Specimen Label Specialty Herbicide ® Trademark of Dow AgroSciences LLC For control of broadleaf weeds and certain woody plants on rangeland, permanent grass pastures, Conservation Reserve Program (CRP) acres and wildlife management areas in these sites. Hay from grass treated with GrazonNext within the preceding 18-months can only be used on the farm or ranch where the product is applied unless allowed by supplemental labeling IMPORTANT USE PRECAUTIONS AND RESTRICTIONS TO PREVENT INJURY TO DESIRABLE PLANTS •Carefullyreadthesection“Restrictions in Hay or Manure Use .” •Itismandatorytofollowthe“Use Precautions and Restrictions” section ofthislabel. •Manureandurinefromanimals consuminggrassorhaytreatedwith thisproductmaycontainenough aminopyralidtocauseinjurytosensitive broadleafplants. •Haycanonlybeusedonthefarmor ranchwhereproductisappliedunless allowedbysupplementallabeling. •ConsultwithaDowAgroSciences representativeifyoudonotunderstand the“UsePrecautionsandRestrictions”. Call [1-(800) 263-1196] Customer Information Group. Copyright2011DowAgroSciencesLLC © Not For Sale, Distribution, or Use in New York State. Group 4 HERBICIDE ActiveIngredient: Triisopropanolammoniumsaltof2-pyridine carboxylicacid,4-amino-3,6-dichloro-....................................... 6.58% Triisopropanolammoniumsaltof (2,4-dichlorophenoxy)aceticacid............................................. 51.06% OtherIngredients............................................................................. 42.36% Total................................................................................................ 100.00% AcidEquivalents: aminopyralid(2-pyridinecarboxylicacid,4-amino-3,6-dichloro-)– 3.4%-0.33lb/gal(40g/L) 2,4-D[(2,4-dichlorophenoxy)aceticacid]–27.2%-2.67lb/gal(320g/L) Precautionary Statements Hazard to Humans and Domestic Animals EPAReg.No.62719-587 DANGER Corrosive • Causes Irreversible Eye Damage • Harmful if Swallowed Do not get in eyes or on clothing. Personal Protective Equipment (PPE) Somematerialsthatarechemical-resistanttothisproductarelisted below.Ifyouwantmoreoptions,followtheinstructionsforcategoryAon anEPAchemicalresistancecategoryselectionschart. All mixers, loaders, applicators, flaggers, and other handlers must wear: •Long-sleevedshirtandlongpants •Shoesplussocks •Protectiveeyewear •Chemical-resistantgloves,whenapplyingwithanyhandheldnozzle orequipment,mixingorloading,cleaningupspillsorequipment,or otherwiseexposedtotheconcentrate. •Chemicalresistantapronwhenmixingorloading,cleaningupspillsor equipment,orotherwiseexposedtotheconcentrate Seeengineeringcontrolsforadditionalrequirements Discardclothingandotherabsorbentmaterialsthathavebeendrenched orheavilycontaminatedwiththisproduct'sconcentrate.Donotreuse them.Followmanufacturer'sinstructionsforcleaning/maintainingPPE. Ifnosuchinstructionsforwashables,usedetergentandhotwater.Keep andwashPPEseparatelyfromotherlaundry. Engineering Controls Statements Whenhandlersuseclosedsystemsorenclosedcabsinamannerthat meetstherequirementslistedintheWorkerProtectionsStandard(WPS) foragriculturalpesticides[40CFR170.240(d)(4-6)],thehandlerPPE requirementsmaybereducedormodifiedasspecifiedintheWPS. Pilotsmustuseanenclosedcockpitthatmeetstherequirementslistedin theWorkerProtectionsStandard(WPS)foragriculturalpesticides[40CFR 170.240(d)(4-6)]. User Safety Recommendations Usersshould: •Washhandsbeforeeating,drinking,chewinggum,usingtobacco,or usingthetoilet. •Removeclothing/PPEimmediatelyifpesticidegetsinside.Thenwash thoroughlyandputoncleanclothing. •RemovePPEimmediatelyafterhandlingthisproduct.Washthe outsideofglovesbeforeremoving.Assoonaspossible,wash thoroughlyandchangeintocleanclothing. First Aid If in eyes:Holdeyeopenandrinseslowlyandgentlywithwaterfor1520minutes.Removecontactlenses,ifpresent,afterthefirst5minutes, thencontinuerinsing.Callapoisoncontrolcenterordoctorfor treatmentadvice. If swallowed:Callapoisoncontrolcenterordoctorimmediatelyfor treatmentadvice.Havepersonsipaglassofwaterifabletoswallow. Donotinducevomitingunlesstoldtodosobyapoisoncontrolcenter ordoctor.Donotgiveanythingbymouthtoanunconsciousperson. Havetheproductcontainerorlabelwithyouwhencallingapoison controlcenterordoctororgoingfortreatment.Youmayalsocontact 1-800-992-5994foremergencymedicaltreatmentinformation. Environmental Hazards Thisproductistoxictoaquaticinvertebratesandmaybetoxictofish. Driftorrunoffmayadverselyaffectaquaticinvertebratesandnontarget plants.Donotapplydirectlytowater,toareaswheresurfacewateris presentortointertidalareasbelowthemeanhighwatermarkexceptas permittedonthislabel.Driftandrunoffmaybehazardoustoaquatic organismsinwateradjacenttotreatedareas.Donotcontaminatewater whendisposingofequipmentwashwaterorrinsate. Thischemicalhaspropertiesandcharacteristicsassociatedwith chemicalsdetectedingroundwater.Theuseofthischemicalinareas wheresoilsarepermeable,particularlywherethewatertableisshallow, mayresultingroundwatercontamination.Applicationaroundacisternor wellmayresultincontaminationofdrinkingwaterorgroundwater. Directions for Use ItisaviolationofFederallawtousethisproductinamannerinconsistent withitslabeling. ReadallDirectionsforUsecarefullybeforeapplying. Donotapplythisproductinawaythatwillcontactworkersorother persons,eitherdirectlyorthroughdrift.Onlyprotectedhandlersmaybe intheareaduringapplication.ForanyrequirementsspecifictoyourState orTribe,consulttheagencyresponsibleforpesticideregulation. Not For Sale, Distribution, or Use in New York State. Agricultural Use Requirements Usethisproductonlyinaccordancewithitslabelingandwiththe WorkerProtectionStandard,40CFRpart170.ThisStandardcontains requirementsfortheprotectionofagriculturalworkersonfarms,forests, nurseries,andgreenhouses,andhandlersofagriculturalpesticides.It containsrequirementsfortraining,decontamination,notification, Agricultural Use Requirements (Cont.) andemergencyassistance.Italsocontainsspecificinstructionsand exceptionspertainingtothestatementsonthislabelaboutPersonal ProtectiveEquipment(PPE)andrestricted-entryinterval.The requirementsinthisboxonlyapplytousesofthisproductthatare coveredbytheWorkerProtectionStandard. Donotenterorallowworkerentryintotreatedareasduringthe restrictedentryinterval(REI)of48hours. PPErequiredforearlyentrytotreatedareasthatispermittedunderthe WorkerProtectionStandardandthatinvolvescontactwithanythingthat hasbeentreated,suchasplants,soil,orwater,is: •Coveralls •Chemical-resistantglovesmadeofanywaterproofmaterialsuchas naturalrubber. •Protectiveeyewear •Shoesplussocks Non-Agricultural Use Requirements TherequirementsinthisboxapplytousesofthisproductthatareNOT withinthescopeoftheWorkerProtectionStandardforAgricultural Pesticides(40CFRPart170).TheWPSapplieswhenthisproduct isusedtoproduceagriculturalplantsonfarms,forests,nurseries,or greenhouses. Entry Restrictions for Non-WPS Uses:Forapplicationsonrangeland andpermanentgrasspastures,donotenterorallowworkerentryinto treatedareasuntilsprayshavedried. Storage and Disposal Donotcontaminatewater,food,feedorfertilizerbystorageordisposal. Pesticide Storage: Ifthisproductisexposedtosubfreezingtemperatures, theactiveingredientmaycrystallizeandsettleoutofsolution.Under theseconditionstheproductshouldbewarmedtoatleast40°Fand agitatedwelltodissolveanycrystallizedmaterialpriortouse. Pesticide Disposal: Wastesresultingfromtheuseofthisproductmay bedisposedofonsiteoratanapprovedwastedisposalfacility. Nonrefillable containers 5 gallons or less: Container Handling:Nonrefillablecontainer.Donotreuseorrefillthis container.Offerforrecyclingifavailable,orpunctureanddisposeofin asanitarylandfill,orbyincineration,orbyotherproceduresallowedby stateandlocalauthorities. Triplerinseorpressurerinsecontainer(orequivalent)promptlyafter emptying.Triple rinseasfollows:Emptytheremainingcontents intoapplicationequipmentoramixtankanddrainfor10seconds aftertheflowbeginstodrip.Fillthecontainer1/4fullwithwaterand recap.Shakefor10seconds.Pourrinsateintoapplicationequipment oramixtankorstorerinsateforlateruseordisposal.Drainfor 10 secondsaftertheflowbeginstodrip.Repeatthisproceduretwo moretimes.Pressure rinseasfollows:Emptytheremainingcontents intoapplicationequipmentoramixtankandcontinuetodrainfor 10 secondsaftertheflowbeginstodrip.Holdcontainerupsidedown overapplicationequipmentormixtankandcontinuetodrainfor 10 secondsaftertheflowbeginstodrip.Holdcontainerupsidedown overapplicationequipmentormixtankorcollectrinsateforlateruseor disposal.Insertpressurerinsingnozzleinthesideofthecontainer,and rinseatabout40psiforatleast30seconds.Drainfor10secondsafter theflowbeginstodrip. Refillable containers larger than 5 gallons: Container Handling:Refillablecontainer.Refillthiscontainerwith pesticideonly.Donotreusethiscontainerforanyotherpurpose. Cleaningthecontainerbeforefinaldisposalistheresponsibilityof thepersondisposingofthecontainer.Cleaningbeforerefillingisthe responsibilityoftherefiller.Tocleanthecontainerbeforefinaldisposal, emptytheremainingcontentsfromthiscontainerintoapplication equipmentoramixtank.Fillthecontainerabout10%fullwithwater. Agitatevigorouslyorrecirculatewaterwiththepumpfortwominutes. Pourorpumprinsateintoapplicationequipmentorrinsatecollection system.Repeatthisrinsingproceduretwomoretimes. Nonrefillable containers larger than 5 gallons: Container Handling:Nonrefillablecontainer.Donotreuseorrefillthis container.Offerforrecyclingifavailable,orpunctureanddisposeofin asanitarylandfill,orbyincineration,orbyotherproceduresallowedby stateandlocalauthorities. Triplerinseorpressurerinsecontainer(orequivalent)promptlyafter emptying.Triple rinseasfollows:Emptytheremainingcontentsinto applicationequipmentoramixtank.Fillthecontainer1/4fullwith water.Replaceandtightenclosures.Tipcontaineronitssideand rollitbackandforth,ensuringatleastonecompleterevolution,for 30 seconds.Standthecontaineronitsendandtipitbackandforth 2 SpecimenLabelRevised02-01-12 Storage and Disposal (Cont.) severaltimes.Turnthecontaineroverontoitsotherendandtipitback andforthseveraltimes.Emptytherinsateintoapplicationequipment oramixtankorstorerinsateforlateruseordisposal.Repeatthis proceduretwomoretimes.Pressure rinseasfollows:Emptythe remainingcontentsintoapplicationequipmentoramixtankand continuetodrainfor10secondsaftertheflowbeginstodrip.Hold containerupsidedownoverapplicationequipmentormixtankorcollect rinsateforlateruseordisposal.Insertpressurerinsingnozzleinthe sideofthecontainer,andrinseatabout40psiforatleast30seconds. Drainfor10secondsaftertheflowbeginstodrip. Product Information GrazonNext®specialtyherbicidecontrolsbroadleafweedsandcertain woodyplants onrangeland,permanentgrasspastures,Conservation ReserveProgram(CRP)acresandwildlifemanagementareasinthesesites. Hay from grass treated with GrazonNext within the preceding 18-months can only be used on the farm or ranch where the product is applied unless allowed by supplemental labeling Itispermissibletotreatnon-irrigationditchbanks,seasonallydry wetlands(suchasfloodplains,deltas,marshes,swamps,orbogs)and transitionalareasbetweenuplandandlowlandsites.GrazonNextcan beusedtothewatersedge.Donotapplydirectlytowaterandtake precautionstominimizespraydriftontowater. Resistance Management Guidelines •Developmentofplantpopulationsresistanttothisherbicidemode ofactionisusuallynotaproblemonrangeland,permanentgrass pastures,orCRP,sincethesesitesreceiveinfrequentpesticide applications. •Similarlookingbiotypesofagivenweedspeciesoccurringinatreated areamayvaryintheirsusceptibilitytoaherbicide.Applicationofa herbicidebelowitsrecommendedratemayallowmoretolerantweeds tosurviveandashifttomoretolerantbiotypeswithinthetreatedarea. •Whereidentified,spreadingofresistantweedstootherfieldsmaybe preventedbycleaningharvestingandtillageequipmentbeforemoving tootherareasandbyplantingweed-freeseed. •Contactyourextensionspecialist,certifiedcropconsultant,orDow AgroSciencesrepresentativeforthelatestresistancemanagement information. Use Precautions and Restrictions Consult with a Dow AgroSciences representative if you do not understand the “Use Precautions and Restrictions.” Call (1-800-263-1196) for more information. •Do not use grasses treated with GrazonNext in the preceding 18-months for hay intended for export outside the United States. •Hay from areas treated with GrazonNext in the preceding 18-months CANNOT be distributed or made available for sale off the farm or ranch where harvested unless allowed by supplemental labeling. •Hay from areas treated with GrazonNext in the preceding 18-months CANNOT be used for silage, haylage baylage and green chop unless allowed by supplemental labeling. •Do not move hay made from grass treated with GrazonNext within the preceding 18-months off farm unless allowed by supplemental labeling. •Do not use hay or straw from areas treated with GrazonNext within the preceding 18-months or manure from animals feeding on hay treated with GrazonNext in compost. •Do not use grasses treated with GrazonNext in the preceding 18-months for seed production. •This product is not intended for reformulation or repackaging into other end-use products. •Maximum Application Rate: Donotbroadcastapplymorethan 42 floz(2.6pints)peracreofGrazonNextperyear.Thetotalamount ofGrazonNextappliedbroadcast,asare-treatment,and/orspot treatmentperyearmustnotexceed42floz(2.6pints)peracre.Spot treatmentsmaybeappliedatanequivalentbroadcastrateofupto 84 fl ozofGrazonNextperacreperannualgrowingseason;however, notmorethan50%ofanacremaybetreatedatthatrate. •Avoiding Injury to Non-Target Plants:Donotaeriallyapply GrazonNextwithin50feetofaborderdownwind(inthedirectionof windmovement),orallowspraydrifttocomeincontactwith,any broadleafcroporotherdesirablebroadleafplants,including,butnot limitedto,alfalfa,cotton,drybeans,flowers,grapes,lettuce,potatoes, radishes,soybeans,sugarbeets,sunflowers,tobacco,tomatoesor otherbroadleaforvegetablecrop,fruittrees,ornamentalplants,orsoil wheresensitivecropsaregrowingorwillbeplanted.Avoidapplication underconditionsthatmayallowspraydriftsinceverysmallquantities ofspraymayseriouslyinjurecrops.ReadandconsiderthePrecautions forAvoidingSprayDriftandSprayDriftAdvisoryattheendofthislabel tohelpminimizethepotentialforspraydrift. •GrazonNext is highly active against many broadleaf plant species. Donotusethisproductonareaswherelossofdesirablebroadleaf forageplants,includinglegumes,cannotbetolerated. •Chemigation: Donotapplythisproductthroughanytypeofirrigation system. •Do not contaminate water intended for irrigation or domestic purposes.Donottreatinsidebanksorbottomsofirrigationditches, eitherdryorcontainingwater,orotherchannelsthatcarrywaterthat maybeusedforirrigationordomesticpurposes. •Donotapplythisproducttolawns,turf,ornamentalplantings,urban walkways,driveways,tenniscourts,golfcourses,athleticfields, commercialsodoperations,orotherhigh-maintenance,fineturfgrass areas,orsimilarareas. •Applicationsmadeduringperiodsofintenserainfall,tosoilssaturated withwater,surfacespavedwithmaterialssuchasasphaltorconcrete, orsoilsthroughwhichrainfallwillnotreadilypenetratemayresult inrunoffandmovementofthisproduct.Injurytocropsmayresultif treatedsoiland/orrunoffwatercontainingthisproductiswashed, ormovedontolandusedtoproducecrops.Exposuretothisproduct mayinjureorkillsusceptiblecropsandotherplants,suchasgrapes, soybeans,tobacco,sensitiveornamentals.Donottreatfrozensoil whererunoffcoulddamagesensitiveplants. •Treesadjacenttoorinatreatedareacanoccasionallybeaffectedby rootuptakeofGrazonNextthroughmovementintothesoil.Donot applyGrazonNextwithintherootzoneofdesirabletreesunlesssuch injurycanbetolerated.Usespecialcautionnearroses,andleguminous treessuchaslocusts,redbud,mimosa,andcaragana. •Crop Rotation: Donotrotatetocroplandforoneyearfollowingan applicationofGrazonNext.Cerealsandcorncanbeplantedoneyear aftertreatment.Mostbroadleafcropsaremoresensitiveandcan requireat least2yearsdependingonthecropandenvironmental conditions.Donotplantabroadleafcropuntilanadequatelysensitive fieldbioassayshowsthatthelevelofaminopyralidpresentinthesoil willnotadverselyaffectthatbroadleafcrop. •Seeding grasses: - Preemergence:Grassesmaybereseededinthefallfollowingan applicationofGrazonNextappliedinthespringorearlysummer. - Postemergence:Duringtheseasonofestablishment,GrazonNext shouldbeappliedonlyafterperennialgrassesarewellestablished (havedevelopedagoodsecondaryrootsystemandshowgood vigor).MostperennialgrassesaretoleranttoGrazonNextat thisstageofdevelopment.GrazonNextmaysuppresscertain establishedgrasses,suchassmoothbromegrass(Bromus inermis), especiallywhenplantsarestressedbyadverseenvironmental conditions.Plantsshouldrecoverfromthistransientsuppression withtheonsetofenvironmentalconditionsfavorabletograssgrowth anduponreleasefromweedcompetition. •Seeding Legumes: Donotplantforagelegumesuntilasoilbioassay hasbeenconductedtodetermineifaminopyralidresiduesremainingin thesoilwilladverselyaffectthelegumeestablishment. •Grazing and Haying Restrictions: Therearenorestrictionson grazingfollowingapplicationofGrazonNextatlabeledrates.Do notharvestforageforhaywithin7daysofGrazonNextapplication. Cuttinghaytoosoonaftersprayingweedscancompromisetheweed control.Wait14dayspriortocuttinggrasshaytoallowformaximum herbicideactivity.Donottransfergrazinganimalsfromareastreated withGrazonNexttoareaswheresensitivebroadleafcropoccurwithout firstallowing3daysofgrazingonanuntreatedpasture.Otherwise, urineandmanuremaycontainenoughaminopyralidtocauseinjuryto sensitivebroadleafplants. •Grazing Poisonous Plants: Herbicideapplicationmayincrease palatabilityofcertainpoisonousplants.Donotgrazetreatedareasuntil poisonousplantsaredryandnolongerpalatabletolivestock. •Restrictions in Hay or Manure Use: - Donotusetreatedplantresidues,includinghayorstrawfromareas treatedwithinthepreceeding18-months,incompost,mulchor mushroomspawn. 3 SpecimenLabelRevised02-01-12 - Donotusemanurefromanimalsthathavegrazedforageoreaten hayharvestedfromtreatedareaswithintheprevious3days,in compost,mulchormushroomspawn. - Donotspreadmanurefromanimalsthathavegrazedorconsumed forageorhayfromtreatedareaswithintheprevious3daysonland usedforgrowingbroadleafcrops. - Manurefromanimalsthathavegrazedforageoreatenhayharvested fromaminopyralid-treatedareaswithintheprevious3daysmayonlybe usedonpasturegrasses,grassgrownforseed,andwheatandcorn. - Donotplantabroadleafcrop(includingsoybeans,sunflower, tobacco,vegetables,fieldbeans,peanuts,andpotatoes)infields treatedwithmanurefromanimalsthathavegrazedforageoreaten hayharvestedfromaminopyralid-treatedareasuntilanadequately sensitivefieldbioassayisconductedtodeterminethatthe aminopyralidresiduesinthesoilisatlevelthatisnotinjurioustothe croptobeplanted. - Donotplantabroadleafcropinfieldstreatedinthepreviousyear withmanurefromanimalsthathavegrazedforageoreatenhay harvestedfromaminopyralid-treatedareasuntilanadequately sensitivefieldbioassayisconductedtodeterminethatthe aminopyralidconcentrationinthesoilisatlevelthatisnotinjurious tothecroptobeplanted. - Topromoteherbicidedecomposition,plantresiduesshouldbeevenly incorporatedinthesurfacesoilorburned.Breakdownofaminopyralid inplantresiduesormanureismorerapidunderwarm,moistsoil conditionsandmaybeacceleratedbysupplementalirrigation. •Field Bioassay Instructions: Infieldspreviouslytreatedwiththis product,plantshorttestrowsoftheintendedrotationalcropacross theoriginaldirectionofapplicationinamannertosamplevariabilityin fieldconditionssuchassoiltexture,soilorganicmatter,soilpH,rainfall patternordrainage.Thefieldbioassaycanbeinitiatedatanytime betweenharvestofthetreatedcropandtheplantingoftheintended rotationalcrop.Observethetestcropforsymptomsofherbicidal activity,suchaspoorstand(effectonseedgermination),chlorosis (yellowing),andnecrosis(deadleavesorshoots),orstunting(reduced growth).Ifherbicidalsymptomsdonotoccur,thetestcropcanbe grown.Ifthereisapparentherbicidalactivity,donotplantthefieldto theintendedrotationalcrop;plantonlytowheat,foragegrasses,native grassesorgrassesgrownforhay. Sprayer Clean-Out Instructions It is recommended that separate spray equipment be used on highly sensitive crops such as tobacco, soybeans, peanuts, and tomatoes. DonotusesprayequipmentusedtoapplyGrazonNextforother applicationstolandplantedto,ortobeplantedto,cropsordesirable sensitiveplants,unlessithasbeendeterminedthatallresiduesofthis herbicidehasbeenremovedbythoroughcleaningofequipment. EquipmentusedtoapplyGrazonNextshouldbethoroughlycleaned beforereusingtoapplyanyotherchemicalsasfollows. 1.Rinseandflushapplicationequipmentthoroughlyafteruse.Dispose ofrinsewaterawayfromwatersupplies. 2.Rinseasecondtime,adding1quartofhouseholdammoniaortank cleaningagentforevery25gallonsofwater.Circulatethesolution throughtheentiresystemsothatallinternalsurfacesarecontacted (15to20minutes).Letthesolutionstandforseveralhours,preferably overnight. 3.Flushthesolutionoutofthespraytankthroughtheboom. 4.Rinsethesystemtwicewithcleanwater,recirculatinganddraining eachtime. 5.Spraynozzlesandscreensshouldberemovedandcleanedseparately. Spot Application: Spottreatmentsmaybeappliedatratesequivalentto broadcast-appliedrateofuptoamaximumof84floz(5.2pints)on50% ofthetreatedfield.Sprayvolumeshouldbesufficienttothoroughlyand uniformlywetweedfoliage.Repeattreatmentsmaybemade,butthe totalamountofGrazonNextappliedmustnotexceed42floz(2.6pints) peracreperyear(seecommentsintheUsePrecautionsandRestrictions sectionaboveonMaximumApplicationRate). Table1:AmountofGrazonNextherbicide(in fi oz)tomixin3 gallon of water GrazonNext Amount (In fi oz) To Mix In 3 Gal Of Water With Various Application Rates GPA 24 fi oz/A 32 fi oz/A 42 fi oz/A 20 3.6 4.8 6.3 30 2.4 3.2 4.2 40 1.8 2.4 3.2 50 1.4 1.9 2.5 60 1.2 1.6 2.1 70 1.0 1.4 1.8 80 0.9 1.2 1.6 90 0.8 1.1 1.4 100 0.7 1.0 1.3 Table 2: Applicationratesinthetablebelowarebasedontreatinganarea of1000sqft.Anareaof1000sqftisabout10.5by10.5yardsinsize. MixtheamountofGrazonNext(flozormilliliters)correspondingtothe desiredbroadcastratein0.5to2.5gallonsofwater,dependinguponthe sprayvolumerequiredtotreat1000sqft.Adeliveryvolumeof0.5 gallons per1000sqftisequivalentto22gallonsperacreand2.5 gallonsper 1000sqftisequivalentto109gallonsperacre. Amount of GrazonNext per 1000 sq ft to Equal Broadcast Rate Broadcast Rate Amount of GrazonNext per 1000 sq ft (fi oz/acre) (pt/acre) (fi oz) (mL) 24 1.5 0.55 16.3 32 2 0.74 21.7 42 2.6 0.96 28.5 Note:1mL=1ccand1fluidounce(floz)=29.6milliliters(mL)= 2 tablespoons=6teaspoons To calculate the amount of GrazonNext for areas larger than 1000 sq ft:Multiplythetablevalue(flozormilliliters)bytheareatobe treatedin"thousands"ofsquarefeet.Forexample,iftheareatobe treatedis3500 sqft,multiplythetablevalueby3.5(3500sqftdividedby 1000sqft=3.5). Mixing Instructions Mixing with Water Topreparethespray,addabouthalftherequiredamountofwaterin thespraytank.Then,withagitation,addtherecommendedamount ofGrazonNextandotherregisteredtankmixherbicides.Finally,with continuedagitation,addtherestofthewaterandadditivessuchas surfactantsordriftcontrolanddepositionaids. Application Methods Addition of Surfactants or Adjuvants on All Labled Use Sites:The additionofahighqualitynon-ionicsurfactant(ofatleast80%active ApplytherecommendedrateofGrazonNextasacoarselow-pressure ingredient)at0.25to0.5%volumepervolume(1to2quartsper spray.Do not apply this product with mist blower systems that 100 gallonsofspray)isrecommendedtoenhanceherbicideactivityunder deliver very flne spray droplets. Use of mist blower equipment can adverseenvironmentalconditions(suchas,hightemperature,lowrelative reduce weed control and increase spray drift potential. humidity,droughtconditions,dustyplantsurfaces)orwhenweedsare Sprayvolumeshouldbesufficienttouniformlycoverfoliage.Increase heavilypubescentormoremature. sprayvolumetoensurethoroughanduniformcoveragewhentarget vegetationistalland/ordense.Toenhancefoliagewettingandcoverage, Tank Mixing with Other Herbicides anapprovednon-ionicagriculturalsurfactantmaybeaddedtothespray GrazonNextatratesofupto42floz(2.6pints)peracremaybemixed mixtureasrecommendedbythesurfactantlabel. withlabeledratesofotherlabeledherbicidestobroadenthespectrumof weedscontrolledortoimprovecontrolofcertainweeds.GrazonNextmay Ground Broadcast Application: Highersprayvolumes(greaterthan 10 gallonsperacre)generallyprovidesbettercoverageandbettercontrol, beappliedintankmixcombinationwithlabeledratesofotherherbicides provided:(1)thetankmixproductislabeledforthetimingandmethodof particularlyindenseand/ortallfoliage. applicationfortheusesitetobetreatedand(2)mixingisnotprohibitedby Aerial Broadcast Application: Donotapplylessthan2gallonsperacre thelabeloftheregisteredtankmixedproducts,and(3)thatthetankmix totalsprayvolume.Fivegallonsperacreorgreaterwillgenerallyprovide combinationisphysicallycompatible(seetankmixcompatibilitytesting bettercoverageandbettercontrol,particularlyindenseand/ortallfoliage. below).Whentankmixing,useonlyinaccordancewiththerestrictions, precautionsandlimitationsontherespectiveproductlabels High-Volume Foliar Application: Highvolumefoliartreatmentsmaybe •Readcarefullyandfollowallapplicableusedirections,precautions,and appliedatratesequivalenttoamaximumof42floz(2.6pints)peracre limitationsontherespectiveproductlabels. perannualgrowingseason.Usesufficientsprayvolumetothoroughly anduniformlywetfoliageandstems. 4 SpecimenLabelRevised02-01-12 •Donotexceedrecommendedapplicationrates.Ifproductscontaining thesameactiveingredientaremixed,donotexceedthemaximum allowableactiveingredientuserates. •Fordirectinjectionorothersprayequipmentwheretheproduct formulationswillbemixedinundilutedform,specialcareshouldbe takentoensuretankmixcompatibility. •Alwaysperformajartesttoensurethecompatibilityofproductstobe usedintankmixture. Tank Mixing Precautions: •Forproductspackagedinwatersolublepackaging,donottankmix withproductscontainingboronormixinequipmentpreviouslyused toapplyaproductmixturecontainingboronunlessthetankandspray equipmenthasbeenadequatelycleaned.(SeeSprayerClean-Out instructions.) •Alwaysperforma(jar)testtoensurethecompatibilityofproductstobe usedintankmixture. Tank Mix Compatibility Testing:Performajartestpriortomixingina spraytanktoensurecompatibilityofGrazonNextandotherpesticides orcarriers.Useaclearglassjarwithlidandmixingredientsinthesame orderandproportionsaswillbeusedinthespraytank.Themixtureis compatibleifthematerialsmixreadilywhenthejarisinvertedseveral times.Themixtureshouldremainstableafterstandingfor1/2houror,if separationoccurs,shouldreadilymixifagitated.Anincompatiblemixture isindicatedbyseparationintodistinctlayersthatdonotreadilyremix whenagitatedand/orthepresenceofflakes,precipitates,gels,orheavy oilyfilminthejar.Useofanappropriatecompatibilityagentmayresolve mixincompatibility. Mixing with Sprayable Liquid Fertilizer Solutions GrazonNextisusuallycompatiblewithliquidfertilizersolutions.Itis anticipatedthatGrazonNextwillnotrequireacompatibilityagentfor mixingwithfertilizers;however,acompatibilitytest(jartest)shouldbe madepriortomixing.Jartestsareparticularlyimportantwhenanew batchoffertilizerorpesticideisused,whenwatersourceschange, orwhentankmixtureingredientsorconcentrationsarechanged. Compatibilitymaybedeterminedbymixingthespraycomponentsinthe desiredorderandproportionsinaclearglassjarbeforelargescalemixing ofspraycomponentsinthespraytank.Useofacompatibilityagent isrecommendedtohelpobtainandmaintainauniformspraysolution duringmixingandapplication.Note:Thelowerthetemperatureofthe liquidfertilizer,thegreaterthelikelihoodofmixingproblems.Mixing GrazonNext in N-P or N-P-K liquid fertilizer solutions is more difflcult than mixing with straight nitrogen fertilizer and should not be attempted without flrst conducting a successful compatibility jar test.Agitation inthespraytankmustbevigoroustobecomparablewithjartestagitation. Applythespraymixturethesamedayitispreparedwhilemaintaining continuousagitation.Rinsethespraytankthoroughlyafteruse. Note: Foliar-appliedliquidfertilizersthemselvescancauseyellowingof thefoliageofforagegrassesandothervegetation. Use Rates and Timing Do not use GrazonNext if loss of legumes species or other broadleaf species cannot be tolerated. GrazonNextmaybeappliedpostemergenceasabroadcastsprayoras aspotapplicationtocontrolweedslistedonthislabel;weedsotherthan thoselistedmayalsobecontrolledbythisherbicide.Whenaraterange isgiven,useahigherrateintherangetocontrolweedsatadvanced growthstagesorunderless-than-favorablegrowingconditions(e.g., droughtstress)orforlongerresidualcontrol.Bestweedcontrolresults areobtainedwhensprayvolumeissufficienttoprovideuniformcoverage oftreatedplants.Foroptimumuptakeandtranslocationoftheherbicide, avoidmowing,haying,shredding,burningorsoildisturbanceintreated areasforatleast7daysfollowingapplication. GrazonNextalsoprovidespreemergencecontrolofgerminatingseeds oremergingseedlingsofsusceptibleweedsandre-growthofcertain perennialweedsfollowingapplication.Weedestablishmentfollowing GrazonNextapplicationwilldependuponapplicationrate,seasonof application,andgrowingcondition. GrazonNextcanprovidelong-termcontrolofweeds.Thelengthof controlisdependentupontheapplicationrate,conditionandgrowth stageoftargetweeds,environmentalconditionsatandfollowing application,andthedensityandvigorofcompetingdesirablevegetation. Long-termbroadleafweedcontrolismosteffectivewhereforagegrasses areallowedtorecoverfromovergrazing,drought,etc.,andcompetewith weeds. GrazonNextcanbeanimportantcomponentofintegratedvegetation managementprogramsdesignedtorenovateorrestoredesiredplant communities.Tomaximizeandextendthebenefitsofweedcontrol providedbyGrazonNext,itisimportantthatvegetationmanagement practices,includinggrazingmanagement,biologicalcontrolagents, replanting,fertilization,prescribedfire,reseedingwithdesirableplants, etc.,beusedtoincreasethecompetitivenessofdesiredforages.Usedas partofanintegratedmanagementprogram,GrazonNextcanserveas a catalystforrapidimprovementofrangeland,permanentgrasspasture, andCRP,byalleviatingtheadversecompetitiveeffectofweedsontheyield andqualityofforagesandotherdesirableplantspecies.Agriculturaland naturalresourcesspecialistswithfederalandstategovernmentagencies canprovideguidanceonbestmanagementpracticesanddevelopmentof integratedvegetationmanagementsystems. Broadleaf Weeds Controlled The following weeds will be controlled at 1.5 to 2.6 pint/acre.For bestresults,applywhenweedsareactivelygrowingandconditionsare favorableforplantgrowth.Useahigherrateintheraterangewhen growingconditionsarelessthanfavorable,whenweedsaremature, whenweedfoliageistallanddenseorwhenresidualcontrolisimportant. GrazonNextalsoprovidespreemergencecontrolofgerminatingseeds orseedlingsofsusceptibleweedsthatemergefollowingapplication. Increasingapplicationratetothehighendoftheraterangespecifiedwill extendperiodofresidualcontrol. Table3:BroadleafWeedsControlled Weed Species Common Name broomweed,annual* carrot,wild* clover,sweet clover,white cocklebur* croton,woolly*,** crownvetch* falsedandelion,Carolina* fleabane,annual* gumweed,curlycup horsenettle,Carolina*,** lettuce,prickly* pokeweed,common ragweed,common*,** ragweed,western sneezeweed,bitter* thistle,bull*,** thistle,musk*,** Scientiflc Name Rate Range: 1.5 to 2 pints/acre Amphiachyris dracunculoides Daucus carota Melilotus officinalis Trifolium repens Xanthium strumarium Croton capitatus Securigera varia Pyrrhopappus carolinianus Erigeron annus Grindelia squarrosa Solanum carolinense Lactuca serriola Phytolacca americana Ambrosia artemisiifolia Ambrosia psilostachya Helenium amarum Cirsium vulgare Carduus nutans 5 Life Cycle*** Plant Family annual biennial biennial perennial annual annual perennial annual/biennial annual biennial perennial annual perennial annual perennial annual biennial biennial Asteraceae Apiaceae Fabaceae Fabaceae Asteraceae Euphorbiaceae Fabaceae Asteraceae Asteraceae Asteraceae Solanaceae Asteraceae Phytolaccaceae Asteraceae Asteraceae Asteraceae Asteraceae Asteraceae SpecimenLabelRevised02-01-12 Table3:BroadleafWeedsControlled(Cont.) Weed Species Common Name Scientiflc Name Life Cycle*** Plant Family Rate Range: 1.5 to 2 pints/acre thistle,plumeless*,** Carduus acanthoides biennial Asteraceae Verbena hastata perennial Asteraceae vervain,blue* vervain,hoary* Verbena stricta perennial Asteraceae vetch,common* Vicia sativa annual Fabaceae Rate Range: 2 to 2.6 pints/acre amaranth,spiny* Amaranthus spinosus annual Amaranthaceae Arctium minus biennial Asteraceae burdock,common*,** camphorweed* Heterotheca subaxillaris annual Asteraceae chickweed,common* Stellaria media annual Caryophyllaceae chicory* Cichorium intybus perennial Asteraceae cudweed,purple Gnaphalium purpureum annual Asteraceae dandelion,common* Taraxacum offlcinale perennial Asteraceae dock,broadleaf* Rumex obtusifolius perennial Polygonaceae dock,curly* Rumex crispus perennial Polygonaceae dogfennel*** Eupatorium capillifolium perennial Asteraceae eveningprimrose,cutleaf* Oenothera laciniata annual Asteraceae falsedandelion,Carolina* Tragopogon dubius biennial Asteraceae fleabane,annual* Erigeron annus annual Asteraceae goldenrod,Canada* Solidago canadensis perennial Asteraceae Solidago missouriensis perennial Asteraceae goldenrod,Missouri* goldenrod,rigid Solidago rigida perennial Asteraceae henbit* Lamium amplexicaule annual/biennial Lamiaceae horseweed* Conyza canadensis annual Asteraceae ironweed,tall Vernonia gigantea perennial Asteraceae ironweed,western Vernonia baldwinii perennial Asteraceae kudzu*,** Pueraria montana perennial Fabaceae lambsquarters,common* Chenopodium album annual Chenopodiaceae lespedeza,annual Lespedeza striata annual Fabaceae locust Robinia pseudoacacia perennial Fabaceae marshelder,annual* Iva annua annual Asteraceae medic,black* Medicago lupulina perennial Fabaceae Mexican-tea Dysphania ambrosioides annual/perennial Chenopodiaceae mullein**** Verbascum spp. biennial Scrophulariaceae partridgepea* Chamaecrista fasciculata annual Fabaceae Plantago major perennial Plantaginaceae plantain,broadleaf* plantain,buckhorn* Plantago lanceolata perennial Plantaginaceae rose,multiflora***** Rosa multifiora perennial Rosaceae sicklepod* Senna obtusifolia annual Fabaceae smartweed,Pennsylvania Polygonum pensylvanicum annual Polygonaceae sodaapple,tropical*,** Solanum viarum perennial Solanaceae Spanishneedles Bidens bipinnata annual Asteraceae sunflower,common* Helianthus annua annual Asteraceae thistle,scotch Onopordum acanthium biennial Asteraceae yarrow,common* Achillea millefolium perennial Asteraceae *TheseplantsareindicatedtobeinvasiveintheUSDA-NRCS,PLANTSDatabase(http://plants.usda.gov/index.html). **Plantsdesignatedasnoxiousweedsinatleastonestate(PLANTSDatabase,USDA-NRCS,http://plants.usda.gov/index.html). ***Spottreatmentatratesupto84floz(5.2pints)ofGrazonNextmaybeparticularlyeffectiveagainstdensepatchesofperennialbroadleafplants. ****applyduringrosettestage *****seespecificuserecommendationsbelowformultiflorarose. Speciflc Use Recommendations Multifiora rose, individual plant treatment-Use42flozofGrazonNext in100galofwaterwith32floz(0.25%v/v)ofanon-ionicsurfactant.Or, 32flozofGrazonNextcanbetankmixedwithRemedyUltraat32floz. Applyfromfullleafthroughflowering.Forbestresults,delaytreatment for9-12monthsaftermowing.Spottreatmentsmaybeappliedatan equivalentbroadcastrateofupto84flozofGrazonNextperacreper annualgrowingseason;however,notmorethan50%ofanacremaybe treatedatthatrate. Multifiora rose, broadcast treatment:32to42flozofGrazonNextcan betankmixedwithRemedyUltraat16floz.Applyfromfullleafthrough flowering.Forbestresults,delaytreatmentfor9-12monthsaftermowing. Spray Drift Management Avoidapplicationunderconditionsthatmayallowspraydriftbecause verysmallquantitiesofspray,whichmaynotbevisible,mayseriously injurecrops.Thisproductshouldbeappliedonlywhenthepotentialfor drifttoadjacentsensitiveareas(e.g.,residentialareas,bodiesofwater, knownhabitatforthreatenedorendangeredspecies,non-targetcrops 6 SpecimenLabelRevised02-01-12 andotherplants)isminimal(e.g.,whenwindisblowingawayfromthe sensitiveareas.Adriftcontrolaidmaybeaddedtothespraysolutionto furtherreducethepotentialfordrift.Ifadriftcontrolaidisused,follow theusedirectionsandprecautionsonthemanufacturer'slabel.Donot useathickeningagentwithMicrofoil,Thru-Valvebooms,orotherspray deliverysystemsthatcannotaccommodatethickenedspraysolutions. Avarietyoffactorsincludingweatherconditions(e.g.,winddirection,wind speed,temperature,relativehumidity)andmethodofapplication(e.g., ground,aerial,airblast,chemigation)caninfluencepesticidedrift.The applicatormustevaluateallfactorsandmakeappropriateadjustments whenapplyingthisproduct. Droplet Size Whenapplyingspraysthatcontain2,4-Dasthesoleactiveingredient,or whenapplyingspraysthatcontain2,4-Dmixedwithactiveingredients thatrequireaCoarseorcoarserspray,applyonlyasaCoarseorcoarser spray(ASAEstandard572)oravolumemeandiameterof385micronsor greaterforspinningatomizernozzles. Whenapplyingspraysthatcontain2,4-Dmixedwithotheractive ingredientsthatrequireaMediumormorefinespray,applyonlyasa Mediumorcoarserspray(ASAEstandard572)oravolumemeandiameter of300micronsorgreaterforspinningatomizernozzles. Wind Speed Donotapplyatwindspeedsgreaterthan15mph.Onlyapplythis productifthewinddirectionfavorson-targetdepositionandthereare notsensitiveareas(including,butnotlimitedto,residentialareas,bodies ofwater,knownhabitatfornontargetspecies,nontargetcrops)within 250 feetdownwind.IfapplyingaMediumspray,leaveoneswatch unsprayedatthedownwindedgeofthetreatedfield. Temperature Inversions Ifapplyingat windspeedslessthan3mph,theapplicatormustdetermine if:a)conditionsoftemperatureinversionexist,orb)stableatmospheric conditionsexistatorbelownozzleheight.Donotmakeapplicationsinto areasoftemperatureinversionsorstableatmosphericconditions. Susceptible Plants Donotapplyundercircumstanceswherespraydriftmayoccurtofood, forage,orotherplantingsthatmightbedamagedorcropsthereof renderedunfitforsale,useorconsumption.Susceptiblecropsinclude, butarenotlimitedto,cotton,okra,flowers,fruittrees,grapes(ingrowing stage),fruittrees(foliage),soybeans(vegetativestage),ornamentals, sunflowers,tomatoes,beans,andothervegetables,ortobacco.Small amountsofspraydriftthatmaynotbevisiblemayinjuresusceptible broadleafplants. Other State and Local Requirements Applicatorsmustfollowallstateandlocalpesticidedriftrequirements regardingapplicationof2,4-Dherbicides.Wherestateshavemore stringentregulations,theymustbeobserved. Equipment Allaerialandgroundapplicationequipmentmustbeproperlymaintained andcalibratedusingappropriatecarriersorsurrogates. Aerial Application Theboomlengthmustnotexceed75%ofthewingspanor90%ofthe rotorbladediameter. Releasesprayatthelowestheightconsistentwithefficacyandflight safety.Donotreleasesprayataheightgreaterthan10feetabovethe cropcanopyunlessagreaterheightisrequiredforaircraftsafety.This requirementdoesnotapplytoforestryorrights-of-wayapplications. Whenapplicationsaremadewithacrosswind,theswathwillbedisplaced downwind.Theapplicatormustcompensateforthisbyadjustingthe pathoftheaircraftupwind. Ground Boom Application Donotapplywithanozzleheightgreaterthan4feetabovethecropcanopy. Terms and Conditions of Use IftermsofthefollowingWarrantyDisclaimer,InherentRisksofUseand LimitationofRemediesarenotacceptable,returnunopenedpackage atoncetothesellerforafullrefundofpurchasepricepaid.Tothe extentpermittedbylaw,otherwise,usebythebuyeroranyotheruser constitutesacceptanceofthetermsunderWarrantyDisclaimer,Inherent RisksofUseandLimitationofRemedies. Warranty Disclaimer DowAgroScienceswarrantsthatthisproductconformstothechemical descriptiononthelabelandisreasonablyfitforthepurposesstatedon thelabelwhenusedinstrictaccordancewiththedirections,subjectto theinherentriskssetforthbelow.Totheextentpermittedbylaw,Dow AgroSciencesMAKESNOOTHEREXPRESSORIMPLIEDWARRANTY OFMERCHANTABILITYORFITNESSFORAPARTICULARPURPOSEOR ANYOTHEREXPRESSORIMPLIEDWARRANTY. Inherent Risks of Use Itisimpossibletoeliminateallrisksassociatedwithuseofthisproduct. Cropinjury,lackofperformance,orotherunintendedconsequences mayresultbecauseofsuchfactorsasuseoftheproductcontraryto labelinstructions(includingconditionsnotedonthelabel,suchas unfavorabletemperatures,soilconditions,etc.),abnormalconditions (suchasexcessiverainfall,drought,tornadoes,hurricanes),presenceof othermaterials,themannerofapplication,orotherfactors,allofwhich arebeyondthecontrolofDowAgroSciencesortheseller.Totheextent permittedbylaw,allsuchrisksshallbeassumedbybuyer. Limitation of Remedies Totheextentpermittedbylaw,theexclusiveremedyforlossesor damagesresultingfromthisproduct(includingclaimsbasedoncontract, negligence,strictliability,orotherlegaltheories),shallbelimitedto,at DowAgroSciences'election,oneofthefollowing: 1.Refundofpurchasepricepaidbybuyeroruserforproductbought,or 2.Replacementofamountofproductused. Totheextentpermittedbylaw,DowAgroSciencesshallnotbeliablefor lossesordamagesresultingfromhandlingoruseofthisproductunless DowAgroSciencesispromptlynotifiedofsuchlossordamageinwriting. Totheextentpermittedbylaw,innocaseshallDowAgroSciencesbe liableforconsequentialorincidentaldamagesorlosses. ThetermsoftheWarrantyDisclaimer,InherentRisksofUseandthis LimitationofRemediescannotbevariedbyanywrittenorverbal statementsoragreements.NoemployeeorsalesagentofDow AgroSciencesorthesellerisauthorizedtovaryorexceedthetermsofthe WarrantyDisclaimerorthisLimitationofRemediesinanymanner. ® Trademark of Dow AgroSciences LLC Produced for Dow AgroSciences LLC 9330 Zionsville Road Indianapolis, IN 46268 LabelCode:D02-366-003 ReplacesLabel:D02-366-002 LOESNumber:010-02186 EPAaccepted08/04/11 Revisions: 1.Addedrestrictionforhayforgrasstreatedwithinthepreceding 18-monthstobeusedonlyonthefarmorranchwheretheproductis appliedunlessallowedbysupplementallabeling. 2.Revisedadvisorytextandgraphic 3.RevisedPPEandspraydriftsections 4.Seedinggrasses–Preemergence:revisetostatethatgrassescan bereseededinthefallfollowinganapplicationinthespringorearly summer. 5.Croprotation:addedcerealsandcornplantedoneyearafter treatment 6.Added18-monthrestrictionfortreatedplantresiduesincompost, mulch,ormushroomspawn 7.Addedrestrictiononuseofmanuretreatedwithinprevious3days 8.Addedcorntolistformanurefromanimalsthathavegrazedwithin theprevious3days 9.Addedrestrictionforcropsinfieldtreatedwithmanurefromanimals thathavegrazed 10.Addedrestrictionsforonandofffarmhay 11.Addedadvisoryforapplicationsmadeduringperiodofintenserainfall 12.ApplicationMethods:removed"broadcastupto"fromHighVolume FoliarApplication 7 SpecimenLabelRevised02-01-12
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