Station 1: Ionization Reactions Directions: For each of the following acids, write the ionization reaction that displays what happens to the acid in water. Ionization should include only 1 of the hydrogen atoms. Remember that the charges on both sides of the equation must balance. Example: H2SO3: H2SO3(aq) + H2O(l) H3O+(aq) + HSO3-(aq) 1. H3PO4: 2. H2SO4 : 3. HF: 4. HBr: Directions: For each of the following bases, write the ionization reaction that displays what happens to the base in water. Assume that all bases start as solids. Remember that the charges and atoms on both sides of the equation must balance. Example: NaOH: 5. LiOH: 6. Ca(OH)2: 7. Ba(OH)2: 8. Fe(OH)3: NaOH (s) Na+ (aq) + OH- (aq) Station 2: Identifying Arrhenius Acids and Bases 1. Complete the following neutralization equations. Make sure each equation is balanced, and circle the salt produced. a. CH3COOH + LiOH b. Mg(OH)2 + H3PO4 c. Sulphuric acid reacting with iron(III) hydroxide 2. Write the formula and the name for the parent acid and the parent base that react to form each salt listed: Parent Acid a. KNO2 b. NH4Cl c. CuC2O4 Parent Base Station 3: Identifying Conjugate Acid-Base Pairs 1. In the following equilibrium, identify the acids and bases, and the two conjugate acid-base pairs: HF(aq) + CN-(aq) ⇌ HCN(aq) + F-(aq) 2. Complete the following table: Conjugate Acid H2C2O4 Conjugate Base SO32- HCO3H2O 3. Complete the following equilibrium, which represents the reaction of a Bronsted-Lowry acid and base. Circle the substances that make up one of the conjugate acid base pairs. NO2-(aq) + H2CO3(aq) ⇌ 4. Write the Bronsted-Lowry acid-base equilibria which occurs when the following pairs of substances are mixed in solution. a. HPO42- and SO42- b. HIO3 and C2O42- Station 4: Amphiprotic Species 1. Write an equation for a reaction between HCO3- and CNwhere HCO3- acts as an acid. 2. Write an equation for a reaction between HCO3- and H2O where HCO3- acts as a base. 3. a. Identify the amphiprotic substances in the following list: i. CH3COOH ii. H2PO4iii. PO43iv. H2C2O4 v. HC2O4b. Explain what an amphiprotic species is and give the characteristics it must possess. ANSWER KEY Station 1 1. H3PO4(aq) + H2O H3O+ + H2PO4- 2. H2SO4(aq) + H2O H3O+ + HSO4- 3. HF(aq) + H2O H3O+ + F- 4. HBraq) + H2O H3O+ + Br- 5. LiOH(s) Li+(aq) + OH-(aq) 6. Ca(OH)2(s) Ca2+(aq) + 2 OH-(aq) 7. Ba(OH)2(s) Ba2+(aq) + 2 OH-(aq) 8. Fe(OH)3(s) Fe3+(aq) + 3 OH-(aq) 1. a. CH3COOH(aq) Station 2 + LiOH(aq) H2O(l) + LiCH3COO(aq) b. 3 Mg(OH)2 (aq) + 2 H3PO4(aq) 6 H2O(l) + Mg3(PO4)2(aq) c. 3 H2SO4(aq) + 2 Fe(OH)3(aq) 6 H2O(l) + Fe2(SO4)3(aq) 2. KNO2 Parent Acid: HNO2 – nitrous acid Parent Base: KOH – potassium hydroxide NH4Cl Parent Acid: HCl – hydrochloric acid Parent Base: NH3 – ammonia or NH4OH – ammonium hydroxide CuC2O4 Parent Acid: H2C2O4 – oxalic acid Parent Base: Cu(OH)2 – copper(II) hydroxide Station 3 1. 2. 3. HF(aq) + CN-(aq) ⇌ HCN(aq) + F-(aq) Acid Base Acid Base Conjugate Acid H2C2O4 HSO3HCO3H3O+ Conjugate Base HC2O4SO32CO32H2O NO2-(aq) + H2CO3(aq) ⇌ HNO2 + HCO3- 4. a. HPO42- and SO42HPO42- + SO42- ⇌ PO43- + HSO4b. HIO3 and C2O42HIO3 + C2O42- ⇌ IO3- and HC2O4Station 4 1. HCO3- + CN- ⇌ CO32- + HCN 2. HCO3- + H2O ⇌ H2CO32- + OH3. a. H2PO4- , HC2O4b. Can act both as an acid and as a base. An AMPHIPROTIC species has an easily removed hydrogen, and a negative charge Names: _______________________________________________________________________ Station 1 1. 2. 3. 4. 5. 6. 7. 8. Station 2 1. a. b. c. 2. KNO2 Parent Acid: Parent Base: NH4Cl Parent Acid: Parent Base: CuC2O4 Parent Acid: Parent Base: Station 3 HF(aq) + CN-(aq) ⇌ HCN(aq) + F-(aq) 1. 2. Conjugate Acid H2C2O4 Conjugate Base SO32- HCO3H2O NO2-(aq) + H2CO3(aq) ⇌ 3. 4. a. HPO42- and SO42- b. HIO3 and C2O42- Station 4 1. 2. 3. a. b.
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