TASMANIAN QUALIFICATIONS AUTHORITY PLACE LABEL HERE Tasmanian Certificate of Education PHYSICAL SCIENCES Senior Secondary 5C Subject Code: PSC5C External Assessment 2006 Part 1 Time: approximately 45 minutes On the basis of your performance in this examination, the examiners will provide a result on the following criteria taken from the syllabus statement: Criterion 6 Demonstrate knowledge and understanding of the impact of science on society and the environment. Criterion 7 Demonstrate knowledge and understanding of the principles of forces and motion. Pages: Questions: © 11 7 Copyright for part(s) of this examination may be held by individuals and/or organisations other than the Tasmanian Qualifications Authority. Physical Sciences – Part 1 CANDIDATE INSTRUCTIONS Candidates MUST ensure that they have addressed ALL of the externally assessed criteria on this examination paper. Answer ALL questions. Answers must be written in the spaces provided on the examination paper. The 2006 Physical Sciences Information Sheet can be used throughout the examination. No other printed material is allowed into the examination. Spend about 45 minutes in total answering the questions in this booklet. No credit can be given for incorrect answers unless they are accompanied by details of the working. Some credit will be given for unsimplified answers. Appropriate units must be included. Each part includes a question that is used in the assessment of Criterion 6. Page 2 Physical Sciences – Part 1 For Marker Use Only Question 1 This question assesses Criterion 7. (a) -1 -1 Convert a speed of 50.0 km h to a speed in m s . (1 mark) ............................................................................................................................................. ............................................................................................................................................. (b) When answering these parts you will need to show your working in order to gain full marks. -1 A car is travelling at a speed of 50.0 km h due north on a straight and level road when the driver brakes to avoid hitting an obstacle. The car takes 5.00 s to come to rest. Calculate: (i) The acceleration of the car when coming to rest. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... (ii) The displacement of the car in the 5.00 s it takes to come to rest. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... Page 3 Physical Sciences – Part 1 Question 2 This question assesses Criterion 7. In the space provided below neatly sketch a velocity-time graph for a ball dropped onto a smooth concrete floor. After bouncing, the ball is caught at about half the height from which it was dropped. On your graph indicate when the ball changes its direction of motion and when it is caught. (4 marks) Page 4 For Marker Use Only Physical Sciences – Part 1 Question 3 This question assesses Criterion 7. When answering this question you will need to show your working, in order to gain full marks. A firecracker of mass 105 g was placed on a near friction-free flat surface. The firecracker exploded into two fragments that travelled apart in opposite directions. A fragment of mass -1 60.0 g travelled to the left with a speed of 20.0 m s . Calculate the velocity of the smaller fragment just after the explosion. (4 marks) ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... Page 5 For Marker Use Only Physical Sciences – Part 1 Question 4 This question assesses Criterion 7. When answering this question you will need to show your working in order to gain full marks. On a calm day a hot air balloon of total mass 350.0 kg rises vertically from rest with an -2 acceleration of 0.500 m s upwards. (a) Calculate the weight of the balloon. (1 mark) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) Calculate the resultant (net) force acting on the balloon as it rises. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (c) Calculate the upwards lift force acting on the balloon. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 6 For Marker Use Only Physical Sciences – Part 1 Question 5 This question assesses Criterion 7. When answering this question you will need to show your working in order to gain full marks. A stone was thrown horizontally from a lookout point overlooking the sea with a velocity of -1 28.0 m s horizontally. When thrown the stone was at a vertical height of 95.0 m above the sea. Ignore air resistance when answering the following questions. (a) Determine the time it took for the stone to reach the sea. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) Calculate the vertical velocity of the stone as it entered the sea. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (c) In the space provided below, draw an appropriate vector diagram and use this to calculate the resultant (net) velocity of the stone as it entered the sea. (4 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 7 For Marker Use Only Physical Sciences – Part 1 For Marker Use Only Question 6 This question assesses Criterion 7. Answer each of the following in the spaces provided. (a) While driving down the road, Anna observes an insect striking the windscreen of her car. Is the force of the insect on the windscreen greater, less than, or the same as the force of the windscreen on the insect? Give the reason for your answer using at least one of Newton’s Laws of Motion. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) A sky diver steps from a hovering helicopter and the vertical forces acting on her after 1.00 s and 20.0 s are shown in the force diagrams below that have been drawn to the same scale. The sky diver is represented by the circle. t = 1.00 s (i) t = 20.0 s Compare the resultant, or net force acting on the sky diver at 1.00 s with that at 20.0 s. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... Question 6 continues opposite. Page 8 Physical Sciences – Part 1 Question 6 (continued) (ii) The sky diver opens her parachute 25.0 s after leaving the helicopter. In the space below, draw another diagram representing the vertical forces acting on the sky diver as her parachute opens. Label the forces and indicate their relative sizes. (2 marks) Page 9 For Marker Use Only Physical Sciences – Part 1 Question 7 This question assesses Criterion 6. The table below shows the overall stopping distances for a car, tested on the same straight road with the same experienced driver. -1 Speed (m s ) 10.0 20.0 30.0 40.0 Reaction time distance (m) 6.00 12.0 18.0 24.0 Braking distance (m) 6.00 24.0 54.0 96.0 Overall stopping distance (m) 12.0 36.0 72.0 120.0 (The ‘reaction time distance’ is the distance travelled during the driver’s reaction time. The reaction time is the time between seeing something ahead and applying the brakes. (a) Determine the driver’s reaction time. You will need to show your working. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) -1 Predict the stopping distance for a speed of 50.0 m s . Using the table, show how you arrive at your answer. (3 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (c) In everyday driving conditions, what factors may affect the overall stopping distance of the car? Give reasons with your answer. (3 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 10 For Marker Use Only Physical Sciences – Part 1 BLANK PAGE Page 11 TASMANIAN QUALIFICATIONS AUTHORITY PLACE LABEL HERE Tasmanian Certificate of Education PHYSICAL SCIENCES Senior Secondary 5C Subject Code: PSC5C External Assessment 2006 Part 2 Time: approximately 45 minutes On the basis of your performance in this examination, the examiners will provide a result on the following criteria taken from the syllabus statement: Criterion 6 Demonstrate knowledge and understanding of the impact of science on society and the environment. Criterion 8 Demonstrate knowledge and understanding of the principles of structures and properties of materials. Pages: Questions: © 15 9 Copyright for part(s) of this examination may be held by individuals and/or organisations other than the Tasmanian Qualifications Authority. Physical Sciences – Part 2 BLANK PAGE Page 2 Physical Sciences – Part 2 CANDIDATE INSTRUCTIONS Candidates MUST ensure that they have addressed ALL of the externally assessed criteria on this examination paper. Answer ALL questions. Answers must be written in the spaces provided on the examination paper. The 2006 Physical Sciences Information Sheet can be used throughout the examination. No other printed material is allowed into the examination. Spend about 45 minutes in total answering the questions in this booklet. No credit can be given for incorrect answers unless they are accompanied by details of the working. Some credit will be given for unsimplified answers. Appropriate units must be included. Each part includes a question that is used in the assessment of Criterion 6. Page 3 Physical Sciences – Part 2 Question 8 This question assesses Criterion 8. Complete the following table in the spaces provided. The first row has been done as an example. (4 marks) Name methane Symbol or Formula Bonding Type CH4 covalent molecular calcium fluoride graphite uranium chlorine gas Page 4 For Marker Use Only Physical Sciences – Part 2 Question 9 This question assesses Criterion 8. Use your knowledge of bonding models to explain the following observations: (a) Crystals of potassium chloride are brittle. When hit with a hammer they shatter into tiny fragments. Explain this property using a diagram, or otherwise. (3 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) Perfumes and aftershave lotions are mixtures of organic compounds which have low boiling points that give rise to distinctive odours. (3 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 5 For Marker Use Only Physical Sciences – Part 2 Question 10 This question assesses Criterion 8. In the spaces provided below, draw an electron dot (‘Lewis’) diagram for each of the following substances. (4 marks) phosphorus trichloride (PCl3 ) propyne (C3 H4 ) Page 6 For Marker Use Only Physical Sciences – Part 2 Question 11 This question assesses Criterion 8. For each general formula listed below, give an example of an ionic compound with that type of formula. (X and Y do not represent the symbols of elements.) (4 marks) General formula Example of an ionic compound with this type of formula. You may give either its correct chemical name or its formula. X2 Y XY2 X2 Y3 XY3 Page 7 For Marker Use Only Physical Sciences – Part 2 For Marker Use Only Question 12 This question assesses Criterion 8. Complete the following table. (4 marks) Chemical name of compound Structural formula of compound H 2-methylbut-1-ene 2-bromo-3-methylbut-2-ene Page 8 F Cl H C C C H H H H H H H C C Br H C C Br H Br Physical Sciences – Part 2 For Marker Use Only Question 13 This question assesses Criterion 8. Under suitable conditions polyvinyl chloride (PVC) is formed when chloroethene shown below reacts with many more molecules of itself. Cl H C C H H Using three units in your answer, show how chloroethene can form the polymer PVC. (2 marks) ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... Page 9 Physical Sciences – Part 2 For Marker Use Only Question 14 This question assesses Criterion 8. Complete the following table: Isotope symbol (3 marks) No. of protons No. of neutrons 6 8 28 3+ Al 13 € 16 2O 8 € Page 10 No. of electrons 6 Physical Sciences – Part 2 Question 15 This question assesses Criterion 8. (a) The electrical conductivity of metals is explained by the theory that metals possess delocalised valence electrons. Explain how the delocalised valence electrons result in the metal being a good electrical conductor. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) Describe a simple laboratory test to show that copper (II) chloride (CuCl2 ) is an example of an ionic solid. Briefly explain how the information gained supports the conclusion that copper (II) chloride is an ionically bonded solid. (3 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 11 For Marker Use Only Physical Sciences – Part 2 For Marker Use Only Question 16 This question assesses Criterion 6. (a) You are a laboratory assistant working for customs. A customs officer has given you a plastic bag containing a powder that was found in the luggage of a visitor. The visitor claims the bag contains powdered common salt (sodium chloride). You subject the white powder to various laboratory tests, the results of which are summarised below: Colour White Odour Odourless Stability Does not decompose or react with the air when kept at 15˚C. Solubility Slightly soluble in water to form a solution which has a pH of 8 Melting point 98˚C Electrical conductivity Very poor in the solid or liquid states, or in aqueous solution. From the above information, could the powder be sodium chloride? Justify your decision giving full reasons. (4 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Question 16 continues opposite. Page 12 Physical Sciences – Part 2 Question 16 (continued) (b) The packaging on the milk carton shown below states that the milk contains calcium and sodium. (i) Does the milk contain calcium and sodium atoms or calcium and sodium ions? Justify your decision giving full reasons. (3 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... (ii) Reference is made on the packaging to saturated fats. Explain in terms of carbon bonding what this term means. (1 mark) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... Page 13 For Marker Use Only Physical Sciences – Part 2 BLANK PAGE Page 14 Physical Sciences – Part 2 BLANK PAGE Page 15 TASMANIAN QUALIFICATIONS AUTHORITY PLACE LABEL HERE Tasmanian Certificate of Education PHYSICAL SCIENCES Senior Secondary 5C Subject Code: PSC5C External Assessment 2006 Part 3 Time: approximately 45 minutes On the basis of your performance in this examination, the examiners will provide a result on the following criteria taken from the syllabus statement: Criterion 6 Demonstrate knowledge and understanding of the impact of science on society and the environment. Criterion 9 Demonstrate knowledge and understanding of the principles of sources and properties of energy. Pages: Questions: © 11 7 Copyright for part(s) of this examination may be held by individuals and/or organisations other than the Tasmanian Qualifications Authority. Physical Sciences – Part 3 BLANK PAGE Page 2 Physical Sciences – Part 3 CANDIDATE INSTRUCTIONS Candidates MUST ensure that they have addressed ALL of the externally assessed criteria on this examination paper. Answer all questions on this paper. Answers must be written in the spaces provided on the examination paper. The 2006 Physical Sciences Information Sheet can be used throughout the examination. No other printed material is allowed into the examination. Spend about 45 minutes in total answering the questions in this booklet. No credit can be given for incorrect answers unless they are accompanied by details of the working. Some credit will be given for unsimplified answers. Appropriate units must be included. Each part includes a question that is used in the assessment of Criterion 6. Page 3 Physical Sciences – Part 3 Question 17 This question assesses Criterion 9. (a) State the Law of Conservation of Energy. (1 mark) ............................................................................................................................................. ............................................................................................................................................. (b) The drawing below shows a proposed device intended to create energy out of nothing. In the drawing, continuously falling water is shown turning a water wheel. However, it is not possible to build such a device. Using the Law of Conservation of Energy explain why this particular device does not work. (3 marks) Water wheel ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 4 For Marker Use Only Physical Sciences – Part 3 For Marker Use Only Question 18 This question assesses Criterion 9 -1 A 55.0 g ball was thrown vertically upwards with a speed of 12.0 m s . When answering this question, you will need to show your working to gain full marks. Assume air resistance is negligible. (a) Calculate the kinetic energy of the ball at the instant it was thrown. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) How much gravitational potential energy is possessed by the ball at its highest point? (1 mark) ............................................................................................................................................. ............................................................................................................................................. (c) -1 Calculate the gravitational potential energy of the ball when its velocity is 4.00 m s downwards. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (d) -1 Calculate the height of the ball when its velocity is 4.00 m s downwards. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 5 Physical Sciences – Part 3 Question 19 This question assesses Criterion 9. Complete the following table in the spaces provided. Species Mass number (4 marks) Electrical charge Penetration in air alpha particle (α) beta particle (β) gamma radiation (γ) neutron (n) very large distances Question 20 This question assesses Criterion 9. (a) Complete the following nuclear equations by identifying the particle shown as X. (1 mark) 14 6C 147 N + X X = _______________________________________ € € (b) Thorium-234 ( 234 90Th) undergoes α-decay. Write down the nuclear equation for this decay. (2 marks) ............................................................................................................................................. € ............................................................................................................................................. Page 6 For Marker Use Only Physical Sciences – Part 3 For Marker Use Only Question 21 This question assesses Criterion 9. Technetium-99 ( 99 43Tc) is commonly used as a tracer in medical diagnosis. Its half life is 6.00 hours and it decays by way of beta (β) particle emission. (a) Write a nuclear equation showing the decay of technetium-99. (2 marks) € ............................................................................................................................................. ............................................................................................................................................. When tested initially with a Geiger counter, a 50 mg sample of technetium-99 gave a radiation count of 300 Bq. (b) Determine the mass of technetium-99 remaining after 36.0 hours. Show your working. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (c) Explain what has happened to the ‘missing’ mass of technetium-99 after 36 hours. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (d) After how many hours will the sample of Tc-99 have a radiation count of approximately 40 Bq? Show your working. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 7 Physical Sciences – Part 3 For Marker Use Only Question 22 This question assesses Criterion 9. When you answer this question, you will need to show your working in order to gain full marks. A current of 56.0 mA passes through a resistor when a potential difference of 9.00 V is applied to it. (a) Calculate the resistance of this resistor. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) Calculate the charge that passes through the resistor in 20.0 minutes. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (c) Calculate the energy the resistor uses in 20.0 minutes of operation. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 8 Physical Sciences – Part 3 For Marker Use Only Question 23 This question assesses Criterion 6. (a) (i) Explain what is likely to happen when an American kitchen appliance, designed to operate using the American domestic 110 V mains supply, is fitted with the correct electrical plug and connected to the Australian 240 V mains supply. Will it function correctly? (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... (ii) As a prize in a recent promotion, the Tasmanian electrical supplier Aurora offered ‘$100 worth of power’ to households. Explain why this advertisement is badly worded from the point of view of a Physical Sciences student and how this should be changed. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... Question 23 continues over the page. Page 9 Physical Sciences – Part 3 Question 23 (continued) (b) The following information was provided with a 240 V electrical extension lead purchased at a local hardware store. ‘This lead must be fully uncoiled before use. The lead must not be used with a load exceeding 3.0 A uncoiled, or 2.0 A coiled.’ (i) Can a 2.5 kW heater be used with this extension lead uncoiled? Show how you arrive at your answer. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... (ii) Suggest a likely reason why the current specified for the coiled extension lead is less than when it is uncoiled. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... Page 10 For Marker Use Only Physical Sciences – Part 3 BLANK PAGE Page 11 TASMANIAN QUALIFICATIONS AUTHORITY PLACE LABEL HERE Tasmanian Certificate of Education PHYSICAL SCIENCES Senior Secondary 5C Subject Code: PSC5C External Assessment 2006 Part 4 Time: approximately 45 minutes On the basis of your performance in this examination, the examiners will provide a result on the following criteria taken from the syllabus statement: Criterion 6 Demonstrate knowledge and understanding of the impact of science on society and the environment. Criterion 10 Demonstrate knowledge and understanding of the principles of chemical reactions and change. Pages: Questions: © 11 7 Copyright for part(s) of this examination may be held by individuals and/or organisations other than the Tasmanian Qualifications Authority. Physical Sciences – Part 4 CANDIDATE INSTRUCTIONS Candidates MUST ensure that they have addressed ALL of the externally assessed criteria on this examination paper. Answer all questions on this paper. Answers must be written in the spaces provided on the examination paper. The 2006 Physical Sciences Information Sheet can be used throughout the examination. No other printed material is allowed into the examination. Spend about 45 minutes in total answering the questions in this booklet. No credit can be given for incorrect answers unless they are accompanied by details of the working. Some credit will be given for unsimplified answers. Appropriate units must be included. Each part includes a question that is used in the assessment of Criterion 6. Page 2 Physical Sciences – Part 4 Question 24 This question assesses Criterion 10. (a) Balance this chemical equation. HNO 3 (aq) + Fe(OH) 3 (aq) (1 mark) → Fe(NO 3 ) 3 (aq) + H 2O(l) ............................................................................................................................................. € (b) Write the balanced chemical equation that corresponds to the following word equation. (2 marks) potassium hydrogen carbonate(s) + sulfuric acid(aq) → potassium sulfate(aq) + carbon dioxide(g) + water(l) ............................................................................................................................................. ............................................................................................................................................. (c) Write an ionic equation to show the reaction between copper (II) ions and hydroxide ions in aqueous solution to form a precipitate of copper (II) hydroxide. (2 marks) ............................................................................................................................................. ............................................................................................................................................. Page 3 For Marker Use Only Physical Sciences – Part 4 Question 25 This question assesses Criterion 10. A compound contains the elements carbon, hydrogen and oxygen. Its composition by mass is carbon 37.5%, hydrogen 12.5%, with the remainder oxygen. When answering the following questions you will need to show your working to gain full marks. (a) Calculate the empirical formula of this compound. (3 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (b) 0.200 mole of the compound has a mass of 12.8 g. Calculate the molar mass of the compound. (1 mark) ............................................................................................................................................. ............................................................................................................................................. (c) Calculate the molecular formula of the compound. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 4 For Marker Use Only Physical Sciences – Part 4 Question 26 This question assesses Criterion 10. When mixed, aqueous solutions of barium chloride and sodium sulfate react to form a precipitate of barium sulfate. BaCl2 (aq) (a) € + Na 2SO 4 (aq) → Write an ionic equation for the above reaction. BaSO 4 (s) + 2NaCl(aq) (2 marks) ............................................................................................................................................. ............................................................................................................................................. (b) Calculate the molar mass of barium sulfate. (1 mark) ............................................................................................................................................. ............................................................................................................................................. You will need to show your working in order to gain full marks when answering this part. (c) Using the reaction above, determine the mass of barium chloride that is required to prepare 11.7 g of barium sulfate. (3 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 5 For Marker Use Only Physical Sciences – Part 4 Question 27 This question assesses Criterion 10. A student is trying to determine the concentration of a hydrochloric acid solution. He finds -1 that 20.1 mL of this acid just neutralizes a 25.0 mL volume of 0.102 mol L sodium hydroxide solution: NaOH(aq) + HCl(aq) → NaCl(aq) + H 2O(l) Determine the concentration of the hydrochloric acid solution. You will need to show your working to gain full marks. (4 marks) € ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... Page 6 For Marker Use Only Physical Sciences – Part 4 For Marker Use Only Question 28 This question assesses Criterion 10. A candy bar contains 36.5 g of glucose (C6 H12O6 ). Glucose reacts with oxygen in the cells of the body as shown in the following equation: C 6H12O 6 (aq) + 6O 2 (aq) → 6CO 2 (aq) + 6H 2O(l) Calculate the mass of oxygen required to fully react with the glucose in this candy bar. You will need to show your working to gain full marks. (4 marks) € ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... ....................................................................................................................................................... Page 7 Physical Sciences – Part 4 Question 29 This question assesses Criterion 10. When answering this question, you will need to show your working in order to gain full marks. (a) Consider 4.50 g of water. (i) Determine the number of molecules of water. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... (ii) Determine the number of hydrogen atoms. (1 mark) .................................................................................................................................... .................................................................................................................................... (b) Calculate the mass of the water molecule. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. (c) -1 15.0 mL of a 0.400 mol L calcium chloride solution is diluted with water to a solution of total volume of 250.0 mL. Calculate the concentration of this diluted solution. (2 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. Page 8 For Marker Use Only Physical Sciences – Part 4 For Marker Use Only Question 30 This question assesses Criterion 6. (a) One major component of petrol is the hydrocarbon, octane, C8 H18. The equation below shows the complete combustion of octane. 2C8H18 (l) + 25O 2 (g) → 16CO 2 (g) + 18H 2O(g) When a car’s engine is warming up, black and sooty exhaust gases may be formed as unwanted by-products of the incomplete combustion of petrol. € (i) Explain this observation. (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... (ii) Write a balanced chemical equation that is consistent with your explanation in (i). (2 marks) .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... .................................................................................................................................... (b) There is strong evidence that acid rain can thin the egg shells laid by birds. This has led to the unfortunate decline of some bird species. Egg shells are mainly calcium carbonate. Assuming acid rain contains dilute nitric acid, give an explanation for the thinning of the egg shells. Include a balanced chemical equation for this reaction. (4 marks) ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. 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