. However, by reuse, recycling and/ compounds economically and effectively. or conservation of these flows a circular metabolism is created and emissions to soil, water and air can be 3. Smart water control: integration of water, energy and reduced or prevented. material flows requires new and innovative operation and control systems. Especially in the case of decentralized In this research, urban water is the starting point. Urban systems, traditional monitoring is much too expensive and water is defined as drinking water, storm water and new monitoring and sensoring strategies are required. wastewater. Water is the starting point in this research Closing loops in the urban water cycle introduces new because it offers excellent possibilities to close the (human health) risks. To manage these risks smart water watercycle and reuse urban water, to recover energy control systems have to be developed based on new and from urban water, and to recover and reuse materials innovative monitoring and sensoring strategies. from urban water. 4. Sustainable system integration: although water is Concepts to realize an urban metabolism with water chosen as staring point in this research, a sustainable as starting point have been proposed and tested both system integration is a prerequisite to make the water on centralized scale and on decentralized scale. The harvesting successful and to make a contribution to the choice between centralized and decentralized concepts concept of the circular city. Up till now water, materials and depends amongst others on local circumstances, on the energy are quite separated domains. System innovations materials aimed at to recover and reuse, on financial and are required to realize the integrated approach. environmental considerations, and also on the preferences of the stakeholders involved. Whether centralized or decentralized, four main topics require special attention and up till now these aspects have not been considered in an integrated approach. TU Delft, Amsterdam Intitute of Advanced Metropolitan Solutions (AMS) Project partners: Funded by: TU Delft, Amsterdam Intitute of Advanced Metropolitan Solutions (AMS) Project coordinator: Jan Peter van der Hoek Period:2016-2018 18 Research grants 2016 The research is carried out in the framework of the position of Prof. Jan Peter van der Hoek as Principal Investigator at the AMS Institute. AMS (www.amsinstitute.org ) is the institute in Amsterdam, founded in 2014 and supported by the City of Amsterdam, in which Technische Universiteit Delft, Wageningen University Research and Massachusetts Institute of Technology, together with partners from the public and private sector, work on three specific themes: Circular City – Vital City – Connected City. Project partners: TU Delft, Amsterdam Intitute of Advanced Metropolitan Solutions (AMS) Funded by: TU Delft, Amsterdam Intitute of Advanced Metropolitan Solutions (AMS) Project coordinator: Jan Peter van der Hoek Period:2016-2018 19 Research Research grants 2016 SewerSense - Multi-sensor condition assessment for sewer asset management Proactive asset management is necessary to ensure the We aim to address these challenges by improving high levels of service currently provided by the sewer automated defect detection and classification diagnostics system. There are three main challenges to sewer asset for closed-circuit sewer inspection (CCTV) and promising management addressed within this project: Firstly, the novel inspection techniques (e.g. laser range scanning, lack of reliable sewer condition data, which limits our stereo vision). Their applicability and performance will ability to assess the past, current, and future condition of be assessed and validated in the lab and in the field. sewers and hence to identify immediate, mid-term, and Together with representatives from the Dutch urban long-term rehabilitation (and financial, personnel) needs. drainage sector, we want to develop a framework for Secondly, a sewer condition assessment framework sewer condition assessment so that defect information is needed that links observed defects to performance can implications and hence to decision-making objectives. and predictive modelling of potential performance This also requires practically applicable models to implications. We will adapt, test, and use suitable models describe, understand, and predict deterioration as well to quantify the added value of better inspection and as associated risks. Thirdly, validation of inspection condition assessment techniques for identifying sewer techniques to obtain this data, as well as predictive network condition, optimal inspection intervals and the models exploiting it, are crucial for providing dependable most suitable inspection approach. decision support to sewer asset managers. Project partners: TU Delft, Leiden University Funded by: Technologiestichting STW Project coordinator: Lisa Scholten Period:2016-2020 20 be directly used for condition assessment Current research grants AMBR tool developments for full-scale applications Project partners: Biothane-Veolia Funded by:Biothane-Veolia TU coordinator: Jules van Lier Period:2010 - 20-10-2015 A-Racer - Anaerobic MBR for Aquacleaning and energy recovery Project partners: Pentair (Norit), Saxion Funded by: Agentschap NL - Innowater program TU coordinator: Jules van Lier Period:2011 - 20-10-2015 Aquademia Project partners: University of Girona, WUSMED, Aqualogy, Spain, TU Graz, Austria, IWTH, Germany, TU Delft, Waterboard De Dommel Funded by: EU Life Long Learning Programme TU coordinator: Jeroen Langeveld Period:2013 - 01-10-2015 Ceramic nanofiltration as the key step for sustainable wastewater treatment with reuse of water, energy and nutrients Project partners: TU Delft, Evides Industriewater, Logisticon Funded by:STW-TKI TU coordinator: Bas Heijman Period:2014-2018 DELTAP (an integrative approach for smart small-scale piped water supply in the Ganges-Brahmaputra-Meghna Delta) Project partners: Studio Bereikbaar, Schlumberger, Evides, Precious Plastics, Dhaka University, AN College, EPRC, Max Foundation, UNICEF India, PRACTICA Funded by: NWO WOTRO Urbanising Deltas of the World 2 TU coordinator: Doris van Halem Period:2016-2021 Domestic Slurry Transportability Project partners: TU Delft, Deltares Funded by: STW Watertech2013, Deltares, STOWA/Rioned, Waternet, Waterschap Zuiderzeeland, XYLEM BV Grontmij BV, Desah BV TU coordinator: Ivo Pothof Period:2014-2018 Dynafil - Dynamic filtration of A-stage activated sludge in aeration tank and anaerobic digester Project partners: KWR, Logisticon, STOWA, WS Brabantse Delta, Waternet, Bert Daamen Funded by: Agentschap NL - Efficiente vergistingsketen TU coordinator: Jules van Lier Period:2011 - 11-2015 21 Research Current research grants EFRO Swimming pools Project partners: Hellebrekers Technieken, Van Remmen UV techniek, Akzo Nobel, Coram International, Sportfondsen Nederland Funded by: EFRO East Netherlands TU coordinator: Luuk Rietveld Period:2010-2013 Enhanced low-cost ceramic membrane filters for drinking water treatment Project partners: TU Delft’s ChemE and Industrial Design Engineering. Research institutes, NGOs and the Ministry of Water in Nicaragua Funded by: Delft Global Initiative TU coordinator: Doris van Halem Period:2016-2020 Enzyfor - Enzymatically enhanced digestion for enhanced treatment of secondary sludge Project partners: DSM, COSUN, Tauw, STOWA Funded by: STW - W2R program TU coordinator: Jules van Lier Period:2011 - 02-2016 E4Water Project partners: Dechema Funded by: EU (FP7 Program) TU coordinator: Luuk Rietveld Period:2012-2015 FixAs Project partners: Vitens, Brabant Water, Hatenboer Water, RH-DHV, Dunea, Pidpa, Evides, RIVM, TU Delft Funded by:STWatertechnology TU coordinator: Doris van Halem Period:2014-2019 Fungi - Increasing the utilization of organic waste and low value feeds with the help of lignin degrading fungi Project partners: Wageningen University and Research Center Funded by: STW - Waste to Resource TU coordinator: Henri Spanjers Period:2012-2016 GFSA Project partners: Paques, TU Delft Funded by: STW, Partnership program: “Partnership Paques - The VFA Platform” TU coordinator: Merle de Kreuk Period:2013-2017 22 Current research grants Hydraulic modelling of liquid-solid fluidisation in drinking water treatment processes Project partners: TU Delft, Waternet Funded by:Waternet TU coordinator: Jan Peter van der Hoek Period:2016 - 2020 Lightning Project partners: PoolwaterTreatment and Stichting Gorinchemse Sportaccomodaties Funded by: Agentschap NL - Innowater Program TU coordinator: Luuk Rietveld Period:2010-2015 Integrated Filter Technology Project partners: Visser & Smit Hanab BV, Grontmij Nederland BV, TU Delft, Waterschap Veluwe Funded by: Agentschap NL - Innowater Program TU coordinator: Luuk Rietveld Period:2010-2015 Integration and optimization of water, energy and material flows to achieve sustainable urban solutions Project partners: TU Delft, Amsterdam Intitute of Advanced Metropolitan Solutions (AMS) Funded by: TU Delft, Amsterdam Intitute of Advanced Metropolitan Solutions (AMS) TU coordinator: Jan Peter van der Hoek Period:2016 – 2018 Microbiologically safe drinking water Project partners: RCEES (China), Oasen, TU Delft Funded by:NWO TU coordinator: Gertjan Medema Period:2014-2015 NICHE-KEN 212 Project partners: Pwani University Kenia, Q-point, K.I.Samen, DLV Dier, Egerton University Funded by: Nuffic TU coordinator: Bas Heijman Period:2015-2018 OASIS Project partners: Imperial College of Science, Technology and Medicine (London), ) Commissariat a I’Energie Atomique et aux Energies Alternatives (France), TU Delft, Stichting Deltares, ARIA Technologies S.A. (France), METNEXT (France), PIK (Germany) Funded by:KIC-Climate TU coordinator: Marie-Claire ten Veldhuis Period:2012-2015 23 Research Current research grants OPTI-VFA Project partners: Attero, Optomeasures (France), Rikola (Finland), MTT Multantiv (Finland), MSI (Spain), Maris Projects, VTT Technical Research Centre of Finland (Finland), CEIT (Spain), TU Delft Funded by:EU TU coordinator: Henri Spanjers Period:2013-2015 Propopi - Towards Pro-Poor Private Investments in water supply in Kota Bandung Project partners: Vitens-Evides-International (VEI), Simavi, PDAM-Bandung Funded by:RVO TU coordinator: Bas Heijman Period:2014-2019 PS Drink – Priority-setting System to assess emerging risks for safe Drinking water supply Project partners: TU Delft, Universiteit Utrecht – Institute for Risk Assessment Sciences, RIVM – National Institute for Public Health and the Environment Funded by: RIVM – National Institute for Public Health and the Environment TU coordinator: Jan Peter van der Hoek Period:2016 - 2020 Puro Project partners: Logisticon, Haitjema, Waternet, Oasen Funded by: Agentschap NL - Innowater Program TU coordinator: Bas Heijman Period:2010-2015 Quantifying Uncertainty in Integrated Catchment Studies (QUICS) Project partners: University of Sheffield, University of Bristol, TU Delft, CH2M Hill (formerly Halcrow), Wageningen University, Justus-Liebig-University of Giessen, University of Coimbra, Public Research Centre Henri Tudor, Eawag (Swiss Federal Institute of Aquatic Science and Technology), Aquafin, Waterways srl, Ruhr-Universitat Bochum, Witteveen+Bos, Universite Laval, CTGA - Technological Center for Environmental Management Funded by: EU funded FP7 Marie Curie Initial Training Network (ITN) TU coordinator: Jeroen Langeveld/Marie-Claire ten Veldhuis Period:2014-2018 RainGain Project partners: TU Delft, Provincie Zuid-Holland, Gemeentewerken Rotterdam, KU Leuven, Aquafin BV, Imperial College London, MetOffice, ENPC/ParisTech, Local Government Floof Forum, Val de Marne County, Seine-St Denis County, MeteoFrance, Veolia Funded by: Interreg IVB NWE TU coordinator: Marie-Claire ten Veldhuis Period:2011-2015 24 Current research grants Rain Sense Project partners: TU Delft, WUR, IBM, Cisco, Waternet, Deltares, KPN, future: Achmea Funded by: AMS, TU Delft (EWI & CiTG), WUR, and sponsors Waternet, IBM, KPN, Cisco, Deltares TU coordinator: Marie-Claire ten Veldhuis, Wouter Koole Period:2014-2015 Set-up of the FIPAG Academy for Professional Development in Water and Sanitation Project partners: IHE-Delft (Lead), TU Delft, IRC Water and Sanitation Centre, UNESCO-HydroEX, Rand Water, Eduardo Mondiane University Funded by: Nuffic/NICHE TU coordinator: Luuk Rietveld Period:2012-2016 SewerSense - Multi-sensor condition assessment for sewer asset management Project partners: TU Delft, Leiden University Funded by: Technologiestichting STW TU coordinator: Lisa Scholten Period:2016-2020 Shell ZLD research formulation Project partners: Shell Funded by:Shell TU coordinator: Henri Spanjers Period:2012 - 2015 STW valorisation grant Project partners: TU Delft, Elemental Water Makers, STW Funded by:STW TU coordinator: Luuk Rietveld Period:2014-2015 Sustainable fresh water and energy production for the Island of Johnny Cay (Colombia) Project partners: Solteq Energy, Lenntech, Coralina, TU Delft Funded by: Transition Facility 2014, ODA subsidy, Education & Capacity building TU coordinator: Bas Heijman Period:2014-2018 Sustainable fresh water supply in urbanizing Maputo, Mozambique Project partners: TU Delft, UNESCO-IHE, Universidade Eduardo Mondlane, Vitens-Evides-International, FIPAG, Royal HaskoningDHV, Waterbedrijf Limburg, IRC Funded by: TU coordinator: Luuk Rietveld Period:2014-2018 25 Research Current research grants TAPES - Transnational Action Program on Emerging Substances Project partners: TU Delft, Waternet, Waterschap De Dommel, KWR, DVGW, Erftverband, VMW, University of Edinburgh FNHW, VITO Funded by: Interreg IVB NWE TU coordinator: Jan Peter van der Hoek Period:2013-2018 Thermal Energy Recovery from Drinking Water Project partners: TU Delft, Waternet Funded by: Waternet, Topsector Water TKI Watertechnology TU coordinator: Jan Peter van der Hoek Period:2015-2019 VEWIN - Improving and broadening of the Dutch drinking water benchmark Project partners: Vewin, TU Delft (Faculty TBM), Dutch drinking water companies Funded by: Vewin (Association of Dutch water companies), PWN, Oasen, Waternet TU coordinator: Jan Peter van der Hoek Period:2013-2018 Virus control - Enhanced elimination of viruses in household water treatment processes Project partners: Unilever (UK & Hindustan), Berson UV, WLN, Wetsus, RIVM, TU Delft Funded by: TTI Watertechnologie TU coordinator: Gertjan Medema Period:2012-2015 Water Institute Indonesia (WII) Project partners: Institut Teknologi Bandung, Directorat General of Human Settlements, Perpamsi, BPPSPAM, Stichting Wateropleidingen Funded by: Agentschap NL - EVD Program TU coordinator: Bas Heijman Period:2010-2015 WOTRO Subsurface arsenic removal Project partners: Free University Amsterdam, Wageningen University, Dhaka University, Bangladesh University of Engineering and Technology Funded by: NWO - Wotro program TU coordinator: Doris van Halem Period:2010-2015 Zeolites as novel adsorbent in water treatment (Zeotreat) Project partners: Oasen, Evides, PWN, HWL, TU Delft Funded by: TKI Watertechnolgie TU coordinator: Bas Heijman Period:2015-2018 26 Academic staff Head section Sanitary Engineering Professor Environmental Engineering /Wastewater Treatment Room 4.57 [email protected] +31 15 27 81 615 Prof. Dr. Ir. Jules van Lier Head Water Management dept Professor Urban Water Cycle and Drinking Water Technology Room 4.53 [email protected] +31 15 27 84 732 Prof. Dr. Ir. Luuk Rietveld Professor Sewerage Room 4.65 Professor Water and Health Room 4.63 [email protected] +31 15 27 85 450 [email protected] +31 15 27 89 128 Prof. Dr. Ir. Francois Clemens Prof. Dr. Gertjan Medema Professor Drinking Water Engineering Room 4.49 [email protected] +31 15 27 85 227 Prof. Dr. Ir. Jan Peter van der Hoek Associate professor Wastewater Room 4.63 H.L.F.M. [email protected] +31 15 27 89 128 Dr. Ir. Henri Spanjers Assistant professor Sewerage Room 4.65 [email protected] +31 15 27 84 734 Dr. Ir. Marie-Claire ten Veldhuis Assistant Professor Water & Control Room 4.95 [email protected] Dr. Edo Abraham Assistant professor Wastewater Treatment Room 4.61 [email protected] +31 15 27 85 274 Dr. Ir. Merle de Kreuk Associate professor Drinking Water Room 4.51 [email protected] +31 15 27 84 282 Dr. Ir. Bas Heijman Director Urban Drainage Programme Room 4.68 Assistant professor Drinking Water Room 4.48 [email protected] +31 6 18 97 62 83 [email protected] +31 15 27 86 588 Dr. Ir. Jeroen Langeveld Dr. Ir. Doris van Halem 27 Research Academic staff Assistant professor Urban Water infrastructure Room 4.65 | 3.45 Postdoc Room 4.68 [email protected] +31 15 27 89 576 [email protected] +31 15 27 81 734 Dr. Lisa Scholten Ir. Mathieu Lepot Assistant professor Water Quality Modelling Room 4.49 Postdoc Room 4.61 [email protected] +31 15 27 85 227 [email protected] +31 15 27 87 174 Dr. Boris van Breukelen Dr. ir. André Arsénio Assistant Professor Resource Recovery from Waste Water Room 4.61 [email protected] +31 15 27 82069 Dr. ir. Ralph Lindeboom [email protected] +31 15 27 88 578 Dr. ir. Matthieu Spekkers Postdoc Room 4.52 Postdoc Room S3.02.041 [email protected] +31 15 27 81 585 [email protected] +31 15 27 82 231 Dr. ir. Maria Lousada Ferreira Dr. Marjet Oosterkamp Postdoc Room 4.48 Postdoc Room 4.44 [email protected] +31 15 27 81 567 [email protected] +31 15 27 81 567 Dr. ir. Annemarie Mink Dr. ir. Ran Shang Lab Technician Room S3 0.03 Lab Technician Room S3.02.010 [email protected] +31 15 27 84 946 [email protected] +31 15 27 89 894 Ing. Mohammed Jafar 28 Postdoc Room 4.66 Armand Middeldorp Academic Academic staff Academic staff Lecturer Room 4.48 Online education officer Room 4.52 [email protected] +31 15 27 87 490 [email protected] +31 15 27 87894 Dr. Ir. Anke Grefte Sabrina Kestens MSc Executive Secretary Room 4.78 Secretary Room 4.55 [email protected] +31 6 20 10 23 68 [email protected] +31 15 27 81 812 Drs. Petra Jorritsma MSc Mariska van der Zee 29 Research Strategic programs Sewerage and urban drainage research program The Dutch urban drainage sector will be facing a number performance. The research projects within this theme will of significant challenges in the next decade. The sector provide knowledge on the relation between the operation has to deal with new issues such as climate change and and maintenance strategy applied and overall system priority pollutants, whilst at the same time there is a societal performance. The main focus will be on the front end of pressure on cutting cost levels, reducing CO2 emissions and sewerage, being house connections and gully pots. This topic nutrient recovery. In addition, there is an increasing lack of is dealt with by ir. Johan Post. In addition, Marco van Bijnen highly qualified personnel. This urged the sector to decide to is doing research on the relation between the condition of support the sewerage chair at Delft University of Technology, the sewer system in terms of root intrusion and sediment with the following objectives: beds and hydraulic performance. Matthijs Rietveld started • an increase of the number of MSc students; November 1st, 2016 with follow up research on risk based • an increase of the number of PhD students; • fundamental research answering the sewer asset management. observed challenges. Theme 3. Dynamics of sewer systems Continuous monitoring of hydraulics and wastewater quality Research program is applied at a number of locations in the Netherlands. These The research program comprises 4 themes, therewith data open an enormous opportunity to study the dynamics of covering the main challenges of the sewerage and urban sewer systems itself and in relation with wwtps and receiving drainage sector. waters and to enhance the knowledge on in sewer processes. Ir. Petra van Daal-Rombouts works on this topic, using the Theme 1 Asset management extensive database of Waterboard De Dommel and closely In the Netherlands, each year € 600 million is spend on cooperating with the Waterboard. Antonio Moreno Rodenas is asset management or, more specifically, on sewer renovation working on the uncertainties in integrated modelling. and rehabilitation. Recent research has demonstrated visual sewer inspections to be associated with significant uncertainty Theme 4. Sustainable urban water cycle and limited reproducibility. As these inspections are the main Theme 4 focuses on research on new concepts for the urban source of information used in sewer rehabilitation projects, water cycle enabling energy recovery and reuse of materials. these annual investments lack a profound basis. The The main issue left to be dealt with is the conveyance of research within this theme focuses on alternative sources black water. Adithya Thota Radhakrishnan, M.Sc is the Phd of information (or ways of working) in order to organize student working on this theme within the STW funded project the asset management in such a way that sewer system Domestic Slurry Transport. performance (serviceability) will be maintained at the desired level. Laser scanning and core sampling have been tested as Organization alternative technology, verified by full scale testing of pipe The research program is funded by partners from the Dutch strength. In addition, a serious game has been developed to urban drainage sector. Each contributor to the research analyse the role of information quality and the influence of program participates in this Program Committee. The Program interactions between stakeholders. Nikola Stanic M.Sc and ir. Committee advises the sewerage chair on the composition of Wouter van Riel both successfully defended their PhD thesis the research program. In addition, the members have the in 2016. Their work will be succeeded by Eva Nieuwenhuis in privilege to actively participate in the supervisory committees the beginning of 2017. of the research projects within the program and to provide case studies. Theme 2. Operation and maintenance Operation and maintenance in sewer systems is driven by The partners of the research program are (in alphabetical local criteria, e.g. gully pots are typically cleaned once a order): year, irrespective of the type of sewer system (combined or ARCADIS, Deltares, Gemeente Almere, Gemeente Arnhem, storm sewer) and irrespective of the impact on sewer system Gemeente Breda, Gemeente ’s-Gravenhage, Gemeentewerken 30 Strategic programs Rotterdam, Gemeente Utrecht, GMB Rioleringstechnieken, thus creating a solid base for the further development of this KWR, Royal HaskoningDHV, Stichting RIONED, STOWA, challenging research field. Sweco, Tauw, Vandervalk & De Groot, Vitens, Waterboard De Dommel, Waternet en Witteveen+Bos. dr.ir. J.G. Langeveld (Jeroen) Director Kennisprogramma Urban Drainage The urban drainage research program started in 2010 with a Associated professor Sewerage and Urban Drainage 5-year budget. Given the success of the program, in 2015 all partners decided to prolonged their participation until 2020, TU Delft cooperation Vitens in the field of drinking water research On 14 January 2011, the Faculty of Civil Engineering and opinion that knowledge development for ‘Innovative Geosciences (CEG) signed a contract in the field of water water technology’ in the drinking water supply chain is research. an essential precondition for retaining the high quality of drinking water both nationally and internationally. The A cooperation was entered into with drinking water research focuses on integral, sustainable approaches to company Vitens in the field of drinking water research the sub-fields of sources, purification and distribution. and a new chair of Innovative Water Technology was set up at the Faculty’s Water Management department. The cooperation agreement coincided with the appointing Vitens provides an annual, 200 k€ financial contribution of two new part-time professors at the Drinking water and TU Delft sees to staffing and facilities. The two chair. Prof. dr. ir. Jan Peter van der Hoek MBA, director parties signed the agreements in Delft during the 63rd of Waternet, the Amsterdam water company’s strategic Vakantiecursus [Summer Holiday Course], the Dutch centre and Prof. dr. ir. Walter van der Meer lead the water industry’s annual networking symposium, by Dean drinking water research together with Prof. dr. ir. Luuk Prof. ir. Louis de Quelerij, director of Stichting RIONED Rietveld. Hugo Gastkemper and chairman of the board of directors ir. Rik van Terwisga of Vitens. Vitens is the Netherlands largest drinking water company and provides the provinces of Friesland, Overijssel, Flevoland, Gelderland and Utrecht and a number of municipalities in the provinces of Noord-Holland and Drenthe with drinking water. Both parties are of the 31 Research Strategic programs Evides IW and TU Delft: Update on cooperation on “Innovations in the Industrial Waterloop” Evides IW for application in the industry to compile know-how to Next to drinking water, Evides water company is one of optimize the industrial water loop and reduce its water the largest suppliers of water & water services to the footprint. industry in the Netherlands. Evides Industry Water (EIW) is acting as a full-service water partner to the industry, The cooperation aims to establish a permanent base providing a utility portfolio compiling: industrial water with substantial expertise and know-how of the industrial treatment (process and demineralised water), waste water utility within the Delft University. In time this should water treatment and integrated treatment (water reuse). be aggregated into a professorship at the Delft University In addition EIW designs, finances and operates their in the field of knowledge of Industrial water treatment custom-made water treatment plants. EIW is operating and utilities. The enhancement of structural knowledge water plants for all major (petro)chemical multinational about the improvement of existing and development companies and makes use of both proven technology as of new technologies will add to the attractiveness of well as innovative new process designs. the water technology sector for young, well-educated professionals. Water Reuse One of the mayor targets of EIW is to establish water The cooperation will support MSc and PhD research reuse and recycling. Closing the water loop has a positive projects to develop technologies & solutions with effect on the environment, as it reduces the industrial superior performance in relation to (i) reduced energy use of precious water resources, such as groundwater footprint, (ii) maximized sustainable production of re- and drinking water. Effluent water coming from waste usable water and brine (concentrates) conversion (iii) water treatment plants is a potential feedstock and operational stability over substantial periods of time at suited to apply as a source for the production of process lowest operational expenses. water. EIW has excellent experiences with the recycling of wastewater for the production of process water in the At present 2 PhD students are working in the framework Netherlands, for example on the Dow Chemical Terneuzen of this cooperation. Julian Munoz is researching the site (reusing both industrial as well as municipal effluent potentials for bio-treatment under extreme conditions, to serve as process & demin water). The coming years characterized the water cycle of the site and its Terneuzen surroundings salinity and high temperature. Franca Kramer is working will even be further closed. This development is on the use of ceramic nanofiltration for direct wastewater supported by the results of the EU FP7 E4Water treatment and water reuse. 17 November 2015 David project (completed 2016): ”Towards a paradigm shift Moed defended his PhD thesis “Organic Contaminants in the chemical industry to create a breakthrough in and Treatment Chemicals in Steam-Water Cycles”. industrial water treatment by enhanced reuse, recycling In addition to the PhD students, several MSc students have and valorization of complex wastewater”. For this case performed their thesis research in the framework of and other examples, see: www.evides.nl/en/industrial. this cooperation. Joeri Legierse by refractory/toxic compounds, high worked on closed (domestic) water systems in the ‘Stadshavens’ project of TUD-EIW Cooperation Evides researching the potentials of ceramic membranes, On May 24th-2011 TUDelft CiTG and Evides signed an whereas exclusive long-term cooperation aiming at a research desalinisation using electro dialysis and capacitive de- program focused on the industrial water utility. The ionisation to prepare cooling water from blow down research program is focusing on fundamental and water and other sources. Mark Schetters researched applied research into the water production, waste the flocculation of activated sludge treating chemical water treatment, reuse & zero discharge technologies wastewaters under saline conditions. Currently, in the 32 Marleen Heinekamp worked on mild Strategic programs is investigating the phosphate limitation in industrial Cooperation with Shell on Zero Liquid Discharge Technology waste water plants. In addition, under this cooperative Shell is a new partner in our industrial water (reuse) framework, Diana Brandao, researched the potential programme with interest to optimize the Zero Liquid for upgrading Harnaschpolder effluent to high-quality Discharge (ZLD) technology and finding solutions for surface water, combatting salt water intrusion in the Produce Water in oil extraction wells. Basak Savun drafted Westland area. The latter research was part of the “Delft literature research reports in current ZLD technologies Blue Water” pilot project focusing on water reuse, and with focus on high quality salt production. In May 2015, in the long run, full scale effluent water reuse from the second phase of the project was started, focusing on the Harnaschpolder sewage treatment plant. The main the characterization of salt streams resulting from zero activity of “Delft Blue Water” was conducting research on liquid discharge systems in the petrochemical industry. demonstration scale which focused on the production of Within this project Niels van Linden is carrying out his two different water qualities: high quality ground water MSc research with emphasis on the dissolved sodium & surface water and high quality greenhouse water. For chloride recovery from brines for reuse purposes in a Zero this case and reuse studies, see: www.delftbluewater.nl Liquid Discharge system. framework of her internship, Alexandra Prodanescu Dunewater in the 21th century – Strategic cooperation Dunea Duin en Water – TUD in the field of drinking water research On 9 October 2013 Dunea drinking water company and the Faculty of Civil Engineering and Geosciences signed a 4-year contract for strategic cooperation in the field of of chlorine, on microbiological contamination. ▪▪ Preliminary research into the extension of the lifetime of the transport system “Afgedamde Maas”. drinking water research. In fact it is a continuation of the previous contract. The cooperation covers the period Dunea will contribute € 50,000 per year to support these 2013-2017 and focuses on four specific subjects: researches. ▪▪ ▪▪ ▪▪ The effect of advanced oxidation processes on managed aquifer recharge during the removal of Dunea Duin en Water produces and distributes drinking organic micro pollutants from drinking water. water for over 1.2 million customers in the province Zuid- Research into the effect of dune infiltration on the Holland. The dunes near Scheveningen, Katwijk and arsenic concentration, and research into methods Monster are the centre of Dunea’s treatment process, to reduce the increase during dune infiltration and which enable the production of safe and reliable drinking methods into removal of arsenic from drinking water. water. Surface water from the Afgedamde Maas is Research into the effect of flushing the drinking Dunea’s main water source. After pretreatment this water water distribution system, with and without the use is transported to the dune area and infiltrated. 33 Research Strategic programs Waternet and TU Delft investigate innovation in water cycle On May 27 2008 ir. Roelof Kruize, CEO of Waternet, has been assigned to perform these tasks by waterboard and prof.ir. Louis de Quelerij, dean of the faculty of Amstel, Gooi en Vecht and the city of Amsterdam. With Civil Engineering and Geosciences of TU Delft signed a Waternet’s ambition to shape the innovation in the water strategic collaboration contract. The collaboration focuses cycle and the expertise of TU Delft in the sectors of the on research in innovation in the water cycle, particularly water cycle, this collaboration is a logical next step. on the sectors drinking water, waste water and water systems. The duration of the collaboration was, in first instance, four years and still continues. The collaboration consists Waternet is the first water cycle company in the of MSc work of TU Delft students at Waternet, PhD Netherlands. Waternet takes care of the entire water cycle: research of employees of TU Delft and Waternet, post from drinking water, sewerage and treatment of waste doc research by employees of TU Delft at Waternet, water to discharge of waste water effluent into surface employees of Waternet doing their MSc (in part time) at water. Furthermore, maintenance of ditches, lakes and TU Delft and the use of the pilot installation at Leiduin as ponds, advice during high ground water levels and dike a “water cycle laboratory”. supervision are part of the tasks of Waternet. Waternet Strategic research collaboration HWL TU Delft cooperates closely with Het Waterlaboratorium Enduring relationship (an partnership Het Waterlaboratorium invests 50,000 euro’s in this agreement was signed on Thursday 11 March 2010 by partnership annually. TU Delft and Het Waterlaboratorium Marcel Tielemans, the director of Het Waterlaboratorium, were already partners, but on a smaller scale. Both parties and Prof. Louis de Quelerij, Dean of the Faculty of continue this successful cooperation on a systematic Civil Engineering and GeoSciences at TU Delft. Het basis. institute for water research). A Waterlaboratorium makes funding available totalling 50,000 euro’s for innovative research into the detection Het Waterlaboratorium and removal of organic micro-pollutants in the urban Het Waterlaboratorium specialises in high-quality advice water cycle. and research relating to water. The laboratory’s expertise is available for all those who want to achieve perfect Innovative research water quality. Its customers are companies that supply Cooperation brings benefits for both parties. Het drinking water, but also include hospitals and health Waterlaboratorium institutions, the off-shore sector, municipal government, benefits from easier access to knowledge and research at the university, while TU Delft gains access to the expertise of Het Waterlaboratorium in the field of detecting and identifying organic micropollutants. Research themes include the presence and behaviour of priority substances and emerging substances within the urban water cycle, the behaviour and selective removal of natural organic material, and the quality of water in distribution networks. This research is carried out both by staff at Het Waterlaboratorium and by students, PhD researchers and postdoc researchers. 34 businesses and sports institutions. Strategic programs Collaboration Oasen Water company and TU Delft Oasen water company and TU Delft collaborate in Oasen water company and TU Delft were already working research on drinking water engineering. Ir. Alexander together, on drinking water research for some years. Vos de Wael, CEO of Oasen water company, and Prof.ir. With this strategic collaboration both organisations aim Hans van Dijk, professor in Drinking Water Engineering to have a more structured research relationship. The at TU Delft, signed a collaboration agreement on June collaboration has advantages for both organisations. 30, 2008. Oasen water company has more access to knowledge and research at the university. TU Delft has the possibility Oasen Water company produces drinking water for to execute applied research on pilot locations close to 750,000 customers and 7,200 companies in the eastern Delft. Both organisations intend to do innovative research part of the province of South-Holland. The supply area on different aspects of the drinking water process. The has an surface area of 1,115 km2. The head office of research is carried out by employees of Oasen water Oasen water company is located in Gouda. company, PhD students and post docs from TU Delft. Bron: Digidaan 35 Research Strategic programs TISCA: Cooperation Programme Technology Innovation for Sewer Condition Assessment Sewer systems and wastewater transport systems are inspection technologies. In total 5 research projects have vital parts of the urban wastewater infrastructure. In been granted as part of the TISCA program, two of which the Netherlands, like in many other countries in Europe, have been granted to Jeroen Langeveld and one to Lisa over 90 % of the population is served by the urban Scholten. wastewater infrastructure. Managing these assets is one Lisa Scholten is responsible for the project SewerSense of the main challenges for the municipalities and water – Multi-sensor condition assessment for sewer asset boards that own and operate these systems. In order management. to further develop and optimize asset management for This project aims at four aspects of condition assessment: urban wastewater infrastructures, it is essential to have 1) data acquisition, 2) validation of inspection technology, sufficiently reliable information about the current status 3) a framework to assess the impacts of assessed sewer of the assets. condition and 4) prediction models. TU Delft and Leiden During the last decades, CCTV inspection has been the University will develop automated defect detection and main source of information for the assessment of the status classification diagnostics for CCTV and promising novel of gravity sewers. For rising mains, generally having less inspection techniques, such as laser profiling and stereo capabilities to enable easy access during operation, the vision camera’s. The framework will be adjusted to make development of dedicated (non-destructive) inspection a direct relation between condition assessment and techniques is still at an early stage of development. expected remaining service life. Recent research at Delft University has demonstrated Jeroen Langeveld is responsible for the projects FOULC: that the information obtained by CCTV inspections Fast Over-all scanning of Underground and Linear is associated with high uncertainties and that this Constructions and Geo-Electrical Sewer Leak Detection, information is by definition limited to failure mechanisms Quantification and Location. accompanied by visible damage within the pipe. In order The FOULC project aims at obtaining information on to overcome these limitations, other methods, such as some of the main functionalities of a sewer using non- core sampling, laser profiling, tilt meters, have been intrusive techniques. Several sensors will be positioned tested as part of the ‘Kennisprogramma Urban Drainage on a hoovercraft drone, that can move in partly filled (KPUD) at Delft University of Technology. In order to pipes. Information can be gathered in-situ to quantify the speed up the process of technology development for actual hydraulic capacity, the presence and the amount sewer inspection, the KPUD, RIONED and STOWA have of sediments and biofilm, detailed 3D information on the set up the TISCA programme in cooperation with STW. actual sewer geometry and information on the locations where and the amount of infiltrating groundwater. The The programme budget amounts to a maximum of € 3 development of this sensor platform is dedicated to sewer million. The financial resources for this programme come systems, but the application is not limited to sewers from Technology Foundation STW (€ 1,5 million), KPUD since it can also be applied for obtaining information on (€ 0,75 million), RIONED (€ 0,5 million) and STOWA (€ hydraulic capacity of and the presence of sediments in 0,25 million). ditches and canals. The researchers in TISCA will cooperate very closely with the researchers in the KPUD. Part of the programme are monthly TISCA days, which will comprise colloquia to exchange ideas and results, working sessions on specific topics, (in-)formal meetings with fellow PhD students and meetings with the user groups and user committees. The main focus of TISCA is on solutions for a coherent methodology for the (partly in-situ) condition assessment of sewers. Or, in other words, the next generation of sewer 36 Strategic programs The leak detection project addresses leakage, which is one of main causes of failures of pressure mains and the nightmare of sewer operators in areas where ground water is used as a source for drinking water production. Leaks occur due to ageing of our underground wastewater infrastructure, leakage of sewers and pressure mains and subsequent infiltration or exfiltration (I/E) is becoming an increasingly important issue. In order to be able to deal with leakage, sewer operators need to be able to detect, quantify and locate I/E. The project focusses on exploring the potential of geo-electrical monitoring: Self Potential monitoring and Electrical Resistivity Tomography in the soil and Focused Electrode Leak Location from within the sewer to detect, quantify and locate leaks. Dr. ir. J.G. Langeveld (Jeroen) Director Kennisprogramma Urban Drainage Associated professor Sewerage and Urban Drainage 37 Research Strategic programs PROPOPI Towards Pro-poor private investments in water supply in Kota Bandung PROPOPI is a project of the water company of Bandung ▪▪ PROPOPI leads to an enabling environment for PDAM in cooperation with, Vitens Evides International attracting B.V., Delft University of Technology and Simavi. The provision in Bandung. This means that all parts of the overall goal is to improve water supply (pro-poor access supply value chain are to generate positive returns and quality) in Bandung, Indonesia. The most important result will be the production and distribution of drinking (private) investors to water supply on investment. ▪▪ Social context: sense of ownership amongst poor water to an additional 35.000 people in Bandung, the consumers; sense of priority for improving pro building of 120 public stand posts serving 12.000 poor poor access among water utility staff and other people located in 12 currently inadequately supplied stakeholders; neighbourhoods. Result 4 Improvement of distribution and access Investments and in kind contributions are provided ▪▪ Implementation of DMAs by PDAM Kota Bandung, VEI, TU Delft and Simavi. ▪▪ Planning and construction of public stand posts (poor Further, the project is supported by a subsidy from the communities) Netherlands Enterprise Agency RVO through the ‘Fonds ▪▪ Training/capacity building Duurzaam Water’ (‘Sustainable Water Fund’). ▪▪ Plan and construct 45 km of new pipeline to The initial activities for the project started in 2015. The connect inadequately served neighbourhoods to the distribution network. project is intended to be completed by 31 December 2018. The project is devided in the following workpackages: ▪▪ ▪▪ Demonstrate how water utilities can create enough capacity to successfully mobilise private investments. Result 1 Inception Phase Quickscan existing situation with respect to treatment and distribution ▪▪ Business case: Lower non-revenue water levels by 20%. Dr. Ir. Rusnandi Garsadi Result 2 Improvement of production Dr. Ir. Bas Heijman ▪▪ Assessment WTP processes and operations ▪▪ Determine improvement actions, measures ▪▪ Investments for improvement ▪▪ Operation and maintenance systems and procedures ▪▪ Training/capacity building ▪▪ Water demand study ▪▪ Improvement and optimization of the water treatment plants at Badaksinga as design capacity 1000 & 800 l/sec , Total actual capacity 1500 l/sec, possibility improve to 2500 l/sec, by Micro Hydraulic Water Treatment technology (TU Delft – ITB), target capacity minimal 25% increasing. Result 3 Community awareness and participation ▪▪ Strategy on community awareness and participation ▪▪ Seminars/workshops with relevant institutional actors ▪▪ Preparation of information and education materials ▪▪ Training/workshops for facilitators ▪▪ Creating awareness and ownership as well as behavioural changes of (prospective) end users. 38 Strategic programs TU Delft en Turkije continueren samenwerking afvalwaterbehandeling De Turkse overheid stelt opnieuw beurzen beschikbaar Beurzen aan Turkse promovendi om aan de TU Delft onderzoek De drie promovendi kregen een beurs van de Turkse te verrichten naar afvalwaterbehandelingstechnologieën. overheid om aan de TU Delft onderzoek te verrichten. Dat gaf de Turkse ambassadeur in Nederland 21 Van Lier zet de belangrijkste resultaten op een rij. “Het oktober aan na afloop van een workshop over anaerobe onderzoek van Hale Özgün, richtte zich op de productie membraanbioreactoren bij de TU Delft waarbij drie Turkse van promovendi hun onderzoeksresultaten presenteerden. afvalwater. nutriëntenrijk Daarvoor irrigatiewater gebruikte uit zij huishoudelijk een anaerobe bioreactor met geïntegreerde membranen. De workshop bij de TU Delft is de voorlopige kroon op het Het voordeel van haar aanpak is dat er geen energie voor werk van drie Turkse promovendi die vier jaar geleden beluchting nodig is. Ook kun je met deze technologie de met het AMBROSIUS-project zijn gestart en die op 20 ziekteverwekkende organismen uit het afvalwater filteren oktober achter elkaar de doctorstitel behaalden. Professor om zo alleen waardevolle nutriënten voor irrigatie over Afvalwaterzuivering / Milieutechnologie Jules van Lier te houden.” van de TU Delft en promotor van de drie promovendi is hier vanaf de start bij betrokken. “Doel van het project Industrie was om kosteneffectieve oplossingen voor anaerobe De membraantechnologieën in kaart te brengen. Ook keken onderzocht samen met Biothane Veolia hoe diverse de promovendi naar de herbruikbaarheid van het effluent industriële afvalwaterstromen zich in een anaerobe in de industrie en in de landbouw voor irrigatie.” membraanbioreactor gedragen. Van Lier wijst erop tweede promovendus, Recep Kaan Dereli, V.l.n.r.: Prof İzzet Öztürk (ITU), Dr. Henri Spanjers, Dr. Evren Erşahin, Mr. Sadık Arslan (Turkish Ambassador in the Netherlands), Prof. Jules van Lier, Dr. Hale Özgün, Dr. Kaan Dereli, Prof. İsmail Koyuncu (ITU) 39 Research Strategic programs dat Biothane Veolia bezig is om deze technologie te Voortzetting vermarkten. “Zo staat er bij Mars in Veghel sinds twee Vijftig jaar een waterzuiveringsinstallatie die gebruik maakt van van bedrijven zoals Royal HaskoningDHV, Pentair en de anaerobe Memthane technologie. Biothane Veolia Nijhuis wilde vooral inzicht krijgen in hoeverre afvalwaterstromen van universiteiten uit binnen-en buitenland, volgden uit diverse industriële sectoren de bedrijfsvoering van met veel belangstelling de workshop waarin de drie zo’n waterzuiveringsinstallatie beïnvloedt.” promovendi genodigden, Water waaronder Technology, hun vertegenwoordigers evenals representanten onderzoeksresultaten toelichtten. De Turkse ambassadeur in Nederland, Sadik Arslan, Afvalwater gaf in zijn toespraak aan dat de Turkse overheid de Zo keek Recep Kaan Dereli onder meer naar het afvalwater samenwerking met de TU Delft graag wil continueren. van een bedrijf dat mais verwerkt om er vervolgens bio- Van Lier: “Inmiddels zijn er weer toptalenten van de energie van te maken. Van Lier benadrukt dat het afvalwater Istanbul Technical University geselecteerd voor een beurs dat bij het proces vrijkomt lastig is te behandelen met om aan de TU Delft onderzoek te verrichten. De eerste conventionele waterzuiveringstechnologieën. “Daarvoor promovendi komen binnenkort naar Nederland.” zijn meerdere zuiveringsstappen nodig die in de praktijk veel geld kosten. Het onderzoek van Recep Kaan Dereli heeft Biothane Veolia meer inzicht gegeven in de manier waarop het bedrijf zijn anaerobe membraanbioreactoren het beste kan instellen voor optimale zuiveringsresultaten van lastig te behandelen industriële afvalwaterstromen.” Textiel Mustafa Evren Ersahin, de derde promovendus, kwam er tijdens zijn onderzoek achter dat textiel met een laagje biomassa niet alleen veel goedkoper is, maar net zo effectief is als een kostbaar membraan. Van Lier: “Daarbij maakte hij gebruik van een speciaal soort textiel van Lampe Technical Textiles in Sneek. Hij slaagde erin om op het textiel een laagje biomassa te laten groeien dat in de praktijk net zo goed als een membraan werkt. Bovendien zijn er geen chemische coatings nodig.” Toepassing Van Lier wijst er op dat de Turkse overheid de resultaten van de promovendi in de praktijk gaat toepassen. “Een van de deelnemers aan de workshop is niet alleen hoogleraar aan een Turkse universiteit, maar werkt tevens voor het Turkse ministerie van Milieu. Hij gaf aan dat de overheid met de resultaten van Hale Özgun en Mustafa Evren Ersahin aan de slag gaat bij diverse communale waterzuiveringen.” 40 Awards Jaap van der Graaf award 2015/2016 Op 8 januari 2016 is tijdens de 68e Vakantiecursus ‘Water toegekend en bestaat uit een geldbedrag van 5.000 euro in de Stad’ van de afdeling Watermanagement van de en een glasobject. TU Delft de Jaap van der Graaf-prijs uitgereikt. De prijs wordt toegekend aan een student of onderzoeker die in Artikelen dienen te voldoen aan de volgende voorwaarden: het voorgaande jaar het beste Engelstalige artikel over de • het onderwerp betreft de stedelijke watercyclus stedelijke watercyclus schreef. (drinkwater, afvalwater en riolering) en draagt bij aan de Het winnende artikel van André Marques Arsénio en profilering van de Nederlandse expertise op dit gebied; mede-auteurs is gepubliceerd in het blad ‘Structure and • Infrastructure Engineering’ en is getiteld ‘Pipe failure of is werkzaam binnen de Nederlandse beroeps-praktijk; de auteur studeert aan een Nederlandse universiteit predictions in drinking water systems using satellite • observations’. werkzaam is binnen de Nederlandse beroepspraktijk, De jury beoordeelde in totaal 52 artikelen, waarvan geldt dat het onderzoek in Nederland moet hebben het niveau hoog was en erg dichtbij elkaar lag. Tijdens plaatsgevonden; de Vakantiecursus werden de drie genomineerden • en de winnaar bekendgemaakt. De jury heeft bij de peer reviewed tijdschrift; beoordeling vooral gelet op vijf criteria: maatschappelijke • bijdrage, innovatie, toepasbaarheid op korte/middellange De onafhankelijke jury bestond dit jaar uit prof.dr.ir. termijn, wetenschap en taal. De artikelen die door twee Jules van Lier (TU Delft/Unesco-IHE, voorzitter), prof. of meer juryleden in de top 10 genoemd waren, zijn dr.ir. Gertjan Medema (TU Delft/KWR Water), dr.ir. opnieuw bekeken. De jury koos het artikel van Arsénio Jelle Roorda (Evides), dr.ir. Jasper Verberk (Evides), ir. als winnaar, met name gezien de maatschappelijke Ad de Man (Waterschapsbedrijf Limburg), ir. Fred de relevantie van leidingonderhoud en het voorspellen van Bruijn (Witteveen+Bos), dr.ir. Arjen van Nieuwenhuijzen leidingbreuken. De jury identificeert het vervangen van (Witteveen+Bos), en dr.ir. Hardy Temmink (WUR/ (drinkwater)leidingen als dé opgave van de komende Wetsus). indien de auteur ten tijde van publicatie niet (meer) het Engelstalige artikel is in 2015 gepubliceerd in een het onderwerp is in de praktijk toepasbaar. decennia. Daarbij zijn de resultaten simpel te vertalen naar onderhoud van andere leidingnetwerken, zoals gasleidingen of rioolsystemen. Arsénio heeft zijn MSc behaald in Biological Engineering aan het Instituto Superior Técnico (Lisboa, Portugal) en promoveerde aan de TU Delft, sectie Sanitary engineering in 2013 (proefschrift getiteld ‘Lifetime prediction of PVC push-fit joints’). Sinds 2014 is hij verbonden aan de TU Delft als post-doc binnen het project ‘Sustainable freshwater supply in Maputo, Mozambique’ een vijf jaar durend project gefinancierd door NWO en WOTRO in het kader van het overkoepelende project Urbanizing Deltas of the World’. De Jaap van der Graaf-prijs is op initiatief van ingenieursen adviesbureau Witteveen+Bos ingesteld in 2009 toen Van der Graaf terugtrad als hoogleraar in de Behandeling van Afvalwater aan de TU Delft. Jaap van der Graaf was van 1988 tot 2003 algemeen directeur van het ingenieursbureau uit Deventer. De prijs wordt jaarlijks 41 Research Awards Vidi for Merle de Kreuk: the effects of suspended solids on granular sludge NWO has awarded 800,000 euros to ten TU Delft This meant that, in theory, there was an alternative for researchers. They include Merle de Kreuk and her the large sedimentation basins required for conventional research into the effects of suspended solids on granular sewage purification plants, in which the bacteria grow in sludge. Vidis are awarded to experienced researchers flocs that do not settle so readily. However, managing who have conducted a number of years of successful a process in a small 3-litre reactor in a laboratory is research after receiving their PhD. Vidi grants enable one thing; converting it into an effective, profitable researchers to conduct five years of research and develop type of sewage purification plant is quite another. It is their own, innovative research lines. a classic feat of engineering: developing and upscaling a technically rational invention into an installation that Merle on this subject: ‘I want to see and comprehend what works in practice and can be applied, preferably in an bacteria do to the colloidal fraction and decomposable economically sustainable way, with effluent that is slightly particles in granular systems, in (an)aerobic processes. I cleaner and with a view to wider social acceptance. want to unravel the granules and their components - cells, polymers, enzymes. If fundamental research enables you This challenge, the process from invention to practical to understand exactly what is going on, the opportunity application, turned out to be something De Kreuk was cut exists that you may be able to devise different, smarter out to do. ‘I did environmental hygiene at Wageningen processes.’ University and after graduating I immediately started a job at IHC Holland. I was the only woman in the shipyard. Elected Simon Stevin Fellow, finalist for the European I advanced quite quickly up the career ladder but always Inventor Award, awarded the Jaap van der Graaf Prize... felt that I really wanted to do research and take my PhD. Before the awarding of the Vidi Merle de Kreuk had In 2000, I came into contact with Mark van Loosdrecht already been honoured for her prior work on the Nereda (Professor of environmental biotechnology) when he waste water treatment system. This technology enables was looking for someone who could work out the proof the treatment of domestic waste water using 25% less of principle for the aerobic granular sludge reactor. It energy and taking up 75% less space. really appealed to me: the chance to put something into practice.’ The fact that aerobic bacteria (‘requiring oxygen’) are able to convert the carbon and nitrates from sewage water into CO2 and nitrogen gas and that these bacteria can grow in granules, making it easier to separate biomass from the purified water, had already been proven in the laboratory. 42 Awards Cees Boeter Prijs 2016 Ook dit jaar is de Cees Boeter prijs weer uitgereikt voor Het Bachelor Eind Project wat er voor de jury boven het beste BSc eindwerk. uitstak had een zeer sterke wiskundige basis, een De Cees Boeter prijs voor het beste BSc eindwerk op indrukwekkende hoeveelheid gegevens, en dat allemaal het gebied van Watermanagement is ingesteld door zeer goed opgeschreven in het Engels. De student die dit de afdeling Watermanagement van de faculteit Civiele project heeft afgerond is Luc Koppens, en hij is dan ook Techniek en Geowetenschappen van de TU Delft en heeft de winnaar van de Cees Boeter Prijs 2016! een tweeledig doel: ▪▪ Het stimuleren van studenten tot het leveren van prestaties van hoog academisch niveau. ▪▪ Daar waar mogelijk het bevorderen van de toepassing van de resultaten van de eindwerken in de beroepspraktijk Criteria voor het beoordelen van de eindwerken zijn de breedte en diepgang van het werk, de originaliteit, de bruikbaarheid van de resultaten en het niveau van de rapportage en presentatie. Aan de “Cees Boeter Prijs” is een geldbedrag verbonden van €250,00. Genomineerden voor 2016 Dit jaar waren er vier genomineerden: • Cömert en Niek van de Koppel werkten aan een project rond moisture recycling in China en Australië. • Koppens rondde een project over bodemvocht succesvol af. • Bouhnouf heeft het grondwater in Delft aangepakt. Alle studenten hebben blijk gegeven van inzicht in de materie die ze bestudeerd hebben. Verder hebben ze allemaal theorie en toepassing weten te koppelen, en hebben ze het goed en toegankelijk op weten te schrijven. 43 Research Awards Gijs Oskam Award 2016 Marij Zwart, werkzaam bij Evides, won de Gijs Oskam prijs met haar scriptie over energie uit afvalwater. Voor de Gijs Oskam prijs komen jonge ademici in aanmerking recent zijn afgestudeerd op het gebied van de Stedelijke Watercyclus. De aanmoedigingsprijs van 2500 euro moet jonge onderzoekers/ingenieurs een extra stimulans geven. The Best Thesis of Istanbul Technical University” of 2015 The thesis of Hale Özgün, Anaerobic Membrane Bioreactors for Cost-Effective Municipal Water Reuse, was selected in Turkye as the best Thesis of 2015 of the Istanbul Technical University Prof. J.P. van der Hoek appointed as Pricipal Investigator at AMS -Postdoc position available for 1 year In September 2016 the board of the Amsterdam Institute As AMS Principle Investigator he received a TU Delft for Advanced Metropolitan Solutions (AMS) has appointed strategic Professor Jan Peter van der Hoek as Principal Investigator “Integration and optimization of water, energy and for a period of two years. material flows to achieve sustainable urban solutions”. AMS is the institute in Amsterdam, founded in 2014 and The fellowship consists of the salary costs for one post- supported by the City of Amsterdam, in which Technische doctoral researcher for one year, starting as soon as Universiteit Delft, Wageningen University Research and possible, complemented with a budget for travel costs. Massachusetts Institute of Technology, together with partners from the public and private sector, work on three specific themes: Circular City – Vital City – Connected City. 44 research support grant for the project Annual report 2016 Individual Projects 45 Individual Projects Annelies Aarts Uncertainty of phenomenological models applied to full scale wastewater treatment filters Research objectives was well presented by Gaussian copula (Kurowicka and The aim of the research is to identify and quantify sources Cooke, 2004), the BN was used for sensitivity analysis. of uncertainty of phenomenological models when applied to Nodes that contributed most to uncertainty, i.e. nodes full scale wastewater treatment systems in order to evaluate that were strongest correlated to the model fit errors, reliable use of the models for optimization projects. were identified. Project outline Results Introduction The most important result was that the model of Iwasaki Many phenomenological models were developed to et al. (1937) described well the solids removal process. describe particle deposition and head loss in deep bed The main part of model output uncertainty was found filters. However, few filter optimization studies were to be measurement uncertainty. Only during (heavy) published that include these models. An important rain events, higher uncertainty was calculated. Here, reason might be that authors claimed that simplified the solids and phosphate concentration of the secondary phenomenological models such as the solids removal effluent that entered the tertiary treatment filter, and the models proposed by Iwasaki et al. (1937) and the head dosage of coagulants were identified as contributing most loss models developed by Carman (1937) and Mays to model output uncertainty. and Hunt (2005) are not able to describe the full scale The uncertainty of the hydraulic models of Carman (1937) filtration installations. and Mays and Hunt (2005) was higher, especially for Therefore, the aim of this study was to investigate the subdatasets where coagulants were used. As parameter uncertainty models uncertainty was found to contribute to uncertainty despite applied to deep bed filters of a tertiary treatment system. the local calibration scheme, calibration in windows of simplified phenomenological smaller than three hours should decrease model output Approach uncertainty. Sources of model structure uncertainty were First, the models of Iwasaki et al. (1937), Carman (1937) mainly found in the solids concentration of the secondary and Mays and Hunt (2005) were used to model solids effluent, water temperature and the flow itself. removal and decrease of flow rate of a variable declining rate filtration installation. The models were calibrated Scientific relevance within windows of three hours based on full scale data This work contributes to correct understanding and from the wastewater treatment plant of Harderwijk. After interpretation of the uncertainty of well-known filtration calibration, the model fit error which is the difference models by using founded mathematical methods such as between the modelled output and the measured Bayesian Networks. value, was calculated. The errors quantified the output uncertainty of the phenomenological models. Social relevance Correct interpretation of model uncertainty allows using Second, the marginal distribution of the model fit errors, the calibration parameters and the operational variables was calculated. A joint distribution was constructed from the included marginal distributions. As such, a Bayesian Network (BN) was built. Such network connects the variables, parameters and model fit errors as nodes to each other and contains information about (conditional) rank correlations between the nodes of the network. Third, after validation of the assumption that the BN 46 models to optimize wastewater treatment technologies. Annelies Aarts Literature Carman, P. 1937. Fluid flow through granular beds. Chem Eng Res Des, 75:32–48. Cooke, R. M., Kurowicka, D., Hanea, A. M., Morales, O., Ababei, D. A., Ale, B., and Roelen, A. 2007. Continuous/discrete non parametric Bayesian belief nets with unicorn and Uninet. Iwasaki, T., J. J. Slade, J., and Stanley, W. E. 1937. Some notes on sand filtration. American Water Works Association, 29(10):1591–1602. Mays, D. and Hunt, J. 2005. Hydrodynamic aspects of particle clogging in porous media. Environmental Science and Technology, 39(2):577– 584. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Figure 1. Example of a Bayesian Network with all nodes connected to each other Start date project: Jun 2010 Expected end date: 2017 Key words: Models, uncertainty, wastewater Cooperation with other institutes: BWA/Brightworks, Grontmij, Visser&Smith Hanab, Waterschape Veluwe, Waterschap de Dommel 47 Individual Projects Jawairia Imtiaz Ahmad Biostability in Drinking water distribution networks (DWDN) during and after Thermal Energy Recovery Research objectives Scientific relevance The aim of the current research is to determine the The impacts of thermal energy recovery on microbiological distribution network vulnerable quality and biostability of drinking water in distribution bacterial communities. Theimpact may also be the network. The study will also focus on determining opposite for some microbes which cannot compete at the maximum allowable temperature change without high temperatures. This is one of the questions to be compromising the biostability and microbiological quality solved: TER either will enhance the growth of microbial after thermal energy recovery (TER). communities in the system or it will increase the microbial thermal energy recovery might make the for growth of some quality of drinking water in DWDN. The current study is Project outline trying to fill this knowledge gap in field of drinking water Introduction supplies and biostability of water. Climate Change is happening and it results into temperature changes globally and also at regional and local levels. It Social relevance is also impacting the water bodies, as reported in the Reducing carbon emissions is the human responsibility IPCC AR5. It is strongly agreed that fresh water resources to save earth from climate change. The supply of safe will be negatively impacted by climate change, resulting and wholesome drinking water to masses of population in reduced water quality. These risks will occur due to is also the core responsibility of drinking water utilities. increased temperature, sediment and nutrient load due to This research is trying to correlate/link both goals by heavy rainfalls, which cause malfunctioning of treatment extracting the TER from DWDN under the condition plants (Cisneros et al. 2014). But every threat comes which cannot compromise biostability and microbiological with an opportunity. In the same manner the water sector quality of the drinking water. has a huge potential to contribute in lessening the impacts of climate change by reducing CO2 emissions from its Literature processes. Because water contains a lot of energy, both Douterelo, I., Sharpe, R.L. & Boxall, J.B. (2013). Influence thermal and chemical energy, recovery of this energy and of hydraulic regimes on bacterial community structure using it as an alternative for fossil fuel will reduce CO2 and composition in an experimental drinking water emissions (Van der Hoek 2012). But the changes in water distribution system. Water Res. 47, 503-516. temperature may effect the microbiological, physical and Elias-Maxil chemical properties of water during distribution ( McNeill L.(2014). Energy in the urban water cycle: Actions to & Edward, 2002). It was highly observed that frequency reduce the total expenditure of fossil fuels with emphasis abundance of many dominant phyla in DWDN increased in on heat reclamation from urban water. Renewable and summer and in extreme winter conditions. Apart from this sustainable energy reviews 30: 808-820. some opportunistic pathogens do exist in DWDN under Frijns, J., Hofman, J., and Nederlof, M. (2013). The favourable temperature conditions above 25oC (Pinto et potential of (waste)water as energy carrier. Energy al. 2014; Chakhtoura et al. 2015; Hammes et al. 2010). conversion and Management. 65, 357-363. JA, Van der Hoek JP, Hofman J, Rietveld J. El-Chakhtoura, E.I. Prest, P. Saikaly, M.C.M. van Approach The current study Loosdrecht, F. Hammes, J.S. Vrouwenvelder (2015). is carried out both at bench scale Dynamics of bacterial communities before and after and full scale distribution networks with a thermal distribution in a full-scale drinking water network. Water energy recovery system to evaluate the impacts of TER Research 74, 180-190. on biostability and microbiological water quality under Microbial growth in Drinking-water supplies; problems, different process regimes. causes, control and research needs. 2014 IWA Publishing. Edited by Van der Kooij D & Van der Wielen P W J.J. 2014. 48 Jawairia Imtiaz Ahmad Van der Hoek JP. (2012). Towards a Climate neutral water cycle. Journal of Water and Climate Change. Van der Hoek, JP. (2011). Energy from the water cycle: a promising combination to operate climate neutral. Water Science and Technology, 6(2):1–2. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: May 2015 Expected end date: May 2019 Key words: Thermal energy recovery, Drinking water distribution network, Biostability, Microbial water quality Cooperation with other institutes: Waternet, TKI 49 Individual Projects Lina Bachert Review of virus reduction by metals and nanometals for water treatment Research objectives (dataset). One dataset described one virus applied with The main objective of this study was to review one metal application (Figure 1). publications addressing reduction of human pathogenic viruses and/ or bacteriophages in water by metals alone with major focus on silver and copper and in combination with disinfectants. Project outline Introduction Approximately 1.7 million cases including 760,000 child deaths under the age of five years and a significant number of illnesses annually are primarily attributed to diarrheal diseases due to poor hygiene and inadequate access to safe and clean drinking water and sanitation facilities [1, 2]. Waterborne viruses, such as rotavirus and hepatitis E virus (HEV) are major agents of diarrheal diseases and are persistent for long periods in the aquatic environment [3, 4]. To address this health risk, household water treatment and safe storage (HWTSS) systems may improve and protect drinking water quality from enteric viruses and contribute to the reduction of diarrheal disease transmission. Numerous HWTSS systems include conventional disinfection methods such as UV light and chlorine, however, some enteric viruses are highly resistant and thereby not effectively inactivated by conventional disinfectants alone [5, 6]. Metals such as silver and copper have emerged in water disinfection applications for their antiviral effects. Significant interest has also arisen in the use of metal nanoparticles. In combination with other existing technologies such as UV light or membranes, metals and metal nanoparticles have been demonstrating strong synergistic effects to enhance disinfection [7-9]. Approach and results A systematic literature search was performed for Figure 1. Distribution of datasets on applications of (A) silver and (B) copper in function of virus species (white=pathogenic viruses, gray=bacteriophages; dotted=filters and/or mebranes, grid=nanoparticles, upward diagnol=ions, vertical=surfaces, dashed horizontal=coagulants) publications addressing the primary outcome of virus Scientific relevance reduction by metals in water by combined disinfection This review demonstrated that silver and copper have a treatments. Publications were searched with relevant potential as alternative disinfectants in water treatment, search terms that combined selected viral pathogens mainly in combination with other disinfectants, e.g. in and terms describing process selections. The systematic multi-barrier approach. The individual use of the metal literature search identified 1,375 publications based on ions and nanoparticles apparently showed minor antiviral the search terms. Application of specified selection criteria activities for water treatment compared to conventional yielded 69 publications from which data were extracted disinfectants. The most efficient applications of silver 50 Lina Bachert as an alternative disinfectant were in combination with irradiation and immobilized in structures and membranes. Copper in conjunction with conventional disinfectants such as hydrogen peroxide showed enhanced disinfection efficacy in many publications. Social relevance This review demonstrated that pathogenic virus studies are needed which display true viral reduction. For example, rotavirus, HEV, and norovirus are of utmost concern in developing countries. No publication was found that included HEV or norovirus against metals and nanometals. Only a few datasets were obtained for rotavirus. Effective technologies for household water treatment and safe storage (HWTSS) systems improve and protect water quality from fecal contamination and contribute to the reduction of diarrheal disease transmission. The WHO estimates that 6-90% of diarrheal diseases can be prevented by using HWTSS systems for the production of safe and clean drinking water depending on the technology, exposed population and local conditions [10]. Literature World Health Organization. Diarrhoeal disease. 2013 [cited 2014 November 26, 2014]; Available from: http://www.who.int/mediacentre/factsheets/fs330/en/. United Nations Children’s Fund, Pneumonia and diarrhoea: Tackling the deadliest diseases for the world’s poorest children. 2012, UNICEF: New York, NY. Lopes-João, A., et al., Multiple enteropathogenic viruses in a gastroenteritis outbreak in a military exercise of the Portuguese Army. Journal of Clinical Virology, 2015. 68: p. 73-75. Rodríguez-Lázaro, D., et al., Virus hazards from food, water and other contaminated environments. FEMS Microbiology Reviews, 2012. 36(4): p. 786814. Hijnen, W.A.M., E.F. Beerendonk, and G.J. Medema, Inactivation credit of UV radiation for viruses, bacteria and protozoan (oo)cysts in water: A review. Water Research, 2006. 40(1): p. 3-22. Au, K.-K., Water treatment and pathogen control: Process efficiency in achieving safe drinking-water. 2004: IWA Publishing. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jan 2012 Expected end date: 2017 Key words: Ag, Cu nanoparticles, ions, UV, antiviral effect, enteric viruses Cooperation with other institutes: RIVM Bilthoven, Wetsus Leeuwarden Butkus, M.A., et al., Use of aqueous silver to enhance inactivation of coliphage MS-2 by UV disinfection. Applied and Environmental Microbiology, 2004. 70(5): p. 2848-2853. Zodrow, K., et al., Polysulfone ultrafiltration membranes impregnated with silver nanoparticles show improved biofouling resistance and virus removal. Water Research, 2009. 43(3): p. 715-723. Kim, J.Y., et al., Enhanced inactivation of E. coli and MS-2 phage by silver ions combined with UV-A and visible light irradiation. Water Research, 2008. 42(12): p. 356-362. World Health Organization. Household water treatment and safe storage Treatment technologies. 2015 [cited 2015 October 9, 2015]; Available from: http://www.who.int/household_water/research/technologies_intro/en/. 51 Individual Projects Yasmina Bennani Electrochemically active biofilm Research objectives Approach Heterogeneous photocatalysis is a well understood and TiO2 film electrodes were manufactured according to highly investigated topic, and despite its promising results the paint-thermal decomposition method [3]. Impact on in water decontamination, its practical exploitation has phenol degradation of progressing biofilm growth on the been restricted by its low photonic efficiency, which anode was studied. This was done by first evaluating the is mainly due to recombination of the e−/h+ pair. degradation by the individual processes: biodegradation, In order to decrease the recombination limitation of photolysis and photo(electro)catalysis. Subsequently, photogenerated charge carriers and to enhance the various combinations of these processes were investigated quantum efficiency of the immobilised photocatalyst, few with respect to the mineralization of phenol. Every approaches were adopted in this study (figure 1). Building mentioned process was evaluated by the rate of phenol upon the knowledge gained in the previous research, the degradation and the extent of enhancement driven by objective of this research was to bring insight into the either applied potential, E or attached bacteria in biofilm. coupled system, bio-photoelectrocatalysis, as well as to assess and demonstrate the efficiency for decreasing Results and conclusions the electron/hole recommbination. The role of biofilm growth (6, 12, 20 and 40 days) and the extent of its coverage on the anode surface was studied, in relation to enhanced degradation kinetics of phenol in a batchscale photoelectrocatalytic reactor. An anode with a fully developed biofilm (FDB) was compared with an electrode without biofilm coverage in separate systems. Figure 2. SEM image (20 kV, 50 µm, x 400) mixed culture of bacteria cells Figure 1. Approaches for enhancing PEC efficiency and scaling up of the technology Project outline Introduction Microorganisms as bio-catalysts are used in bioelectrochemical systems. The major role of microorganisms is to generate electrons through substrate metabolism and to help mediate the electron transfer to the anode, functioning as a catalyst [1]. TiO2 coated on the Ti offers rich abundance, low cost, nontoxicity, chemical stability and good electron transfer [2, 3]. In addition, the use of solar light with a non-doped simple, TiO2/Ti composite electrode, e.g., prepared with the paint-thermal method, Figure 3. Phenol degradation by photolysis (◊); biodegradation (x); photocatalysis (□); photoelectrocatalysis (Δ); bio-photocatalysis with a biofilm developed after 20 days (ж) and bio-photoelectrocatalysis with a biofilm developed after 20 days (ᴏ) would avoid drawbacks such as thermal instability (metal centres acting as electron traps), which reduces the photocatalytic efficiency, and would be less expensive [2]. ▪▪ An electrochemically active biofilm (figure 2) on the TiO2/Ti composite electrode was found to increase the current density (8.4x10-2 mAcm-2) and charge transfer (lower impedance) and phenol degradation 52 Yasmina Bennani efficiency, confirming that electron transfer can be enhanced by biofilm formation on the electrode. ▪▪ A positive effect in phenol degradation efficiency (62% after 4 hours) was observed by coupling photo(electro)catalysis and biofilm formation into one system (figure 3). ▪▪ The degradation efficiency of phenol was far higher in the biofilmelectrode process than in the photocatalytic (23.2%) and biological processes (2.3%) within the same degradation time (four hours). ▪▪ Impedance related to biofilm was sensitive to the duration of biofilm growth (thickness) and it reached its lowest value at the optimal amount of bacteria coverage on the electrode (electrochemically active biofilm developed for 20 days). ▪▪ Impedance related to biofilm was sensitive to the duration of biofilm growth (thickness) and it reached its lowest value at the optimal amount (20 days growth period) of bacteria coverage on the electrode. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Scientific relevance A promising approach for water treatment and the removal of toxic organics is thus to combine characteristics from AOP with biodegradation. By understanding the phenomena, optimal combinations can be found and innovative, efficient and cost effective technologies can be developed. In this research the residence time for sufficient phenol removal could be diminished by a factor 2. Societal relevance Photoelectrocatalysis is a relatively cheap green technology. It does not generate secondary waste nor involve the use of additional chemicals, and offers improved beneficial uses of produced water. It can generate and store energy, use renewable energy source (solar light), remove Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Oct 2011 Expected end date: 2017 Key words: TiO2, photoelectrocatalysis, enhancement, photodegradation organics, produce clean water and recover valuable materials from produced water with little or no negative impact on the environment. Literature [1] B. Erable, N. M. Duţeanu, M. M. Ghangrekar, C. Dumas, K. Scott, Application of electro-active biofilms, Biofouling 26 (2010) 57. [2] M. M. Khan, S. A. Ansari, J. Lee, J. Lee, M. H. Cho, Mixed Culture Electrochemically Active Biofilms and their Microscopic and Spectroelectrochemical Studies, ACS Sustain. Chem. Eng. 2 (2014) 423. [3] X. D. Benetton, S.G. Navarro-Ávila, C. Carrera-Figueiras, Electrochemical Evaluation of Ti/TiO2-polyaniline Anodes for Microbial Fuel Cells using Hypersaline Microbial Consortia for Syntheticwastewater Treatment, J. New Mater. Electrochem. Syst. 13 (2010). [4] A. Nickehslat, M. M. Amin, H. Izanloo, A, Fatehizadeh, S. M. Mousavi, Phenol photocatalytic degradation by advanced oxidation process under ultraviolet radiation using titanium dioxide, J. Environ. Public Health 2013 (2013) 9. 53 Individual projects Irene Caltran Organic Matter removal from surface waters: Separation of Dissolved Organic Carbon and ions from Ion Exchange brine using Ceramic Nano Filtration Research objectives • This research aims to: concentrate for other uses, for instance for agricultural • purposes Make an inventory of the state of the art for Organic Separate salts from OM, in order to recover the OM Matter removal from drinking water • Test and upscale Nano Filtration ceramic membranes in order to treat Organic Matter rich brine Approach The current techniques for OM removal and their combinations will be inventoried, with particular attention Project outline to the drinking water companies in the European Two Introduction Channels region. The inventory will include the approach Organic Matter (OM) is usually present in surface water. used by different water companies and their experienced OM is not only the cause of odor and color problems in challenges. Both literature research and questionnaires drinking water. It is also responsible for the majority of the are used for this purpose. demand for coagulants and disinfectants, the competition IEX is a promising OM removal technique and the disposal with removal of other compounds, membrane fouling, of the brine produced is challenging its use. To address biological instability and bacterial growth and formation this problem, separation between ions (Cl- , NO3- and of disinfection by-products (DBPs) (Matilainen and SO42-) and OM by ALD Ceramic Nano Filtration will be Sillanpää, 2010). investigated. Both artificial water with single compounds In locations where fresh ground water is scarce, the and IEX brine from a drinking water treatment plant will removal of OM from surface waters is one of the main be used. challenges of drinking water companies. Therefore, many companies are performing experimental work about Scientific this subject. DOC2C’s is a joint project of different West The work will contribute to understand the different relevance European drinking water companies and universities and approaches used to remove Organic Matter and can be a has the aim to improve the OM removal processes with basis for the choice of the most suitable Organic Matter research and mutual collaboration. treatment technique(s) in a specific situation. One of the technologies for OM removal is Ion Exchange Moreover, a performance study of the innovative (IEX). The resin used during IEX has to be periodically Nano Filtration ceramic membrane with Atomic Layer regenerated. From the regeneration process, there is Deposition will be provided. production of brine containing salts, OM and other ions. The disposal and the treatment of the brine can be a Social relevance limiting factor for the use of IEX at a large scale (Verdickt, The inventory and the integration of the experimental 2012). work of different companies and institution can facilitate Several approaches are studied in order to reduce the the optimization of the efforts for research on Organic amount of brine to be disposed and in order to recover Matter. resources present in the IEX brine, such as water, salt Further, studies on brine treatment using ceramic Nano and OM. Filtration will contribute to waste reduction and resource TU Delft is developing Ceramic Nano Filtration membranes recovery in the drinking water sector. (CNF), coated by Atomic Layer Deposition (ALD). The membranes will be studied in order to be applied to the IEX brine with the objective to: • Separate the regeneration salt (e.g. NaCl) from OM and the other ions (e.g. NO3-, SO42-), in order to reuse the recovered salty water in the regeneration process 54 Irene Caltran Literature Matilainen, A., & Sillanpää, M. (2010). Removal of natural organic matter from drinking water by advanced oxidation processes. Chemosphere, 80(4), 351-365. Verdickt, L. (2012). Verwijdering van NOM door middel van ionenwisseling. Report Vlaamse Maatschappij voor Water Voorziening. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: 0652473226 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Apr 2016 Expected end date: Apr 2020 Cooperation with other institutes: PWNT, South West Water, De Watergroup, University of Lille 55 Individual projects Pamela Ceron Chafla Steering Product Formation in High-Pressure Digestion Systems Research objectives Approach The aim of the project is to produce high-value bulk The research will focus in the development of a suitable products from low-grade biomass through further HPD technology for production of high-value bulk research on product steering in High Pressure Digestion products using undefined mixed cultures. The feasibility reactors which will include optimization of process of treating simple and complex substrates, mechanisms conditions and reactor design, as well as alternatives for for controlling the product spectrum as well as the feasible and cost-effective downstream processing. requirements for process optimization, reactor design and alternatives for downstream processing will be Project outline studied along the project. Introduction Anaerobic Digestion is a widely used and advantageous Scientific relevance technology for wastewater treatment, since besides HPD has been proposed as a cost-effective technology for organic material degradation, biogas is produced (Van Lier direct biogas upgrading. However, its possible use inside et al. 2008). Using conventional technology and process the “carboxylate platform” remains as an unexploited conditions, the methane content reaches 50-75% (IEA field of study. The forthcoming results of this research will Bioenergy 2009). This, plus a high CO2, NH3, H2S and provide insights into establishing HPD as an innovative water content make the obtained biogas not suitable for and cost-effective resource recovery technology focused natural gas grid direct injection, so upgrading systems are on viable bioproducts. required. Previous proof-of-principle research work has demonstrated the feasibility of using Autogenerative High Social relevance Pressure Anaerobic Digestion (AHPD) to produce biogas Increased waste production is a direct consequence with improved quality (90-95% methane content) and at a of population growth, so alternatives to sustainably pressure suitable for high grade use (Lindeboom 2014a). reduce/treat them are required. Wastewater treatment Furthermore, AHPD has also proved to produce other has traditionally been seen as an expenditure and metabolites (carboxylates), that by themselves or through an environmental compliance requirement. However, further conversion, could be of interest for the chemical using an innovative technological approach focused on industry (Lindeboom 2014b). New insights into waste to resource recovery, this perspective about wastewater and bioproduct conversion have been established and it has its treatment can be significantly changed. This research been demonstrated that interesting and economically- project aims that inside the context of a biobased attractive end-products can be obtained with undefined economy, wastewater can become an innovative source mixed cultures dealing with complex substrates (Agler et of organic “feedstocks” for the carboxylate platform. al. 2011). In this context, High Pressure Digestion (HPD) offers some interesting features. Based on previous work, it is expected that specific pressure effects influence the kinetics of mixed culture fermentations (e.g. role of the CO2 partial pressure). This project aims to further address these effects and determine to what extent they can be exploited to improve the production yield or increase the selectivity once optimized process conditions are achieved regarding substrate, inoculum and operational parameters. 56 Pamela Ceron Chafla Literature Agler, M.T. et al., 2011. Waste to bioproduct conversion with undefined mixed cultures: the carboxylate platform. Trends in Biotechnology, 29(2), pp.70–78. IEA Bioenergy, 2009. Biogas upgrading technologies – developments and innovations, Van Lier, J.B., Mahmoud, N. & Zeeman, G., 2008. Anaerobic Wastewater Treatment. In Biological Wastewater Treatment: Principles, Modelling and Design. pp. 401–442. Lindeboom, R.E.F., 2014a. Autogenerative High Pressure Digestion: Biogas production and upgrading in a single step. Wageningen University. Lindeboom, R.E.F., 2014b. Piezo-tolerant natural gas-producing microbes under accumulating pCO2. In Autogenerative High Pressure Digestion: Biogas production and upgrading in a single step. pp. 98–127. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Oct 2016 Expected end date: Oct 2020 Key words: High Pressure, Anaerobic Digestion, Carboxylates Production, Resource Recovery, Undefined Mixed cultures Cooperation with other institutes: Ghent University (Belgium), Paques 57 Individual Projects Elena Cristiano Effects of high spatial and temporal resolution of rainfall data on hydrological response in lowland urban catchment Research objectives Two different approaches, a theoretical and a numerical This research aims to study the effects of combinations one, will be developed to study the hydrological processes of different spatial and temporal resolutions on urban in the urban catchment. models, considering the influence that catchment and storm’s characteristics (such as drainage area, slope, Results imperviousness, rainfall intensity, duration and velocity) The study developed until now confirms a higher have on the hydrological response. sensitivity of the hydrological response to the temporal resolution than to the spatial resolution and shows In particular this study aims to investigate the hydrological that some characteristics of the storm, as velocity and processes of urban catchments located in lowland areas, intermittency of the peaks, have a strong influence on the where the slope is nearly absent and the flow is by gravity. sensitivity of the model. Project outline Scientific relevance Introduction In the last years new instruments and techniques have Flooding in urban areas is one of the main weather- been developed to measure rainfall with high spatial and related risk problems of the last decades. The increase of temporal resolution (e.g. weather radars, microwave urbanization produces a fast and short in time response links, etc.), but the sensitivity of the hydrological response to the heavy rainfall that characterize the climate to these data in urban areas has not been studied yet. changing of the last years. On top of that, the increase In particular, the response in a lowland area, still needs of the density of the population in the city makes these further investigations. areas more vulnerable to flood events. Social relevance Due to the lack of slope, in lowland urban areas it is more This study aims to better understand the behavior of the complex to estimate the amount and the direction of runoff in urban lowland areas, in order to estimate possible runoff. This scenario is typical in the Netherlands, where flooding during rainfall events. A better knowledge of the the looped drainage system, characterized by pumps runoff helps to choose the best solutions to apply in order and weirs, allows the flow to choose different paths, to reduce the flooding risk in urban area. depending on the characteristic of the rainfall event. Approach Considering the fast response and the relative small dimensions of the urban catchments, high temporal and spatial resolution rainfall data are required as input (Berne et al.,2004). Previous researches have studied the sensitivity of different spatial and temporal resolutions on urban catchments, highlighting correlations between the rainfall resolution and the model scales (Bruni et al., 2015, Ochoa-Rodriguez et al., 2015). In this study rainfall data from a dual polarimetric X-band weather radar with a resolution of 1min and 100x100m are used to study different districts of Rotterdam (NL). 58 Elena Cristiano Literature Berne, A., Delrieu, G., Creutin, J.-D., & Obled, C. (2004). Temporal and spatial resolution of rainfall measurements required for urban hydrology. Journal of Hydrology, 299, 166-179. Bruni, G., Reinoso, R., van de Giesen, N. C., Clemens, F. H. L. R., and ten Veldhuis, J. A. E.: On the sensitivity of urban hydrodynamic modelling to rainfall spatial and temporal resolution, Hydrol. Earth Syst. Sci., 19, 691-709, doi:10.5194/hess-19-691-2015, 2015. Ochoa-Rodriguez, S., Wang, L. P., Gires, A., Pina R. D., Reinoso Rondinel, R., Bruni, G., Ichiba, A., Gaitan, S., Cristiano, E., van Assel, J., Kroll, S., Murla-Tuyls, D., Schertzer, D., Tchiguirinskaia, I., Onof C., Willems, P., ten Veldhuis J. A.E., Impact of spatial and temporal resolution of rainfall inputs on urban hydrodynamic modelling outputs: a multi-catchment investigation, Journal of Hydrology, 2015. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Dec 2014 Expected end date: Dec 2018 Key words: Urban hydrology, Drainage system, Rainfall, Radar Cooperation with other institutes: Deltares, Gemeente Rotterdam 59 Individual Projects Petra van Daal-Rombouts Quality based real time control in wastewater systems Research objectives the functioning of the contributing sewer systems into The main research question of this project is: “Under account as well, allowing SST discharges only if the sewer which conditions can real time control (RTC) based on system is prone to discharge. Preliminary results show a the quality of the receiving water be used in wastewater decrease in SST discharges of 40 % in number of events systems?” and 20 % in volume. The PC control aims at reducing the peak load of the WWTP at the onset of wet weather This question is divided into two sub questions: ▪▪ ▪▪ conditions by changing the amount of PCs in operation Is there added value in applying RTC based during different phases of a rain event. Example of on the intended functioning of the PC-control are given in increasingly demanding strategies and implementation levels? Figures 1 (simplified example) and 2 (based on current Can the added value be demonstrated in practice? measurements). The control will be implemented in the near future. Measurements and modeling will be applied Project outline to quantify the impact of the control on the effluent Introduction quality of the WWTP. A wastewater system consists of different subsystems: a sewer system, a wastewater treatment plant (WWTP) Scientific relevance and receiving water. These subsystems interact with Previous research performed by Langeveld (2004) and one another through water quantity and water quality. Schilperoort (2011) has shown there are possibilities to However, the influence of the quality of the receiving decrease the impact of a sewer system and WWTP on water on the sewer system or the WWTP is very limited the surface water. One very likely means is using RTC. and indirect. Improvement of the quality of the receiving Previous research on RTC in wastewater systems covers water could be achieved through the application of e.g. volume based RTC, optimization techniques and RTC in the wastewater system: using information from theoretical research. There is a lack of research on quality downstream locations to adjust the operation of upstream based RTC, large case studies, comparison between systems. theory and practice, and studies on the total wastewater system. The research presented here aims at filling these Approach gaps and making the knowledge available for practice. As the research questions imply, the project consists of both theoretical and practical elements. The theory Social relevance focuses on determining the added value of applying RTC Social relevance is at the very basis of this project. It is in wastewater systems based on quality and impact. To aimed to decrease the impact of the sewer system and do this, models and measurements from a case study WWTP on the receiving water through RTC, therefore (Langeveld et al., 2013) are used and effort is made to improving its quality and thus leading to a higher improve them. The practical element consists of making ecological/recreational value. an effort to demonstrate the added value in real life by implementing the RTC in the case study and monitoring Literature the effects. Langeveld, J. G. (2004). Interactions within wastewater systems. Analysis. TU Delft. Results Langeveld, J.G., Benedetti, L., De Klein, J., Nopens, I., As a first step towards incorporating impact based RTC in Amerlinck, Y., Van Nieuwenhuijzen, A., Flameling, T., Van the wastewater system of the case study, new controls Zanten, O., Weijers, S.R. (2013). Impact-based integrated for the stormwater settling tank (SST) and primairy real-time control for improvement of the Dommel River clarifiers (PC’s) at the WWTP have been designed and water quality. Urban Water Journal, 10, 312–329. (are) implemented. The SST was originally controlled Schilperoort, R. (2011). Monitoring as a tool for the by the WWTP operation only. The new control takes assessment of wastewater quality dynamics. TU Delft. 60 Petra van Daal-Rombouts Figure 1. Example of intended PC-control functioning for heavy, system wide rainfall Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Figure 2. Example of intended PC-control functioning based on current measurements Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jan 2012 Expected end date: 2017 Key words: Wastewater system, real time control, water quality, monitoring, integrated modelling, optimisation, conceptual models Cooperation with other institutes: Witteveen+Bos, Waterboard De Dommel, Municipality of Eindhoven, INSA de Lyon, Deltares 61 Individual projects Daniel Daniel Tools for the selection of household water treatment and safe storage intervention in developing countries Research objectives common tools for decision support system or using new The aim of this research is to develop a framework or concept. Finally, the tools will be tested in the study area selection tools for household water treatment and safe in developing countries. The tools can be used to develop storage (HWTS) intervention program in developing a new intervention program or to evaluate the running countries. It can help decision makers or relevant HWTS intervention program. stakeholders to designing implementation program that can improve the health status by improving the drinking One of the purposes in this research is to involve different water quality at household level in the study area. discipline and stakeholder. Expert interview, focus group discussion, and field data collection will be conducted to Project outline answer all the research questions. Introduction A wastewater system consists of different subsystems: There Although access to improved water supplies has increased research: slum area, remote or inaccessible area, or worldwide, poor drinking water quality remains a major underdeveloped ethnic. The main reason behind that challenge globally. One of the reasons is contamination is because those areas have a bigger challenge and in household level. Household water treatment and safe limitation than others (urban), in terms of accessibility, storage was introduced to tackle this problem. social norm, culture, economic, etc. They may also have are three possible study areas for this a health problem due to bad drinking water quality. Bad Currently, there are many options for HTWS intervention selection of intervention for people in that area will cause in developing countries. The problem arises when we unsustainable and ineffective project. All those areas are need to select the appropriate intervention program. planned to be located in Indonesia. From literature review, all factors relevant that need to be considered for selecting the HWTS intervention Scientific relevance in developing countries can be categorized into four The research was designed to address the gaps about aspects: economic, social, technical, and institution. the selection tools for HWTS intervention in developing countries. Most of the current intervention program was However, despite a many options of intervention program, selected based on intuition or past experience. We need there is limited research available concerning tools for the to use schematic approach to select the appropriate selection of appropriate HTWS intervention. The selection program. tools need to consider all those four aspects and then implement the best intervention option. Otherwise the The current selection tools for HWTS intervention were intervention program will not run sustainably in the not addressing all four relevant factors. Most of them future. focused on technical or performance factors and may not be used in developing countries because they do not From literature review, I expect that social factor has consider some factors that play an important role, e.g., the highest impact, whereas technical has the lowest social norm and local belief. one that need to be considered for HWTS intervention in developing countries. Approach First, factors relevant for selection of HWTS will be investigated. Afterwards, choosing the appropriate tools to select the best intervention program will be the next step in this research. We could choose either using 62 Daniel Daniel Social relevance Since the study area of this research will be applied in slum area, remote area, or underdeveloped ethnic, the result could help them to improve their health status by consuming better and cleaner drinking water. The output of this research can be used also by relevant stakeholder or decision makers to develop the next HWTS intervention Literature Baffrey, R. M. N. (2005). Development of program implementation, evaluation, and selection tools for household water treatment and safe storage systems in developing countries. Massachusetts Institute of Technology. Loo, S.-L., Fane, A. G., Krantz, W. B., & Lim, T.-T. (2012). Emergency water supply: a review of potential technologies and selection criteria. Water research, 46(10), 3125-3151. Sobsey, M. D., Stauber, C. E., Casanova, L. M., Brown, J. M., & Elliott, M. A. (2008). Point of use household drinking water filtration: a practical, effective solution for providing sustained access to safe drinking water in the developing world. Environmental science & technology, 42(12), 4261-4267. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 682329482 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Oct 2016 Expected end date: Oct 2020 Key words: drinking water, developing countries, selection tools Cooperation with other institutes: EAWAG 63 Individual Projects Alex Duinmeijer On the research into the mechanisms of formation and degradation of debris layers in wastewater pump sumps Research objectives Obtaining knowledge about mechanisms of formation and degradation of debris layers in wastewater pumping stations. Knowledge will be used to adapt the current design guidelines for wastewater pump sumps. Project outline Introduction Wastewater pumping stations can experience problems due to the presence of floating fat, scum and other debris in the pump sump (hereafter referred to as ‘pollution’). The presence of this pollution can result in pump failures which may result in a 16% increase of yearly volume of CSO (Korving, 2006). The current guidelines for sump design (e.g. ANSI/HI (2012)) only deal with the transport of pollution in a superficial manner for a limited number of sump geometries (i.e. trench type and circular sumps). Figure 1. Side and front view of test facility: 1) pump sump, 2) pump, 3) flow meter, 4) inlet conduit, 5) hydraulic gate in overflow sill, 6) measurement of entrained air, 7) control valve, 8) ultrasonic sensor for water level measurement, 9) outflow, 10) reservoir According to the author, basically there is a need for a Next, the obtained knowledge about the potential more generic formulation of design guidelines which transport mechanisms will be tested in in real wastewater provides a balanced compromise between avoiding poor pumping stations which experiences problems with flow conditions and air-entrainment on one hand while floating pollution. Finally, based on the experimental avoiding the formation of pollution on the other hand. The research, field research and a serviceability inventory processes involved are currently only poorly understood. of real pumping stations, new generic guidelines will be Therefore, the author has started a (experimental) formulated that address conflicting criteria (optimal flow research to the mechanisms of the formation and conditions, no air-entrainment, no pollution) resulting degradation of debris layers. The obtained knowledge in robust, efficient and maintenance friendly pumping will be used to adapt the current guidelines which must stations. lead to more robust, efficient and maintenance friendly pumping stations. Results Based on the first executed experiments, the preliminary Approach conclusions can be drawn that the presence of floating First, a theoretical research is conducted into potential pollution affects the formation of strong free-surface mechanisms for transport of pollution. Initially, two vortices, see Figure 2 and Figure 3. Extensive future hypotheses are defined: (1) using the vertical transport research will be executed by the author to investigate the capacity of free-surface vortices and (2) horizontal ability of strong free-surface vortices as a mechanism for transport by keeping pollution in suspension. An the transport of floating pollution. extensive experimental research will be conducted in a full scale test facility to investigate the validity of both hypotheses as a mechanism for the transport of pollution into the pump suction inlet. Figure 1 shows the set-up of the test facility. 64 Alex Duinmeijer Figure 2. Formation of free-surface vortex in ‘clean’ water test facility Figure 3. No formation of freesurface vortex at same hydraulic conditions but with presence of floating layer of polystyrene pearls Scientific relevance The experimental data from experimental and field research in wastewater pump sumps is considered essential for science-based optimized design of wastewater pumping stations. The experimental research provides insights in the flow phenomena’s in wastewater sumps with respect to formation and degradation of layers of floating debris. Social relevance Generic design guidelines for sumps with respect to pollution decreases pump failures and therefore increasing the sewer system serviceability. As a result, the yearly volume of CSO spills of raw wastewater into receiving surface water bodies decreases providing a better environmental health. Also, less pollution of pump sumps significantly decreases the annual costs for sump cleaning and pump failure repair costs. Literature Korving, J.L., Clemens, F.H.L.R., and van Noortwijk, J.M., 2006b. “Statistical Modelling of the Serviceabilitiy of Sewage Pumps”, Journal of Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: spa.duinmeijer@ rotterdam.nl www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Oct 2014 Expected end date: Sep 2018 Key words: Pump sump, waste water, floating debris, experiments Cooperation with other institutes: Municipality of Rotterdam Hydraulic Engineering, 2006.132, 1076 - 1085 American National Hydraulic Standards Institute (2012) American National Standard for rotodynamic pumps for pump intake design. ANSI 9.8-2012. ISBN 978-880952-70-2 65 Individual Projects Astrid Fischer Decision Support System for controlling emerging substances in the water cycle Research objectives 1. Emerging substances in water The aim of the project is to build, validate and demonstrate a.Sources a Decision Support System (DSS) that will help actors within the water-cycle to make informed decisions on how to control emerging substances in the water-cycle system the most effective and efficient way. b. Are there adverse effects on human health, the ecosystem or susceptible functions of the water 2. Possible mitigation measures a. Choice of measure, eg. removal efficiencies and Project outline costs Introduction b. Location of the measure (if relevant) Emerging substances in surface water are increasingly c. Long term vs. short term solutions giving concern to the public, regulators and users of 3. Future scenarios this water as a drinking water source (Houtman 2010). 4. Research needs However legislation both on a national and international level is often running behind especially in the case of The TAPES project focuses on the two first issues, due to emerging substances, due to complex decision structures the relatively short time span of the project of 2,5 years. and the need for indisputable scientific evidence. Water authorities and water companies struggle with the Results question where and how to combat these substances To address the issues outlined above, the DSS will give in the water cycle. As a part of the EU Interreg project the user information on the source, pathway, chemical TAPES (Transnational Action Programme on Emerging characteristics Substances) a novel Decision Support System (DSS) substances and their mixtures, together with information is being developed to deal with this issue. The specific on the efficiency of water treatment technologies for aim of the TAPES DSS is to focus on the management drinking and wastewater. Also decentral technical and non- of emerging compounds within the whole water cycle, technical mitigation methods were included, as requested to suggest mitigation methods also beyond technical by a part of the stakeholders. To fulfil these requirements solutions, make use of the enormous amount of several parameters are included in the DSS; general (scientific) information available, while being a simple and substance information (description, physical/chemical easy-to-access tool for the informed but not-expert user, characteristics and legislation), hazard (toxicity), water that does not require any particular training. cycle entrance with the associated mitigation methods, and toxicity of individual emerging and if possible monitoring measurements to give a more Approach With a preliminary DSS as basis, interviews were carried out with TAPES project partners representing different actors within the water sector. i.e. a drinking water utility, a wastewater utility, a water board, two research institutes, and a water management organisation. The interviews were recorded and analysed, the points raised were clustered to the main issues for the interviewed stakeholders representing decision makers within the water cycle. The main conclusion from the interviews was that there is no struggle with a lack of information, the struggle is how to decide which information is relevant. The main issues mentioned are 66 accurate assessment of the toxicity (Figure 1). Astrid Fischer Figure 1. Diagram of information included in the DSS Scientific relevance The DSS aims to be the link between the scientific knowledge available and the people that need to use this not always easily accessible knowledge in their daily work to make better and more informed decisions. As such it is not only scientifically relevant, but it is actively making science relevant outside the scientific community. Social relevance When the DSS is completely developed and working adequately it will lead to more informed decision-making throughout the whole water cycle and a more effective and uniform way of managing emerging Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering substances in the water cycle. Start date project: Jan 2013 Expected end date: Jan 2018 Literature Key words: Emerging substances, water treatment techniques, water cycle Houtman C.J. (2010) Emerging contaminants in surface waters and their relevance for the production of drinking water in Europe. J. Integr. Environ. Sci. 7(4), 271-295. Cooperation with other institutes: KWR, Waternet, Waterschap De Dommel, TZW, VITO, De Watergroep, FHNW 67 Individual Projects Katie Friedman Metal-Impregnated Ceramic Water Filters for Point-of-Use Water Treatment Research objectives The The main goal of this research is to improve virus disinfection studies to determine the disinfection kinetics inactivation in POU household water treatment systems, of silver and copper ions in different concentrations specifically through the incorporation of metals such and combinations for E. coli and MS2. These studies as silver, copper, and iron into ceramic pot filters. The will be conducted both in dark (designed to minimize variables considered include form of the metals (ionic light exposure) and light (solar simulator) conditions or particle), concentration of the metals in the ceramic to determine if the presence of light may affect and matrix, and flow rate or contact time. The research will potentially enhance the disinfection kinetics and potential also investigate the role of leached metal ions in the synergies. research also includes complementary batch effluent and characterize the potential added disinfection benefits achieved during storage time in the effluent Results storage receptacle. Combinations of copper and silver showed potential synergistic benefits for the reduction of E. coli and copper Project outline demonstrated antiviral activity for batch disinfection Introduction studies conducted in dark conditions, and experiments Ceramic water filters (CWFs) are a widely used Point- with light exposure are to follow in November 2015. Initial of-Use technology that utilizes a network of fine pores results for filter experiments showed that filters with both created by organic burnout material within ceramic media copper and silver showed a potential synergistic effect in order to remove pathogens. In addition, aqueous for log10 reduction values of MS2 and that additional solutions or suspensions of silver are typically applied disinfection was achieved during overnight storage, to the finished ceramic filter, adding additional microbial highlighting an added benefit from contact time with protection. Due to the presence of micropores, these leached ions. In general, increasing metal concentrations filters are able to remove most bacteria and parasites achieved increasing E. coli log10 reduction values, but based on size occlusion and to maintain this performance this effect was not consistently observed for MS2. Flow with the aid of silver. However, the filters are not very rates varied based on filter type and may also play a effective in reducing or inactivating viruses due to their role in microbial reductions in combination with metal significantly smaller size and different properties. concentration. Approach Scientific relevance Ceramic water filter disks with different concentrations, This research was designed with the aim to address the forms, and combinations of silver, copper, and iron following knowledge gaps in the use of metals in ceramic fired into the ceramic media were manufactured at the water filtration: FilterPure ceramic water filter manufacturing facility in 1) effective methods to inactivate or remove viruses by the Dominican Republic. Filter disks are then tested for CWFs filtration efficacy using buffered test water spiked with 2) effectiveness of incorporation of alternative and/ E. coli and MS2 bacteriophage. Samples are analyzed or complementary metals, such as iron or copper (with to determine microbial reductions, and flow rates and exception of iron oxide) effluent metal ion concentrations are also monitored. 3) contribution of leached metal ions in effluent to Samples are taken both directly from the filter as well disinfection within the CWF system as from the effluent collection receptacle after overnight 4) performance storage. properties of fired-in metals in CWFs 68 efficacy and chemical/physical Katie Friedman Social relevance POU treatment systems such as CWFs play an important role in safe water solutions, whether in the interim for emergency response situations or the long-term for communities that have significant logistical challenges to achieving community-level water treatment and distribution. Improvements in efficacy can potentially help to reduce the global burden of waterborne disease, helping to make more effective POU treatments available to those without access to safe water. Literature Rayner, J. et al. (2013). Laboratory Investigation into the Effect of Silver Application on the Bacterial Removal Efficacy of Filter Material for Use on Locally Produced Ceramic Water Filters for Household Drinking Water Treatment. ACS Sustainable Chem. Eng., 1, 737–745. Van der Laan, H. et al. (2014). Bacteria and virus removal effectiveness of ceramic pot filters with different silver applications in a long term experiment. Water Research, 51, 47– 54. Van Halem, D. (2006). Ceramic silver impregnated pot filters for household drinking water treatment in developing countries. Master’s thesis, TU Delft, Netherlands. WHO (2011). Evaulating Household Water Treatment Options: Healthbased targets and microbiological performance specifications. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Nov 2014 Expected end date: March 2017 Key words: Ceramic water filters, silver, copper, HWTS, virus inactivation, POU water treatment Cooperation with other institutes: University of North Carolina at Chapel Hill (USA) 69 Individual projects Victor Servando Garcia Rea Phenolic compounds degradation in AnMBR under mesophilic and thermophilic operation: BioXtremefollowing up. Research objectives An AnMBR can be simply defined as a biological treatment The aim of this research is to analyze the biological process operated without oxygen and using a membrane degradation process of phenol, p-cresol, and resorcinol to provide solid-liquid separation(Lin et al. 2013). In an in anaerobic membrane bioreactors (AnMBR) under AnMBR, biomass can be effectively retained inside the mesophilic conditions and the degradation of phenol reactor providing optimal conditions for organic matter under thermophilic conditions. degradation without any carry-over of suspended This PhD project is part of the BioXtreme project, which solids (SS). By incorporating membranes to anaerobic its goal is to show the potential of AnMBR technology wastewater treatment, superior effluent quality in terms for the treatment of chemical wastewaters under of chemical oxygen demand (COD), suspended solids and extreme conditions. So, in this PhD research the extreme pathogen counts can be achieved in comparison with conditions are: 1) high toxicity, be given by the phenolic conventional anaerobic processes, and a stable treatment compounds and its mixture; 2) high temperature, given performance can be obtained to meet stringent discharge by the thermophilic (48-55 °C) operation. standards(Ozgun et al. 2013) Project outline Approach Introduction 3 AnMBRs will be used for the experimental approach. Water is one of the most valuable resources not only Different sources of anaerobic biomass will be used and for the human society development but for all forms of synthetic wastewater containing phenol and/or phenolic life. Human population is growing and also the usage compounds will be used as a model compound for the and the demand of water, while in some locations of the toxic degradation research. earth (especially in the western society and industrialized countries) there is an indiscriminate use of this resource, The degradation of the phenol (an probably the other other countries present a shortage of water. two phenolic) compounds under anaerobic thermophilic conditions will be assessed as well; although, as a Rapid industrialization has resulted in the generation of pioneer study in this area care should be taken due to the large quantity of effluents (Shao et al. 2006; Ozgun et blockages of the operation in high temperatures. al. 2013), which include the major sources of industrial wastewaters from food processing, pulp and paper, Physicochemical studies of the biomass and of the textile, chemical, pharmaceutical, petroleum tannery, and permeate obtained from the reactor will be held regularly. manufacturing industries(Lin et al. 2013) between others. Molecular biology and methagenomic studies studies will be performed to unravel the microbial population involved This wastewaters present a challenge for the conventional in the degradation process of the toxics. biological treatment methods, because usually implies characteristics like high organic strength and extreme Scientific relevance conditions(van Lier et al. 2001): high toxicity, high This study will help to understand the degradation process temperature, high salinity and very high or low pH values. of chemical wastewaters in anaerobic conditions and the Is in this niche in which the Bio-Xtreme project enters, effect of AnMBRs in the process. Nowadays this is a quite having the goal of develop thermophilic anaerobic new technology so more research is need to be done in membrane (AnMBR) treatment technology for wastewater order to assess the AnMBR like the best technology for with high concentrations of salt and aromatics, in order to the treatment of this kind of effluents. solve the urgent need for sustainable and cost effective treatment of these types of wastewaters making them suitable for reuse(van Lier 2013). 70 Victor Servando Garcia Rea Social relevance Every day tons of toxic wastewaters are generated and discharged (a great percentage without treating) all over the world, which is a major concern because of their environmental impact. If an adequate performance of AnMBR is achieved, a breakthrough for the chemical wastewater treatment will be delivered helping to reduce the water footprint and presenting a very viable option for closing water cycles. Literature Lin, Hongjun, Wei Peng, Meijia Zhang, Jianrong Chen, Huachang Hong, and Ye Zhang. 2013. ‘A review on anaerobic membrane bioreactors: Applications, membrane fouling and future perspectives’, Desalination, 314: 169-88. Ozgun, Hale, Recep Kaan Dereli, Mustafa Evren Ersahin, Cumali Kinaci, Henri Spanjers, and Jules B. van Lier. 2013. ‘A review of anaerobic membrane bioreactors for municipal wastewater treatment: Integration options, limitations and expectations’, Separation and Purification Technology, 118: 89-104. Shao, Min, Xiaoyan Tang, Yuanhang Zhang, and Wenjun Li. 2006. ‘City clusters in China: air and surface water pollution’, Frontiers in Ecology and the Environment, 4: 353-61. van Lier, J. B. 2013. “Wateretech 2013 Application template BioXtreme Anaerobic wastewater treatment under extreme conditions.” In, 19. Delft, The Netherands.: TU Delft. van Lier, J. B., A. Tilche, B. K. Ahring, H. Macarie, R. Moletta, M. Dohanyos, L. W. Pol, P. Lens, and W. Verstraete. 2001. ‘New perspectives in anaerobic digestion’, Water Sci Technol, 43: 1-18. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: V.S.garciarea@ tudelft.nl Phone: +31 152787380 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Feb 2016 Expected end date: Feb 2020 Key words: BioXtreme, AnMBR, phenolics degradation, extreme toxicity 71 Individual Projects Marieke de Goede Broadening and renewal of the Dutch drinking water benchmark Research objectives ▪▪ Benchmarking can slow down innovation: innovation This study is initiated to develop a framework to broaden means and renew the Dutch drinking water benchmark. The increases the risk that the results are lower than benchmark can be broadened by adding new subjects expected. Benchmarking rewards reproduction of the to it. The idea is that adding new subjects will push organizations to learn and improve on these subjects exploring of the unknown. Innovation known. ▪▪ The learning effect from the Dutch drinking water leading to improvement of the drinking water supply benchmark seems to be decreased. While productivity sector. The research develops a framework that decides grew between 2000 and 2008, currently the growth on adding new themes and deleting “exhausted” themes. stopped, as can be seen in Figure 1. ▪▪ Variations in performances between drinking water Project outline supply organizations have decreased. Because of Introduction small variation, there is less differentiation between Benchmarking is a management instrument for performance good and bad performance. This makes the impact comparison. In the drinking water sector it serves two and learning effect of the benchmark smaller (van goals. On the one hand improvement of the performances of the water supply companies and on the other hand it Helden and Brouwer 2005). ▪▪ Participating in the benchmark became mandatory is a form of accountability for the sector (ILT 2012). The in 2012. When performance measurements become drinking water benchmark is first executed over the year mandatory the chances of undesired effects (i.e. 1997. Since then, the productivity of the drinking water strategic behavior) increase. The measures become supply sector has significantly improved (Dumaij and van targets and as Goodhart’s law explains: ‘When a Heezik 2012). measure becomes a target, it ceases to be a good measure’. Approach ▪▪ The Dutch drinking water benchmark only has First an evaluation of the current drinking water attention for the short term, and does not focus on benchmark is executed to get an overview of the effects long term plans of organizations. of the Dutch drinking water benchmark. This evaluation is performed by literature research and interviews with the Dutch drinking water companies. Based on this evaluation a framework will be designed to make the benchmark fit for the future. Results When the drinking water benchmark is made fit for the future, with the use of the framework, the negative effects of the current benchmark are expected to be solved: ▪▪ The current drinking water benchmark has two goals: improvement and justification. If a benchmark serves two goals, organizations can become too focused on showing that there level of performance is sufficient that the improvement objective is under pressure (de Bruijn 2002). 72 Figure 1. Productivity index numbers of drinking water Marieke de Goede Further research plan The goal to make the benchmark fit for the future requires that themes that are benchmarked should be able to change, because the future changes and some themes lose impact and get exhausted. Besides future developments and consumer preferences, also “sudden events” will be incorporated as in input variable. The research is framed along six specific research questions: ▪▪ How can a benchmark be made fit for the future? ▪▪ How can consumer preferences be integrated in a benchmark? ▪▪ how can “sudden events” be translated into a benchmark? ▪▪ What should a framework – that integrates future changes and “sudden event”, that decide on adding new themes and deleting “exhausted” themes and that incorporate consumer preferences – look like? ▪▪ What are the effects of application of the framework? ▪▪ How does the designed framework fits in the current governance Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl structure of the Dutch water sector? Social relevance Improvement of the Dutch drinking water benchmark should lead to improvement of the drinking water supply sector. Making the benchmark fit for the future will lead to a situation where drinking water organizations are learning from each other again. This is expected to improve their performance on the subjects which fit with the changed environment the drinking water companies operate in. Good performance on these subjects is expected to improve the overall performance of these organizations. Literature de Bruijn, H. (2002). Managing Performance in the Public Sector. London, Routledge. Dumaij, A. C. M. and A. A. S. van Heezik (2012). Productiviteitstrends in de drinkwatersector - Een empirisch onderzoek naar het effect van regulering op de productiviteitsontwikkeling tussen 1985 en 2010. Delft, Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Feb 2013 Expected end date: Feb 2017 Key words: Drinking water benchmark, risk management, assets management, innovation, sustainability, water cycle, future orientation Cooperation with other institutes: VEWIN, Oasen, PWN, Waternet TU Delft. ILT (2012). Protocol prestatievergelijking drinkwaterbedrijven 2012. Den Haag, Inspectie Leefomgevinng en Transport. van Helden, J. and N. Brouwer (2005). “Benchmarking en prestatieverbetering in de publieke sector - Ervaringen met de bedrijfsvergelijking zuiveringsbeheer.” Maandblad voor accountancy en bedrijfseconomie(6): 9. 73 Individual projects Adrian Gonzalez Ortega Maximisation of energy recovery from sewage sludge with an innovative digestion process Research objectives 1. Step 1: The influence of different sets of operational The objective of the project is to analyse the non-degraded parameters, such as temperature, exposure time and fraction of waste activated sludge after pretreatment and feed TS concentration, on biodegradability of WAS will be anaerobic digestion, and to devise methods to improve tested. WAS of different sewage treatment plants (high/ digestibility for achieving energy-neutrality at sewage low loaded, bio-P activated sludge systems) will be used treatment plants. to determine the influence of the variation in composition. Optimal conditions for these different WAS samples will Project outline be defined and energetically assessed. Introduction Waste activated sludge (WAS) is produced at 60-90 g (as 2. Step 2: In this part, the non-degraded fraction under dry solids) per day per person-equivalent (Appels et al. the different conditions studied in Step 1 will be identified. 2008) at sewage treatment plants (STPs). WAS consists The WAS composition is not fixed and varies depending mainly of microorganisms, exopolymers and inorganic on the STP process configuration. Therefore, WAS matter, and may contain pathogens, heavy metals and treatment parameters will be customized, considering the other contaminants. WAS, therefore, is a threat for both different WAS compositions. Studies in pilot and full-scale human and environmental health and needs to be disposed facilities will be performed. off safely. Costs for WAS disposal determines to a large extent the economy of a sewage treatment plant. In the 3. Step 3: After application of thermal treatment, the Netherlands, where incineration is the sole option, the total recalcitrant organic parts of the sludge will be identified costs are between 150-200 million euros per year. and subjected to other treatment techniques, in order to achieve their destruction. Finally, the net energy Anaerobic digestion (AD) is a common method to stabilize balance of the proposed pre-treatment will be assessed, WAS prior to dewatering and final disposal, resulting in a applying co-digestion of primary sludge and/or applying volume reduction of 30-40% and in methane production. thermophilic anaerobic digestion. However, WAS digestion requires long solids residence times (SRTs) of about 20-30 days and less than half of Results the theoretical organic matter conversion is achieved Ongoing tests to assess the: (Nielsen et al. 2011). To enhance WAS digestion, sludge • impact pre-treatment methods (e.g thermal, chemical) have been pretreatment on specific methane production. widely applied. Pretreatment-techniques usually increase • potentials of the cation exchange capacity (CEC) the WAS biodegradability by 10-15% (in absolute terms), within WAS to increase its biodegradability. of TS concentration during thermal however it is not clear which parts are not converted during digestion and even less is known about the exact cause of Scientific relevance the increased biodegradability by means of a pretreatment Several studies have been published on pretreatments nor about the net energy gain of WAS pre-treatment. and their effect on WAS biodegradability. However, only few researches had their focus on the analysis of the Approach non-degraded part after application of both pretreatment Low temperature (<100 degrees Celcius) thermochemical and AD. In order to release this recalcitrant fraction (and pre-treatment is the main technology studied in this thus improve the efficiency of AD) within the framework project, as it results in increased biodegradability at of energy-neutrality, it is required to know which relatively low energy consumption. The research steps components are not degraded with current techniques. are: 74 Adrian Gonzalez Ortega Social relevance Expansion of the wastewater treatment infrastructure has resulted in an increase in the effluent water quality, but also in an increase in sludge production that will continue in the future (Appels et al. 2011). Any improvement in AD efficiency will lead to a further reduction of sludge for disposal (Devlin et al. 2011), resulting in less intensive use of resources and even possibilities for increased resource recovery from WAS. Literature Appels, L. et al., 2011. Peracetic acid oxidation as an alternative pre-treatment for the anaerobic digestion of waste activated sludge. Bioresource Technology, 102(5), pp.4124–4130. Available at: http:// dx.doi.org/10.1016/j.biortech.2010.12.070. Appels, L. et al., 2008. Principles and potential of the anaerobic digestion of waste-activated sludge. Progress in Energy and Combustion Science, 34(6), pp.755–781. Available at: http://www.sciencedirect. com/science/article/pii/S0360128508000312 [Accessed July 11, 2014]. Devlin, D.C. et al., 2011. The effect of acid pretreatment on the anaerobic digestion and dewatering of waste activated sludge. Bioresource Technology, 102(5), pp.4076–4082. Available at: http:// dx.doi.org/10.1016/j.biortech.2010.12.043. Pilli, S. et al., 2011. Ultrasonic pretreatment of sludge: A review. Ultrasonics Sonochemistry, 18(1), pp.1–18. Available at: http://dx.doi. org/10.1016/j.ultsonch.2010.02.014. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: j.a.gonzalezortega@ tudelft.nl Phone: +31 15 2781916 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Feb 2016 Expected end date: Feb 2020 Key words: Waste Activated Sludge; Thermochemical treatment; anaerobic digestion; VS reduction; methane production Cooperation with other institutes: Royal Haskoning DHV 75 Individual Projects Bayardo Gonzalez Rodriguez Arsenic Removal for Drinking Water Treatment in Nicaraguan Rural Communities Research objectives Health etc). The second step consists in locating arsenic- The aim of this research is to enhance fundamental affected communities and determine As concentration, As understanding of As(III) and As(V) removal NF speciation, As source, as well as measuring the chemical membranes. These finding will be used to develop an and physical composition of water. This baseline study effective and affordable RO/NF treatment system driven will allow for a smart design of experimental procedures by Human and Solar power for the removal of arsenic in for the laboratory experiments to be executed in the groundwater for rural communities and small towns in Netherlands. by Nicaragua. Project outline Scientific relevance Nanofiltration (NF) membranes have proved to be reliable Introduction in removing arsenic species from water over a wide range Water ingestion with high concentrations of Arsenic (As), of operational conditions. Furthermore NF is a promising leads to greater cancer risk than any other common technology for arsenic removal since it requires less water contaminant. (Smith AH et al, 2007). According energy than traditional reverse osmosis membranes. to a study published by Barragne-Bigot in 2004, in However the biggest challenges ahead lie in applying the Nicaragua approximately 55,700 people were ingesting technologies in poor and rural communities. Therefore water contaminated by arsenic (As). Most of those people is a need for systematic investigation of the use of NF lived in scattered small rural communities or were semi- membranes for small scale systems. concentrated in municipal and small towns. The number of people who currently are ingesting water with arsenic Social relevance in rural Nicaraguan communities is unknown. A clean and In Nicaragua the knowledge of arsenic removal systems safe drinking water supply is a basic human right that is comes from the research performed by local universities being denied to poor and rural communities affected by or NGOs working with water and sanitation. Despite the arsenic poisoning and a limited access to water. great efforts of the universities and NGOs, there is still very little hands-on experience with arsenic removal. For this reason, it can be said that this first and long-term study is aimed at evaluating, adapting and developing arsenic removal systems so they can be used at a local level. By combining scientific inquiry with a concern for social welfare, this study will be useful as a document of reference in universities, research centers on water resources, NGOs and institutions working on water supply projects or managing this service at a private or public Figure 1. Municipalities of Nicaragua with water sources where arsenic concentration exceeds the national regulatory limit of arsenic in drinking water (10μg As/ l) as of 2011. (Bundschuh J, et al, 2011) level. Approach to arsenic problems in rural communities in Nicaragua, In the first PhD year, the aim is to gather all the available recently defined arsenic as a forgotten deadly threat. information related to arsenic in Nicaragua. This Therefore, this study will be of great help to understand information is scattered in different institutions (e.g the the real reach of the arsenic problem in Nicaragua. Nicaraguan Institute of Aqueducts and Sewers, Ministry of 76 The Director of UNICEF in Nicaragua, Philippe BarragneBigot, who a few years ago led several research related Bayardo Gonzalez Rodriguez Literature Altamirano Espinoza M. Bundschuh J. Natural arsenic groundwater contamination of the sedimentary aquifers of the southwestern Sébaco valley, Nicaragua. In: Bundschuh J. Armienta MA Birkle P. Battacharya P, Matschullat J, Mukherjee AB, editors, Natural arsenic in groundwater of Latin America, Leiden, The Netherlands : CRC Press/Balkema Publisher : 2009. P 109- 2002 Barragne P (2004). Contribución al estudio de cinco zonas contaminadas naturalmente por arsénico en Nicaragua. UNICEF, Managua, Nicaragua. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: b.j.gonzalezrodriguez@ tudelft.nl www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jun 2014 Expected end date: Jun 2018 Key words: Arsenic, removal, groundwater, nanofiltration , adpsortion, zerovalent iron Cooperation with other institutes: PIENSA (Research Program, National Studies and Environmental Services), Nicaragua, The National Water Authority (ANA), Nicaragua 77 Individual Projects Jink Gude Understanding arsenic mobility for smart fixation during drinking water treatment Research objectives Approach ▪▪ Understanding arsenic redox behavior and arsenic The focus of the research will be to understand the natural adsorption. arsenic removal capacity of groundwater treatment plants Developing a water quality model for arsenic removal during (1) abstraction/mixing, (2) aeration, (3) short during groundwater treatment. storage, and (4) sand filtration. ▪▪ ▪▪ Optimizing arsenic removal in groundwater treatment plants by adjusting operational parameters and/or adding natural groundwater components. Project outline Introduction Arsenic removal is extensively researched because intake of arsenic can lead to skin disease, cancer, kidney heart failure and diabetes and paralysis. WHO guidelines on arsenic are 10 µg/l, but drinking water companies in Figure 1. Typical groundwater treatment set-up in the Netherlands the Netherlands recently set a new target value, arsenic For this purpose, extensive measurements in 3 typical concentrations smaller than 1 µg/L, to eliminate every groundwater treatment plants were executed. The health risk. measurements included typical groundwater parameters, Expensive and invasive methods for complete arsenic but also arsenic speciation, analysis of filter sand coatings, removal exist. However, more elegant solutions for backwash water and supernatant water experiments. A this concentration range are yet to be investigated for graphical abstract of the findings is shown in Figure 2. existing groundwater treatment plants. Current practices The results of these measurements are published and for arsenic removal include reverse osmosis, which has unravel the major aspects and mechanisms of arsenic excellent arsenic retention, but such an installation is oxidation and adsorption during groundwater treatment. expensive for the removal of few micrograms of arsenic. The same is valid for building a polishing step that can be applied by passing the water through adsorptive media or ion-exchange resins. More realistic options are the use of strong oxidants in combination with coagulants like ferric chloride to adsorb all arsenic. However the use of these chemicals must be accompanied with extensive safety measures. This research project will develop alternative solutions for smart fixation of arsenic to concentrations below 1 µg/L without expensive installations and ‘dangerous’ chemicals. Preferably natural components will be added Figure 2. Arsenic mobility during full-scale aeration and rapid sand filtration before or during treatment to minimize cost, making large Results from extensive jar test with arsenic, iron and adjustments to the treatment schemes obsolete and do manganese are being interpreted. Subsequently batch not compromise the stability of the groundwater. reactors and column tests will be used to further investigate reaction kinetics under controlled, isolated conditions. Based on the results of the previous steps a model for kinetic arsenic behavior during oxidation, precipitation and adsorption reactions will be developed. 78 Jink Gude Scientific relevance Most detailed arsenic related studies are executed by geochemists and are concerning arsenic processes on an infinite time scale in the soil. In these studies the focus lies on equilibrium reactions, rather than kinetics. Existing arsenic removal studies are focussed on removal of moderate to high arsenic concentrations in groundwater containing low iron. Virtually no research has been done on arsenic oxidation and adsorption behavior at very low concentrations in a natural groundwater matrix. The aim of this research project is to develop a model that will predict arsenic oxidation, precipitation and adsorption processes during groundwater treatment. Social relevance The best drinking water for a reasonable price is the ambition of every drinking water company. Arsenic is a substance that even at low concentrations is now considered for removal, but not at all cost. By understanding the detailed mechanisms of arsenic removal at low concentrations, we are developing new, elegant technologies to assure safe water. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jun 2014 Expected end date: Jun 2018 Key words: Arsenic removal, low concentrations Cooperation with other institutes: - 79 Individual Projects Noor Gulamussen Potentials of sewage water reclamation for industrial use in Maputo, Mozambique Research objectives and application requirements that create an optimal ▪▪ Review reuse of water reclamation for industrial balance between maximum use of all available water and applications in sub-Saharan Africa. minimum treatment costs. ▪▪ Identify water requirement for industries in Maputo. Technological research will be designed based on the ▪▪ Develop appropriate technologies for wastewater observations in the field and technological options that are treatment and reuse in those industries. available (and under research at TU Delft and UNESCO- ▪▪ Test the selected technologies. ▪▪ Evaluate the impact of IHE) and can be adapted to the local situation. Typically, implementing water reclamation. the technologies, such as low-cost membranes, biological and crystallization processes, will be investigated in the lab, before being tested in the field at pilot scale. Project outline Knowledge sharing with experts in the field is part of the Introduction methods. Water is a critical natural resource that is becoming progressively scarce mainly due to increasing demand Results as a result of high population, economic growth and Enhanced fundamental knowledge on water reuse climate change (Schewe et al., 2014; United Nations, methodologies, by: 2015). Serious water shortages and stricter regulations ▪▪ on wastewater discharge increase the interest in water reclamation worldwide (Rietveld, Norton-Brandão et al. Obtaining knowledge on informal, and formal use of alternative water sources in Maputo. ▪▪ Contributing to study of water reuse from an 2011). On the other hand, the potential for resource integrated socio-technical perspective combined with recovery from wastewater and sludge is largely untapped formal and informal practices and understanding and in developing countries only a small portion of wastewater is used in a planned and safe manner, while power dynamics. ▪▪ Producing required water quality for industrial reuse the majority remains untreated or partially treated, applications in terms of health risks, clogging, fouling, and is more commonly used in the unregulated than corrosion and scaling. formal irrigation sector (Wichelns, Drechsel et al. 2015). Compared to surface water, reclaimed wastewater can be Scientific relevance a more attractive source, because of low fluctuations of The project will contribute on new approaches and water quality and its abundant availability (Van Agtmaal, technologies in planning and design of wastewater de Boks et al. 2007). The planning for water reuse is treatment systems in the context of sub-Saharan crucial for sustainable water resource management as countries by developing: it can constitute an essential component of local efforts ▪▪ drivers. (Wichelns, Drechsel et al. 2015). This project will identify and evaluate technological and socio-economic options ▪▪ New technologies for sewer mining, re-using water energy and nutrients on a profitable basis. for water reclamation for industrial use in sub-Saharan countries – the case of Maputo, Mozambique Novel conceptual models for co-creative participation on water reuse, that provides insight in end users’ to optimize water use and reduce the water shortage ▪▪ The concept of “water-fit-for-use” that will result in a matrix tool linking raw water quality, required Approach water quality and possible (scalable) water treatment In this project a mixed methods approach of qualitative technologies. and quantitative research and water cascading will be used. Key element of water cascading is determining combinations of water source qualities, water treatment 80 Noor Gulamussen Social relevance This approach will reduce the pressure on the limited water resources and increase the total available water supply for domestic use. It will also create driving forces for appropriate sanitation services. A direct impact of this project will be the reduction of nutrients and other pollutants entering waterways and the preservation of wetlands and sensitive marine ecosystems, reducing also health risks in touristic areas. Literature Rietveld, L., et al. (2011). “Possibilities for reuse of treated domestic wastewater in The Netherlands.” Water Science and Technology 64(7): 1540. Schewe, J., et al. (2014). “Multimodel assessment of water scarcity under climate change.” Proceedings of the National Academy of Sciences 111(9): 3245-3250. United Nations. (2015). Water for a sustainable world. World water report Van Agtmaal, J., et al. (2007). “Evaluation of feed water sources and retrofitting of an Integrated Membrane System.” IWA, Antwerpen: 1. Wichelns, D., et al. (2015). Wastewater: Economic Asset in an Urbanizing World. Wastewater, Springer: 3-14. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: May 2015 Expected end date: May 2019 Key words: Water, reuse, industry, wastewater treatment, water reclamation Cooperation with other institutes: Eduardo Mondale University, UNESCO IHE 81 Individual projects Hongxiao Guo Biomethane and alginate-like exo-polymers recovery from sewage sludge by a two-phase plug-flow anaerobic digestion system Research objectives ALEs The overall research objectives of this study are: commercially available alginate, which generally is 1. To obtain comprehensive understanding of key extracted from seaweed, and has been detected in high factors affecting hydrolysis rate, biomethane production quantities in WAS, especially in aerobic granular sludge. and alginate-like exo-polymers (ALEs) liberation, in a Their susceptibility for degradation or partial conversion, two-phase plug-flow anaerobic digestion (AD) system, i.e. changes in molecular structure during anaerobic and digestion, is still unknown. Degradation or liberation of 2. To assess the optimized operational performance ALEs during the different process phases of a multiple in terms of maximized VS reduction, maximized bio- stage AD system will be determined and optimized for methane production, and highest possible ALEs recovery product recovery. from WAS have similar characteristics as in combination with the shortest possible HRT and lowest energy input. Approach 1. A multiple phase plug-flow AD system and a Project outline conventional CSTR will be operated in parallel for Introduction long-term operational experiments, in which different Anaerobic digestion (AD) is generally accepted as one of operational parameters will be assessed that will lead to the most technically mature and cost-effective process maximized process efficiency and product recovery. for partially converting waste activated sludge (WAS) 2. Anaerobic degradation of the different fractions of into biogas. In order to further enhance the digester WAS, as well as ALE liberation and/or partial conversion performance, reactor design will be re-evaluated and will be studied in batch tests. adjusted. Thus far, different configurations have been 3. A modified ALEs extraction method will be used, used to digest WAS, including continuous-flow stirred- which was developed by Lin et al. (2010). tank reactors (CSTRs) and (multi-) phased AD systems. Although the CSTR is widely used for degrading the Scientific and Social relevance organic fraction of WAS, the nature of the reactor design A novel multiple-phase plug-flow AD system will be forces diverse groups of bacteria to coexist within the developed for increased WAS stabilization and biogas same physical and chemical environment, contradicting production, leading to reduced costs at sewage treatment with the aim to optimise each different process step in plants. In addition, the perceived system provides good AD. In other words, long solids retention times (SRTs) opportunities to research the dynamic changes of ALEs are usually required during CSTR operation to balance during excess sewage sludge anaerobic digestion. hydrolytic conversions, acidogenesis and methanogenis Based on the novel insights, their potential for industrial in order to avoid fatty acid accumulation and ensure applications will be evaluated. The overall findings of this stable process operation. In contrast, in (two-) phased research will contribute to convert sewage treatment AD systems, WAS conversion is separated into a plants into “energy and resource recovery plants”. hydrolytic/acidogenic phase and a methanogenic phase, which sometimes improved reactor stability and WAS degradation efficiency (references needed!!!). However, knowledge about the degradation of the different organic fractions in WAS in the different phases of such system and their relationship between optimal digester performance and biomethane production is still unknown. 82 Hongxiao Guo Literature Pohland, F.G., Ghosh, S. 1971. Developments in anaerobic stabilization of organic wastes-the two-phase concept. Environ Lett, 1(4), 255-66. Lin, Y., de Kreuk, M., van Loosdrecht, M.C.M., Adin, A. 2010. Characterization of alginate-like exopolysaccharides isolated from aerobic granular sludge in pilot-plant. Water Research, 44(11), 33553364. Maspolim, Y., Zhou, Y., Guo, C.H., Xiao, K.K., Ng, W.J. 2015. Comparison of single-stage and two-phase anaerobic sludge digestion systems Performance and microbial community dynamics. Chemosphere, 140, 54-62. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 682329482 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Sept 2015 Expected end date: Sept 2019 Key words: Anaerobic digestion, bioenergy, resource recovery Cooperation with other institutes: Royal Haskoning DHV 83 Individual Projects Juan Pablo Gutierrez Suspended sediments in a highly turbid river: implications for infiltration capacity during riverbank filtration Research objectives (Cauca River in Cali, Colombia) were used during the The main goal of this study is to understand the experiments). mechanisms involved in the reduction of the infiltration capacity during riverbank filtration (RBF) as result of Results clogging processes. During the experiments, after 10 h a sudden flow drop was observed when passing a 800 NTU turbid solution Project outline over the columns (Figure 2a). With the 90 NTU turbid Introduction solution the flow reduction occurred only after 70-80 h RBF is a way of filtering surface water to be purified for use (Figure 2b). Deep deposition of sediments did not occur as drinking water through the banks of the river source, when both turbid solutions passed the bed, indicating using extraction wells located near to the water body in that cake formation was the primary clogging mechanism. order to ensure direct aquifer recharge. Using riverbeds The formed cake layer, when subjected to 90 NTU was and banks as filters implicates that RBF systems (like lower (3 mm during eight days) than the one obtained at other filters) are susceptible to some degree of clogging, 800 NTU (10 mm during three days), mainly due to the since fine particles, suspended in the river water, can lower sediment load, regardless of the difference in the significantly alter the hydraulic conductivity of the bed runtimes. This layer influences considerably the behavior and limit aquifer recharge (Caldwell, 2006). Riverbed of the flow rate. clogging may occur on the surface or into the porous media. External clogging corresponds to the cake build- Cake clogging is preferred over deep bed clogging in RBF up on the surface due to the deposition of suspended systems, since the cake could be periodically cleaned solids, reducing the permeability of the riverbed. The by the river water flows. Deep clogging is not desired cake formation depends on many factors, such as the since it may be non-reversible, permanently negatively particle size and concentration. Internal clogging befalls influencing the hydraulic conductivity of the media as when small particles enter the porous media. The cake described by the experiences in the Netherlands. layer, mainly formed by the deposition of sediments on the riverbed surface, and the internal clogging must be Scientific relevance balanced by scouring of the riverbed in order for an RBF This research will provide a better understanding of the system to be sustainable. mechanisms involved in the renewability of the infiltration capacity in RBF systems, which may be extended to Approach stream systems where clogging and scouring processes During 2015, clogging and turbidity removal experiments are involved. Cross-flow velocity affects the deposition were executed and consisted of: (1) conservative tracer and resuspension of suspended solids in natural BF injection in clean media, (2) turbidity solutions injection, systems. Therefore, the practical application of this and (3) conservative tracer injection in clogged media. research to RBF systems is limited, since the experiments These experiments were developed under different were conducted under the absence of scouring forces. turbidity levels and riverbed media sizes. The data obtained will be used for the configuration of further Social relevance filtration – self-cleansing experiments. The use of RBF has been limited due to perceived risks of clogging during high sediment loads. Therefore, this During laboratory-scale studies, two (2) cylindrical plexi- research will offer information for engineers and decision- glas columns (120 cm long and 13.5 cm ID) packed with makers in order to assess properly the technology transfer well-graded material (Figure 1) were used simultaneously to places where highly turbid streams are found. to test clogging during high and a low turbidity events. Natural suspended sediments from a highly turbid river 84 Juan Pablo Gutierrez Literature Caldwell T. (2006). Presentation of data for factors significant to yield from several riverbank filtration systems in the U.S. and Europe. Proceedings of the NATO Advanced Research Workshop on Riverbank Filtration Hydrology: Impacts on System Capacity and Water Quality, Bratislava, Slovakia, September 2004, pp. 299-344. Figure 1. Infiltration columns experiments conducted in Cali, Colombia, using natural sediments from Cauca River Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Figure 2. Head loss and flow variation during experiments with well-graded bed and natural suspended sediments into (a) 800 NTU and (b) 90 NTU Start date project: Oct 2011 Expected end date: 2017 Key words: Riverbank Filtration, Clogging, Turbidity Peaks Cooperation with other institutes: Cinara Institute / Universidad del Valle 85 Individual Projects Amir Haidari Visualization of hydraulic conditions inside the feed channel of RO using PIV Research objectives Results Comparison of the hydraulic conditions inside the empty and Figure 1 illustrates the spatial variations of the velocity spacer-filled channel is the main objective of this study. averaged over time at the middle of spacer-filled channel (Z2). Figure 8a shows the vector velocity map over the Project outline whole field of view, while the Figure 1b and Figure 1c Introduction respectively illustrate the cross section X(y= -2.41mm) Desalination by Reverse Osmosis (RO) and Nanofiltration and Y(x = 4.73mm) of vector velocity values for empty and (NF) increases is the dominate desalination technology spacer-filled channel. Figure 1a shows that the greatest at the moment. DesalData reported that about 78.4% of diversion of the vector velocity from the flow direction at Z2 contracted desalination capacity in 2015 was provided by can be observed in the direct adjacent of the filaments at the RO and NF. The takeover of desalination by RO is mainly the downstream part of each mesh. due to lower cost of RO compare to other desalination Comparing Figure 1a with cross-section in the X-direction techniques. That is while that the spiral wound modules (Figure 1b) reveals that the lowest velocity occurs at the of RO (SWMRO), by far, is the most applied configuration nodes, while highest velocity values occur in the distance of RO. The wider application of RO influenced the choice between the nodes and the middle of mesh. The velocity of the feed water as well. Historically, the first generation values in the middle of the meshes, however, are slightly of RO used for purification of seawater. With passing lower than the average velocity. Lau et al. [39] achieved of time, brackish water, wastewater and freshwater are a comparable velocity map as Figure 1a in the middle of also indirectly exposed to RO for purification. Application the flow channel they used for a feed spacer of 1.0 mm at of RO on freshwater is mainly increased due to increase flow attract angle of 45o by using a computer model. When of xenobiotics substances in surface freshwater as the comparing Figure 1a with cross-sectional profile parallel to consequence of presence of residual wastewater from the flow (Figure 1c), the lowest velocity can be observed industrial, agricultural and medical sections. However, at the nodes, while the highest velocity can be detected the only important change SWMRO have undergone was directly at the downstream of the nodes. That is while at the increasing of the thickness of their feed spacer, which distance of about 25% toward each node from the center results in ultralow pressure ROs (second generation). That is of each mesh, the velocity remains more or less constant. partly due to the fact that our understanding of membrane process is limited [1, 2]. For instance, our undressing of the temporal and spatial hydraulic conditions inside the feed channel of SWMRO is incomplete. Our limited understanding of hydraulic conditions of SWM is thanks to visualization by computational models. Visualization by experimental models was limited due to low resolution of available methods in the past and difficulty of application of proper methods at the moment. Approach Particle image velocimetry is an experimental visualization method, which is used in this study to obtain information about the temporal and spatial conditions inside the empty and spacer-filled channel in the laboratory scale. Some of these results are mentioned below. 86 Figure 1. For ease of visualization, the numbers of vectors in Figure 1a are reduced from its original state Amir Haidari Scientific relevance Succeeding in better understanding of the hydraulic conditions inside the feed channel of RO leads us to the proper design of membrane modules for each type of the feed water. Social relevance At the moment our drinking water companies provide top water quality. This can be remains the same by applying the new trustworthy methods such as RO as a barrier against all kinds of known and unknown pollutants. Liturature [1] W.G.J.v.d. Meer, Het drinkwaterbedrijf van de toekomst?, in, TU-Delft, Delft University Of Technology, 2013. [2] W.G.J. van der Meer, Membraanfiltratie : Presteren onder druk, University of Twente, Enschede, the Netherlands, 2008, pp. 44. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Nov 2011 Expected end date: Nov 2015 Key words: Feed Spacer, Fouling, Reverse Osmosis, Visiualization Cooperation with other institutes: Vitens Water Company 87 Individual Projects Geert-Jan van Heck How to close the gap between the outcomes of the asset management analyses and the decision-making process in Waternet’s drinking water section? Research objectives Decision-making literature was explored, which will form Develop an asset management model for effective decision- together with the outcomes of the interviews the basis making in Waternet’s drinking water division. for the development of an improved asset management framework. This framework will be applied in another case Project outline and adopted based on the results of this case. Introduction The complexity of decision-making for drinking water Results utilities is growing. Drinking water systems are growing The results so far include an overview of asset management fully automated, existing of several subsystems and objects frameworks with more sophisticated and interconnected loops. At the framework for Waternet’s drinking water division [3] and same time, a large part of the utilities’ infrastructure is different case studies applying the latter framework [4-7]. world-wide [1], an asset management aging, while the condition and the risk of failure are often unknown. Furthermore, the environment and society in Scientific relevance which the utilities operate are changing and becoming An improved the asset management process by incorporating more demanding. The interaction between the drinking relevant decision-making theory and learning from applying water infrastructure and its densely occupied operational asset management theory in practice. environment is increasing, causing a rise of conflicting goals. Also the utilities’ internal goals are becoming more Social relevance and more conflicting. Problems are becoming more confuse The asset management model, which will be developed, and ill-structured, and additionally decision-making has to is supposed to increase transparency in decision-making deal with uncertainties. and contribute to delivering drinking water utilities’ goals at lowest social costs. Asset management provides methods for capital intensive utilities to translate the required service level of an Literature organisation to operation, maintenance and investment 1. Heck, G.J. van. Asset Management Frameworks activities for the assets. The goal of asset management is for (drinking water) infrastructures around the world. to provide present and future required service level in the An (not exhaustive) overview of different initiatives and most effective way. Although decision-making and asset developments. Proceedings of International Conference on management are aiming at the same goals, in practice the Infrastructure Systems. Infra 2008. Building Networks for a outcomes of asset management analyses and the outcomes Brighter Future. Rotterdam. 10-12 November 2008. of the decision-making processes in drinking water utilities 2. Heck, G.J. van. Implementing asset management in the show sometimes significant differences. first water cycle company of the Netherlands (Waternet). Proceedings of IPWEA International Public Works Approach Conference. Melbourne, Australia. 6-10 September 2009. The research is aiming to answer the question: how to close 3. Heck. G.J. van. Waternet drinking water tactical planning the gap between the outcomes of the asset management process. Proceedings of the ICE-Municipal Engineer, Volume analyses and the decision-making process? To answer the 163, Issue 4, December 2010, pages 247-256. question the following steps are undertaken. Based on asset 4. Heck, G.J. van. Herder, P. Kuit, J. Condition Assessment management literature an asset management framework of Pre-stressed Concrete Water Mains. Proceedings of the is developed for Waternet’s1 drinking water division. This 24th International Congress on Condition Monitoring and framework is applied in different cases in Waternet and Diagnostics Engineering Management. Stavanger, Norway. decision-makers were interviewed to discover their opinions 30th May till 1st June, 2011. about asset management implementation within Waternet. 5. van Heck, G. and Hillegers, S. (2012) Answering 5 Basic 88 Geert-Jan van Heck Asset Management Questions for Pre-Stressed Concrete Water Transport Mains. Pipelines 2012: pp. 1265-1278. 6. van Heck, G., Hillegers, S. and Haazebroek, I. (2012) Interaction of Water Transport Pipelines with Their Surroundings and Third Party Activities. Pipelines 2012: pp. 1233-1244. 7. Van Heck, G.J. and Twigt. F.A. Linking drinking water supply level of service to RAM performance criteria of production and pumping installations. Proceedings of Asset management Conference 2012, IET and IAM. 27-28 November 2012. London. 1 Waternet is a water cycle utility taking care of wastewater, drinking water, surface water, groundwater and safety behind dykes in Amsterdam and surroundings Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: geertjan.van.heck@ waternet.nl [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jan 2008 Expected end date: 2017 Key words: Asset management, decisionmaking Cooperation with other institutes: Waternet 89 Individual Projects Alexander Hendriks High-rate VFA production from industrial waste using the granular sludge process Research objectives Figure 1 gives an overview of the reactor setup that is For the production of bioplastics, polyhydroxyalkanoate going to be used for this research. (PHA) can be used as raw material. For efficient PHA production, volatile fatty acids (VFAs) are needed, which Results can be obtained through anaerobic fermentation using The project aims on elucidating typical process engineering low-grade wastewater. Using granular sludge technology related aspects of the process like the impact of solids for the fermentation process could enhance conversion retention time and operational variables. Figure 2 is an efficiencies, reduce reactor size and will lead to biomass example of the temperature and pH dependent growth free, but VFA rich effluent. The application of granular rate of Clostridium butyricum according to a Cardinal sludge technology for VFA production of wastewater growth model. Experiments will be conducted with is however a largely unexplored research topic. Aim of specific substrates and mixtures of substrates (artificial this research is to develop a novel reactor technology wastewater). Also the influence of (un)degradable solids using different operational conditions and (mixtures of) on the granule formation and VFA product spectrum will substrates and study its effect on granule formation and be investigated. VFA product spectra. Project outline Scientific relevance The application of the granular sludge technology for Introduction pre-acidification of wastewater is a largely unexplored Polyhydroxyalkanoates (PHAs) are biopolymers produced research topic. This results of this research should by many different bacteria as an intracellular carbon and shed some light on the effects of different operational energy reserve material. In response to the problems and conditions and (mixtures of) substrates on granule harmful effects of plastic wastes on the environment, formation and VFA product spectra. PHAs attract considerable attention as alternative for petroleum based plastics because they are biodegradable Social relevance and made from renewable resources (Braunegg et al., As mankind we should shift to a more sustainable and 1998; Leaversuch, R., 1987). This research will focus biobased society. VFA’s are a useful building block for on the production of a VFA rich medium from effluent products in this biobased society, as for bioplastics. of agro- and food industries. This medium could be used The results of this research will bring valorization of hereafter for bioplastic production or utilised differently. wastewater streams a step closer. Approach Literature For efficient PHA production, the conversion of organic Braunegg, substrate into VFA should be maximized, the VFA Polyhydroxyalkanoates, biopolyesters from renewable composition should be controllable, production of resources: physiological and engineering aspects. Journal hydrogen and methane gas should be avoided, biomass of Biotechnology 65 (2-3), 127-161. concentrations in the bioreactor’s effluent should be Johson, K., Jiang, Y., Kleerebezem, R., Muyzer, G., Van minimized and the reactor should be as compact as Loosdrecht, M.C.M., 2009. Enrichment of a mixed possible to minimize investment costs. A possible way bacterial culture with a high polyhydroxyalkanoate to fulfill these objectives is by using a granular sludge storage capacity. Biomacromolecules 10 (4), 670-676 process. The research will focus on granule formation, Leaversuch, R., 1987. Industry weighs the need to make stability and the effects of operational conditions, like polymer degradable. Modified Plastics 64, 52-55 temperature and pH, and suspended solids as substrate on granules VFA production and VFA spectra. 90 G., Lefebvre, G., Genser, K.F., 1998. Alexander Hendriks Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Figure 1. Reactor set-up Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Sep 2013 Expected end date: Sep 2017 Key words: Volatile Fatty Acids, Anaerobic Fermentation, Bioplastics, Hydrogen Cooperation with other institutes: STW, Paques Figure 2. Example of a fermentation pattern during a stable period 91 Individual Projects Jingyi Hu Micro-pollutant removal from domestic wastewater treatment plant effluent by activated carbon Research objectives scale anthracite-sand filter was operated to immobilize This thesis aims at clarifying the adsorption mechanisms, PAC for micro-pollutant adsorption from the secondary i.e. the adsorption competition between micro-pollutants effluent of a WWTP. and the bulk organic matter originated from wastewater treatment plant (WWTP) effluents; and identifying the Results optimal application of activated carbon in the WWTP for The PAC with the highest amount of micropores performed efficient micro-pollutant removal. The following research the best for micro-pollutant adsorption in a batch system questions were raised: where site competition was the main mechanism (Hu ▪▪ ▪▪ ▪▪ ▪▪ What type of activated carbon is less subjected to et al., 2014a). While the GAC, exhibiting a wider pore adsorption competition? size distribution (including micropores and mesopores), Which fraction of the bulk organic matter contributes was apt to the bulk organic matter preloading, reducing most to the adsorption competition? the micro-pollutant adsorption considerably (Hu et al., How are the physicochemical properties of the 2015c). In terms of the co-present organic matter, it was target micro-pollutant related to the adsorption discovered that the low molecular weight organics (Hu competition? et al., 2014a) and the hydrophobic organics (Hu, 2015) Where to dose powdered activated carbon (PAC) in represented the most competing components, mainly the WWTP? How to dose the PAC to the tertiary filter via site competition. During full-scale operation of a GAC of a WWTP? filter, the low molecular weight organics occupied the micropores of GAC, rendering less adsorption sites for the Project outline target micro-pollutant (Hu et al., 2015b). The positively Introduction charged and hydrophobic micro pollutants were less Activated carbon has been widely applied for surface influenced when GAC was preloaded by the co-present water treatment (Hu et al., 2014b), and is increasingly bulk organic matter (Hu et al., 2015c). being adopted for the advanced wastewater treatment, particularly aiming at micro-pollutant removal. The It was suggested to dose PAC in secondary effluent of a adsorption ability of activated carbon for micro-pollutants WWTP instead of primary effluent (e.g. in the activated is compromised by the co-present organic matter, e.g. sludge tank), due to less site competition derived from the humic substances, polysaccharides, proteins, lipids, the secondary effluent, which contains less low molecular small acids etc, via adsorption competition. In practice, weight organics (Hu, 2015). As an alternative option of the approach of activated carbon application in the dosing PAC in the secondary effluent, a novel approach WWTP can determine its utilization efficiency. This work to immobilizing PAC inside the WWTP tertiary filter has been carried out to add more scientific and practical demonstrated its feasibility and effectiveness. Specially, insights on micro-pollutant elimination from the WWTP a homogeneous distribution of PAC particles inside the effluent by activated carbon adsorption. filter bed offered a delayed micro-pollutant breakthrough (Hu et al., 2015a). Approach Various PACs and granular activated carbons (GACs) Scientific relevance were used in batch and small-scale column experiments. Although numerous studies have attempted to elucidate WWTP effluent containing the co-present organic matter the mechanisms of adsorption competition, there seems was isolated by an anionic exchange resin (AER) and a very few successful strategies that have been proposed in nanofiltration membrane (NF), respectively, to analyze practice to reduce adsorption competition. This research the influence of different organic matter fractions. A further clarifies the adsorption competition between subset of pharmaceutically active compounds (PhACs) micro-pollutants and the organic matter originated was selected as the main target micro-pollutants. A pilot- from WWTP effluents. Furthermore, it demonstrates an 92 Jingyi Hu economic and effective approach to enhancing the activated carbon utilization in WWTP. Societal relevance Advanced wastewater treatment for micro-pollutant elimination is becoming a necessity throughout Europe and the rest of the world. This research provides practical solutions e.g. pre-treatment of the copresent organic matter, reuse of the spent GACs, and applying PAC in a fixed-adsorber mode, for improving the removal of micro-pollutants from WWTP effluents. Literature Hu, J., Aarts, A., Shang, R., Heijman, B., Rietveld, L., 2015a. Integrating powdered activated carbon into a tertiary filter for micro-pollutant removal from wastewater secondary effluent. In preparation. Hu, J., Martin, A., Shang, R., Siegers, W., Cornelissen, E., Heijman, B., Rietveld, L., 2014a. Anionic exchange for NOM removal and the effects on micropollutant adsorption competition on activated carbon. Sep. Purif. Technol. 129, 25-31. Hu, J., Shang, R., Deng, H., Heijman, S.G.J., Rietveld, L.C., 2014b. Effect of PAC dosage in a pilot-scale PAC–MBR treating micro-polluted surface water. Bioresour. Technol. 154, 290-296. Hu, J., Shang, R., Heijman, B., Rietveld, L., 2015b. Reuse of spent granular activated carbon for organic micro-pollutant removal from treated wastewater. J. Environ. Manage. 160, 98-104. Hu, J., Shang, R., Heijman, S.G.J., Rietveld, L.C., 2015c. Influence of activated carbon preloading by EfOM fractions from treated wastewater on adsorption of pharmaceutically active compounds. Chemosphere, Under review. Hu, J., Shang, R., Frolova, M., Heijman, B., Rietveld, L, 2015. Pharmaceutical adsorption from the primary and secondary effluents of a wastewater treatment plant by powdered activated carbon. Desalination and Water Treatment, under minor revision. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Mar 2011 Expected end date: 2017 Key words: Organic micro-pollutants, activated carbon, wastewater treatment plant, adsorption competition, tertiary filter Cooperation with other institutes: - 93 Individual Projects Nan Jiang Zeolites as novel adsorbent in water treatment Research objectives while MFI type zeolites showed no obvious adsorption. The objectives of the project are removing organic BEA type zeolites had slightly better performance than micropollutants with high-silica zeolites. The aim is to MOR zeolites. In most cases, zeolite with higher SiO2/ ensure high water quality standards at lower operational Al2O3 mole ratio showed higher adsorption capacity, costs and at a lower environmental footprint compared to since they are more hydrophobic. activated carbon. Adsorption of phenol: Phenol is a small and highly Project outline water-soluble compound. The capacity of all tested Introductio zeolites for phenol were below 5mg/g at the equilibrium Currently, activated carbon filtration is the state-of-the- concentration range 0-5mg/L. No significant relationship art for the adsorption of organic micropollutants. High- was observed between framework type, SiO2/Al2O3 silica zeolites can be an attractive alternative adsorbent mole ratio of zeolites and adsorption capacity. MFI type for activated carbon, as, zeolites, the pore size of which are similar to the molecule ▪▪ Most NOM molecules are larger than the zeolite size of phenol, did not show higher adsorption capacity pores (<1 nm), and consequently will not compete than other zeolites. with targeted organic micro-pollutants or AOC for ▪▪ adsorption [Hung and Lin 2006]. Adsorption of 2,4,6-trichlorophenol: The adsorption The adsorption is more effective with high-silica experiments of 2,4,6-trichlorophenol is undergoing now. zeolites than with activated carbon when there is a close match in size between pollutant molecule and Scientific relevance zeolite pore[Ridder e.a. 2012]. Zeolites can be applied as a novel adsorbent to remove a broad range of micropollutants. Their mechanism and Approach kinetics will be studied in detail. Adsorption and oxidation ▪▪ A broad set of pharmaceuticals is selected with regeneration process can be combined to ensure the variations in molecule charge, size and hydrophobicity. long-term adsorption efficiency. ▪▪ ▪▪ A series of commercial, high-silica zeolites are selected based on a close fit with pharmaceuticals in Literature the selected set. H.-W. Hung, T.-F. Lin, Adsorption of MTBE from 3 target organic compounds are selected in the contaminated test: phenol, 2,4,6-trichlorophenol and tricloson, mordenite zeolite, J. Hazard. Mater., B, 135, 210-217, with molecular weight 94, 197 and 289.54 g/mol, 2006. respectively. Adsorption performance is related D.J. de Ridder, J.Q.J.C. Verberk, S.G.J. Heijman, G.L. Amy, to J.C. van Dijk, Zeolites for nitrosamine and pharmaceutical possible adsorption mechanisms (close fit, hydrophobic interaction, charge interaction). removal from water by carbonaceous demineralised and resins surface and water: Mechanisms and efficacy. Separation and Purification Results Technology, 89, 71-11, 2012. The data from experiments are analyzed by Langmuir Zhang Y, Mancke RG, Sabelfeld M, Geissen S-U, adsorption isotherm model. Most of the results fit Adsorption of Trichlorophenol on Zeolite and Adsorbent Langmuir models well by giving R2 value more than 0.9. Regeneration with Ozone. Journal of Hazardous Material, Adsorption of triclosan: Triclosan has the largest molecule 271, 178-184, 2014. size among the 3 tested pharmaceuticals. The highest adsorption capacity which is 370.37mg/g, was achieved by FAU(500)(SiO2/Al2O3 mole ratio=500). FAU type zeolites with largest pore size and BET surface area displayed the highest adsorption capacity for triclosan, 94 Nan Jiang Table 1. Basic properties of selected zeolites Table 2. Langmuir isotherm parameters for adsorption of tricloson by FAU type zeolites Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 15 2783539 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Nov 2014 Expected end date: Oct 2018 Fig. 1. Results of phenol adsorption by high-silica zeolites Key words: Zeolites, micropollutants, AOC, NOM, oxidation regeneration Cooperation with other institutes: Evides, PWN, Oasen, HWL 95 Individual Projects Maarten Keuten DIPool: Dutch Innovative Pool Advanced UV-based technology for pool water treatment Research objectives Results Reduction of chemical disinfectants in public swimming The biofilm formation potential was studied at different pools. This can be done by combining alternative swimming pool conditions. Both chlorinated and non/ disinfection techniques with adapted water treatment in chlorinated swimming pool water have low biofilm formation a new pool water treatment concept including aspects potential compared to tap water at 30°C (figure 2). of hygienic control of pool visitors. The goal is to have The use of biological filtration in both chlorinated and chemical disinfectant free swimming pool water for public non-chlorinated pool water treatment improves the swimming pools. removal of nitrogen containing pollutants, which can be seen at the concentration of nitrate-n, which is more or Project outline less equal to the concentration of total nitrogen (figure Introduction The main disadvantage 3). On the absence of a biological filtration, nitrogen of chemically disinfected containing pollutants are remaining which may lead to swimming pools is the formation of unwanted disinfection the formation of nitrogen containing DBP. by-products (DBPs). Reducing DBPs by abandoning Hygienic behaviour of swimmers can be changed with the chemical disinfectants introduces new challenges for use of arguments. Pre-swim showering increased from pool water treatment. The DIPool project investigates 25-28% during the experiment with the use of carefully swimming pool water treatment without chemical designed stickers (figure 4). The awareness on the disinfectants to face these challenges. The biological importance of hygienic behaviour among swimmers needs stability of swimming pool water, pool water treatment to be improved to reduce the release of anthropogenic and the hygienic behaviour of swimmers was studied in pollutants. 2014. Approach A pilot plant setup was used to focus on the pool water treatment at chlorinated and non-chlorinated swimming pool conditions (figure 1). The biofilm formation potential was determined with the use of membrane fouling simulators. Efficiency of treatment steps was also determined. The hygienic behaviour of swimmers was studied in cooperation with behavioural scientists from Twente University. Figure 2. Biofilm formation potential during chlorinated and non-chlorinated experiments Figure 3. Concentrations of NPOC, TN and nitrate-N during chlorinated and non-chlorinated experiments Figure 1. Experimental setup DIPool for biological stability and treatment efficiency 96 Maarten Keuten Figure 4. Sticker to improve hygienic behaviour of swimmers Scientific relevance Current pool water treatment relies on chemical disinfection. The development of a pool water treatment with alternative disinfection techniques is a new field of expertise. The influence of the dynamic bathing load on the water quality must be kept in control. Creating stable microbial pool water without the use of chemical disinfectants can lead to new viewpoints for comparable water treatment processes. Social relevance Since the early ages bathing and swimming play an important role in communities. The use of water basins changed over ages, while swimming has always been a social activity. Complaints about “swimming pool odour” and eye irritation are common reasons why nowadays some people never visit public swimming pools. UV-Disinfected swimming pools will provide healthy swimming without nuisance from disinfection Delft University of Technology Faculty of Civil Engineering and Faculty of Applied Sciences E-mail: [email protected] / [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2628 CN Delft by-products. Julianalaan 67 2628 BC Delf Literature Start date project: End date project: M.G.A. Keuten, M.C.F.M. Peters, H.A.M. Daanen, M.K. de Kreuk, L.C. Rietveld, J.C. van Dijk Quantification of continual anthropogenic pollutant release in swimming pools Water Research 53, (2014) p.259270. M.G.A. Keuten, F.M. Schets, J.F. Schijven, J.Q.J.C. Verberk, J.C. van Dijk Corrigendum to “Definition and quantification of initial anthropogenic pollutant release in swimming pools” Water Research 49, (2014) p.484. M.G.A. Keuten, F.M. Schets, J.F. Schijven, J.Q.J.C. Verberk, J.C. van Dijk Definition and quantification of initial anthropogenic pollutant release in swimming pools Water Research 46 (2012) p.3682-3692. Jan 2009 2017 Key words: Swimming pools, alternative disinfection, disinfection by-products, anthropogenic pollutants, pool water treatment, CFD, biofilm formation potential Cooperation with other institutes: Hellebrekers Technieken, Van Remmen UV techniek, Akzonobel Industrial Chemicals, Coram International, Sportfondsen Nederland 97 Individual Projects Rian Kloosterman Improving the effectiveness of assetmanagement of the drinking water process Research objectives Approach Vitens wants to know how they can integrate future The research area is defined and divided into 3 research uncertainties in their decisions of today. The investment parts, corresponding with the three questions. The three and operational decisions, or governance, concern all research parts are subdivided into smaller parts. the assets which are needed to produce drinking water. This is called asset management of the drinking water Results infrastructure. Two draft publications are submitted. All the processes which are needed to manage 1) A better relation between innovation and public the assets is the assetmanagement process. The infrastructures; Drivers for successful innovation. assetmanagement process is in a complex way influenced 2) Conflicting claims; Water provision in a world of by a lot of stakeholders, physical conditions and technical infrastructures possibilities, a so called (drinking water) system. Project outline Scientific and social relevance Assetmanagement is a young research field. Combining The main question is to develop “rules” to handle future scientific (institutional) theories in assetmanagement uncertainties in the assetmanagement drinking water theories for new assetmanagement questions is the process. scientific contribution. To answer this question the following sub-questions have to be answered: Literature 1. Understanding and characterizing the system and the PM different components. 2. Understanding and describing the complexity of the system in different environments 3. Developing “rules” to handle future uncertainties To handle future uncertainties in the assetmanagement drinking water process several theoretical concepts are important: Common pool resources, Time dependency, Uncertainty and Values. 98 Rian Kloosterman Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: May 2012 Expected end date: Oct 2017 Key words: Strategic assetmanagement, governanace, long term uncertainty Cooperation with other institutes: PhD is a collaboration between the faculty of CiTG and TBM 99 Individual Projects Guido Kooijman Application of flocculants in todays sewage treatment plant Research objectives Results Effects of application of flocculants as chemically Although pharmaceuticals are reported to sorp to colloids enhanced primary treatment on a sewage treatment in sewage to large extent, they could not be removed from plant with a special focus on pharmaceutical removal, wastewater by removing the colloids with flocculation. anaerobic digestion and sludge dewatering. We investigated the reason for this and it appeared that pharmaceuticals do not sorp to small particulates (>0.1 Project outline µm). Introduction Application of chemically enhanced pre-treatment (CEPT) The sludge resulting from CEPT with flocculants appeared is not widely used in the Netherlands. This is mainly to be better degradable in anaerobic digestion (AD) with because the critical COD/N ratio for denitrification will higher degradation rates and higher biomethane potential be negatively influenced by extensive pre-treatment. (BMP) of the sludge. This was investigated and it was However, with the perspective of a low COD/N tolerant concluded that this was partially due to the flocculation sewage treatment plant (STP) such as Nereda with of more easily degradable material and partially due to nitritation and Anammox (Winkler, Kleerebezem, & van the reduced viscosity. Adding flocculants directly to the Loosdrecht, 2012), CEPT is a concept that will regain digester showed a higher digestion rate but a lower attention in the future. Although CEPT is used already Biomethane potential (BMP) due to irreversible binding of since the ’30, in the Optimix project CEPT is evaluated the substrate. This is shown the figure below. as a solution for today’s problems. Micro pollutant treatment, sludge dewaterability, improved biogas anaerobic digestion as well as small footprint sewage treatment plants (STPs) are considered in this project. Approach The consumption of pharmaceuticals has increased over the last decades and is expected to further increase in the future (Griens, 2010). The treatment of these compounds in STPs is not complete and therefore pharmaceuticals are accumulating in the environment. In literature, pharmaceuticals are reported to sorb to large extent to colloids. And since CEPT with flocculants enhances the removal of colloids, a large share of pharmaceuticals were expected to be concentrated in the primary Also sludge dewatering is affected with the application sludge, facilitating the treatment of these persistent of CEPT with flocculants. Even after digestion the effects compounds. Application of CEPT will also have an impact of flocculants applied in the primary settler is well on the subsequent STP treatment units. The anaerobic maintained resulting in a particulates and a lower soluble digestion (AD) may be affected and since flocculants are protein content. known to be poorly biodegradable in AD, the final sludge dewatering might be favored by CEPT as well. CEPT were Scientific relevance used to flocculate raw sewage to create the samples for This work gives more insight in the effects of flocculants our laboratory experiments. Furthermore, experiments on an anaerobic digester and opens the new perspective with primary, secondary and digested sludges were on pharmaceutical sorption in sewage. performed to study the effects of CEPT dosage. 100 Guido Kooijman Social relevance The treatment plant of the future will allow for a lower COD/N ratio and this will open the opportunity to remove as much as possible COD from the wastewater as possible. Doing this with flocculants can have several advantages such as small plant food print, higher biogas or VFA production, lower aeration requirements and increased dewatering of waste sludge. Literature Griens, A. M. G. F. (2010). Data en feiten 2010 - het jaar 2009 in cijfers. Stichting Farmaceutische Kengetallen. Winkler, M.-K. H., Kleerebezem, R., & van Loosdrecht, M. C. M. (2012). Integration of anammox into the aerobic granular sludge process for main stream wastewater treatment at ambient temperatures. Water Research, 46(1), 136–44. doi:10.1016/j.watres.2011.10.034. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jan 2011 Expected end date: 2017 Key words: Anaerobic digestion, micro pollutants, flocculants, sludge dewatering Cooperation with other institutes: Hoogheemraadschap van Rijnland Nalco B.V. Het Waterlaboratorium 101 Individual Projects Franca Kramer Ceramic nanofiltration as the key step for sustainable wastewater treatment with reclamation of water, energy and nutrients Research objectives Project outline Where people live and work, wastewater is produced that First, the interaction between the feed water and has to be cleaned before discharge. Moreover, the quantity the membrane surface will be investigated on lab of clean and safe water is decreasing worldwide, as well scale with artificial and real wastewater to obtain a as our current nutrient sources like phosphate mines that better understanding of the fouling behaviour in the are depleting. The goal of this research project is to study membranes. This knowledge will be useful for all the a new concept of reclamation of water, nutrients and next research objectives. Second, different membrane energy from municipal wastewater. The concept consists cleaning methods will be tested to obtain the best way of a fine sieves to remove large particles followed by to control fouling. Then, the water recovery and fluxes a newly developed ceramic nanofiltration membrane. of this filtration technique will be optimised to increase The wastewater is expected to be concentrated with at the efficiency, e.g. by using different stages of filtration. least a factor 5, which results in a more than 80% water Finally, a theoretical description of the ion retention recovery. This water is polished with reverse osmosis to behaviour in the membranes will be studied, using make it suitable for industrial use, while the concentrate transport mechanisms, ionic balances and experimental from the ceramic membrane and the debris is fed to a data to gain insight in the mechanisms of ceramic digester to produce biogas, while nutrients from this flow membrane filtration. are recovered by precipitation (see alsofigure 1). From lab and pilot scale, this innovative concept will be scaled Scientific relevance up to a demo plant in Stadshaven area in Rotterdam, the Scientific knowledge on ceramic nanofiltration membranes Netherlands, to provide high quality water to industries is very limited especially in terms of wastewater treatment. in that area. This PhD research will lead to the understanding of the ceramic nanofiltration and the driving forces of the This PhD research focusses on ceramic nanofiltration, filtration process. With this knowledge, the ceramic the core of this concept. The research objectives are (i) nanofiltration process can be designed to operate in the understanding interaction between membrane and cake most economical efficient way, considering the amount layer formed by the retained suspended (and dissolved) water produced and energy and chemical consumption. matter, (ii) controlling the membrane fouling, and (iii) optimising water recovery and fluxes. Social relevance Currently municipal wastewater is treated as a waste; after collecting municipal wastewater in the sewer system, and leading it through a wastewater treatment plant, the water is discharged in the rivers. In this ceramic nanofiltration concept municipal wastewater is used as a resource for the reclamation of high quality water, energy and nutrients. As our current reserves for fresh water, energy, and nutrients (e.g. phosphate) are becoming scarce, this concept will contribute to a more sustainable Figure 1. New concept for reclamation of high quality water, energy and nutrient from municipal wastewater using ceramic nanofiltration society. This research is part of the RINEW (Rotterdam Innovative Nutrients Energy Water) project, which is searching for alternative concepts for the reclamation of municipal wastewater from city areas and transfer it to valuable products. RINEW is a collaboration between Evides 102 Franca Kramer Industriewater, TU Delft, the City of Rotterdam, Hoogheemraadschap van Delfland, Waterschap Hollandse Delta, and Clean Tech Delta. Literature Kramer, F.C., Shang, R., Heijman, S.G.J., Scherrenberg, S.M., van Lier, J.B., Rietveld, L.C., 2015. Direct water reclamation from sewage using ceramic tight ultra- and nanofiltration. Sep. Purif. Technol. 1–21. Shang, R., Vuong, F., Hu, J., Li, S., Kemperman, A.J.B., Nijmeijer, K., Cornelissen, E.R., Heijman, S.G.J., Rietveld, L.C., 2015. Hydraulically irreversible fouling on ceramic MF/UF membranes: Comparison of fouling indices, foulant composition and irreversible pore narrowing. Sep. Purif. Technol. 147, 303–310. Shang, R., 2014. Ceramic Ultra- and Nanofiltration for Municipal Wastewater Reuse. PhD Thesis. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jun 2014 Expected end date: Jun 2018 Key words: Ceramic Nanofiltration, wastewater, demi water production, sewer mining Cooperation with other institutes: Evides Industriewater 103 Individual projects Niels van Linden Project Description N2kWh – From pollutant to power Research objectives harmless N2 and water: no greenhouse gas emission. The objective of this research is to develop an energy This electrochemical process results in the production positive system, including a solid oxide fuel cell, removing of both electrical and thermal energy (Wojcik, Middleton ammonia from low carbon, high nitrogen residual water et al., 2003). SOFCs are considered to be high efficient streams. energy production systems, having an electrical efficiency of approximately 50% and a total energy efficiency of 85 Project outline – 95% (Larminie & Dicks, 2003). Introduction Ammonia (NH3) is world’s second most produced chemical Approach and is a vital resource for protein production. One of the An SOFC has various fuel requirements, which do not reasons NH3 becomes present in residual (waste) water match to the composition of the residual water streams. streams is protein degradation by organisms. NH3 is Therefore, a suitable NH3 fuel must be produced from regarded to be a pollutant for aqueous environments, the residual streams. To this extent, a concentration step because it potentially leads to algae blooming. and a gas production step are required. The selection of the most suitable techniques for these steps is key In order to avoid environmental pollution, NH3 must be for this research. After the selection, experiments will removed from residual water streams, before the water be conducted in order to optimize the performance of is discharged to the aqueous environment. Current the respective techniques. Simultaneously, a mass and methods applied in waste water treatment plants (WWTP) energy balance tool will be developed to evaluate various consume significant amounts of energy. For example: scenarios. aeration (to facilitate NH3 removal by (de-)nitrification)) accounts for approximately 50-70% of the total energy The produced electrical and thermal energy can internally usage of a WWTP. be used, in order to produce a suitable fuel from the residual water streams. When the energy consumption of the fuel production process is lower than the energy production of the SOFC, an energy positive system to remove NH3 from residual streams can be realized. Results Initial experiments with a SOFC on NH3 showed that 2.88 [kWh/kg-NH3] of electrical energy could be produced when using a 10% w/w NH3 fuel. Additionally, in exploring electrodialysis experiments, it was shown that the migration of ionized NH3 required 0.40 – 0.65 [kWh/kg-NH3]. This performance indicator can be used to determine the energy consumption for ionized NH3 concentration. This project focusses on the recovery of NH3 from residual streams and subsequent processing of NH3 fuel ¬in a solid oxide fuel cell (SOFC). In a SOFC, NH3 will be cracked into nitrogen gas (N2) and hydrogen gas (H2). The H2 is oxidized using oxygen gas (O2), which is present in air. The exhaust gases of a SOFC contain 104 Niels van Linden Scientific relevance Multiple topics in this research will be of scientific relevance, such as the mechanisms and energy optimization for concentration processes of ionized NH3. The same holds for the production of a suitable NH3 fuel for an SOFC out of concentrated NH3 residual streams. Additionally, the performance of a SOFC on NH3 fuel produced from residual streams has not be studied previously (according to current understanding). Social relevance The processing of NH3 in the described system addresses both the production of clean energy and the treatment of residual water streams. Since NH3 is no longer seen as pollutant, but as a compound carrying energy, this might lead to a paradigm shift: from pollutant to power. Considering NH3 as a suitable energy carrier as alternative for carbonbased compounds, adds to the promotion NH3 usage for residual produced sustainable energy (from wind, sun, water, etc.) storage. The energy reclamation of NH3 by means of a SOFC further strengthens this idea. Finally, the energy savings on the current techniques for NH3 removal from residual streams might directly lead to financial consequences for residual water treatment. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 6 51260780 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Apr 2016 Expected end date: Apr 2020 Key words: Ammonia, SOFC, Electrodialysis, Electrochemistry Cooperation with other institutes: KU Leuven Literature Larminie, J., & Dicks, A. (2003). Fuel Cell Systems Explained. Southern Gate, Chichester: John Wiley & Sons Ltd. Wojcik, A., Middleton, H., Damopoulos, I., & Van herle, J. (2003). Ammonia as a fuel in solid oxide fuel cells. Journal of Power Sources, 118(1–2), 342-348. doi:http://dx.doi.org/10.1016/S03787753(03)00083-1 105 Individual Projects Antonio Manuel Moreno Rodenas Propagation of uncertainties in integrated catchment models Research objectives Approach In the Eindhoven catchment, calibrated detailed water This research has as main target to increment the current quality models are available for the sewer, WWTP and knowledge on catchment scale water quality modeling. receiving waters, together with a simplified integrated The objectives involve: model (eg. in Langeveld et al., 2013). In addition, validated monitoring data is available in all sub compartments. ▪▪ ▪▪ ▪▪ ▪▪ Study how operational applications of integrated This provides an excellent opportunity to assess the catchment modeling affect the model structure propagation of uncertainties in integrated models, as definition. monitoring data is available on the input (rainfall) and the Evaluate the effects of spatiotemporal variability in output (ammonia and dissolved oxygen concentration in rainfall inputs on the model outcomes for dissolved the receiving waters), as well as intermediate locations oxygen/Ammonium quantification. (CSOs, WWTP, influent). Evaluate the trade off between model complexity and information present in rainfall products. This enables the influence of model structure uncertainty Quantify how uncertainties propagate through the transmission to be examined by comparing the uncertainty different components of a simplified integrated in the full and simplified models. catchment model Project outline Scientific and social relevance Watershed management under model-based decision Introduction making requires of a deeper knowledge of the uncertainty The use of an Integrated Catchment Models (ICM) produced in current water quality models, this project is a common strategy to assess the compliance of will try to provide a more complete identification of the environmental requirements on water systems, to production and transmission of it in each sub model part. generate optimal decisions in infrastructure investment or This can lead to a better understanding of the overall acting as a valuable tool for policy makers. Unfortunately, process and to be able to highlight the further research due to the number and complexity of the linked processes needs on data acquisition techniques features. and the scarcity of monitoring data, the predictive capability of these models is often compromised. It is Social relevance henceforth of importance to acknowledge the degree of An incorrect investment plan can either overestimate or uncertainty present in their responses. Allowing taking underestimate the real needs of the physical system, decisions from an informed perspective and avoiding wasting social resources or not fulfilling the quality “blind” confidence on the model outcomes. requirements. With a finer assessment of the uncertainty in model results, decision makers can select corrective Large water systems at catchment scale are composed measures and management practices under an objective by several urban systems draining their waters along a and informed perspective. natural water body. Heavy storm events induce combined sewer systems to overflow untreated wastewater at different locations in the river. Those sub catchments are located at distances beyond the decorrelation lengths of many rainfall processes. Henceforth variability in time and space of precipitation inputs influence the processes in the system. It is still to assess what is the degree of spatial and temporal discretization necessary to be able to represent water quality dynamics in the receiving waters. 106 Antonio Manuel Moreno Rodenas Literature J.G. Langeveld, L. Benedetti, J. J. M. de Klein, I. Nopens, Y. Amerlinck, A. van Nieuwenhuijzen, T. Flameling, O. van Zanten & S. Weijers (2013). Impact-based integrated real-time control for improvement of the Dommel River water quality. Urban Water Journal 10-5. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: a.m.morenorodenas-1@ tudelft.nl www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Room 4.64 Start date project: Dec 2014 Expected end date: Dec 2018 Key words: Uncertainty transmision, integrated modeling, water framework directive Cooperation with other institutes: University of Bradford, University of Sheffield, University of Bristol, Halcrow Group Limited, Wageningen Universiteit, JustusLeibig-Universitaet Giessen, Centre de Recherche Public Henri Tudor, Eaewag: Swiss Federal Institute of Aquatic Science and Technology 107 Individual Projects Julian Muñoz Sierra BioXtreme – Anaerobic wastewater treatment under extreme conditions Research objectives Approach The aim of the study is to understand the bioconversion of A selection of waste streams of interest is made, i.e. at those model organic compounds (toxic/recalcitrant) existing in industries where increased water efficiency is considered industrial wastewaters streams under extreme conditions. but hampered by the nature of the organic pollutants The research is focused on the most suitable technology for present. The treatability of the process water stream will this purpose (i.e. anaerobic membrane bioreactors, AnMBrs) be researched under controlled lab conditions and synthetic to encourage reclamation of process waters for reuse. wastewater making use of down-scaled reactor systems. Attention is paid to the bioaugmentation of specific microbial Relevant aspects of interests will be addressed such as communities and their growth dynamics in highly filterable biomass sludge. An online control strategy will be proposed for the of organic compounds, microbial population dynamics, mitigation of membrane fouling within a long term operation filterability, and fouling potentials. Trials will be conducted of the AnMBRs, specially under thermophilic conditions. with phenolic compounds. Phenol is a key intermediate in retention/bio-augmentation, conversion/toxicity the anaerobic conversion of a wide variety of aromatics, Project outline and, therefore, is of particular interest. Anaerobic treatment Introduction of phenol-containing wastewater has been mostly carried Industrial wastewaters generated in oil and chemical out using granular reactors, and its application has been industries are often characterized by extreme conditions limited under mesophilic and ambient temperature making such as the presence of refractory and hazardous chemical the anaerobic degradation of phenolic compounds under compounds, high salinity, high temperatures. Particularly thermophilic condition a challenge for AnMBRs. The microbial for these extreme types of wastewaters the conventional community from the reactors will be analyzed using different biological technologies have many limitations, but membrane techniques. assisted bio-treatment offers many advantages such as inreactor bio-augmentation of the required bacterial species Experimental set-up and maximized sludge retention times (SRT), ensuring high The experiments are performed using three laboratory metabolic conversion properties per unit of reactor volume. scale anaerobic MBR reactors with an effective volume of In case auto-immobilization or sludge granulation is difficult, 7°L, and using an ultra-filtration (UF) membrane modules. application of membrane technology for pre-treating The systems are equipped with feed, recycle and effluent industrial process waters has several striking advantages: pumps, pH and temperature sensors and a gas meters. i) system compactness, allowing installation at or even Biogas recirculation pumps are used to mix the liquor. The inside the industry; ii) production of suspended solids free temperature of the jacketed reactors is controlled at 35.0° effluents, simplifying effluent upgrading techniques; iii) full and 55.0° ± 0.8°C by thermostatic water baths. Currently, retention of specific bacterial communities that are required tubular PVDF membranes with 5.5 mm inner diameter and for conversion of complex, recalcitrant and hazardous 0.64 m length are employed. The experimental system compounds. is connected to a computer running LabView software to There is an urgent need for sustainable and cost effective control all pumps and collect pH, temperature, pressures treatment technology that can make this water suitable for and biogas flow data on-line. (re-)use. BioXtreme is aiming to deliver such a technology. If industrial effluents are properly treated, pollution can be prevented, and water produced can serve as an alternative source for existing freshwater resources or industrial processes. Figure 1. Experimental set-up/Research keywords 108 Julian Muñoz Sierra Scientific relevance Extreme conditions in the process water and wastewater of the industrial sector encourage the development of non-conventional biological treatment solutions. The research will increase the understanding of how the complex compounds are converted by the microorganisms, what is the influence of different conditions on the biomass properties, microbial community and functionality, and how the process is addressed within the technology selected (AnMBR). Findings are compared with current technologies, elucidating the added advantages of the developed extreme bioreactor concept, including new process configurations and water reuse possibilities. Impact Enabling An-MBR application to a wide range of industrial processes with the potential of water reuse. Challenge Finding the optimum operational condition for maximised bioconversion under extreme conditions, without being limited by reduced membrane Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section fluxes. E-mail: [email protected] www.sanitaryengineering.tudelft.nl Social relevance Postal address: P.O. BOX 5048 2600 GA Delft In the Netherlands, about 80% of the fresh water use is industrial use. The research is focused on fundamental and applied research into the wastewater treatment and reuse technologies for application in the industry to compile know-how for optimizing the industrial water cycle and reducing its water footprint. Research with the final aim in water recycling has the potential to improve the effectiveness of the existing technologies and invest in the future well-being of the world’s population. Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Dec 2012 Expected end date: Dec 2017 Literature Dereli, R. K., M. E. Ersahin, et al. (2012). “Potentials of anaerobic membrane bioreactors to overcome treatment limitations induced by industrial wastewaters.” Bioresource Technology 122: 160-170 Jeison, D. (2007). Anaerobic membrane bioreactors for wastewater treatment: Feasibility and potential applications. PhD thesis. Wageningen University, Wageningen, The Netherlands Kleerebezem, R. (1999). Anaerobic treatment of Phthalates: Microbial and Technological aspects. PhD thesis. Wageningen University, Key words: An-MBR, aromatic compounds, biodegradation, salinity, thermophilic Cooperation with other institutes: Evides Industriewater, Paques, TU Delft Environmental Biotechnology section(EBT), Wageningen University Wageningen, The Netherlands Lin, H., W. Gao, et al. (2012). “Membrane bioreactors for industrial wastewater treatment: A critical review.” Critical Reviews in Environmental Science and Technology 42(7): 677-740. Van Lier, J.B. 2008 High-rate anaerobic wastewater treatment: Diversifying from end-of-the-pipe treatment to resource-oriented conversion techniques, pp. 1137-1148. 109 Individual projects Gabriela Paulus Investigations on the Pre-valence and Transfer of AR/ARG in Surface Water through MGEs and Investigations on the Possible Ecotoxic Effects of Antibiotics Research objectives The work proposed in this document will generate knowledge The research objectives are to (1) develop novel tools that will help to decrease the risk of outcomes which might for the detection and monitoring of AR and the transfer be unpredictable by the current state of knowledge and of AR/ARG in surface water bodies and to (2) apply will help to elucidate how unbeneficial situations might be innovative batteries of advanced tests for the evaluation created and what their impact on human health might be. of the effects of antibiotics and their metabolites in the environment and on human health (3) conduct a risk Approach assessment supported by data obtained. This will be done by employing different techniques in order to 1) prove and monitor transfer of antibiotic resistance and Project outline antibiotic resistance genes in surface water to quantify the Introduction impact of anthropogenic activities on the environmental Antibiotic resistance has been on the rise in recent years, resistome and 2) expose potentially harmful effects antibiotic increasing the risk of entering the “post-antibiotic era” . resistance might have on human health. The methods which Estimated expenses caused by antibiotic resistance range will be employed to achieve this goal will be discussed in the as high as 1.5 Billion Euros per year in Europe alone . The present document. estimated damage to human well-being and risk to society cannot be monetarily captured but can be said to be one of the most devastating effects of antibiotic resistance. Antibiotic resistance genes can emerge and propagate through different methods including horizontal gene transfer . Environmental bacteria are likely to serve as a reservoir for antibiotic resistance and antibiotic resistance genes which could be transferred to clinically relevant bacterial strains in surface water environments . 110 Gabriela Paulus Scientific relevance Scholars in the field have not yet adequately addressed the topic of transfer of antibiotic resistance genes in the environment, as only a small number of studies exist which trace the origin of antibiotic resistance in and to environmental bacteria and their transfer to clinically relevant bacterial strains Social relevance This gap of knowledge could result in disastrous outcomes for society, especially in an environmental and economic context and, more substantial, in the medical field. Literature Kåhrström, C. T. (2013). Entering a post-antibiotic era?. Nature Reviews Microbiology, 11(3), 146. ECDC/EMEA Joint Working Group. (2009). The bacterial challenge: time to react. EMEA/576176, 13-42. Wellington, E. M., Boxall, A. B., Cross, P., Feil, E. J., Gaze, W. H., Hawkey, P. M., Johnson-Rollings, A.S., Jones, D.L., Lee, N.M., Otten, W. and Thomas, C. M. (2013). The role of the natural environment in the emergence of antibiotic resistance in Gram-negative bacteria. The Lancet infectious diseases, 13(2), 155-165. Poirel, L., Rodriguez-Martinez, J. M., Mammeri, H., Liard, A., & Nordmann, P. (2005). Origin of plasmid-mediated quinolone resistance determinant QnrA. Antimicrobial agents and chemotherapy, 49(8), 3523-3525. Nordmann, P., & Poirel, L. (2005). Emergence of plasmid-mediated Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: gabriela.paulus@ kwrwater.nl Phone: +31 646186948 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering resistance to quinolones in Enterobacteriaceae. Journal of Antimicrobial Chemotherapy, 56(3), 463-469. Poirel, L. Rodriguez-Martinez, J.M., Mammeri, H. Liard, A., & Nordman, P. (2005). Origin of plasmid-mediated quinolone resistance determinant QnrA. Antimicrobial agents and chemotherapy, 49(8), 3523-3525. Start date project: Sep 2016 Expected end date: Sep 2020 Key words: antibiotic resistance, bioinformatics, mobile genetic elements, toxicology Cooperation with other institutes: KWR Watercycle Research Institute 111 Individual Projects Celma Niquice Technical aspects of reclaimed water treatment for irrigation purposes in Maputo Research objectives addition, a literature review will be conducted to analyze The aim of this project is to evaluate the technical current practices for irrigation with reclaimed water in aspects for water reclamation in Maputo and assess the Sub-Saharan countries, to evaluate reclaimed water potentials for water reclamation in Maputo for agriculture potential for irrigation in Maputo. Moreover, laboratory by analyzing current practices for irrigation with analysis for the selected treatment technology according reclaimed water in Sub-Saharan countries, evaluating to local conditions will be conducted. Furthermore, field reclaimed water potential for irrigation in Maputo, work/pilot test to evaluate the impact of wastewater selecting wastewater treatment technology and irrigation treatment technologies in irrigation systems operation. technique and evaluating the impact of wastewater treatment technologies in irrigation systems operation. Expected Results The main expected results from this project is the Project outline Identification of experiences of water reclamation for Introduction water reuse in sub-Saharan region, the potential amount Mozambique is facing water shortage: agricultural water of wastewater that can be reclaimed in Maputo, the uses accounts with around of 80% of total water uses existing wastewater quality for potential agricultural (DFID, 2003). From total available water flow only 46% users, the selection of wastewater treatment technology is produced in the country and projections indicate that to be used water for irrigation purposes. urban water demand will increase by about 40%, with industrial use being expected to augment by about Scientific relevance 65% (TWWW and GWP, 2013). Additionally, the storage this project is expected to contribute to: capacity is low and limits the expansion of agriculture, ▪▪ industries and the overall economic development of the country. Furthermore, access to sanitation services both Development of water reclamation solutions for irrigation that can be applied to the local situation. ▪▪ in cities and rural areas, is deficient. Less than half of Knowledge about local water quality available from different sources. population has improved sanitation systems, and only limited amounts of wastewater, which, in some areas, is Social relevance unsafely reused in irrigation. Also in, Maputo, many of From this research is expected that contribute to: these issues can be identified with the situation being ▪▪ solution to address these issues is water reuse. Some ▪▪ ▪▪ ▪▪ Increasing the relevance of water reuse as means of adding water to the water cycle guaranteeing the 2003) and contributes to urban development (Agodzo et availability of water in Mozambique for irrigation. al 2003). This study aims to evaluate the potentials for water reuse for agricultural purposes in Maputo. Building a realistic approach for water reclamation in agriculture for Maputo. contributes to addition of water source as well the addition of nutrients for the crops increasing yields (Duran et al Reducing the risks associated with untreated water for irrigation purposes. studies have pointed positive effects of water reuse in agriculture, such as that adequate water reclamation Reduction of pressure on freshwater resources by using reclaimed water. further exacerbated by population growth. A possible ▪▪ Influencing institutions and companies to change their decisions making and contributing to sustainable Approach The research methodology will involve both quantitative and qualitative analysis based on available primary and secondary data obtained through direct observations, direct interviews to individuals and field measurements. In 112 development of Mozambique. Celma Niquice Literature Agodzo SK, Huibers FP, Chenini F, van Lier JB, Duran A. 2003 Use of wastewater in irrigated agriculture. Country studies from Bolivia, Ghana and Tunisia. Volume 2: Ghana. Wageningnen: - W4F- Wastewater ISBN 90-6754-704-2 Department for International Development (DFID) 2003 Handbook for the assessment of water demand and use, United Kingdom consulted in 05.01.2015 http://www.samsamwater.com/library/handbook_ catchment_water.pdf Duran A, Moscoso O, Romero AM, Huibers FP, Agodzo SK, Chenini F, van Lier JB. 2003 Use of wastewater in irrigated agriculture. Country studies from Bolivia, Ghana and Tunisia. Volume 1: Bolivia. Wageningnen:W4F- Wastewater ISBN 90-6754-705-0] The World We Want (TWWW) and Global water Partnership (GWP) 2013: National stakeholder consultation on Water: Supporting the post 2015 agenda: Stakeholder Thematic Consultation Report consulted on http://www.gwp.org/Global/About%20GWP/Publications/Reports/ Country%20Consultation%20Reports/Mozambique%20Final%20 National%20Consultation%20Report.pdf Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected]@ tudelft.nl www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jul 2015 Expected end date: Jul 2019 Key words: Water reuse irrigation, waste water treatment, Agriculture water reclamation Cooperation with other institutes: UEM, UNESCO IHE 113 Individual Projects Marjolein Peters Biofilm growth on swimming pool materials Research objectives Within the DIPool project the overall goal is to develop a chemical disinfectant free swimming pool. The project consists of different sub-projects to study the contamination of swimming pools by users, the risks of chorine free swimming pools, prevention of biofilm growth and the development of a water treatment system. In the (sub)study described here, biofilm growth on different swimming pool materials under non-chlorinated swimming pool conditions was determined. Project outline Introduction Biofilms occur in water environments as soon as Figure 1. The set-up microorganisms settle on and attach to a surface. In Results swimming pools biofilms are unwanted, since they can The biofilm growth on the different materials was shelter pathogens introducing a health risk and they feel determined after 14 days of incubation, Figure 2. The slimy. In the DIPool project a swimming pool without lowest cATP concentration was found on polypropylene, the use of chemical disinfectants is proposed. In this indicating that this would be a good material to use in concept microorganisms are able to survive in the pool swimming pools. Highest cATP concentrations were found and form biofilms. To prevent biofilm growth under (non- for concrete and stainless steel and therefore they are not chlorinated) swimming pool conditions, biofilm formation preferred to use in a swimming pool. on different swimming pool materials was studied. The results can give insight in which material would be preferred to use in (chlorine free) swimming pools. Approach Biofilms were grown on 11 different swimming pool materials in a climate controlled set-up at 32˚C. A nonlimiting nutrient medium was used, containing mainly urea and a concentration of total carbon of 95 mg/L and total nitrogen of 199 mg/L. The materials were placed at the bottom of a jar for biofilm growth tests. 4 jars containing the same material were connected in series, Figure 1. The average biofilm Figure 2. The average biofilm growth after 14 days per pool material. Errorbars present the standard error of the mean of the 4 jars measured per lane development on each material was determined with intracellular ATP (cATP) measurements of the plates of Scientific relevance the 4 jars out of 1 lane. Although the materials used in this research are swimming pool materials, they are used outside swimming pools as well in, for example, drinking water and waste water pipelines and cooling towers. Therefore the results of this research can be extrapolated to other fields and prevent biofilm formation on surfaces where it is unwanted. 114 Marjolein Peters Social relevance Normally, chemical disinfection is used in swimming pools to ensure microbiologic safe swimming pool water. However, the use of a chemical disinfectant, like chlorine, produces also disinfection by-products (DBPs) which are bad for human health. One way of lowering DBPs could be done by not adding any disinfectants. Since microorganisms are not disinfected, they might start growing in a biofilm which could also shelter pathogens. It is therefore important to know which swimming pool materials promote biofilm growth and which prevent it. Literature M.G.A. Keuten, M.C.F.M. Peters, H.A.M. Daanen, M.K. de Kreuk, L.C. Rietveld, J.C. van Dijk. Quantification of continual anthropogenic pollutants released in swimming pools. Water Research 53 (2014) pages 259 - 270. Y. Bennani, M.C.F.M. Peters, P.W. Appel, L.C. Rietveld. Electrochemically active biofilm and photoelectrocatalytic regeneration of the titanium dioxide composite electrode for advanced oxidation in water treatment. Electrochimica Acta http://dx.doi.org/10.1016/j.electacta.2015.09.101 Delft University of Technology Faculty of Civil Engineering and Faculty of Applied Sciences E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2628 CN Delft Julianalaan 67 2628 BC Delft Start date project: End date project: Jul 2011 nov 2016 Key words: Pool water treatment, alternative disinfection, microbial populations, chlorine Cooperation with other institutes: Hellebrekers Technieken, Van Remmen UV Techniek, AkzoNobel Coram International, Sportfondsen Nederland, EFROGO, Agentschap NL 115 Individual Projects Johan Post Serviceability of lateral sewer connections and gully pots Research objectives The second phase aims to quantify the contribution This research aims to identify relevant failure mechanisms of failure mechanisms (e.g. roots, fat/grease etc.) by for lateral (house) sewer connections as well as gully interrogating failure databases. For gully pots a new pots and to ascertain the interaction between these data collection method is proposed where during repairs, mechanisms and the state of the main sewer system. information on the actual cause of failure is collected in a Knowledge on this topic can aid to improve current sewer more comprehensive way. By interrogating the database management strategies in order to maximise the level of of service provided given the available budget. information on the occurrence of blockages in privately a commercial drainage maintenance database, owned lateral house connections is obtained. Project outline Introduction A statistical approach is applied in the third phase in order The performance of an urban drainage system is assessed to ascertain relationships between system factors and the based on the ability of the system to deliver a certain occurrence of failure mechanisms. This will provide insight service. This vital service encompasses, among others, the in effect of management strategies and fundamental drainage of wastewater and excess stormwater in order design choices on the level of service provided. to prevent public health issues and flooding. In order to maintain the desired level of service at the lowest costs, Results maintenance and rehabilitation strategies developed by Results presented in Figure 1, together with failure rates local water authorities should aim to focus work on assets reported for other sewer components by Ten Veldhuis et that have a significant impact on the overall operational al. (2009) show that these components have failure rates condition of the system (Fenner 2000). Currently, only exceeding hydraulic overloading by far. Therefore, the the condition of components of the main sewer system impact of lateral house connections on the serviceability are taken into account in this process. of sewer systems can be considered substantial. Previous research has shown that the contribution of lateral connections and gully pots transporting runoff to the main sewer system on the serviceability of sewer systems is significant (Ten Veldhuis and Clemens 2011, Caradot et al. 2011). Yet, knowledge on how the current condition of lateral house sewers affects the overall level of service provided remains scarce. Moreover, it is Figure 1. Failure rates for different components of the sewer system unclear how the probability of failure of lateral (house) connections and gully pots is related to the state of the The spatial distribution of failures is presented in Figure main sewer system. 2. The red and green lines show areas with significantly more and less failures. Identifying factors that may Approach explain the difference in failure rate are subject to future This research is divided in three phases. The first phase research. is exploratory and entails the identification of relevant failure mechanisms for the front end of the sewer system and possible factors influencing the occurrence of these failure mechanisms. The main sources of information are semi-structured interviews with employees from the field and a review of scientific literature. 116 Johan Post Figure 2. Spatial distribution of lateral house connection failures Scientific & social relevance With respect to the performance of the sewer system, the front end is generally assumed to perform as designed. This does not only mean that there is a gap in scientific knowledge, but also suggest that most studies concerned with the serviceability of sewer systems will overestimate the actual level of service provided. Moreover, by improving management strategies, the same level of service can be provided with a lower budget. Literature Fenner, R.A. (2000) Approaches to sewer maintenance: a review. Urban Water 2(4), 343-356. Ten Veldhuis, J.A.E. and Clemens, F.H.L.R. (2011) The efficiency of asset management strategies to reduce urban flood risk. Water Science & Technology 64(6), 1317-1324. Caradot, N., Granger, D., Chapgier, J., Cherqui, F. and Chocat, B. (2011) Urban flood risk assessment using sewer flooding databases. Water science and technology 64(4), 832-840. Ten Veldhuis, J.A.E., Clemens, F.H.L.R. and van Gelder, P.H.A.J.M. (2009) Fault tree analysis for urban flooding. Water science and technology: a journal of the International Association on Water Pollution Research 59(8), 1621-1629. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Nov 2012 Expected end date: Nov 2016 Key words: Sewer asset management, serviceability, lateral connections, gully pots Cooperation with other institutes: ARCADIS, Deltares, Gemeente Almere, Gemeente Breda, Gemeente ’s-Gravenhage, Gemeente Utrecht, Gemeentewerken Rotterdam, GMB Rioleringstechnieken, Grontmij, KWR Watercycle Research Institute, RoyalHaskoningDHV, Stichting RIONED, STOWA, Tauw, Vandervalk+degroot, Waternet, Waterschap De Dommel, Gemeente Arnhem, Evides en Witteveen+Bos 117 Individual Projects Adithya Thota Radhakrishnan D-SHiT: Domestic Slurry Hydraulics in Transport systems Research objectives Approach Focused on studying the transport aspects of domestic The rheological characterisation of the slurries will be slurries, the study aims at characterizing the slurries done using a rotating viscometer resulting in a relation with respect to its rheological behavior and building a for shear stress for shear rate applied on the fluid. The 1-dimensional non-Newtonian multiphase flow model. influence of solid concentration and temperature on the This enables us to design efficient slurry transport rheology will be determined. The experiments will be systems for future sanitation concepts. performed using slurry samples collected from a smallscale pilot project in Sneek (Leuwarden) running these Project outline sanitation concepts. Introduction New sanitation concepts (Fig. 1) stem from the need Artificial slurry which mimics the rheological behaviour for better nutrient recovery from domestic slurries and of CDS will be used to perform the experiments in the water management. Traditional sanitation concepts use pipeline test loop. Initially the turbulent flow of the fluid large amount of water, thereby making the slurries dilute. will be studied and later the flow with gas. Using the data Whereas, new sanitation concepts focus on reducing the from experiments, a 1-dimensional transport model will consumption of water and possess pressurized pipelines be built to design the transport system. Assumptions that to transport them. This reduction in the consumption of reduce the complexity of the model will be validated using water are generally attributed to the success of these CFD. new sanitation concepts, and investigations show that these slurries can be treated more efficiently. Results The viscosity and yield stress of grinded kitchen waste and brown water increase with concentration of total solids present as seen in Fig. 2. This can be attributed to the complex solid-solid and solid-liquid interaction. A decrease in yield stress and viscosity can be observed with the increase in temperature; due to the increase in Figure 1. Schematic of a new sanitation concept thermal activity. Future domestic slurries are likely to contain a significant fraction of grinded kitchen waste; with low water consumption, it makes the slurry concentrated with solids and therefore they exhibit non-Newtonian behavior. A number of transportability issues for new sanitation concepts arise, related to the dilution and multiphase interaction. The D-SHiT (Domestic Slurry Hydraulics in Transport systems) project was initiated to address these issues of Figure 2. (Left) Rheology of Grinded Kitchen Waste at 11% and 6% solid concentration with Combined Herschel-Bulkley model fit. (Right) Rheology of Brown Water at 1.8%, 3% and 4% solid concentration with Sisko model fit concentrated domestic slurry (CDS); for this the project is The assumption that CDS can be modelled as a divided into three parts. homogenous single-phase fluid represented by its bulk ▪▪ Rheological characterisation of non-Newtonian viscosity and density is verified using CFD (Fig. 3). This multiphase CDS is done by mirroring the rheological experiment in CFD ▪▪ Transport experiments at the pipeline test loop where the fluid is modelled as being homogenous and ▪▪ Developing a transport model for these slurries comparing the results (Fig. 4). 118 Adithya Thota Radhakrishnan Figure 3. CFD mirror of the rheological experiment Figure 4. Comparing the experiment results (-) to that from CFD (x) Social & Scientific relevance In the industrialized world, flushing the toilet with large quantities of water is a routine. In other parts of the world sanitation is not that simple. Due to lack of infrastructure and water scarcity, around 2.5 billion people have no sufficient sanitation at their disposal. The new sanitation concept overcomes the sanitation problems due to lack of water resources. Moreover, the sanitation concept offers promising results with respect to recovery of nutrients and production of energy (bio-gas). All these benefits can be achieved in large scale if the whole chain of new sanitation systems are economically competitive with the common practise. Although all recent research on the new sanitation concept focus on treatment processes and source separation, to benefit from these concepts all aspects of sanitation systems including the collection and transport need to be considered. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: a.k.thotaradhakrishnan@ tudelft.nl www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Oct 2014 Expected end date: Oct 2018 Key words: Domestic slurries, rheology, pressure loss, transport design, hydraulics, CFD, non-Newtonian, multiphase Cooperation with other institutes: Research is conducted within the framework of a STW project: Waternet, Rioned, STOWA, Deltares, Waterschap Zuiderzeeland, Grontmij, XYLEM 119 Individual Projects Maja Taucer-Kapteijn Screening municipal wastewater effluents and surface water used for drinking water production for the presence of ampicillin and vancomycin resistant enterococci Research objectives Approach To study the occurrence of ampicillin resistant enterococci A membrane filtration was used for the enumeration (ARE) and vancomycin resistant enterococci (VRE) in of enterococci using SBA and parallel methods with WWTP effluents and surface water used for drinking addition of 16 µg ml-1 ampicillin or addition of 16 µg ml-1 water production in the Netherlands applying Slanetz and vancomycin for the enumeration of ARE and VRE. Species Bartley agar (SBA) modified with 16 µg ml-1of ampicillin found on the selective media were identified using MALDI- or vancomycin. TOF MS. E-test was used to determine MIC values for vancomycin in the selection of ampicillin resistant isolates Project outline and PCR was applied to detect vanA or vanB gene in Introduction Enterococcus species are part of the natural intestinal flora selected isolates. of humans and animals. In immunocompromised persons, Results enterococci may become opportunistic pathogens and Applying ampicillin medium high numbers (0.4x103 to can cause infections (Jett et al., 1994). Ampicillin and 4.4x103 cfu L-1) were observed in WWTPs effluents and vancomycin are important antibiotics in treatment of those no ampicillin resistant isolates were found at intake infections. However, some Enterococcus spp. strains are locations. All ARE isolates (n = 1033) were identified as E. no longer susceptible to one or both antibiotics and are faecium. No enterococci, but Leuconostoc, Lactobacillus known as ARE and VRE. Vancomycin intrinsically resistant and Pediococcus genus were identified using vancomycin species, do not pose the same infection control concerns medium. None of the selected ampicillin resistant E. as E. faecium or E. faecalis VRE, as their resistance is faecium (AREfm) was vancomycin resistant or possessed chromosomal rather than plasmid mediated (Griffin et al., vanA or vanB gene. AREfm isolates with elevated 2012). VanA and VanB are clinically the most important vancomycin MICs were observed in all studied WWTP genotypes and are most frequently found in E. faecium effluents. and E. faecalis (Cetinkaya et al., 2000). Wastewater from WWTP’s is favourable environment, Scientific relevance consisting of variable mixtures of bacteria, nutrients and The use of SBA modified with ampicillin or vancomycin antimicrobial agents, for both survival and gene transfer, has been shown to be suitable two-step screening spreading resistant bacteria in both aquatic and terrestrial method for clinically relevant enterococci in water. environment (Iversen et al., 2004). Transfer of resistant bacteria through contaminated surface water used for Social relevance irrigation or recreational water and the possible presence Although, no ampicillin resistant strains were found in of resistant bacteria in surface water used as a source surface water used for drinking water production, further for the production of drinking water might be of concern. monitoring, which would allow to evaluate the numbers and possible increase in antibiotic resistance levels in enterococci and other clinically relevant micro-organisms present especially in recreational waters is desirable. 120 Maja Taucer-Kapteijn Literature Jett B. D., Huycke M. M. and Gilmore M. S. (1994).Virulence of Enterococci. Clinical Microbiology Reviews 7(4), 462-478. Griffin, P.M., Price, G.R., Schooneveldt, J.M., Schlebusch, S., Tilse, M.H., Urbanski, T., Hamilton, B., and Venter, D. 2012. Use of MatrixAssisted Laser Desorption Ionization–Time of Flight Mass Spectrometry To Identify Vancomycin-Resistant Enterococci and Investigate the Epidemiology of an Outbreak. J Clin Microbiol. 2012 Sep; 50(9): 2918– 2931. Cetinkaya Y.et al., Vancomycin-Resistant Enterococci, Clinical Microbiology Reviews, 2000, volume 13, edition 4, p. 686 – 707. Iversen, A., Kuhn, I., Rahman, M., Franklin, A., Burman, L.G., OlssonLiljequist, B., Torell, E., Mollby, R., 2004. Evidence for transmission between humans and the environment of a nosocomial strain of Enterococcus feacium. Environ. Microbiol. 6 (1), 55–61. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: m.taucer-kapteijn@ tudelft.nl www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jan 2012 Expected end date: 2017 Key words: The role and source tracking of Enterococci als feacal indicator in dune recharge area Cooperation with other institutes: Het Waterlaboratorium 121 Individual projects Muhammad Risalat Rafiq Water quality assessment of small-scale managed aquifer recharge systems for drinking water provision in coastal Bangladesh Project outline Introduction A consortium of UNICEF, Department of Public Health Sustainable drinking water supply is a major concern (DPHE), Dhaka University (Department of Geology) and issue for achieving millennium development goals. But Acacia Water (Consultants, the Netherlands) built 20 pilot it becomes a major challenge due to rapid population MAR systems in Khulna-Satkhira-Bagerhat regions in growth in urbanizing deltas. Groundwater and surface 2012. At present, a total of 99 sites have been constructed water often become vulnerable to climatic change, over- after initial successes. The NWO UDW DeltaMAR project exploitation, and to some extent economic development. investigates scientific knowledge caps in relation to the This situation becomes worse in coastal regions of self-propelling of MAR systems in the region. The project Bangladesh. Groundwater is brackish to saline in many includes 4 PhD projects concerning water quantity, places and surface water availability is not sufficient in water quality, governance, and hydrogeological research the dry season. questions. To combat against above described scenario, MAR Research objectives (Managed Aquifer Recharge) is introduced as promising In Managed Aquifer Recharge (MAR), aerobic fresh techniques in coastal areas of Bangladesh. A typical MAR surface water is injected into anoxic brackish aquifers. system consists of infiltration wells which recharge the The research objective of this water quality PhD project shallow aquifer during times of water abundance in the (started January 2016) is to assess the hydrogeochemical monsoon period. During the dry season when surface changes (water quality improvements and deteriorations) water recources dry up, the stored water is recovered that could occur when surface water is stored in these from a central well (Figure 1). Other advantages of MAR aquifers. A focus issue is the potential mobilization of systems include filtering of pathogens and availability arsenic which has been observed at some sites. of water sources being protected during cyclonic storm surges that leads to flooding of the area. Figure 1: Conceptualized diagram of Managed Aquifer Recharge (MAR) system 122 Muhammad Risalat Rafiq Approach a) Interpretation of existing data of the 99 MAR sites: interpretation will be using python programming to define groups of sites with similar geochemical behaviour. 4-6 representative sites in terms of geochemistry will be identified for furter research. b) Detailed research at these selected sites: push-pull test, sediment incubation experiments, and complete hydrochemical monitoring will be carried out to better assess sediment-water interactions. Understanding sediment-water interactions will aid in further developing site specific geochemical hypothesis especially for As (im)mobilization. c) Hydrogeochemical reactive transport models will be developed and tested with field data from the selected sites using PHREEQC software in order to enable quantitative assessment of water quality changes during MAR at specific locations. Scientific relevance This research will provide insights in arsenic mobilization and immobilization reactions during MAR. With the developed geochemical model site specific conditions can be identified than produce the best water quality and low arsenic levels. Social relevance The DeltaMAR project aims to set the scientific framework and provide (practical) knowledge to build many more of these MAR systems in coastal Bangladesh and comparable delta settings. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Mar 2016 Expected end date: Mar 2020 123 Individual Projects Steef de Valk Enhanced Enzymatic Anaerobic Fermentation of Organic Residues (EnzyFOR) Research objectives Aquatic worms that flora is researched. Additionally, the changes in microbial great communities due to the activity of the worms will be opportunities to investigate the way nature efficiently researched. Furthermore an in-depth analysis will be hydrolyses made regarding the biodegradability of excess sludge and complex degrade organic sludge, matter. offer The aim of this research is to explain the increase of sludge what part the worms consume of the sludge. biodegradability, observed in worm predated excess activated sludge. This research will give insight into Results ways to mimic the biological activity of these worms for large scale processes in order to increase the valorisation of waste streams by degradation of complex organic substrates. Project outline Introduction The activated sludge process is most used process to remove organic carbon and other pollutants from waste water. The organic fraction of waste water is aerobically respired and partly converted into biomass. The surplus biomass is a by-product of this process and is called excess activated sludge. The main constituents of activated sludge are biomass, organic matter and water. In general, this sludge stream is partly converted in Figure 1. Aspects of worm predation. Batch experiment with (Worms) and without (Blank) worms. Activated sludge as substrate, 12g/l Worms, DO> 5 mg/l, pH 7. 1: Total Suspended Solids reduction. 2: Inorganic nutrient release. 3: Settleability: Sludge Volume Index. 4: The difference in particle size between blank and worms over the course of 2 days biogas and partly processed e.g. incinerated. The following was found in the presence of worms (figure The major fraction of excess activated sludge consists 1): An 3 fold increase in sludge decay rate, the release of complex organic matter, which could be utilized if of inorganic nutrients namely nitrate and phosphate, transformed into VFA precursors for use in (bio)-chemical an increase in sCOD. Furthermore the solids reduction industrial processes or biogas. Hereby increasing the resulted in smaller particles and an improved settleability valorisation of sludge and reducing the amount of sludge of the processed sludge. Additionally, preliminary test that has to be disposed of. with worms treated with antibiotics, to suppress internal bacterial activity (figure 2), revealed that there is a It has been shown that the aquatic worms increases the dependence on the intestinal bacteria for hydrolysis. solids removal rate of excess sludge significantly. Worms feed on complex bio matter present in sludge and by hydrolyses convert this bio matter into VFA and simple sugars. However the mechanisms in the intestines of the worms are unknown. Approach The aquatic worm Tubefix tubefix is used as model organism. Worm predated sludge will be compared to untreated sludge, both processed under the same conditions. Also a distinction between the hydrolytic activity of the aquatic worms and the intestinal microbial 124 Figure 2. Preliminary results if the effect if antibiotic treated worms on the hydrolysis of azocasein. Azocasein hydrolysis was monitored by measuring the optical density of the Azo-dye that is released upon hydrolysation of the azocasein Steef de Valk The bacterial community analysis of the worm process and the biodegradability of excess sludge in the presence of worms is still ongoing at the time of writing. Scientific relevance This project will give insight into the hydrolysis of complex organic molecules. Developing a cost effective process for the degradation of complex organics into VFA or biogas is in the scope of this research. Social relevance In order to achieve a sustainable bio-based society, we should be able to transfer complex organic waste (e.g. excess sludge) into useable products, such as VFAs. In order to reduce sludge disposal costs and improve the utilization of complex organics, this project aims at enhancing product formation from excess sludge. This would result in a decrease in sludge disposal and an increase in the utilisation of excess sludge. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jan 2012 Expected end date: 2017 Key words: Sludge reduction, Aquatic Oligochaetes, Worms, Hydrolysis Cooperation with other institutes: DSM, Delfluent Services BV, Royal Cosun, STOWA, STW, Tauw, Wageningen UR 125 Individual Projects Feifei Wang The Fate of hydrogen peroxide and bromate as by-products of AOP within MAR Research objectives ▪▪ Approach To investigate the reactions of H2O2 with various To investigate the fate of H2O2, batch experiments were biotic (bacteria/catalase in water and soil) and performed to simulate MAR using slow sand filter sand abiotic constituents (pure sand, organic matter and with natural microbial communities and synthetic MAR minerals). water. 5mg/L H2O2 was dosed into different batch reactors To evaluate the effect of H2O2 on bacterial population containing different types of sand and water to compare ▪▪ and bacterial diversity. decay rate of H2O2. To study the feasibility of bromate removal within To investigate the effects of carbon source and NO3- MAR. Specifically, 1 the competition removal of on BrO3- removal and the fate of BrO3- in MAR, batch nitrate and bromate by anoxic bacteria; 2 carbon and column experiments will be conducted. 60 μg/l ▪▪ ▪▪ source consumption with depth. BrO3- will be dosed into batch reactors with different To assess bromate removal in reactor filling with H2O2 carbon sources and NO3- concentrations to compare quench material. BrO3- removal efficiency. 24 columns filled with natural dune sand will simulate MAR to investigate anoxic and Project outline anaerobic bacterial degradation on BrO3-. Introduction The combination of advanced oxidation process (AOP) Results and managed aquifer recharge (MAR) is a potential Figure 1 showed that bromate removal in control system to remove more organic micro-pollutants during group and AC group were quite similar under enough drinking water treatment processes. Bromate formation nitrate. After 28 days the average bromate remaining has been observed to happen during ozonation of concentration in control group and the acetate group bromide containing water. The disinfection by-product, were 39.66 µg/L and 44.33 μg/L. The bromate removal bromate, is an issue to be considered since bromate has percentage in these two groups on 28 days were 29.43% been designated as carcinogenic to humans. To prevent and 20.40% respectively. bromate formation through O3 during UV, alternatively H2O2 can be dosed, leaving residual H2O2 in the treated water. The fate of H2O2 in aquatic system has been investigated comprehensively, however an improved understanding of the fate of H2O2, in terms of H2O2 decomposition mechanisms, during MAR is key to set the maximum allowed H2O2 concentration in the infiltrated water of MAR. There is a great potential in microbiological bromate removal. Studies have shown that bio-reduction of bromate occurs best under anoxic conditions since it Figure 1. Bromate removal in AC group and control is inhibited by oxygen. It can be carried out by various bacterial strains A cheaper alternative was pointed out Some researchers found bromate was reduced in by Hijnen, namely the possibility of bromate reduction a denitrifying bioreactor when nitrate was almost in the anaerobic zone of deep bank filtration sites. Kuhnt completely removed, which indicated that Nitrate would investigated bromate removal in soil passage of a bank be the preferred electron acceptor and bromate would filtration site and had positive results under anoxic be the terminal electron acceptor for anaerobic growth conditions. However, no further research about bromate [1, 2]. Some researchers found bromate reduction was removal in MAR has been conducted. achieved in the present of nitrate and results indicated that DO was a competitor of bromate as an electron acceptor while nitrate was not. For this reason, higher 126 Feifei Wang bromate consumption would be expected when nitrate is completely removed [3]. In one extra experiment the effect of nitrate depletion on bromate removal will be studied. Scientific relevance An improved understanding of the fate of H2O2 within MAR is key to set the maximum allowed H2O2 concentration in the infiltrated water. The research on BrO3- fate in MAR is the precondition for improving BrO3- removal efficiency. Investigation on bromate fate and removal mechanism within MAR is valuable for developing a natural microbiological bromate method. Social relevance For drinking water companies, an improved understanding of the fate of H2O2 is useful to make an optimal H2O2 decomposition solution before MAR by adding some kind of H2O2 decomposition catalyst and the feasibility of BrO3- removal by denitrification biodegradation in MAR would be a big discover as a new and cost-efficient BrO3- removal Literature [1] W.A.M. Hijnen, R. Jong, D. Van Der Kooij, Bromate removal in a denitrifying bioreactor used in water treatment, Water research, 33 (1999) 1049-1053. [2] C.G. Van Ginkel, A.M. Van Haperen, B. Van Der Togt, Reduction of bromate to bromide coupled to acetate oxidation by anaerobic mixed microbial cultures, Water research, 39 (2005) 59-64. [3] J. Liu, J. Yu, D. Li, Y. Zhang, M. Yang, Reduction of bromate in a biological activated carbon filter under high bulk dissolved oxygen and E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft method. conditions Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section characterization of bromate-reducing Biochemical Engineering Journal, 65 (2012) 44-50. isolates, Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Nov 2012 Expected end date: 2017 Key words: Drinking water, AOP, MAR, H2O2, bromate Cooperation with other institutes: Dunea 127 Individual Projects Peng Wei Optimized Mixing for Enhanced Biomass Conversion Using CFD Modeling of Multiphase Flow in Anaerobic Digester Research objectives implemented to determine the actual mixing performance (1) In full-scale anaerobic digesters, the influence of of the digesters. specific key factors (rheology, temperature, mixing mode) (3) Validation, including simulation referred to published on mixing processes will be identified and quantified by experimental results in lab-scale digesters [4], and the CFD modelling and experimental validation. tracer experiments in the full-scale tank. (2) Obtaining an optimised reactor design for better (4) The concentric rotational rheometer is utilised for operational performance based on improved mixing and measuring the sludge rheological properties, applying hydrodynamics in practice. different solid concentrations at varying temperature. Project outline Results Introduction A lab-scale reactor experiment from literature [4] was Anaerobic digesters are commonly applied for the successfully described by a CFD model choosing proper stabilisation of excess sewage sludge, converting the input parameters (Fig. 1). The impacts on velocity field biodegradable organic matter into energy-rich biogas. prediction from interphase force, bubble size, liquid Effective conversion of the organic mass can only be viscosity and scheme accuracy were well described and accomplished when proper mixing of the digester found to be important. Using parameter settings from the content is warranted, maximising mass transfer between simulation of the lab experiment, simulation in a full-scale substrates anaerobic digester was implemented as well. Based on results of digesters are generally implemented as continuous rheological measurement, sludge from the digester in de stirred tank reactors (CSTR) [1]. Nonetheless, full Groote Lucht showed a typical non-Newtonian behaviour scale treatment performances are sometimes below (Fig. 2, shear-thinning with yield stress) and microorganisms. Hence, expectations: sludge stabilisation and gas production are less than expected. Possibly, the actual full scale mixing regime differs from the theoretical design [2]. In order to better understand the discrepancy between full scale reactor performance and theoretical potentials, enhanced insight in the actual mixing regime is of crucial importance. Possibly, the full scale performance is limited by short-circuiting or appearance of dead zones inside the reactor [3].In the current research, we use computational fluid dynamics (CFD) modelling as a numerical simulation for solving fluid flows, in combination with extensive rheological characterisation of waste activated sludge (WAS), to identify imperfections in flow regimes in anaerobic digesters aiming at a better digester design. Approach (1) CFD modelling implementation, mainly by package ANSYS Workbench and Fluent, using non-Newtonian fluid characteristics, gas-liquid phase and turbulence are solved by specific models. (2) The full-scale digester with gas mixing in WWTP de Groote Lucht (Hoogheemraadschap van Delfland) is selected for investigation. Tracer experiments will be 128 Fig. 1 The simulated and experimental[4] results of velocity distribution at (A) local and (B) entire regions in laboratory scale digester. Peng Wei Fig. 2 The rheogram of the waste activated sludge from WWTP de Groot Lucht. Scientific relevance Most mixing studies have been carried out so far on laboratory scale and pilot scale installations. Full-scale studies are limited to tracer experiments, only returning an overall image of solid retention times. The detailed mixing properties in current systems therefore need to be unravelled to reach better performance of current digester systems. Social relevance Optimised operation and enhanced biomass conversion in practice will result in more biogas from waste activated sludge. This leads to more energy recovery from wastewater and less release of greenhouse gases during digestate storage and transport. Modification and/or improvement of the design of full-scale digesters will lead to a more sustainable processing of residual organic streams. Literature Lindmark, J., et al., Effects of mixing on the result of anaerobic digestion: Review. Renewable and Sustainable Energy Reviews, 2014. 40(0): p. 1030-1047. Capela, I., et al., Hydrodynamic behaviour of a full-scale anaerobic contact reactor using residence time distribution technique. Journal of Chemical Technology & Biotechnology, 2009. 84(5): p. 716-724. Wu, B., Advances in the use of CFD to characterize, design and optimize Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 152785457 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Oct 2013 Expected end date: Oct 2017 Key words: Anaerobic digestion, twophase flow, computational fluid dynamics (CFD), mixing, temperature, rheology Cooperation with other institutes: coupled to STOWA project “Community of Practice -Menging slibgisting” bioenergy systems. Computers and Electronics in Agriculture, 2013. 93(0): p. 195-208. Karim, K., et al., Flow pattern visualization of a simulated digester. Water Research, 2004. 38(17): p. 3659-3670. 129 Individual Projects Mostafa Zahmatkesh Bioremediation of Humic compounds from water using fungi Research objectives The objective of this research is to study the possibility of removing humic compounds, namely humic acid (HA), from wastewater by fungal treatment. Project outline Introduction This project is part of a STW project entitled “Increasing Figure 1. White rot fungi growing on Humic-agar plates, degradation of humics would cause bleaching layers on agar the utilization of organic waste and low value feeds with the help of lignin degrading fungi”, in cooperation In the next step, the selected strains were used to with Wageningen University. The research in TU Delft remove humic acid from wastewater. Results showed is focused on using White Rot Fungi (WRF) to remove that Trametes versicolor could remove around 40% of recalcitrant compounds from wastewater. For the last three the humic acid after 3 days and 90% after 15. Laccase years the research was focused on humics as targeted activity was correlating with color removal (Fig 2). Results compounds for fungal treatment. Humic substances are of the liquid chromatography revealed that mechanism of natural organic substances, which are ubiquitous in the humic removal by WRF is a combination of absorption ( environment, both aquatic and terrestrial. In nature, humic by fungal mycelia) and degradation (by fungal enzymes). substances are extremely resistant to biodegradation. WRF constitute a physiological group comprising mostly of basidiomycetous, and to a lesser extent, litterdecomposing fungi. WRF are the most abundant wood degraders in nature, which possess the unique ability of efficiently degrading lignin to CO2 [1]. Thanks to WRF nonspecific enzymes, they can also degrade other recalcitrant compounds with molecular structure similar to lignin, like azo dyes, poly aromatic hydrocarbons, and humics [2]. Figure 2. Left: Color removal (humic acid removal) and enzyme activity, Right: Results of Size exclusion chromatography Lignin Peroxidase, Manganese Peroxidase, Laccase and versatile peroxidases are the major extracellular enzymes Based on the previous results of jar tests, a sequential produced by white rot fungi, which are responsible for batch fungal reactor was applied to treat HA-containing degradation of recalcitrant compounds [3]. wastewater. Three batches were done and each batch lasted 3 weeks. Results are shown in Table 1. Approach Prescreening of several strains of WRF has been done in agar plates to evaluate their ability to grow and bleach humic acid. Selected strains tested in liquid phase, and based on results of the jar tests, a 7 Lit fungal reactor was designed to treat wastewater containing humic acid. Results Four strains of WRF were selected after prescreening in humic-agar plates for their ability to grow and bleach the humic acid (Fig 1). 130 Figure 3. Left: Fungal reactor (Beginning), middle: Fungal reactor (end of first batch), Filtered samples at the beginning and end of the batch Mostafa Zahmatkesh Table 1. Results of the sequential fungal reactor (Decolorization represents the removal of humic acids) Scientific relevance Humic compounds can limit the bacterial growth in digesters, cause fouling in membrane units and also reduce the quality of the effluent due to their color. Therefore, removal of humic compounds in wastewater will increase the efficiency of wastewater treatment plants. Social relevance Removal of recalcitrant or hardly degradable compounds would increase the efficiency of the wastewater treatment plants, which results in a cleaner and healthier environment, which benefit all living species in it, namely humans. 1. A. Hataka, “biodegradation of lignin,” in Lignin, Humic Substances and Coal, Martin Hofrichter and A. Steinbüchel, Eds. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2005, pp. 129–179. 2. M. Tišma, B. Zelić, and Đ. Vasić-rački, “White-rot fungi in phenols, dyes and other xenobiotics treatment – a brief review,” vol. 2, pp. 34– 47, 2010. Sánchez, “Lignocellulosic residues: biodegradation and bioconversion by fungi.,” Biotechnol. Adv., vol. 27, no. 2, pp. 185– 94, Jan. 2009. Email: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Literature 3.C. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: May 2012 Expected end date: 2017 Key words: Humic acid, Bioremediation, Wastewater treatment, Fungi Cooperation with other institutes: Wageningen University 131 Individual Projects Ljiljana Zlatanovic Drinking water quality in domestic drinking water systems Research objectives Demand, an End Use Model. Every tap point is fitted The main aim of this research was to determine the key with a flow sensor and a temperature probe. Before every factors that affect quality of drinking water in domestic stagnation experiment, water was flushed through the drinking water systems (DDWSs) while detailed objectives system by opening the solenoid valves for 10 minutes, of the study were as follows. at a flow rate between 20 - 30 L/min. After flushing the ▪▪ To assess the temporal influence on water quality of pipes, samples of fresh water were collected. Then, water fresh water in DDWSs was allowed to stagnate in the plumbing rig for 40 min, To evaluate microbial quality of stagnant water in 4 hours, 10 hours, 24 hours, 48 hours, 96 hours and 168 DDWSs hours, After every stagnation interval water samples (i.e. ▪▪ stagnant water) was taken for further analysis. Project outline Introduction Results DDWSs which include plumbing between water meters Adenosine tri-phosphate (ATP) is the major energy and consumer taps, represent the final stage of a currency drinking water supply process. In distribution systems, concentrations over 10ong/L are considered high, while water temperature and water residence time are often ATP concentrations below 1ong/L are regarded as low in regarded as surrogate parameters for water quality. drinking water distributed without persistent residual. As Long residence time, which may vary from 2 to 30 days, shown Figure 1, microbial activity in drinking water during depending on the population size, is reported to promote winter (ATP~1ong/L) can be considered low. In summer, microbial growth in distribution networks. When it comes however, the ATP concentrations in fresh water samples to DDWSs, water can further stagnate in pipes for hours, were found to be somewhat elevated (average ~5ong/L) days or even weeks before being consumed. The drinking and could be related to greater microbial activity in the water temperature is known to affect the chemical and drinking water samples. A significant difference was microbiological processes within the distribution phase. also found in total number of intact cells between the In The Netherlands, water temperature in the distribution winter and summer experiments, i.e. during the winter systems varies from a few degrees Celsius in the winter experiments considerably lower intact cell concentrations months to about 20°C in the summer. In DDWSs, were measured in fresh drinking water samples (average on the other hand, the drinking water temperature ~0.45x105ocell/mL), compared to the cell concentration is pretty stable throughout a year and is equal to the in summer water samples (average ~1.45x105 ocell/mL). molecule of all living organisms. ATP room temperature (considering the fact that water in DDWSs is used at varying frequencies, often with long During the winter experiments, as presented in Figure 2, intermissions). Therefore, it is possible that the quality stagnation obviously promoted microbial re-growth, as on of drinking water can further change in DDWSs under average 2-fold increase in intact cell concentration was favourable conditions. measured after water stagnation of 10 to 168 hours. In the summer experiments, stagnation resulted in a linear Approach reduction in intact cell counts, i.e. 5-fold reduction in cell A full scale DDWS was built in the water laboratory located concentration after 168 hours was observed. in the building of Civil Engineering and Geosciences, TU Delft. The design of the experimental plumbing rig was Scientific relevance done according to a plan of a 2 storey house (Typical In 2006, growth of opportunistic pathogens in DDWSs Dutch House). In order to simulate realistic drinking was recognized as a high priority research area by water consumption at the household level, the test rig National Research Council, since the ability of pathogens comprises 11 solenoid valves (tap points), which are to amplify is greatly favoured by an increase in water configured to run automatically according to the one temperature, year demand patterns generated by SIMulation of water stagnation time. Still, the scientific knowledge about the 132 available nutrients and long water Ljiljana Zlatanovic impact of DDWSs on water quality is very limited. This project will lead to a better understanding of the factors affecting the quality of drinking water within DDWSs. Figure 1. Left: ATP levels in fresh water during winter and summer stagnation experiments. Right: Number of intact cells in fresh water during winter and summer stagnation experiments. Number of water samples = 21 Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Figure 2. ICC levels in water samples during winter (left) and summer (right) stagnation experiments Postal address: P.O. BOX 5048 2600 GA Delft Social relevance Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering High quality and microbially safe drinking water is essential for human health. Despite significant advances in drinking water treatment technologies, well treated water is not necessarily reaching consumer’s tap, as water quality might deteriorate in the distribution systems. A better understanding of the factors governing deterioration of water quality within DDWSs can help designing an effective control strategy that will ensure safe drinking water at the consumers’ tap. Literature Blokker, E.J.M., Vreeburg, J.H.G. and van Dijk, J.C. (2010) Simulating Residential Water Demand with a Stochastic End-Use Model. Journal of Water Resources Planning and Management-Asce 136(1), 19-26. Start date project: Dec 2011 Expected end date: 2017 Key words: Water quality, premise plumbing, fire sprinkler systems Cooperation with other institutes: Bam techniek, Brandweer Haaglanden, VSH, Dunea, Waternet, PWN and Vitens Lautenschlager, K., Boon, N., Wang, Y., Egli, T. and Hammes, F. (2010) Overnight stagnation of drinking water in household taps induces microbial growth and changes in community composition. Water Research 44(17), 4868-4877. Lehtola, M.J., Miettinen, I.T., Hirvonen, A., Vartiainen, T. and Martikainen, P.J. (2007) Estimates of microbial quality and concentration of copper in distributed drinking water are highly dependent on sampling strategy. International Journal of Hygiene and Environmental Health 210(6), 725732. van der Wielen, P.W.J.J. and van der Kooij, D. (2010) Effect of water composition, distance and season on the adenosine triphosphate concentration in unchlorinated drinking water in the Netherlands. Water Research 44(17), 4860-4867. 133 Individual Projects André Arsénio (Postdoc) Sustainable freshwater supply in urbanizing Maputo, Mozambique Introduction Maputo, and other Deltas cities in developing countries, suffers from freshwater shortage, improper sanitation, limited access to safe drinking water and reuse of untreated wastewater. In fact, despite the good work done in the country regarding water supply and sanitation since the independency from the colonial power in 1975, there is still a long road ahead. In the country more than 50% of the population still lacks access to an improved water source (WHO, 2013) and according to UNECA (2013), Mozambique has demonstrated a “slow rate of progress” regarding access to safe drinking water and basic sanitation, with TAC (2014) predicting that the Figure 1. Detail of the material flow diagram for nitrogen in the city of Maputo. The arrows indicate the mass flow (tonne/ year) between different sub-systems goals for both indicators will only be reached after 2025 instead of 2015. Research objectives and approach This project aims at developing centralized and decentralized wastewater reuse systems to supply farmers and industries. In this way it will be possible to alleviate the pressure on the already strained freshwater sources that supply the city, reduce risks associated with unsafe reuse wastewater while generating revenue. The project is divided into two branches, a technical, responsibility of TU Delft, and a social, responsibility of UNESCO-IHE. Results Figure 2. If you wish to get more information about the project please this scan QR-code. Alternatively surf to https://sustainablewatermz.weblog.tudelft.nl/ Throughout 2015 we quantified the flows of nitrogen Scientific relevance and water in the city (Fig. 1). The conclusions have been The project will provide fundamental knowledge on presented to local authorities and will support their future informal use of alternative water sources in delta areas; decisions regarding projected city developments. We it will also allow studying water reuse from an integrated were also involved in a city-wide survey to more than socio-technical perspective combined with formal and 1,200 households together with WSP of World Bank in informal practices and understanding power dynamics. Maputo. During the survey we enquired about practices Simultaneously it will be possible to develop new of emptying on-site sanitation systems. These results technologies for “sewer mining”, re-using water, energy will help understanding how to remove fecal sludge can and nutrients on a profitable basis. Finally, the project be removed from the domestic environment and how to aims at helping to implement policies for sustainable appropriately treated it while generating revenue. For an development of freshwater supply on large and small overview of all the work done, check updated information scale, making use of innovative combinations of (N) or download our reports please scan the QR-code (Fig. 2) GOs and private operators and proposing alternative ways of management and operation of centralised and de-centralised systems for reuse making it attractive and profitable for both managers and consumers. 134 André Arsénio Social relevance One of the projects objectives is improving the current situation regarding water and sanitation in Maputo and improve the lives of its inhabitants. This will be done through capacity building and by providing a platform where novel approaches to water management can be discussed. Ideally, the technologies, tools and models developed for Maputo can be implemented in other Mozambican cities and elsewhere and help improving the lives of millions of people. Literature TAC. (2014). Monitoring progress towards the Millennium Development Goals. UNECA. (2013). Assessing progress in Africa towards the Millennium Development Goals. WHO. (2013). Progress on sanitation and drinking-water – 2013 Update. WSP. (2014). Characterization of the Sanitation Sector in Maputo (in Portuguese). Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: a.marquesarsenio@ tudelft.nl www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Feb 2014 Expected end date: Feb 2019 Key words: Water reuse, wastewater treatment, digestion, sewer mining, governance, ecosan, fecal sludge management, sustainability Cooperation with other institutes: UNESCO-IHE, Erasmus University, Universidade Eduardo Mondlane (Mozambique), FIPAG, VitensEvidesInternational, Royal HaskoningDHV, DNA, CRA, Municipality of Maputo, WSUP, WSP, Pamodzi 135 Individual Projects Mathieu Lepot (Postdoc) QUICS: An European project on integrated modeling Research objectives Scientific and social relevance QUICS is a European project, which started a year ago. For this project, scientific and social relevance are the Some details of the project can be found here. Within same: to provide guidelines. Scientists and practitioners QUICS, I focus on practices that may affect data quality can use these expected guidelines to improve their in hydrology. The main goal is to write some guidelines in existing or new systems, in order to get good data for order to improve data quality. subsequent uses. Project outline Introduction Based on past experience of the Urban Drainage group and my own (master, PhD thesis and a first Post-Doc in Lyon), a wide range of practices from the design of a monitoring station till the data validation/storage has been identified. Except for some specific issues (such as interpolation methods), the “good” methods are well known, but not always applied. Approach In order to know what are other researchers and practitioners doing, a dynamic survey has been written and spread through different network. It is a multi-steps survey, dealing with several aspects: design of monitoring station, building, verification, calibration, use, data collection, validation and storage. Based on the survey results, past and/or shared experiences, the methods will be ranked from “bad” to “good” in order to draw some useful guidelines for subsequent works. For interpolation methods, a literature review has been done. Results Despite some effort in spreading the survey and probably due to the required time to answer to the survey (~ 1 hour), there were not so many answers (33 in total). This is enough to sort the method, but not to draw a state of the art of practices in Europa. The results will be processed soon. A review paper dealing with interpolation methods is under review. This paper aims to be a critic and introductive review to such methods, in order to help end-users to choose the best interpolation method for their purposes. 136 Mathieu Lepot Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Sep 2014 Expected end date: Aug 2016 Key words: Data quality, practice Cooperation with other institutes: - 137 Individual Projects Maria Lousada Ferreira (Postdoc) “On-line control tool of AnMBR fouling based on filterability measurements and flux enhancers additions”BestF2 project Research objectives samples. Weekly samples of anaerobic sludge are being The aim of the BestF2 project “Bio-methane production collected at the Harnaschpolder (HNP) WWTP, transported from urban organic matter” is to build a demo-scale to the TUD Water Lab and submitted to filterability AnMBR in Spain, which is energy neutral and produces measurements and other physical-chemical parameters. water for reclamation purposes, demonstrating AnMBR New operational parameters and new cleaning procedures technology for municipal wastewater. adapted to anaerobic sludge are being tested. In parallel, comprehensive tests with flux enhancers are being The TUD goal, within the BestF2 project, is to develop performed to determine optimal dosages and simplified an on-line fouling control tool for Anaerobic Membrane selection procedures, which can be implemented on Bioreactors (AnMBR). The control tool should accurately site to rapidly identify the best flux enhancer according measure fouling of any AnMBR installation, and if needed to the local wastewater characteristics. The preliminary according to the obtained fouling measurement results, tests, comprising filterability and flux enhancers results, add a suitable flux enhancer to minimize fouling. will provide an operational task list, which will be further tested at AnMBR pilots and demo-scale installations. Project outline Campaign measurements are being planned for the UK Introduction and Spain, to test both the on-line DFCm measurement Aerobic MBRs produce high quality and largely disinfected and flux enhancers additions. The following step water, further designated as permeate, which is particularly will be the control strategy development and on-line suitable for water reuse. Anaerobic technologies provide implementation. the biological conversion of wastewater contaminants in the absence of an oxygen source, simultaneously Results producing methane-rich biogas. Approximately 1kwh To adapt the DFCm to the measurement of anaerobic (fossil energy), per kg of chemical oxygen demand samples, means to define new operational settings for (COD) removed, is saved when anaerobic treatment is sludge filtration and an adapted cleaning procedure. In used instead of activated sludge systems [1]. AnMBRs particular, by operational settings we refer to flux (L h combine the advantages of aerobic MBRs with anaerobic -1m-2) and cross-flow velocity (ms-1) in the membrane technologies, producing permeate free of solids and rich loop of the DFCm installation. Figure 1 shows the in ammonia and orthophosphate, particularly suitable to development with time of the ∆R20 parameter, i.e. the agriculture fertilization. Nevertheless, the wide-spread additional resistance obtained when a volume of 20 L m-2 of AnMBR technology, following the foot-steps of the of permeate is obtained, by applying a flux of 60 L h-1m-2 aerobic MBR systems, has been particularly hampered by and a cross-flow of either 1 or 1.5 ms-1, obtained with the problem of membrane fouling. Nowadays, the applied the weekly anaerobic samples collected at HNP WWTP. fluxes in AnMBRs are 3 to 4 times lower than in MBRs. The goal of the weekly measurements is both to tune the Therefore, fouling reduction strategies are particularly DFCm operational settings and to identify the range of required to increase sustainability and overall application variation of the filterability results. of AnMBR technology. Approach The TUD developed a tool to unequivocally measure fouling in aerobic MBRs, the Delft Filtration Characterization method (DFCm), which measures filterability as the sludge fouling potential [2,3]. The DFCm installation has been updated and adapted to measure anaerobic 138 Maria Lousada Ferreira Figure 1- Development of the ∆R20 parameter with time, when a flux of 60 Lh1m-2 and a cross-flow of either 1 or 1.5 ms-1 is applied, in the weekly anaerobic samples collected at HNP WWTP. Scientific relevance The accurate and standard measurement of the fouling potential of AnMBR sludge, allows the following: firstly a fair comparison between the sludge filterability of different AnMBRs installation, secondly the identification of the operational practices and designs producing sludge with the best possible filterability, thirdly an effective on-line monitoring tool to reduce fouling by linking the filterability results to flux enhancers additions. Social relevance According to the World Health Organization, by 2025 half of the world’s population will be living in fresh water stressed areas. To minimize the problem, unconventional water sources, such as wastewater, are being increasingly considered as water source. Water reclamation relies on membrane technology to assure compliance with the reuse criteria. However, membrane technologies require high capital and operational costs. Therefore, there is the need to develop potentially sustainable membrane wastewater treatment technologies, such as AnMBRs, able Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: m.lousadaferreira@ [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Feb 2015 Expected end date: Jan 2018 Key words: AnMBR, Fouling, Filterability Cooperation with other institutes: Aqualia, Spain, University of Southampton UK to overcome technical and economic barriers and allowing overall application of water reclamation from wastewater. Literature van Lier et al. (2015) Celebrating 40 years anaerobic sludge bed reactors for industrial wastewater treatment, Reviews in Environmental Science and Bio/technology 14(4), 681-702. Evenblij H., Geilvoet S., van der Graaf J. H. J. M. and van der Roest H. F. (2005). Filtration characterisation for assessing MBR performance: three cases compared. Desalination 178, 115-24. Lousada-Ferreira M., Krzeminski P., Geilvoet S., Moreau A., Gil J. A., Evenblij H., van Lier J. B. and van der Graaf J. H. J. M. (2014). Filtration Characterization Method as Tool to Assess Membrane Bioreactor Sludge Filterability-The Delft Experience. Membranes 4(2), 227-42. 139 Individual projects Annemarie Mink (Postdoc) Mobile crowd participation as innovative methodology for water research Research objectives increasing connectivity through mobiles phones (Tran et ▪▪ Develop and apply MCP as an integrated research al., 2015), and in particular smart phones, the end user tool for water supply in the local context through can be involved in research and monitoring (Silvertown, behavioral adaptation and end-user participation. 2009). MCP tools rely on mobile phone applications ▪▪ (apps), which are a novelty in water research. Mobile Project outline phone coverage has increased rapidly over the past Urbanization of deltas puts a severe stress on availability decade in Bangladesh, with 80% having a mobile phone of clean, safe drinking water and therefore threatens in urban areas (GSMA, 2014) and 8% being a smart the lives of millions, mostly affecting the poorest. Water phone (GSMA, 2013). MCP technology allows real-time supply Delta monitoring and also facilitates a dialogue with the end- (GBM Delta) in India and Bangladesh is predominantly user. In this research, the intention is to develop a mobile organized through the use of scattered household hand- phone application, which can be utilized to monitor water pumps, where the water safety is un-controlled, leading to supply and quality of the SPWS system. in the Ganges-Brahmaputra-Meghna contaminant exposure. Centralized water supply through Small-scale Piped Water Supply (SPWS; IRC, 1981, Approach Ahmed, 2002, Trifunovic, 2002, WHO, 2005) offers crucial Interviews at urban laboratories and literature review to advantages over other technological interventions, as it identify generic and context specific boundary targets the safest source in the area, provides a degree conditions for MCP. The app development will be an of centralization (<100 households) for water quality iterative process in short sprints with extensive field control and treatment, provides in-house or courtyard tap testing: a continuous cycle of requirements specification, connections, which are socially-economically desirable, development, user testing, requirements specification, and limits the number of (re-)contamination events development, user testing etc. A team of user experience between water collection and consumption. design students will perform the end-user testing and develop wire-frames. These will be input for the app Stakeholder interaction and participation leads to a developers. thorough understanding of the social, technical and economic factors that play a role in the region. End- Results users determine the (changing) water demand and can Practical results: Each functionality will be programmed, guarantee rootedness in the local context. According to tested and improved upon separately, to in the end come Dreibelbis et al., 2013, the success of interventions to up with one final application ready to use in the field. improve water, sanitation and hygiene practices ultimately Scientific results: generic and context specific boundary rests on the ability to foster and maintain behaviour conditions for MCP which are empirically validated. change. To improve the accessibility, applicability, acceptance and adoption of the SPWS system, the Scientific relevance end-users and other stakeholders should be included Mobile phone applications (apps) are a novelty in water (Donaldson 2009; Nakata and Weidner 2012; Prahalad research, and by this project its relevance for evaluating 2012; Robertson and Simonsen 2012; Wilkinson and De and monitoring SPWS systems will be determined, and Angeli 2014). To involve the potential users in research generic and context specific boundary conditions for MCP and monitoring of the water supply system, Mobile Crowd will be established. Participation (MCP) can be deployed. Social relevance Access to mobile services in the developing world has The results of this study can be used by governments, outpaced the rate at which much of the population NGOs working in SPWS projects in Bangladesh or other is gaining access to basic services such as electricity, urbanizing delta areas. sanitation, and banking (GSMA, 2013). With the 140 Annemarie Mink (Postdoc) Literature Literature • Ahmed, F. (2002). Alternative Water Supply Options for Arsenic Affected Areas of Bangladesh. Dhaka, Bangladesh: ITN-Bangladesh. • Chowdhury, N.T., 2010. Water management in Bangladesh: an analytical review. Water Policy 12: 32–51 • Donaldson, Krista M. 2009. “The Future of Design for Development: Three Questions.” Review of. Information Technologies & International Development 5 (4):97-100. • Dreibelbis, P., et al. (2013) The Integrated Behavioural Model for Water, Sanitation, and Hygiene: a systematic review of behavioural models and a framework for designing and evaluating behaviour change interventions in infrastructure-restricted settings. BMC Public Health 2013, 13:1015. • GSMA Intelligence (2013) Scaling Mobile for Development, August 2013 • GSMA (2014) Analysis Country Overview: Bangladesh, August 2014. Groupe Speciale Mobile Association • International Reference Centre (1981) Small community water supplies: Technology of small water supply systems in developing countries. Rijswijk, The Netherland: International Reference Centre. • Nakata, Cheryl, and Kelly Weidner. 2012. “Enhancing New Product Adoption at the Base of the Pyramid: A Contextualized Model.” Review of. Journal of Product Innovation Management 29 (1):21-32. doi: 10.1111/j.1540-5885.2011.00876.x. • Prahalad, Coimbatore. 2012. “Bottom of the Pyramid as a Source of Breakthrough Innovations.” Review of. Journal of Product Innovation Management 29 (1):6-12. doi: 10.1111/j.1540-5885.2011.00874.x. • Robertson, Toni, and Jesper Simonsen. 2012. “Challenges and opportunities in contemporary participatory design.” Review of. Design Issues 28 (3):3-9. • Silvertown, J. (2009). A new dawn for citizen science. Trends in ecology & evolution, 24(9), 467-471. • Tran, M. C., Labrique, A. B., Mehra, S., Ali, H., Shaikh, S., Mitra, M., ... & West Jr, K. (2015). Analyzing the Mobile “Digital Divide”: Changing Determinants of Household Phone Ownership Over Time in Rural Bangladesh. JMIR mHealth and uHealth, 3(1), e24. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 613161335 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jun 2016 Expected end date: Nov 2018 Key words: Mobile Crowd Participation, End-User Interaction, Small-scale Piped Water Supply Cooperation with other institutes: AN College Patna India, Dhaka University Bangladesh, National Institute of Design Ahmedabad India, Industrial Design Engineering TU Delft • Trifunovic, N. (2002). Small community water supplies: Water distribution. Delft, The Netherlands: International Reference Centre. • WHO (2005). Rehabilitating small-scale piped water distribution systems. Geneva, Switzerland: WHO Press. • Wilkinson, Christopher R, and Antonella De Angeli. 2014. “Applying user centred and participatory design approaches to commercial product development.” Review of. Design Studies 35 (6):614-31. 141 Individual Projects Marjet Oosterkamp (Postdoc) Microbial community analysis of anaerobic bioreactors treating extreme wastewater Research objectives Approach The microbial community of anaerobic membrane Samples from bioreactors treating wastewater with bioreactors and an upflow anaerobic sludge blanket reactor various concentrations of phenol and salt and under treating (synthetic) industrial wastewater containing mesophilic as well as thermophilic conditions will be various concentrations of phenol and salt and under studied using molecular techniques such as DNA isolation, mesophilic as well as thermophilic conditions (BioXtreme) polymerase chain reaction and denaturing gradient gel will be analyzed. The first objective is to provide detailed electrophoresis. Furthermore we will use high throughput characterization of the microbial community composition deep-sequencing techniques (Illumina MiSeq, Figure 1) to of the anaerobic bioreactors. This will allow us to identify characterize in more detail the bacteria and archaea that which microorganisms are important under the different are present. Advanced bioinformatics tools, such as QIIME conditions. In this regard, we will also focus on the effect and the R environment, will allow us to get information of bioaugmentation as well as differences in community of community composition as well as diversity. To address composition of the bulk and cake layer on the membrane. the functions of the community in the bioreactors in more The second objective is to identify functional metabolic detail, more advanced omics techniques such as RNAseq pathways employed by the variety of microorganisms and proteomics will be used. Furthermore, single-genome in the anaerobic bioreactors under different conditions, sequencing and isolation of key microorganisms from which will increase understanding of metabolic pathways the bioreactors can provide more information about the involved and aids selection of microorganisms for a properties and possible functions of a single bacterial or designed minimal microbial community necessary for archaeal strain present in the bioreactors. Based on the treating extreme wastewater. information obtained from community as well as strain studies, a selection of microorganisms can be combined Project outline and their optimal performance in the bioreactors can be Introduction tested. Anaerobic digestion is important for wastewater treatment and combines reduction of waste and pollutants with energy production. Furthermore, compared to aerobic treatment, the costs of operation and sludge handling are low. The upflow anaerobic sludge blanket reactor is a very successful system that is widely applied for anaerobic digestion. The use of the membrane bioreactor technology has been well established in aerobic treatment. More recently, the advantages of this technique and of anaerobic digestion have been combined into the anaerobic membrane bioreactor. Excellent effluent quality, low sludge production, total biomass retention and hence bioaugmentation of specialized bacteria, and net energy production are among the advantages of the anaerobic membrane bioreactor technology. To ensure optimal performance, a more fine-grained insight in the composition and functionality of microbial communities of bioreactors is important. This insight will also allow us to develop a designed microbial community that can be applied for optimal anaerobic digestion. 142 Figure 1. Overview of the Illumina sequencing workflow Marjet Oosterkamp Scientific relevance This research will lead to novel insights in microbial communities treating wastewater containing phenol and under high saline and mesophilic as well as thermophilic conditions. We will identify (novel) microbial specialists involved in this process, which will increase our understanding of optimal anaerobic digestion of extreme wastewater and also of the mechanisms of bioaugmentation of specialists in membrane bioreactors. More detailed research of these microorganisms increases our understanding of pollutant degradation at a molecular level. Social relevance Insight in microbial communities of anaerobic bioreactors and development of communities that are able to perform optimally will enhance the treatment of waste and wastewater. Improvement of extreme wastewater treatment will lead to more environmental-friendly industry as it will not only reduce the release of industrial pollutants, but also increase green energy production. Literature 1. Lin H, Peng W, Zhang M et al. 2013, A review on anaerobic membrane bioreactors: Applications, membrane fouling and future perspectives. Desalination 314: 169-188. 2. Dereli RK, Ersahin ME, Ozgun H et al. 2012, Potentials of anaerobic membrane bioreactors to overcome treatment limitations induced by industrial wastewaters. Bioresour Technol 122: 160-170. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Jul 2015 Expected end date: Jul 2017 Key words: Microbial community analysis, next generation sequencing, anaerobic digestion, bioaugmentation, AnMBR, UASB, aromatic compounds, salinity, mesophilic, thermophilic Cooperation with other institutes: Environmental Biotechnology TU Delft, Evides Energiewater, Paques, Wageningen University 143 Individual Projects Ran Shang (Postdoc) ceramic nanofiltration as the key step for sustainable wastewater treatment with reclamation of water, energy and nutrients Research objectives This research is part of the RINEW (Rotterdam - Innovative Nutrients Energy Water) project, which is To optimize the ceramic nanofiltration process for domestic wastewater filtration searching for alternative concepts for the reclamation - of municipal wastewater from city areas and transfer To develop effective cleaning methods for the ceramic nanofiltration membranes filtrating wastewater. it to valuable products. RINEW is a collaboration - To investigate a new route to prepare ceramic between Evides Industriewater, the City of Rotterdam, nanofiltration Hoogheemraadschap van Delfland, Waterschap Hollandse (NF) membranes with homogeneous micropores, high organic and P rejection and yet high Delta, and Clean Tech Delta. water flux. - To study the performance of the new NF membranes during sewer mining application. Recent results show that an advanced deposition technique is feasible route to synthesize tight ceramic NF membranes with high water permeability. The deposition Project description was applied on a commercial ceramic NF membrane Sewer mining using a commercially available ceramic with 450 Da, in order to narrow its pore aperture. The nanofiltration membrane (450 Da cut-off) has been synthesized tight ceramic NF membranes had a molecular previously studied by direct nanofiltration of sewage 1. weight cut-off (MWCO) ranging from 260 to 380 Da. Yet, The aim of sewer mining is to concentrate COD (chemical they maintained high water permeability at 11-16 L m-2 oxygen demand) and/or phosphate from the sewage h-1 bar-1, which is notably higher than the commercial so that energy and nutrients can be reclaimed in an tight polymeric NF and traditional sol-gel-made tight anaerobic digester (Fig. 1). ceramic NF membranes. Figure 1 PEG rejection (a) and modelled active pore size distribution (b) of the pristine (substrate) membranes and the synthesized membranes. Zeolites as novel adsorbent in water treatment Research objectives Project description ▪▪ To investigate the efficiency of high silica zeolites (of Activated carbon is typically used to remove organic various pore size and Si/Al ratios) for adsorption of the micropollutants from contaminated water, but during this organic micropollutants (OMPs) and the assimilable process, natural organic matter (NOM) present in the organic carbon (AOC) from drinking water. water competes with adsorption sites and may restrict To study the competitive adsorption between the pore access. Both these effects reduce the filtration time natural organic matters and the OMPs or AOC. until regeneration, and during regeneration, energy is To investigate if the zeolites can be effectively wasted on removing NOM. Zeolites have pore sizes that regenerated by in-situ oxidation. are too small for NOM to enter, and initial lab tests have ▪▪ ▪▪ 144 Ran Shang already shown that equilibrium adsorption of organic micropollutants on ZSM5 zeolite was similar with or without the presence of NOM 2. The research focus will be on understanding what molecule and zeolite properties affect adsorption (both equilibrium and kinetics). Based on this, combinations of zeolites will be selected and agglomerated to granules. The adsorption capacities of these granules for a broad range of organic micropollutants and AOC will then be tested. The regeneration of saturated zeolites will also be investigated. Since zeolites are chemically inert, oxidative techniques can be used for their regeneration. These techniques are envisioned to be more costeffective than the current thermal regeneration used for activated carbon regeneration. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 152783539 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Figure 2. Scanning electron microscope image of FAU type zeolite with a Si/Al ratio of 500 Literature Shang, R. Ceramic ultra- and nanofiltration for municipal wastewater reuse. Delft University of Technology, Delft, 2014. de Ridder, D. J. Adsorption of organic micropollutants onto activated carbon and zeolites. Delft University of Technology, 2012. Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: May 2014 Expected end date: May 2017 Key words: Ceramic NF, Sewer mining, Zeolite, Adsorption Cooperation with other institutes: STW, Evides, Logisticon 145 Individual Projects Matthieu Spekkers (Postdoc) Collecting rainstorm damage data through household Research objective Data are collected by means of a telephone and online The objective of this project was to develop and test survey. A total of around 350 surveys were completed in a a new questionnaire to assess rainstorm damage to period of 4 months. The newly collected data can be used residential buildings. for the development and validation of damage estimation models. Preliminary results show that a considerable Project outline part of the damage was caused by leaking roofs and Rainstorms cause considerable damage to residential facades. Moreover, this case study shows that 25% of the buildings worldwide, such as flooded basements and respondents did not claim their damage, although they ground floors and leaking roofs. To effectively take have a property and content insurance. precautionary measures, an understanding of the nature and causes of rainstorm damage is required; however, Scientific relevance this is hampered by the lack of empirical damage data Results that are relevant for science: from real-life examples. • A new international questionnaire for the collection of rainstorm damage data. For this reason, we have, in collaboration with the • A new research database on rainstorm damage to German Research Centre for Geosciences, developed a residential buildings. questionnaire to assess rainstorm damage to residential buildings. The new questionnaire contains question items Social relevance related to the damage a household experienced and the • Damage data and damage models have a high local circumstances under which the damage occurred. potential of providing valuable information to households, Contextual variables that are covered by the questionnaire water authorities, insurers and meteorologists to support include hazard and building information and preparedness damage prevention and reduction. and precaution indicators. The questionnaire is developed •In using international standards, allowing the questionnaire waterproofing their houses can benefit from information to be applied to other European countries/cities in the on the efficiency of precautionary measures and the future. potential damage reduction. Using the new questionnaire, we have carried out a household survey among rain-affected households in the city of Amsterdam (i.e. neighbourhood Oud-West). The city of Amsterdam was severely hit by an extreme rain event on 28 July 2014, and there was a clear need to gain more insights into the vulnerability of the city. Data collection took place within the Impact project “Samen met verzekeraars naar een regenbestendige stad”; a collaboration between Waternet, TU Delft and Achmea insurance group. 146 particular, homeowners who consider Matthieu Spekkers Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] Phone: +31 152788578 www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Mar 2015 Expected end date: Mar 2017 Key words: Telephone interviews, rainstorm damage data, damage modelling Cooperation with other institutes: GFZ Potsdam, Waternet, Amsterdam Rainproof 147 Individual Projects Xuedong Zhang (Postdoc) Online VFA monitoring in an anaerobic leaching process using a mid-infrared spectroscopy based sensor Research objectives applied to develop calibration models for the sensor. OPTI-VFA is a two-year European project mainly aiming to develop low-cost industrial sensors for online monitoring Approach volatile fatty acids (VFA) in anaerobic digestion reactors The FT-MIRS system (Figure 1, Left) consists of a Bruker (http://www.opti-vfa.eu). The aim of this study is Matrix FT-MIRS (spectral range: 5.2-17 µm (600-1900 twofold: first, to develop an acceptable calibration model cm-1) and an ATR fiber sensor (diamond-ATR probe, 2 for a sensor based on Fourier transformed middle infrared bounces reflection) from Art Photonics. Spiking VFAs into spectroscopy (FT-MIR) to predict total VFA and individual effluent and leachate of an AD process was carried out VFAs in anaerobic digestion (AD) process; second, to (Figure 1, Right). validate the performance of the OPTIVFA sensor in a large number of batch tests (off-process measurements), real-time monitoring VFAs of a lab-scale AD reactor and in a leaching process of a full-scale biogas plant. Project outline Introduction Anaerobic digestion is considered a relatively simple Figure 1. The FT-MIRS system and the digester (Left) and the procedure of spiking and measurements (Right) biological approach to achieve sludge stabilization and Results recover bioenergy from organic residues. However, In this study, to develop the calibration models for the many full-scale digesters are operated under suboptimal OPTIVFA sensor, 3 calibration approaches were tested: conditions because of a lack of reliable on-line data to traditional PLS regression, parsimonious calibration efficiently control the process. Variations in substrate model, and direct SMF calibration method based on the characteristics and changes in organic loading rate can efficient use of prior spectroscopic information on the lead to unstable performance of anaerobic reactors, target signal and on the unwanted spectral noises. The possibly resulting in the accumulation of fatty acids and 3 calibration approaches gave very similar predictions even failure of the process. The mechanism of reactor in terms of calibration fit: the RMSEC and RMSEP perturbation is only limitedly investigated due to a lack values were very close to each other. However, there of real time VFA monitoring systems as VFAs are also is a positive offset in the total VFA predictions for the considered good indicators for digester performance. datasets, which can be caused by systematic bias and In addition, another driving force to develop the online can be compensated using an offset into the calibration monitoring systems is the increasing attention to recover models. However, each of the calibration methods has resources such as VFAs from waste streams. their advantages and disadvantages. A PLS regression Fourier transformed near/middle infrared spectroscopy model is simple to construct, but when the PLS regression has been broadly applied in food processing industry and model is built with an observational dataset the dataset pharmaceutical industry. This technology has been proven size shall be large enough to eliminate the chance to be potentially used as an alternative for online VFA correlations. The parsimonious calibration model reduces monitoring for anaerobic digesters. However, variations in the number of regression coefficients to a minimum, substrates and operational conditions of digesters result therefore reducing the needed size of training dataset. in substantial differences in characteristics of digestates. Furthermore, the calibration model is insensitive to Thus, a reliable online VFA monitoring system needs the spectral interferences that occur outside the few a robust and accurate calibration model. In this study, spectral regions used in the model. The small number of traditional PLS regression, a parsimonious calibration explanatory variables decreases the ability of the model model based on four wavelength regions, and direct to compensate for certain complex spectral interferences spectral matched filter (SMF) calibration method were which occur also in the chosen spectral channels. The 148 Xuedong Zhang SMF method makes efficient use of measurable spectroscopic prior information that forms the basis of the training dataset. Identifying and measuring the most important signal and the interferences/noises sources is the main difficulty of the SMF calibration method, i.e., high level of spectroscopic expertise and industrial process are needed. Figure 2 shows the predictions of the OTIVFA sensor in an anaerobic leaching process, and the comparisons between the predictions and the GC-VFA reference values. The results indicate that the sensor was able to follow the trends of total VFA and acetic acid in the process. However, for total VFA, there is a clear difference between the predictions and the GC measurements. The calibration model for total VFA can be compensated by using an offset as aforementioned. The OTPIVFA sensor seems to be able to follow the trend of propionic acid as well. However, the predictions are still not satisfactory. It is likely because of the relatively lower concentration of propionic acid in the process, compared to acetic acid. The predictions of propionic acid in the process would be better if the concentration was higher. In short, the online VFA monitoring system is capable of detecting the dynamic profile of some VFAs species and total VFA in the AD process, and probably would be very conducive to steering VFA production in AD processes and obtaining the desired VFA spectra. However, the further improvement of the calibration models for more VFA species still needs to be carried out. Delft University of Technology Faculty of Civil Engineering Water Management Department Sanitary Engineering Section E-mail: [email protected] www.sanitaryengineering.tudelft.nl Postal address: P.O. BOX 5048 2600 GA Delft Visiting address: Stevinweg 1 2611 CN Delft Building of Civil Engineering Start date project: Sep 2013 Expected end date: 2017 Key words: Anaerobic digestion, online VFA monitoring sensor, middle infrared spectroscopy, biogas production, and VFA production Figure 2. In-process predictions of VFAs using the OPTIVFA sensor and the off-process analyses by GC in a cycle of a lab-scale leaching process Scientific relevance OPTIVFA project will develop a reliable VFA monitoring system based on middle infrared spectroscopy. The system will be conducive to Cooperation with other institutes: Maris projects (Netherlands), Attero (Netherlands), VTT(Finland), CEIT(Spain), Rikola (Finland), Optomesures (France), MTT (Finland ), Multantiv (Finland), and MSI (Spain) understand the dynamic profile of individual VFA, and then better decipher the fermentation process, finally resulting in effective control strategies to optimize biogas or VFA production from organic residues. Social relevance Optimal operation of AD reactors treating organic waste contributes to reduce the investment in AD plant due to post-treatment units. Eventually, OPTIVFA project will be helpful in achieving a more sustainable society, that is: efficient use of all organic residues and reduction of waste emissions. 149 150 Annual report 2016 Education 151 Education WaterLab The Waterlab: where education and research meet The department is proud of its unique laboratory facilities System, Flat-sheet cross-flow module for arsenate in the WaterLab. The WaterLab is a research and education removal. lab providing an unique infrastructure for experimental research. We support numerous and very different kinds In the WaterLab we also often see proof-of-concept of permanent practical set-ups and research experiments, experiments with novel sensors or set-ups, not seldom of course bounded by the safety regulations. build using huge amounts of industrial Duc tape. Examples are smart-roofs for dynamic water storage on The WaterLab hosts permanent experimental set-ups flat roofs using small-weirs or developing temperature for education: a gas-transfer cascade, filtration columns, sensing using glass optical fibres. After intense testing in bubble aeration column, the online nanofiltration, specific the laboratory, the set-ups, sensors or reactors are taken ultrafiltration resistance, sand columns for soil hydrology to a real-life test. tests and a reverse osmose filtration setup. The WaterLab facilitates MSc and PhD students with the The WaterLab of our department is managed by two experiments of wastewater treatment in a ML-I certified enthusiastic lab technicians, Armand Middeldorp and laboratory. Here we study the recovery of energy, Mohammed Jafar. They provide the training for analytical biochemicals and water from the sewer or industrial equipment. They provide support for designing and effluent, with special focus on the hydrolysis processes, building experiments, safeguarding our high safety and granular biomass and Anaerobic Membrane Bioreactors environmental standards, purchasing equipment and (AnMBR). consumables. In the open lab area of the WaterLab, the drinkwater Our Water Laboratory is not a ‘standard’ analytical lab, treatment and experiments are located which are but it does possess plenty high end analytical equipment not bounded by special safety regulations. Here we like GC, HPLC, IC, Automatic biomethane potential test see experimental set-ups like DFCm- Delft Filtration system (AMPTS), TOC analyser, particle counter and PSD Characterization method, Aquatic worms bioreactor to system, Solar simulator, isotope analyser and soon to be study biodegradability of sludge, Ceramic Nanofiltration available an ICP MS. membrane installation, Ceramic water filter columns for the removal of phages, Drinking Water Distribution 152 WaterLab A small drinking water distribution network of grey PVC pipes is built to mimic the real distribution network situation. Photo by TU Delft/Frank Auperlé The DIPool project of Marjolein Peters and Maarten Keuten looks at how the formation of harmful disinfection by-products can be counteracted. Photo by TU Delft/Frank Auperlé 153 Education Study trip Dispuut Watermanagement Ethiopia On the third of July 2016, 16 students of the student association Watermanagement of the TU Delft started their journey through Ethiopia. The students were accompanied by three staff members of the department, Prof. Huub Savenije, Prof. Nick van de Giesen and Dr. Lisa Scholten. During the trip the students visited the cities Addis Ababa, Bahir Dar, Lalibela, Adama and Ziway and their surroundings. In total the trip lasted three weeks and was an unforgettable experience for all the participants. Day 3:Visit to ENTRO and the Dutch Embassy After an exciting first day in Addis Ababa, we’re even more excited the morning with the first visits on the program! Starting with a visit to ENTRO, the Eastern Nile Technical Regional Office from the Nile Basin Initiative (NBI), which was followed by a visit to the Dutch Embassy in the afternoon. At ENTRO we learned about the NBI, which is an intergovernmental partnership and the first institution for the Nile basin with all countries in the basin included. Day 4: First try to visit the university As the Nile has a long history of different agreements Even though we saw the Ethiopian students walking in, concerning the water resources division between the the guards were without remorse: we could not enter the countries, the NBI is the first with a shared vision and Engineering faculty of the University of Addis Ababa. Due strategy program. After an interesting presentation we to the Eid al-Fitr (end of ramadan feast), the university continued our journey through Addis Ababa by a short was closed, even the professor with whom we made an visit to the famous Merkato, which is known as the appointment could not get us in. A pity, but luckily we largest open-air market of Africa. Driving around in a could reschedule the visit for the next day and we had bus in such a crowded place isn’t easy, so after twenty some free time instead. minutes driving with only getting ahead 500 meters, we Some of us went to the National Museum, and with a group decided to get out of the bus to find lunch and nice cup of I went to the big campus of the University. Once more, Ethiopian coffee. With renewed energy we were ready for the guards immediately stopped us. “it’s closed”. Again, our visit to the Dutch Embassy, and while we thought the we saw many Ethiopians entering. We still don’t know day couldn’t get better, Professor Huub Savenije joined us what changed, but from one second to the other they did during the visit at the Embassy. The Embassy is located on let us through the gates. The campus consists of a big the western outskirts of Addis Ababa and is designed by park and some very nice buildings. One of them used to the Dutch Architect Dick van Gameren, who is a professor be the palace of Haile Selassi himself. We walked around at the TU Delft. Although we got a nice presentation and got into some nice conversations with students that and guided tour, it was a small disappointment for us also happened to study engineering. We drank coffee, as Water Managers when we learned that water is not or should say, participated in a coffee ceremony, in a on the action program of the Embassy of Ethiopia! After small but cosy coffee hut. To get our lunch, we looked the visit, bus driver Esayas dropped us of near the hotel for the students’ cafeteria and we stumbled upon a large at a nice Ethiopian bar where we started the night with group of cheering students, waiting for the doors of the tea (and maybe some beers later on). Our study trip to cafeteria to open. In Ethiopia the Summer holidays had Ethiopia definitely started today! started as well. Surprisingly, people even started running in once the doors of the cafetria opened. 154 Study trip Dispuut Watermanagement It happened to be a special meal due to the Eid al-Fitr. July 8th, at 0:00 in the Lounge Bar in Addis. Club H20, Unfortunately, we were not allowed to join. where we had come from before, was too quiet and St. Yellow caps, safety glasses, safety suit and earplugs. George’s medicine had yet to pulverize our inhibitions Our outfit during the afternoon excursion to the one and before we would dare the dance off with the local only Heineken factory in Addis Ababa. Marc, a Dutch privileged. When returning an hour later, only to find the Delft alumni, and now production manager of the three dance floor still empty, we decided to teach the observers year old factory in Addis Ababa hosted us. To enter the something of our own culture after having already Ethiopian market, Heineken introduced a new Ethiopian learned so much of theirs. The next morning the YEP-ers brand named Walia and the success is “unbelievable”, Jelmer and Annelies from Belgian engineering contractor 1.2 million hectolitre of beer was sold during the first DENYS showed us the process of designing and executing year. Durin g our visit we also received a presentation the construction of the major new sewerage network by Royal Haskoning, which helped building the brewery. in Addis. They fascinated us with information ranging The visit to the factory was intriguing: the bottles going from the concept, blue print mark-ups to the digging of through the different phases of the process can hardly tunnels under bridges for the pipelines, to their personal not hypnotize you. Unfortunately the factory bar was experiences being expatriated to Ethiopia as well as closed, so no beer for us. Luckily we could make up for working in the environment of a rapidly developing this during our free evening. country. This was then followed up by a visit to Dr. Melesse Temesgen who showed us his innovation on the Aybar BBM. This plough requires less than half the energy to use and creates broad bed furrows that much more efficiently regulate the water balance for crops in both extremely dry conditions through water conservation, as well as wet areas through drainage - depending how it is applied. This day was a day of inspiration, where we truly came to realize how individual people can make a tremendous difference to a society and a nation by taking the initiative, being proactive and by applying their well Day 6: The sewage of Addis Ababa developed skills in engineering. Blood red walls spotted with mini-portraits of Vladimir Putin, a mist of shisha smoke and a group of pale faranjis (foreigners) dancing to the great Ethiopian thump. This stark contrast of colors marks the technical beginning of 155 Education Study trip Dispuut Watermanagement Day 9/10: Fieldwork Even though the first two days in Bahir Dar were rather relaxed, Monday morning it was time to get back to work, fieldwork more specifically. After a short walk from the Blue Nile Hotel to Bahir Dar University, we arrived at the Institute of Technology. For a moment we thought the banner congratulating the “class of 2008” hadn’t been updated for a while, but then we remembered it is actually 2008 at the moment in Ethiopia. At the University we met Dr. Seifu Tilahun, who had been the Dean of the university until a couple of days before. Also, we were introduced to two of his PhD students currently doing research on gully erosion in Ethiopia, the topic of our fieldwork. Later, Prof. Dr. Tammo Steenhuis gave us a short introduction on soil erosion preparing us for the fieldwork. Tammo Steenhuis, Dutch, but working at Cornell University, was the promoter of Nick van de Giesen and has been working on soil erosion in Ethiopia for many years now. Having enjoyed lunch with the now well-known Ethiopian injera, we started working on the plans for the fieldwork, collecting equipment and materials and getting ready for the field. Around 2 p.m., or wait, 8 o’clock in Ethiopian sunlight hours, we left the university by bus to set-up the measuring equipment in the field so that we could have a quick start the next morning. However, never expect everything to go according to plans in Ethiopia. One hour away from Bahir Dar heavy rain caused traffic jam on the small, muddy and bumpy road. The traffic jam allowed us to leave the bus to see some gullies along the road and for some of us to run to the top of a hill to oversee the amazing landscape. However, by the time the traffic started moving again it was too late to continue to the fields and we decided to return to Bahir Dar. The next day we left the hotel early and got to the sight on time. The students were divided in groups and we all set out to investigate what causes gully formation in the Ethiopian Highlands. Sometimes accompanied by the local children herding their animals in the fields. 156 Study trip Dispuut Watermanagement Day 18: Sugar cane for lunch Day 18: Lake Ziway Waking up in a hotel that looked like an old castle filled Leaving the sugarcane plantation behind, we made with a mixture of medieval and oriental style furniture, our way to Lake Ziway, which hosts most of Ethiopia’s a visit to a sugar cane plantation in Adama was on the booming, flower exporting industries. The Netherlands programme. After a warm welcome in the office we first being a flower country itself, it comes to no surprise that visited the pumping station of the irrigation system of even in Ziway we find a handful of Dutch agriculturalists the plantation. On the wall in the pumping station we busy making a living for themselves and their hundreds found a sign “Werkspoor N.V. Amsterdam” the trademark of employees. Growing on no less than 38 hectares, AQ- of the Koninklijke Nederlandsche Fabriek van Werktuigen roses produces a variety of different kinds of roses for en Spoorwegmateriaal, a Dutch company building the massive flower auction in Aalsmeer, The Netherlands. machinery from the 50’s. A Dutch company originally Lake Ziway’s pristine waters, the Ethiopian sunshine and established the plantation back in 1953. With the arrival the hardworking employees together with the Dutch of the communist DERG government in 1974, the Dutch expertise in horticulture and company management, left the country and the sugar cane plantation was make the perfect recipe for AQ’S quality products. nationalized. All Dutch equipment was still in use until Although, we only spent a short-time walking around on a couple of years ago. Now the old Dutch factory has the companies grounds, we could find little evidence to been replaced by a new one, mainly build with Indian reaffirm Zembla’s, a critical Dutch television program, made machinery. Besides signs from the Netherlands and accusations of unsafe working conditions and horrible India, some Japanese influence appeared on the walls in environmental impacts of the rose industry on the water the form of phrases like “Heart is the life to body: Kaizen balance or quality of the lake. Of course, research would is the life to industry” and “What is your Kaizen today?” have to be done to say this with any certainty but the The business mind in this plantation became even more impression we got was very different to the report of clear when we were told that the sugar cane plantation Zembla. Remarkable was also that next to every toilet currently was 6000 ha large and the plan was to expand free condoms were made available and that the nurse was to 12000 ha. Driving around the plantation we noticed helping someone with family planning at the moment we how big that actually is! Apparently some of us had been dropped by the company’s medical clinic. Most impressed too long away from their calculators as they started a were we, however, by the artificial swamp wastewater back of envelop calculation while driving around in the treatment facility. The wastewater would in sequence fields, how much water is needed to grow a kg of cane pass by different ponds each filled with a different kind sugar? We were told it required about 1700 m3 water of water plant. These would in turn remove different per ha per month, with sugar cane growing in cycles of kind of pollutants before the water was discharged into a 17 months, so each harvest about 30 000 m3 water per larger pond with fish, before then being discharged into hectare. Each hectare leading to 150 tons of cane, which the open water. We then returned to our resort to take exists for about 11% of sugar, resulted in about 1800 L a dive in the pool while it was raining, reflecting on all water per kg sugar. Being back home now, Google tells the great things we learned about water and business in me that this is quite close to the estimations of UN Water developing countries. of 1500 L per kg cane sugar. Well done, Jacco! Returning to the hotel with pieces of sugar cane still between our teeth, we had the chance to meet, Debebe, who works for the Awash Basis Authority, he told us about the cooperation of the Waterboard Zuiderzeeland and Unie van Waterschappen with the Awash Basin Authority. Main focus points in the Awash Basin are water scarcity, floods, water pollution, and land degradation. It was very interesting to hear his stories. 157 Education Marc van Eekeren Reisfonds Marc van Eekeren Reisfonds Uit respect voor de bijdrage die Marc van Eekeren aan bijwonen van een congres/studiereis). de watersector heeft geleverd en geïnspireerd door zijn Het fonds had in 2015 een redelijke omvang (ongeveer € passie voor het vak en zijn drive om de Nederlandse water 10.000 per jaar) en de resultaten waren erg positief. Zie sector internationaal te verbreden en te laten inspireren, hiervoor de enthousiaste reisverslagen van de studenten. is een fonds opgericht om Bachelor studenten van de TU Het Marc van Eekeren Reisfonds is onderdeel van Delft te motiveren en te ondersteunen om internationaal een campagne Bachelor studenten van de TU Delft te ervaring op te doen binnen de watersector: het Marc van interesseren in de watersector en uiteindelijk te binden Eekeren Reisfonds. en te werven voor de Mastertrack Watermanagement van de opleiding Civiele Techniek en Geowetenschappen. De TU Delft zet het Marc van Eekeren Reisfonds in als belangrijk strategisch middel om talentvolle Bachelor studenten aan de sector te binden. Het reisfonds biedt de Bachelor studenten de mogelijkheid om binnen de Bachelor studie een reis gesubsidieerd te krijgen, welke onderdeel vormt van een watergerelateerde 158 ervaring (stage/afstudeeropdracht/ [email protected] Marc van Eekeren Reisfonds Addressing the issues with the non-operating sewerage pumps in Maputo Proposing environmentally sustainable improvements During the winter of 2015/2016 we had the opportunity deal with the wastewater of the new building: treatment to do a study on the sewage system of Maputo, by septic tank and drain into the ground afterwards. The Mozambique. It was an experience we will never forget. University agreed with this solution although they knew We learned a lot about Mozambique and about the that this is not a solution on long term. (waste)water system over there. First of all we would like to thank the Marc van Eekeren travel fund for their Jesse Salet and Hidde Schijfsma contribution to our project. We would also like to thank Luuk Rietveld, André Marques Arsénio, Nelson Matsinhe and Noor Jehan Gulamussen for their support during our project. The goal of our research was to analyze the issues of the municipal sewerage system of Maputo. The pumps are not operating for over eight years and at the moment all the wastewater (that is normally pumped to the WWTP) is now discharged into the bay. This causes extra pressure to the already heavily polluted bay of Maputo. Our goal was to find out the issue behind the non-operating pumps and investigate how the system can be restored or even improved to operate in a more sustainable way. To gather all the necessary information people who know about the sewerage system in Maputo were consulted, and visual inspections have been done. With the gathered information we could conclude what the issues were behind the non-operating pumps. The problem had to do with an electrical meltdown which occurred in 2008. After this AIAS (governmental organization responsible for drinking water, sanitation and wastewater in Mozambique) was founded in 2009 and they replaced the pumps in 2013. We have reviewed the new pumps to see if they are suited for this particular situation and we concluded they are fine. In the time that the pumps did not operate and there was no pressure on the pressure line, the University of Eduardo Mondlane (UEM) connected the sewage line of a new building to the pressure line. AIAS discovered this when they wanted to test the pumps. The connection has already been removed, but the pressure line is not properly repaired. This pipeline should be repaired as soon as possible. The company that constructed the new building at the UEM-campus came up with a solution to 159 Education Marc van Eekeren Reisfonds PDAM Tirtawening Kota Bandung Improving the water treatment processes Since we are both internationally oriented, we wanted with a whopping 60% just by changing the dosage of to give our bachelor thesis an extra dimension by doing coagulant. the research abroad. We were lucky enough to receive the Mark van Eekeren fund and realize our plans. Our Most problems that cause the poor water quality final choice fell on Indonesia, a country far away from are simply fixed by properly operating the plant and the Netherlands where life is quite different from life back maintaining the equipment. This means that no big home. We were forced to adjust to living in a different investments are needed for the new part of the treatment country with a different culture. This was not always easy, plant to produce water of good quality. Instead, the staff but in the end we feel enriched with new experiences that should be educated on how to operate the plant properly. we will carry with us for the rest of our lives. At the end of the project we presented and discussed our For our thesis we travelled to Bandung, the capital findings to the director and staff of the water treatment of West-Java. The centrally located water treatment plant. Everybody is very happy with the results and we plant PDAM Tirtawening Kota Bandung is currently not hope that we have contributed to the improvement of operating optimally. The treatment steps are not able to PDAM Tirtawening Kota Bandung. We are very grateful treat the water properly, resulting in too high turbidities that we were able to travel across the planet to have in the system and in the effluent. Since the budget for this invaluable experience. We can wholeheartedly upgrading is limited, solutions should ideally be effective recommend doing a project abroad to anyone who is and cheap. The water treatment plant consists of two interested. parts, an old part built in 1958 and a new part added in Nicael Jooste & Bas Holman 1989. Our research was focused on the new part. The goal of our research was to improve the water treatment processes at PDAM Tirtawening Kota Bandung by evaluating the current process steps of the new part and improving upon them by applying simple adaptations. After multiple visual inspections in the first week it became apparent that the cause of the treatment inefficiency is not caused by a single large malfunction, but rather by a number of small problems. Due to poor maintenance nearly all metering equipment is malfunctioning or broken. Treatment processes are operated by instincts, guesstimation and trial and error. Jar tests are carried out by external high school students who have no knowledge on the matter, resulting in incorrect coagulant dosages and subsequently poor flocculation and sedimentation. Plastic is found throughout the system. The list of seemingly marginal problems goes on and on. After pinpointing multiple problems, base turbidity measurements were taken for one week throughout the plant. Multiple adaptations were researched and introduced to the system, which improved the removal of turbidity. It was found that turbidity levels decreased 160 Marc van Eekeren Reisfonds Soil Passage Water Purification A conceptual design for Jiaxing, China To write a thesis is a great experience on its own but dumplings and drink a few Tsingtaos. After this we took additional to the normal procedure, we got the experience the high speed train back to Beijing and stayed one more of travelling to China. Doing a project on the other side week in the Hutongs, were we worked hard to finish our of the world with such a great culture, that leads to cross thesis. sectional learning experiences. It was without doubt the most meaningful period of our bachelor curriculum. We We would really like to thank the Marc van Eekeren fonds did not only learn a lot about the subject of our thesis, for making this possible. It gave us a once in a lifetime we were also able to meet many interesting people. experience and great friendships. It was really swang! We met professors of the water section in Beijing, phD students, contractors and engineers that were all very Servaas Kievits and Vibeke van der Bilt warm in welcoming us into their country. We were able see the real action during our visits to the different water treatment plants and got to know a little bit more about international cooperation and especially the Chinese way of engineering. From the moment we arrived in China, it was a rollercoaster of experiences. The first days we were still insecure about everything , but excited to start. The professors told us more about the complexity of our subject and everything we needed to know. From that day on our motto was: work hard, play hard. We spend a lot of hours in the library or in cafes working on the thesis during the week. We worked from early in the morning, mostly until midnight. That was our way of getting the most out of the experience, because than we had plenty of time in the weekends to enjoy China. Another philosophy of ours was: ‘Learning a new Chinese word every day, and making a new friend every day’. This way we really pushed each other to meet new people and to get to learn more about the Chinese culture. One friend of us which we got to know via another friend was an extreme hiker. He took us to a forbidden section of the Great Wall. This was absolutely the most impressive day of our trip. We hiked hours in the wilderness to reach the Great Wall, and once we were there it was all left alone. Parts were all gone or overgrown, but with all the equipment we brought we were able to walk the Great Wall a few kilometers. Except for this experience, we also traveled to Chengdu, the city of the Jasmin tea, hotpots, eating rabbit heads and of course the center of the Pandas. Here we were also able to visit a drinking water treatment plant to learn more about their perspective on the subject. Finally we travelled to Shanghai to eat fried 161 Education Marc van Eekeren Reisfonds Innovative rainfall measurement devices in tropical regions A comparative data analysis for Yangon and Bago, Myanmar Due to the fact that Myanmar is a rapidly developing Results showed that rain intensities of the tipping bucket country, a good understanding of the precipitation and the manual rain gauges corresponded quite well, systems is becoming increasingly important. Last year the while the Delft-disdrometer results were very different. opportunity to do my Bachelor Thesis in Myanmar arose. This indicated that the calibration of the Delft-disdrometer Performing water related studies abroad has piqued my was not performed correctly. Recalibration was therefore interest since the start of my bachelor. During the monsoon performed using tipping bucket rain intensity results. period there are regular floods in Myanmar. To address this problem, it is necessary to study the hydrological cycle. In Rain forecasts in Myanmar are currently limited to the my research, I studied the rain which is very important for amount of showers per day in a large area. The desire designing a proper sewer system. The main focus of my to improve the temporal and spatial resolution of these Bachelor Thesis was comparing the measurement results forecasts is understandable. It is however, quite challenging of different rain devices. Furthermore, satellite precipitation to improve the quality in a developing country such as measurements were compared to ground based disdrometer Myanmar. The use of satellite imagery could provide a cheap measurements. solution to improve the rain forecasting system in Myanmar. The results of Global Precipitation Measurement results When I arrived in Myanmar, the country was celebrating was therefore compared to two disdrometers; the Delft- Thingyan. This is the Burmese New year, which ends in a disdrometer and the Thies LPM. The dropsize distribution five-day water festival. On every street in Yangon people and the rain intensity were the two main parameters for were partying and buckets were continuously filled with comparing results of these three devices. water. These buckets were subsequently emptied above everyone that joined these festivities. I was not spared of Firstly, theoretical dropsize distributions were compared to course, seeing a foreigner was a reason to even increase measurement results of the GPM and the two disdrometers. the rate at which buckets were filled and emptied. In the Both the GPM and the Thies LPM resulted directly in city centre a large waterfestival was organized. Water was a theoretically correct dropsize distribution (DSD). A being pumped out of Inya Lake and was used to spray theoretically sound DSD was also obtained with the results dancing visitors using a large garden hose. I came to of the Delft-disdrometer. In order to obtain this DSD an Myanmar to assess the rain intensities in this country, but additional step had to be performed, due to the fact that this extreme amount of human induced precipitation was the Delft-disdrometer is not capable of measuring droplets not something I expected to happen the first day of my smaller than 1 mm. arrival. After the water festival, I was less lucky with the Secondly, it was concluded that the DSD of the GPM was amount of precipitation however, the rainy season started very similar to measurements of the Thies LPM, in contraty extremely late this year. to the measured rain intensity. Unfortunately it was not possible to compare Delft-disdrometer measurements to After processing the first cultural shocks it was time GPM data due to the lack of simultaneous occurrences of to start with my research. Three types of precipitating rain events and GPM flyover. measurement devices had to be installed at the Yangon Dorien Honingh Technical University (YTU) in Yangon and at the Irrigration Technology Centre (ITC) in Bago. Installing these devices should be a relatively simple task, but I have experienced that even the smallest things can result in very long delays in Myanmar. After writing various letters and having multiple conversations at both institutes, the tipping buckets, Delftdisdrometer and the manual rain gauges were placed. 162 Completed MSc theses 2016 Arsenic oxidation and removal with Manganese oxides in Introduction Main results The actual European Union (EU) guidelines for allowed In the three experiment groups it is resulted that: concentration of arsenic (As) in drinking water fix a 1. With lower concentration of purer MnO2 materials, maximum of 10 μg/L. However, this limit is expected to oxidation of As(III) to As(V) was the main process involving become more stringent: the recommended health related As. limitation from the US Natural Resources Defense Council 2. As removal in presence of MnO2 material was is below 1 μg/L. enhanced by addition of Fe(II) to the system. However, the addition of Fe(II) inhibited As(III) oxidation by MnO2. Problem definition This inhibition is avoided in experiments with delayed In Dutch ground water treatment plants, the produced addition of Fe(II), when the As(III) oxidation step is drinking water is already far below the EU guidelines due completed. to As removal during sand filtration. On the sand grains, 3. The MnO2 in the column was active in the oxidation Manganese dioxide (MnO2) is present. MnO2 is able to processes of As and Fe. When the free surface MnO2 grains oxidize As(III) to As(V). This is advantageous because is still largely available, the resulting As concentration was As(III), usually the prevalent specie in groundwater, is lower than 5 μg/L. Afterwards, when more grain surface uncharged and more difficult to remove. On the other is occupied by Fe and other compounds, As removal hand, negatively charged As(V) molecules can be easier decreased. removed by positively charged iron (Fe) (hydro)oxides in filters. Main conclusions and recommendations Fe inhibits As(III) oxidation by MnO2, but it is also The oxidation of As(III) to As(V) during filtration responsible for As removal. The inhibition processes of groundwater in presence of MnO2 needs to be suggested by the results are competitive oxidation and understood in order to improve this process by adjusting surface passivation. The relative importance of these the operational parameters of treatment plants. two processes should be studied further. Regarding the operational parameters, tests with a broader pH range Research can be performed. Moreover, the influence of filter My research focused on the processes of As(III) oxidation bacteria has to be considered as well. to As(V) by MnO2 at neutral or slightly alkaline pH. I also took into consideration the role of (oxidizing) Fe Student: I. Caltran as inhibitor in As(III) oxidation and as remover of As. I Committee: Prof. Dr. Ir. L.C.Rietveld, performed laboratory three groups of experiments at the Dr. Ir. D.van Halem, TU Delft Waterlab and at the treatment plant of Vitens in Ir. Jink Gude, Loosdrecht: Prof. Dr. P.J.Stuijfzand, 1. Ir. F.Schoonenberg (Vitens) Jar tests using demineralized water with low concentration of As(III) and powders containing MnO2 2. Jar tests using demineralized water with low concentration of As(III), powder containing MnO2 and oxidizing Fe(II). 3. Column tests using groundwater after aeration with As and Fe, and fresh grains containing MnO2 163 Education Completed MSc theses 2016 Sodium chloride recovery from brines for reuse purposes in zero liquid discharge Introduction Research In the application of the Zero Liquid Discharge (ZLD) This research focussed on the production of a high strategy, no liquid waste streams leave the waste water purity NaCl stream, either solid or dissolved, as the ZLD treatment plant (WWTP). In this strategy, all water is WWTP is able to finally produce solid NaCl. The research recovered for reuse from concentrated saline water question was: “What is/are the most suitable intervention streams: brines. ZLD is an interesting strategy in case technique(s) contributing to produce high purity NaCl in of fresh water scarcity, brine discharge regulations (both the ZLD WWTP?” are often related) and the availability of waste heat and is To this extend, nanofiltration, electrodialysis and ion therefore mostly applied in industry. exchange were experimentally tested to their potential to isolate dissolved NaCl (separate NaCl from the Problem definition contaminants). Additionally, a solid purification technique In the strategy of an actual full-scale ZLD WWTP the focus (SALEX) was tested as alternative to produce high purity lies on high quality water production, which is recovered solid NaCl by post-treatment. from reverse osmosis brine. After full water recovery of this stream, a solid residual stream is produced, consisting of mixed solids. Currently the mixed solids are landfilled. The bulk of these solids consists of sodium chloride (NaCl), which has great potential to be reused when it is of high purity. To this extent, the purity of the NaCl must be improved, because in the mixed solids various contaminants are found: organic matter, silica and iron. 164 Completed MSc theses 2016 Results Of the three tested water treatment techniques, electrodialysis and ion exchange proved to produce a high purity dissolved NaCl stream, in terms of organic matter, but did not meet the silica quality restrictions. Results of iron content in the NaCl appeared to be unreliable, caused by major concentration differences between the bulk elements (sodium and chloride) and iron during analysis. The SALEX technique proved to produce a high purity solid NaCl, meeting the quality restrictions for both organic matter and silica in solid NaCl. Conclusions and recommendations The isolation of NaCl in dissolved state appeared to depend on the specific characteristics of the various dissolved contaminants. Certain constituents have similar characteristics as NaCl and are therefore not separated from the dissolved NaCl. Therefore, no water treatment technique was able to produce a dissolved NaCl stream with a purity high enough to be reused. SALEX proved to be able to extract the contaminants from the mixed solids and did produce a solid NaCl stream with sufficiently high purity to be reused. Therefore, for this situation, it is recommended to implement SALEX in the ZLD WWTP, in order to also recover NaCl for reuse purposes. Student: Niels van Linden Committee: Prof. Dr. Ir. L.C. Rietveld, Prof. Dr. Ir. G.J. Witkamp, Dr. Ir. H. Spanjers, Dr. Ir. S.G.J. Heijman, Dr. Ir. R. Shang, G. Stockinger MSc. (Shell Global Solution International B.V.) 165 Education Completed MSc theses 2016 Overview of all completed MSc theses NameSubject Janneke Moors: Model-based leak localization in small water supply networks John Laurence Esguerra: A life cycle analysis of the technical costs and social costs for the provision of sanitation services in Maputo, Mozambique Kjell Wansleeben: Spatial consequences of circular water systems Vanida Salgado Ismodes – Bromate removal by chemical reduction using iron (II) Nathalie van Veen Possibilities for rooftop rainwater harvesting for off-grid households - Case study: Serang, Indonesia Stefanie Stubbé: The Fate of Phosphate in Full-scale Aerobic Granular Sludge Systems Niels van Linden: Sodium chloride recovery from brines for reuse purposes in zero liquid discharge Frans Willem Hamer: Calcium carbonate precipitation during subsurface injection of RO-brine: The effect on the hydraulic conductivity Irene Caltran: Arsenic oxidation and removal with Manganese oxides in filters Joanne Haveman: Effect of drilling fluid contamination by zinc ions on drilling fluid rheological behaviour Abel Heinsbroek: Calcium Hydroxide as Precipitative Antiscalant for Nanofiltration 166 Completed BSc theses 2016 Overview of all completed Watermanagement BSc theses NameSubject Samet Agca Anaerobic Membrane Bioractors Coen Hulsebosch Nicaragua Jochem Roubos Nicaragua Jef Vleugels Het gebruik van natuur in de drinkwatervoorziening Stan Vernimmen Het gebruik van natuur in de drinkwatervoorziening Lennart Dekker Reverse osmosis Thomas Vos Virusverwijdering door potfilters Laura van der Hucht Verwijdering van organische micro-verontreiniging Gerben Postema Project Bangladesh Wilson Haaijen Water in Maputo, Mozambique Sara Essam Drinking water Nile River Nathaniel Rasmioen Influence of flow velocity on thermal energy recovery Toan Nguyen Sustainable water management in the CiTG building Karen Silvius De stedelijke watercyclus in Amsterdam Bas Holman Water treatment in Bandung Nicael Jooste Water treatment in Bandung Jesse Salet Water in Maputo, Mozambique Hidde Schijfsma Water in Maputo, Mozambique Teun Doggenaar De stedelijke watercyclus in Amsterdam Tom Damen Asbest in de rioolwaterzuiveringsinstallatie Carmen Liu De waterkwaliteit voor beton Noor Holland Is het water uit de Hoge Venen in de Ardennen drinkbaar? Yoram Houtsma Is het water uit de Hoge Venen in de Ardennen drinkbaar? Tom Remijn Marmerfilters bij waterzuiveringsbedrijven in Nederland Auke Tempel Amsterdam/De stedelijke watercyclus in de SWEDES city index Holland Berend Eldonk, van Comparison of two water treatment simulator platforms Ainoa Areso Rossi Handpump membrane filtration for developing countries Ruben Doggen Arseenverwijdering uit water Emma Croiset van Uchelen Afvalwater in India Pim Versteeg Hydrorock D’tasha Demmerer Anaerobic Membrane Bioreactors Vibeke Bilt, van der Water in China Karel Hof Waterkwaliteit in Bandung, Indonesië Marijn Rooij, de Realtime zwemmen in Amsterdam 167 Education Online Education MOOCs It was back in 2007 that our section, as one of the pioneers that help to build a community for the learners, where of this university, offered its first courses on water treatment professors and teaching assistants actively participate in as OpenCourseWare (OCW). OCW is a free and open digital forum discussions. Today, the TU Delft has reached over one publication of high quality university-level educational million enrolments in its 36 MOOCs in the field of science, material. OCW is openly licensed, accessible to anyone and design and engineering. Hundreds of thousands of learners anytime via the internet. A more recent and much more from all around the world are now able to gain access to appealing form is a Massive Open Online Course (MOOC). A the knowledge and expertise of the TU Delft through open MOOC is a free online course aiming at large-scale interactive online courses. participation and open access via the web. In addition to traditional course materials such as videos, readings, and problem sets. MOOCs provide interactive user-forums 168 Online Education WaterX series At the Sanitary Engineering department we have two the learner has successfully completed the online course. MOOCs running, namely “Drinking Water Treatment” and During the last run, almost 400 learners bought a verified “Treatment of Urban Sewage”. We even won an award for certificate. Together with the MOOC “Water & Climate” from them! During the last run in March 2016, more than 25.000 the Water Resources section, the three MOOCs form the learners from more than 180 countries enrolled for these WaterX series. When a learner successfully completes all online courses. When finishing the course, learners can buy three MOOCs, he will receive the XSeries Certificate, which a verified certificate. A verified certificate can provide proof is a true achievement! for an employer, school, or other institution that 169 Education Online Education Blended learning Therefore the course has a strong practical approach; Because of the availability of the MOOC material, campus participants can apply the learning material into their education has changed into a more blended way of teaching. working environment and get personal feedback from the The knowledge clips, tutorials and quiz questions that were professors. Combining academics and action! For example, developed for online education purposes are now being in the ProfEd about Nereda technology, participants can used by our own campus students as additional educational learn how to integrate this technology in their existing material. Campus students are sometimes required to have system. They’re assisted by consultants from Royal read the material before attending the lecture, so that Haskoning DHV, who are partner in this ProfEd. Developing the lecturer can actively interact with the students during one ProfEd would be just plain, that’s why the section is the lecture in a so-called “flip the class room” approach. creating another two more! One is about “Membrane This new way of teaching has shown that not only the Filtration” and the other covers “Anaerobic Treatment”. As inscriptions to these courses but also the passing rates have the course teams strive to give the learners the best online increased remarkably. learning experience, they stretch all their potentials, like filming on a Marine ship. Feeling enthusiastic? All three will New developments: ProfEd go live during the upcoming year, so stay tuned. As the university promotes lifelong learning, our section has come up with a new product: the ProfEd! This is a short and More information & registration intensive course for working professionals. The ProfEd is an For the look and feel of our MOOCs go to edX and participate! online education product for which learners have to pay, in For an overview of all online education activities at the TU contrary to the MOOCs. Learners also receive more personal Delft, please visit the online learning website. The online guidance from the course team and the team works actively courses of our Mastertrack can be found on the website of together with (water)companies in creating the course. our department. 170 Online Education ProfEd membrane filtration Reliable access to fresh water is one of the fundamental The course divided into seven weeks and each week pillars on which a society is built. However, only a tiny has its own theme. First, the course provides general fraction of planet’s water is directly readily available as information about the RO, its principle, and calculation freshwater [1, 2]. The shortage of potable water, as methods (Week 01). Then, it will focus on the applications consequence of population growth, current consumption of the RO on different type of water: seawater (Week patterns and climate changing, will be a major problem in 02), Brackish water (Week 03), and fresh surface water the coming decades and will have the same social impact (Week 05) and the main problems of using RO with this as that of increased energy prices [3-6]. Groundwater is type of water: concentration polarization and scaling by far the most abundant and readily available source (week 04) and biofouling (week05). Finally, some design of freshwater [2]. When used for drinking water, fresh consideration will be explained (Week 07). groundwater sources are preferred to other readily freshwater sources because of the absence of pathogens. Each week consist of several knowledge clips, quiz However, regions with sustainable fresh groundwater questions, and homework. Knowledge clips are about the resources are shrinking by the day, throughout the world. theoretical matters, practical matters, or an excursion to a A solution to this problem is the use of saline water to membrane based treatment plant. Excursions are planned produce drinking water. Among different desalination to a seawater RO on a ship (Karel Doorman ship), a techniques, Reverse Osmosis (RO) has become an brackish water RO (Oasen water company), and industrial attractive solution for water shortage. The purified water RO treatment plant (Evides water company). Home water from RO can be used in drinking water, dialysis, works are also very diverse. For example, the participant power generation, pharmaceuticals and medical devices, has to do an online measurement by the provided manufacturing of semiconductors, and paper, sugar animated simulation (week 04) or making his own SWM and beverage industry as well as concentrating and modules by using colored papers and glue (week 06). reclamation of wastewater [1-10]. Therefore, knowing the RO-technologies is important for a significant number of people with the diverse educational background. Therefore, the sanitary engineering department of Delft University of Technology developed an online about the RO membrane to offer busy, working professionals all over the world a flexible, convenient way to strengthen and enhance their professional skills, increase their value as employees, and advance themselves to a higher position or earn a higher salary. The online membrane professional education focuses particularly on the Spiral-wound membrane (SWM) configuration because that is predominately applied in NF and RO. 171 172 Annual report 2016 Publications 173 Publications Publications Doctoral dissertation Bruins, J. (2016) Manganese removal from groundwater: Role of biological and physico-chemical autocatalytic processes. TUD Technische Universiteit Delft. Ghasimi, S. M. D. (2016) Bio-methanation of fine sieved fraction sequestered from raw municipal sewage. TUD Technische Universiteit Delft. Peters, M. (2016, 25 November) Microbiology in swimming pools: UV-based treatment versus chlorination. TUD Technische Universiteit Delft. Post, J. (2016) A statistical approach to guide the management of the anterior part of the sewer system. TUD Technische Universiteit Delft. Sanchez Torres, L. (2016, 28 April) Upflow gravel filtration for multiple uses. TUD Technische Universiteit Delft. Stanic, N. (2016) Assessment methods for structural and hydraulic properties of concrete sewer pipes. TUD Technische Universiteit Delft. Sánchez Guillén, J. A. (2016) Autotrophic Nitrogen Removal from Low Concentrated Effluents: Study of system configurations and operational features for post-treatment of anaerobic effluents. TUD Technische Universiteit Delft. van Riel, W. (2016, 6 July) On decision-making for sewer replacement. TUD Technische Universiteit Delft. Journal refereed papers Agtas, M., Ersahin, M. E., Ozgun, H. & Koyuncu, I. 2016 In : Separation Science and Technology (Philadelphia). p. 1-10 10 p. Impact of module design on the performance of membrane bioreactors treating municipal wastewater Agudelo-Vera, C., Blokker, M., Vreeburg, J., Vogelaar, H., Hillegers, S. & van der Hoek, J. P. 7 Apr 2016 In : Journal of Water Resources Planning and Management. 142, 8, p. 1 - 11 11 p., 05016003. Testing the robustness of two water distribution system layouts under changing drinking water demand Alidai, A. & Pothof, I. W. M. 2016 In : Desalination and Water Treatment: science and engineering. 57, 5, p. 1917-1928 12 p. Guidelines for hydraulic analysis of treatment plants equipped with ultrafiltration and reverse osmosis membranes Barrera, E. L., Rosa, E., Spanjers, H., Romero, O., De Meester, S. & Dewulf, J. 1 Feb 2016 In : Journal of Cleaner Production. 113, p. 459-471 13 p. A comparative assessment of anaerobic digestion power plants as alternative to lagoons for vinasse treatment: Life cycle assessment and exergy analysis Bennani, Y., Perez-Rodriguez, P., Alani, M. J., Smith, W. A., Rietveld, L. C., Zeman, M. & Smets, A. H. M. 14 Sep 2016 In : Journal of Materials Research. 31, 17, p. 2627-2639 13 p. Photoelectrocatalytic oxidation of phenol for water treatment using a BiVO4 thin-film photoanode Bertelkamp, C., van der Hoek, J. P., Schoutteten, K., Hulpiau, L., Vanhaecke, L., Vanden Bussche, J., Cabo, A. J., Callewaert, C., Boon, N., Lowenberg, J., Singhal, N. & Verliefde, A. R. D. 2016 In : Chemosphere. 144, February, p. 932-939 8 p. The effect of feed water dissolved organic carbon concentration and composition on organic micropollutant removal and microbial diversity in soil columns simulating river bank filtration 174 Publications Bertelkamp, C., Verliefde, A. R. D., Schoutteten, K., Vanhaecke, L., Vanden Bussche, J., Singhal, N. & van der Hoek, J. P. 2016 In : Science of the Total Environment. 544, February, p. 309-318 10 p. The effect of redox conditions and adaptation time on organic micropollutant removal during river bank filtration: A laboratory-scale column study Bonte, M., Wols, B., Maas, K. & Stuijfzand, P. J. 11 Oct 2016 In : Hydrogeology Journal. p. 1-12 12 p. Fuentes de oxígeno disuelto en pozos de monitoreo y de bombeo Boogaard, F. C., van de Ven, F. H. M., Langeveld, J. G., Kluck, J. & van de Giesen, N. C. 2016 In : Urban Water Journal. p. 1-8 8 p. Removal efficiency of storm water treatment techniques: Standardized full scale laboratory testing Chen, Y., Xie, P., Wang, Z., Shang, R. & Wang, S. 2016 In : Journal of Hazardous Materials. 8 p. UV/persulfate preoxidation to improve coagulation efficiency of Microcystis aeruginosa Deng, Z., Mol, S. & van der Hoek, J. P. 2016 In : Drinking Water Engineering and Science. 9, January, p. 1-8 8 p. Shower heat exchanger: reuse of energy from heated drinking water for CO2 reduction Ersahin, M. E., Tao, Y., Ozgun, H., Spanjers, H. & van Lier, J. B. 2016 In : Biotechnology and Bioengineering. 113, 4, p. 761771 11 p. Characteristics and role of dynamic membrane layer in anaerobic membrane bioreactors Ghasimi, S. M. D., Aboudi, K., de Kreuk, M. K., Zandvoort, M. H. & van Lier, J. B. 2016 In : Chemical Engineering Journal. 295, July, p. 181-191 11 p. Impact of lignocellulosic-waste intermediates on hydrolysis and methanogenesis under thermophilic and mesophilic conditions Ghasimi, S. M. D., de Kreuk, M. K., Maeng, S. K., Zandvoort, M. H. & van Lier, J. B. 2016 In : Applied Energy. 165, March, p. 569-582 14 p. High-rate thermophilic bio-methanation of the fine sieved fraction from Dutch municipal raw sewage: Costeffective potentials for on-site energy recovery Ghasimi, D. S. M., Zandvoort, M. H., Adriaanse, M., van Lier, J. B. & de Kreuk, M. 1 Jul 2016 In : Waste Management. 53, p. 156-164 9 p. Comparative analysis of the digestibility of sewage fine sieved fraction and hygiene paper produced from virgin fibers and recycled fibers Gude, J. C. J., Rietveld, L. C. & van Halem, D. 2016 In : Water Research. 88, January, p. 566-574 9 p. Fate of low arsenic concentrations during full-scale aeration and rapid filtration Hrachowitz, M., Benettin, P., van Breukelen, B., Fovet, O., Howden, N. J. K., Ruiz, L., van der Velde, Y. & Wade, A. J. 2016 In : Wiley Interdisciplinary Reviews: Water. 3, 5, p. 629–657. Transit times: The link between hydrology and water quality at the catchment scale Hu, J., Shang, R., Frolova, M., Heijman, S. G. J. & Rietveld, L. C. 2016 In : Desalination and Water Treatment: science and engineering. p. 1-10 10 p. Pharmaceutical adsorption from the primary and secondary effluents of a wastewater treatment plant by powdered activated carbon Hu, J., Shang, R., Heijman, S. G. J. & Rietveld, L. C. 2016 In : Chemosphere. 150, May, p. 49-56 8 p. Influence of activated carbon preloading by EfOM fractions from treated wastewater on adsorption of pharmaceutically active compounds Hu, J., Aarts, A., Shang, R., Heijman, B. & Rietveld, L. 2016 In : Journal of Environmental Management. 177, p. 45-52. Integrating powdered activated carbon into wastewater tertiary filter for micro-pollutant removal 175 Publications Publications Lepot, M., Pouzol, T., Aldea Borruel, X., Suner, D. & Bertrand-Krajewski, J. L. 3 Mar 2016 In : Urban Water Journal. p. 1-9 9 p. Measurement of sewer sediments with acoustic technology: From laboratory to field experiments Liu, G., Ling, F. Q., van der Mark, E. J., Zhang, X., Knezev, A., Verberk, J. Q. J. C., van der Meer, W. G. J., Medema, G., Liu, W. T. & van Dijk, J. C. 2016 In : Scientific Reports. 6, February, p. 1-8 8 p. Comparison of particle-associated bacteria from a drinking water treatment plant and distribution reservoirs with different water sources Liu, X., Tzimiris, G., Scarpas, A. & Li, J. 1 May 2016 In : Journal of Testing and Evaluation. 44, 3, p. 1205-1216 12 p. Analysis and assessment of fatigue response of multilayer asphalt surfacing system on orthotropic steel deck bridge with the fivepoint bending beam tests Liu, Z., Guo, Y., Shang, R., Fang, Z., Wu, F. & Wang, Z. 2016 In : Journal of the Taiwan Institute of Chemical Engineers. 7 p. A triple system of Fe(III)/sulfite/persulfate: Decolorization and mineralization of reactive Brilliant Red X-3B in aqueous solution at near-neutral pH values Lousada-Ferreira, M., van Lier, J. B. & van der Graaf, J. H. J. M. 2016 In : Separation and Purification Technology. 161, March, p. 16-24 9 p. Particle counting as surrogate measurement of membrane integrity loss and assessment tool for particle growth and regrowth in the permeate of membrane bioreactors Mangimbulude, J. C., Goeltom, M. T., van Breukelen, B., van Straalen, N. M. & Roling, W. F. M. 2016 In : Asian Journal of Water, Environment and Pollution. 13, 4, p. 49–57. Hydrochemical Characterization of a Tropical, Coastal Aquifer Affected by Landfill Leachate and Seawater Intrusion Mohd Amin, M. F., Heijman, S. G. J. & Rietveld, L. C. 1 Apr 2016 In : Water Science and Technology. 73, 7, p. 1719-1727 9 p. Clay-starch combination for micropollutants removal from wastewater treatment plant effluent Post, J. A. B., Pothof, I. W. M., Dirksen, J., Baars, E. J., Langeveld, J. G. & Clemens, F. H. L. R. 1 Jan 2016 In : Water Research. 88, p. 245-256 12 p. Monitoring and statistical modelling of sedimentation in gully pots Reyes, M. F., Trifunovic, N., Sharma, S. & Kennedy, M. D. 2016 In : Desalination and Water Treatment: science and engineering. 57, 45, p. 21335-21349. Data assessment for water demand and supply balance on the island of Santa Cruz (Galápagos Islands Rodríguez-Escales, P., Folch, A., Vidal-Gavilan, G. & van Breukelen, B. 28 Jan 2016 In : Chemical Geology. 425, May, p. 5264 13 p. Modeling biogeochemical processes and isotope fractionation of enhanced in situ biodenitrification in a fractured aquifer Rodríguez-Escales, P., Folch, A., van Breukelen, B. M., Vidal-Gavilan, G. & Sanchez-Vila, X. 1 Jul 2016 In : Journal of Hydrology. 538, p. 127-137 11 p. Modeling long term Enhanced in situ Biodenitrification and induced heterogeneity in column experiments under different feeding strategies Ross, P. S., Van Der Helm, A. W. C., Van Den Broeke, J. & Rietveld, L. C. 21 Apr 2016 In : Analytical Methods. 8, 15, p. 3148-3155 8 p. On-line monitoring of ozonation through estimation of Ct value, bromate and AOC formation with UV/Vis spectrometry 176 Publications Sanchez, L. D., Valencia-Zuluaga, V., Echeverri-Sanchez, A., Visscher, J. T. & Rietveld, L. C. 2016 In : Journal of Irrigation and Drainage Engineering. 142, 1, p. 04015035-1-04015035-7. Impact of upflow gravel filtration on the clogging potential in microirrigation Sanchez Guillen, J. A., Lopez Vazquez, C. M., de Oliveira Cruz, L. M., Brdanovic, D. & van Lier, J. B. 2016 In : Biochemical Engineering Journal. 110, June, p. 95-106 12 p. Long-term performance of the Anammox process under low nitrogen sludge loading rate and moderate to low temperature Schoutteten, K. V. K. M., Hennebel, T., Dheere, E., Bertelkamp, C., De Ridder, D. J., Maes, S., Chys, M., Van Hulle, S. W. H., Vanden Bussche, J., Vanhaecke, L. & Verliefde, A. R. D. 1 Dec 2016 In : Chemosphere. 165, p. 191-201 11 p. Effect of oxidation and catalytic reduction of trace organic contaminants on their activated carbon adsorption Stanic, N., Langeveld, J., Salet, T. & Clemens, F. 5 Jun 2016 In : Structure and Infrastructure Engineering (online). p. 1-15 15 p. Relating the structural strength of concrete sewer pipes and material properties retrieved from core samples Taucer-Kapteijn, M., Hoogenboezem, W. & Medema, G. 1 Aug 2016 In : Water Science and Technology: Water Supply. 16, 4, p. 971-979 9 p. Environmental growth of the faecal indicator Enterococcus moraviensis Taučer-Kapteijn, M., Hoogenboezem, W., Heiliegers, L., de Bolster, D. & Medema, G. 1 Jul 2016 In : International Journal of Hygiene and Environmental Health. 219, 4-5, p. 437-442 6 p. Screening municipal wastewater effluent and surface water used for drinking water production for the presence of ampicillin and vancomycin resistant enterococci Van Riel, W., Langeveld, J., Herder, P. & Clemens, F. 1 Aug 2016 In : Water Science and Technology. 74, 4, p. 796-804 9 p. Valuing information for sewer replacement decisions Wang, W., Wang, S., Feng, J., Yuan, S., Hu, Z., Munoz Sierra, J. D. & Zhang, X. 2016 In : Desalination and Water Treatment: science and engineering. p. 1-8 8 p. Kinetics of hydroquinone oxidation by a wire¿cylinder dielectric barrier discharge reactor Wang, F., van Halem, D. & van der Hoek, J. P. 2016 In : Chemosphere. 148, April, p. 263-269 7 p. The fate of H2O2 during managed aquifer recharge: A residual from advanced oxidation processes for drinking water production Wang, W., Wang, S., Zhang, J., Hu, Z., Zhang, X. & Munoz Sierra, J. D. 2016 In : International Biodeterioration and Biodegradation. p. 1-8 8 p. Degradation kinetics of pentachlorophenol and changes in anaerobic microbial community with different dosing modes of co-substrate and zero-valent iron Wang, Z., Chen, Y., Xie, P., Shang, R. & Ma, J. 15 Sep 2016 In : Chemical Engineering Journal. 300, p. 245-253 9 p. Removal of Microcystis aeruginosa by UV-activated persulfate: Performance and characteristics Yaya-Beas, R. E., Cadillo-La-Torrea, E. A., Kujawa-Roeleveld, K., van Lier, J. B. & Zeeman, G. 2016 In : Water Research. 90, March, p. 286-293 8 p. Presence of helminth eggs in domestic wastewater and its removal at low temperature UASB reactors in Peruvian highlands Zhang, X., Hu, J., Spanjers, H. & van Lier, J. 2016 In : Bioresource Technology. 218, p. 1151-1156. Struvite crystallization under a marine/brackish aquaculture condition Zhang, X., Tao, Y., Hu, J., Liu, G., Spanjers, H. & van Lier, J. 2016 In : Bioresource Technology. 214, p. 338-347. Biomethanation and microbial community changes in a digester treating sludge from a brackish aquaculture recirculation system 177 Publications Publications de Goede, M., Enserink, B., Worm, I. & van der Hoek, J. P. 2016 In : Water Policy. 18, 5, p. 1247–1266. Drivers for performance improvement originating from the Dutch drinking water benchmark de Valk, S., Khadem, A. F., Foreman, C. M., van Lier, J. B. & de Kreuk, M. K. 29 Sep 2016 In : Environmental Technology. p. 1-15 15 p. Physical and biochemical changes in sludge upon Tubifex tubifex predation van Breukelen, B. & Bonte, M. 2016 In : Environmental Science & Technology (Washington). 50, 13, p. 7263-7264. Comment on “Thermally Released Arsenic in Porewater from Sediments in the Cold Lake Area of Alberta, Canada” van Daal-Rombouts, P., Sun, S., Langeveld, J., Bertrand-Krajewski, J-L. & Clemens, F. 4 May 2016 In : Journal of Hydrology. 538, July, p. 609-624 16 p. Design and performance evaluation of a simplified dynamic model for combined sewer overflows in pumped sewer systems van Riel, W., van Bueren, E., Langeveld, J., Herder, P. & Clemens, F. 2016 In : Urban Water Journal. 13, 1, p. 57-68 12 p. Decision-making for sewer asset management: Theory and practice van Riel, W., Post, J., Langeveld, J., Herder, P. & Clemens, F. 6 Aug 2016 In : Structure and Infrastructure Engineering (online). p. 1-14 14 p. A gaming approach to networked infrastructure management van Riel, W., Langeveld, J., Herder, P. & Clemens, F. 25 May 2016 In : Structure and Infrastructure Engineering (online). p. 1-13 13 p. The influence of information quality on decision-making for networked infrastructure management van der Hoek, J. P., Struker, A. & de Danschutter, J. E. M. 2016 In : Urban Water Journal. p. 1-8 8 p. Amsterdam as a sustainable European metropolis: integration of water, energy and material flows van der Hoek, J. P., Mol, S., Janse, T., Klaversma, E. & Kappelhof, J. 2016 In : Journal of Water and Climate Change. 7, 1, p. 29-38 10 p. Selection and prioritization of mitigation measures to realize climate neutral operation of a water cycle company van der Hoek, J. P., de Fooij, H. & Struker, A. 11 Jun 2016 In : Resources, Conservation and Recycling. 113, October, p. 53-64 12 p. Wastewater as a resource: Strategies to recover resources from Amsterdam’s wastewater Conference papers Cristiano, E., ten Veldhuis, M-C., van de Giesen, N. & ten Veldhuis, M-C. (ed.) 2016 In : Geophysical Research Abstracts (online). 18, p. 1-1 1 p., EGU2016-8941. Influence of high resolution rainfall data on the hydrological response of urban flat catchments Rietveld, L. C., Siri, J. G., Chakravarty, I., Arsenio, A. M., Biswas, R. & Chatterjee, A. 2016 Proceedings of the 11th international conference on urban health. Vardoulakis, S., Wilkinson, P. & Dear, K. (eds.). London: Biomes central, p. 151-160 10 p. (Environmental Health: AGlobal Access Science Source; vol. 15). Improving health in cities through systems approaches for urban water management Roezer, V., Spekkers, M., Kreibich, H. & Kreibich, H. (ed.) 2016 In : Geophysical Research Abstracts (online). 18, p. 1-1 1 p., EGU2016-14587. Preliminary results from two international pluvial flood event studies van Daal-Rombouts, P., de Jonge, J., Langeveld, J. & Clemens, F. 2016 Proceedings of the 8th International Conference on Sewer Processes and Networks: SPN8 , Rotterdam, The Netherlands. 4 p. Integrated real time control of influent pumping station and primary settling tanks at WWTP Eindhoven 178 Publications van de Giesen, N., Selker, J., Sayde, C., Thomas, C. K., Higgins, C., Schilperoort, B., Coenders, M., Luxemburg, W., Hilgersom, K., van Emmerik, T., Solcerova, A., Berghuijs, W. & Vivekanandan, . J. (ed.) 2016 In : Geophysical Research Abstracts (online). 18, p. 1-1 1 p., EGU2016-4382. Distributed Temperature Sensing in the Atmosphere Newspaper article Bertelkamp, C., van der Hoek, J. P., Schoonenberg Kegel, F., Timmer, H. & Verliefde, A. 28 Apr 2016 In : H2O: tijdschrift voor watervoorziening en waterbeheer. 2016, 1, p. 1-5 5 p. Hoe voorspelbaar is de zuivering via oeverfiltratie? van der Hoek, J. P. 2016 In : Waterspiegel. 2016, Juni, p. 12-13 2 p. Water en Gezondheid 179 180
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