Chemistry States of Matter Key Ideas/Takeaways: 1. Characteristics of the three states of matter: solid, liquid, and gas 2. How a substance can change between the three states – by pressure or temperature Duration of Lesson: 60 minutes Materials: -Access to a large screen to show an online video -Alternative: -Empty, clear 2 liter soda bottle with the labels removed -A few tablespoons of rubbing alcohol -Bike pump -Rubber stopper with a hole in the middle for the bike pump/something to create a tight seal around the bike pump and the soda bottle that can be removed quickly -Enough of each of the following for each student: -Two Dixie cups -Two strips of paper towel -Few strips of tape -A pencil -Large cup -Four ice cubes -String -A few pinches of table salt -Bottle of rubbing alcohol -Bag of cotton balls -Water -Role of tape Introduction: (15 minutes) Begin by asking the students if they have heard of states of matter before and if they can name the three states: solid, liquid, and gas. Explain that the states of matter are three distinct, physical forms that matter takes on. Another word used to describe a state of matter is a phase. Matter is anything that takes up space, even if you can’t see how small it is. So, everything in the universe is made out of matter! Ask the students to list characteristics of each state and write them up on the board. Then, ask students to name examples of substances that they know change phases, such as water. Follow up by asking the students how they make these substances change phases. For example, for water, to change from a liquid to a solid, we freeze it. To change from a liquid to a gas, we boil it. Explain that one way to change the state of matter is by changing the substance’s temperature. Each substance has its own melting and boiling point. The melting point is the temperature at which a solid changes into a liquid or vice-versa. The boiling point is the temperature at which a liquid changes into a gas, and the other way around. Explain that when a substance’s temperature is raised, the substance has more energy. So when a solid changes to a liquid, the liquid has enough energy to break some of the bonds between the molecules so they can move more freely. Therefore, a gas has more energy than a liquid which has more energy than a solid. Heating up a substance adds energy whereas freezing a substance removes it. Now, have four or five student volunteers come up to the front of the classroom to help demonstrate the differences in the three phases. Start as a solid, with everyone huddled really closely together. Explain that the molecules that make up a solid objects are tightly packed together and can’t move – that’s why a solid feels rigid and it doesn’t change shape. Next, tell the students that they are going to warm up into a liquid. Have the volunteers grab hands. Even though the molecules are still connected and close to each other, they can move freely around. This is like a liquid which can moved and take the shape of the container it’s in, but it doesn’t completely spread out. Finally, have the students gain even more energy and change into a gas. Everyone let’s go of each other’s hands and they can spin and run around the class. Gas molecules have a lot of energy and thus, don’t like to be near each other, otherwise they’ll run into each other. The main part of the vocabulary for this lesson comes from the diagram below. This is a great visual aid for students to understand and relate the three phases of matter to one another. It’s important to walk through the diagram and explain that a solid doesn’t always have to change to a liquid before it changes to a gas. One example of a solid changing to a gas is dry ice which students should be familiar with. Dry ice is frozen carbon dioxide which has a melting point of -109.3 °F! To give the students perspective on how cold this is, explain that water freezes at 32 °F and boils at 212 °F. Because the environment surrounding dry ice is so warm (room temperature is around 70 °F), the carbon dioxide sublimes or changes straight from a solid to a gas. Cloud in the Bottle Demonstration Video: (5-10 minutes) Ask the students if they know the other way to change a substance’s state of matter. While they’re thinking about it, this is a good time to get the video set up to show: https://www.youtube.com/watch?v=msSVQ903T8k Alternatively, you can do this demo yourself. Take a two liter soda bottle, pour a few tablespoons of rubbing alcohol in it, then turn the bottle sideways and let the rubbing alcohol cover the inside of the bottle, all the way up to the opening. Then, place the bike pump in the opening of the bottle and create a tight seal so no air escapes. With one hand on the seal and another on the walls of the bottle, have a second person pump up the amount of air in the bottle. When the walls are very rigid and don’t bend under your hands, stop the pumping and quickly release the seal. A cloud should form in the bottle like in the video. While the cloud is still visible, you can also repump up the pressure in the bottle to force the alcohol vapor into its liquid form again. When you let go, the cloud will reappear. If they’re having trouble thinking of the answer (pressure), ask them if they’re ever watched the weather report on the news with their parents. Ask them what the weatherman talks about with sunny days versus cloudy days – he mentions changes in atmospheric pressure. So, the other way to change phases is by increasing or decreasing the pressure on the object. Pressure is another word for force. So, when there is a lot of pressure, a lot of force is being applied on the object. Now, explain the cloud in the bottle, telling students that you will show them how to create their own cloud using pressure, just like in the atmosphere. Pause the video after the bottle is pumped full of air and ask the students to predict what they think will happen when the scientists releases the seal. Then, show that portion, and pause again after the cloud forms to discuss what is happening. When the scientists pumps air into the bottle, all of the air molecules are being forced into a certain space, so they have to get really close together to fit, and as a result, there is a lot of pressure built up in the bottle. When the seal is released, the pressure is released, and as a result, the liquid rubbing alcohol turns into a gas. This is because the molecules are no longer being forced to be really close together in the liquid state and can instead, spread out into a gas. Now, show the class when the pump is used to push the cloud back into the liquid state, again, pausing the video to ask the students what will happen now that pressure is being applied to the gas-phase rubbing alcohol. So the takeaway message that students should get is that to change from a solid to a liquid to a gas, pressure has to be decreased so the molecules can spread out. In contrast, pressure has to be increased for a gas to change to a liquid and then to a solid. Rubbing Alcohol Evaporation Experiment: (15 minutes) Pass out the Dixie cups and strips of tape to students. They should already have pencils, but if not, pass those out as well. Then, show students how to construct their “drying line.” To do so, flip the Dixie cups upside-down on the table and lay a pencil on top of the two cups, making a bridge. Tape down the two pencil ends so it doesn’t role off. Now, have the students make theirs. Next, pass out two Dixie cups to each table group, one containing rubbing alcohol and one water. Also pass out two paper towel strips to each student. Have them label the strips so they know which one is for water and which one is for rubbing alcohol. Now, ask students whether different substances change phases at the same rate. After they’re done discussing, have them predict whether they think the water or the rubbing alcohol will evaporate faster. The students will then dip the water strip in the water cup and the alcohol strip in the alcohol cup and lay them out to dry over the pencil. Have the students watch the strips to observe how quickly the strips dry, noting which one is changing faster. Come back as a class to discuss their observations and discuss why the rubbing alcohol evaporated more quickly. This is because the rubbing alcohol is made up of different molecules than water, and these molecules don’t bond really well with each other. As a result, it requires less energy for them to break apart and change from a liquid to a gas. In comparison, the water molecules really like each other and bond very strongly, so it’s harder to break them apart and it takes longer to do so. Now, pass out cotton balls to each student. Either have them dip the cotton balls in the rubbing alcohol or walk around the classroom and use the original bottle. Have student wipe the tops of their hands with the rubbing alcohol and then make observations. They should notice how cool the rubbing alcohol feels and how quickly it evaporates, even faster than when it was hanging on the pencil. Some students won’t want to do this activity, but reassure them it’s perfectly safe and won’t hurt. Reconvene as a class to discuss their observations. Ask them if it felt cool or warm while it evaporated. A change that feels cool is endothermic. Endothermic reactions feel cool because they require energy in the form of heat. Another way to think of this is that if you have to share a bed with a sibling and your sibling steals the blanket (acting as energy in this scenario), then you’re going to be left without the energy and feel cold as a result. That’s what’s happening on your skin – the rubbing alcohol is using your warm body temperature to help it evaporate more quickly than it did on the pencil. Fishing with String Experiment: (15 minutes) Now, students will be trying to fish for ice cubes using string. Pass out the larger cups filled with cold water and four ice cubes dropped in each for each student. They can also do this activity in pairs. Also pass out the string and a Dixie cup or two containing table salt for each table. Then, have students try to use the string to “fish” for an ice cube. The rules of the game are that they can’t use their hands, they can only dip the string in the cup. The students won’t be able to pick up an ice cube. Now, have the students hold the string so that one end is resting on the surface of an ice cube. Now, have them pour salt over both the ice cube and the string, counting to 15 seconds after they’re done pouring. Now, have the students try fishing again. They should find that initially the salt melted the ice, but then the ice refroze to the string and now they can pull the ice cube out. Come back together as a class to discuss why the salt made fishing for ice cubes possible. We use salt on roads in the winter time to prevent them from freezing, but if it’s cold enough, then the water on the road will refreeze just like they did in the cup. As the ice cube refroze, the string got stuck in the ice which is why students were able to pull it out. Conclusion: (5 minutes) Go over the characteristics of the three states of matter and the two ways those states can be changed (temperature and pressure). Then, finish up by going over the vocabulary from the triangle diagram above.
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