Welcome to Chem 1A Significant Figures Any non zero number is significant 54, _______ significant figures Zeros between other significant numbers are significant 504, _______ significant figures Zeros left of non zero digit aren’t significant 0.00504, _______ significant figures 0000454, _______ significant figures For numbers greater than 1 all zeros right of decimal point are significant. 2.000, _____ significant figures Trailing zeros are not significant unless decimal point/sci notation is used. 4200, _______ significant figures 4200., _______significant figures 4.20x103 _____ significant figures. Significant Figures cont… Addition and Subtraction: use lowest number of “places”, decimal points, tens, hundreds ect…. 0.24 + 0.345 = _______ 3233 + 1300 = _______ Multiplication and Division: use lowest number of significant figures. 23*436 = ________ 453 / 3.2 = _______ Dimensional Analysis: Conversion Factors The average speed of helium at 25°C is 1255 m/s. Convert this to miles per hour How many minutes does it take light from the sun to reach earth given that the distance from the sun is 93 million miles and the speed of light is 3.00x108m/s Structure of an atom Bohr Model Isotopes, Natural Abundance, and molecular masses What is an isotope? ________________________________ Why are molecular masses on the periodic table decimal points? 51.839% 107Ag and the rest is 109Ag. Find the weighted average molecular mass. Periodic Table Empirical vs. Chemical Formulas Hydrazine Ethane 1,2-Ethanediol Molecular Formula N2H4 C2H6 C2H6O2 Empirical Formula NH2 CH3 CH3O Naming Ionic Lots of memorization: It is a pain. I know. Its also worth it so please, just do it. Molecular Acids Organic Don’t worry about it too much. I’ll refer to it from time to time, you have homework on it, but I won’t test you on it. Bonding: Finding that special element(s) that completes you Share or take electrons to be isoelectronic with noble gas. aka have a full octet. I have 6 valence electrons. Me too! How about me and you go back to my place and form a covalent bond or two? Types of Bonds Ionic: •“__________” electrons •___________________ Covalent: •“________” electrons •________________ Metallic: •delocalized electrons NaCl CO Ag •metals •electrically conductive •collective description of many bonds Ionic Bonds K + + K I I - •Elements want a ___________________ • Electrons are __________ • Elements develop a _______ F + Mg + F - 2+ - F Mg F Lewis Dot Structure Making Ionic Compounds 3+ Al 2O Making Ionic Compounds 2+ Mg 2O Charges of Atoms You need to know: Ions shown here Including ions with multiple charges Polyatomic ions Inert Pair Effect Tendency of heavier atoms to form ions with a difference in charge of two. Eventually we’ll use electron configurations to figure out the reasons for this. For now, why do you think it is? Section 1.19 Naming: Ionic Compounds: Extra notes for you: You need to know: Ions on last slide, use group of periodic table to help with memorizing. Polyatomic ions- see following slides Ions with multiple charges- see following slides Naming Ionic Compounds: Memorization Help -ate, -ite, ide per-, hypo- -ous -ic Memorize all –ate OR –ite in a group, then know that –ate, have one more oxygen atom than -ite -ic has one more charge than ous use the periodic table to help with charges Chapter 2 Naming Ionic Compounds Acids -ous -ic -ic has one more charge than –ous -ate ions turn into –ic acids, -ite ions turn into –ous acids Chapter 2 Ionic Naming Practice Write the formula of the following: Write the name of the following: Aluminum Oxide FeCl2 and FeCl3 Silver Sulfate Rb(SCN)2 Magnesium cyanide SnF2 Zinc Oxide Na3PO4 Covalent bonding: Molecular Compounds In a covalent bond electrons are shared Cl + Cl Covalent bonding: Molecular Compounds In a covalent bond electrons are shared 2 O O O O O Chapter 2 Naming: Molecular Compounds Composed of ________________ Prefix on the first word, ______________ Prefix on second word, ____________ Add ________as suffix to second word Molecular Compounds: Naming Practice Write the formula of the following: Carbon Monoxide Nitrogen trihydride Sulfur dioxide Sulfur hexafluoride Write the name of the following: S2F10 N2H4 PH3 PCl5 Moles, Masses and Chemical Reactions To convert from one chemical species to another use ____________ from balanced ______________ Example Problems: Calculate the number of cations and anions in 8.38 g of Na2O Platinum forms two different compounds with chlorine. One contains 26.7% Cl by mass and the other 42.1% Cl by mass. Find the empirical formula of each. One of the reactions that occurs in a blast furnace where iron ore is converted to cast iron, is shown below. Suppose that 1.64x103kg sample of Fe are obtained from 2.62x103 kg Fe2O3. Assuming that the reaction goes to completion, what is the percent purity of Fe2O3 in the original sample. Fe2O3+ CO Fe+CO2 A compound made up of C, H, and Cl contains 55.0% Cl by mass. If 9.00g of the compound contain 4.19x1023H atoms. What is the empirical formula of the compound? If the molecular mass is 193.5g/mol what is the molecular formula? Energy Energy= capacity to do work SI unit is J kg*m2/s2 Kinetic energy ½ mv2 Many types of energy gravitational potential energy, electromagnetic energy, thermal energy Total energy= Potential Energy+Kinetic Energy Example Mars orbits the Sun at 25 km/s. A spaceship attempting to land on mars must match its orbital speed. If the mass of the spaceship is 3.6x105kg, what is its kinetic energy when its speed has matched that of Mars? =1.1x1014 kg*m2*s-2=1.1x1014 J
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